JPH0511302B2 - - Google Patents
Info
- Publication number
- JPH0511302B2 JPH0511302B2 JP58160018A JP16001883A JPH0511302B2 JP H0511302 B2 JPH0511302 B2 JP H0511302B2 JP 58160018 A JP58160018 A JP 58160018A JP 16001883 A JP16001883 A JP 16001883A JP H0511302 B2 JPH0511302 B2 JP H0511302B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- coupler
- acid
- polymer
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 90
- 229920000642 polymer Polymers 0.000 claims description 76
- 229910052709 silver Inorganic materials 0.000 claims description 41
- 239000004332 silver Substances 0.000 claims description 41
- 239000000839 emulsion Substances 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 12
- 125000000623 heterocyclic group Chemical group 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 229920000126 latex Polymers 0.000 description 39
- 239000004816 latex Substances 0.000 description 35
- 239000000243 solution Substances 0.000 description 29
- 239000000203 mixture Substances 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
- 108010010803 Gelatin Proteins 0.000 description 22
- 229920000159 gelatin Polymers 0.000 description 22
- 239000008273 gelatin Substances 0.000 description 22
- 235000019322 gelatine Nutrition 0.000 description 22
- 235000011852 gelatine desserts Nutrition 0.000 description 22
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 21
- 238000000034 method Methods 0.000 description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000000975 dye Substances 0.000 description 18
- 239000000178 monomer Substances 0.000 description 16
- 125000001424 substituent group Chemical group 0.000 description 16
- 239000007864 aqueous solution Substances 0.000 description 15
- 239000010410 layer Substances 0.000 description 15
- 239000002253 acid Substances 0.000 description 14
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000002243 precursor Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000000084 colloidal system Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 239000003960 organic solvent Substances 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 125000005843 halogen group Chemical group 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 125000001309 chloro group Chemical group Cl* 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 6
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 229960000583 acetic acid Drugs 0.000 description 5
- 238000010556 emulsion polymerization method Methods 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 239000003505 polymerization initiator Substances 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 125000004442 acylamino group Chemical group 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 150000005690 diesters Chemical class 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 4
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 3
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 3
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 3
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 3
- 125000000565 sulfonamide group Chemical group 0.000 description 3
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- AXCGIKGRPLMUDF-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one;sodium Chemical compound [Na].OC1=NC(Cl)=NC(Cl)=N1 AXCGIKGRPLMUDF-UHFFFAOYSA-N 0.000 description 2
- REIAETDXSWRCRG-UHFFFAOYSA-N 2-[2-(prop-2-enoylamino)ethoxy]ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOCCNC(=O)C=C REIAETDXSWRCRG-UHFFFAOYSA-N 0.000 description 2
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Natural products CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 2
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 2
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 2
- 125000004423 acyloxy group Chemical group 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000005153 alkyl sulfamoyl group Chemical group 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 125000004391 aryl sulfonyl group Chemical group 0.000 description 2
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 150000002344 gold compounds Chemical class 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical group CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- SMUQFGGVLNAIOZ-UHFFFAOYSA-N quinaldine Chemical compound C1=CC=CC2=NC(C)=CC=C21 SMUQFGGVLNAIOZ-UHFFFAOYSA-N 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229940001482 sodium sulfite Drugs 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 150000003852 triazoles Chemical group 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000001043 yellow dye Substances 0.000 description 2
- HNISBYCBIMPXKH-UHFFFAOYSA-N (1,1-dichloro-2-ethoxyethyl) prop-2-enoate Chemical compound CCOCC(Cl)(Cl)OC(=O)C=C HNISBYCBIMPXKH-UHFFFAOYSA-N 0.000 description 1
- GBVJQAULALBKDU-UHFFFAOYSA-N (1-bromo-2-methoxyethyl) prop-2-enoate Chemical compound COCC(Br)OC(=O)C=C GBVJQAULALBKDU-UHFFFAOYSA-N 0.000 description 1
- NGDOLKDENPCYIS-UHFFFAOYSA-N (2-chlorocyclohexyl) prop-2-enoate Chemical compound ClC1CCCCC1OC(=O)C=C NGDOLKDENPCYIS-UHFFFAOYSA-N 0.000 description 1
- MRIKSZXJKCQQFT-UHFFFAOYSA-N (3-hydroxy-2,2-dimethylpropyl) prop-2-enoate Chemical compound OCC(C)(C)COC(=O)C=C MRIKSZXJKCQQFT-UHFFFAOYSA-N 0.000 description 1
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- KPPNTDKZDHZJNN-UHFFFAOYSA-N 1-anilino-3-[1-[[1-(anilinocarbamoylamino)cyclohexyl]diazenyl]cyclohexyl]urea Chemical compound C1CCCCC1(N=NC1(CCCCC1)NC(=O)NNC=1C=CC=CC=1)NC(=O)NNC1=CC=CC=C1 KPPNTDKZDHZJNN-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- GXZPMXGRNUXGHN-UHFFFAOYSA-N 1-ethenoxy-2-methoxyethane Chemical compound COCCOC=C GXZPMXGRNUXGHN-UHFFFAOYSA-N 0.000 description 1
- YAOJJEJGPZRYJF-UHFFFAOYSA-N 1-ethenoxyhexane Chemical compound CCCCCCOC=C YAOJJEJGPZRYJF-UHFFFAOYSA-N 0.000 description 1
- GIVBQSUFWURSOS-UHFFFAOYSA-N 1-ethenyltriazole Chemical compound C=CN1C=CN=N1 GIVBQSUFWURSOS-UHFFFAOYSA-N 0.000 description 1
- HRBLHUVHOWWBEN-UHFFFAOYSA-N 1-n,4-n-diethylbenzene-1,4-diamine;hydrochloride Chemical compound Cl.CCNC1=CC=C(NCC)C=C1 HRBLHUVHOWWBEN-UHFFFAOYSA-N 0.000 description 1
- PXJHVKRLFWZUNV-UHFFFAOYSA-N 1-n,4-n-dimethylbenzene-1,4-diamine;hydron;dichloride Chemical compound Cl.Cl.CNC1=CC=C(NC)C=C1 PXJHVKRLFWZUNV-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- KUIZKZHDMPERHR-UHFFFAOYSA-N 1-phenylprop-2-en-1-one Chemical compound C=CC(=O)C1=CC=CC=C1 KUIZKZHDMPERHR-UHFFFAOYSA-N 0.000 description 1
- CBQFBEBEBCHTBK-UHFFFAOYSA-N 1-phenylprop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)C(C=C)C1=CC=CC=C1 CBQFBEBEBCHTBK-UHFFFAOYSA-N 0.000 description 1
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- BUZAXYQQRMDUTM-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-yl prop-2-enoate Chemical compound CC(C)(C)CC(C)(C)OC(=O)C=C BUZAXYQQRMDUTM-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- QGTBRAFPWNISIJ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CCCCOCCOCCOC(=O)C(C)=C QGTBRAFPWNISIJ-UHFFFAOYSA-N 0.000 description 1
- KEVOENGLLAAIKA-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl prop-2-enoate Chemical compound CCCCOCCOCCOC(=O)C=C KEVOENGLLAAIKA-UHFFFAOYSA-N 0.000 description 1
- WFTWWOCWRSUGAW-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CCOCCOCCOC(=O)C(C)=C WFTWWOCWRSUGAW-UHFFFAOYSA-N 0.000 description 1
- ZKLMKZINKNMVKA-UHFFFAOYSA-N 2-(2-hydroxypropoxy)propan-1-ol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CC(O)COC(C)CO ZKLMKZINKNMVKA-UHFFFAOYSA-N 0.000 description 1
- DAVVKEZTUOGEAK-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound COCCOCCOC(=O)C(C)=C DAVVKEZTUOGEAK-UHFFFAOYSA-N 0.000 description 1
- HZMXJTJBSWOCQB-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl prop-2-enoate Chemical compound COCCOCCOC(=O)C=C HZMXJTJBSWOCQB-UHFFFAOYSA-N 0.000 description 1
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- DLLMHEDYJQACRM-UHFFFAOYSA-N 2-(carboxymethyldisulfanyl)acetic acid Chemical compound OC(=O)CSSCC(O)=O DLLMHEDYJQACRM-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- WTBIHKZYDZQMQA-UHFFFAOYSA-N 2-(n-ethylanilino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCN(CC)C1=CC=CC=C1 WTBIHKZYDZQMQA-UHFFFAOYSA-N 0.000 description 1
- RUYYZQCJUGZUCW-UHFFFAOYSA-N 2-(prop-2-enoylamino)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCNC(=O)C=C RUYYZQCJUGZUCW-UHFFFAOYSA-N 0.000 description 1
- MVYVKSBVZFBBPL-UHFFFAOYSA-N 2-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(C)NC(=O)C=C MVYVKSBVZFBBPL-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- RCSBILYQLVXLJG-UHFFFAOYSA-N 2-Propenyl hexanoate Chemical compound CCCCCC(=O)OCC=C RCSBILYQLVXLJG-UHFFFAOYSA-N 0.000 description 1
- PFHOSZAOXCYAGJ-UHFFFAOYSA-N 2-[(2-cyano-4-methoxy-4-methylpentan-2-yl)diazenyl]-4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)(C)OC PFHOSZAOXCYAGJ-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- MZGMQAMKOBOIDR-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCO MZGMQAMKOBOIDR-UHFFFAOYSA-N 0.000 description 1
- ZTJNPDLOIVDEEL-UHFFFAOYSA-N 2-acetyloxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOC(C)=O ZTJNPDLOIVDEEL-UHFFFAOYSA-N 0.000 description 1
- UFIOPCXETLAGLR-UHFFFAOYSA-N 2-acetyloxyethyl prop-2-enoate Chemical compound CC(=O)OCCOC(=O)C=C UFIOPCXETLAGLR-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- ICGLGDINCXDWJB-UHFFFAOYSA-N 2-benzylprop-2-enamide Chemical compound NC(=O)C(=C)CC1=CC=CC=C1 ICGLGDINCXDWJB-UHFFFAOYSA-N 0.000 description 1
- DJKKWVGWYCKUFC-UHFFFAOYSA-N 2-butoxyethyl 2-methylprop-2-enoate Chemical compound CCCCOCCOC(=O)C(C)=C DJKKWVGWYCKUFC-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- WHBAYNMEIXUTJV-UHFFFAOYSA-N 2-chloroethyl prop-2-enoate Chemical compound ClCCOC(=O)C=C WHBAYNMEIXUTJV-UHFFFAOYSA-N 0.000 description 1
- AEPWOCLBLLCOGZ-UHFFFAOYSA-N 2-cyanoethyl prop-2-enoate Chemical compound C=CC(=O)OCCC#N AEPWOCLBLLCOGZ-UHFFFAOYSA-N 0.000 description 1
- XUOKWZRAWBZOQM-UHFFFAOYSA-N 2-cyclohexylprop-2-enamide Chemical compound NC(=O)C(=C)C1CCCCC1 XUOKWZRAWBZOQM-UHFFFAOYSA-N 0.000 description 1
- JWCDUUFOAZFFMX-UHFFFAOYSA-N 2-ethenoxy-n,n-dimethylethanamine Chemical compound CN(C)CCOC=C JWCDUUFOAZFFMX-UHFFFAOYSA-N 0.000 description 1
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 description 1
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
- YXYJVFYWCLAXHO-UHFFFAOYSA-N 2-methoxyethyl 2-methylprop-2-enoate Chemical compound COCCOC(=O)C(C)=C YXYJVFYWCLAXHO-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- FSAHAOQXCSZZHG-UHFFFAOYSA-N 2-methyl-2-(2-methylprop-2-enoylamino)butane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(C)(CC)NC(=O)C(C)=C FSAHAOQXCSZZHG-UHFFFAOYSA-N 0.000 description 1
- VSSGDAWBDKMCMI-UHFFFAOYSA-N 2-methyl-2-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)NC(C)(C)CS(O)(=O)=O VSSGDAWBDKMCMI-UHFFFAOYSA-N 0.000 description 1
- LPNSCOVIJFIXTJ-UHFFFAOYSA-N 2-methylidenebutanamide Chemical compound CCC(=C)C(N)=O LPNSCOVIJFIXTJ-UHFFFAOYSA-N 0.000 description 1
- GASMGDMKGYYAHY-UHFFFAOYSA-N 2-methylidenehexanamide Chemical compound CCCCC(=C)C(N)=O GASMGDMKGYYAHY-UHFFFAOYSA-N 0.000 description 1
- YICILWNDMQTUIY-UHFFFAOYSA-N 2-methylidenepentanamide Chemical compound CCCC(=C)C(N)=O YICILWNDMQTUIY-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- ODPPVFMETNCIRW-UHFFFAOYSA-N 2-methylprop-2-enoyloxymethanesulfonic acid Chemical compound CC(=C)C(=O)OCS(O)(=O)=O ODPPVFMETNCIRW-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- FMFHUEMLVAIBFI-UHFFFAOYSA-N 2-phenylethenyl acetate Chemical compound CC(=O)OC=CC1=CC=CC=C1 FMFHUEMLVAIBFI-UHFFFAOYSA-N 0.000 description 1
- IMOLAGKJZFODRK-UHFFFAOYSA-N 2-phenylprop-2-enamide Chemical compound NC(=O)C(=C)C1=CC=CC=C1 IMOLAGKJZFODRK-UHFFFAOYSA-N 0.000 description 1
- SEILKFZTLVMHRR-UHFFFAOYSA-N 2-phosphonooxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(O)=O SEILKFZTLVMHRR-UHFFFAOYSA-N 0.000 description 1
- UDXXYUDJOHIIDZ-UHFFFAOYSA-N 2-phosphonooxyethyl prop-2-enoate Chemical compound OP(O)(=O)OCCOC(=O)C=C UDXXYUDJOHIIDZ-UHFFFAOYSA-N 0.000 description 1
- GQTFHSAAODFMHB-UHFFFAOYSA-N 2-prop-2-enoyloxyethanesulfonic acid Chemical compound OS(=O)(=O)CCOC(=O)C=C GQTFHSAAODFMHB-UHFFFAOYSA-N 0.000 description 1
