JPH09500884A - スルホコハク酸ジエステル含有液体組成物 - Google Patents
スルホコハク酸ジエステル含有液体組成物Info
- Publication number
- JPH09500884A JPH09500884A JP7505551A JP50555195A JPH09500884A JP H09500884 A JPH09500884 A JP H09500884A JP 7505551 A JP7505551 A JP 7505551A JP 50555195 A JP50555195 A JP 50555195A JP H09500884 A JPH09500884 A JP H09500884A
- Authority
- JP
- Japan
- Prior art keywords
- liquid composition
- liquid
- composition according
- sulfosuccinate
- cosolvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000007788 liquid Substances 0.000 title claims abstract description 45
- -1 sulfosuccinic acid diester Chemical class 0.000 title claims abstract description 38
- 229920000642 polymer Polymers 0.000 claims abstract description 29
- 239000006184 cosolvent Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 5
- 150000002892 organic cations Chemical class 0.000 claims abstract description 5
- 150000001767 cationic compounds Chemical class 0.000 claims abstract description 4
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 4
- 125000003342 alkenyl group Chemical group 0.000 claims abstract 3
- 238000006243 chemical reaction Methods 0.000 claims description 28
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 27
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 17
- 239000011541 reaction mixture Substances 0.000 claims description 15
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 9
- 239000011976 maleic acid Substances 0.000 claims description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- HWJHLQSSWFHRQU-UHFFFAOYSA-N 1,4-didecoxy-1,4-dioxobutane-2-sulfonic acid Chemical group CCCCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCCCC HWJHLQSSWFHRQU-UHFFFAOYSA-N 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 238000009736 wetting Methods 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 description 11
- 238000010992 reflux Methods 0.000 description 9
- 150000005690 diesters Chemical class 0.000 description 8
- 239000012263 liquid product Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 239000013543 active substance Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 4
- 235000010262 sodium metabisulphite Nutrition 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YFNXLKFOUVOSMS-UHFFFAOYSA-N S(=O)(=O)(O)C(C(=O)OCCCCCCCC(C)C)CC(=O)OCCCCCCCC(C)C.[Na] Chemical compound S(=O)(=O)(O)C(C(=O)OCCCCCCCC(C)C)CC(=O)OCCCCCCCC(C)C.[Na] YFNXLKFOUVOSMS-UHFFFAOYSA-N 0.000 description 3
- WVUCNLQROBXNOX-UHFFFAOYSA-N bis(8-methylnonyl) but-2-enedioate Chemical compound CC(C)CCCCCCCOC(=O)C=CC(=O)OCCCCCCCC(C)C WVUCNLQROBXNOX-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- LWSCWNIJVWGYEH-UHFFFAOYSA-N 2,3-disulfobutanedioic acid Chemical compound OC(=O)C(S(O)(=O)=O)C(C(O)=O)S(O)(=O)=O LWSCWNIJVWGYEH-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- LZSHYKPUQCQJOP-UHFFFAOYSA-N 1,4-diethoxy-1,4-dioxobutane-2-sulfonic acid Chemical compound CCOC(=O)CC(S(O)(=O)=O)C(=O)OCC LZSHYKPUQCQJOP-UHFFFAOYSA-N 0.000 description 1
