JPH0759345B2 - Powder mold release agent for high pressure casting - Google Patents

Powder mold release agent for high pressure casting

Info

Publication number
JPH0759345B2
JPH0759345B2 JP3067975A JP6797591A JPH0759345B2 JP H0759345 B2 JPH0759345 B2 JP H0759345B2 JP 3067975 A JP3067975 A JP 3067975A JP 6797591 A JP6797591 A JP 6797591A JP H0759345 B2 JPH0759345 B2 JP H0759345B2
Authority
JP
Japan
Prior art keywords
release agent
pressure casting
high pressure
compound
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP3067975A
Other languages
Japanese (ja)
Other versions
JPH04279243A (en
Inventor
孝 花野
Original Assignee
花野商事株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 花野商事株式会社 filed Critical 花野商事株式会社
Priority to JP3067975A priority Critical patent/JPH0759345B2/en
Priority to CA002041502A priority patent/CA2041502A1/en
Priority to DE4116259A priority patent/DE4116259A1/en
Priority to KR1019910008263A priority patent/KR940009798B1/en
Priority to GB9111499A priority patent/GB2253410A/en
Priority to US07/915,763 priority patent/US5279750A/en
Publication of JPH04279243A publication Critical patent/JPH04279243A/en
Publication of JPH0759345B2 publication Critical patent/JPH0759345B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/02—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a non-macromolecular organic compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
    • C—CHEMISTRY; METALLURGY
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    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
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    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/22—Carboxylic acids or their salts
    • C10M105/24—Carboxylic acids or their salts having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
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    • C10M2229/0535—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/054—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus
    • C10M2229/0545—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Mold Materials And Core Materials (AREA)
  • Lubricants (AREA)

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【産業上の利用分野】本発明は、溶湯鍛造を含む高圧鋳
造の作業において金型内面に吹付けて用いる離型剤に関
するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a mold release agent which is sprayed onto the inner surface of a mold in a high pressure casting operation including a molten metal forging.

【０００２】[0002]

【従来の技術】溶湯鍛造を含む高圧鋳造法は高精度の鋳
造品を連続して且つ大量に製造できるので、自動車や電
気機器等の各種部品の製造に多く利用されている。そし
てこの高圧鋳造法においては、成形型の金型と溶湯との
直接接触を避けて焼付を防止し製品の型離れを良くする
ために離型剤が用いられている。2. Description of the Related Art A high-pressure casting method including molten metal forging is capable of producing highly accurate casting products continuously and in large quantities, and is therefore widely used for the production of various parts such as automobiles and electric equipment. In this high-pressure casting method, a mold release agent is used in order to avoid direct contact between the mold and the molten metal, prevent seizure, and improve product release.

【０００３】高圧鋳造用離型剤は一般に水溶性離型剤と
不水溶性離型剤とに大別される。そして不水溶性離型剤
は発煙、引火性の危険性が高く安全性に問題があるた
め、水溶性離型剤が多用されている。水溶性離型剤は一
般に、水、鉱物油等の離型剤基材に、界面活性剤や極圧
性付与剤として用いられるシリコ―ンオイル、合成又は
天然のワックス、油脂類、脂肪酸エステル等が添加され
てなるものである。Release agents for high pressure casting are generally classified into water-soluble release agents and water-insoluble release agents. Since the water-insoluble release agent has a high risk of smoking and flammability and a safety problem, the water-soluble release agent is often used. Water-soluble release agents generally include silicone oil, which is used as a surfactant or extreme pressure imparting agent, synthetic or natural wax, fats and oils, fatty acid esters, etc., added to release agent base materials such as water and mineral oil. It has been done.

【０００４】[0004]

【発明が解決しようとする問題点】ところで近年、高圧
鋳造技術の進歩に伴ってより高品質の製品をより作業性
良く得るための離型剤が要望されるようになってきた。
そして水溶性離型剤ではそのような要望を満足させられ
なくなってきた。即ち水溶性離型剤では、水溶性である
ために金型温度のコントロ―ルが困難であり、また水残
りに起因して製品内部に欠陥が生じる可能性が高いとい
う問題があった。更に使用後の水質汚濁防止のために廃
水処理を必要としそのための設備投資等の諸経費を必要
とするという問題があった。そこで新しい形態の離型剤
が強く望まれるようになってきた。By the way, in recent years, with the progress of high-pressure casting technology, a mold release agent for obtaining higher quality products with higher workability has been demanded.
And it has become impossible to satisfy such demands with water-soluble release agents. That is, the water-soluble release agent has a problem that it is difficult to control the mold temperature because it is water-soluble, and there is a high possibility that defects will occur inside the product due to residual water. Further, there is a problem that wastewater treatment is required to prevent water pollution after use, and various expenses such as facility investment are required for that purpose. Therefore, a new type of release agent has been strongly desired.

