JPH0560818B2 - - Google Patents
Info
- Publication number
- JPH0560818B2 JPH0560818B2 JP61044315A JP4431586A JPH0560818B2 JP H0560818 B2 JPH0560818 B2 JP H0560818B2 JP 61044315 A JP61044315 A JP 61044315A JP 4431586 A JP4431586 A JP 4431586A JP H0560818 B2 JPH0560818 B2 JP H0560818B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- hydrazo
- hydrogen peroxide
- acid
- oxidizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- -1 azo compound Chemical class 0.000 claims description 3
- 239000012429 reaction media Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000005855 radiation Effects 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- NICLKHGIKDZZGV-UHFFFAOYSA-N 2-cyanopentanoic acid Chemical compound CCCC(C#N)C(O)=O NICLKHGIKDZZGV-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012431 aqueous reaction media Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- HWQXBVHZYDELQG-UHFFFAOYSA-L disodium 2,2-bis(6-methylheptyl)-3-sulfobutanedioate Chemical compound C(CCCCC(C)C)C(C(C(=O)[O-])S(=O)(=O)O)(C(=O)[O-])CCCCCC(C)C.[Na+].[Na+] HWQXBVHZYDELQG-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229940040102 levulinic acid Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/63—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton
- C07C255/65—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8503147A FR2578249B1 (fr) | 1985-03-04 | 1985-03-04 | Procede d'oxydation de composes hydrazoiques en azoiques correspondants par l'eau oxygenee |
| FR8503147 | 1985-03-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61212548A JPS61212548A (ja) | 1986-09-20 |
| JPH0560818B2 true JPH0560818B2 (en, 2012) | 1993-09-03 |
Family
ID=9316834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61044315A Granted JPS61212548A (ja) | 1985-03-04 | 1986-03-03 | ヒドラゾ化合物を酸化する方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4637868A (en, 2012) |
| JP (1) | JPS61212548A (en, 2012) |
| FR (1) | FR2578249B1 (en, 2012) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2032316A1 (en) * | 1989-12-26 | 1991-06-27 | John T. Lai | Process for the preparation of symmetrical azodinitrile dicarboxylic acids from keto acids |
| FR2826652B1 (fr) * | 2001-06-28 | 2005-09-09 | Atofina | Procede de preparation de composes type azoique. |
| FR2879597B1 (fr) * | 2004-12-20 | 2007-02-23 | Arkema Sa | Procede de preparation de derives azoiques n, n'disubstitues par oxydation des derives hydrazoiques correspondants |
| FR3008092B1 (fr) | 2013-07-02 | 2015-07-31 | Arkema France | Procede de synthese de composes azo |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2469358A (en) * | 1947-03-22 | 1949-05-10 | Du Pont | Preparation of hydrazonitriles from azines of butyl ketones |
| US2586995A (en) * | 1948-01-15 | 1952-02-26 | Du Pont | Polyfurcate azonitriles |
| US3192196A (en) * | 1962-11-27 | 1965-06-29 | Wallace & Tiernan Inc | Oxidation of aliphatic hydrazo compounds to the corresponding aliphatic azo compounds |
| GB1177177A (en) * | 1967-03-23 | 1970-01-07 | Fisons Ind Chemicals Ltd | Electrolytic Oxidation Process |
| GB1449946A (en) * | 1974-10-04 | 1976-09-15 | Wako Pure Chem Ind Ltd | Unsymmetrical azonitriles |
| JPS52144622A (en) * | 1976-05-26 | 1977-12-02 | Otsuka Chem Co Ltd | Praparation of a,a-azobisalkanenitrile |
| US4094868A (en) * | 1977-03-22 | 1978-06-13 | Olin Corporation | Azo di-ester polyols for graft copolymerization |
| GB2115810A (en) * | 1982-03-04 | 1983-09-14 | Ici Plc | Esthers and amides of azobis (cyanscarbonglie acids) polymerisation initiators |
-
1985
- 1985-03-04 FR FR8503147A patent/FR2578249B1/fr not_active Expired
-
1986
- 1986-03-03 JP JP61044315A patent/JPS61212548A/ja active Granted
- 1986-03-04 US US06/835,910 patent/US4637868A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61212548A (ja) | 1986-09-20 |
| US4637868A (en) | 1987-01-20 |
| FR2578249B1 (fr) | 1987-05-15 |
| FR2578249A1 (fr) | 1986-09-05 |
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