- JPXZAISSLVEZTK-UHFFFAOYSA-N 2-propan-2-yloxyethyl 2-methylprop-2-enoate Chemical compound CC(C)OCCOC(=O)C(C)=C JPXZAISSLVEZTK-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- UELIBMUMKLRTKJ-UHFFFAOYSA-N 3-amino-1,4-dihydropyrazol-5-one Chemical compound NC1=NNC(=O)C1 UELIBMUMKLRTKJ-UHFFFAOYSA-N 0.000 description 1
- QCSXJJWJFMJGQY-UHFFFAOYSA-N 3-amino-3-ethoxypropanoic acid Chemical compound CCOC(N)CC(O)=O QCSXJJWJFMJGQY-UHFFFAOYSA-N 0.000 description 1
- JBTDFRNUVWFUGL-UHFFFAOYSA-N 3-aminopropyl carbamimidothioate;dihydrobromide Chemical compound Br.Br.NCCCSC(N)=N JBTDFRNUVWFUGL-UHFFFAOYSA-N 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- IWTYTFSSTWXZFU-UHFFFAOYSA-N 3-chloroprop-1-enylbenzene Chemical compound ClCC=CC1=CC=CC=C1 IWTYTFSSTWXZFU-UHFFFAOYSA-N 0.000 description 1
- XHULUQRDNLRXPF-UHFFFAOYSA-N 3-ethenyl-1,3-oxazolidin-2-id-4-one Chemical compound C(=C)N1[CH-]OCC1=O XHULUQRDNLRXPF-UHFFFAOYSA-N 0.000 description 1
- UVRCNEIYXSRHNT-UHFFFAOYSA-N 3-ethylpent-2-enamide Chemical compound CCC(CC)=CC(N)=O UVRCNEIYXSRHNT-UHFFFAOYSA-N 0.000 description 1
- NWKKCUWIMOZYOO-UHFFFAOYSA-N 3-methoxybutyl 2-methylprop-2-enoate Chemical compound COC(C)CCOC(=O)C(C)=C NWKKCUWIMOZYOO-UHFFFAOYSA-N 0.000 description 1
- NPYMXLXNEYZTMQ-UHFFFAOYSA-N 3-methoxybutyl prop-2-enoate Chemical compound COC(C)CCOC(=O)C=C NPYMXLXNEYZTMQ-UHFFFAOYSA-N 0.000 description 1
- CEBRPXLXYCFYGU-UHFFFAOYSA-N 3-methylbut-1-enylbenzene Chemical compound CC(C)C=CC1=CC=CC=C1 CEBRPXLXYCFYGU-UHFFFAOYSA-N 0.000 description 1
- ZTHJQCDAHYOPIK-UHFFFAOYSA-N 3-methylbut-2-en-2-ylbenzene Chemical compound CC(C)=C(C)C1=CC=CC=C1 ZTHJQCDAHYOPIK-UHFFFAOYSA-N 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- MTOJDBAZGOYUOZ-UHFFFAOYSA-N 4-aminobenzenesulfonyl chloride Chemical compound NC1=CC=C(S(Cl)(=O)=O)C=C1 MTOJDBAZGOYUOZ-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- VVAAYFMMXYRORI-UHFFFAOYSA-N 4-butoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCCCOC(=O)CC(=C)C(O)=O VVAAYFMMXYRORI-UHFFFAOYSA-N 0.000 description 1
- MSZCRKZKNKSJNU-UHFFFAOYSA-N 4-chlorobutyl prop-2-enoate Chemical compound ClCCCCOC(=O)C=C MSZCRKZKNKSJNU-UHFFFAOYSA-N 0.000 description 1
- LZHLUTZGFZAYCH-UHFFFAOYSA-N 4-cyano-2-methylidenebutanamide Chemical compound NC(=O)C(=C)CCC#N LZHLUTZGFZAYCH-UHFFFAOYSA-N 0.000 description 1
- RTTAGBVNSDJDTE-UHFFFAOYSA-N 4-ethoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCOC(=O)CC(=C)C(O)=O RTTAGBVNSDJDTE-UHFFFAOYSA-N 0.000 description 1
- YKXAYLPDMSGWEV-UHFFFAOYSA-N 4-hydroxybutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCO YKXAYLPDMSGWEV-UHFFFAOYSA-N 0.000 description 1
- OIYTYGOUZOARSH-UHFFFAOYSA-N 4-methoxy-2-methylidene-4-oxobutanoic acid Chemical compound COC(=O)CC(=C)C(O)=O OIYTYGOUZOARSH-UHFFFAOYSA-N 0.000 description 1
- PIRPEUWCTMKABH-UHFFFAOYSA-N 4-methoxy-2-methylidenebutanamide Chemical compound COCCC(=C)C(N)=O PIRPEUWCTMKABH-UHFFFAOYSA-N 0.000 description 1
- MTOCKMVNXPZCJW-UHFFFAOYSA-N 4-n-dodecyl-4-n-ethyl-2-methylbenzene-1,4-diamine Chemical compound CCCCCCCCCCCCN(CC)C1=CC=C(N)C(C)=C1 MTOCKMVNXPZCJW-UHFFFAOYSA-N 0.000 description 1
- IJJSFSXLZYFTKV-UHFFFAOYSA-N 4-n-methylbenzene-1,4-diamine;hydrochloride Chemical compound Cl.CNC1=CC=C(N)C=C1 IJJSFSXLZYFTKV-UHFFFAOYSA-N 0.000 description 1
- JXRGUPLJCCDGKG-UHFFFAOYSA-N 4-nitrobenzenesulfonyl chloride Chemical compound [O-][N+](=O)C1=CC=C(S(Cl)(=O)=O)C=C1 JXRGUPLJCCDGKG-UHFFFAOYSA-N 0.000 description 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 description 1
- INRQKLGGIVSJRR-UHFFFAOYSA-N 5-hydroxypentyl prop-2-enoate Chemical compound OCCCCCOC(=O)C=C INRQKLGGIVSJRR-UHFFFAOYSA-N 0.000 description 1
- RYHAZBFRQQCSOJ-UHFFFAOYSA-N 5-methoxypent-1-en-3-one Chemical class COCCC(=O)C=C RYHAZBFRQQCSOJ-UHFFFAOYSA-N 0.000 description 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 description 1
- NUXLDNTZFXDNBA-UHFFFAOYSA-N 6-bromo-2-methyl-4h-1,4-benzoxazin-3-one Chemical compound C1=C(Br)C=C2NC(=O)C(C)OC2=C1 NUXLDNTZFXDNBA-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- LYJHVEDILOKZCG-UHFFFAOYSA-N Allyl benzoate Chemical compound C=CCOC(=O)C1=CC=CC=C1 LYJHVEDILOKZCG-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- MZNHUHNWGVUEAT-XBXARRHUSA-N Hexyl crotonate Chemical compound CCCCCCOC(=O)\C=C\C MZNHUHNWGVUEAT-XBXARRHUSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000002262 Schiff base Substances 0.000 description 1
- 150000004753 Schiff bases Chemical class 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- LCXXNKZQVOXMEH-UHFFFAOYSA-N Tetrahydrofurfuryl methacrylate Chemical compound CC(=C)C(=O)OCC1CCCO1 LCXXNKZQVOXMEH-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- LKOIPYBSUJWJSM-UHFFFAOYSA-N [2-(dimethylamino)-2-phenoxyethyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(N(C)C)OC1=CC=CC=C1 LKOIPYBSUJWJSM-UHFFFAOYSA-N 0.000 description 1
- MPLZNPZPPXERDA-UHFFFAOYSA-N [4-(diethylamino)-2-methylphenyl]azanium;chloride Chemical compound [Cl-].CC[NH+](CC)C1=CC=C(N)C(C)=C1 MPLZNPZPPXERDA-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- DQVUUGHMHQPVSI-UHFFFAOYSA-N [chloro(phenyl)methyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(Cl)C1=CC=CC=C1 DQVUUGHMHQPVSI-UHFFFAOYSA-N 0.000 description 1
- CXSXCWXUCMJUGI-UHFFFAOYSA-N [methoxy(phenyl)methyl] prop-2-enoate Chemical compound C=CC(=O)OC(OC)C1=CC=CC=C1 CXSXCWXUCMJUGI-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000004466 alkoxycarbonylamino group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 125000005098 aryl alkoxy carbonyl group Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000005129 aryl carbonyl group Chemical group 0.000 description 1
- 125000005162 aryl oxy carbonyl amino group Chemical group 0.000 description 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- MCIURFJELJKSNV-UHFFFAOYSA-N benzene-1,4-diamine;hydron;chloride Chemical compound Cl.NC1=CC=C(N)C=C1 MCIURFJELJKSNV-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- ZJRCIQAMTAINCB-UHFFFAOYSA-N benzoylacetonitrile Chemical compound N#CCC(=O)C1=CC=CC=C1 ZJRCIQAMTAINCB-UHFFFAOYSA-N 0.000 description 1
- 125000001231 benzoyloxy group Chemical group C(C1=CC=CC=C1)(=O)O* 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- 125000001584 benzyloxycarbonyl group Chemical group C(=O)(OCC1=CC=CC=C1)* 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- FCSHDIVRCWTZOX-DVTGEIKXSA-N clobetasol Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@H](C)[C@@](C(=O)CCl)(O)[C@@]1(C)C[C@@H]2O FCSHDIVRCWTZOX-DVTGEIKXSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical class C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 description 1
- ONNFZHAVUSXWTP-UHFFFAOYSA-N diazenylmethanesulfinic acid Chemical compound OS(=O)CN=N ONNFZHAVUSXWTP-UHFFFAOYSA-N 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- OGVXYCDTRMDYOG-UHFFFAOYSA-N dibutyl 2-methylidenebutanedioate Chemical compound CCCCOC(=O)CC(=C)C(=O)OCCCC OGVXYCDTRMDYOG-UHFFFAOYSA-N 0.000 description 1
- ZEFVHSWKYCYFFL-UHFFFAOYSA-N diethyl 2-methylidenebutanedioate Chemical compound CCOC(=O)CC(=C)C(=O)OCC ZEFVHSWKYCYFFL-UHFFFAOYSA-N 0.000 description 1
- XSBSXJAYEPDGSF-UHFFFAOYSA-N diethyl 3,5-dimethyl-1h-pyrrole-2,4-dicarboxylate Chemical compound CCOC(=O)C=1NC(C)=C(C(=O)OCC)C=1C XSBSXJAYEPDGSF-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 description 1
- ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 description 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
- 229960004419 dimethyl fumarate Drugs 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- XJELOQYISYPGDX-UHFFFAOYSA-N ethenyl 2-chloroacetate Chemical compound ClCC(=O)OC=C XJELOQYISYPGDX-UHFFFAOYSA-N 0.000 description 1
- CMXXMZYAYIHTBU-UHFFFAOYSA-N ethenyl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC=C CMXXMZYAYIHTBU-UHFFFAOYSA-N 0.000 description 1
- AFIQVBFAKUPHOA-UHFFFAOYSA-N ethenyl 2-methoxyacetate Chemical compound COCC(=O)OC=C AFIQVBFAKUPHOA-UHFFFAOYSA-N 0.000 description 1
- WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- LZWYWAIOTBEZFN-UHFFFAOYSA-N ethenyl hexanoate Chemical compound CCCCCC(=O)OC=C LZWYWAIOTBEZFN-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- XWNVSPGTJSGNPU-UHFFFAOYSA-N ethyl 4-chloro-1h-indole-2-carboxylate Chemical compound C1=CC=C2NC(C(=O)OCC)=CC2=C1Cl XWNVSPGTJSGNPU-UHFFFAOYSA-N 0.000 description 1
- FKIRSCKRJJUCNI-UHFFFAOYSA-N ethyl 7-bromo-1h-indole-2-carboxylate Chemical compound C1=CC(Br)=C2NC(C(=O)OCC)=CC2=C1 FKIRSCKRJJUCNI-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 1
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 description 1
- DWXAVNJYFLGAEF-UHFFFAOYSA-N furan-2-ylmethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CO1 DWXAVNJYFLGAEF-UHFFFAOYSA-N 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- PTFYQSWHBLOXRZ-UHFFFAOYSA-N imidazo[4,5-e]indazole Chemical compound C1=CC2=NC=NC2=C2C=NN=C21 PTFYQSWHBLOXRZ-UHFFFAOYSA-N 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000002650 laminated plastic Substances 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 125000006626 methoxycarbonylamino group Chemical group 0.000 description 1
- MPHUYCIKFIKENX-UHFFFAOYSA-N methyl 2-ethenylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C=C MPHUYCIKFIKENX-UHFFFAOYSA-N 0.000 description 1
- NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- RCLLINSDAJVOHP-UHFFFAOYSA-N n-ethyl-n',n'-dimethylprop-2-enehydrazide Chemical compound CCN(N(C)C)C(=O)C=C RCLLINSDAJVOHP-UHFFFAOYSA-N 0.000 description 1
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 1
- HVYCQBKSRWZZGX-UHFFFAOYSA-N naphthalen-1-yl 2-methylprop-2-enoate Chemical compound C1=CC=C2C(OC(=O)C(=C)C)=CC=CC2=C1 HVYCQBKSRWZZGX-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000006678 phenoxycarbonyl group Chemical group 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- 150000003012 phosphoric acid amides Chemical class 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- IBGXDQCATAOYOE-UHFFFAOYSA-N prop-2-enoyloxymethanesulfonic acid Chemical compound OS(=O)(=O)COC(=O)C=C IBGXDQCATAOYOE-UHFFFAOYSA-N 0.000 description 1
- ZQMAPKVSTSACQB-UHFFFAOYSA-N prop-2-enyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC=C ZQMAPKVSTSACQB-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 125000003226 pyrazolyl group Chemical group 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000006462 rearrangement reaction Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229940065287 selenium compound Drugs 0.000 description 1
- 150000003343 selenium compounds Chemical class 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical group O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- LESFYQKBUCDEQP-UHFFFAOYSA-N tetraazanium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound N.N.N.N.OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O LESFYQKBUCDEQP-UHFFFAOYSA-N 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- HERBOKBJKVUALN-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O HERBOKBJKVUALN-UHFFFAOYSA-K 0.000 description 1
- 238000001132 ultrasonic dispersion Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/327—Macromolecular coupling substances
- G03C7/3275—Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
ç£æ¥äžã®å©çšåé
æ¬çºæã¯ãããã²ã³åéã«ã©ãŒåçæå
ææã«
é¢ããæŽã«è©³çŽ°ã«ã¯æ°èŠãªããŒã³ã¿ãŒè²çŽ ç»å圢
ææ§ããªããŒã«ãã©ãŒãå«æãåçç¹æ§ãæ¹è¯ã
ããããã²ã³åéã«ã©ãŒåçæå ææã«é¢ããã åŸæ¥æè¡ æžè²æ³ã«åºã¥ãã«ã©ãŒåçç»åã®åœ¢æã¯ãäžè¬
ã«ããã²ã³åéåçæå ææãã·ã¢ã³ã«ãã©ãŒã
ããŒã³ã¿ã«ãã©ãŒããã³ã€ãšããŒã«ãã©ãŒã®ååš
äžã«è³éŠæ第äžçŽã¢ãã³çŸåäž»è¬ãçšããŠçºè²çŸ
ååŠçããããšã«ãã€ãŠè¡ãããé²å ããããã
ã²ã³åéåçæå ææã®ããã²ã³åéç²åã¯ãçŸ
åäž»è¬ã«ãã€ãŠéå ãããåæã«çæããçŸåäž»
è¬ã®é žåäœã¯ã«ãã©ãŒãšã«ãããªã³ã°åå¿ããŠã
ã·ã¢ã³è²çŽ ãããŒã³ã¿è²çŽ ããã³ã€ãšããŒè²çŽ ã
ããªãã«ã©ãŒåçç»åã圢æããã äžèšåã«ãã©ãŒã¯ããã²ã³åéä¹³å€äžãŸãã¯çº
è²çŸå液äžã®ããããã«å«æããããããšãã§ã
ãã éåžžã€ãšããŒè²çŽ ã圢æããããã«ã¯äŸãã°ã¢
ã·ã«ã¢ã»ãã¢ããªãç³»ãŸãã¯ãã³ãŸã€ã«ã¡ã¿ã³ç³»
ã«ãã©ãŒã䜿ãããããŒã³ã¿è²çŽ ã圢æãããã
ã«ã¯äž»ãšããŠãã©ãŸãã³ç³»ããã©ãŸããã³ãºã€ã
ããŸãŒã«ç³»ãã·ã¢ãã¢ã»ãããšãã³ç³»ãŸãã¯ã€ã³
ããã³ç³»ã«ãã©ãŒçã䜿ãããã·ã¢ã³è²çŽ ã圢æ
ããããã«ã¯äž»ãšããŠããšããŒã«ç³»ãŸãã¯ããã
ãŒã«ç³»ã«ãã©ãŒã䜿ãããã䜿çšãããã«ãã©ãŒ
ãšããŠã¯çºè²çŸåã«ããåã«è²çŽ ã圢æããã ã
ã§ãªããäŸãã°çºè²çŸåæ§ãè¯ãããšãããã²ã³
åéä¹³å€ãžã®åæ£æ§ããã³å®å®æ§ãè¯ãããšããŸ
ã圢æãããè²çŽ ãå ãç±ã湿æ°çã«å¯ŸããŠå ç¢
æ§ãæããå åžåæ³¢é·åãæãŸããç¯å²ã«ããã
ãšçã®çš®ã ã®ç¹æ§ãæããããšãå¿ èŠã§ããã å€å±€ã«ã©ãŒåçæå ææã«ãããŠã¯åè²çŽ ã®æ··
è²ããªãããè²åçŸãåäžãããããã«ãããã
ã®ã«ãã©ãŒãåé¢ããå±€ã«åºå®ããå¿ èŠãããã
ãã®ããã®ã«ãã©ãŒã®èæ¡æ£æ³ãšããŠã¯åŸæ¥ãã
