JPH10316849A - ポリアミド樹脂組成物およびその成形品 - Google Patents
ポリアミド樹脂組成物およびその成形品Info
- Publication number
- JPH10316849A JPH10316849A JP12735797A JP12735797A JPH10316849A JP H10316849 A JPH10316849 A JP H10316849A JP 12735797 A JP12735797 A JP 12735797A JP 12735797 A JP12735797 A JP 12735797A JP H10316849 A JPH10316849 A JP H10316849A
- Authority
- JP
- Japan
- Prior art keywords
- polyamide resin
- polyamide
- inorganic filler
- resin
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920006122 polyamide resin Polymers 0.000 title claims abstract description 108
- 239000011342 resin composition Substances 0.000 title claims abstract description 32
- 239000011256 inorganic filler Substances 0.000 claims abstract description 41
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 41
- 229920005989 resin Polymers 0.000 claims abstract description 35
- 239000011347 resin Substances 0.000 claims abstract description 35
- 229920002302 Nylon 6,6 Polymers 0.000 claims abstract description 32
- 238000000465 moulding Methods 0.000 claims abstract description 5
- 239000003365 glass fiber Substances 0.000 claims description 47
- 239000000203 mixture Substances 0.000 claims description 38
- 229920001577 copolymer Polymers 0.000 claims description 9
- 229920002292 Nylon 6 Polymers 0.000 claims description 5
- -1 polyhexamethylene isophthalamide Polymers 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 claims description 3
- 230000002528 anti-freeze Effects 0.000 abstract description 14
- 239000000463 material Substances 0.000 abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 239000000126 substance Substances 0.000 abstract description 8
- 239000008188 pellet Substances 0.000 description 24
- 238000000034 method Methods 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000012937 correction Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 150000004985 diamines Chemical group 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000010414 supernatant solution Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000000045 pyrolysis gas chromatography Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920000572 Nylon 6/12 Polymers 0.000 description 1
- 229920000007 Nylon MXD6 Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- MTEOMEWVDVPTNN-UHFFFAOYSA-E almagate Chemical compound O.O.[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Al+3].[O-]C([O-])=O MTEOMEWVDVPTNN-UHFFFAOYSA-E 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000000954 titration curve Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12735797A JPH10316849A (ja) | 1997-05-16 | 1997-05-16 | ポリアミド樹脂組成物およびその成形品 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12735797A JPH10316849A (ja) | 1997-05-16 | 1997-05-16 | ポリアミド樹脂組成物およびその成形品 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH10316849A true JPH10316849A (ja) | 1998-12-02 |
| JPH10316849A5 JPH10316849A5 (enExample) | 2005-04-07 |
Family
ID=14957953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12735797A Pending JPH10316849A (ja) | 1997-05-16 | 1997-05-16 | ポリアミド樹脂組成物およびその成形品 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH10316849A (enExample) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002541503A (ja) * | 1999-03-31 | 2002-12-03 | イーエムエス ケミー アクチエン ゲゼルシャフト | 光導波装置 |
