JPS5884889A - パラフインの異性化法 - Google Patents
パラフインの異性化法Info
- Publication number
- JPS5884889A JPS5884889A JP57189390A JP18939082A JPS5884889A JP S5884889 A JPS5884889 A JP S5884889A JP 57189390 A JP57189390 A JP 57189390A JP 18939082 A JP18939082 A JP 18939082A JP S5884889 A JPS5884889 A JP S5884889A
- Authority
- JP
- Japan
- Prior art keywords
- isomerization
- catalyst
- hydrogen
- nickel
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 description 26
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- 239000001257 hydrogen Substances 0.000 description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- 238000006317 isomerization reaction Methods 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 8
- 229910052914 metal silicate Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 229940078487 nickel acetate tetrahydrate Drugs 0.000 description 2
- OINIXPNQKAZCRL-UHFFFAOYSA-L nickel(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Ni+2].CC([O-])=O.CC([O-])=O OINIXPNQKAZCRL-UHFFFAOYSA-L 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- FGRBYDKOBBBPOI-UHFFFAOYSA-N 10,10-dioxo-2-[4-(N-phenylanilino)phenyl]thioxanthen-9-one Chemical compound O=C1c2ccccc2S(=O)(=O)c2ccc(cc12)-c1ccc(cc1)N(c1ccccc1)c1ccccc1 FGRBYDKOBBBPOI-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101000583556 Paramecium tetraurelia Phosphoglucomutase-1 Proteins 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000001030 gas--liquid chromatography Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Lubricants (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8104950 | 1981-11-02 | ||
| NL8104950A NL8104950A (nl) | 1981-11-02 | 1981-11-02 | Werkwijze voor het isomeriseren van paraffinen. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5884889A true JPS5884889A (ja) | 1983-05-21 |
Family
ID=19838306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57189390A Pending JPS5884889A (ja) | 1981-11-02 | 1982-10-29 | パラフインの異性化法 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4417090A (enExample) |
| EP (1) | EP0079091B1 (enExample) |
| JP (1) | JPS5884889A (enExample) |
| AT (1) | ATE13518T1 (enExample) |
| AU (1) | AU547287B2 (enExample) |
| CA (1) | CA1183877A (enExample) |
| DE (1) | DE3263912D1 (enExample) |
| DK (1) | DK437682A (enExample) |
| ES (1) | ES8307196A1 (enExample) |
| FI (1) | FI71924C (enExample) |
| NL (1) | NL8104950A (enExample) |
| NO (1) | NO162231C (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8201716A (nl) * | 1982-04-26 | 1983-11-16 | Shell Int Research | Werkwijze voor de bereiding van een katalytisch actief metaalsilicaat. |
| US4497903A (en) * | 1982-12-17 | 1985-02-05 | Gulf Research & Development Company | Activated cobalt-substituted layered aluminosilicate for synthesis gas conversion |
| US4757040A (en) * | 1985-04-01 | 1988-07-12 | Research Institute Of Petroleum Processing Sinopec | Class of pillared interlayered clay molecular sieve products with regularly interstratified mineral structure |
| JPH0624971B2 (ja) * | 1989-03-06 | 1994-04-06 | 工業技術院長 | イオン固着により減少したモンモリロナイトのカチオン交換容量の回復法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3766292A (en) * | 1970-11-23 | 1973-10-16 | Chevron Res | Process for obtaining isopentane from butane hexane or mixtures thereof |
| US4022684A (en) * | 1974-04-18 | 1977-05-10 | Gulf Research & Development Company | Hydrocarbon conversion process using a Ni and/or CO substituted synthetic aluminosilicate catalyst |