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 101100346764 Mus musculus Mtln gene Proteins 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 241000555745 Sciuridae Species 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 238000005844 autocatalytic reaction Methods 0.000 description 1
- ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 150000001656 butanoic acid esters Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 1
- AEVBUGHMKXBGBL-UHFFFAOYSA-N didecyl butanedioate Chemical compound CCCCCCCCCCOC(=O)CCC(=O)OCCCCCCCCCC AEVBUGHMKXBGBL-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/20—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by addition of sulfurous acid or salts thereof to compounds having carbon-to-carbon multiple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/32—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/03—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C309/17—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing carboxyl groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/04—Sulfonates or sulfuric acid ester salts derived from polyhydric alcohols or amino alcohols or derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/905—Agent composition per se for colloid system making or stabilizing, e.g. foaming, emulsifying, dispersing, or gelling
- Y10S516/909—The agent contains organic compound containing sulfoxy*
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Medicinal Preparation (AREA)
- Saccharide Compounds (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.溶媒または補助溶媒としての水中、以下の一般式: および/または (式中、Mは、無機または有機カチオンであり、RおよびR’は、互いに独立し て、脂肪族または環式脂肪族のC3-22アルキル、C2-22アルケニルまたは任意に C1-8アルキル置換されたC6-22アリールを表す。) で表されるスルホコハク酸ジエステルを含有する液体組成物であって、補助溶媒 が、10℃で液体であるアルキレンオキサイド単位を含有するポリマーであるこ とを特徴とする液体組成物。 2.補助溶媒が、エチレンオキサイド(EO)およびプロピレンオキサイド( PO)のブロックポリマーまたは単官能もしくは多官能アルコールへのEOおよ び/またはPO付加物から選ばれる請求項1に記載の液体組成物。 3.多官能アルコールがエチレングリコールまたはプロピレングリコールであ る請求項2に記載の液体組成物。 4.EO/POのブロックポリマーがPO含有率少なくとも20モル%を有す る請求項2または3に記載の液体組成物。 5.EO/POのブロックポリマーの分子量が500〜20,000である請 求項2ないし4のいずれかに記載の液体組成物。 6.アルキレンオキサイド単位を含有する液体ポリマーが、組成中、スルホコ ハク酸ジエステルに対して1〜40重量%の量で存在する請求項1ないし5のい ずれかに記載の液体組成物。 7.スルホコハク酸ジエステルが、水と液体ポリマーの混合物中、70重量% までの量で存在する請求項1ないし5のいずれかに記載の液体組成物。 8.スルホコハク酸ジエステルが、スルホコハク酸ジデシル、スルホコハク酸 ジイソデシル、スルホコハク酸ジ-2-エチルヘキシルまたはスルホコハク酸ジイ ソトリデシルである請求項1ないし6のいずれかに記載の液体組成物。 9.溶媒としての水中、液体補助溶媒の存在下、60〜150℃の温度におい て、場合により加圧下での(ここで、RおよびR’はC3-8アルキルを表し、補 助溶媒を、亜硫酸化反応後および冷却前に反応混合物に添加することができる。 )、一般式: ROOC-CH=CH-COOR’ (式中、RおよびR’は、互いに独立して、脂肪族または環式脂肪族のC3-22ア ルキル、C2-22アルケニルまたは任意にC1-8アルキル置換されたC6-22アリー ルを表す。) で表されるマレイン酸ジエステルと適する亜硫酸化剤からの請求項1ないし8の いずれかに記載の液体組成物の製造方法。 10.マレイン酸ジエステルと(HSO3 -基準での)亜硫酸化剤とのモル比が 1:0.9〜1:2である請求項9に記載の方法。 11.亜硫酸化剤が、MHSO3、M2SO3またはM2S2O5(式中、Mは、上 記のような無機または有機カチオンである。)である請求項9または10に記載 の方法。 12.製造しようとしている生成物を開始剤として使用する請求項9ないし1 1のいずれかに記載の方法。 13.液体ポリマーがエチレンオキサイド(EO)/プロピレンオキサイド( PO)ブロックポリマーまたは単官能もしくは多官能アルコールへのEOおよび /またはPO付加物である請求項9ないし12のいずれかに記載の方法。 14.多官能アルコールがエチレングリコールまたはプロピレングリコールで ある請求項13に記載の方法。 15.湿潤剤または乳化剤としての請求項1ないし8のいずれかに記載の液体 組成物の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4325923.5 | 1993-08-02 | ||