| JP2007277391A (ja) * | 2006-04-06 | 2007-10-25 | Asahi Kasei Chemicals Corp | ガラス長繊維強化ポリアミド樹脂組成物および成形品 |
| JP2010269995A (ja) * | 2009-04-22 | 2010-12-02 | Asahi Kasei Chemicals Corp | ガラス繊維集束剤及びガラス繊維強化熱可塑性樹脂組成物 |
| JP2014526597A (ja) * | 2011-09-21 | 2014-10-06 | ローディア オペレーションズ | ポリアミド６６とポリアミド６１０、ポリアミド１０１０およびポリアミド１０１２からなる群から選ばれるポリアミドとを含む組成物 |
| CN110964316A (zh) * | 2018-10-01 | 2020-04-07 | 旭化成株式会社 | 聚酰胺组合物、成型品和半芳香族聚酰胺 |
| JP2022519760A (ja) * | 2019-02-12 | 2022-03-24 | アセンド・パフォーマンス・マテリアルズ・オペレーションズ・リミテッド・ライアビリティ・カンパニー | 加水分解抵抗性ポリアミド |
| CN114685981A (zh) * | 2022-03-17 | 2022-07-01 | 江苏金发科技新材料有限公司 | 树枝状聚酰胺-胺聚合物作为提高聚酰胺组合物耐热耐水解耐醇解性能添加剂的应用 |
| WO2025044738A1 (zh) * | 2023-08-28 | 2025-03-06 | 珠海万通特种工程塑料有限公司 | 一种半芳香聚酰胺组合物及其制备方法和应用 |
-
1997
- 1997-05-16 JP JP12735797A patent/JPH10316849A/ja active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002541503A (ja) * | 1999-03-31 | 2002-12-03 | イーエムエス ケミー アクチエン ゲゼルシャフト | 光導波装置 |
| JP2007277391A (ja) * | 2006-04-06 | 2007-10-25 | Asahi Kasei Chemicals Corp | ガラス長繊維強化ポリアミド樹脂組成物および成形品 |
| JP2016034897A (ja) * | 2009-04-22 | 2016-03-17 | 旭化成ケミカルズ株式会社 | ガラス繊維集束剤及びガラス繊維強化熱可塑性樹脂組成物 |
| JP2010269995A (ja) * | 2009-04-22 | 2010-12-02 | Asahi Kasei Chemicals Corp | ガラス繊維集束剤及びガラス繊維強化熱可塑性樹脂組成物 |
| JP2018024871A (ja) * | 2011-09-21 | 2018-02-15 | ローディア オペレーションズ | ポリアミド６６とポリアミド６１０、ポリアミド１０１０およびポリアミド１０１２からなる群から選ばれるポリアミドとを含む組成物 |
| JP2016164268A (ja) * | 2011-09-21 | 2016-09-08 | ローディア オペレーションズ | ポリアミド６６とポリアミド６１０、ポリアミド１０１０およびポリアミド１０１２からなる群から選ばれるポリアミドとを含む組成物 |
| JP2014526597A (ja) * | 2011-09-21 | 2014-10-06 | ローディア オペレーションズ | ポリアミド６６とポリアミド６１０、ポリアミド１０１０およびポリアミド１０１２からなる群から選ばれるポリアミドとを含む組成物 |
| CN110964316A (zh) * | 2018-10-01 | 2020-04-07 | 旭化成株式会社 | 聚酰胺组合物、成型品和半芳香族聚酰胺 |
| CN110964316B (zh) * | 2018-10-01 | 2023-02-17 | 旭化成株式会社 | 聚酰胺组合物、成型品和半芳香族聚酰胺 |
| JP2022519760A (ja) * | 2019-02-12 | 2022-03-24 | アセンド・パフォーマンス・マテリアルズ・オペレーションズ・リミテッド・ライアビリティ・カンパニー | 加水分解抵抗性ポリアミド |
| CN114685981A (zh) * | 2022-03-17 | 2022-07-01 | 江苏金发科技新材料有限公司 | 树枝状聚酰胺-胺聚合物作为提高聚酰胺组合物耐热耐水解耐醇解性能添加剂的应用 |
| CN114685981B (zh) * | 2022-03-17 | 2024-05-14 | 江苏金发科技新材料有限公司 | 树枝状聚酰胺-胺聚合物作为提高聚酰胺组合物耐热耐水解耐醇解性能添加剂的应用 |
| WO2025044738A1 (zh) * | 2023-08-28 | 2025-03-06 | 珠海万通特种工程塑料有限公司 | 一种半芳香聚酰胺组合物及其制备方法和应用 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Written amendment |
Effective date: 20040427 Free format text: JAPANESE INTERMEDIATE CODE: A523 |
|
| A621 | Written request for application examination |
Effective date: 20040427 Free format text: JAPANESE INTERMEDIATE CODE: A621 |
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| A977 | Report on retrieval |
Effective date: 20060515 Free format text: JAPANESE INTERMEDIATE CODE: A971007 |
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| A131 | Notification of reasons for refusal |
Effective date: 20061121 Free format text: JAPANESE INTERMEDIATE CODE: A131 |
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| A02 | Decision of refusal |
Effective date: 20070320 Free format text: JAPANESE INTERMEDIATE CODE: A02 |