CA2041502A1 - Squeeze casting powdery mold releasing agent - Google Patents

Squeeze casting powdery mold releasing agent

Info

Publication number
CA2041502A1
CA2041502A1 CA002041502A CA2041502A CA2041502A1 CA 2041502 A1 CA2041502 A1 CA 2041502A1 CA 002041502 A CA002041502 A CA 002041502A CA 2041502 A CA2041502 A CA 2041502A CA 2041502 A1 CA2041502 A1 CA 2041502A1
Authority
CA
Canada
Prior art keywords
mold releasing
releasing agent
squeeze casting
powdery
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002041502A
Other languages
French (fr)
Inventor
Takashi Hanano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanano Commercial Co
Original Assignee
Hanano Commercial Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hanano Commercial Co filed Critical Hanano Commercial Co
Publication of CA2041502A1 publication Critical patent/CA2041502A1/en
Abandoned legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
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    • C10M111/00Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/02Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a non-macromolecular organic compound
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/22Carboxylic acids or their salts
    • C10M105/24Carboxylic acids or their salts having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working

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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
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  • Mold Materials And Core Materials (AREA)
  • Lubricants (AREA)

Abstract

Abstract of the Disclosure In this invention; the squeeze casting mold releasing agent comprising the mixture of the mold releasing base material composed of the inorganic compound and the organic compound is formed into the releasing agent wherein at least the mold releasing base material has the powdery or granulated form. Therefore, the mold releasing agent allows productions of castings of high quality, in a squeeze casting work, with good workability and without worsening environmental situations.

Description

20~150~

DESCRIPTION

Title of the Invention Squeeze casting powdery mold releasing agent Background of the Invention ~Industrial useful feild) This invention relates to a mold releasing agent which is used by being sprayed onto an inside surfaces of molding die in a squeeze casting work which includes a forging cast work.
(Prior art) A squeeze casting method which includes a forging cast is being utilized widely in manufacturing various parts for automobile and electrical equipment because cast parts of high precision can be manufactured continuously and in large quantities by this method. And,in this squeeze casting method, a mold releasing agent is used in order to prevent a molding die from direct contact with molten metal for avoiding seizure and for betterning release of products from dies.
The squeeze casting mold releasing agent is generally classified into two principal groups: a water soluble mold releasing agent and a water insoluble mold releasing agent.
Among these agents, the water insoluble mold releasing agent 2 ~ 0 2 includes problems from standpoint of safety because of its large danger due to smoke and flammability so that the water soluble mold releasing agent is being used frequently. The water soluble mold releasing agent is generally composed of mold releasing base materials such as water, mineral oil etc., to which silicon oil, synthetic or natural wax, fats and oils, fatty acid ester etc. for use is surface active agent or extreme pressure providing agent, are annexad.
(Problems to be solved by the Invention) Incidentally, with a progress of squeeze casting technology in recent years, there has been an increasing demand for a mold releasing agent to obtain products of high quality with better workability. However, it has become impossible to satisfy this demand by using the water soluble mold releasing agent. Namely, the water soluble mold releasing agent has included problems that control of die temperature has been difficult due to its water solubility and there has been a high possibility of defects arising in product insides due to remaining water. Further, there has been a problem that liquld-waste treatment has become required for prevention of water pollution to induce increases in various expenses for plant and equipment investment. Therefore, a strong demand for a mold releasing agent of new type has arisen.

~41~2 Summary of the Inventio_ This invention has been made on the basis of detailed studies and systematic experiments in due consideration of the foregoing situations. An object of this invention is to provide a squeeze casting ~old releasing agent for obtaining cast products of higher quality with better workability and without worsening environmental conditions; namely, in more concrete form, to provide a mold relesing agent which can securely prevent seizure of products and occurence of inside defécts to improve die-releasing ability of products from dies, can be easily removed from die insides and product surfaces after use, and permits no generation of gas during casting and no pollution of water after casting.
This invention is, in a squeeze casting mold releasing agent-which is used by being sprayed onto an inside surfaces of molding die in a squeeze casting work which includes a forging cast work, a squeeze casting powdery mold releasing agent comprising a mixture of a powdery or granulated mold releasing base material composed of an inorganic compound as used for lubricant in a solld form and an organic compound giving adhesive property to the mold releasing base material, wherein the both have powdery or granulated form, or the mold releasing base material is coated with the organic compound.