【０００５】本発明は以上のような点に鑑みて鋭意研究
し各種の系統的実験を行なった結果なされたもので、高
圧鋳造法においてより高品質の鋳造品をより作業性良く
且つ環境を悪化させることなく得るために用いられる高
圧鋳造用離型剤、即ち具体的には製品の焼付や内部欠陥
の発生を確実に防止でき、しかも製品の金型からの型離
れをより良好に行なわせることができ、また使用後に金
型内面や製品表面から取除き易く、更には使用中のガス
の発生が少なく、使用後に水質を汚染することのない高
圧鋳造用離型剤を提供することを目的とする。The present invention has been made as a result of intensive studies and various systematic experiments in view of the above points. In the high pressure casting method, a higher quality cast product has better workability and environmental degradation. Release agent for high-pressure casting that is used to obtain the product without causing it, that is, in particular, it is possible to reliably prevent the seizure of the product and the occurrence of internal defects, and to allow the product to be released from the mold better. The purpose of the present invention is to provide a mold release agent for high-pressure casting that can be easily removed from the inner surface of a mold or a product surface after use, and that generates less gas during use and does not contaminate water quality after use. To do.

【０００６】[0006]

【問題点を解決するための手段】本発明は、溶湯鍛造を
含む高圧鋳造の作業において金型内面に吹付けて用いる
高圧鋳造用離型剤において、固体で潤滑剤として用いら
れる無機化合物からなる粉末状又は顆粒状の離型剤基材
と、離型剤基材に付着性を付与する有機化合物とを混合
してなり、両者とも粉末状又は顆粒状の形態を有し、又
は離型剤基材が有機化合物により被覆された形態を有す
ることを特徴とする高圧鋳造用粉末離型剤である。SUMMARY OF THE INVENTION The present invention comprises a solid inorganic compound used as a lubricant in a mold release agent for high pressure casting, which is used by spraying on the inner surface of a mold in a high pressure casting operation including molten metal forging. A release agent base material in the form of powder or granules and an organic compound that imparts adhesiveness to the release agent base material are mixed, and both have a powdery or granular form, or a release agent. A powder mold release agent for high-pressure casting, characterized in that the base material has a form coated with an organic compound.

【０００７】本発明の最大の特徴は、離型剤基材が粉末
状又は顆粒状の形態を有することである。The greatest feature of the present invention is that the release agent base material has a powdery or granular form.

【０００８】そして有機化合物の無機化合物に対する含
有割合は０．１〜４５重量％の範囲から選択するのが有
効である。０．１重量％より小さいと無機化合物の金型
内面に対する付着効果が充分には得られず、４５重量％
より大きいとビルトアップが発生し、離型剤が金型内面
から取除きにくくなったり即ち離型効果が悪くなったり
製品の寸法精度が悪くなったりするからである。It is effective that the content ratio of the organic compound to the inorganic compound is selected from the range of 0.1 to 45% by weight. If it is less than 0.1% by weight, the effect of adhering the inorganic compound to the inner surface of the mold cannot be sufficiently obtained, and 45% by weight
If it is larger than the above range, build-up occurs, which makes it difficult to remove the release agent from the inner surface of the mold, that is, the release effect is deteriorated and the dimensional accuracy of the product is deteriorated.

【０００９】本発明で用い得る離型剤基材は、固体で潤
滑剤として用いられる無機化合物であれば特に制限はな
い。一般には窒化ホウ素、雲母、金属酸化物、窒化ケイ
素、硫黄化合物、弗化物、タルク、ホウ素化合物、リン
化合物が好ましく用いられるが、その他従来から離型剤
として用いられている公知の固体潤滑剤、例えば二硫化
モリブデン、グラファイト等も用いることができる。そ
してこれらの無機化合物は粉末状又は顆粒状の形態で、
その１種類のみが、又は２種類以上が組合せて用いられ
る。The release agent base material usable in the present invention is not particularly limited as long as it is a solid inorganic compound used as a lubricant. Generally, boron nitride, mica, metal oxides, silicon nitride, sulfur compounds, fluorides, talc, boron compounds, phosphorus compounds are preferably used, but other known solid lubricants conventionally used as release agents, For example, molybdenum disulfide, graphite or the like can be used. And these inorganic compounds are in the form of powder or granules,
Only one type or a combination of two or more types is used.