çš®ã ã®æ¹æ³ãç¥ãããŠããã ãã®ïŒã€ã®æ¹æ³ã¯ãã«ãã©ãŒååäžã«æ¡æ£ãé²
ãããã«é·éã®èèªæåºãå°å ¥ãããã®ã§ããã
ã«ãã©ãŒã¯ã¢ã«ã«ãªå¯æº¶æ§ãšãªããŒã©ãã³æ°Žæº¶æ¶²
ã«æ·»å ããããé«æ²žç¹ææ©æº¶å€ã«æº¶ãããŠãŒã©ã
ã³æ°Žæº¶æ¶²äžã«ä¹³ååæ£ãããããããªããããã
ã®ã«ãã©ãŒã¯ãŒã©ãã³æ°Žæº¶æ¶²ã®ç²åºŠãèãããäž
æãããããŸãã¯ä¹³å€äžã§çµæ¶ã®æåºãåŒèµ·ãã
ãããæ¬ ç¹ãæããããŸãé«æ²žç¹ã®ææ©æº¶å€ã¯ä¹³
å€å±€ãè»åãããããå€éã®ãŒã©ãã³ãå¿ èŠãš
ããä¹³å€å±€ã®èèåãå°é£ã§ãã€ããäžæ¹ã«ãã©
ãŒã®èæ¡æ£æ§ãšãã«ãã©ãŒååã«éåå¯èœãªäžé£œ
åçµåãå«ãåºãå°å ¥ããåéäœã«ãã©ãŒãéå
ããããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãçšããæ¹æ³
ãããã ããªããŒã«ãã©ãŒã¯ã©ããã¯ã¹ã®åœ¢ã§èŠªæ°Žæ§ã³
ãã€ãçµæç©ã«å ããããã®æ¹æ³ã«ã¯ã次ã®æ¹æ³
ããããïŒã€ã¯ã«ãã©ãŒã¢ãããŒãå¿ èŠã«ããä»
ã®å ±éåæåãšå ±ã«ä¹³åéåæ³ã«ããéåãçŽæ¥
ã©ããã¯ã¹ã圢æããããããã²ã³åéä¹³å€ã«å
ããæ¹æ³ã§ãããä»ã®ïŒã€ã¯ãã«ãã©ãŒã¢ãããŒ
ãå¿ èŠã«ããä»ã®å ±éåæåãšå ±ã«æº¶æ¶²éåã«ã
ãéåãåŸãããããªããŒã«ãã©ãŒã溶åªã«æº¶è§£
ããã®ã¡ããããŒã©ãã³æ°Žæº¶æ¶²äžã«åæ£ãã©ãã
ã¯ã¹ãšããæ¹æ³ã§ãããåè ã®ä¹³åéåæ³ã«ã€ã
ãŠã¯ç±³åœç¹èš±3370952å·ããã³å4080211å·ã«ãã
ããèšèŒãããŠãããåŸè ã®æ¹æ³ã«ã€ããŠã¯ãäŸ
ãã°ç±³åœç¹èš±3451820å·ã«èšèŒãããŠããããã®
ãããªããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢ã§èŠªæ°Ž
æ§ã³ãã€ãçµæç©ã«å ããæ¹æ³ã¯ä»ã®æ¹æ³ã«æ¯ã¹
ãŠæ¬¡ã®ãããªå©ç¹ãæããã ããªãã¡ãããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã¯é«
æ¿åºŠã®ã«ãã©ãŒåäœãå«ãããšãã§ããé«æ²žç¹æ
æ©æº¶å€ãå«ãŸãªãããèèåãå¯èœã§ãããé®®é
æ§ã®åäžãã¯ãããããŸããŒã©ãã³æ°Žæº¶æ¶²ã®å¢ç²
ãå°ãªãããé«éåäžå¡åžãå¯èœãšãªããããã«
ããªããŒã«ãã©ãŒã¯ã©ããã¯ã¹åãããŠããã
ãã圢æãããèã®åŒ·åºŠãå£åãããããšããª
ãã ãã®ããã«ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢
ã§ããã²ã³åéä¹³å€ã«å ãããã®ãšããŠãããã€
ãã®äŸãæãããããäŸãã°ç±³åœç¹èš±ç¬¬4080211
å·ãå第3451820å·ãè±åœç¹èš±ç¬¬1247688å·ã§ã¯ïŒ
åœéããŒã³ã¿ããªããŒã«ãã©ãŒã©ããã¯ã¹ã«ã€ã
ãŠã®è£œé æ³ãèšèŒãããç±³åœç¹èš±ç¬¬3767412å·ã«
ã¯ã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãèšèŒã
ãããŸãç±³åœç¹èš±ç¬¬3926436å·ãªãã³ã«è¥¿ç¬ç¹èš±
第2725591å·ã«ã¯ç«¶äºã«ãã©ãŒãšã®å ±éåã©ãã
ã¯ã¹ãèšèŒãããŠãããããããªããããããã®
ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã¯åèšã®ãããªåª
ããå€ãã®å©ç¹ãæããŠãããã次ã®ãããªæ¹è¯
ãã¹ãåé¡ç¹ãæããŠããã解決ãæãŸããŠã
ãã (1) ã«ãããªã³ã°åå¿é床ãé ããååãªè²çŽ æ¿
床ãåŸãããªãã (2) çºè²çŸåã«ããäžå¿ èŠãªã«ããªãçãæãã (3) ã«ãã©ãŒã¢ãããŒã®æº¶è§£æ§ãäœãã極ããŠé
åæ§ãäœãã (4) 圢æãããè²çŽ ç»åã®æ¹¿ç±å ç¢æ§ãå£ãã çºæã®ç®ç æ¬çºæã®ç®çã¯ãè匷床ãèèåã«ããé®®éæ§
ãªãã³ã«æ¹¿ç±å ç¢æ§çã®åªããè²çŽ ã圢æãåŸã
ã°ããã§ãªããç¹ã«çºè²æ§ãæ床ãã«ããªãæ¹è¯
ãããããŒã³ã¿ããªããŒã«ãã©ãŒã©ããã¯ã¹ãå«
æããããã²ã³åéã«ã©ãŒåçæå ææãæäŸã
ãããšã«ããã çºæã®æ§æ äžèšæ¬çºæã®ç®çã¯æ¯æäœäžã«ãäžèšäžè¬åŒ
ã§ç€ºãããç¹°è¿ãåäœãæããããŒã³ã¿è²
çŽ åœ¢ææ§ããªããŒã«ãã©ãŒãå«æããããã²ã³å
éä¹³å€å±€ãæããããã²ã³åéã«ã©ãŒåçæå æ
æã«ããéæããããšãã§ãã äžè¬åŒïŒ»ïŒœ åŒäžãArã¯ã¢ãªãŒã«åºãŸãã¯è€çŽ ç°åºãè¡šã
ããã¯ãšãã¬ã³æ§äžé£œååºãŸãã¯ãšãã¬ã³æ§äž
飜ååºãæããåºãè¡šãããã¯æ°ŽçŽ ååãŸãã¯
çºè²çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°åå¿ã«ã
ãé¢è±å¯èœãªåºãè¡šããã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èšèŒããã æ¬çºæã«ä¿ããããŒã³ã¿è²çŽ 圢æããªããŒã«ã
ã©ãŒåéäœãè¡šããåèšäžè¬åŒïŒ»ïŒœã«ãããŠïŒ±
ãè¡šãããšãã¬ã³æ§äžé£œååºãæããåºãšããŠ
ã¯ã奜ãŸããã¯äžèšäžè¬åŒïŒ»ïŒœã§è¡šããããšã
ã§ããã äžè¬åŒïŒ»ïŒœ åŒäžãã¯æ°ŽçŽ ååãããã²ã³ååãŸãã¯ã¢ã«
ãã«åºã奜ãŸããã¯ççŽ æ°ïŒãïŒåã®äœçŽã¢ã«ã
ã«åºïŒäŸãã°ãã¡ãã«åºããšãã«åºãïœâããã«
åºçïŒãè¡šããããã®ã¢ã«ãã«åºã¯çœ®æåºãæã
ãŠããŠããããã¯âCONHâïŒäœããçªçŽ åå
ã¯äžè¬åŒïŒ»ïŒœã®ïŒ¡ã«çµåããŠãããïŒãâSO2â
äœããé žçŽ ååã¯äžè¬åŒïŒ»ïŒœã®ïŒ¡ã«çµåããŠã
ããïŒãŸãã¯ãâCOOâïŒäœããé žçŽ ååã¯äžè¬åŒ
ã®ïŒ¡ã«çµåããŠãããïŒã®äºäŸ¡ã®åºãè¡šã
ããã¯ã¢ã«ãã¬ã³åºïŒå¥œãŸããã¯ççŽ æ°ïŒã10
åã®ã¢ã«ãã¬ã³åºïŒããŸãã¯ããšãã¬ã³åºã®äºäŸ¡
ã®åºãè¡šããããããŠäžèšã¢ã«ãã¬ã³åºã¯çŽéã§
ãåå²éã§ããããäŸãã°ã¡ãã¬ã³åºãã¡ãã«ã¡
ãã¬ã³åºããžã¡ãã¬ã³åºããã«ã¡ãã¬ã³åºçã§ã
ãããŸãäžèšã¢ã«ãã¬ã³åºåã³ããšãã¬ã³åºã¯çœ®
æåºãæããŠããŠããããïœããã³ïœã¯ïŒãŸãã¯
ïŒãè¡šããã åèšäžè¬åŒïŒ»ïŒœã§ã奜ãŸãããã®ã¯ãïœãïŒ
ã®å Žåã§ãã€ãŠããïœâãŸãã¯ïŒ°âããšãã¬ã³
ã§ãããïœãïŒã§ïŒ°ãâCONHâã®å Žåã§ããã
ãäœçŽã¢ã«ãã«åºã®å Žåã§ããã æŽã«ãã奜ãŸããã¯ãïœããã³ïœãïŒã®å Žåã§
ããããã€ïŒ²ãäœçŽã¢ã«ãã«åºãç¹ã«ã¡ãã«åºã®
å Žåã§ããã ã§è¡šããããã¢ã«ãã¬ã³åºãŸãã¯ããšãã¬ã³
åºã®çœ®æåºãšããŠã¯ãã¢ãªãŒã«åºïŒäŸãã°ããšã
ã«åºïŒããããåºãæ°Žé žåºãã·ã¢ãåºãã¹ã«ãåºã
ã¢ã«ã³ãã·åºïŒäŸãã°ãšããã·åºïŒãã¢ã·ã«ãªã
ã·åºïŒäŸãã°ã¢ã»ããã·åºïŒãã¢ã·ã«ã¢ããåº
ïŒäŸãã°ã¢ã»ãã«ã¢ããåºïŒãã¹ã«ãã³ã¢ããåº
ïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³ã¢ããåºïŒãã¹ã«ãã¢ã¢ã€
ã«åºïŒäŸãã°ã¡ãã«ã¹ã«ãã¢ã¢ã€ã«åºïŒãããã²
ã³ååïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ åå
çïŒãã«ã«ããã·ã«åºãã«ã«ãã¢ã€ã«åºïŒäŸãã°
ã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¢ã«ã³ãã·ã«ã«ãã¢ã€
ã«åºïŒäŸãã°ã¡ããã·ã«ã«ãã¢ã€ã«åºçïŒãã¹ã«
ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºçïŒãçã
æããããããããã®çœ®æåºã¯ïŒå以äžæããŠã
ãŠãå·®æ¯ããªãããã®å Žåã¯ãããã®çœ®æåºãå
äžã§ãã€ãŠãç°ãªã€ãŠããŠãããã äžè¬åŒïŒ»ïŒœã«ãããŠãã§è¡šãããããçºè²
çŸåäž»è¬ã®é žåäœãšã«ãããªã³ã°åå¿ããéã«é¢
è±ãåŸãåºã¯ã詳ããã¯ãäžèšäžè¬åŒïŒ»ïœïŒœ
ïœïŒœãããã³ïŒ»ïœïŒœã§è¡šããããã äžè¬åŒïŒ»ïœïŒœ ââR1 äžè¬åŒïŒ»ïœïŒœ ââR2 äžè¬åŒïŒ»ïœïŒœ åŒäžãR1ïŒR2ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢
ã·ã«åºãçãè¡šãããR3ã¯ïŒå¡ãŸãã¯ïŒå¡ã®è€
çŽ ç°ïŒäŸãã°ã€ãããŸãŒã«ç°ããã©ãŸãŒã«ç°ãã
ããªãžã³ç°ãã¢ã«ããªã³ç°ãã¹ã¯ã·ã³ã€ããç°ã
ããªã¢ãŸãŒã«ç°çïŒã圢æããã®ã«å¿ èŠãªééå±
åå矀ãè¡šããã 次ã«äžè¬åŒïŒ»ïœïŒœïŒïŒ»ïœïŒœåã³ïŒ»ïœïŒœã§è¡š
ããããã®ãã¡ã奜ãŸããå ·äœäŸãäžèšã«ç€ºã
ãæ¬çºæã¯ããã«éå®ãããªãã (1) äžè¬åŒïŒ»ïœïŒœã®ââR1ã«è©²åœããå ·äœ
äŸ ââC12H25ïŒ
é¢ããæŽã«è©³çŽ°ã«ã¯æ°èŠãªããŒã³ã¿ãŒè²çŽ ç»å圢
ææ§ããªããŒã«ãã©ãŒãå«æãåçç¹æ§ãæ¹è¯ã
ããããã²ã³åéã«ã©ãŒåçæå ææã«é¢ããã åŸæ¥æè¡ æžè²æ³ã«åºã¥ãã«ã©ãŒåçç»åã®åœ¢æã¯ãäžè¬
ã«ããã²ã³åéåçæå ææãã·ã¢ã³ã«ãã©ãŒã
ããŒã³ã¿ã«ãã©ãŒããã³ã€ãšããŒã«ãã©ãŒã®ååš
äžã«è³éŠæ第äžçŽã¢ãã³çŸåäž»è¬ãçšããŠçºè²çŸ
ååŠçããããšã«ãã€ãŠè¡ãããé²å ããããã
ã²ã³åéåçæå ææã®ããã²ã³åéç²åã¯ãçŸ
åäž»è¬ã«ãã€ãŠéå ãããåæã«çæããçŸåäž»
è¬ã®é žåäœã¯ã«ãã©ãŒãšã«ãããªã³ã°åå¿ããŠã
ã·ã¢ã³è²çŽ ãããŒã³ã¿è²çŽ ããã³ã€ãšããŒè²çŽ ã
ããªãã«ã©ãŒåçç»åã圢æããã äžèšåã«ãã©ãŒã¯ããã²ã³åéä¹³å€äžãŸãã¯çº
è²çŸå液äžã®ããããã«å«æããããããšãã§ã
ãã éåžžã€ãšããŒè²çŽ ã圢æããããã«ã¯äŸãã°ã¢
ã·ã«ã¢ã»ãã¢ããªãç³»ãŸãã¯ãã³ãŸã€ã«ã¡ã¿ã³ç³»
ã«ãã©ãŒã䜿ãããããŒã³ã¿è²çŽ ã圢æãããã
ã«ã¯äž»ãšããŠãã©ãŸãã³ç³»ããã©ãŸããã³ãºã€ã
ããŸãŒã«ç³»ãã·ã¢ãã¢ã»ãããšãã³ç³»ãŸãã¯ã€ã³
ããã³ç³»ã«ãã©ãŒçã䜿ãããã·ã¢ã³è²çŽ ã圢æ
ããããã«ã¯äž»ãšããŠããšããŒã«ç³»ãŸãã¯ããã
ãŒã«ç³»ã«ãã©ãŒã䜿ãããã䜿çšãããã«ãã©ãŒ
ãšããŠã¯çºè²çŸåã«ããåã«è²çŽ ã圢æããã ã
ã§ãªããäŸãã°çºè²çŸåæ§ãè¯ãããšãããã²ã³
åéä¹³å€ãžã®åæ£æ§ããã³å®å®æ§ãè¯ãããšããŸ
ã圢æãããè²çŽ ãå ãç±ã湿æ°çã«å¯ŸããŠå ç¢
æ§ãæããå åžåæ³¢é·åãæãŸããç¯å²ã«ããã
ãšçã®çš®ã ã®ç¹æ§ãæããããšãå¿ èŠã§ããã å€å±€ã«ã©ãŒåçæå ææã«ãããŠã¯åè²çŽ ã®æ··
è²ããªãããè²åçŸãåäžãããããã«ãããã
ã®ã«ãã©ãŒãåé¢ããå±€ã«åºå®ããå¿ èŠãããã
ãã®ããã®ã«ãã©ãŒã®èæ¡æ£æ³ãšããŠã¯åŸæ¥ãã
çš®ã ã®æ¹æ³ãç¥ãããŠããã ãã®ïŒã€ã®æ¹æ³ã¯ãã«ãã©ãŒååäžã«æ¡æ£ãé²
ãããã«é·éã®èèªæåºãå°å ¥ãããã®ã§ããã
ã«ãã©ãŒã¯ã¢ã«ã«ãªå¯æº¶æ§ãšãªããŒã©ãã³æ°Žæº¶æ¶²
ã«æ·»å ããããé«æ²žç¹ææ©æº¶å€ã«æº¶ãããŠãŒã©ã
ã³æ°Žæº¶æ¶²äžã«ä¹³ååæ£ãããããããªããããã
ã®ã«ãã©ãŒã¯ãŒã©ãã³æ°Žæº¶æ¶²ã®ç²åºŠãèãããäž
æãããããŸãã¯ä¹³å€äžã§çµæ¶ã®æåºãåŒèµ·ãã
ãããæ¬ ç¹ãæããããŸãé«æ²žç¹ã®ææ©æº¶å€ã¯ä¹³
å€å±€ãè»åãããããå€éã®ãŒã©ãã³ãå¿ èŠãš
ããä¹³å€å±€ã®èèåãå°é£ã§ãã€ããäžæ¹ã«ãã©
ãŒã®èæ¡æ£æ§ãšãã«ãã©ãŒååã«éåå¯èœãªäžé£œ
åçµåãå«ãåºãå°å ¥ããåéäœã«ãã©ãŒãéå
ããããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãçšããæ¹æ³
ãããã ããªããŒã«ãã©ãŒã¯ã©ããã¯ã¹ã®åœ¢ã§èŠªæ°Žæ§ã³
ãã€ãçµæç©ã«å ããããã®æ¹æ³ã«ã¯ã次ã®æ¹æ³
ããããïŒã€ã¯ã«ãã©ãŒã¢ãããŒãå¿ èŠã«ããä»
ã®å ±éåæåãšå ±ã«ä¹³åéåæ³ã«ããéåãçŽæ¥
ã©ããã¯ã¹ã圢æããããããã²ã³åéä¹³å€ã«å
ããæ¹æ³ã§ãããä»ã®ïŒã€ã¯ãã«ãã©ãŒã¢ãããŒ
ãå¿ èŠã«ããä»ã®å ±éåæåãšå ±ã«æº¶æ¶²éåã«ã
ãéåãåŸãããããªããŒã«ãã©ãŒã溶åªã«æº¶è§£
ããã®ã¡ããããŒã©ãã³æ°Žæº¶æ¶²äžã«åæ£ãã©ãã
ã¯ã¹ãšããæ¹æ³ã§ãããåè ã®ä¹³åéåæ³ã«ã€ã
ãŠã¯ç±³åœç¹èš±3370952å·ããã³å4080211å·ã«ãã
ããèšèŒãããŠãããåŸè ã®æ¹æ³ã«ã€ããŠã¯ãäŸ
ãã°ç±³åœç¹èš±3451820å·ã«èšèŒãããŠããããã®
ãããªããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢ã§èŠªæ°Ž
æ§ã³ãã€ãçµæç©ã«å ããæ¹æ³ã¯ä»ã®æ¹æ³ã«æ¯ã¹
ãŠæ¬¡ã®ãããªå©ç¹ãæããã ããªãã¡ãããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã¯é«
æ¿åºŠã®ã«ãã©ãŒåäœãå«ãããšãã§ããé«æ²žç¹æ
æ©æº¶å€ãå«ãŸãªãããèèåãå¯èœã§ãããé®®é
æ§ã®åäžãã¯ãããããŸããŒã©ãã³æ°Žæº¶æ¶²ã®å¢ç²
ãå°ãªãããé«éåäžå¡åžãå¯èœãšãªããããã«
ããªããŒã«ãã©ãŒã¯ã©ããã¯ã¹åãããŠããã
ãã圢æãããèã®åŒ·åºŠãå£åãããããšããª
ãã ãã®ããã«ããªããŒã«ãã©ãŒãã©ããã¯ã¹ã®åœ¢
ã§ããã²ã³åéä¹³å€ã«å ãããã®ãšããŠãããã€
ãã®äŸãæãããããäŸãã°ç±³åœç¹èš±ç¬¬4080211
å·ãå第3451820å·ãè±åœç¹èš±ç¬¬1247688å·ã§ã¯ïŒ
åœéããŒã³ã¿ããªããŒã«ãã©ãŒã©ããã¯ã¹ã«ã€ã
ãŠã®è£œé æ³ãèšèŒãããç±³åœç¹èš±ç¬¬3767412å·ã«
ã¯ã·ã¢ã³ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãèšèŒã
ãããŸãç±³åœç¹èš±ç¬¬3926436å·ãªãã³ã«è¥¿ç¬ç¹èš±
第2725591å·ã«ã¯ç«¶äºã«ãã©ãŒãšã®å ±éåã©ãã
ã¯ã¹ãèšèŒãããŠãããããããªããããããã®
ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã¯åèšã®ãããªåª
ããå€ãã®å©ç¹ãæããŠãããã次ã®ãããªæ¹è¯
ãã¹ãåé¡ç¹ãæããŠããã解決ãæãŸããŠã
ãã (1) ã«ãããªã³ã°åå¿é床ãé ããååãªè²çŽ æ¿
床ãåŸãããªãã (2) çºè²çŸåã«ããäžå¿ èŠãªã«ããªãçãæãã (3) ã«ãã©ãŒã¢ãããŒã®æº¶è§£æ§ãäœãã極ããŠé
åæ§ãäœãã (4) 圢æãããè²çŽ ç»åã®æ¹¿ç±å ç¢æ§ãå£ãã çºæã®ç®ç æ¬çºæã®ç®çã¯ãè匷床ãèèåã«ããé®®éæ§
ãªãã³ã«æ¹¿ç±å ç¢æ§çã®åªããè²çŽ ã圢æãåŸã
ã°ããã§ãªããç¹ã«çºè²æ§ãæ床ãã«ããªãæ¹è¯
ãããããŒã³ã¿ããªããŒã«ãã©ãŒã©ããã¯ã¹ãå«
æããããã²ã³åéã«ã©ãŒåçæå ææãæäŸã
ãããšã«ããã çºæã®æ§æ äžèšæ¬çºæã®ç®çã¯æ¯æäœäžã«ãäžèšäžè¬åŒ
ã§ç€ºãããç¹°è¿ãåäœãæããããŒã³ã¿è²
çŽ åœ¢ææ§ããªããŒã«ãã©ãŒãå«æããããã²ã³å
éä¹³å€å±€ãæããããã²ã³åéã«ã©ãŒåçæå æ
æã«ããéæããããšãã§ãã äžè¬åŒïŒ»ïŒœ åŒäžãArã¯ã¢ãªãŒã«åºãŸãã¯è€çŽ ç°åºãè¡šã
ããã¯ãšãã¬ã³æ§äžé£œååºãŸãã¯ãšãã¬ã³æ§äž
飜ååºãæããåºãè¡šãããã¯æ°ŽçŽ ååãŸãã¯
çºè²çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°åå¿ã«ã
ãé¢è±å¯èœãªåºãè¡šããã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èšèŒããã æ¬çºæã«ä¿ããããŒã³ã¿è²çŽ 圢æããªããŒã«ã
ã©ãŒåéäœãè¡šããåèšäžè¬åŒïŒ»ïŒœã«ãããŠïŒ±
ãè¡šãããšãã¬ã³æ§äžé£œååºãæããåºãšããŠ
ã¯ã奜ãŸããã¯äžèšäžè¬åŒïŒ»ïŒœã§è¡šããããšã
ã§ããã äžè¬åŒïŒ»ïŒœ åŒäžãã¯æ°ŽçŽ ååãããã²ã³ååãŸãã¯ã¢ã«
ãã«åºã奜ãŸããã¯ççŽ æ°ïŒãïŒåã®äœçŽã¢ã«ã
ã«åºïŒäŸãã°ãã¡ãã«åºããšãã«åºãïœâããã«
åºçïŒãè¡šããããã®ã¢ã«ãã«åºã¯çœ®æåºãæã
ãŠããŠããããã¯âCONHâïŒäœããçªçŽ åå
ã¯äžè¬åŒïŒ»ïŒœã®ïŒ¡ã«çµåããŠãããïŒãâSO2â
äœããé žçŽ ååã¯äžè¬åŒïŒ»ïŒœã®ïŒ¡ã«çµåããŠã
ããïŒãŸãã¯ãâCOOâïŒäœããé žçŽ ååã¯äžè¬åŒ
ã®ïŒ¡ã«çµåããŠãããïŒã®äºäŸ¡ã®åºãè¡šã
ããã¯ã¢ã«ãã¬ã³åºïŒå¥œãŸããã¯ççŽ æ°ïŒã10
åã®ã¢ã«ãã¬ã³åºïŒããŸãã¯ããšãã¬ã³åºã®äºäŸ¡
ã®åºãè¡šããããããŠäžèšã¢ã«ãã¬ã³åºã¯çŽéã§
ãåå²éã§ããããäŸãã°ã¡ãã¬ã³åºãã¡ãã«ã¡
ãã¬ã³åºããžã¡ãã¬ã³åºããã«ã¡ãã¬ã³åºçã§ã
ãããŸãäžèšã¢ã«ãã¬ã³åºåã³ããšãã¬ã³åºã¯çœ®
æåºãæããŠããŠããããïœããã³ïœã¯ïŒãŸãã¯
ïŒãè¡šããã åèšäžè¬åŒïŒ»ïŒœã§ã奜ãŸãããã®ã¯ãïœãïŒ
ã®å Žåã§ãã€ãŠããïœâãŸãã¯ïŒ°âããšãã¬ã³
ã§ãããïœãïŒã§ïŒ°ãâCONHâã®å Žåã§ããã
ãäœçŽã¢ã«ãã«åºã®å Žåã§ããã æŽã«ãã奜ãŸããã¯ãïœããã³ïœãïŒã®å Žåã§
ããããã€ïŒ²ãäœçŽã¢ã«ãã«åºãç¹ã«ã¡ãã«åºã®
å Žåã§ããã ã§è¡šããããã¢ã«ãã¬ã³åºãŸãã¯ããšãã¬ã³
åºã®çœ®æåºãšããŠã¯ãã¢ãªãŒã«åºïŒäŸãã°ããšã
ã«åºïŒããããåºãæ°Žé žåºãã·ã¢ãåºãã¹ã«ãåºã
ã¢ã«ã³ãã·åºïŒäŸãã°ãšããã·åºïŒãã¢ã·ã«ãªã
ã·åºïŒäŸãã°ã¢ã»ããã·åºïŒãã¢ã·ã«ã¢ããåº
ïŒäŸãã°ã¢ã»ãã«ã¢ããåºïŒãã¹ã«ãã³ã¢ããåº
ïŒäŸãã°ã¡ã¿ã³ã¹ã«ãã³ã¢ããåºïŒãã¹ã«ãã¢ã¢ã€
ã«åºïŒäŸãã°ã¡ãã«ã¹ã«ãã¢ã¢ã€ã«åºïŒãããã²
ã³ååïŒäŸãã°ããçŽ ååãå¡©çŽ ååãèçŽ åå
çïŒãã«ã«ããã·ã«åºãã«ã«ãã¢ã€ã«åºïŒäŸãã°
ã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¢ã«ã³ãã·ã«ã«ãã¢ã€
ã«åºïŒäŸãã°ã¡ããã·ã«ã«ãã¢ã€ã«åºçïŒãã¹ã«
ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºçïŒãçã
æããããããããã®çœ®æåºã¯ïŒå以äžæããŠã
ãŠãå·®æ¯ããªãããã®å Žåã¯ãããã®çœ®æåºãå
äžã§ãã€ãŠãç°ãªã€ãŠããŠãããã äžè¬åŒïŒ»ïŒœã«ãããŠãã§è¡šãããããçºè²
çŸåäž»è¬ã®é žåäœãšã«ãããªã³ã°åå¿ããéã«é¢
è±ãåŸãåºã¯ã詳ããã¯ãäžèšäžè¬åŒïŒ»ïœïŒœ
ïœïŒœãããã³ïŒ»ïœïŒœã§è¡šããããã äžè¬åŒïŒ»ïœïŒœ ââR1 äžè¬åŒïŒ»ïœïŒœ ââR2 äžè¬åŒïŒ»ïœïŒœ åŒäžãR1ïŒR2ã¯ã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢
ã·ã«åºãçãè¡šãããR3ã¯ïŒå¡ãŸãã¯ïŒå¡ã®è€
çŽ ç°ïŒäŸãã°ã€ãããŸãŒã«ç°ããã©ãŸãŒã«ç°ãã
ããªãžã³ç°ãã¢ã«ããªã³ç°ãã¹ã¯ã·ã³ã€ããç°ã
ããªã¢ãŸãŒã«ç°çïŒã圢æããã®ã«å¿ èŠãªééå±
åå矀ãè¡šããã 次ã«äžè¬åŒïŒ»ïœïŒœïŒïŒ»ïœïŒœåã³ïŒ»ïœïŒœã§è¡š
ããããã®ãã¡ã奜ãŸããå ·äœäŸãäžèšã«ç€ºã
ãæ¬çºæã¯ããã«éå®ãããªãã (1) äžè¬åŒïŒ»ïœïŒœã®ââR1ã«è©²åœããå ·äœ
äŸ ââC12H25ïŒ
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
ãåŒã
(2) äžè¬åŒïŒ»ïœïŒœã®ââR2ã«è©²åœããå
·äœ
äŸ
äŸ
ãåŒãâ
SC12H25ïŒâSC18H37ïŒâSC2H5ïŒâSCH2CH2OHïŒ
ãåŒã
ãåŒã
(3) äžè¬åŒïŒ»ïœïŒœã®
ãåŒãã«è©²åœãã
å
·äœäŸ
ãåŒã
ãåŒã
次ã«äžè¬åŒïŒ»ïŒœã«ãããŠArãè¡šããã¢ãªãŒ
ã«åºãšããŠã¯çœ®æåºãæããããšãã«åºãŸãã¯çœ®
æåºãæããªãããšãã«åºãããããããšãã«åº
ã眮æåºãæããå Žåã«ã¯å¥œãŸããã¯æ¬¡ã®äžè¬åŒ
ã§è¡šããããšãã§ããã äžè¬åŒïŒ»ïŒœ åŒäžãã¯ããã²ã³ååïŒäŸãã°å¡©çŽ ååãè
çŽ ååïŒãŸãã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åºã
è¡šãããã¢ã«ãã«åºãšããŠã¯äŸãã°ã¡ãã«åºããš
ãã«åºããããã«åºãããã«åºãããã眮æåºã
æããŠããŠãããã眮æåºãšããŠã¯ãå¡©çŽ ååã
ããçŽ ååçã®ããã²ã³ååãã¢ã«ãã«ã¹ã«ãã
ã«åºããã³ã¢ãªãŒã«ã¹ã«ããã«åºçãããã眮æ
åºãšããŠå¥œãŸããã¯ããã²ã³ååã§ãããã®ã
ãã«å¥œãŸããã¯ã¡ãã«åºã§ããããŸãã¯é»ååž
åŒæ§ã®çœ®æåºãè¡šããããé»ååžåŒæ§ã®çœ®æåºãš
ã¯Hammettãã«ãã€ãŠå®çŸ©ãããÎŽå€ãããã¯
Swainããã³Luptonãã«ãã€ãŠå°ãããå€ã
é¶ããã倧ãªã眮æåºãšããŠå®çŸ©ããããå ·äœç
ãªé»ååžåŒæ§ã®çœ®æåºãšããŠã¯äŸãã°ããã²ã³å
åãããã²ã³åã¢ã«ãã«ãã«ã«ããã·ã«ãã¹ã«
ããããããã·ã¢ããã¢ã«ãã«ã¹ã«ããã«ãã¢ã«
ãã«ã¹ã«ãã¢ã¢ã€ã«ãã¢ã»ãã«ãã¢ã«ã³ãã·ãã«
ã«ããã«çã®åºããããããããããã«J.Med.
Chem.Vol 16ïŒ1207é ïŒ1973ïŒãJ.Med.Chem.
