JPS58185686A - 石油留分の水素処理方法 - Google Patents
石油留分の水素処理方法Info
- Publication number
- JPS58185686A JPS58185686A JP58059131A JP5913183A JPS58185686A JP S58185686 A JPS58185686 A JP S58185686A JP 58059131 A JP58059131 A JP 58059131A JP 5913183 A JP5913183 A JP 5913183A JP S58185686 A JPS58185686 A JP S58185686A
- Authority
- JP
- Japan
- Prior art keywords
- offretite
- catalyst
- hydrogen
- silica
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003208 petroleum Substances 0.000 title claims description 16
- 238000005984 hydrogenation reaction Methods 0.000 title description 2
- 239000003054 catalyst Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 238000011282 treatment Methods 0.000 claims description 10
- 239000010457 zeolite Substances 0.000 claims description 9
- 229910021536 Zeolite Inorganic materials 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 8
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- -1 ammonium ions Chemical class 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910001414 potassium ion Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910001415 sodium ion Inorganic materials 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 150000001868 cobalt Chemical class 0.000 claims description 2
- 230000003009 desulfurizing effect Effects 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- 229910021645 metal ion Inorganic materials 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 239000005078 molybdenum compound Substances 0.000 claims 1
- 150000002752 molybdenum compounds Chemical class 0.000 claims 1
- 150000002816 nickel compounds Chemical class 0.000 claims 1
- 150000003658 tungsten compounds Chemical class 0.000 claims 1
- 239000003921 oil Substances 0.000 description 22
- 238000006477 desulfuration reaction Methods 0.000 description 8
- 230000023556 desulfurization Effects 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 2
- 239000005695 Ammonium acetate Substances 0.000 description 2
- 101150096414 MIM2 gene Proteins 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 229940043376 ammonium acetate Drugs 0.000 description 2
- 235000019257 ammonium acetate Nutrition 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000002751 molybdenum Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 150000003657 tungsten Chemical group 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/26—Drill bits with leading portion, i.e. drill bits with a pilot cutter; Drill bits for enlarging the borehole, e.g. reamers
- E21B10/28—Drill bits with leading portion, i.e. drill bits with a pilot cutter; Drill bits for enlarging the borehole, e.g. reamers with non-expansible roller cutters
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/08—Roller bits
- E21B10/10—Roller bits with roller axle supported at both ends
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D1/00—Sinking shafts
- E21D1/03—Sinking shafts mechanically, e.g. by loading shovels or loading buckets, scraping devices, conveying screws
- E21D1/06—Sinking shafts mechanically, e.g. by loading shovels or loading buckets, scraping devices, conveying screws with shaft-boring cutters
Landscapes
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- Earth Drilling (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US376793 | 1982-05-10 | ||
| US06/376,793 US4448270A (en) | 1982-05-10 | 1982-05-10 | Variable diameter earth boring bit |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58185686A true JPS58185686A (ja) | 1983-10-29 |
Family
ID=23486525
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58059131A Pending JPS58185686A (ja) | 1982-05-10 | 1983-04-04 | 石油留分の水素処理方法 |
| JP58071343A Granted JPS58195686A (ja) | 1982-05-10 | 1983-04-21 | ア−スボ−リングビツト |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58071343A Granted JPS58195686A (ja) | 1982-05-10 | 1983-04-21 | ア−スボ−リングビツト |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4448270A (enExample) |
| JP (2) | JPS58185686A (enExample) |
| AU (1) | AU543855B2 (enExample) |
| CA (1) | CA1185276A (enExample) |
| DE (1) | DE3313396C2 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4697652A (en) * | 1986-09-19 | 1987-10-06 | Reed Mining Tools, Inc. | Reversible roller stabilizer extensions for earth boring head |
| TWI221501B (en) * | 2001-07-23 | 2004-10-01 | Taisei Corp | Shield tunneling method and shield tunneling machine |
| US8252225B2 (en) * | 2009-03-04 | 2012-08-28 | Baker Hughes Incorporated | Methods of forming erosion-resistant composites, methods of using the same, and earth-boring tools utilizing the same in internal passageways |
| US7828089B2 (en) * | 2007-12-14 | 2010-11-09 | Baker Hughes Incorporated | Erosion resistant fluid passageways and flow tubes for earth-boring tools, methods of forming the same and earth-boring tools including the same |