【００１０】また本発明で用い得る有機化合物は、上述
のような無機化合物に付着性、接着性を付与する性質を
有するものであれば、特に制限はない。一般には金属石
鹸や高分子化合物が好ましく用いられる。金属石鹸とし
てはカルボン酸骨格にナトリウム、カルシウム、バリウ
ム、リチウム、カリウム、マグネシウム、又は亜鉛を付
加したものが、また高分子化合物としてはポリエチレ
ン、ポリプロピレン、エポキシ樹脂、ケイ素樹脂、フェ
ノ―ル樹脂、アクリル樹脂、アルキッド樹脂、又はポリ
スチレンが特に好ましく用いられる。そしてこれらの有
機化合物は、粉末状又は顆粒状の形態で離型剤基材と混
合され、又は加熱溶融された状態で離型剤基材と混合さ
れる。従って本発明の離型剤は、離型剤基材と有機化合
物の両方が粉末状又は顆粒状の形態を有し、又は粉末状
又は顆粒状の離型剤基材が有機化合物により被覆された
形態を有することとなる。なお有機化合物は、上述した
化合物の１種類のみが、又は２種類以上が組合せて用い
られる。金属石鹸と高分子化合物とを組合せて用いても
よい。The organic compound that can be used in the present invention is not particularly limited as long as it has a property of imparting adhesiveness and adhesiveness to the above-mentioned inorganic compound. Generally, metal soap and polymer compounds are preferably used. The metal soap is a carboxylic acid skeleton to which sodium, calcium, barium, lithium, potassium, magnesium, or zinc is added, and the polymer compound is polyethylene, polypropylene, epoxy resin, silicon resin, phenol resin, acrylic resin. Resin, alkyd resin, or polystyrene is particularly preferably used. Then, these organic compounds are mixed with the release agent base material in the form of powder or granules, or are mixed with the release agent base material in the state of being heated and melted. Therefore, in the release agent of the present invention, both the release agent base material and the organic compound have a powdery or granular form, or the powdery or granular release agent base material is coated with the organic compound. Will have a morphology. As the organic compound, only one kind of the above-mentioned compounds or a combination of two or more kinds is used. A metal soap and a polymer compound may be used in combination.

【００１１】[0011]

【作用】本発明の高圧鋳造用粉末離型剤は少なくとも離
型剤基材が粉末状又は顆粒状の形態を有しているので、
離型剤が付着された金型内面の部分では製品と金型内面
とが確実に少なくとも離型剤基材の粉末又は顆粒の粒子
径だけ隔てられることとなる。従って離型剤が金型内面
にまんべんなく付着されることにより、製品と金型内面
とが直接に接触することによる焼付は確実に防止され
る。また本発明の離型剤は有機化合物と無機化合物とか
らなり水分を含有してはいないので、製品内部に水残り
に起因する欠陥が発生することもない。従って製品の品
質は向上することとなる。In the powder mold release agent for high pressure casting of the present invention, at least the mold release agent base material has a powdery or granular form.
In the portion of the inner surface of the mold to which the release agent is attached, the product and the inner surface of the mold are reliably separated from each other by at least the particle size of the powder or granules of the release agent base material. Therefore, since the release agent is evenly attached to the inner surface of the mold, seizure due to direct contact between the product and the inner surface of the mold is reliably prevented. Further, since the release agent of the present invention is composed of an organic compound and an inorganic compound and does not contain water, no defect due to water residue is generated inside the product. Therefore, the quality of the product will be improved.

【００１２】また本発明の離型剤は少なくとも離型剤基
材が粉末状又は顆粒状の形態を有し、水分を含有しては
いないので、金型内面と製品との間で働く張力は弱い。
従って製品の金型からの取出しは容易となる。しかも金
型内面及び製品表面から容易に取除かれる。Further, in the release agent of the present invention, at least the release agent base material has a powdery or granular form and does not contain water, so that the tension acting between the inner surface of the mold and the product is weak.
Therefore, it is easy to remove the product from the mold. Moreover, it can be easily removed from the inner surface of the mold and the product surface.