Vol 20ïŒ304é ïŒ1977ïŒã«èšèŒãããŠããåºçã
å«ããããšãåºæ¥ããã奜ãŸããã¯å¡©çŽ ååãã
ãçŽ ååçã®ããã²ã³ååãŸãã¯ãžã¡ãã«ã¹ã«ã
ã¢ã¢ã€ã«çã®ã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«ã§ãããã
ãã«å¥œãŸããã¯å¡©çŽ ååã§ããã ïœã¯ïŒãïŒã®æŽæ°ãè¡šãããïœãïŒä»¥äžã®ãšã
ïŒã€ä»¥äžããã¯åäžã§ãç°ãªã€ãŠããŠããã
ãã奜ãŸããã¯ïœïŒïŒã§ããããïŒäœã«çµåã
ãŠãããã®ã§ããããŸãArãè¡šããè€çŽ ç°åºãš
ããŠã¯ã眮æåºãæããŠãããïŒå¡ãŸãã¯ïŒå¡ã®
è€çŽ ç°åºãçž®åè€çŽ ç°åºçãããã該è€çŽ ç°ã圢
æããååã®ãã¡å°ãªããšãïŒã€ã¯é žçŽ ååãçª
çŽ ååãŸãã¯ã€ãªãŠååããéžã°ãããã®ã§ãè€
çŽ ç°åºã®äŸãšããŠã¯ãããªã¢ãŸãŒã«ããã¢ãŸãŒ
ã«ããã³ãºãã¢ãŸãŒã«ããã©ã³ãã€ãããŸãŒã«ã
ãªããµãŸãŒã«ããã³ãºãªããµãŸãŒã«ãããªããž
ã³ãããã«ãžã³ãããªãžã³çãæããããšãã§ã
ãããããŠãããè€çŽ ç°åºã®çœ®æåºãšããŠã¯ãäŸ
ãã°ççŽ ååæ°ïŒã10ã®çŽéãªããã¯åå²ç¶ã®ã¢
ã«ãã«åºïŒäŸãã°ã¡ãã«åºãïœâããã«åºãïœâ
ãªã¯ãã«åºïŒãç°ç¶ã¢ã«ãã«åºïŒäŸãã°ã·ã¯ãã
ã³ãã«åºãã·ã¯ãããã·ã«åºïŒã¢ã©ã«ãã«åºïŒäŸ
ãã°ãã³ãžã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ããšãã«
åºãããªã«åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·
åºããšããã·åºïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸ
ãã°ã¡ããã·ã«ã«ããã«åºïŒãã¢ãªãŒã«ãªãã·åº
ïŒäŸãã°ããšããã·åºïŒãã¢ãªãŒã«ãªãã·ã«ã«ãã
ã«åºïŒäŸãã°ããšããã·ã«ã«ããã«åºïŒãã¢ã©ã«
ãã«ãªãã·ã«ã«ããã«åºïŒäŸãã°ãã³ãžã«ãªãã·
ã«ã«ããã«åºïŒãã¢ã«ãã«ããªåºïŒäŸãã°ã¡ãã«
ããªåºããšãã«ããªåºïŒãã«ã«ããã·ã«åºãã¢ã·
ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«ã¢ããåºããã³ãŸã€
ã«ã¢ããåºïŒããžã¢ã·ã«ã¢ããåºïŒäŸãã°ãžã¢ã»
ãã«ã¢ããåºããžãã³ãŸã€ã«ã¢ããåºïŒãâã¢
ã«ãã«ã¢ã·ã«ã¢ããåºïŒäŸãã°ïŒ®âã¡ãã«ã¢ã»ã
ã«ã¢ããåºïŒãâã¢ãªãŒã«ã¢ã·ã«ã¢ããåºïŒäŸ
ãã°ïŒ®âããšãã«ã¢ã»ãã«ã¢ããåºïŒããŠã¬ã€ã
åºïŒäŸãã°ãŠã¬ã€ããã¡ãã«ãŠã¬ã€ãåºïŒãããª
ãŠã¬ã€ãåºïŒäŸãã°ããªãŠã¬ã€ããã¡ãã«ããªãŠ
ã¬ã€ãåºïŒãã¢ã«ãã«ãªãã·ã«ã«ããã«ã¢ããåº
ïŒäŸãã°ã¡ããã·ã«ã«ããã«ã¢ããåºïŒãã¢ãªãŒã«
ãªãã·ã«ã«ããã«ã¢ããåºïŒäŸãã°ããšããã·ã«
ã«ããã«ã¢ããåºïŒãã¢ããåºãã¢ããªãåºãã¢
ã«ãã«ã¢ããåºïŒäŸãã°ã¡ãã«ã¢ããåºïŒãã·ã¯
ãã¢ããåºïŒäŸãã°ã·ã¯ãããã·ã«ã¢ããåºïŒã
ã¢ã«ãã«ã«ã«ããã«åºïŒäŸãã°ã¢ã»ãã«åºïŒãã¢
ãªãŒã«ã«ã«ããã«åºïŒäŸãã°ãã³ãŸã€ã«åºïŒãã¹
ã«ãã³ã¢ããåºïŒäŸãã°ã¡ãã«ã¹ã«ãã³ã¢ãã
åºãã¹ã«ãã³ã¢ããåºïŒãã«ã«ãã¢ã€ã«åºïŒäŸã
ã°ã«ã«ãã¢ã€ã«åºãã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¹
ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹ã«ãã¢ã¢ã€ã«åºãã¡ã
ã«ã¹ã«ãã¢ã¢ã€ã«åºïŒãã·ã¢ãåºãã¢ã·ã«ãªãã·
åºïŒäŸãã°ã¢ã»ãã«ãªãã·åºããã³ãŸã€ã«ãªãã·
åºïŒãã¹ã«ããã«åºãã¹ã«ããã«ãªãã·åºãã¢ã«
ãã«ã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºïŒã
ã¢ãªãŒã«ã¹ã«ããã«åºïŒäŸãã°ããšãã«ã¹ã«ãã
ã«åºïŒãã¹ã«ãåºããããåºãããããã·åºãã
ãã²ã³ååïŒäŸãã°å¡©çŽ ååïŒãŸãã¯è€çŽ ç°åº
ïŒäŸãã°ãã¢ãŸãŒã«åºããªããµãŸãŒã«åºïŒçãæ
ããããšãã§ããã 次ã«æ¬çºæã«ä¿ããããŒã³ã¿ã«ãã©ãŒåéäœã®
å ·äœäŸãèšèŒãããæ¬çºæã¯ãããã®ã¿ã«éå®ã
ãããã®ã§ã¯ãªãã äžèšäŸç€ºããæ¬çºæã«ä¿ããããªããŒããŒã³ã¿
ã«ãã©ãŒã¢ãããŒã¯ãã¢ã¯ãªã«é žãŸãã¯Î±â眮æ
ã¢ã¯ãªã«é žã®é žãã©ã€ãäŸãã°ã¢ã¯ãªã«é žã¯ãã©
ã€ããŸãã¯ã¡ã¿ã¯ãªã«é žã¯ãã©ã€ãçãšïŒâïŒïŒ
âã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ããïŒâïŒâãã©ãŸ
ãªã³âïŒâãªã³ãŸãã¯ïŒâïŒÏâã¢ããã¹ã«ãã³
ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³ãšãåå¿ã
ããããšã«ãã€ãŠåæããããšãã§ããã äžèšã®ïŒâïŒïŒâã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ã
ãïŒâïŒâãã©ãŸãªã³âïŒâãªã³ã¯ïŒâã¢ããâ
ïŒâãã©ãŸãªã³âïŒâãªã³ãšïœâããããã³ãŒã³
ã¹ã«ãã³é žã¯ãã©ã€ããåå¿ãããŠãéå ããã
ãšã«ããåŸãããããïœäœã®ã¢ããåºãã¢ããçµ
å圢æã«ãã€ãŠä¿è·ããïœâã¢ãããã³ãŒã³ã¹ã«
ãã³é žã¯ãã©ã€ããšåå¿åŸãå æ°Žå解ããããšã«
ãã€ãŠãåŸãããšãã§ããã ïŒâïŒÏâã¢ããã¹ã«ãã³ã¢ããïŒâïŒâãã©ãŸ
ãªã³âïŒâãªã³ã¯ïŒâã¢ããâïŒâãã©ãŸãªã³â
ïŒâãªã³ãšã¢ããåºãã¢ããçµå圢æã«ããä¿è·
ããÏâã¢ããã¹ã«ãã³é žã¯ãã©ã€ããšåå¿åŸå
æ°Žå解ããããšã«ããåŸãããšãã§ããã äžèšïŒâã¢ããâïŒâãã©ãŸãªã³âïŒâãªã³ã¯
ç±³åœç¹èš±ç¬¬2376380å·ãè±åœç¹èš±ç¬¬1069563å·ãå
第1166035å·ãå第1190914å·ãå第1269355å·ã«
èšèŒãããŠããåŠããè³éŠæããã©ãžã³ãβâã¢
ããâβâãšããã·ããããªã³é žã§ç°ç¶äœãšãªã
ããJ.Amer.Chem.Soc.66å·»ã1851é ã1855é ã
ïŒ1944幎ïŒã«èšèŒã®è³éŠæããã©ãžã³ãšÎ²âãšã
ãã·âβâã€ããããããªã³é žãšã¹ãã«ãšã®åå¿
ã«ããåæããããšãã§ããã以äžã«æ¬çºæã«ä¿
ããã«ãã©ãŒã¢ãããŒã®ä»£è¡šçãªåæäŸãå ·äœç
ã«èšèŒããã åæäŸ(1) ïŒååç©äŸ(3)ã®åæïŒ ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ããïŒâïŒâãã©
ãŸãªã³âïŒâãªã³20ïœïŒ0.046ã¢ã«ïŒãããã©ã
ãããã©ã³200mlã«æº¶è§£ããããªãžã³11.5ml
ïŒ0.14ã¢ã«ïŒãšããããã³ãŒã³20mlãå ããæ°·å·
äžã§ã¡ã¿ã¯ãªã«é žã¯ãã©ã€ã11.0ïœïŒ0.105ã¢ã«ïŒ
ããã€ãã滎äžãã滎äžåŸïŒæéæªæããã®ã¡æ°Ž
200mlãå ããŠé ¢é žãšãã«ã§æœåºããã æœåºæ¶²ãç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥åŸãæžå§äž
25ã35âã§é ¢é žãšãã«ãçå»åŸãæ®çæ²¹ç¶ç©ã«ãš
ã¿ããŒã«70mlãå ãæ°·å·äžã§æªæããªããæ°Ž20ml
ã«æ°Žé žåãããªãŠã 6.5ïœïŒ0.103ã¢ã«ïŒã溶解ã
ã氎溶液ã滎äžããŠ30åéæªæããã®ã¡ãé ¢é žã§
äžåããæåºããçµæ¶ãå¥ããããšã¿ããŒã«ã
ãåçµæ¶ããäžèšç®çç©12.3ïœïŒåç53ïŒ ïŒãåŸ
ããèç¹235âïŒå解ïŒãFDâMasãNMRãIR
çã®æ©åšåæã§åå®ããã åæäŸ(2) ïŒååç©äŸ(10)ã®åæïŒ ïŒâïŒïŒïŒïŒâãžã¯ããããšãã«ïŒâïŒâïŒïŒâ
ã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ããïŒâïŒâãã©ãŸãª
ã³âïŒâãªã³20ïœïŒ0.05ã¢ã«ïŒãããã©ãããã
ã©ã³200mlã«æº¶è§£ããããªãžã³12mlïŒ0.15ã¢ã«ïŒ
ãšããããã³ãŒã³20mlãå ããæ°·å·äžã§ã¡ã¿ã¯ãª
ã«é žã¯ãã©ã€ã120ïœïŒ0.115ã¢ã«ïŒããã€ãã滎
äžãã滎äžçµäºåŸïŒæéæªæããã®ã¡ãæ°Ž200ml
ãå ããŠé ¢é žãšãã«ã§æœåºãããæœåºæ¶²ãç¡æ°Žç¡«
é žãããªãŠã ã§ä¹Ÿç¥åŸãæžå§äž25ã35âã§é ¢é žãš
ãã«ãçå»ããæ®çç©ã«ãšã¿ããŒã«70mlãå ãã
æ°·å·äžã§æªæããªããæ°Ž20mlã«æ°Žé žåãããªãŠã
6.5ïœïŒ0.103ã¢ã«ïŒã溶解ãã氎溶液ã滎äžããŠ
30åéæªæããã®ã¡é ¢é žã§äžåããæåºããçµæ¶
ãå¥ããããšã¿ããŒã«ããåçµæ¶ããäžèšç®ç
ç©13.7ïœãåŸããåç59ïŒ ãèç¹173âãFDâ
MasãNMRãIRçã®æ©åšåæã«ããåå®ããã æ¬çºæã«ä¿ãããªããŒã«ãã©ãŒã¯ãäžè¬åŒ
ã§è¡šããããç¹°è¿ãåäœã®ã¿ãããªããã
ãããã¢ããªããŒã§ãã€ãŠãããããŸããä»ã®å ±
éåãåŸãã³ã¢ãããŒãšã®ããããã³ããªããŒã§
ãã€ãŠãããããæ¬çºæã«ãããŠã¯å¥œãŸããã¯ã³
ããªããŒåãããããªããŒã«ãã©ãŒã§ããã å ±éåãããã³ã¢ãããŒã®äŸã«ã¯ãã¢ã¯ãªã«é ž
ãšã¹ãã«ãã¡ã¿ã¯ãªã«é žãšã¹ãã«ãã¯ããã³é žãš
ã¹ãã«ãããã«ãšã¹ãã«ããã¬ã€ã³é žãžãšã¹ã
ã«ãããã«é žãžãšã¹ãã«ãã€ã¿ã³ã³é žãžãšã¹ã
ã«ããªã¬ãã€ã³é¡ãã¹ãã¬ã³é¡çãæããããã ãããã®ã³ã¢ãããŒã«ã€ããŠæŽã«å ·äœçã«ç€ºã
ãšãã¢ã¯ãªã«é žãšã¹ãã«ãšããŠã¯ãã¡ãã«ã¢ã¯ãª
ã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœâãããã«ã¢ã¯
ãªã¬ãŒããã€ãœãããã«ã¢ã¯ãªã¬ãŒããïœâãã
ã«ã¢ã¯ãªã¬ãŒããã€ãœããã«ã¢ã¯ãªã¬ãŒããsec
âããã«ã¢ã¯ãªã¬ãŒããã¢ãã«ã¢ã¯ãªã¬ãŒããã
ãã·ã«ã¢ã¯ãªã¬ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãª
ã¬ãŒãããªã¯ãã«ã¢ã¯ãªã¬ãŒããtertâãªã¯ãã«
ã¢ã¯ãªã¬ãŒããïŒâã¯ãããšãã«ã¢ã¯ãªã¬ãŒãã
ïŒâããã¢ãšãã«ã¢ã¯ãªã¬ãŒããïŒâã¯ãããã
ã«ã¢ã¯ãªã¬ãŒããã·ã¢ããšãã«ã¢ã¯ãªã¬ãŒããïŒ
âã¢ã»ããã·ãšãã«ã¢ã¯ãªã¬ãŒãããžã¡ãã«ã¢ã
ããšãã«ã¢ã¯ãªã¬ãŒãããã³ãžã«ã¢ã¯ãªã¬ãŒãã
ã¡ããã·ãã³ãžã«ã¢ã¯ãªã¬ãŒããïŒâã¯ããã·ã¯
ãããã·ã«ã¢ã¯ãªã¬ãŒããã·ã¯ãããã·ã«ã¢ã¯ãª
ã¬ãŒãããã«ããªã«ã¢ã¯ãªã¬ãŒããããã©ããã
ãã«ããªã«ã¢ã¯ãªã¬ãŒããããšãã«ã¢ã¯ãªã¬ãŒ
ããïŒâããããã·ãã³ãã«ã¢ã¯ãªã¬ãŒããïŒïŒ
ïŒâãžã¡ãã«âïŒâããããã·ãããã«ã¢ã¯ãªã¬
ãŒããïŒâã¡ããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâã¡
ããã·ããã«ã¢ã¯ãªã¬ãŒããïŒâãšããã·ãšãã«
ã¢ã¯ãªã¬ãŒããïŒâisoâããããã·ã¢ã¯ãªã¬ãŒ
ããïŒâãããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâïŒïŒ
âã¡ããã·ãšããã·ïŒãšãã«ã¢ã¯ãªã¬ãŒããïŒâ
ïŒïŒâãããã·ãšããã·ïŒãšãã«ã¢ã¯ãªã¬ãŒãã
Ïâã¡ããã·ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã¯ãªã¬ãŒ
ãïŒä»å ã¢ã«æ°ïœïŒïŒïŒãïŒâããã¢âïŒâã¡ã
ãã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒïŒïŒâãžã¯ããâïŒ
âãšããã·ãšãã«ã¢ã¯ãªã¬ãŒãçãæããããã ã¡ã¿ã¯ãªã«é žãšã¹ãã«ã®äŸãšããŠã¯ãã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒãããšãã«ã¡ã¿ã¯ãªã¬ãŒããïœâãã
ãã«ã¡ã¿ã¯ãªã¬ãŒããã€ãœãããã«ã¡ã¿ã¯ãªã¬ãŒ
ããïœâããã«ã¡ã¿ã¯ãªã¬ãŒããã€ãœããã«ã¡ã¿
ã¯ãªã¬ãŒããsecâããã«ã¡ã¿ã¯ãªã¬ãŒããã¢ã
ã«ã¡ã¿ã¯ãªã¬ãŒããããã·ã«ã¡ã¿ã¯ãªã¬ãŒããã·
ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒãããã³ãžã«ã¡ã¿ã¯ãª
ã¬ãŒããã¯ãããã³ãžã«ã¡ã¿ã¯ãªã¬ãŒãããªã¯ã
ã«ã¡ã¿ã¯ãªã¬ãŒããã¹ã«ããããã«ã¡ã¿ã¯ãªã¬ãŒ
ããâãšãã«ââããšãã«ã¢ãããšãã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâïŒïŒâããšãã«ãããã«ãªãã·ïŒ
ãšãã«ã¡ã¿ã¯ãªã¬ãŒãããžã¡ãã«ã¢ããããšãã
ã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒãããã«ããªã«ã¡ã¿ã¯ãªã¬
ãŒããããã©ããããã«ããªã«ã¡ã¿ã¯ãªã¬ãŒãã
ããšãã«ã¡ã¿ã¯ãªã¬ãŒããã¯ã¬ãžã«ã¡ã¿ã¯ãªã¬ãŒ
ãããããã«ã¡ã¿ã¯ãªã¬ãŒããïŒâããããã·ãš
ãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâããããã·ããã«ã¡ã¿
ã¯ãªã¬ãŒããããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ã¿ã¯
ãªã¬ãŒãããžãããã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ã¿ã¯ãª
ã¬ãŒããïŒâã¡ããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒ
âã¡ããã·ããã«ã¡ã¿ã¯ãªã¬ãŒããïŒâã¢ã»ãã
ã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâã¢ã»ãã¢ã»ããã·
ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâãšããã·ãšãã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâisoâããããã·ãšãã«ã¡ã¿ã¯
ãªã¬ãŒããïŒâãããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒãã
ïŒâïŒïŒâã¡ããã·ãšããã·ïŒãšãã«ã¡ã¿ã¯ãªã¬
ãŒããïŒâïŒïŒâãšããã·ãšããã·ïŒãšãã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâïŒïŒâãããã·ãšããã·ïŒãšã
ã«ã¡ã¿ã¯ãªã¬ãŒããÏâã¡ããã·ããªãšãã¬ã³ã°
ãªã³ãŒã«ã¡ã¿ã¯ãªã¬ãŒãïŒä»å ã¢ã«æ°ïœïŒïŒïŒãª
ã©ãæããããšãã§ããã ããã«ãšã¹ãã«é¡ã®äŸãšããŠã¯ãããã«ã¢ã»ã
ãŒããããã«ããããªããŒããããã«ããã¬ãŒ
ããããã«ã€ãœããã¬ãŒããããã«ã«ãããšãŒ
ããããã«ã¯ããã¢ã»ããŒããããã«ã¡ããã·ã¢
ã»ããŒããããã«ããšãã«ã¢ã»ããŒããå®æ¯éŠé ž
ããã«ããµãªãã«é žããã«ãªã©ãæããããã ãŸããªã¬ãã€ã³é¡ã®äŸãšããŠã¯ããžã·ã¯ããã³
ã¿ãžãšã³ããšãã¬ã³ããããã¬ã³ãïŒâããã³ã
ïŒâãã³ãã³ãå¡©åããã«ãå¡©åãããªãã³ãã€
ãœãã¬ã³ãã¯ãããã¬ã³ããã¿ãžãšã³ãïŒïŒïŒâ
ãžã¡ãã«ãã¿ãžãšã³çãæããããšãã§ããã ã¹ãã¬ã³é¡ãšããŠã¯ãäŸãã°ãã¹ãã¬ã³ãã¡ã
ã«ã¹ãã¬ã³ããžã¡ãã«ã¹ãã¬ã³ãããªã¡ãã«ã¹ã
ã¬ã³ããšãã«ã¹ãã¬ã³ãã€ãœãããã«ã¹ãã¬ã³ã
ã¯ãã«ã¡ãã«ã¹ãã¬ã³ãã¡ããã·ã¹ãã¬ã³ãã¢ã»
ããã·ã¹ãã¬ã³ãã¯ãã«ã¹ãã¬ã³ããžã¯ãã«ã¹ã
ã¬ã³ãããã ã¹ãã¬ã³ãããã«å®æ¯éŠé žã¡ãã«ãš
ã¹ãã«ãªã©ãæããããã ã¯ããã³é žãšã¹ãã«ã®äŸãšããŠã¯ãã¯ããã³é ž
ããã«ãã¯ããã³é žããã·ã«ãªã©ãæããããã ãŸãã€ã¿ã³ã³é žãžãšã¹ãã«é¡ãšããŠã¯ãäŸã
ã°ãã€ã¿ã³ã³é žãžã¡ãã«ãã€ã¿ã³ã³é žãžãšãã«ã
ã€ã¿ã³ã³é žãžããã«ãªã©ãæããããã ãã¬ã€ã³é žãžãšã¹ãã«é¡ãšããŠã¯ãäŸãã°ãã
ã¬ã€ã³é žãžãšãã«ããã¬ã€ã³é žãžã¡ãã«ããã¬ã€
ã³é žãžããã«ãªã©ãæããããã ããã«é žãžãšã¹ãã«é¡ãšããŠã¯ãäŸãã°ããã
ã«é žãžãšãã«ãããã«é žãžã¡ãã«ãããã«é žãžã
ãã«ãªã©ãæããããã ãã®ä»ã®ã³ã¢ãããŒã®äŸãšããŠã¯ã次ã®ãã®ã
æããããã ã¢ã¯ãªã«ã¢ããé¡ãäŸãã°ã¢ã¯ãªã«ã¢ãããã¡