DE4325923A DE4325923A1 (de) | 1993-08-02 | 1993-08-02 | Sulfobernsteinsäurediester enthaltende flüssige Formulierungen |
PCT/EP1994/002450 WO1995004035A1 (de) | 1993-08-02 | 1994-07-25 | Sulfobernsteinsäurediester enthaltende flüssige formulierungen |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH09500884A true JPH09500884A (ja) | 1997-01-28 |
JP3929482B2 JP3929482B2 (ja) | 2007-06-13 |
Family
ID=6494291
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50555195A Expired - Lifetime JP3929482B2 (ja) | 1993-08-02 | 1994-07-25 | スルホコハク酸ジエステル含有液体組成物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5908582A (ja) |
EP (1) | EP0712391B1 (ja) |
JP (1) | JP3929482B2 (ja) |
AT (1) | ATE164836T1 (ja) |
DE (2) | DE4325923A1 (ja) |
ES (1) | ES2115966T3 (ja) |
WO (1) | WO1995004035A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017204149A1 (ja) * | 2016-05-27 | 2017-11-30 | 花王株式会社 | 洗浄剤組成物 |
JP2018162446A (ja) * | 2017-03-24 | 2018-10-18 | 三洋化成工業株式会社 | 界面活性剤組成物の製造方法 |
WO2021187488A1 (ja) | 2020-03-17 | 2021-09-23 | 花王株式会社 | 界面活性剤組成物 |
WO2021187489A1 (ja) | 2020-03-17 | 2021-09-23 | 花王株式会社 | 硬質物品の洗浄方法 |
WO2022138602A1 (ja) | 2020-12-21 | 2022-06-30 | 花王株式会社 | スルホン酸塩組成物 |
WO2022138603A1 (ja) | 2020-12-21 | 2022-06-30 | 花王株式会社 | スルホン酸塩組成物の製造方法 |
US12018230B2 (en) | 2020-03-17 | 2024-06-25 | Kao Corporation | Surfactant composition |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5675033A (en) * | 1995-06-06 | 1997-10-07 | Allergan | 2,4-pentadienoic acid derivatives having retinoid-like biological activity |
US6110381A (en) * | 1996-04-19 | 2000-08-29 | Betzdearborn Inc. | Method and composition for inhibiting microbial adhesion on surfaces |
US6241898B1 (en) | 1996-04-19 | 2001-06-05 | Betzdearborn Inc. | Method for inhibiting microbial adhesion on surfaces |
DE19829082A1 (de) * | 1998-06-30 | 2000-01-05 | Bayer Ag | Wasserspreitend beschichtete Formkörper |
DE19829165C2 (de) | 1998-06-30 | 2003-06-18 | Bayer Ag | Beschichtete Formkörper und deren Verwendung |
DE19829081A1 (de) * | 1998-06-30 | 2000-01-05 | Bayer Ag | Wasserspreitend beschichtete Formkörper |
US7378451B2 (en) * | 2003-10-17 | 2008-05-27 | 3M Innovative Properties Co | Surfactant composition having stable hydrophilic character |
DE102004056853A1 (de) * | 2004-11-25 | 2006-06-01 | Cognis Deutschland Gmbh & Co. Kg | Verwendung von Fettalkoholpolyglykolethersulfaten für die Emulsionspolymerisation |
DE102006009971A1 (de) * | 2006-03-03 | 2007-09-06 | Cognis Ip Management Gmbh | Salze von Alkylestern sulfonierter Dicarbonsäuren |
EP2179986A1 (de) * | 2008-10-24 | 2010-04-28 | Cognis IP Management GmbH | Mischungen von Alkylsulfosuccinaten und ihre Verwendung |