【００１３】更に本発明の離型剤は少なくとも離型剤基
材が粉末状又は顆粒状の形態を有しているので、高圧鋳
造中に熱が加わっても反応しにくくガスを殆んど発生し
ない。また水溶性離型剤のように使用後に水質を汚染す
ることもない。従って作業場の環境を悪化させることは
なく、また廃水処理のための経費が不要となり安価に用
いられることとなる。Further, in the release agent of the present invention, since at least the release agent base material has a powdery or granular form, it hardly reacts even if heat is applied during high pressure casting, and almost no gas is generated. do not do. Further, unlike the water-soluble release agent, it does not pollute the water quality after use. Therefore, the environment of the workplace is not deteriorated, and the expense for wastewater treatment is unnecessary and the cost is low.

【００１４】[0014]

【発明の効果】本発明によれば無機化合物からなる離型
剤基材と有機化合物との混合物からなる高圧鋳造用離型
剤を、少なくとも離型剤基材が粉末状又は顆粒状の形態
を有するものとしたので、高圧鋳造法により得られる例
えばアルミニウム合金や亜鉛合金等の鋳造品の焼付や内
部の欠陥発生を確実に防止してその品質を向上させるこ
とができ、しかも高圧鋳造法による鋳造をより作業性良
く行なわせることができ、更には使用中及び使用後にお
ける環境の悪化を充分に防止することができる。特に有
機化合物の無機化合物に対する含有割合を０．１〜４５
重量％の範囲とすることにより、得られる鋳造品の品質
をより良好なものにすることができる。更に無機化合物
として、窒化ホウ素、雲母、金属酸化物、窒化ケイ素、
硫黄化合物、弗化物、タルク、ホウ素化合物、リン化合
物を、また有機化合物として、カルボン酸骨格にナトリ
ウム、カルシウム、バリウム、リチウム、カリウム、マ
グネシウム、又は亜鉛を付加してなる金属石鹸や、ポリ
エチレン、ポリプロピレン、エポキシ樹脂、ケイ素樹
脂、フェノ―ル樹脂、アクリル樹脂、アルキッド樹脂、
又はポリスチレンの高分子化合物を用いることにより上
記効果をより良好に発揮することができる。そして上記
の無機化合物、有機化合物の内、それぞれ２種類以上の
ものを組合せて用いることにより、各高圧鋳造作業にお
いてより最適に用い得る離型剤を得ることができる。According to the present invention, a release agent for high pressure casting comprising a mixture of a release agent base material made of an inorganic compound and an organic compound, at least the release agent base material being in the form of powder or granules. Since it has, it is possible to reliably prevent the seizure of cast products such as aluminum alloys and zinc alloys obtained by the high pressure casting process and the occurrence of internal defects, and improve their quality. Can be performed with better workability, and further, deterioration of the environment during and after use can be sufficiently prevented. Particularly, the content ratio of the organic compound to the inorganic compound is 0.1 to 45.
When the content is in the range of wt%, the quality of the obtained cast product can be improved. Further, as an inorganic compound, boron nitride, mica, metal oxide, silicon nitride,
Metal compounds such as sulfur compounds, fluorides, talc, boron compounds and phosphorus compounds, or metal soaps obtained by adding sodium, calcium, barium, lithium, potassium, magnesium or zinc to the carboxylic acid skeleton as organic compounds, polyethylene, polypropylene , Epoxy resin, silicon resin, phenol resin, acrylic resin, alkyd resin,
Alternatively, by using a polystyrene polymer compound, the above effects can be more effectively exhibited. By using two or more of the above-mentioned inorganic compounds and organic compounds in combination, a release agent that can be more optimally used in each high-pressure casting operation can be obtained.

【００１５】[0015]

