JPS56125320A - Substituted bynzoyltrimethylsilane - Google Patents

Substituted bynzoyltrimethylsilane

Info

Publication number
JPS56125320A
JPS56125320A JP2889380A JP2889380A JPS56125320A JP S56125320 A JPS56125320 A JP S56125320A JP 2889380 A JP2889380 A JP 2889380A JP 2889380 A JP2889380 A JP 2889380A JP S56125320 A JPS56125320 A JP S56125320A
Authority
JP
Japan
Prior art keywords
formula
complex
bivalent
compound shown
organophosphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2889380A
Other languages
Japanese (ja)
Inventor
Kyoji Yamamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Momentive Performance Materials Japan LLC
Original Assignee
Toshiba Silicone Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Silicone Co Ltd filed Critical Toshiba Silicone Co Ltd
Priority to JP2889380A priority Critical patent/JPS56125320A/en
Publication of JPS56125320A publication Critical patent/JPS56125320A/en
Pending legal-status Critical Current

Links

Abstract

NEW MATERIAL:A compound shown by the formula I (X is electron attractive group, e.g., Cl, Br, methoxycarbonyl, nitro, etc.)
EXAMPLE: p-Chlorobenzoyltrimethylsilane.
USE: An intermediate for various organic silicon compounds. A carbonion source in various organic syntheses.
PROCESS: Hexamethyldisilane is reacted with a compound shown by the formula II in the coexistence of bivalent palladium complex and an organophosphite as a catalyst system, or in the presence of 0-bivalent palladium-phosphite complex, to give a compound shown by the formula I. A compound shown by the formula [(η3 -C3H5)PdCl]2 and a bivalent Pd-P complex shown by the formula PdCl2(PR2 3)2 (R2 is hydrocarbonoxy group) may be cited as the bivalent Pd complex, and its amount used is preferably 3W10mol% based on disilane. the organophosphite is shown by the formula P(OR3)3(R3 is hydrocarbon group having no aliphatic unsaturated bond).
COPYRIGHT: (C)1981,JPO&Japio
JP2889380A 1980-03-07 1980-03-07 Substituted bynzoyltrimethylsilane Pending JPS56125320A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2889380A JPS56125320A (en) 1980-03-07 1980-03-07 Substituted bynzoyltrimethylsilane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2889380A JPS56125320A (en) 1980-03-07 1980-03-07 Substituted bynzoyltrimethylsilane

Publications (1)

Publication Number Publication Date
JPS56125320A true JPS56125320A (en) 1981-10-01

Family

ID=12261067

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2889380A Pending JPS56125320A (en) 1980-03-07 1980-03-07 Substituted bynzoyltrimethylsilane

Country Status (1)

Country Link
JP (1) JPS56125320A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0057858A2 (en) * 1981-02-07 1982-08-18 BASF Aktiengesellschaft Process for the preparation of aromatic silanes
JP2011184327A (en) * 2010-03-05 2011-09-22 Eiweiss Kk Method for producing acylsilane

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0057858A2 (en) * 1981-02-07 1982-08-18 BASF Aktiengesellschaft Process for the preparation of aromatic silanes
JP2011184327A (en) * 2010-03-05 2011-09-22 Eiweiss Kk Method for producing acylsilane

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