Detailed description of the Invention The most outstanding feature of this invention is that the mold releasing base material has the powdery or granulated form.
It is effective to select a content of organic compound in relation to inorganic compound from a range of 0.1 through 45 weight percent. The reason is that the adhesion effect of the inorganic compound to metal mold insides is not enough when the content is smaller than 0.1 weight percent, and a built-up occurs to cause a difficulty in removing the mold releasing agent from the metal mold insides, i.e. a decrease in mold releasing efficiency or a worsening of dimensional accuracy of product when the content is larger than 45 weight percent.
There is no limitation to the mold releasing base material for use in the present invention, provided that they are composed of solid inorganic compound used for lubricant.
Generally, boron nitride, mica, metal oxides, silicon nitride, sulfur compound, fluoride, talc, boron compound and phosphorus compound are preferably used therefor. However, another well known solid lubricants may be used therefor, which have conventionally been used as the mold releasing agent, such as molybdenum disulfide, graphite etc. These inorganic compounds have powdery or granulated form, and 2 ~

only one kind of them or two or more kinds thereof are used in combined form.
Further, there is no special limitation to the organic compounds used for the present invention, provided that they have characteristics of giving the adhesive and bonding properties to the foregoing inorganic compounds. Generally, metal soap or high molecular compound are preferably used therefor. Carboxylic acid construction annexed with sodium, calcium, barium, lithium, potassium, magnesium or zinc is used for the metal soap; and polyethylene, polypropylene, epoxy resin, silicon resin, phenol resin, acrylate resin, alkyd resin or polystyrene are preferably used for the high molecular compound. These organic compounds are mixed with the mold releasing base materail in the powdery or granulated form or mixed with it in a heated molten state.
Accordingly, in the mold releasing agent according to the present invention, both the mold releasing base materail and the organic compound are formed into the powdery or granulated form, or the powdery or granulated mold releasing base material is coated with the organic compound.
Incidentally, only one kind of the above-mentioned organic compounds is used, or two or more kinds of them are used in combined form.-A combination of the metal soap with the high molecular compound may be used.
(Function) 21~15~

In the squeeze casting powdery mold releasing agent according to the present invention, the mold releasing base material has at least the powdery or granulated form so that the product is surely separated from the metal mold inside surface at least by a particle dlameter of powder or granule of the mold releasing base material at a part of the metal mold inside surface to which the mold releasing agent adheres. Consequently, the mold releasing agent adheres uniformly to the whole metal mold inside surface so that the seizure caused by the direct contact of the product with the metal mold inside surface can be avoided without fail.
Further, since the mold releasing agent according to this invention is composed of the organic compound and the inorganic compound and does not include water content, no defec~ due to remaining water arises in the product inside surface. Accordingly, the quality of product can be improved.
Moreover, in the mold releasing agent according to the present invention, the mold releasing base material has at least the powdery or granulated form and does not include water content so that a tension working between the metal mold inside surface and the product is weak. Therefore, taking-out of the product from the metal mold becomes easy.
Furthermore, the mold releasing agent can be removed easily from the metal mold inside surface and the product surface.