【実施例】以下、本発明の実施例を示すが、本発明はこ
れに限定されるものではない。次に示す（Ａ）〜（Ｆ）
の離型剤を得、これらの離型剤を用いて高圧鋳造法によ
る鋳造の試験を行ない、［表］に示す各項目について比
較検討した。本発明の例である（Ａ）〜（Ｃ）の混合物
としては、用いる有機化合物を粉末状又は顆粒状の形態
で無機化合物に混合したものと、加熱溶融した状態で無
機化合物に混合したものとの両方を得、それぞれについ
て検討したが、結果は両者とも同じであった。なお
（Ａ）〜（Ｆ）の離型剤において用いる各化合物は市販
のものである。 （Ａ）窒化ホウ素（平均粒度１〜５μ）９５部と、ステ
アリン酸カルシウム５部との混合物からなる本発明の第
１の例、（Ｂ）窒化ホウ素２０部と、雲母７５部と、ポ
リエチレン５部との混合物からなる本発明の第２の例、
（Ｃ）窒化ホウ素５０部と、窒化ケイ素４５部と、ステ
アリン酸バリウム３部と、ポリプロピレン２部との混合
物からなる本発明の第３の例、（Ｄ）窒化ホウ素のみ
（比較例１）（Ｅ）ワックスとシリコ―ンオイルを１：
８０の比で主成分として含有してなる水溶性離型剤（比
較例２）、（Ｆ）ワックス、シリコ−ンオイル、及び黒
鉛からなる市販の水溶性離型剤（比較例３）、 EXAMPLES Examples of the present invention will be shown below, but the present invention is not limited thereto. (A) to (F) shown below
The mold releasing agents were obtained, and casting tests by a high pressure casting method were carried out using these mold releasing agents, and the respective items shown in [Table] were compared and examined. As the mixture of (A) to (C) which is an example of the present invention, one in which the organic compound to be used is mixed with the inorganic compound in the form of powder or granules, and one in which the organic compound is mixed with the inorganic compound in the state of being heated and melted Both were obtained and examined for each, but the results were the same for both. Each compound used in the release agents (A) to (F) is commercially available. (A) A first example of the present invention comprising a mixture of 95 parts of boron nitride (average particle size 1 to 5 µ) and 5 parts of calcium stearate, (B) 20 parts of boron nitride, 75 parts of mica, and 5 parts of polyethylene. A second example of the invention consisting of a mixture with
(C) A third example of the present invention comprising a mixture of 50 parts of boron nitride, 45 parts of silicon nitride, 3 parts of barium stearate and 2 parts of polypropylene, (D) only boron nitride (Comparative Example 1) ( E) Wax and silicone oil 1:
A water-soluble mold release agent (Comparative Example 2) containing as a main component in a ratio of 80, a commercially available water-soluble mold release agent (Comparative Example 3) consisting of (F) wax, silicone oil, and graphite.

Claims (6)

【特許請求の範囲】[Claims] 【請求項１】溶湯鍛造を含む高圧鋳造の作業において金
型内面に吹付けて用いる高圧鋳造用離型剤において、固
体で潤滑剤として用いられる無機化合物からなる粉末状
又は顆粒状の離型剤基材と、離型剤基材に付着性を付与
する有機化合物とを混合してなり、両者とも粉末状又は
顆粒状の形態を有し、又は離型剤基材が有機化合物によ
り被覆された形態を有することを特徴とする高圧鋳造用
粉末離型剤。1. A release agent in the form of powder or granules, which is a solid and is used as a lubricant in a release agent for high-pressure casting, which is used by spraying on the inner surface of a mold in the operation of high-pressure casting including molten metal forging. A mixture of a base material and an organic compound that imparts adhesiveness to the release agent base material, and both have a powdery or granular form, or the release agent base material is coated with an organic compound. A powder mold release agent for high pressure casting, which has a form. 【請求項２】有機化合物を無機化合物に対して０．１〜
４５重量％の割合で含有した請求項１記載の高圧鋳造用
粉末離型剤。2. An organic compound is used in an amount of 0.1 to 0.1 with respect to an inorganic compound.
The powder release agent for high-pressure casting according to claim 1, which is contained in a proportion of 45% by weight. 【請求項３】無機化合物としては、窒化ホウ素、雲母、
金属酸化物、窒化ケイ素、硫黄化合物、弗化物、タル
ク、ホウ素化合物、リン化合物のうち、１種類以上が用
いられる請求項１又は２記載の高圧鋳造用粉末離型剤。3. The inorganic compound includes boron nitride, mica,
The powder mold release agent for high pressure casting according to claim 1 or 2, wherein one or more kinds of metal oxide, silicon nitride, sulfur compound, fluoride, talc, boron compound and phosphorus compound are used. 【請求項４】有機化合物としては、複数種類の金属石鹸
や複数種類の高分子化合物のうち、１種類以上が用いら
れる請求項１ないし３のいずれかに記載の高圧鋳造用粉
末離型剤。4. The powder mold release agent for high pressure casting according to claim 1, wherein one or more kinds of a plurality of kinds of metal soaps and a plurality of kinds of polymer compounds are used as the organic compound. 【請求項５】金属石鹸は、カルボン酸骨格にナトリウ
ム、カルシウム、バリウム、リチウム、カリウム、マグ
ネシウム、又は亜鉛を付加したものである請求項４記載
の高圧鋳造用粉末離型剤。5. The powdery mold release agent for high pressure casting according to claim 4, wherein the metal soap has carboxylic acid skeleton to which sodium, calcium, barium, lithium, potassium, magnesium or zinc is added. 【請求項６】高分子化合物は、ポリエチレン、ポリプロ
ピレン、エポキシ樹脂、ケイ素樹脂、フェノ―ル樹脂、
アクリル樹脂、アルキッド樹脂、又はポリスチレンであ
る請求項４又は５記載の高圧鋳造用粉末離型剤。6. The polymer compound is polyethylene, polypropylene, epoxy resin, silicon resin, phenol resin,
The powder mold release agent for high pressure casting according to claim 4 or 5, which is an acrylic resin, an alkyd resin, or polystyrene.
JP3067975A 1991-03-06 1991-03-06 Powder mold release agent for high pressure casting Expired - Lifetime JPH0759345B2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP3067975A JPH0759345B2 (en) 1991-03-06 1991-03-06 Powder mold release agent for high pressure casting
CA002041502A CA2041502A1 (en) 1991-03-06 1991-04-30 Squeeze casting powdery mold releasing agent
DE4116259A DE4116259A1 (en) 1991-03-06 1991-05-17 POWDER-MOLDED MOLD RELEASE AGENT FOR A PRESS MOLDING PROCESS
KR1019910008263A KR940009798B1 (en) 1991-03-06 1991-05-22 Method for squeeze casting powdery mold releasing agent
GB9111499A GB2253410A (en) 1991-03-06 1991-05-29 Squeeze casting powdery mold releasing agent
US07/915,763 US5279750A (en) 1991-03-06 1992-07-21 Method for squeeze casting powdery mold releasing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3067975A JPH0759345B2 (en) 1991-03-06 1991-03-06 Powder mold release agent for high pressure casting