ãã«ã¢ã¯ãªã«ã¢ããããšãã«ã¢ã¯ãªã«ã¢ãããã
ããã«ã¢ã¯ãªã«ã¢ãããããã«ã¢ã¯ãªã«ã¢ããã
tertâããã«ã¢ã¯ãªã«ã¢ãããã·ã¯ãããã·ã«ã¢
ã¯ãªã«ã¢ããããã³ãžã«ã¢ã¯ãªã«ã¢ãããããã
ãã·ã¡ãã«ã¢ã¯ãªã«ã¢ãããã¡ããã·ãšãã«ã¢ã¯
ãªã«ã¢ããããžã¡ãã«ã¢ãããšãã«ã¢ã¯ãªã«ã¢ã
ããããšãã«ã¢ã¯ãªã«ã¢ããããžã¡ãã«ã¢ã¯ãªã«
ã¢ããããžãšãã«ã¢ã¯ãªã«ã¢ãããβâã·ã¢ããš
ãã«ã¢ã¯ãªã«ã¢ãããªã©ïŒã¢ãªã«ååç©ãäŸãã°
é ¢é žã¢ãªã«ãã«ããã³é žã¢ãªã«ãã©ãŠãªã³é žã¢ãª
ã«ãå®æ¯éŠé žã¢ãªã«ãªã©ïŒããã«ãšãŒãã«é¡ãäŸ
ãã°ã¡ãã«ããã«ãšãŒãã«ãããã«ããã«ãšãŒã
ã«ãããã·ã«ããã«ãšãŒãã«ãã¡ããã·ãšãã«ã
ãã«ãšãŒãã«ããžã¡ãã«ã¢ãããšãã«ããã«ãšãŒ
ãã«ãªã©ïŒ ããã«ã±ãã³é¡ãäŸãã°ãã¡ãã«ããã«ã±ã
ã³ãããšãã«ããã«ã±ãã³ãã¡ããã·ãšãã«ãã
ã«ã±ãã³ãªã©ïŒ ããã«ç°ç¯ç°ååç©ãäŸãã°ãããã«ããªãž
ã³ãâããã«ã€ãããŸãŒã«ãâããã«ãªããµ
ãŸãªãã³ãâããã«ããªã¢ãŸãŒã«ãâããã«
ãããªãã³ãªã©ïŒ ã°ãªã·ãžã«ãšã¹ãã«é¡ãäŸãã°ãã°ãªã·ãžã«ã¢
ã¯ãªã¬ãŒããã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒããªã©ïŒ äžé£œåãããªã«é¡ãäŸãã°ãã¢ã¯ãªããããª
ã«ãã¡ã¿ã¯ãªããããªã«ãªã©ïŒ å€å®èœæ§ã¢ãããŒãäŸãã°ããžããã«ãã³ãŒ
ã³ãã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ããããšãã¬ã³ã°ãª
ã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããªã©ã æŽã«ãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã€ã¿ã³ã³
é žããã¬ã€ã³é žãã€ã¿ã³ã³é žã¢ãã¢ã«ãã«ãäŸã
ã°ãã€ã¿ã³ã³é žã¢ãã¡ãã«ãã€ã¿ã³ã³é žã¢ããšã
ã«ãã€ã¿ã³ã³é žã¢ãããã«ãªã©ïŒãã¬ã€ã³é žã¢ã
ã¢ã«ãã«ãäŸãã°ããã¬ã€ã³é žã¢ãã¡ãã«ããã¬
ã€ã³é žã¢ããšãã«ããã¬ã€ã³é žã¢ãããã«ãªã©ïŒ
ã·ãã©ã³ã³é žãã¹ãã¬ã³ã¹ã«ãã³é žãããã«ãã³
ãžã«ã¹ã«ãã³é žãããã«ã¹ã«ãã³é žãã¢ã¯ãªãã€
ã«ãªãã·ã¢ã«ãã«ã¹ã«ãã³é žãäŸãã°ãã¢ã¯ãªã
ã€ã«ãªãã·ã¡ãã«ã¹ã«ãã³é žãã¢ã¯ãªãã€ã«ãªã
ã·ãšãã«ã¹ã«ãã³é žãã¢ã¯ãªãã€ã«ãªãã·ããã
ã«ã¹ã«ãã³é žãªã©ïŒã¡ã¿ã¯ãªãã€ã«ãªãã·ã¢ã«ã
ã«ã¹ã«ãã³é žãäŸãã°ã¡ã¿ã¯ãªãã€ã«ãªãã·ã¡ã
ã«ã¹ã«ãã³é žãã¡ã¿ã¯ãªãã€ã«ãªãã·ãšãã«ã¹ã«
ãã³é žãã¡ã¿ã¯ãªãã€ã«ãªãã·ãããã«ã¹ã«ãã³
é žãªã©ïŒã¢ã¯ãªã«ã¢ããã¢ã«ãã«ã¹ã«ãã³é žãäŸ
ãã°ïŒâã¢ã¯ãªã«ã¢ããâïŒâã¡ãã«ãšã¿ã³ã¹ã«
ãã³é žãïŒâã¢ã¯ãªã«ã¢ããâïŒâã¡ãã«ããã
ã³ã¹ã«ãã³é žãïŒâã¢ã¯ãªã«ã¢ããâïŒâã¡ãã«
ãã¿ã³ã¹ã«ãã³é žãªã©ïŒã¡ã¿ã¯ãªã«ã¢ããã¢ã«ã
ã«ã¹ã«ãã³é žãäŸãã°ïŒâã¡ã¿ã¯ãªã«ã¢ããâïŒ
âã¡ãã«ãšã¿ã³ã¹ã«ãã³é žãïŒâã¡ã¿ã¯ãªã«ã¢ã
ãâïŒâã¡ãã«ãããã³ã¹ã«ãã³é žãïŒâã¡ã¿ã¯
ãªã«ã¢ããâïŒâã¡ãã«ãã¿ã³ã¹ã«ãã³é žãªã©ïŒ
ã¢ã¯ãªãã€ã«ãªãã·ã¢ã«ãã«ãã¹ããšãŒããäŸã
ã°ãã¢ã¯ãªãã€ã«ãªãã·ãšãã«ãã¹ããšãŒããïŒ
âã¢ã¯ãªãã€ã«ãªãã·ãããã«âïŒâãã¹ããšãŒ
ããªã©ïŒã¡ã¿ã¯ãªãã€ã«ãªãã·ã¢ã«ãã«ãã¹ããš
ãŒããäŸãã°ã¡ã¿ã¯ãªãã€ã«ãªãã·ãšãã«ãã¹ã
ãšãŒããïŒâã¡ã¿ã¯ãªãã€ã«ãªãã·ãããã«âïŒ
âãã¹ããšãŒããªã©ïŒãªã©ãæãããããããã
ã®é žã¯ã¢ã«ã«ãªéå±ïŒäŸãã°ãNaïŒïŒ«ãªã©ïŒãŸ
ãã¯ã¢ã³ã¢ããŠã ã€ãªã³ã®å¡©ã§ãã€ãŠããããã
ãã«ãã®ä»ã®ã³ã¢ãããŒãšããŠã¯ãç±³åœç¹èš±ç¬¬
3459790å·ãå第3438708å·ãå第3554987å·ãå
第4215195å·ãå第4247673å·ãç¹éæ57â205735
å·å ¬å ±æ现æžçã«èšèŒãããŠããæ¶æ©æ§ã¢ãããŒ
ãçšããããšãã§ããããã®ãããªæ¶æ©æ§ã¢ãã
ãŒã®äŸãšããŠã¯ãå ·äœçã«ã¯ïŒ®âïŒïŒâã¢ã»ãã¢
ã»ããã·ãšãã«ïŒã¢ã¯ãªã«ã¢ãããâïœïŒâïŒïŒ
âã¢ã»ãã¢ã»ããã·ãšããã·ïŒãšãã«ïœã¢ã¯ãªã«
ã¢ããçãæããããšãã§ããã ãããã®ã³ã¢ãããŒã®äžã§ãã³ã¢ãããŒã®èŠªæ°Ž
æ§ã芪油æ§ãŸãã¯ã³ã¢ãããŒã®å ±éåæ§ããã³ç
æããããªããŒã«ãã©ãŒã®çºè²æ§ãçæè²çŽ ã®è²
調ãªã©ããã奜ãŸããçšããããã³ã¢ãããŒã«
ã¯ãã¢ã¯ãªã«é žãšã¹ãã«ãã¡ã¿ã¯ãªã«é žãšã¹ã
ã«ããã¬ã€ã³é žãšã¹ãã«ãã¢ã¯ãªã«ã¢ãããã¡ã¿
ã¯ãªã«ã¢ããé¡ãå«ãŸããã ãããã®ã³ã¢ãããŒã¯ãïŒçš®ä»¥äžã䜵çšããŠã
ãããïŒçš®ä»¥äžã䜵çšããå Žåã®çµã¿åããšããŠ
ã¯ãäŸãã°ãïœâããã«ã¢ã¯ãªã¬ãŒããšã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒããã¹ãã¬ã³ãšïŒ®âïœïŒâïŒïŒâã¢ã»ã
ã¢ã»ããã·ãšããã·ïŒãšãã«ïœã¢ã¯ãªã«ã¢ããã
tertâããã«ã¢ã¯ãªã¬ãŒããšã¡ãã«ã¢ã¯ãªã¬ãŒã
ãªã©ãæããããã æ¬çºæã«ä¿ãããªããŒã«ãã©ãŒã¯ãããããã³
ã¢ãããŒã§ããå Žåã奜ãŸãããããã®å Žåã奜
ãŸããã¯ãäžè¬åŒïŒ»ïŒœã§ç€ºãããç¹°ãè¿ãåäœ
ãééã§å šäœã®40ã70ïŒ å«ãå Žåãç¹ã«ã¯ãäžè¬
åŒïŒ»ïŒœã§ç€ºãããç¹°è¿ãåäœãšã³ã¢ãããŒãšã®
æ¯ã¯ããããééã§ïŒïŒïŒã§ããå Žåã奜ãŸã
ãã æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã¯ä¹³åéå
æ³ã§äœã€ãŠãããããããã¯åéäœã«ãã©ãŒã®é
åã§åŸãã芪油æ§ããªããŒã«ãã©ãŒãææ©æº¶åªäž
ã«æº¶ããããã®ããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹
ã®åœ¢ã§åæ£ããŠäœã€ãŠããããä¹³åéåæ³ã«ã€ã
ãŠã¯ç±³åœç¹èš±ç¬¬4080211å·ãå第3370952å·ã«ããŸ
ã芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«
ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠã¯ç±³åœç¹
蚱第3451820å·ã«èšèŒãããŠããæ¹æ³ãçšããã
ãšãã§ããã ãããã®æ¹æ³ã¯ãã¢ããªããŒã®åœ¢æããã³ã³ã
ãªããŒã®åœ¢æã«ãå¿çšã§ããåŸè ã®å Žåãã³ã¢ã
ããŒã¯æ¶²äœã³ã¢ãããŒã§ãããšãããä¹³åéåã®
å Žåã«ã¯åžžæ ã§åºäœåéäœã®ããã®æº¶åªãšããŠã
äœçšããã æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã®ä¹³åéå
æ³ããã³æº¶æ¶²éåæ³ã«çšããããéåéå§å€ãšã
ãŠã¯ã氎溶æ§éåéå§å€ãšèŠªæ²¹æ§éåéå§å€ãçš
ããããã氎溶æ§éåéå§å€ãšããŠã¯ãäŸãã°é
ç¡«é žã«ãªãŠã ãéç¡«é žã¢ã³ã¢ããŠã ãéç¡«é žãã
ãªãŠã çã®éç¡«é žå¡©é¡ãïŒïŒ4â²âã¢ãŸãã¹âïŒâ
ã·ã¢ãåèé žãããªãŠã ãïŒïŒ2â²âã¢ãŸãã¹ïŒïŒ
âã¢ããžããããã³ïŒå¡©é žå¡©çã®æ°Žæº¶æ§ã¢ãŸåå
ç©ãéé žåæ°ŽçŽ ãçšããããšãã§ããããŸã溶液
éåæ³ã«çšãããã芪油æ§éåéå§å€ãšããŠã¯ã
äŸãã°ã¢ãŸãã¹ã€ãœããããããªã«ãïŒïŒ2â²âã¢
ãŸãã¹âïŒïŒïŒïŒâãžã¡ãã«ãã¬ããããªã«ïŒã
ïŒïŒ2â²âã¢ãŸãã¹ïŒïŒâã¡ããã·âïŒïŒïŒâãžã¡
ãã«ãã¬ããããªã«ïŒãïŒïŒ1â²âã¢ãŸãã¹ïŒã·ã¯
ããããµãã³âïŒâã«ã«ããããªã«ïŒçã®èŠªæ²¹æ§
ã¢ãŸååç©ããã³ãŸã€ã«ããŒãªãã·ããã©ãŠãªã«
ããŒãªãã·ãããžã€ãœãããã«ããŒãªãã·ãžã«ã«
ãããŒãããžâtertâããã«ããŒãªãã·ãçã®èŠª
æ²¹æ§ããŒãªãã·ããæããããšãã§ããã ä¹³åéåæ³ã«ãããŠçšããããä¹³åå€ãšããŠ
ã¯ãçé¢æŽ»æ§å€ãé«ååä¿è·ã³ãã€ãããã³å ±é
åä¹³åå€ãæãããããçé¢æŽ»æ§å€ãšããŠã¯ãåœ
該åéã«ãããŠå ¬ç¥ã®ã¢ããªã³æŽ»æ§å€ããããªã³
掻æ§å€ãã«ããªã³æŽ»æ§å€åã³äž¡æ§æŽ»æ§å€ãæãã
ãããã¢ããªã³æŽ»æ§å€ã®äŸãšããŠã¯ãç³ã±ã³é¡ã
ããã·ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ãã©ãŠãª
ã«ç¡«é žãããªãŠã ããžãªã¯ãã«ã¹ã«ãã³ãã¯é žã
ããªãŠã ããããªã³æŽ»æ§å€ã®ç¡«é žå¡©ãæããã
ãããããªã³æŽ»æ§å€ã®äŸãšããŠã¯ãããªãªãã·ãš
ãã¬ã³ããã«ããšãã«ãšãŒãã«ãããªãªãã·ãšã
ã¬ã³ã¹ãã¢ãªã³é žãšã¹ãã«ãããªãªãã·ãšãã¬ã³
ãœã«ãã¿ã³ã¢ãã©ãŠãªã«é žãšã¹ãã«ãããªãªãã·
ãšãã¬ã³âããªãªãã·ãããã¬ã³ãããã¯å ±éå
äœçãæããããããŸãã«ããªã³æŽ»æ§å€ã®äŸãšã
ãŠã¯ãã¢ã«ãã«ããªãžãŠã å¡©ã第ïŒã¢ãã³é¡çã
æããããããŸãäž¡æ§æŽ»æ§å€ã®äŸãšããŠã¯ããžã¡
ãã«ã¢ã«ãã«ãã¿ã€ã³é¡ãã¢ã«ãã«ã°ãªã·ã³é¡ç
ãæããããããŸãé«ååä¿è·ã³ãã€ããšããŠã¯
ããªããã«ã¢ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«ã
ãŒã¹çãæããããããããã®ä¿è·ã³ãã€ãã¯ã
åç¬ã§ä¹³åå€ãšããŠçšããŠãããããŸãä»ã®çé¢
掻æ§å€ãšçµã¿åããŠçšããŠãããããããã®æŽ»æ§
å€ã®çš®é¡ããã³ãã®äœçšã«ã€ããŠã¯ãBelgische
Chemische Industrieã28å·»ã16â20é ïŒ1963ïŒ
ã«èšèŒãããŠããã 溶液éåæ³çã«ãã€ãŠåæããã芪油æ§ããªã
ãŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹ã®åœ¢
ã§åæ£ããã«ã¯ããŸã芪油æ§ããªããŒã«ãã©ãŒã
ææ©æº¶åªäžã«æº¶ãããã®ã¡ãããããŒã©ãã³æ°Žæº¶
液äžã«åæ£å€ã®å©ãããããŠãè¶ é³æ³¢ãã³ãã€ã
ãã«çã«ããã©ããã¯ã¹ç¶ã«åæ£ããã芪油æ§ã
ãªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹
ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠã¯ç±³åœç¹èš±ç¬¬
3451820å·ã«èšèŒãããŠããã芪油æ§ããªããŒã«
ãã©ãŒã溶解ããææ©æº¶åªãšããŠã¯ããšã¹ãã«
é¡ãäŸãã°é ¢é žã¡ãã«ãé ¢é žãšãã«ãé ¢é žããã
ã«çãã¢ã«ã³ãŒã«é¡ãã±ãã³é¡ãããã²ã³åçå
æ°ŽçŽ ããšãŒãã«é¡çãçšããããšãã§ããããŸã
ãããã®ææ©æº¶åªã¯ãåç¬ã§åã¯ïŒçš®ä»¥äžãçµã¿
åããŠçšããããšãã§ããã 次ã«æ¬çºæã®ããªããŒã«ãã©ãŒã®åæã«ã€ããŠ
以äžã«å ·äœçã«ç€ºããæ¬çºæã¯ããã«éå®ãããª
ãã ããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã®è£œé 補é äŸ (1) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³
ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³ïŒäŸç€ºå
åç©(3)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®èŠªæ²¹æ§ã
ãªããŒã«ãã©ãŒã®ã©ããã¯ã¹(A)ã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³ã¢
ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãšïœâã
ãã«ã¢ã¯ãªã¬ãŒã10ïœãšãžãªããµã³120mlã®æ··å
ç©ã80âã§çªçŽ æ°æµäžã§æªæãããžãªããµã³ïŒml
ã«æº¶è§£ããã¢ãŸãã¹ã€ãœããããããªã«0.36ïœã
å ããã®ã¡ãïŒæéåå¿ãããæ°ŽïŒäžã«ãžãªã
ãµã³æº¶æ¶²ã滎äžããæåºããåºäœãå¥ããæ°Žã§
æŽæµåŸã也ç¥ã14.8ïœïŒ74ïŒ ïŒã®èŠªæ²¹æ§ããªããŒ
ã«ãã©ãŒãåŸãããã®èŠªæ²¹æ§ããªããŒã«ãã©ãŒã®
å ±éåäœçµæã¯å çŽ åæïŒçªçŽ åæïŒã«ããã«ã
ã©ãŒåéäœå«æç54.1ïŒ ã§ãã€ãã äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒã10ïœã¥ã€é ¢é žãš
ãã«30mlã«æº¶ããããã®æº¶æ¶²ã«ã©ãŠãªã«ç¡«é žãã
ãªãŠã ã®10ééïŒ æ°Žæº¶æ¶²ïŒmlãšãŒã©ãã³ïŒééïŒ
氎溶液100mlã®æ··å液ãå ãè¶ é³æ³¢åæ£ãè¡ã€ãã
ãã®åŸæžå§èžçã«ãŠé ¢é žãšãã«ãé€å»ãããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹(A)ãåŸãã 補é äŸ (2) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹
ã«ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³
ïŒäŸç€ºååç©(10)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®
芪油æ§ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(B)ã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«
ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãš
ïœâããã«ã¢ã¯ãªã¬ãŒã10ïœãšãžãªããµã³120ml
ã®æ··åç©ã80âã§çªçŽ æ°æµäžã§æªæãããžãªããµ
ã³ïŒmlã«æº¶è§£ããã¢ãŸãã¹ã€ãœããããããªã«
0.36ïœãå ããã®ã¡ãïŒæéåå¿ãããæ°ŽïŒäž
ã«ãžãªããµã³æº¶æ¶²ã滎äžããæåºããåºäœãå¥
ããæ°Žã§æŽæµåŸã也ç¥ã15.2ïœïŒåç76ïŒ ïŒã®ã
ãªããŒã«ãã©ãŒãåŸãããã®ããªããŒã«ãã©ãŒã®
å ±éåçµæã¯å çŽ åæïŒçªçŽ åæïŒã«ããã«ãã©
ãŒåéäœå«æç52.7ïŒ ã§ãã€ãã åŸãããããªããŒã«ãã©ãŒããäžèšåæäŸ(1)ãš
åãæ¹æ³ã§ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(B)ãåŸ
ãã 補é äŸ(3)ã補é äŸ(17) äžèšç¬¬ïŒè¡šã«èšèŒãããåéäœã«ãã©ãŒããã³
ã³ã¢ãããŒãçšããŠåèšåæäŸ(1)ããã³(2)ã«æºã
ãŠæº¶æ¶²éåæ³ã«ããè¡šã«ç€ºãåŠãããªããŒã«ãã©
ãŒãåæããããããŠåŸãããããªããŒã«ãã©ãŒ
äžã®ã«ãã©ãŒã¢ãããŒå«æçãåè¡šã«ééïŒ ã§ç€º
ããã
ã«åºãšããŠã¯çœ®æåºãæããããšãã«åºãŸãã¯çœ®
æåºãæããªãããšãã«åºãããããããšãã«åº
ã眮æåºãæããå Žåã«ã¯å¥œãŸããã¯æ¬¡ã®äžè¬åŒ
ã§è¡šããããšãã§ããã äžè¬åŒïŒ»ïŒœ åŒäžãã¯ããã²ã³ååïŒäŸãã°å¡©çŽ ååãè
çŽ ååïŒãŸãã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åºã
è¡šãããã¢ã«ãã«åºãšããŠã¯äŸãã°ã¡ãã«åºããš
ãã«åºããããã«åºãããã«åºãããã眮æåºã
æããŠããŠãããã眮æåºãšããŠã¯ãå¡©çŽ ååã
ããçŽ ååçã®ããã²ã³ååãã¢ã«ãã«ã¹ã«ãã
ã«åºããã³ã¢ãªãŒã«ã¹ã«ããã«åºçãããã眮æ
åºãšããŠå¥œãŸããã¯ããã²ã³ååã§ãããã®ã
ãã«å¥œãŸããã¯ã¡ãã«åºã§ããããŸãã¯é»ååž
åŒæ§ã®çœ®æåºãè¡šããããé»ååžåŒæ§ã®çœ®æåºãš
ã¯Hammettãã«ãã€ãŠå®çŸ©ãããÎŽå€ãããã¯
Swainããã³Luptonãã«ãã€ãŠå°ãããå€ã
é¶ããã倧ãªã眮æåºãšããŠå®çŸ©ããããå ·äœç
ãªé»ååžåŒæ§ã®çœ®æåºãšããŠã¯äŸãã°ããã²ã³å
åãããã²ã³åã¢ã«ãã«ãã«ã«ããã·ã«ãã¹ã«
ããããããã·ã¢ããã¢ã«ãã«ã¹ã«ããã«ãã¢ã«
ãã«ã¹ã«ãã¢ã¢ã€ã«ãã¢ã»ãã«ãã¢ã«ã³ãã·ãã«
ã«ããã«çã®åºããããããããããã«J.Med.
Chem.Vol 16ïŒ1207é ïŒ1973ïŒãJ.Med.Chem.