2 ~

In addition, in the mold releasing agent of this invention, the mold releasing base material has at least the powdery or granulated form so that the material is hard to react and scarcely generates gas even if it is subjected to heat during squeeze casting. And, this agent does not produce water pollution after casting as encounterd in case of water soluble mold releasing agent. Therefore, worsening of field environment can be avoided and expenses for liquid-waste treatment become unnecessary to cut off maintenance cost.
(Effect of the Invention) In this invention; the squeeze casting mold releasing agent comprising the mixture of the mold releasing base material composed of the inorganic compound and the organic compo~nd is formed into the releasing agent wherein at least the mold releasing base material has the powdery or granulated form. Therefore, castings produced by means of the squeeze casting method, such as aluminium alloy and zinc alloy etc., can be surely prevented from seizures and inside defects; to be improved the quality of casting; the casting work based on the squeeze casting can be carried out with good workability; and the worsening of environment before and after use of agent can be fully avoided. Especially, the quality of obtained castings can be improved by settling the content of organic compound in relation to inorganic 2 ~

compound to the range of 0.1 through 45 weight percent.
Further; the above-mentioned effect can be enhanced still more when boron nitride, mica, metal oxides, silicon nitride ,sulfur compound, fluoride, talc, boron compound or phosphorus compound is used for the inorganic compound; and when the metal soap comprising the carboxylic acid construction annexed with sodium, calcium, barium, lithium, potassium, magnessium or zinc, or the high molecular compound such as polyethylene, polypropylene, epoxy resin, silicon resin, phenol resin, acrylate resin, alkyd resin or polystyrene is used for the organic compound. And the mold releasing agents, which are usable most suitably in respective die-casting works, can be obtained by using two or more kinds of the foregoing inorganic compounds and organic compounds respectively in the combined manner.
(Embodiments) Embodiments of the present invention will be described below, but the invention is not limi~ted to these embodiments.
Following mold releasing agents (A) through (F) were obtained, casting tests based on the squeeze casting method were carried out by using these mold releasing agents, and items listed in [TABLE3 were compared and examined.
Two kinds of mixtures: a mixture wherein organic compound is mixed with inorganic compound in powdery or granulated 2 0 ~ 2 configuration, and a mixture wherein the organic compound is mixed with the inorganic compound in a heated molten state;
were obtained for the embodiments (A) through (C) of the present invention.
The two kinds of mixtures were examined and obtained results were the same for the both mixtures. Incidentally, compounds as used for the mold releasing agents (A) through (F) are those available in the market.
(A) First embodiment comprising a mixture of 95 parts of boron nitride (average particle size: 1 through 5 microns) and 5 parts of calcium stearate (B) Second embodiment comprising a mixture of 20 parts of boron nitride, 75 parts of mica and 5 parts of polyethylene (C) Third embodiment comprising a mixture of 50 parts of boron nitride, 45 parts of silicon nitride, 3 parts of barium stearate and 2 parts of polypropylene (D) Boron nitride only (comparison embodiment 1) (E) Water soluble mold releasing agent containing, as major components, wax and silicon oil at a ratio of 1:80 (comparison embodiment 2) (F) Water soluble mold releasin~ agent on the market comprising of wax, silicon oil and graphite (comparison embodiment 3) 2~5~

[TABLE]

(~ IB) (C) (D) ( E ) ( F ) _ Adhesion to metal mold o @ @ x o o Effect for preventing @ @ @ _ o o seizure ____ Effect for preventing de- @ @ @ _ * *
fects in product inside _ _ Effect for preventing worsening of field envi- @ @ @ _ * x ronment due to generation of smoke and steam _ _ x: Compretely non, -: Measurement impossible, *:~Small, o: Intermediate, @: Large

Claims (6)

