JPS5527161A - Production of alcohol or its ether derivative - Google Patents

Production of alcohol or its ether derivative

Info

Publication number
JPS5527161A
JPS5527161A JP10035178A JP10035178A JPS5527161A JP S5527161 A JPS5527161 A JP S5527161A JP 10035178 A JP10035178 A JP 10035178A JP 10035178 A JP10035178 A JP 10035178A JP S5527161 A JPS5527161 A JP S5527161A
Authority
JP
Japan
Prior art keywords
alcohol
formula
acetal
aldehyde
hydrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10035178A
Other languages
Japanese (ja)
Inventor
Hideki Sakurai
Akira Hosomi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP10035178A priority Critical patent/JPS5527161A/en
Publication of JPS5527161A publication Critical patent/JPS5527161A/en
Pending legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: The isoprene unit is introduced in an aldehyde or its acetal using a silyl derivative of isoprene to produce a terpene compound useful as perfume or drug under calm conditions in high yield.
CONSTITUTION: The reaction between 2-silylmethyl-1,3-butadiene derivative of formula I (R1WR3 are alkyl, aryl, aralkyl) and an aldehyde of formula II (R4 is hydrocarbyl that may be substituted) or its acetal is effected in a solvent as dichloromethane in the presence of a Lewis acid catalyst as TiCl4 at -100W +100°C and is followed by hydrolysis to give the alcohol of formula III or its ether. The hydrolysis is effected by keeping the reaction mixture to about 0°C, adding ice water and ethyl ether and standing for 1W30min.
COPYRIGHT: (C)1980,JPO&Japio
JP10035178A 1978-08-17 1978-08-17 Production of alcohol or its ether derivative Pending JPS5527161A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10035178A JPS5527161A (en) 1978-08-17 1978-08-17 Production of alcohol or its ether derivative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10035178A JPS5527161A (en) 1978-08-17 1978-08-17 Production of alcohol or its ether derivative

Publications (1)

Publication Number Publication Date
JPS5527161A true JPS5527161A (en) 1980-02-27

Family

ID=14271676

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10035178A Pending JPS5527161A (en) 1978-08-17 1978-08-17 Production of alcohol or its ether derivative

Country Status (1)

Country Link
JP (1) JPS5527161A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS591704A (en) * 1982-06-28 1984-01-07 住友電気工業株式会社 Garment having alloy wire woven therein
JPS62126309U (en) * 1986-01-29 1987-08-11
JP3036519U (en) * 1996-08-30 1997-04-22 株式会社ワコール Clothing equipped with wires or bones

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS591704A (en) * 1982-06-28 1984-01-07 住友電気工業株式会社 Garment having alloy wire woven therein
JPH0160081B2 (en) * 1982-06-28 1989-12-21 Sumitomo Electric Industries
JPS62126309U (en) * 1986-01-29 1987-08-11
JP3036519U (en) * 1996-08-30 1997-04-22 株式会社ワコール Clothing equipped with wires or bones

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