| CN110735640B (zh) * | 2019-11-06 | 2022-03-22 | 中国铁建重工集团股份有限公司 | 一种竖井掘进机及其刀盘 |
| CN113250701B (zh) * | 2021-06-15 | 2021-09-21 | 中国铁建重工集团股份有限公司 | 一种竖井掘进机及其刀盘 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS505335A (enExample) * | 1973-02-09 | 1975-01-21 | ||
| JPS55127491A (en) * | 1979-03-19 | 1980-10-02 | Mobil Oil | Method of catalytically dewaxing hydrocarbon oil with synthetic offretite |
| JPS55145793A (en) * | 1979-04-27 | 1980-11-13 | Mobil Oil | Contact dewaxing method of hydrocarbon oil |
| JPS5620087A (en) * | 1979-07-30 | 1981-02-25 | Mitsubishi Chem Ind Ltd | Conversion of hydrocarbon |
| US4255282A (en) * | 1979-05-11 | 1981-03-10 | Union Oil Company Of California | Hydrotreating catalyst and process for its preparation |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1066161B (de) * | 1959-10-01 | Hughes Tool Company, Houston, Tex. (V. St. A.) | Rollenbohrmeißel mit großem Durchmesser | |
| US961115A (en) * | 1909-05-15 | 1910-06-14 | William P Fouts | Expansion-reamer. |
| US1481546A (en) * | 1920-12-22 | 1924-01-22 | Bethke Leo | Can opener |
| US2131056A (en) * | 1936-03-25 | 1938-09-27 | American Smelting Refining | Drill |
| DE1119194B (de) * | 1958-12-12 | 1961-12-14 | J C Soeding & Halbach Edelstah | Bohrer zum Herstellen von Bohrloechern in anstehenden Mineralien |
| US3231029A (en) * | 1963-10-28 | 1966-01-25 | Robbins & Assoc James S | Articulated drilling shafts for raise drilling |
| DE1216822B (de) * | 1965-03-27 | 1966-05-18 | Beteiligungs & Patentverw Gmbh | Streckenvortriebsmaschine |
| US3460867A (en) * | 1965-10-24 | 1969-08-12 | Russell J Cameron | Mining and retorting of oil shale |
| DE1552437A1 (de) * | 1966-04-30 | 1970-07-23 | Scharmann & Co | Schnellspannvorrichtung an Werkzeugmaschinen,insbesondere fuer kegelige Werkzeuge |
| DE1275976B (de) * | 1966-11-18 | 1968-08-29 | Georg Schoenfeld | Streckenvortriebsmaschine fuer Tunnel und Strecken im Bergbau mit Bohrwerkzeugen |
| US3486572A (en) * | 1967-02-28 | 1969-12-30 | Lawrence Mfg Co | Apparatus for forming inclined bores |
| US3481248A (en) * | 1967-12-28 | 1969-12-02 | Gorton Machine Corp | Drawbar for machine tools |
| US3675729A (en) * | 1970-05-08 | 1972-07-11 | Smith International | Bit lubrication system |
| US3676120A (en) * | 1971-02-26 | 1972-07-11 | Custom Tool & Machine Co Inc | Side operated drawbolt for tool-carrying spindle |
| US3830318A (en) * | 1972-11-17 | 1974-08-20 | Subterranean Tools Inc | Excavating machine |
| GB1469752A (en) * | 1973-04-16 | 1977-04-06 | Mcalpine & Sons Ltd Sir Robert | Tunnelling machines |
| US3905430A (en) * | 1973-08-29 | 1975-09-16 | Consolidation Coal Co | Apparatus for raise drilling |
| US3917009A (en) * | 1974-09-16 | 1975-11-04 | Dresser Ind | Removable stem for raise bits |
| US4069760A (en) * | 1976-03-01 | 1978-01-24 | Eckels Robert E | Method for driving a shaft with shaped charges |
| US4073352A (en) * | 1976-03-03 | 1978-02-14 | Occidental Oil Shale, Inc. | Raise bore drilling machine |
| US4022287A (en) * | 1976-04-20 | 1977-05-10 | Sandvik Aktiebolag | Percussion drill bit |
| DE2709030C2 (de) * | 1977-03-02 | 1985-05-15 | Stahl- Und Apparatebau Hans Leffer Gmbh, 6602 Dudweiler | Drehbohrkrone mit Schwenkflügeln |
-
1982
- 1982-05-10 US US06/376,793 patent/US4448270A/en not_active Expired - Fee Related
-
1983
- 1983-01-20 CA CA000419861A patent/CA1185276A/en not_active Expired
- 1983-04-04 JP JP58059131A patent/JPS58185686A/ja active Pending
- 1983-04-13 DE DE3313396A patent/DE3313396C2/de not_active Expired
- 1983-04-21 AU AU13855/83A patent/AU543855B2/en not_active Ceased
- 1983-04-21 JP JP58071343A patent/JPS58195686A/ja active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS505335A (enExample) * | 1973-02-09 | 1975-01-21 | ||
| JPS55127491A (en) * | 1979-03-19 | 1980-10-02 | Mobil Oil | Method of catalytically dewaxing hydrocarbon oil with synthetic offretite |
| JPS55145793A (en) * | 1979-04-27 | 1980-11-13 | Mobil Oil | Contact dewaxing method of hydrocarbon oil |
| US4255282A (en) * | 1979-05-11 | 1981-03-10 | Union Oil Company Of California | Hydrotreating catalyst and process for its preparation |
| JPS5620087A (en) * | 1979-07-30 | 1981-02-25 | Mitsubishi Chem Ind Ltd | Conversion of hydrocarbon |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6217063B2 (enExample) | 1987-04-15 |
| DE3313396A1 (de) | 1983-11-10 |
| CA1185276A (en) | 1985-04-09 |
| DE3313396C2 (de) | 1986-07-24 |
| JPS58195686A (ja) | 1983-11-14 |
| AU1385583A (en) | 1983-11-17 |
| AU543855B2 (en) | 1985-05-02 |
| US4448270A (en) | 1984-05-15 |
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