Vol 20ïŒ304é ïŒ1977ïŒã«èšèŒãããŠããåºçã
å«ããããšãåºæ¥ããã奜ãŸããã¯å¡©çŽ ååãã
ãçŽ ååçã®ããã²ã³ååãŸãã¯ãžã¡ãã«ã¹ã«ã
ã¢ã¢ã€ã«çã®ã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«ã§ãããã
ãã«å¥œãŸããã¯å¡©çŽ ååã§ããã ïœã¯ïŒãïŒã®æŽæ°ãè¡šãããïœãïŒä»¥äžã®ãšã
ïŒã€ä»¥äžããã¯åäžã§ãç°ãªã€ãŠããŠããã
ãã奜ãŸããã¯ïœïŒïŒã§ããããïŒäœã«çµåã
ãŠãããã®ã§ããããŸãArãè¡šããè€çŽ ç°åºãš
ããŠã¯ã眮æåºãæããŠãããïŒå¡ãŸãã¯ïŒå¡ã®
è€çŽ ç°åºãçž®åè€çŽ ç°åºçãããã該è€çŽ ç°ã圢
æããååã®ãã¡å°ãªããšãïŒã€ã¯é žçŽ ååãçª
çŽ ååãŸãã¯ã€ãªãŠååããéžã°ãããã®ã§ãè€
çŽ ç°åºã®äŸãšããŠã¯ãããªã¢ãŸãŒã«ããã¢ãŸãŒ
ã«ããã³ãºãã¢ãŸãŒã«ããã©ã³ãã€ãããŸãŒã«ã
ãªããµãŸãŒã«ããã³ãºãªããµãŸãŒã«ãããªããž
ã³ãããã«ãžã³ãããªãžã³çãæããããšãã§ã
ãããããŠãããè€çŽ ç°åºã®çœ®æåºãšããŠã¯ãäŸ
ãã°ççŽ ååæ°ïŒã10ã®çŽéãªããã¯åå²ç¶ã®ã¢
ã«ãã«åºïŒäŸãã°ã¡ãã«åºãïœâããã«åºãïœâ
ãªã¯ãã«åºïŒãç°ç¶ã¢ã«ãã«åºïŒäŸãã°ã·ã¯ãã
ã³ãã«åºãã·ã¯ãããã·ã«åºïŒã¢ã©ã«ãã«åºïŒäŸ
ãã°ãã³ãžã«åºïŒãã¢ãªãŒã«åºïŒäŸãã°ããšãã«
åºãããªã«åºïŒãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·
åºããšããã·åºïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒäŸ
ãã°ã¡ããã·ã«ã«ããã«åºïŒãã¢ãªãŒã«ãªãã·åº
ïŒäŸãã°ããšããã·åºïŒãã¢ãªãŒã«ãªãã·ã«ã«ãã
ã«åºïŒäŸãã°ããšããã·ã«ã«ããã«åºïŒãã¢ã©ã«
ãã«ãªãã·ã«ã«ããã«åºïŒäŸãã°ãã³ãžã«ãªãã·
ã«ã«ããã«åºïŒãã¢ã«ãã«ããªåºïŒäŸãã°ã¡ãã«
ããªåºããšãã«ããªåºïŒãã«ã«ããã·ã«åºãã¢ã·
ã«ã¢ããåºïŒäŸãã°ã¢ã»ãã«ã¢ããåºããã³ãŸã€
ã«ã¢ããåºïŒããžã¢ã·ã«ã¢ããåºïŒäŸãã°ãžã¢ã»
ãã«ã¢ããåºããžãã³ãŸã€ã«ã¢ããåºïŒãâã¢
ã«ãã«ã¢ã·ã«ã¢ããåºïŒäŸãã°ïŒ®âã¡ãã«ã¢ã»ã
ã«ã¢ããåºïŒãâã¢ãªãŒã«ã¢ã·ã«ã¢ããåºïŒäŸ
ãã°ïŒ®âããšãã«ã¢ã»ãã«ã¢ããåºïŒããŠã¬ã€ã
åºïŒäŸãã°ãŠã¬ã€ããã¡ãã«ãŠã¬ã€ãåºïŒãããª
ãŠã¬ã€ãåºïŒäŸãã°ããªãŠã¬ã€ããã¡ãã«ããªãŠ
ã¬ã€ãåºïŒãã¢ã«ãã«ãªãã·ã«ã«ããã«ã¢ããåº
ïŒäŸãã°ã¡ããã·ã«ã«ããã«ã¢ããåºïŒãã¢ãªãŒã«
ãªãã·ã«ã«ããã«ã¢ããåºïŒäŸãã°ããšããã·ã«
ã«ããã«ã¢ããåºïŒãã¢ããåºãã¢ããªãåºãã¢
ã«ãã«ã¢ããåºïŒäŸãã°ã¡ãã«ã¢ããåºïŒãã·ã¯
ãã¢ããåºïŒäŸãã°ã·ã¯ãããã·ã«ã¢ããåºïŒã
ã¢ã«ãã«ã«ã«ããã«åºïŒäŸãã°ã¢ã»ãã«åºïŒãã¢
ãªãŒã«ã«ã«ããã«åºïŒäŸãã°ãã³ãŸã€ã«åºïŒãã¹
ã«ãã³ã¢ããåºïŒäŸãã°ã¡ãã«ã¹ã«ãã³ã¢ãã
åºãã¹ã«ãã³ã¢ããåºïŒãã«ã«ãã¢ã€ã«åºïŒäŸã
ã°ã«ã«ãã¢ã€ã«åºãã¡ãã«ã«ã«ãã¢ã€ã«åºïŒãã¹
ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ã¹ã«ãã¢ã¢ã€ã«åºãã¡ã
ã«ã¹ã«ãã¢ã¢ã€ã«åºïŒãã·ã¢ãåºãã¢ã·ã«ãªãã·
åºïŒäŸãã°ã¢ã»ãã«ãªãã·åºããã³ãŸã€ã«ãªãã·
åºïŒãã¹ã«ããã«åºãã¹ã«ããã«ãªãã·åºãã¢ã«
ãã«ã¹ã«ããã«åºïŒäŸãã°ã¡ãã«ã¹ã«ããã«åºïŒã
ã¢ãªãŒã«ã¹ã«ããã«åºïŒäŸãã°ããšãã«ã¹ã«ãã
ã«åºïŒãã¹ã«ãåºããããåºãããããã·åºãã
ãã²ã³ååïŒäŸãã°å¡©çŽ ååïŒãŸãã¯è€çŽ ç°åº
ïŒäŸãã°ãã¢ãŸãŒã«åºããªããµãŸãŒã«åºïŒçãæ
ããããšãã§ããã 次ã«æ¬çºæã«ä¿ããããŒã³ã¿ã«ãã©ãŒåéäœã®
å ·äœäŸãèšèŒãããæ¬çºæã¯ãããã®ã¿ã«éå®ã
ãããã®ã§ã¯ãªãã äžèšäŸç€ºããæ¬çºæã«ä¿ããããªããŒããŒã³ã¿
ã«ãã©ãŒã¢ãããŒã¯ãã¢ã¯ãªã«é žãŸãã¯Î±â眮æ
ã¢ã¯ãªã«é žã®é žãã©ã€ãäŸãã°ã¢ã¯ãªã«é žã¯ãã©
ã€ããŸãã¯ã¡ã¿ã¯ãªã«é žã¯ãã©ã€ãçãšïŒâïŒïŒ
âã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ããïŒâïŒâãã©ãŸ
ãªã³âïŒâãªã³ãŸãã¯ïŒâïŒÏâã¢ããã¹ã«ãã³
ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³ãšãåå¿ã
ããããšã«ãã€ãŠåæããããšãã§ããã äžèšã®ïŒâïŒïŒâã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ã
ãïŒâïŒâãã©ãŸãªã³âïŒâãªã³ã¯ïŒâã¢ããâ
ïŒâãã©ãŸãªã³âïŒâãªã³ãšïœâããããã³ãŒã³
ã¹ã«ãã³é žã¯ãã©ã€ããåå¿ãããŠãéå ããã
ãšã«ããåŸãããããïœäœã®ã¢ããåºãã¢ããçµ
å圢æã«ãã€ãŠä¿è·ããïœâã¢ãããã³ãŒã³ã¹ã«
ãã³é žã¯ãã©ã€ããšåå¿åŸãå æ°Žå解ããããšã«
ãã€ãŠãåŸãããšãã§ããã ïŒâïŒÏâã¢ããã¹ã«ãã³ã¢ããïŒâïŒâãã©ãŸ
ãªã³âïŒâãªã³ã¯ïŒâã¢ããâïŒâãã©ãŸãªã³â
ïŒâãªã³ãšã¢ããåºãã¢ããçµå圢æã«ããä¿è·
ããÏâã¢ããã¹ã«ãã³é žã¯ãã©ã€ããšåå¿åŸå
æ°Žå解ããããšã«ããåŸãããšãã§ããã äžèšïŒâã¢ããâïŒâãã©ãŸãªã³âïŒâãªã³ã¯
ç±³åœç¹èš±ç¬¬2376380å·ãè±åœç¹èš±ç¬¬1069563å·ãå
第1166035å·ãå第1190914å·ãå第1269355å·ã«
èšèŒãããŠããåŠããè³éŠæããã©ãžã³ãβâã¢
ããâβâãšããã·ããããªã³é žã§ç°ç¶äœãšãªã
ããJ.Amer.Chem.Soc.66å·»ã1851é ã1855é ã
ïŒ1944幎ïŒã«èšèŒã®è³éŠæããã©ãžã³ãšÎ²âãšã
ãã·âβâã€ããããããªã³é žãšã¹ãã«ãšã®åå¿
ã«ããåæããããšãã§ããã以äžã«æ¬çºæã«ä¿
ããã«ãã©ãŒã¢ãããŒã®ä»£è¡šçãªåæäŸãå ·äœç
ã«èšèŒããã åæäŸ(1) ïŒååç©äŸ(3)ã®åæïŒ ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ããïŒâïŒâãã©
ãŸãªã³âïŒâãªã³20ïœïŒ0.046ã¢ã«ïŒãããã©ã
ãããã©ã³200mlã«æº¶è§£ããããªãžã³11.5ml
ïŒ0.14ã¢ã«ïŒãšããããã³ãŒã³20mlãå ããæ°·å·
äžã§ã¡ã¿ã¯ãªã«é žã¯ãã©ã€ã11.0ïœïŒ0.105ã¢ã«ïŒ
ããã€ãã滎äžãã滎äžåŸïŒæéæªæããã®ã¡æ°Ž
200mlãå ããŠé ¢é žãšãã«ã§æœåºããã æœåºæ¶²ãç¡æ°Žç¡«é žãããªãŠã ã§ä¹Ÿç¥åŸãæžå§äž
25ã35âã§é ¢é žãšãã«ãçå»åŸãæ®çæ²¹ç¶ç©ã«ãš
ã¿ããŒã«70mlãå ãæ°·å·äžã§æªæããªããæ°Ž20ml
ã«æ°Žé žåãããªãŠã 6.5ïœïŒ0.103ã¢ã«ïŒã溶解ã
ã氎溶液ã滎äžããŠ30åéæªæããã®ã¡ãé ¢é žã§
äžåããæåºããçµæ¶ãå¥ããããšã¿ããŒã«ã
ãåçµæ¶ããäžèšç®çç©12.3ïœïŒåç53ïŒ ïŒãåŸ
ããèç¹235âïŒå解ïŒãFDâMasãNMRãIR
çã®æ©åšåæã§åå®ããã åæäŸ(2) ïŒååç©äŸ(10)ã®åæïŒ ïŒâïŒïŒïŒïŒâãžã¯ããããšãã«ïŒâïŒâïŒïŒâ
ã¢ãããã³ãŒã³ã¹ã«ãã³ã¢ããïŒâïŒâãã©ãŸãª
ã³âïŒâãªã³20ïœïŒ0.05ã¢ã«ïŒãããã©ãããã
ã©ã³200mlã«æº¶è§£ããããªãžã³12mlïŒ0.15ã¢ã«ïŒ
ãšããããã³ãŒã³20mlãå ããæ°·å·äžã§ã¡ã¿ã¯ãª
ã«é žã¯ãã©ã€ã120ïœïŒ0.115ã¢ã«ïŒããã€ãã滎
äžãã滎äžçµäºåŸïŒæéæªæããã®ã¡ãæ°Ž200ml
ãå ããŠé ¢é žãšãã«ã§æœåºãããæœåºæ¶²ãç¡æ°Žç¡«
é žãããªãŠã ã§ä¹Ÿç¥åŸãæžå§äž25ã35âã§é ¢é žãš
ãã«ãçå»ããæ®çç©ã«ãšã¿ããŒã«70mlãå ãã
æ°·å·äžã§æªæããªããæ°Ž20mlã«æ°Žé žåãããªãŠã
6.5ïœïŒ0.103ã¢ã«ïŒã溶解ãã氎溶液ã滎äžããŠ
30åéæªæããã®ã¡é ¢é žã§äžåããæåºããçµæ¶
ãå¥ããããšã¿ããŒã«ããåçµæ¶ããäžèšç®ç
ç©13.7ïœãåŸããåç59ïŒ ãèç¹173âãFDâ
MasãNMRãIRçã®æ©åšåæã«ããåå®ããã æ¬çºæã«ä¿ãããªããŒã«ãã©ãŒã¯ãäžè¬åŒ
ã§è¡šããããç¹°è¿ãåäœã®ã¿ãããªããã
ãããã¢ããªããŒã§ãã€ãŠãããããŸããä»ã®å ±
éåãåŸãã³ã¢ãããŒãšã®ããããã³ããªããŒã§
ãã€ãŠãããããæ¬çºæã«ãããŠã¯å¥œãŸããã¯ã³
ããªããŒåãããããªããŒã«ãã©ãŒã§ããã å ±éåãããã³ã¢ãããŒã®äŸã«ã¯ãã¢ã¯ãªã«é ž
ãšã¹ãã«ãã¡ã¿ã¯ãªã«é žãšã¹ãã«ãã¯ããã³é žãš
ã¹ãã«ãããã«ãšã¹ãã«ããã¬ã€ã³é žãžãšã¹ã
ã«ãããã«é žãžãšã¹ãã«ãã€ã¿ã³ã³é žãžãšã¹ã
ã«ããªã¬ãã€ã³é¡ãã¹ãã¬ã³é¡çãæããããã ãããã®ã³ã¢ãããŒã«ã€ããŠæŽã«å ·äœçã«ç€ºã
ãšãã¢ã¯ãªã«é žãšã¹ãã«ãšããŠã¯ãã¡ãã«ã¢ã¯ãª
ã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒããïœâãããã«ã¢ã¯
ãªã¬ãŒããã€ãœãããã«ã¢ã¯ãªã¬ãŒããïœâãã
ã«ã¢ã¯ãªã¬ãŒããã€ãœããã«ã¢ã¯ãªã¬ãŒããsec
âããã«ã¢ã¯ãªã¬ãŒããã¢ãã«ã¢ã¯ãªã¬ãŒããã
ãã·ã«ã¢ã¯ãªã¬ãŒããïŒâãšãã«ããã·ã«ã¢ã¯ãª
ã¬ãŒãããªã¯ãã«ã¢ã¯ãªã¬ãŒããtertâãªã¯ãã«
ã¢ã¯ãªã¬ãŒããïŒâã¯ãããšãã«ã¢ã¯ãªã¬ãŒãã
ïŒâããã¢ãšãã«ã¢ã¯ãªã¬ãŒããïŒâã¯ãããã
ã«ã¢ã¯ãªã¬ãŒããã·ã¢ããšãã«ã¢ã¯ãªã¬ãŒããïŒ
âã¢ã»ããã·ãšãã«ã¢ã¯ãªã¬ãŒãããžã¡ãã«ã¢ã
ããšãã«ã¢ã¯ãªã¬ãŒãããã³ãžã«ã¢ã¯ãªã¬ãŒãã
ã¡ããã·ãã³ãžã«ã¢ã¯ãªã¬ãŒããïŒâã¯ããã·ã¯
ãããã·ã«ã¢ã¯ãªã¬ãŒããã·ã¯ãããã·ã«ã¢ã¯ãª
ã¬ãŒãããã«ããªã«ã¢ã¯ãªã¬ãŒããããã©ããã
ãã«ããªã«ã¢ã¯ãªã¬ãŒããããšãã«ã¢ã¯ãªã¬ãŒ
ããïŒâããããã·ãã³ãã«ã¢ã¯ãªã¬ãŒããïŒïŒ
ïŒâãžã¡ãã«âïŒâããããã·ãããã«ã¢ã¯ãªã¬
ãŒããïŒâã¡ããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâã¡
ããã·ããã«ã¢ã¯ãªã¬ãŒããïŒâãšããã·ãšãã«
ã¢ã¯ãªã¬ãŒããïŒâisoâããããã·ã¢ã¯ãªã¬ãŒ
ããïŒâãããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâïŒïŒ
âã¡ããã·ãšããã·ïŒãšãã«ã¢ã¯ãªã¬ãŒããïŒâ
ïŒïŒâãããã·ãšããã·ïŒãšãã«ã¢ã¯ãªã¬ãŒãã
Ïâã¡ããã·ããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã¯ãªã¬ãŒ
ãïŒä»å ã¢ã«æ°ïœïŒïŒïŒãïŒâããã¢âïŒâã¡ã
ãã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒïŒïŒâãžã¯ããâïŒ
âãšããã·ãšãã«ã¢ã¯ãªã¬ãŒãçãæããããã ã¡ã¿ã¯ãªã«é žãšã¹ãã«ã®äŸãšããŠã¯ãã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒãããšãã«ã¡ã¿ã¯ãªã¬ãŒããïœâãã
ãã«ã¡ã¿ã¯ãªã¬ãŒããã€ãœãããã«ã¡ã¿ã¯ãªã¬ãŒ
ããïœâããã«ã¡ã¿ã¯ãªã¬ãŒããã€ãœããã«ã¡ã¿
ã¯ãªã¬ãŒããsecâããã«ã¡ã¿ã¯ãªã¬ãŒããã¢ã
ã«ã¡ã¿ã¯ãªã¬ãŒããããã·ã«ã¡ã¿ã¯ãªã¬ãŒããã·
ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒãããã³ãžã«ã¡ã¿ã¯ãª
ã¬ãŒããã¯ãããã³ãžã«ã¡ã¿ã¯ãªã¬ãŒãããªã¯ã
ã«ã¡ã¿ã¯ãªã¬ãŒããã¹ã«ããããã«ã¡ã¿ã¯ãªã¬ãŒ
ããâãšãã«ââããšãã«ã¢ãããšãã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâïŒïŒâããšãã«ãããã«ãªãã·ïŒ
ãšãã«ã¡ã¿ã¯ãªã¬ãŒãããžã¡ãã«ã¢ããããšãã
ã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒãããã«ããªã«ã¡ã¿ã¯ãªã¬
ãŒããããã©ããããã«ããªã«ã¡ã¿ã¯ãªã¬ãŒãã
ããšãã«ã¡ã¿ã¯ãªã¬ãŒããã¯ã¬ãžã«ã¡ã¿ã¯ãªã¬ãŒ
ãããããã«ã¡ã¿ã¯ãªã¬ãŒããïŒâããããã·ãš
ãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâããããã·ããã«ã¡ã¿
ã¯ãªã¬ãŒããããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ã¿ã¯
ãªã¬ãŒãããžãããã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ã¿ã¯ãª
ã¬ãŒããïŒâã¡ããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒ
âã¡ããã·ããã«ã¡ã¿ã¯ãªã¬ãŒããïŒâã¢ã»ãã
ã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâã¢ã»ãã¢ã»ããã·
ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâãšããã·ãšãã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâisoâããããã·ãšãã«ã¡ã¿ã¯
ãªã¬ãŒããïŒâãããã·ãšãã«ã¡ã¿ã¯ãªã¬ãŒãã
ïŒâïŒïŒâã¡ããã·ãšããã·ïŒãšãã«ã¡ã¿ã¯ãªã¬
ãŒããïŒâïŒïŒâãšããã·ãšããã·ïŒãšãã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâïŒïŒâãããã·ãšããã·ïŒãšã
ã«ã¡ã¿ã¯ãªã¬ãŒããÏâã¡ããã·ããªãšãã¬ã³ã°
ãªã³ãŒã«ã¡ã¿ã¯ãªã¬ãŒãïŒä»å ã¢ã«æ°ïœïŒïŒïŒãª
ã©ãæããããšãã§ããã ããã«ãšã¹ãã«é¡ã®äŸãšããŠã¯ãããã«ã¢ã»ã
ãŒããããã«ããããªããŒããããã«ããã¬ãŒ
ããããã«ã€ãœããã¬ãŒããããã«ã«ãããšãŒ
ããããã«ã¯ããã¢ã»ããŒããããã«ã¡ããã·ã¢
ã»ããŒããããã«ããšãã«ã¢ã»ããŒããå®æ¯éŠé ž
ããã«ããµãªãã«é žããã«ãªã©ãæããããã ãŸããªã¬ãã€ã³é¡ã®äŸãšããŠã¯ããžã·ã¯ããã³
ã¿ãžãšã³ããšãã¬ã³ããããã¬ã³ãïŒâããã³ã
ïŒâãã³ãã³ãå¡©åããã«ãå¡©åãããªãã³ãã€
ãœãã¬ã³ãã¯ãããã¬ã³ããã¿ãžãšã³ãïŒïŒïŒâ
ãžã¡ãã«ãã¿ãžãšã³çãæããããšãã§ããã ã¹ãã¬ã³é¡ãšããŠã¯ãäŸãã°ãã¹ãã¬ã³ãã¡ã
ã«ã¹ãã¬ã³ããžã¡ãã«ã¹ãã¬ã³ãããªã¡ãã«ã¹ã
ã¬ã³ããšãã«ã¹ãã¬ã³ãã€ãœãããã«ã¹ãã¬ã³ã
ã¯ãã«ã¡ãã«ã¹ãã¬ã³ãã¡ããã·ã¹ãã¬ã³ãã¢ã»
ããã·ã¹ãã¬ã³ãã¯ãã«ã¹ãã¬ã³ããžã¯ãã«ã¹ã
ã¬ã³ãããã ã¹ãã¬ã³ãããã«å®æ¯éŠé žã¡ãã«ãš
ã¹ãã«ãªã©ãæããããã ã¯ããã³é žãšã¹ãã«ã®äŸãšããŠã¯ãã¯ããã³é ž
ããã«ãã¯ããã³é žããã·ã«ãªã©ãæããããã ãŸãã€ã¿ã³ã³é žãžãšã¹ãã«é¡ãšããŠã¯ãäŸã
ã°ãã€ã¿ã³ã³é žãžã¡ãã«ãã€ã¿ã³ã³é žãžãšãã«ã
ã€ã¿ã³ã³é žãžããã«ãªã©ãæããããã ãã¬ã€ã³é žãžãšã¹ãã«é¡ãšããŠã¯ãäŸãã°ãã
ã¬ã€ã³é žãžãšãã«ããã¬ã€ã³é žãžã¡ãã«ããã¬ã€
ã³é žãžããã«ãªã©ãæããããã ããã«é žãžãšã¹ãã«é¡ãšããŠã¯ãäŸãã°ããã
ã«é žãžãšãã«ãããã«é žãžã¡ãã«ãããã«é žãžã
ãã«ãªã©ãæããããã ãã®ä»ã®ã³ã¢ãããŒã®äŸãšããŠã¯ã次ã®ãã®ã
æããããã ã¢ã¯ãªã«ã¢ããé¡ãäŸãã°ã¢ã¯ãªã«ã¢ãããã¡
ãã«ã¢ã¯ãªã«ã¢ããããšãã«ã¢ã¯ãªã«ã¢ãããã
ããã«ã¢ã¯ãªã«ã¢ãããããã«ã¢ã¯ãªã«ã¢ããã
tertâããã«ã¢ã¯ãªã«ã¢ãããã·ã¯ãããã·ã«ã¢
ã¯ãªã«ã¢ããããã³ãžã«ã¢ã¯ãªã«ã¢ãããããã
ãã·ã¡ãã«ã¢ã¯ãªã«ã¢ãããã¡ããã·ãšãã«ã¢ã¯
ãªã«ã¢ããããžã¡ãã«ã¢ãããšãã«ã¢ã¯ãªã«ã¢ã
ããããšãã«ã¢ã¯ãªã«ã¢ããããžã¡ãã«ã¢ã¯ãªã«
ã¢ããããžãšãã«ã¢ã¯ãªã«ã¢ãããβâã·ã¢ããš
ãã«ã¢ã¯ãªã«ã¢ãããªã©ïŒã¢ãªã«ååç©ãäŸãã°
é ¢é žã¢ãªã«ãã«ããã³é žã¢ãªã«ãã©ãŠãªã³é žã¢ãª
ã«ãå®æ¯éŠé žã¢ãªã«ãªã©ïŒããã«ãšãŒãã«é¡ãäŸ
