JPS60112878A - 基材に対する透明フイルムの積層 - Google Patents

基材に対する透明フイルムの積層

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Publication number
JPS60112878A
JPS60112878A JP59229032A JP22903284A JPS60112878A JP S60112878 A JPS60112878 A JP S60112878A JP 59229032 A JP59229032 A JP 59229032A JP 22903284 A JP22903284 A JP 22903284A JP S60112878 A JPS60112878 A JP S60112878A
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JP
Japan
Prior art keywords
film
adhesive
curing
paper
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59229032A
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English (en)
Inventor
モハメツド　シエイリフ　サリム
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIIDO INTERN PLC
Original Assignee
RIIDO INTERN PLC
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Filing date
Publication date
Application filed by RIIDO INTERN PLC filed Critical RIIDO INTERN PLC
Publication of JPS60112878A publication Critical patent/JPS60112878A/ja
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112—Single lapped joints
    • B29C66/1122—Single lap to lap joints, i.e. overlap joints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/45—Joining of substantially the whole surface of the articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0008—Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1403—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the type of electromagnetic or particle radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1403—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the type of electromagnetic or particle radiation
    • B29C65/1406—Ultraviolet [UV] radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1429—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface
    • B29C65/1435—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the way of heating the interface at least passing through one of the parts to be joined, i.e. transmission welding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
    • B29C65/4845—Radiation curing adhesives, e.g. UV light curing adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/486—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by their physical form being non-liquid, e.g. in the form of granules or powders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1253—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives curable adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/72—Cured, e.g. vulcanised, cross-linked
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
    • B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
    • B32B2310/0831—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using UV radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
    • B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0875—Treatment by energy or chemical effects by wave energy or particle radiation using particle radiation
    • B32B2310/0887—Treatment by energy or chemical effects by wave energy or particle radiation using particle radiation using electron radiation, e.g. beta-rays

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Thermal Sciences (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 〔発明の要約〕 透明なフィルムをたとえば紙、紙状材料、プラスチック
および厚板などの基材に対し接着剤の媒体を介して積層
させ、この接着剤は紫外線または電子ビームにより硬化
することができる。
接着剤には透明フィルムを介し照射して、これをフィル
ムと基材とを合体させる作用により排除された酸素の不
存在下で硬化させる。低粘度と高引火点とを有する高固
形分の接着剤、たとえばメククリレ−１−およびジメタ
クリレートが好適である。
〔発明の属する技術分野〕
本発明は積層接着剤に関し、さらに紫外線および高エネ
ルギ電子ビームに対し透明なフィルムをたとえば紙、紙
状材料、プラスチックおよび厚板などの基材に積層する
ための接着剤に関するものである。
〔従来技術とその問題点〕
包装分野および表紙製造分野においては、透明プラスチ
ックフィルム（たとえば配向されたポリプロピレンまた
はポリエステル）を印刷紙または厚紙に積層して艶を有
し、耐久性でありかつ綺麗な生産物を与えることが知ら
れている。
この公知方法は溶剤または水性の接着剤（３０％〜５０
％固形分）を使用し、この接着剤をフィルムに塗布した
後これを赤外線加熱にかけて溶剤または水媒体を蒸発さ
せ、がっ硬化を開始される。次いで、このフィルムを紙
または厚紙に施こして、硬化を完結させる。
この方法は、溶剤（これは環境問題上面倒であるか、ま
たは有害であり、或いは高コストである）または水の分
散もしくは回収；積層品の単位面積当りの比較的高い消
費エネルギ；並びに比較的遅い（１５〜３０ｍ／ｍ１ｎ
）生産速度を伴なう。
〔発明の目的〕 したがって、本発明の目的は、高固形分（１００％に近
い）を有する接着剤を使用することができ、かつしたが
って溶剤の問題を伴なわず、照射線（たとえば紫外線ま
たは電子ビーム）により硬化させることができかっした
がって電力消費が低く、しかも使用する照射線源の数に
応じて比較的高い（５０〜１００　ｍ　／　ｍｉｎ　）
生産速度を有する積層方法を提供することである。
本発明は、大気酸素が抑制剤として作用するため、紫外
線硬化性接着剤の硬化が遅くなる傾向を有するという知
見に基づいている。しかしながら、基材に対しフィルム
を積層するという限られた範囲で使用する場合、フィル
ムと暴利とを合体させる簡単な動作によるだけで、硬化
を殆んど酸素のない環境で生ぜしめうるので、硬化が急
速に起りうろことが今回判明した。
〔発明の要点〕
したがって本発明によれば、紫外線および高エネルギ電
子ビームに対し透明なフィルムをたとえば紙、紙状材料
、プラスチックおよび厚板などの基材に積層する方法に
おいて、使用ずべく選択する接着剤を酸素の存在下で前
記紫外線または電子ビームによる硬化が遅いが酸素の不
存在下では硬化が早くなるものとして非黄色硬化生成物
を生成させ、かつ硬化をフィルムと基材とを合体させる
作用により排除された酸素の不存在下にてフィルムを通
る照射線により生ぜしめることを特徴とする積層方法が
提供される。
好適接着材は極めて高含量の固形分（１００％にさえな
る）を含有し、かつたとえば２１℃にて２．５　ｃｐｓ
という低粘度を有する。代表的な接着剤は、非黄色化光
開始剤と流動添加剤とを含むメタクリレートおよびジメ
タクリレート、並びに対応するアクリレート（たとえば
不飽和ウレタン、ポリエステルおよびエポキシアクリレ
ート）である。この種の接着剤はさらに、高引火点（典
型的には９５℃以上）という利点を有する。１００％よ
り相当低い固形分を含有する接着剤を使用しうるが、た
とえば赤外線による予備加熱を必要とする。提案される
接着剤は、ゴム配合に使用されるもの、或いはたとえば
ＰＶｃプラスチゾル、注型アクリルシートおよび歯科技
術などにおける改良剤として使用しうるものが現在推奨
される。
表紙材料を作成するために本発明を実施する１つの方法
において、厚さ１３μを有する配向されたポリプロピレ
ンの透明フィルムを、３０〜１００　ｒｎ　／　ｍｉｎ
の周速を有するローラにて、厚さ３００〜６００μおよ
びトリエチレングリコールジメタクリレートの被覆を有
する印刷厚板と接触させ、被覆は光開始剤としての１−
ヒドロキシシクロへキシルフェニルケトンと不飽和ウレ
タンアクリレート、ポリエステルアクリレ−１−および
エポキシアクリレートとを含有する。ローラにおける積
層工程の後、この積層品を２個の媒体圧力水銀紫外線ラ
ンプの下に通して、紫外線をフィルムに貫通させかつ接
着剤を硬化させる。
〔発明の効果〕
高固形分（典型的には９５〜１００％）につき使用する
場合、本発明の方法は任意公知の方法よりも迅速であり
、無駄がなくなり、揮発物がなくなり、引火問題を防止
し、がっ非毒性である。使用する装置は長い赤外線炉が
必要とされないので小型となり、かつ生産物はその艶、
耐久性および透明度が高くなる。

