JPS5871913A - 過早の反応に対するポリエ−テル−またはポリエステル成形用組成物の安定化法 - Google Patents
過早の反応に対するポリエ−テル−またはポリエステル成形用組成物の安定化法Info
- Publication number
- JPS5871913A JPS5871913A JP57171081A JP17108182A JPS5871913A JP S5871913 A JPS5871913 A JP S5871913A JP 57171081 A JP57171081 A JP 57171081A JP 17108182 A JP17108182 A JP 17108182A JP S5871913 A JPS5871913 A JP S5871913A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- methyl
- pentene
- diphenyl
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 229920000728 polyester Polymers 0.000 title description 2
- 238000007348 radical reaction Methods 0.000 title 1
- 230000006641 stabilisation Effects 0.000 title 1
- 238000011105 stabilization Methods 0.000 title 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229940029284 trichlorofluoromethane Drugs 0.000 claims abstract description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 13
- 150000001412 amines Chemical class 0.000 claims abstract description 10
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004604 Blowing Agent Substances 0.000 claims abstract description 5
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 3
- 239000003381 stabilizer Substances 0.000 claims description 22
- -1 methyl-6-phenylindene Chemical compound 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims 3
- 230000002028 premature Effects 0.000 claims 1
- ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 abstract description 9
- 229920005830 Polyurethane Foam Polymers 0.000 abstract description 4
- 239000011496 polyurethane foam Substances 0.000 abstract description 4
- 238000010944 pre-mature reactiony Methods 0.000 abstract description 3
- VOOVDZMAQQVAEW-PFONDFGASA-N [(z)-2-methyl-4-phenylpent-3-en-2-yl]benzene Chemical class C=1C=CC=CC=1C(/C)=C\C(C)(C)C1=CC=CC=C1 VOOVDZMAQQVAEW-PFONDFGASA-N 0.000 abstract 2
- ICLPNZMYHDVKKI-UHFFFAOYSA-N 1,1,3-trimethyl-3-phenyl-2h-indene Chemical compound C12=CC=CC=C2C(C)(C)CC1(C)C1=CC=CC=C1 ICLPNZMYHDVKKI-UHFFFAOYSA-N 0.000 abstract 1
- ZZLCFHIKESPLTH-UHFFFAOYSA-N 4-Methylbiphenyl Chemical compound C1=CC(C)=CC=C1C1=CC=CC=C1 ZZLCFHIKESPLTH-UHFFFAOYSA-N 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 7
- 229920005862 polyol Polymers 0.000 description 7
- 150000003077 polyols Chemical class 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 235000011837 pasties Nutrition 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001414 amino alcohols Chemical group 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- FYZZJDABXBPMOG-UHFFFAOYSA-N ethanol;n-methylmethanamine Chemical compound CCO.CNC FYZZJDABXBPMOG-UHFFFAOYSA-N 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- MMSLOZQEMPDGPI-UHFFFAOYSA-N p-Mentha-1,3,5,8-tetraene Chemical compound CC(=C)C1=CC=C(C)C=C1 MMSLOZQEMPDGPI-UHFFFAOYSA-N 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- VNAFWALXWOAPCK-UHFFFAOYSA-N 1-phenyl-2,3-dihydro-1h-indene Chemical compound C1CC2=CC=CC=C2C1C1=CC=CC=C1 VNAFWALXWOAPCK-UHFFFAOYSA-N 0.000 description 1
- WCVOGSZTONGSQY-UHFFFAOYSA-N 2,4,6-trichloroanisole Chemical compound COC1=C(Cl)C=C(Cl)C=C1Cl WCVOGSZTONGSQY-UHFFFAOYSA-N 0.000 description 1
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 1
- PFBLYDIOJAYTTH-UHFFFAOYSA-N 3,3-dimethyl-1-phenyl-1,2-dihydroindene Chemical compound C12=CC=CC=C2C(C)(C)CC1C1=CC=CC=C1 PFBLYDIOJAYTTH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 241001385733 Aesculus indica Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 208000000474 Poliomyelitis Diseases 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002468 indanes Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229940035339 tri-chlor Drugs 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3278—Hydroxyamines containing at least three hydroxy groups
- C08G18/3281—Hydroxyamines containing at least three hydroxy groups containing three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Developing Agents For Electrophotography (AREA)
- Separation, Sorting, Adjustment, Or Bending Of Sheets To Be Conveyed (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3139401A DE3139401C2 (de) | 1981-10-03 | 1981-10-03 | Stabilisieren von Polyether- oder Polyester-Formmassen gegen vorzeitige Reaktion |