-
1981
- 1981-11-02 NL NL8104950A patent/NL8104950A/nl not_active Application Discontinuation
-
1982
- 1982-09-30 US US06/430,470 patent/US4417090A/en not_active Expired - Fee Related
- 1982-10-01 DK DK437682A patent/DK437682A/da not_active Application Discontinuation
- 1982-10-07 AT AT82201247T patent/ATE13518T1/de not_active IP Right Cessation
- 1982-10-07 CA CA000413008A patent/CA1183877A/en not_active Expired
- 1982-10-07 EP EP82201247A patent/EP0079091B1/en not_active Expired
- 1982-10-07 DE DE8282201247T patent/DE3263912D1/de not_active Expired
- 1982-10-28 ES ES516908A patent/ES8307196A1/es not_active Expired
- 1982-10-29 FI FI823705A patent/FI71924C/fi not_active IP Right Cessation
- 1982-10-29 NO NO823605A patent/NO162231C/no unknown
- 1982-10-29 AU AU90023/82A patent/AU547287B2/en not_active Ceased
- 1982-10-29 JP JP57189390A patent/JPS5884889A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FI71924C (fi) | 1987-03-09 |
| ES516908A0 (es) | 1983-06-16 |
| DK437682A (da) | 1983-05-03 |
| EP0079091A1 (en) | 1983-05-18 |
| NO162231C (no) | 1989-12-06 |
| US4417090A (en) | 1983-11-22 |
| DE3263912D1 (en) | 1985-07-04 |
| AU9002382A (en) | 1983-05-12 |
| CA1183877A (en) | 1985-03-12 |
| NO162231B (enExample) | 1989-08-21 |
| FI823705A0 (fi) | 1982-10-29 |
| ATE13518T1 (de) | 1985-06-15 |
| FI71924B (fi) | 1986-11-28 |
| NL8104950A (nl) | 1983-06-01 |
| FI823705L (fi) | 1983-05-03 |
| AU547287B2 (en) | 1985-10-10 |
| ES8307196A1 (es) | 1983-06-16 |
| EP0079091B1 (en) | 1985-05-29 |
| NO823605L (no) | 1983-05-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Choudhary et al. | H-gallosilicate (MFI) propane aromatization catalyst: Influence of Si/Ga ratio on acidity, activity and deactivation due to coking | |
| DE69701462T2 (de) | Verfahren zur metathese von alkanen | |
| Erofeev et al. | Production of high-octane gasoline from straight-run gasoline on ZSM-5 modified zeolites | |
| JPH02222727A (ja) | ゼオライトを含む触媒及びその製造方法 | |
| JPS5824353A (ja) | 複合ゼオライト | |
| JPH08311461A (ja) | プレミアム異性化ガソリン生成用水素化処理方法 | |
| JPH07500854A (ja) | パラフィン異性化/開環を組合わせた方法 | |
| JPS5926920A (ja) | 改良されたゼオライトの製造方法ならびに得られたゼオライトおよびその使用方法 | |
| CA1185227A (fr) | Titanoborosilicate cristallin et procede de preparation | |
| JP2909591B2 (ja) | 第▲viii▼族の少なくとも1つの金属を含むモルデナイトベース触媒および芳香族c▲下8▼留分の異性化におけるその使用 | |
| EP0090442B1 (en) | Process for the preparation of catalytically active cross-linked metal silicate | |
| JPS6014006B2 (ja) | キシレンの異性化 | |
| US3267023A (en) | Hydrocracking with a crystalline zeolite admixed with a dehydrogenation catalyst | |
| JPS5884889A (ja) | パラフインの異性化法 | |
| JP2905941B2 (ja) | 特定のオメガゼオライトをベースとする少なくとも1つの触媒の存在下における正パラフィンの異性化方法 | |
| US3673267A (en) | Isomerization of cyclohexane in the presence of a mordenite catalyst | |
| US3475345A (en) | Catalyst for paraffin isomerization | |
| JPS62158224A (ja) | アルコール類及びエーテル類からの軽質オレフイン類の製造 | |
| US3314895A (en) | Processes for selective demethylation and for preparation of catalysts for use therein | |
| JP2006518802A (ja) | Atsゼオライトを使用して高ronガソリンを製造する方法 | |
| US5107054A (en) | Zeolite MCM-22 based catalyst for paraffin isomerization | |
| JPS6245540A (ja) | 炭化水素供給原料からの芳香族炭化水素の製造方法 | |
| JPS6333901B2 (enExample) | ||
| CA1195312A (en) | Process for the preparation of a catalytically active metal silicate | |
| DE69324194T2 (de) | Katalysator und verfahren zur dehydrierung von kohlenwasserstoffen |