JPS58170733A - 液晶性エステル化合物 - Google Patents
液晶性エステル化合物Info
- Publication number
- JPS58170733A JPS58170733A JP5182282A JP5182282A JPS58170733A JP S58170733 A JPS58170733 A JP S58170733A JP 5182282 A JP5182282 A JP 5182282A JP 5182282 A JP5182282 A JP 5182282A JP S58170733 A JPS58170733 A JP S58170733A
- Authority
- JP
- Japan
- Prior art keywords
- trans
- liquid crystal
- formula
- compound
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 31
- -1 ester compound Chemical class 0.000 title abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract description 12
- NZNMSOFKMUBTKW-UHFFFAOYSA-N Cyclohexanecarboxylic acid Natural products OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 abstract description 10
- 239000005711 Benzoic acid Substances 0.000 abstract description 6
- 235000010233 benzoic acid Nutrition 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 4
- 125000005233 alkylalcohol group Chemical group 0.000 abstract description 3
- 238000010992 reflux Methods 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- VZFUCHSFHOYXIS-UHFFFAOYSA-N cycloheptane carboxylic acid Natural products OC(=O)C1CCCCCC1 VZFUCHSFHOYXIS-UHFFFAOYSA-N 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000004988 Nematic liquid crystal Substances 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- FPIQZBQZKBKLEI-UHFFFAOYSA-N ethyl 1-[[2-chloroethyl(nitroso)carbamoyl]amino]cyclohexane-1-carboxylate Chemical compound ClCCN(N=O)C(=O)NC1(C(=O)OCC)CCCCC1 FPIQZBQZKBKLEI-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- ZQWPRMPSCMSAJU-UHFFFAOYSA-N methyl cyclohexanecarboxylate Chemical compound COC(=O)C1CCCCC1 ZQWPRMPSCMSAJU-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- LNEMDIUSUQPKIP-UHFFFAOYSA-N 2-phenyl-1,3-dioxane Chemical compound O1CCCOC1C1=CC=CC=C1 LNEMDIUSUQPKIP-UHFFFAOYSA-N 0.000 description 1
- OXPDQFOKSZYEMJ-UHFFFAOYSA-N 2-phenylpyrimidine Chemical compound C1=CC=CC=C1C1=NC=CC=N1 OXPDQFOKSZYEMJ-UHFFFAOYSA-N 0.000 description 1
- OEEAKKCEEKHUPW-UHFFFAOYSA-N 4-(4-methylcyclohexyl)cyclohexane-1-carboxylic acid Chemical group C1CC(C)CCC1C1CCC(C(O)=O)CC1 OEEAKKCEEKHUPW-UHFFFAOYSA-N 0.000 description 1
- JXPGQFKJNKWDKP-UHFFFAOYSA-N 4-(4-propylcyclohexyl)cyclohexane-1-carboxylic acid Chemical compound C1CC(CCC)CCC1C1CCC(C(O)=O)CC1 JXPGQFKJNKWDKP-UHFFFAOYSA-N 0.000 description 1
- WOUHDMGTAFSJAU-WKILWMFISA-N C(CCCCC)[C@@H]1CC[C@H](CC1)C1=CC=C(C(=O)O)C=C1 Chemical compound C(CCCCC)[C@@H]1CC[C@H](CC1)C1=CC=C(C(=O)O)C=C1 WOUHDMGTAFSJAU-WKILWMFISA-N 0.000 description 1
- YXKKMVGGPRVHIL-SHTZXODSSA-N C1C[C@@H](CCCCC)CC[C@@H]1C1=CC=C(C(O)=O)C=C1 Chemical compound C1C[C@@H](CCCCC)CC[C@@H]1C1=CC=C(C(O)=O)C=C1 YXKKMVGGPRVHIL-SHTZXODSSA-N 0.000 description 1
- RHHMSVOVPSNAEC-QAQDUYKDSA-N C1C[C@@H](CCCCCCC)CC[C@@H]1C1=CC=C(C(O)=O)C=C1 Chemical compound C1C[C@@H](CCCCCCC)CC[C@@H]1C1=CC=C(C(O)=O)C=C1 RHHMSVOVPSNAEC-QAQDUYKDSA-N 0.000 description 1
- VRPANQODGRNWRV-GARHLSDISA-N CCCCC[C@H]1CC[C@@H](CC1)[C@H]1CC[C@@H](CC1)C(O)=O Chemical compound CCCCC[C@H]1CC[C@@H](CC1)[C@H]1CC[C@@H](CC1)C(O)=O VRPANQODGRNWRV-GARHLSDISA-N 0.000 description 1
- OQIHEFMTIUJJET-HDRKRICHSA-N CC[C@H]1CC[C@@H](CC1)[C@H]1CC[C@@H](CC1)C(O)=O Chemical compound CC[C@H]1CC[C@@H](CC1)[C@H]1CC[C@@H](CC1)C(O)=O OQIHEFMTIUJJET-HDRKRICHSA-N 0.000 description 1
- 239000004990 Smectic liquid crystal Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- IGARGHRYKHJQSM-UHFFFAOYSA-N cyclohexylbenzene Chemical compound C1CCCCC1C1=CC=CC=C1 IGARGHRYKHJQSM-UHFFFAOYSA-N 0.000 description 1
- 239000012769 display material Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940052296 esters of benzoic acid for local anesthesia Drugs 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Crystal Substances (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5182282A JPS58170733A (ja) | 1982-03-30 | 1982-03-30 | 液晶性エステル化合物 |
| DE8383301440T DE3374415D1 (en) | 1982-03-26 | 1983-03-15 | Liquid-crystalline compounds |
| US06/475,529 US4507222A (en) | 1982-03-26 | 1983-03-15 | Liquid-crystalline compounds |
| EP83301440A EP0090548B1 (en) | 1982-03-26 | 1983-03-15 | Liquid-crystalline compounds |
| US06/688,618 US4704228A (en) | 1982-03-26 | 1985-01-03 | Liquid-crystalline compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5182282A JPS58170733A (ja) | 1982-03-30 | 1982-03-30 | 液晶性エステル化合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58170733A true JPS58170733A (ja) | 1983-10-07 |
| JPS625415B2 JPS625415B2 (enrdf_load_stackoverflow) | 1987-02-04 |
Family
ID=12897579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5182282A Granted JPS58170733A (ja) | 1982-03-26 | 1982-03-30 | 液晶性エステル化合物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58170733A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59144728A (ja) * | 1983-02-07 | 1984-08-18 | Hitachi Ltd | ネマチック液晶およびそれを含む液晶組成物 |
-
1982
- 1982-03-30 JP JP5182282A patent/JPS58170733A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59144728A (ja) * | 1983-02-07 | 1984-08-18 | Hitachi Ltd | ネマチック液晶およびそれを含む液晶組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS625415B2 (enrdf_load_stackoverflow) | 1987-02-04 |
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