ES2503731T3 (es) * | 2008-10-24 | 2014-10-07 | Cognis Ip Management Gmbh | Mezclas de alquilsulfosuccinatos y su empleo |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2028091A (en) * | 1933-07-28 | 1936-01-14 | American Cyanamid & Chem Corp | Esters of sulphodicarboxylic acids |
US2176423A (en) * | 1936-01-13 | 1939-10-17 | American Cyanamid & Chem Corp | Esters of sulphodicarboxylic acids |
US2416254A (en) * | 1945-02-24 | 1947-02-18 | American Cyanamid Co | Antifogging composition |
GB760121A (en) * | 1952-09-23 | 1956-10-31 | American Cyanamid Co | Bis-decyl and bis-tridecyl esters of sulfosuccinic acid and preparation thereof |
US2879214A (en) * | 1955-10-27 | 1959-03-24 | American Cyanamid Co | Preparation of di-esters of sulfodicarboxylic acids |
GB1050578A (ja) * | 1963-06-05 | |||
FR1573080A (ja) * | 1968-03-25 | 1969-07-04 | ||
JPS5159909A (en) * | 1974-11-20 | 1976-05-25 | Kao Corp | Ryujomataha funjosenjozaisoseibutsu |
EP0024711B2 (de) * | 1979-09-01 | 1989-02-08 | Henkel Kommanditgesellschaft auf Aktien | Wässrige Tensidkonzentrate und Verfahren zur Verbesserung des Fliessverhaltens schwer beweglicher wässriger Tensidkonzentrate |
JPS62209200A (ja) * | 1986-03-08 | 1987-09-14 | 日本油脂株式会社 | 非水洗浄用洗浄剤 |
US5098478A (en) * | 1990-12-07 | 1992-03-24 | Sun Chemical Corporation | Water-based ink compositions |
-
1993
- 1993-08-02 DE DE4325923A patent/DE4325923A1/de not_active Withdrawn
-
1994
- 1994-07-25 EP EP94924285A patent/EP0712391B1/de not_active Expired - Lifetime
- 1994-07-25 DE DE59405655T patent/DE59405655D1/de not_active Expired - Fee Related
- 1994-07-25 US US08/592,391 patent/US5908582A/en not_active Expired - Lifetime
- 1994-07-25 JP JP50555195A patent/JP3929482B2/ja not_active Expired - Lifetime
- 1994-07-25 AT AT94924285T patent/ATE164836T1/de not_active IP Right Cessation
- 1994-07-25 WO PCT/EP1994/002450 patent/WO1995004035A1/de active IP Right Grant
- 1994-07-25 ES ES94924285T patent/ES2115966T3/es not_active Expired - Lifetime
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017204149A1 (ja) * | 2016-05-27 | 2017-11-30 | 花王株式会社 | 洗浄剤組成物 |
JP2017214554A (ja) * | 2016-05-27 | 2017-12-07 | 花王株式会社 | 洗浄剤組成物 |
CN109072129A (zh) * | 2016-05-27 | 2018-12-21 | 花王株式会社 | 清洗剂组合物 |
JP2018162446A (ja) * | 2017-03-24 | 2018-10-18 | 三洋化成工業株式会社 | 界面活性剤組成物の製造方法 |
WO2021187488A1 (ja) | 2020-03-17 | 2021-09-23 | 花王株式会社 | 界面活性剤組成物 |
WO2021187489A1 (ja) | 2020-03-17 | 2021-09-23 | 花王株式会社 | 硬質物品の洗浄方法 |
US12018230B2 (en) | 2020-03-17 | 2024-06-25 | Kao Corporation | Surfactant composition |
WO2022138602A1 (ja) | 2020-12-21 | 2022-06-30 | 花王株式会社 | スルホン酸塩組成物 |
WO2022138603A1 (ja) | 2020-12-21 | 2022-06-30 | 花王株式会社 | スルホン酸塩組成物の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
JP3929482B2 (ja) | 2007-06-13 |
DE4325923A1 (de) | 1995-02-09 |
DE59405655D1 (de) | 1998-05-14 |
US5908582A (en) | 1999-06-01 |
EP0712391B1 (de) | 1998-04-08 |
EP0712391A1 (de) | 1996-05-22 |
WO1995004035A1 (de) | 1995-02-09 |
ATE164836T1 (de) | 1998-04-15 |
ES2115966T3 (es) | 1998-07-01 |
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