JPS56125320A - Substituted bynzoyltrimethylsilane - Google Patents
Substituted bynzoyltrimethylsilaneInfo
- Publication number
- JPS56125320A JPS56125320A JP2889380A JP2889380A JPS56125320A JP S56125320 A JPS56125320 A JP S56125320A JP 2889380 A JP2889380 A JP 2889380A JP 2889380 A JP2889380 A JP 2889380A JP S56125320 A JPS56125320 A JP S56125320A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- complex
- bivalent
- compound shown
- organophosphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 3
- 150000008301 phosphite esters Chemical class 0.000 abstract 2
- KEPKQZZZAMQPOV-UHFFFAOYSA-N (4-chlorophenyl)-trimethylsilylmethanone Chemical compound C[Si](C)(C)C(=O)C1=CC=C(Cl)C=C1 KEPKQZZZAMQPOV-UHFFFAOYSA-N 0.000 abstract 1
- 229910002666 PdCl2 Inorganic materials 0.000 abstract 1
- 101150003085 Pdcl gene Proteins 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- PZPGRFITIJYNEJ-UHFFFAOYSA-N disilane Chemical compound [SiH3][SiH3] PZPGRFITIJYNEJ-UHFFFAOYSA-N 0.000 abstract 1
- NEXSMEBSBIABKL-UHFFFAOYSA-N hexamethyldisilane Chemical compound C[Si](C)(C)[Si](C)(C)C NEXSMEBSBIABKL-UHFFFAOYSA-N 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Abstract
NEW MATERIAL:A compound shown by the formula I (X is electron attractive group, e.g., Cl, Br, methoxycarbonyl, nitro, etc.)
EXAMPLE: p-Chlorobenzoyltrimethylsilane.
USE: An intermediate for various organic silicon compounds. A carbonion source in various organic syntheses.
PROCESS: Hexamethyldisilane is reacted with a compound shown by the formula II in the coexistence of bivalent palladium complex and an organophosphite as a catalyst system, or in the presence of 0-bivalent palladium-phosphite complex, to give a compound shown by the formula I. A compound shown by the formula [(η3 -C3H5)PdCl]2 and a bivalent Pd-P complex shown by the formula PdCl2(PR2 3)2 (R2 is hydrocarbonoxy group) may be cited as the bivalent Pd complex, and its amount used is preferably 3W10mol% based on disilane. the organophosphite is shown by the formula P(OR3)3(R3 is hydrocarbon group having no aliphatic unsaturated bond).
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2889380A JPS56125320A (en) | 1980-03-07 | 1980-03-07 | Substituted bynzoyltrimethylsilane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2889380A JPS56125320A (en) | 1980-03-07 | 1980-03-07 | Substituted bynzoyltrimethylsilane |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS56125320A true JPS56125320A (en) | 1981-10-01 |
Family
ID=12261067
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2889380A Pending JPS56125320A (en) | 1980-03-07 | 1980-03-07 | Substituted bynzoyltrimethylsilane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56125320A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0057858A2 (en) * | 1981-02-07 | 1982-08-18 | BASF Aktiengesellschaft | Process for the preparation of aromatic silanes |
JP2011184327A (en) * | 2010-03-05 | 2011-09-22 | Eiweiss Kk | Method for producing acylsilane |
-
1980
- 1980-03-07 JP JP2889380A patent/JPS56125320A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0057858A2 (en) * | 1981-02-07 | 1982-08-18 | BASF Aktiengesellschaft | Process for the preparation of aromatic silanes |
JP2011184327A (en) * | 2010-03-05 | 2011-09-22 | Eiweiss Kk | Method for producing acylsilane |
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