JPS5742644A - Production of ethylphenol and vinylphenol - Google Patents

Production of ethylphenol and vinylphenol

Info

Publication number
JPS5742644A
JPS5742644A JP55118875A JP11887580A JPS5742644A JP S5742644 A JPS5742644 A JP S5742644A JP 55118875 A JP55118875 A JP 55118875A JP 11887580 A JP11887580 A JP 11887580A JP S5742644 A JPS5742644 A JP S5742644A
Authority
JP
Japan
Prior art keywords
catalyst
vinylphenol
ethylphenol
produce
effected
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP55118875A
Other languages
Japanese (ja)
Other versions
JPH0115489B2 (en
Inventor
Kinya Fujii
Masaaki Sekiya
Hiroaki Taniguchi
Akio Takahashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cosmo Oil Co Ltd
Cosmo Co Ltd
Original Assignee
Maruzen Oil Co Ltd
Cosmo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Maruzen Oil Co Ltd, Cosmo Co Ltd filed Critical Maruzen Oil Co Ltd
Priority to JP55118875A priority Critical patent/JPS5742644A/en
Publication of JPS5742644A publication Critical patent/JPS5742644A/en
Publication of JPH0115489B2 publication Critical patent/JPH0115489B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: The thermal decomposition of a specific phenol derivative is effected in the presence of a catalyst in a hydrogen flow to produce ethylphenol, which is useful in industry, in high selectivity and yield and simultaneously produce vinylphenol in higher yield than in the conventional process.
CONSTITUTION: Thermal decomposition of a phenol derivative of the formula (n is 0W5; X is H, methyl, ethyl, propyl, methoxy, chloromethyl, bromomethyl, Cl, Br, F, hydroxyl, carboxyl, nitro) such as 1,1-bis(4-hydroxyphenyl)ethane is effected, when needed, using a diluent, in the presence of a catalyst of silica alumina or cerium oxide in a hydrogen flow under normal presure to produce ethylphenol, the major product, as well as vinylphenol. The amount of hydrogen gas used is preferably 0.1W104mol/mol of the starting compound.
EFFECT: Formation of high-boiling condensation products and coking on the catalyst surface are reduced to prolonging the time of continuous use of the catalyst.
COPYRIGHT: (C)1982,JPO&Japio
JP55118875A 1980-08-27 1980-08-27 Production of ethylphenol and vinylphenol Granted JPS5742644A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55118875A JPS5742644A (en) 1980-08-27 1980-08-27 Production of ethylphenol and vinylphenol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55118875A JPS5742644A (en) 1980-08-27 1980-08-27 Production of ethylphenol and vinylphenol

Publications (2)

Publication Number Publication Date
JPS5742644A true JPS5742644A (en) 1982-03-10
JPH0115489B2 JPH0115489B2 (en) 1989-03-17

Family

ID=14747274

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55118875A Granted JPS5742644A (en) 1980-08-27 1980-08-27 Production of ethylphenol and vinylphenol

Country Status (1)

Country Link
JP (1) JPS5742644A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59181231A (en) * 1983-03-29 1984-10-15 Cosmo Co Ltd Production of p-ethylphenol

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3364727B2 (en) * 1993-10-22 2003-01-08 イハラケミカル工業株式会社 2,2-bis (3,5-disubstituted-4-hydroxyphenyl) propane derivative, method for producing the same, and method for producing pyrogallol using the derivative

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59181231A (en) * 1983-03-29 1984-10-15 Cosmo Co Ltd Production of p-ethylphenol
JPH0251410B2 (en) * 1983-03-29 1990-11-07 Maruzen Sekyu Kagaku Kk

Also Published As

Publication number Publication date
JPH0115489B2 (en) 1989-03-17

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