JPS5564596A - Preparation of alkylmethyl-3-dialkoxy-propylphosphinate - Google Patents

Preparation of alkylmethyl-3-dialkoxy-propylphosphinate

Info

Publication number
JPS5564596A
JPS5564596A JP13817078A JP13817078A JPS5564596A JP S5564596 A JPS5564596 A JP S5564596A JP 13817078 A JP13817078 A JP 13817078A JP 13817078 A JP13817078 A JP 13817078A JP S5564596 A JPS5564596 A JP S5564596A
Authority
JP
Japan
Prior art keywords
formula
alkylmethyl
acrolein
compound
phosphinothricin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13817078A
Other languages
Japanese (ja)
Inventor
Masao Kuwabara
Masashi Matsunaga
Sadaya Tsunoda
Motoo Mutsuto
Koichi Ura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Chemical Corp
Original Assignee
Nissan Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Corp filed Critical Nissan Chemical Corp
Priority to JP13817078A priority Critical patent/JPS5564596A/en
Publication of JPS5564596A publication Critical patent/JPS5564596A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE: To obtain the title compound, an intermediate for antibiotic phosphinothricin or flame-retardants in high yield readily, by using an acrolein dialkyl-acetal as a starting material.
CONSTITUTION: An acrolein dialkyl-acetal of formula I: (R2 is lower alkyl group) is reacted with an alkylmethyl phosphinate of formula II: (R1 is lower alkyl group) in the presence of a radical-forming agent to give the title compound of formula III. The compound of formula I is obtained from acrolein and an alcohol in high yield. The aldehyde of formula IV obtained from hydrolysis of the compound of formula III is reacted with and the reaction product is hydrolyzed by the well-known strecker reaction to give phosphinothricin of formula V.
COPYRIGHT: (C)1980,JPO&Japio
JP13817078A 1978-11-09 1978-11-09 Preparation of alkylmethyl-3-dialkoxy-propylphosphinate Pending JPS5564596A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13817078A JPS5564596A (en) 1978-11-09 1978-11-09 Preparation of alkylmethyl-3-dialkoxy-propylphosphinate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13817078A JPS5564596A (en) 1978-11-09 1978-11-09 Preparation of alkylmethyl-3-dialkoxy-propylphosphinate

Publications (1)

Publication Number Publication Date
JPS5564596A true JPS5564596A (en) 1980-05-15

Family

ID=15215660

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13817078A Pending JPS5564596A (en) 1978-11-09 1978-11-09 Preparation of alkylmethyl-3-dialkoxy-propylphosphinate

Country Status (1)

Country Link
JP (1) JPS5564596A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01224382A (en) * 1988-03-03 1989-09-07 Nissan Chem Ind Ltd Organic phosphorus derivative and production thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01224382A (en) * 1988-03-03 1989-09-07 Nissan Chem Ind Ltd Organic phosphorus derivative and production thereof

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