FI71924C - Foerfarande foer isomerisering av paraffin. - Google Patents
Foerfarande foer isomerisering av paraffin. Download PDFInfo
- Publication number
- FI71924C FI71924C FI823705A FI823705A FI71924C FI 71924 C FI71924 C FI 71924C FI 823705 A FI823705 A FI 823705A FI 823705 A FI823705 A FI 823705A FI 71924 C FI71924 C FI 71924C
- Authority
- FI
- Finland
- Prior art keywords
- hydrogen
- temperature
- catalyst
- metal silicate
- paraffins
- Prior art date
Links
- 239000012188 paraffin wax Substances 0.000 title description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 31
- 239000001257 hydrogen Substances 0.000 claims abstract description 31
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 17
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 10
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 6
- 239000010941 cobalt Substances 0.000 claims abstract description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052914 metal silicate Inorganic materials 0.000 claims description 15
- 238000006317 isomerization reaction Methods 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 abstract description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 14
- 239000000047 product Substances 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 2
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 229940078494 nickel acetate Drugs 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000009089 cytolysis Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000001030 gas--liquid chromatography Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Lubricants (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8104950 | 1981-11-02 | ||
| NL8104950A NL8104950A (nl) | 1981-11-02 | 1981-11-02 | Werkwijze voor het isomeriseren van paraffinen. |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI823705A0 FI823705A0 (fi) | 1982-10-29 |
| FI823705L FI823705L (fi) | 1983-05-03 |
| FI71924B FI71924B (fi) | 1986-11-28 |
| FI71924C true FI71924C (fi) | 1987-03-09 |
Family
ID=19838306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI823705A FI71924C (fi) | 1981-11-02 | 1982-10-29 | Foerfarande foer isomerisering av paraffin. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4417090A (enExample) |
| EP (1) | EP0079091B1 (enExample) |
| JP (1) | JPS5884889A (enExample) |
| AT (1) | ATE13518T1 (enExample) |
| AU (1) | AU547287B2 (enExample) |
| CA (1) | CA1183877A (enExample) |
| DE (1) | DE3263912D1 (enExample) |
| DK (1) | DK437682A (enExample) |
| ES (1) | ES8307196A1 (enExample) |
| FI (1) | FI71924C (enExample) |
| NL (1) | NL8104950A (enExample) |
| NO (1) | NO162231C (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8201716A (nl) * | 1982-04-26 | 1983-11-16 | Shell Int Research | Werkwijze voor de bereiding van een katalytisch actief metaalsilicaat. |
| US4497903A (en) * | 1982-12-17 | 1985-02-05 | Gulf Research & Development Company | Activated cobalt-substituted layered aluminosilicate for synthesis gas conversion |
| US4757040A (en) * | 1985-04-01 | 1988-07-12 | Research Institute Of Petroleum Processing Sinopec | Class of pillared interlayered clay molecular sieve products with regularly interstratified mineral structure |
| JPH0624971B2 (ja) * | 1989-03-06 | 1994-04-06 | 工業技術院長 | イオン固着により減少したモンモリロナイトのカチオン交換容量の回復法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3766292A (en) * | 1970-11-23 | 1973-10-16 | Chevron Res | Process for obtaining isopentane from butane hexane or mixtures thereof |
| US4022684A (en) * | 1974-04-18 | 1977-05-10 | Gulf Research & Development Company | Hydrocarbon conversion process using a Ni and/or CO substituted synthetic aluminosilicate catalyst |
-
1981
- 1981-11-02 NL NL8104950A patent/NL8104950A/nl not_active Application Discontinuation
-
1982
- 1982-09-30 US US06/430,470 patent/US4417090A/en not_active Expired - Fee Related
- 1982-10-01 DK DK437682A patent/DK437682A/da not_active Application Discontinuation
- 1982-10-07 AT AT82201247T patent/ATE13518T1/de not_active IP Right Cessation
- 1982-10-07 CA CA000413008A patent/CA1183877A/en not_active Expired
- 1982-10-07 EP EP82201247A patent/EP0079091B1/en not_active Expired
- 1982-10-07 DE DE8282201247T patent/DE3263912D1/de not_active Expired
- 1982-10-28 ES ES516908A patent/ES8307196A1/es not_active Expired
- 1982-10-29 FI FI823705A patent/FI71924C/fi not_active IP Right Cessation
- 1982-10-29 NO NO823605A patent/NO162231C/no unknown
- 1982-10-29 AU AU90023/82A patent/AU547287B2/en not_active Ceased
- 1982-10-29 JP JP57189390A patent/JPS5884889A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ES516908A0 (es) | 1983-06-16 |
| DK437682A (da) | 1983-05-03 |
| JPS5884889A (ja) | 1983-05-21 |
| EP0079091A1 (en) | 1983-05-18 |
| NO162231C (no) | 1989-12-06 |
| US4417090A (en) | 1983-11-22 |
| DE3263912D1 (en) | 1985-07-04 |
| AU9002382A (en) | 1983-05-12 |
| CA1183877A (en) | 1985-03-12 |
| NO162231B (enExample) | 1989-08-21 |
| FI823705A0 (fi) | 1982-10-29 |
| ATE13518T1 (de) | 1985-06-15 |
| FI71924B (fi) | 1986-11-28 |
| NL8104950A (nl) | 1983-06-01 |
| FI823705L (fi) | 1983-05-03 |
| AU547287B2 (en) | 1985-10-10 |
| ES8307196A1 (es) | 1983-06-16 |
| EP0079091B1 (en) | 1985-05-29 |
| NO823605L (no) | 1983-05-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: SHELL INTERNATIONALE RESEARCH |