1. In a squeeze casting mold releasing agent which is used by being sprayed onto an inside surfaces of molding die in a squeeze casting work which includes a forging cast work; a squeeze casting powdery mold releasing agent comprising a mixture of a powdery or granulated mold releasing base material composed of an inorganic compound as used for lubricant in a solid form and an organic compound giving adhesive property to the mold releasing base material, wherein the both have powdery or granulated form, or the mold releasing base material is coated with the organic compound.
2. A squeeze casting powdery mold releasing agent according to claim 1, which contains the organic compound at a content of 0.1 to 45 weight percent in relation to the inorganic compound.
3. A squeeze casting powdery mold releasing agent according to claim 1 or claim 2, wherein the inorganic compound comprises one or more of boron nitride, silicon nitride, mica, metal oxides, sulfur compound, fluoride, talc, boron compound and phosphorus compound.
4. A squeeze casting powdery mold releasing agent according to any one of claim 1 through claim 3, wherein the organic compound comprises one or more kinds of metal soaps and/or high molecular compounds.
5. A squeeze casting powdery mold releasing agent according to claim 4, wherein the metal soap comprises a carboxylic acid group bonded to sodium, calcium, barium, lithium, potassium, magnesium or zinc.
6. A squeeze casting powdery mold releasing agent according to claim 4 or claim 5, wherein the high molecular compound comprises polyethylene, polypropylene, epoxy resin, silicon resin, phenol resin, acrylate resin, alkyd resin or polystyrene.
CA002041502A 1991-03-06 1991-04-30 Squeeze casting powdery mold releasing agent Abandoned CA2041502A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP067975/1991 1991-03-06
JP3067975A JPH0759345B2 (en) 1991-03-06 1991-03-06 Powder mold release agent for high pressure casting

Publications (1)

Publication Number Publication Date
CA2041502A1 true CA2041502A1 (en) 1992-09-07

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Application Number Title Priority Date Filing Date
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JP (1) JPH0759345B2 (en)
KR (1) KR940009798B1 (en)
CA (1) CA2041502A1 (en)
DE (1) DE4116259A1 (en)
GB (1) GB2253410A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06346075A (en) * 1993-06-04 1994-12-20 Hanano Shoji Kk Powdery releasing agent for molten metal forging
JP4452310B2 (en) * 2008-06-13 2010-04-21 新日本製鐵株式会社 Casting method and casting mold of iron-based alloy in semi-molten or semi-solid state

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB120255A (en) * 1917-10-31 1918-10-31 Thomas William Staine Hutchins Improvements relating to the Manufacture of Carbon Blocks.
GB318740A (en) * 1928-08-27 1929-09-12 Lajos Dorogi Improvements in or relating to templates for the manufacture of articles from sheet rubber
GB334857A (en) * 1929-06-05 1930-09-05 Kelly Graphite Mills Inc Improvements in or relating to parting compounds for foundry moulds
GB676408A (en) * 1950-11-20 1952-07-23 Buttress & Mcclellan Inc Method of constructing concrete building elements
US2937406A (en) * 1959-03-20 1960-05-24 Goodyear Tire & Rubber Fluid pressure core
GB1193645A (en) * 1966-08-05 1970-06-03 Francis Guy Sydenham English Improvements in or relating to Wet-Table Coatings.
US3615071A (en) * 1969-04-16 1971-10-26 Dow Corning Flexible mold
GB1362881A (en) * 1971-06-22 1974-08-07 Scott Bader Co Gel coats for moulds
DE2328337C3 (en) * 1973-06-04 1978-01-19 Wacker Chemie Gmbh PROCESS FOR PRODUCING SHAPED BODIES AND COATING FROM BUILDING MATERIALS ON THE BASIS OF INORGANIC BINDERS
GB2003923B (en) * 1977-09-07 1982-03-10 Foseco Int Metal working lubricants
JPH069730B2 (en) * 1989-01-13 1994-02-09 花野商事株式会社 Powder mold release agent for die casting

Also Published As

Publication number Publication date
DE4116259A1 (en) 1992-09-10
KR940009798B1 (en) 1994-10-17
KR920017741A (en) 1992-10-21
JPH04279243A (en) 1992-10-05
JPH0759345B2 (en) 1995-06-28
GB2253410A (en) 1992-09-09
GB9111499D0 (en) 1991-07-17

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