Publications (2)

Publication Number Publication Date
JPH04279243A JPH04279243A (en) 1992-10-05
JPH0759345B2 true JPH0759345B2 (en) 1995-06-28

Family

ID=13360501

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3067975A Expired - Lifetime JPH0759345B2 (en) 1991-03-06 1991-03-06 Powder mold release agent for high pressure casting

Country Status (5)

Country Link
JP (1) JPH0759345B2 (en)
KR (1) KR940009798B1 (en)
CA (1) CA2041502A1 (en)
DE (1) DE4116259A1 (en)
GB (1) GB2253410A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06346075A (en) * 1993-06-04 1994-12-20 Hanano Shoji Kk Powdery releasing agent for molten metal forging
JP4452310B2 (en) * 2008-06-13 2010-04-21 新日本製鐵株式会社 Casting method and casting mold of iron-based alloy in semi-molten or semi-solid state

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB120255A (en) * 1917-10-31 1918-10-31 Thomas William Staine Hutchins Improvements relating to the Manufacture of Carbon Blocks.
GB318740A (en) * 1928-08-27 1929-09-12 Lajos Dorogi Improvements in or relating to templates for the manufacture of articles from sheet rubber
GB334857A (en) * 1929-06-05 1930-09-05 Kelly Graphite Mills Inc Improvements in or relating to parting compounds for foundry moulds
GB676408A (en) * 1950-11-20 1952-07-23 Buttress & Mcclellan Inc Method of constructing concrete building elements
US2937406A (en) * 1959-03-20 1960-05-24 Goodyear Tire & Rubber Fluid pressure core
GB1193645A (en) * 1966-08-05 1970-06-03 Francis Guy Sydenham English Improvements in or relating to Wet-Table Coatings.
US3615071A (en) * 1969-04-16 1971-10-26 Dow Corning Flexible mold
GB1362881A (en) * 1971-06-22 1974-08-07 Scott Bader Co Gel coats for moulds
DE2328337C3 (en) * 1973-06-04 1978-01-19 Wacker Chemie Gmbh PROCESS FOR PRODUCING SHAPED BODIES AND COATING FROM BUILDING MATERIALS ON THE BASIS OF INORGANIC BINDERS
GB2003923B (en) * 1977-09-07 1982-03-10 Foseco Int Metal working lubricants
JPH069730B2 (en) * 1989-01-13 1994-02-09 花野商事株式会社 Powder mold release agent for die casting

Also Published As

Publication number Publication date
DE4116259A1 (en) 1992-09-10
KR940009798B1 (en) 1994-10-17
KR920017741A (en) 1992-10-21
JPH04279243A (en) 1992-10-05
CA2041502A1 (en) 1992-09-07
GB2253410A (en) 1992-09-09
GB9111499D0 (en) 1991-07-17

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