JPS5527161A - Production of alcohol or its ether derivative - Google Patents
Production of alcohol or its ether derivativeInfo
- Publication number
- JPS5527161A JPS5527161A JP10035178A JP10035178A JPS5527161A JP S5527161 A JPS5527161 A JP S5527161A JP 10035178 A JP10035178 A JP 10035178A JP 10035178 A JP10035178 A JP 10035178A JP S5527161 A JPS5527161 A JP S5527161A
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- formula
- acetal
- aldehyde
- hydrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: The isoprene unit is introduced in an aldehyde or its acetal using a silyl derivative of isoprene to produce a terpene compound useful as perfume or drug under calm conditions in high yield.
CONSTITUTION: The reaction between 2-silylmethyl-1,3-butadiene derivative of formula I (R1WR3 are alkyl, aryl, aralkyl) and an aldehyde of formula II (R4 is hydrocarbyl that may be substituted) or its acetal is effected in a solvent as dichloromethane in the presence of a Lewis acid catalyst as TiCl4 at -100W +100°C and is followed by hydrolysis to give the alcohol of formula III or its ether. The hydrolysis is effected by keeping the reaction mixture to about 0°C, adding ice water and ethyl ether and standing for 1W30min.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10035178A JPS5527161A (en) | 1978-08-17 | 1978-08-17 | Production of alcohol or its ether derivative |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10035178A JPS5527161A (en) | 1978-08-17 | 1978-08-17 | Production of alcohol or its ether derivative |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5527161A true JPS5527161A (en) | 1980-02-27 |
Family
ID=14271676
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10035178A Pending JPS5527161A (en) | 1978-08-17 | 1978-08-17 | Production of alcohol or its ether derivative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5527161A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS591704A (en) * | 1982-06-28 | 1984-01-07 | 住友電気工業株式会社 | Garment having alloy wire woven therein |
JPS62126309U (en) * | 1986-01-29 | 1987-08-11 | ||
JP3036519U (en) * | 1996-08-30 | 1997-04-22 | 株式会社ワコール | Clothing equipped with wires or bones |
-
1978
- 1978-08-17 JP JP10035178A patent/JPS5527161A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS591704A (en) * | 1982-06-28 | 1984-01-07 | 住友電気工業株式会社 | Garment having alloy wire woven therein |
JPH0160081B2 (en) * | 1982-06-28 | 1989-12-21 | Sumitomo Electric Industries | |
JPS62126309U (en) * | 1986-01-29 | 1987-08-11 | ||
JP3036519U (en) * | 1996-08-30 | 1997-04-22 | 株式会社ワコール | Clothing equipped with wires or bones |
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