JPS559025A - Preparation of polyfluoroalcohol - Google Patents
Preparation of polyfluoroalcoholInfo
- Publication number
- JPS559025A JPS559025A JP8129078A JP8129078A JPS559025A JP S559025 A JPS559025 A JP S559025A JP 8129078 A JP8129078 A JP 8129078A JP 8129078 A JP8129078 A JP 8129078A JP S559025 A JPS559025 A JP S559025A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- integer
- per mole
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the title substance useful as water and oil repellents, surfactants, release agents, and intermediates for other substances, in a simple process in high yield, by reacting a polyfluorohalide with a halosulfonic acid, and by hydrolyzing the resulting intermediate.
CONSTITUTION: A compound of formula I or II: (Rf is 2W23C perfluoroalkyl group; Rf' is mC perfluoroalkyl group; X is Br or I; m is an integer 1W21; n is an integer 2W22; m+n is an integer 3W23) is reacted with a compound of the formula YSO3H (Y is F or Cl) at 20W60°C to give an intermediate of formula III or IV which is hydrolized at 70W90°C to form the objective compound of formula V or VI. The halosulfonic acid must be used in excess, preferably 1.5W3.0 moles per mole of the compound of formula I or II. The amount of water in the hydrolysis is preferably 20W150 moles per mole of the intermediate.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP53081290A JPS5839135B2 (en) | 1978-07-03 | 1978-07-03 | Manufacturing method of polyfluoroalcohols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP53081290A JPS5839135B2 (en) | 1978-07-03 | 1978-07-03 | Manufacturing method of polyfluoroalcohols |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS559025A true JPS559025A (en) | 1980-01-22 |
JPS5839135B2 JPS5839135B2 (en) | 1983-08-27 |
Family
ID=13742241
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53081290A Expired JPS5839135B2 (en) | 1978-07-03 | 1978-07-03 | Manufacturing method of polyfluoroalcohols |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5839135B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62120332A (en) * | 1985-11-20 | 1987-06-01 | イ−・アイ・デユポン・ドウ・ヌム−ル・アンド・カンパニ− | Purification of 2-perfluoroalkyl ethanol |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6452408A (en) * | 1987-08-22 | 1989-02-28 | Toto Ltd | Kitchen equipment |
JPS6452406A (en) * | 1987-08-22 | 1989-02-28 | Toto Ltd | Counter of kitchen equipment |
WO2011021623A1 (en) | 2009-08-20 | 2011-02-24 | Agcセイミケミカル株式会社 | Fluoroalkyl group-containing n-substituted (meth)acrylamide compound, polymer thereof, and use thereof |
JP7180074B2 (en) | 2017-01-31 | 2022-11-30 | 株式会社リコー | Imaging device |
WO2018143311A1 (en) | 2017-01-31 | 2018-08-09 | Ricoh Company, Ltd. | Imaging apparatus |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3360568A (en) * | 1963-12-31 | 1967-12-26 | Pennsalt Chemical Corp | Preparation of halogenated organic compounds |
-
1978
- 1978-07-03 JP JP53081290A patent/JPS5839135B2/en not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3360568A (en) * | 1963-12-31 | 1967-12-26 | Pennsalt Chemical Corp | Preparation of halogenated organic compounds |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62120332A (en) * | 1985-11-20 | 1987-06-01 | イ−・アイ・デユポン・ドウ・ヌム−ル・アンド・カンパニ− | Purification of 2-perfluoroalkyl ethanol |
Also Published As
Publication number | Publication date |
---|---|
JPS5839135B2 (en) | 1983-08-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS57197235A (en) | Preparation of 2-hydroxy-3-alkoxypropyl glyceryl ether | |
JPS5690031A (en) | Preparation of aromatic aldehyde | |
JPS5576829A (en) | Beta,gamma-dihydropolyprenyl alcohol and hypotensive agent made from it | |
JPS559025A (en) | Preparation of polyfluoroalcohol | |
JPS562929A (en) | Preparation of optically active cyclopentenolone | |
JPS5711981A (en) | Theobromine derivative and its preparation | |
JPS54151985A (en) | Preparation of aminocarbostyril derivative | |
JPS5610135A (en) | Preparation of di-n-propylmalonic acid | |
JPS55153777A (en) | Improved method of preparation of 3-methyl-3-(substituted phenyl)-glycidic ester | |
JPS5711957A (en) | Novel aldehyde compound and its preparation | |
JPS55143960A (en) | Novel acetal compound and its preparation | |
JPS5585544A (en) | Substituted xylylene glycol | |
JPS5564596A (en) | Preparation of alkylmethyl-3-dialkoxy-propylphosphinate | |
JPS54115376A (en) | Preparation of 5-(4-hydroxyphenyl)-hydantoin | |
JPS54144320A (en) | Preparation of ureidomethylene malonic ester | |
JPS55143925A (en) | Preparation of cyclopentenolone | |
JPS5782345A (en) | Preparation of lactic ester | |
JPS579756A (en) | Novel acetal compound and its preparation | |
JPS552661A (en) | Preparation of glycol ether | |
JPS55141471A (en) | Preparation of alpha-dimethylamino-epsilon-caprolactam | |
JPS54109906A (en) | Preparation of polyhydric alcohols or boric acid esters thereof | |
JPS57197234A (en) | Preparation of perfluoroalkyl compound | |
JPS5770865A (en) | Preparation of 5-aroylpyrrole-2-acetic acid derivative | |
JPS5522613A (en) | Preparation of 2-hydroxy-3-butenoic acid derivative | |
JPS54154759A (en) | Preparation of optically active alcohol |