ãã°ã¡ãã«ããã«ãšãŒãã«ãããã«ããã«ãšãŒã
ã«ãããã·ã«ããã«ãšãŒãã«ãã¡ããã·ãšãã«ã
ãã«ãšãŒãã«ããžã¡ãã«ã¢ãããšãã«ããã«ãšãŒ
ãã«ãªã©ïŒ ããã«ã±ãã³é¡ãäŸãã°ãã¡ãã«ããã«ã±ã
ã³ãããšãã«ããã«ã±ãã³ãã¡ããã·ãšãã«ãã
ã«ã±ãã³ãªã©ïŒ ããã«ç°ç¯ç°ååç©ãäŸãã°ãããã«ããªãž
ã³ãâããã«ã€ãããŸãŒã«ãâããã«ãªããµ
ãŸãªãã³ãâããã«ããªã¢ãŸãŒã«ãâããã«
ãããªãã³ãªã©ïŒ ã°ãªã·ãžã«ãšã¹ãã«é¡ãäŸãã°ãã°ãªã·ãžã«ã¢
ã¯ãªã¬ãŒããã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒããªã©ïŒ äžé£œåãããªã«é¡ãäŸãã°ãã¢ã¯ãªããããª
ã«ãã¡ã¿ã¯ãªããããªã«ãªã©ïŒ å€å®èœæ§ã¢ãããŒãäŸãã°ããžããã«ãã³ãŒ
ã³ãã¡ãã¬ã³ãã¹ã¢ã¯ãªã«ã¢ããããšãã¬ã³ã°ãª
ã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããªã©ã æŽã«ãã¢ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žãã€ã¿ã³ã³
é žããã¬ã€ã³é žãã€ã¿ã³ã³é žã¢ãã¢ã«ãã«ãäŸã
ã°ãã€ã¿ã³ã³é žã¢ãã¡ãã«ãã€ã¿ã³ã³é žã¢ããšã
ã«ãã€ã¿ã³ã³é žã¢ãããã«ãªã©ïŒãã¬ã€ã³é žã¢ã
ã¢ã«ãã«ãäŸãã°ããã¬ã€ã³é žã¢ãã¡ãã«ããã¬
ã€ã³é žã¢ããšãã«ããã¬ã€ã³é žã¢ãããã«ãªã©ïŒ
ã·ãã©ã³ã³é žãã¹ãã¬ã³ã¹ã«ãã³é žãããã«ãã³
ãžã«ã¹ã«ãã³é žãããã«ã¹ã«ãã³é žãã¢ã¯ãªãã€
ã«ãªãã·ã¢ã«ãã«ã¹ã«ãã³é žãäŸãã°ãã¢ã¯ãªã
ã€ã«ãªãã·ã¡ãã«ã¹ã«ãã³é žãã¢ã¯ãªãã€ã«ãªã
ã·ãšãã«ã¹ã«ãã³é žãã¢ã¯ãªãã€ã«ãªãã·ããã
ã«ã¹ã«ãã³é žãªã©ïŒã¡ã¿ã¯ãªãã€ã«ãªãã·ã¢ã«ã
ã«ã¹ã«ãã³é žãäŸãã°ã¡ã¿ã¯ãªãã€ã«ãªãã·ã¡ã
ã«ã¹ã«ãã³é žãã¡ã¿ã¯ãªãã€ã«ãªãã·ãšãã«ã¹ã«
ãã³é žãã¡ã¿ã¯ãªãã€ã«ãªãã·ãããã«ã¹ã«ãã³
é žãªã©ïŒã¢ã¯ãªã«ã¢ããã¢ã«ãã«ã¹ã«ãã³é žãäŸ
ãã°ïŒâã¢ã¯ãªã«ã¢ããâïŒâã¡ãã«ãšã¿ã³ã¹ã«
ãã³é žãïŒâã¢ã¯ãªã«ã¢ããâïŒâã¡ãã«ããã
ã³ã¹ã«ãã³é žãïŒâã¢ã¯ãªã«ã¢ããâïŒâã¡ãã«
ãã¿ã³ã¹ã«ãã³é žãªã©ïŒã¡ã¿ã¯ãªã«ã¢ããã¢ã«ã
ã«ã¹ã«ãã³é žãäŸãã°ïŒâã¡ã¿ã¯ãªã«ã¢ããâïŒ
âã¡ãã«ãšã¿ã³ã¹ã«ãã³é žãïŒâã¡ã¿ã¯ãªã«ã¢ã
ãâïŒâã¡ãã«ãããã³ã¹ã«ãã³é žãïŒâã¡ã¿ã¯
ãªã«ã¢ããâïŒâã¡ãã«ãã¿ã³ã¹ã«ãã³é žãªã©ïŒ
ã¢ã¯ãªãã€ã«ãªãã·ã¢ã«ãã«ãã¹ããšãŒããäŸã
ã°ãã¢ã¯ãªãã€ã«ãªãã·ãšãã«ãã¹ããšãŒããïŒ
âã¢ã¯ãªãã€ã«ãªãã·ãããã«âïŒâãã¹ããšãŒ
ããªã©ïŒã¡ã¿ã¯ãªãã€ã«ãªãã·ã¢ã«ãã«ãã¹ããš
ãŒããäŸãã°ã¡ã¿ã¯ãªãã€ã«ãªãã·ãšãã«ãã¹ã
ãšãŒããïŒâã¡ã¿ã¯ãªãã€ã«ãªãã·ãããã«âïŒ
âãã¹ããšãŒããªã©ïŒãªã©ãæãããããããã
ã®é žã¯ã¢ã«ã«ãªéå±ïŒäŸãã°ãNaïŒïŒ«ãªã©ïŒãŸ
ãã¯ã¢ã³ã¢ããŠã ã€ãªã³ã®å¡©ã§ãã€ãŠããããã
ãã«ãã®ä»ã®ã³ã¢ãããŒãšããŠã¯ãç±³åœç¹èš±ç¬¬
3459790å·ãå第3438708å·ãå第3554987å·ãå
第4215195å·ãå第4247673å·ãç¹éæ57â205735
å·å ¬å ±æ现æžçã«èšèŒãããŠããæ¶æ©æ§ã¢ãããŒ
ãçšããããšãã§ããããã®ãããªæ¶æ©æ§ã¢ãã
ãŒã®äŸãšããŠã¯ãå ·äœçã«ã¯ïŒ®âïŒïŒâã¢ã»ãã¢
ã»ããã·ãšãã«ïŒã¢ã¯ãªã«ã¢ãããâïœïŒâïŒïŒ
âã¢ã»ãã¢ã»ããã·ãšããã·ïŒãšãã«ïœã¢ã¯ãªã«
ã¢ããçãæããããšãã§ããã ãããã®ã³ã¢ãããŒã®äžã§ãã³ã¢ãããŒã®èŠªæ°Ž
æ§ã芪油æ§ãŸãã¯ã³ã¢ãããŒã®å ±éåæ§ããã³ç
æããããªããŒã«ãã©ãŒã®çºè²æ§ãçæè²çŽ ã®è²
調ãªã©ããã奜ãŸããçšããããã³ã¢ãããŒã«
ã¯ãã¢ã¯ãªã«é žãšã¹ãã«ãã¡ã¿ã¯ãªã«é žãšã¹ã
ã«ããã¬ã€ã³é žãšã¹ãã«ãã¢ã¯ãªã«ã¢ãããã¡ã¿
ã¯ãªã«ã¢ããé¡ãå«ãŸããã ãããã®ã³ã¢ãããŒã¯ãïŒçš®ä»¥äžã䜵çšããŠã
ãããïŒçš®ä»¥äžã䜵çšããå Žåã®çµã¿åããšããŠ
ã¯ãäŸãã°ãïœâããã«ã¢ã¯ãªã¬ãŒããšã¡ãã«ã¡
ã¿ã¯ãªã¬ãŒããã¹ãã¬ã³ãšïŒ®âïœïŒâïŒïŒâã¢ã»ã
ã¢ã»ããã·ãšããã·ïŒãšãã«ïœã¢ã¯ãªã«ã¢ããã
tertâããã«ã¢ã¯ãªã¬ãŒããšã¡ãã«ã¢ã¯ãªã¬ãŒã
ãªã©ãæããããã æ¬çºæã«ä¿ãããªããŒã«ãã©ãŒã¯ãããããã³
ã¢ãããŒã§ããå Žåã奜ãŸãããããã®å Žåã奜
ãŸããã¯ãäžè¬åŒïŒ»ïŒœã§ç€ºãããç¹°ãè¿ãåäœ
ãééã§å šäœã®40ã70ïŒ å«ãå Žåãç¹ã«ã¯ãäžè¬
åŒïŒ»ïŒœã§ç€ºãããç¹°è¿ãåäœãšã³ã¢ãããŒãšã®
æ¯ã¯ããããééã§ïŒïŒïŒã§ããå Žåã奜ãŸã
ãã æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã¯ä¹³åéå
æ³ã§äœã€ãŠãããããããã¯åéäœã«ãã©ãŒã®é
åã§åŸãã芪油æ§ããªããŒã«ãã©ãŒãææ©æº¶åªäž
ã«æº¶ããããã®ããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹
ã®åœ¢ã§åæ£ããŠäœã€ãŠããããä¹³åéåæ³ã«ã€ã
ãŠã¯ç±³åœç¹èš±ç¬¬4080211å·ãå第3370952å·ã«ããŸ
ã芪油æ§ããªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«
ã©ããã¯ã¹ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠã¯ç±³åœç¹
蚱第3451820å·ã«èšèŒãããŠããæ¹æ³ãçšããã
ãšãã§ããã ãããã®æ¹æ³ã¯ãã¢ããªããŒã®åœ¢æããã³ã³ã
ãªããŒã®åœ¢æã«ãå¿çšã§ããåŸè ã®å Žåãã³ã¢ã
ããŒã¯æ¶²äœã³ã¢ãããŒã§ãããšãããä¹³åéåã®
å Žåã«ã¯åžžæ ã§åºäœåéäœã®ããã®æº¶åªãšããŠã
äœçšããã æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã®ä¹³åéå
æ³ããã³æº¶æ¶²éåæ³ã«çšããããéåéå§å€ãšã
ãŠã¯ã氎溶æ§éåéå§å€ãšèŠªæ²¹æ§éåéå§å€ãçš
ããããã氎溶æ§éåéå§å€ãšããŠã¯ãäŸãã°é
ç¡«é žã«ãªãŠã ãéç¡«é žã¢ã³ã¢ããŠã ãéç¡«é žãã
ãªãŠã çã®éç¡«é žå¡©é¡ãïŒïŒ4â²âã¢ãŸãã¹âïŒâ
ã·ã¢ãåèé žãããªãŠã ãïŒïŒ2â²âã¢ãŸãã¹ïŒïŒ
âã¢ããžããããã³ïŒå¡©é žå¡©çã®æ°Žæº¶æ§ã¢ãŸåå
ç©ãéé žåæ°ŽçŽ ãçšããããšãã§ããããŸã溶液
éåæ³ã«çšãããã芪油æ§éåéå§å€ãšããŠã¯ã
äŸãã°ã¢ãŸãã¹ã€ãœããããããªã«ãïŒïŒ2â²âã¢
ãŸãã¹âïŒïŒïŒïŒâãžã¡ãã«ãã¬ããããªã«ïŒã
ïŒïŒ2â²âã¢ãŸãã¹ïŒïŒâã¡ããã·âïŒïŒïŒâãžã¡
ãã«ãã¬ããããªã«ïŒãïŒïŒ1â²âã¢ãŸãã¹ïŒã·ã¯
ããããµãã³âïŒâã«ã«ããããªã«ïŒçã®èŠªæ²¹æ§
ã¢ãŸååç©ããã³ãŸã€ã«ããŒãªãã·ããã©ãŠãªã«
ããŒãªãã·ãããžã€ãœãããã«ããŒãªãã·ãžã«ã«
ãããŒãããžâtertâããã«ããŒãªãã·ãçã®èŠª
æ²¹æ§ããŒãªãã·ããæããããšãã§ããã ä¹³åéåæ³ã«ãããŠçšããããä¹³åå€ãšããŠ
ã¯ãçé¢æŽ»æ§å€ãé«ååä¿è·ã³ãã€ãããã³å ±é
åä¹³åå€ãæãããããçé¢æŽ»æ§å€ãšããŠã¯ãåœ
該åéã«ãããŠå ¬ç¥ã®ã¢ããªã³æŽ»æ§å€ããããªã³
掻æ§å€ãã«ããªã³æŽ»æ§å€åã³äž¡æ§æŽ»æ§å€ãæãã
ãããã¢ããªã³æŽ»æ§å€ã®äŸãšããŠã¯ãç³ã±ã³é¡ã
ããã·ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ãã©ãŠãª
ã«ç¡«é žãããªãŠã ããžãªã¯ãã«ã¹ã«ãã³ãã¯é žã
ããªãŠã ããããªã³æŽ»æ§å€ã®ç¡«é žå¡©ãæããã
ãããããªã³æŽ»æ§å€ã®äŸãšããŠã¯ãããªãªãã·ãš
ãã¬ã³ããã«ããšãã«ãšãŒãã«ãããªãªãã·ãšã
ã¬ã³ã¹ãã¢ãªã³é žãšã¹ãã«ãããªãªãã·ãšãã¬ã³
ãœã«ãã¿ã³ã¢ãã©ãŠãªã«é žãšã¹ãã«ãããªãªãã·
ãšãã¬ã³âããªãªãã·ãããã¬ã³ãããã¯å ±éå
äœçãæããããããŸãã«ããªã³æŽ»æ§å€ã®äŸãšã
ãŠã¯ãã¢ã«ãã«ããªãžãŠã å¡©ã第ïŒã¢ãã³é¡çã
æããããããŸãäž¡æ§æŽ»æ§å€ã®äŸãšããŠã¯ããžã¡
ãã«ã¢ã«ãã«ãã¿ã€ã³é¡ãã¢ã«ãã«ã°ãªã·ã³é¡ç
ãæããããããŸãé«ååä¿è·ã³ãã€ããšããŠã¯
ããªããã«ã¢ã«ã³ãŒã«ãããããã·ãšãã«ã»ã«ã
ãŒã¹çãæããããããããã®ä¿è·ã³ãã€ãã¯ã
åç¬ã§ä¹³åå€ãšããŠçšããŠãããããŸãä»ã®çé¢
掻æ§å€ãšçµã¿åããŠçšããŠãããããããã®æŽ»æ§
å€ã®çš®é¡ããã³ãã®äœçšã«ã€ããŠã¯ãBelgische
Chemische Industrieã28å·»ã16â20é ïŒ1963ïŒ
ã«èšèŒãããŠããã 溶液éåæ³çã«ãã€ãŠåæããã芪油æ§ããªã
ãŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹ã®åœ¢
ã§åæ£ããã«ã¯ããŸã芪油æ§ããªããŒã«ãã©ãŒã
ææ©æº¶åªäžã«æº¶ãããã®ã¡ãããããŒã©ãã³æ°Žæº¶
液äžã«åæ£å€ã®å©ãããããŠãè¶ é³æ³¢ãã³ãã€ã
ãã«çã«ããã©ããã¯ã¹ç¶ã«åæ£ããã芪油æ§ã
ãªããŒã«ãã©ãŒããŒã©ãã³æ°Žæº¶æ¶²äžã«ã©ããã¯ã¹
ã®åœ¢ã§åæ£ããæ¹æ³ã«ã€ããŠã¯ç±³åœç¹èš±ç¬¬
3451820å·ã«èšèŒãããŠããã芪油æ§ããªããŒã«
ãã©ãŒã溶解ããææ©æº¶åªãšããŠã¯ããšã¹ãã«
é¡ãäŸãã°é ¢é žã¡ãã«ãé ¢é žãšãã«ãé ¢é žããã
ã«çãã¢ã«ã³ãŒã«é¡ãã±ãã³é¡ãããã²ã³åçå
æ°ŽçŽ ããšãŒãã«é¡çãçšããããšãã§ããããŸã
ãããã®ææ©æº¶åªã¯ãåç¬ã§åã¯ïŒçš®ä»¥äžãçµã¿
åããŠçšããããšãã§ããã 次ã«æ¬çºæã®ããªããŒã«ãã©ãŒã®åæã«ã€ããŠ
以äžã«å ·äœçã«ç€ºããæ¬çºæã¯ããã«éå®ãããª
ãã ããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã®è£œé 補é äŸ (1) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³
ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³ïŒäŸç€ºå
åç©(3)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®èŠªæ²¹æ§ã
ãªããŒã«ãã©ãŒã®ã©ããã¯ã¹(A)ã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³ã¢
ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãšïœâã
ãã«ã¢ã¯ãªã¬ãŒã10ïœãšãžãªããµã³120mlã®æ··å
ç©ã80âã§çªçŽ æ°æµäžã§æªæãããžãªããµã³ïŒml
ã«æº¶è§£ããã¢ãŸãã¹ã€ãœããããããªã«0.36ïœã
å ããã®ã¡ãïŒæéåå¿ãããæ°ŽïŒäžã«ãžãªã
ãµã³æº¶æ¶²ã滎äžããæåºããåºäœãå¥ããæ°Žã§
æŽæµåŸã也ç¥ã14.8ïœïŒ74ïŒ ïŒã®èŠªæ²¹æ§ããªããŒ
ã«ãã©ãŒãåŸãããã®èŠªæ²¹æ§ããªããŒã«ãã©ãŒã®
å ±éåäœçµæã¯å çŽ åæïŒçªçŽ åæïŒã«ããã«ã
ã©ãŒåéäœå«æç54.1ïŒ ã§ãã€ãã äžèšèŠªæ²¹æ§ããªããŒã«ãã©ãŒã10ïœã¥ã€é ¢é žãš
ãã«30mlã«æº¶ããããã®æº¶æ¶²ã«ã©ãŠãªã«ç¡«é žãã
ãªãŠã ã®10ééïŒ æ°Žæº¶æ¶²ïŒmlãšãŒã©ãã³ïŒééïŒ
氎溶液100mlã®æ··å液ãå ãè¶ é³æ³¢åæ£ãè¡ã€ãã
ãã®åŸæžå§èžçã«ãŠé ¢é žãšãã«ãé€å»ãããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹(A)ãåŸãã 補é äŸ (2) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹
ã«ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³
ïŒäŸç€ºååç©(10)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®
芪油æ§ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(B)ã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«
ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãš
ïœâããã«ã¢ã¯ãªã¬ãŒã10ïœãšãžãªããµã³120ml
ã®æ··åç©ã80âã§çªçŽ æ°æµäžã§æªæãããžãªããµ
ã³ïŒmlã«æº¶è§£ããã¢ãŸãã¹ã€ãœããããããªã«
0.36ïœãå ããã®ã¡ãïŒæéåå¿ãããæ°ŽïŒäž
ã«ãžãªããµã³æº¶æ¶²ã滎äžããæåºããåºäœãå¥
ããæ°Žã§æŽæµåŸã也ç¥ã15.2ïœïŒåç76ïŒ ïŒã®ã
ãªããŒã«ãã©ãŒãåŸãããã®ããªããŒã«ãã©ãŒã®
å ±éåçµæã¯å çŽ åæïŒçªçŽ åæïŒã«ããã«ãã©
ãŒåéäœå«æç52.7ïŒ ã§ãã€ãã åŸãããããªããŒã«ãã©ãŒããäžèšåæäŸ(1)ãš
åãæ¹æ³ã§ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(B)ãåŸ
ãã 補é äŸ(3)ã補é äŸ(17) äžèšç¬¬ïŒè¡šã«èšèŒãããåéäœã«ãã©ãŒããã³
ã³ã¢ãããŒãçšããŠåèšåæäŸ(1)ããã³(2)ã«æºã
ãŠæº¶æ¶²éåæ³ã«ããè¡šã«ç€ºãåŠãããªããŒã«ãã©
ãŒãåæããããããŠåŸãããããªããŒã«ãã©ãŒ
äžã®ã«ãã©ãŒã¢ãããŒå«æçãåè¡šã«ééïŒ ã§ç€º
ããã
ãè¡šã
äžèšè¡šã«ãããŠã³ã¢ãããŒã®ç¥ç§°ã¯ä»¥äžã®åå
ç©ãè¡šããã BAïŒïœâããã«ã¢ã¯ãªã¬ãŒã EAïŒãšãã«ã¢ã¯ãªã¬ãŒã BMAïŒïœâããã«ã¡ã¿ã¯ãªã¬ãŒã OMAïŒïœâãªã¯ãã«ã¡ã¿ã¯ãªã¬ãŒã STïŒã¹ãã¬ã³ 補é äŸ (18) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³
ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³ïŒäŸç€ºå
åç©(3)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®ããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ïŒAâ²ïŒã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³ã¢
ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãšïœâã
ãã«ã¢ã¯ãªã¬ãŒã10ïœããšã¿ããŒã«200mlã«å ç±
溶解ããããªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ãã®ãããªãŠ
ã å¡©ïŒïœã溶解ãã氎溶液800mlãçªçŽ æ°æµäžã§
95âã«å ç±ããŠæªæããããã«éç¡«é žã«ãªãŠã
140mgã®æº¶è§£ãã氎溶液20mlãå ããã次ãã§å
èšã®ãšã¿ããŒã«æº¶æ¶²ãïŒæéãããŠæ»Žäžããã滎
äžåŸ85ã95âã§å ç±æªæããïŒæéåŸã«éç¡«é žã«
ãªãŠã ã®60mgã®æ°Žæº¶æ¶²20mlãå ããŠããã«ïŒæé
å枩床ã§æªæãããã®åŸãšã¿ããŒã«ããã³æªåå¿
ã®ïœâããã«ã¢ã¯ãªã¬ãŒããæ°Žã®å ±æ²žæ··åç©ãšã
ãŠçå»ãããåŸãããã©ããã¯ã¹ïŒAâ²ïŒã®åºåœ¢
åæ¿åºŠã¯96ééïŒ ãå ±éåäœçµææ¯ã¯å çŽ åæå€
ããã«ãã©ãŒåéäœå«æçã53.7ïŒ ã§ãã€ãã 補é äŸ (19) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹
ã«ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³
ïŒäŸç€ºååç©(10)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®
ããªããŒã«ãã©ãŒïŒBâ²ïŒã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«
ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãš
ïœâããã«ã¢ã¯ãªã¬ãŒã10ïœããšã¿ããŒã«200ml
ã«å ç±æº¶è§£ããããªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ãã®ã
ããªãŠã å¡©ïŒïœã®æº¶è§£ãã氎溶液800mlãçªçŽ æ°
æµäžã§95âã«å ç±ããŠæªæããããã«éç¡«é žã«ãª
ãŠã 140mgã®æº¶è§£ãã氎溶液20mlãå ããã次ã