Claims (4)

    【特許請求の範囲】
  1. （１）　紫外線および高エネルギ電子ビームに対し透明
    なフィルムをたとえば紙、紙状材料、プラスチックおよ
    び厚板などの基材に積層する方法において、使用すべく
    選択する接着剤を酸素の存在下で前記紫外線または電子
    ビームによる硬化が遅いが、酸素の不存在下では硬化が
    早くなるものとして、非黄色硬化生成物を生成させ、か
    つ硬化をフィルムと基剤とを合体させる作用により排除
    された酸素の不存在下にて、フィルムを通る照射線によ
    り生せしめることを特徴とする積層方法。
  2. （２）接着剤が９５〜１００％の固形分を含有する特許
    請求の範囲第１項記載の方法。
  3. （３）接着剤が２１℃にて約２．５　ｃｐｓ程度の低密
    度を有する特許請求の範囲第２項記載の方法。
  4. （４）接着剤が９５℃以上の引火点を有するメタクリレ
    ートまたはジメタクリレートである特許請求の範囲第３
    項記載の方法。
JP59229032A 1983-11-05 1984-11-01 基材に対する透明フイルムの積層 Pending JPS60112878A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB08329593A GB2148792A (en) 1983-11-05 1983-11-05 Laminating transparent film to a base
GB8329593 1983-11-05

Publications (1)

Publication Number Publication Date
JPS60112878A true JPS60112878A (ja) 1985-06-19

Family

ID=10551303

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59229032A Pending JPS60112878A (ja) 1983-11-05 1984-11-01 基材に対する透明フイルムの積層

Country Status (8)

Country Link
EP (1) EP0142312A3 (ja)
JP (1) JPS60112878A (ja)
AU (1) AU3493784A (ja)
DK (1) DK523684A (ja)
ES (1) ES8606095A1 (ja)
FI (1) FI844295L (ja)
GB (1) GB2148792A (ja)
NO (1) NO844281L (ja)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1319341C (en) * 1985-03-29 1993-06-22 Frederick J. Fox Method of supporting a louvered plastic film
US4766023A (en) * 1987-01-16 1988-08-23 Minnesota Mining And Manufacturing Company Method for making a flexible louvered plastic film with protective coatings and film produced thereby
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ES8606095A1 (es) 1986-04-01
ES537382A0 (es) 1986-04-01
FI844295A0 (fi) 1984-11-01
GB2148792A (en) 1985-06-05
GB8329593D0 (en) 1983-12-07
EP0142312A2 (en) 1985-05-22
EP0142312A3 (en) 1986-06-18
AU3493784A (en) 1985-05-09
NO844281L (no) 1985-05-06
FI844295L (fi) 1985-05-06
DK523684A (da) 1985-05-06
DK523684D0 (da) 1984-11-02

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