| DE31394019 | 1981-10-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5871913A true JPS5871913A (ja) | 1983-04-28 |
Family
ID=6143332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57171081A Pending JPS5871913A (ja) | 1981-10-03 | 1982-10-01 | 過早の反応に対するポリエ−テル−またはポリエステル成形用組成物の安定化法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4463189A (en, 2012) |
| EP (1) | EP0076471B1 (en, 2012) |
| JP (1) | JPS5871913A (en, 2012) |
| AT (1) | ATE17016T1 (en, 2012) |
| AU (1) | AU555115B2 (en, 2012) |
| BR (1) | BR8205775A (en, 2012) |
| CA (1) | CA1189305A (en, 2012) |
| DE (2) | DE3139401C2 (en, 2012) |
| DK (1) | DK438082A (en, 2012) |
| ES (1) | ES516122A0 (en, 2012) |
| FI (1) | FI73450C (en, 2012) |
| GR (1) | GR76711B (en, 2012) |
| IL (1) | IL66898A0 (en, 2012) |
| NO (1) | NO158424C (en, 2012) |
| PT (1) | PT75644B (en, 2012) |
| ZA (1) | ZA827206B (en, 2012) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3730221A1 (de) * | 1987-09-09 | 1989-03-30 | Kali Chemie Ag | Stabilisierung von chlorfluoralkanen |
| DE4028747A1 (de) * | 1990-09-11 | 1992-03-12 | Hoechst Ag | Stabilisierung von cf(pfeil abwaerts)3(pfeil abwaerts)-chcl(pfeil abwaerts)2(pfeil abwaerts) oder cclf(pfeil abwaerts)2(pfeil abwaerts)-chclf oder deren mischungen gegen die reaktion mit kaeltemaschinenoel |
| SI9200047A (en) * | 1991-04-11 | 1992-11-27 | Ausimont S.P.A. | Methods for inhibition of degradation of chlorofluorhydrocarbons used as foaming agents in polyurethane and polyisocianurate foams preparation |
| US5436276A (en) * | 1993-11-10 | 1995-07-25 | International Flavors & Fragrances Inc. | Method for determining the hardness of fragrance containing polyurethane foams |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL284875A (en, 2012) * | 1961-10-30 | |||
| US3352789A (en) * | 1964-01-10 | 1967-11-14 | Allied Chem | Stabilization of chlorofluoroalkanes |
| US3465052A (en) * | 1966-06-15 | 1969-09-02 | Daikin Ind Ltd | Stabilized chlorofluoroalkane compositions |
-
1981
- 1981-10-03 DE DE3139401A patent/DE3139401C2/de not_active Expired
-
1982
- 1982-09-21 US US06/420,938 patent/US4463189A/en not_active Expired - Fee Related
- 1982-09-30 ES ES516122A patent/ES516122A0/es active Granted
- 1982-09-30 AT AT82109040T patent/ATE17016T1/de not_active IP Right Cessation
- 1982-09-30 EP EP82109040A patent/EP0076471B1/de not_active Expired
- 1982-09-30 FI FI823346A patent/FI73450C/fi not_active IP Right Cessation
- 1982-09-30 DE DE8282109040T patent/DE3268050D1/de not_active Expired
- 1982-09-30 IL IL66898A patent/IL66898A0/xx not_active IP Right Cessation
- 1982-10-01 NO NO823313A patent/NO158424C/no unknown
- 1982-10-01 ZA ZA827206A patent/ZA827206B/xx unknown
- 1982-10-01 AU AU88959/82A patent/AU555115B2/en not_active Ceased
- 1982-10-01 CA CA000412709A patent/CA1189305A/en not_active Expired
- 1982-10-01 BR BR8205775A patent/BR8205775A/pt not_active IP Right Cessation
- 1982-10-01 PT PT75644A patent/PT75644B/pt not_active IP Right Cessation
- 1982-10-01 JP JP57171081A patent/JPS5871913A/ja active Pending
- 1982-10-01 GR GR69415A patent/GR76711B/el unknown
- 1982-10-01 DK DK438082A patent/DK438082A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CA1189305A (en) | 1985-06-25 |
| NO158424C (no) | 1988-09-07 |
| ES8504878A1 (es) | 1985-05-16 |
| FI73450B (fi) | 1987-06-30 |
| FI823346L (fi) | 1983-04-04 |
| PT75644A (fr) | 1982-11-01 |
| GR76711B (en, 2012) | 1984-08-29 |
| NO823313L (no) | 1983-04-05 |
| NO158424B (no) | 1988-05-30 |
| FI823346A0 (fi) | 1982-09-30 |
| IL66898A0 (en) | 1982-12-31 |
| EP0076471A3 (en) | 1984-03-07 |
| EP0076471A2 (de) | 1983-04-13 |
| EP0076471B1 (de) | 1985-12-18 |
| ZA827206B (en) | 1983-08-31 |
| ATE17016T1 (de) | 1986-01-15 |
| FI73450C (fi) | 1987-10-09 |
| DK438082A (da) | 1983-04-04 |
| US4463189A (en) | 1984-07-31 |
| PT75644B (fr) | 1985-10-04 |
| DE3139401C2 (de) | 1985-12-12 |
| ES516122A0 (es) | 1985-05-16 |
| BR8205775A (pt) | 1983-09-06 |
| AU555115B2 (en) | 1986-09-11 |
| AU8895982A (en) | 1983-04-14 |
| DE3139401A1 (de) | 1983-04-21 |
| DE3268050D1 (en) | 1986-01-30 |
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