JPS56125395A - Preparation of acylsilane - Google Patents
Preparation of acylsilaneInfo
- Publication number
- JPS56125395A JPS56125395A JP2889280A JP2889280A JPS56125395A JP S56125395 A JPS56125395 A JP S56125395A JP 2889280 A JP2889280 A JP 2889280A JP 2889280 A JP2889280 A JP 2889280A JP S56125395 A JPS56125395 A JP S56125395A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- formula
- bivalent
- substituted
- monovalent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 150000008301 phosphite esters Chemical class 0.000 abstract 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000002541 furyl group Chemical group 0.000 abstract 1
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To obtain the titled compound useful as a synthetic intermediate for various organosilicon compounds in high yield in one stage, by reacting hexaorganodisilane with an acid chloride in the presence of a bivalent Pd complex and an organophosphite as a catalyst.
CONSTITUTION: A compound of formula I [R3 is monovalent group selected from monovalent (substituted)hydrocarbon and (substituted)furyl] is reacted with a compound of formula II (R1 is monovalent hydrocarbon) in the presence of a catalyst selected from the group consisting of a catalyst system consisting of a bivalent Pd complex and an organophosphite of the formula P(OR2)3 [R2 is (substituted) monovalent hydrocarbon containing no aliphatic unsaturation] and a zero- or bivalent Pd-phosphite complex to give the compound of formula III. The titled compound can be prepared advantageously due to no alkali metal which is not readily handled industrially or expensive alkyllithium used as a raw material.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2889280A JPS56125395A (en) | 1980-03-07 | 1980-03-07 | Preparation of acylsilane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2889280A JPS56125395A (en) | 1980-03-07 | 1980-03-07 | Preparation of acylsilane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS56125395A true JPS56125395A (en) | 1981-10-01 |
Family
ID=12261039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2889280A Pending JPS56125395A (en) | 1980-03-07 | 1980-03-07 | Preparation of acylsilane |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56125395A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011184327A (en) * | 2010-03-05 | 2011-09-22 | Eiweiss Kk | Method for producing acylsilane |
-
1980
- 1980-03-07 JP JP2889280A patent/JPS56125395A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011184327A (en) * | 2010-03-05 | 2011-09-22 | Eiweiss Kk | Method for producing acylsilane |
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