ã§åèšã®ãšã¿ããŒã«æº¶æ¶²ãïŒæéãããŠæ»Žäžã
ãã滎äžåŸ85ã95âã§å ç±æªæããïŒæéåŸã«é
ç¡«é žã«ãªãŠã 60mgã®æº¶è§£ãã氎溶液20mlãå ãã
ããã«ïŒæéå枩床ã§æªæãããã®åŸããšã¿ããŒ
ã«ããã³æªåå¿ã®ïœâããã«ã¢ã¯ãªã¬ãŒããæ°Žã®
å ±æ²žæ··åç©ãšããŠçå»ãããåŸãããã©ããã¯ã¹
ïŒBâ²ïŒã®åºåœ¢åæ¿åºŠã¯98ééïŒ ãå ±éåäœçµææ¯
ã¯å çŽ åæå€ããã«ãã©ãŒåéäœå«æçã53.1ïŒ
ã§ãã€ãã 補é äŸ(20)ã補é äŸ(24) äžèšç¬¬ïŒè¡šã«èšèŒãããåéäœã«ãã©ãŒããã³
ã³ã¢ãããŒãçšããŠåèšåæäŸ(18)ããã³(19)ã«æºã
ãŠä¹³åéåæ³ã«ããè¡šã«ç€ºãåŠãããªããŒã«ãã©
ãŒãåæããããããŠåŸãããããªããŒã«ãã©ãŒ
äžã®ã«ãã©ãŒã¢ãããŒå«æçãåè¡šã«ééïŒ ã§ç€º
ããã
ç©ãè¡šããã BAïŒïœâããã«ã¢ã¯ãªã¬ãŒã EAïŒãšãã«ã¢ã¯ãªã¬ãŒã BMAïŒïœâããã«ã¡ã¿ã¯ãªã¬ãŒã OMAïŒïœâãªã¯ãã«ã¡ã¿ã¯ãªã¬ãŒã STïŒã¹ãã¬ã³ 補é äŸ (18) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³
ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³ïŒäŸç€ºå
åç©(3)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®ããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ïŒAâ²ïŒã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«ãã³ã¢
ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãšïœâã
ãã«ã¢ã¯ãªã¬ãŒã10ïœããšã¿ããŒã«200mlã«å ç±
溶解ããããªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ãã®ãããªãŠ
ã å¡©ïŒïœã溶解ãã氎溶液800mlãçªçŽ æ°æµäžã§
95âã«å ç±ããŠæªæããããã«éç¡«é žã«ãªãŠã
140mgã®æº¶è§£ãã氎溶液20mlãå ããã次ãã§å
èšã®ãšã¿ããŒã«æº¶æ¶²ãïŒæéãããŠæ»Žäžããã滎
äžåŸ85ã95âã§å ç±æªæããïŒæéåŸã«éç¡«é žã«
ãªãŠã ã®60mgã®æ°Žæº¶æ¶²20mlãå ããŠããã«ïŒæé
å枩床ã§æªæãããã®åŸãšã¿ããŒã«ããã³æªåå¿
ã®ïœâããã«ã¢ã¯ãªã¬ãŒããæ°Žã®å ±æ²žæ··åç©ãšã
ãŠçå»ãããåŸãããã©ããã¯ã¹ïŒAâ²ïŒã®åºåœ¢
åæ¿åºŠã¯96ééïŒ ãå ±éåäœçµææ¯ã¯å çŽ åæå€
ããã«ãã©ãŒåéäœå«æçã53.7ïŒ ã§ãã€ãã 補é äŸ (19) ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹
ã«ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³
ïŒäŸç€ºååç©(10)ïŒãšïœâããã«ã¢ã¯ãªã¬ãŒãã®
ããªããŒã«ãã©ãŒïŒBâ²ïŒã®è£œé ïŒâïŒïŒïŒïŒïŒïŒâããªã¯ããããšãã«ïŒâïŒâ
ïŒïŒâã¡ãã«ã¡ã¿ã¯ãªãã€ã«ã¢ãããã³ãŒã³ã¹ã«
ãã³ã¢ããïŒâïŒâãã©ãŸãªã³âïŒâãªã³10ïœãš
ïœâããã«ã¢ã¯ãªã¬ãŒã10ïœããšã¿ããŒã«200ml
ã«å ç±æº¶è§£ããããªã¬ã€ã«ã¡ãã«ã¿ãŠã©ã€ãã®ã
ããªãŠã å¡©ïŒïœã®æº¶è§£ãã氎溶液800mlãçªçŽ æ°
æµäžã§95âã«å ç±ããŠæªæããããã«éç¡«é žã«ãª
ãŠã 140mgã®æº¶è§£ãã氎溶液20mlãå ããã次ã
ã§åèšã®ãšã¿ããŒã«æº¶æ¶²ãïŒæéãããŠæ»Žäžã
ãã滎äžåŸ85ã95âã§å ç±æªæããïŒæéåŸã«é
ç¡«é žã«ãªãŠã 60mgã®æº¶è§£ãã氎溶液20mlãå ãã
ããã«ïŒæéå枩床ã§æªæãããã®åŸããšã¿ããŒ
ã«ããã³æªåå¿ã®ïœâããã«ã¢ã¯ãªã¬ãŒããæ°Žã®
å ±æ²žæ··åç©ãšããŠçå»ãããåŸãããã©ããã¯ã¹
ïŒBâ²ïŒã®åºåœ¢åæ¿åºŠã¯98ééïŒ ãå ±éåäœçµææ¯
ã¯å çŽ åæå€ããã«ãã©ãŒåéäœå«æçã53.1ïŒ
ã§ãã€ãã 補é äŸ(20)ã補é äŸ(24) äžèšç¬¬ïŒè¡šã«èšèŒãããåéäœã«ãã©ãŒããã³
ã³ã¢ãããŒãçšããŠåèšåæäŸ(18)ããã³(19)ã«æºã
ãŠä¹³åéåæ³ã«ããè¡šã«ç€ºãåŠãããªããŒã«ãã©
ãŒãåæããããããŠåŸãããããªããŒã«ãã©ãŒ
äžã®ã«ãã©ãŒã¢ãããŒå«æçãåè¡šã«ééïŒ ã§ç€º
ããã
ãè¡šã
äžèšè¡šã«ãããŠBAã¯ïœâããã«ã¢ã¯ãªã¬ãŒã
ãè¡šããã æ¬çºæã«ãããããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©
ããã¯ã¹ã¯åç¬ã§ããããã¯äžè¬ã«ããç¥ããã
ã«ãã©ãŒãšæ··åããŠçšããããšãã§ãããæ¬çºæ
ã®ããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãšåã
è²çŽ ç»å圢ææ§ã«ãã©ãŒã§ãããããŸãç°ãªãè²
çŽ ç»å圢ææ§ã«ãã©ãŒã§ãããããŸãè²è£æ£çšå¹
æããã€ã«ã©ãŒãã«ãã©ãŒãããã¯çŸåæå¶å€æŸ
åºïŒDIRïŒã«ãã©ãŒãã«ãããªã³ã°åå¿ã«ãã€ãŠ
圢æãããçæç©ãç¡è²ã§ããïŒã¯ã€ã¹ïŒã«ãã©
ãŒãæ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒãšäœµçšã
ãŠäœ¿çšããããšãã§ãããæ··åãããã«ãã©ãŒã¯
ååäžã«ãã©ã¹ãåºãšåŒã°ããçæ°Žæ§åºãæãã
éæ¡æ£æ§ã®ã«ãã©ãŒãæãŸããããç±³åœç¹èš±ç¬¬
4080211å·ãå第3163625å·ãå第3451820å·ãå
第4215195å·ãè±åœç¹èš±ç¬¬1247688å·ãç¹éæ57â
94752å·ãå58â28745å·ãå58â42044å·ãå58
â43955å·ãåå ¬å ±æ现æžã«èšèŒãããŠããããª
ããŒã«ãã©ãŒãã¹ã«ãã³é žåºãŸãã¯ã«ã«ãã³é žåº
ãæãã氎溶æ§ããªããŒã«ãã©ãŒã§ãããã ãŸã䜵çšãããããŒã³ã¿è²çŽ ç»å圢ææ§ã«ãã©
ãŒã®äŸãšããŠã¯ãç±³åœç¹èš±ç¬¬2600788å·ãå第
2983608å·ãå第3062653å·ãå第3127269å·ãå
3311476å·ãå第3419391å·ãå第3519429å·ãå
第3558319å·ãå第3582322å·ãå第3615506å·ã
å第3834908å·ãå第3891445å·ã西ç¬ç¹èš±ç¬¬
1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å第2417945å·ãå第2418959å·ãå第2424467å·ã
ç¹å ¬æ40â6031å·ãç¹éæ51â20826å·ãå52â
58922å·ãå49â129538å·ãå49â74027å·ãå50
â159336å·ãå52â42121å·ãå49â74028å·ãå
50â60233å·ãå51â26541å·ãå53â35122å·ã«
èšèŒãããŠããã«ãã©ãŒãæããããã ãŸã䜵çšãããã«ã©ãŒãã«ãã©ãŒã®äŸãšããŠ
ã¯ãç±³åœç¹èš±ç¬¬3148062å·ãå第3227554å·ãå第
3733201å·ãå第3617291å·ãå第3703375å·ãå
第3615506å·ãå第3265506å·ãå第3620745å·ã
å第3632345å·ãå第3869291å·ãå第3642485å·ã
å第3770436å·ãå第3808945å·ãè±åœç¹èš±ç¬¬
1201110å·ãå第1236767å·ã«èšèŒãããŠããã«ã©
ãŒãã«ãã©ãŒãæããããã äžèšã®ã«ãã©ãŒãç±³åœç¹èš±ç¬¬2269158å·ãå第
2304940å·ãå第2322027å·ãå第2772163å·ãå
第2801171å·ãè±åœç¹èš±ç¬¬1151590å·çã«èšèŒã®æ¹
æ³ã§èŠªæ°Žæ§ã³ãã€ãã«åæ£ããã®åæ£ç©ãç¹å ¬æ
48â30494å·ãå51â39853å·å ¬å ±æ现æžã«èšèŒã
ããæ¹æ³ã§æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹ã«å«æµžïŒããŒãïŒããŠäœ¿çšããããšã
ã§ãããããã§å«æµžïŒããŒãïŒãšã¯ãçæ°Žæ§ããŒ
ã³ã¿ã«ãã©ãŒãããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©ã
ãã¯ã¹å éšã«å«ãŸããç¶æ ããããã¯ããŒã³ã¿ã«
ãã©ãŒã®ã©ããã¯ã¹è¡šé¢ã«æ²ç©ããŠããç¶æ ãæ
å³ãããããããå«æµžïŒããŒãïŒããããªãæ©æ§
ã§èµ·ãããã¯æ£ç¢ºã«ã¯ããã€ãŠããªãã æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã¯ãç±³åœç¹
èš±2336327å·ãå2728659å·ãå2336327å·ãå
2403721å·ãå2701197å·ãå3700453å·ãªã©ã«èš
èŒã®ã¹ãã€ã³é²æ¢å€ãè±åœç¹èš±1326889å·ãç±³åœ
ç¹èš±3432300å·ãå3698909å·ãå3574627å·ãå
3573050å·ãå3764337å·ãªã©ã«èšèŒã®è²çŽ åå®å®
å€ã西ç¬åœå ¬é2529350å·ãå2448063å·ãå
2610546å·ãç±³åœç¹èš±3928041å·ãå3958993å·ã
å3961959å·ãå4049455å·ãå4052213å·ãå
3379529å·ãå3043690å·ãå3364022å·ãå
3297445å·ãå3287129å·ããªã©ã«èšèŒã®DIRåå
ç©ã䜵çšããŠäœ¿çšããããšãã§ããã äžèšã®äžè¬ã«ããç¥ãããã«ãã©ãŒãããã²ã³
åéä¹³å€å±€ã«å°å ¥ããã«ã¯ãåŸæ¥å ¬ç¥ã®æ¹æ³ãçš
ããããšãã§ãããäŸãã°ããªã¯ã¬ãžã«ããªã¹ã
ãšãŒãããžããã«ãã¿ã¬ãŒãçã®æ²žç¹175â以äž
ã®é«æ²žç¹ææ©æº¶åªãŸãã¯é ¢é žããã«ãããããªã³
é žããã«çã®äœæ²žç¹æº¶åªã®ããããåç¬ãŸãã¯å¿
èŠã«å¿ããŠãããã®æ··å溶åªã«äžèšã«ãã©ãŒã溶
解ããåŸãçé¢æŽ»æ§å€ãå«ããŒã©ãã³æ°Žæº¶æ¶²ãšæ··
åãã次ã«é«é床å転ãããµãŒãŸãã¯ã³ãã€ãã
ã«ã§ä¹³åããåŸãããã²ã³åéã«æ·»å ããŠæ¬çºæ
ã«äœ¿çšããããã²ã³åéä¹³å€ã調æŽããããšãåº
æ¥ãã ãããŠãæ¬çºæã«äœ¿çšããããã²ã³åéä¹³å€äž
ã«æ·»å ããå Žåãéåžžãããã²ã³åéïŒã¢ã«åœã
0.07ã0.7ã¢ã«ã奜ãŸããã¯0.1ã¢ã«ã0.4ã¢ã«ã®é
ã§æ·»å ããããã«ãã©ãŒããã¹ã«ãã³é žãã«ã«ã
ã³é žãªã©ã®é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æº¶
液ãšããŠèŠªæ°Žæ§ã³ãã€ãäžã«æ·»å ãããã æ¬çºæã«ä¿ãããã²ã³åéä¹³å€å±€ã«çšãããã
ã²ã³åéãšããŠã¯ãå¡©åéãèåéãæ²åéãå¡©
èåéãæ²èåéãå¡©æ²èåéçã®éåžžã®ããã²
ã³åéåçä¹³å€ã«äœ¿çšãããä»»æã®ãã®ãå å«ã
ããã ãããã®ããã²ã³åéç²åã¯ãç²ç²ã®ãã®ã§ã
埮ç²ã®ãã®ã§ããããç²åŸã®ååžã¯çããŠãåºã
ãŠãããããŸãããããã®ããã²ã³åéç²åã®çµ
æ¶ã¯ãæ£åžžæ¶ãåæ¶ã§ãããã100é¢ãšïŒ»111
é¢ã®æ¯çã¯ä»»æã®ãã®ã䜿çšã§ãããæŽã«ããã
ãã®ããã²ã³åéç²åã®çµæ¶æ§é ã¯ãå éšããå€
éšãŸã§åäžãªãã®ã§ãã€ãŠããå éšãšå€éšãç°è³ª
ã®å±€ç¶æ§é ããããã®ã§ãã€ãŠãããããŸããã
ããã®ããã²ã³åéã¯æœåãäž»ãšããŠè¡šé¢ã«åœ¢æ
ããåã®ãã®ã§ããç²åå éšã«åœ¢æããåã®ãã®
ã§ãããããããã®ããã²ã³åéç²åã¯ãåœæ¥ç
ã«ãããŠæ £çšãããŠããå ¬ç¥ã®æ¹æ³ã«ãã€ãŠèª¿è£œ
ããããšãã§ããã æ¬çºæã«ãããŠçšããããããã²ã³åéä¹³å€ã¯
å¯æº¶æ§å¡©é¡ãé€å»ããã®ã奜ãŸããããæªé€å»ã®
ãã®ã䜿çšã§ããããŸããå¥ã ã«èª¿è£œããïŒçš®ä»¥
äžã®ããã²ã³åéä¹³å€ãæ··åããŠäœ¿çšããããšã
ã§ããã æ¬çºæã«ä¿ãããã²ã³åéä¹³å€å±€ã®ãã€ã³ããŒ
ãšããŠã¯ãåŸæ¥ç¥ããããã®ãçšããããäŸãã°
ãŒã©ãã³ãããšãã«ã«ã«ããã«åãŒã©ãã³ãã¢ã·
ã«åãŒã©ãã³ããã¿ã«åãŒã©ãã³çã®ãŒã©ãã³èª
å°äœçãããªããã«ã¢ã«ã³ãŒã«ãããªããã«ãã
ãªãã³ãããªã¢ã¯ãªã«é žã¢ããçã®é«ååéé»è§£
質ãã¢ã«ã®ã³é žå¡©ãããªã¢ã¯ãªã«é žå¡©çã®é žæ§é«
ååç©è³ªããããã³è»¢äœåå¿ã«ãã€ãŠåŠçããã
ãªã¢ã¯ãªã«ã¢ãããã¢ã¯ãªã«é žãšïŒ®âããã«ã€ã
ããŸãŒã«ã®å ±éåç©çã®é«ååäž¡æ§é»è§£è³ªãç±³åœ
ç¹èš±4215195å·ã«èšèŒã®æ¶æ©æ§ããªããŒçãæã
ããããååæ£ãããçæ°Žæ§é«ååç©è³ªãäŸãã°
ããªã¢ã¯ãªã«é žããã«ãšã¹ãã«ãããªã¢ã¯ãªã«é ž
ãšãã«ãšã¹ãã«çã®ã©ããã¯ã¹ãå«ãã§ããŠãã
ãããããã®ãã€ã³ããŒã¯å¿ èŠã«å¿ããŠïŒã€ä»¥äž
ã®çžæº¶æ§æ··åç©ãšããŠäœ¿çšããããšãã§ããã äžè¿°ã®ããã²ã³åéç²åããã€ã³ããŒæ¶²äžã«å
æ£ããããããã²ã³åéåçä¹³å€ã¯ãååŠå¢æå€
ã«ããå¢æããããšãã§ãããæ¬çºæã«ãããŠæ
å©ã«äœµçšããŠäœ¿çšã§ããååŠå¢æå€ã¯ã貎éå±å¢
æå€ãç¡«é»å¢æå€ãã»ã¬ã³å¢æå€åã³éå å¢æå€
ã®ïŒçš®ã«å€§å¥ãããã 貎éå±å¢æå€ãšããŠã¯ãéååç©ããã³ã«ãã
ãŠã ãããžãŠã ããã©ãžãŠã ãã€ãªãžãŠã ãçœé
ãªã©ã®ååç©ãçšããããšãã§ããã ãªããéååç©ã䜿çšãããšãã«ã¯æŽã«ã¢ã³ã¢
ããŠã ããªã·ã¢ããŒãããããªãŠã ããªã·ã¢ããŒ
ãã䜵çšããããšãã§ããã ç¡«é»å¢æå€ãšããŠã¯ã掻æ§ãŒã©ãã³ã®ã»ããç¡«
é»ååç©ãçšããããšãã§ããã ã»ã¬ã³å¢æå€ãšããŠã¯ã掻æ§åã³äžæŽ»æ§ã»ã¬ã³
ååç©ãçšããããšãã§ããã éå å¢æå€ã«ã¯ã第ïŒã¹ãºå¡©ãããªã¢ãã³ãã
ã¹ã¢ã«ãã«ã¢ããã¹ã«ãã€ããã·ã©ã³ååç©ãã€
ããã¢ããã¡ã¿ã³ã¹ã«ãã€ã³é žãããã©ãžããŠã
å¡©ãããã©ãžã³èªå°äœãããã ããã«åããã®ããã²ã³åéã¯ææã®æ³¢é·åã«
å åŠçã«å¢æããããšãã§ããäŸãã°ã¢ãã¡ãã³
è²çŽ ãããªã¡ãã³è²çŽ çã®ã·ã¢ãã³è²çŽ ãããã¯
ã¡ãã·ã¢ãã³è²çŽ çã®å åŠå¢æå€ã§åç¬ãããã¯
䜵çšããŠå åŠçã«å¢æããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã«ã¯ãåè¿°
ããæ·»å å€ä»¥å€ã«å®å®å€ãçŸåä¿é²å€ã硬èå€ã
çé¢æŽ»æ§å€ãæ±æé²æ¢å€ã最æ»å€ã玫å€ç·åžå
å€ããã«ããªã³ã¹ã«ãã³ãžã€ãŒãã®ä»åçæå æ
æã«æçšãªåçš®ã®æ·»å å€ãçšããããã æ¬çºæã®ããã²ã³åéåçæå ææã¯ããã²ã³
åéä¹³å€å±€ã®ä»ã«ä¿è·å±€ãäžéå±€ããã€ã«ã¿ãŒ
å±€ããã¬ãŒã·ãšã³é²æ¢å±€ããããã³ã°å±€çã®è£å©
å±€ãé©å®èšããããšãã§ããã æ¯æäœãšããŠã¯ãã©ã¹ããã¯ãã€ã«ã ããã©ã¹
ããã¯ã©ãããŒãçŽããã©ã€ã¿çŽãåæçŽãçåŸ
æ¥ç¥ããããã®ãåçæå ææã®äœ¿çšç®çã«å¿ã
ãŠé©å®éžæããã°ããããããã®æ¯æäœã¯äžè¬ã«
åçä¹³å€å±€ãšã®æ¥çã匷åããããã«äžåŒå å·¥ã
æœãããã ããããŠæ§æãããæ¬çºæã®ããã²ã³åéåç
æå ææã¯ãé²å ããåŸãçºè²çŸåããããã«
çš®ã ã®åçåŠçæ¹æ³ãçšãããããæ¬çºæã«çšã
ããã奜ãŸããçºè²çŸå液ã¯ãè³éŠæ第ïŒçŽã¢ã
ã³ç³»çºè²çŸåäž»è¬ãäž»æåãšãããã®ã§ãããã
ã®çºè²çŸåäž»è¬ã®å ·äœäŸãšããŠã¯ãïœâããšãã¬
ã³ãžã¢ãã³ç³»ã®ãã®ã代衚çã§ãããäŸãã°ãžãš
ãã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãã¢ãã¡ã
ã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ããžã¡ãã«â
ïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãïŒâã¢ããâïŒ
âãžãšãã«ã¢ãããã«ãšã³å¡©é žå¡©ãïŒâã¢ããâ
ïŒâïŒïŒ®âãšãã«ââããã·ã«ã¢ããïŒâãã«ãš
ã³ãïŒâã¢ããâïŒâïŒïŒ®âãšãã«ââβâã¡
ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒã¢ãããã«ãšã³ç¡«é ž
å¡©ãïŒâïŒïŒ®âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³
ã¢ãããšãã«ã¢ããïŒã¢ããªã³ãïŒâïŒïŒ®âãšã
ã«ââβâããããã·ãšãã«ã¢ããïŒã¢ããª
ã³ãïŒâã¢ããâïŒâïŒïŒ®âãšãã«âβâã¡ãã
ã·ãšãã«ïŒã¢ãããã«ãšã³çãæããããããã
ãã®çºè²çŸåäž»è¬ã¯åç¬ã§ãããã¯ïŒçš®ä»¥äžã䜵
çšããŠããŸãå¿ èŠã«å¿ããŠçœé»çŸåäž»è¬ãäŸãã°
ãã€ããããã³ãããšããã³çãšäœµçšããŠçšãã
ãããæŽã«çºè²çŸå液ã¯ãäžè¬ã«ã¢ã«ã«ãªå€ãäŸ
ãã°æ°Žé žåãããªãŠã ãæ°Žé žåã¢ã³ã¢ããŠã ãç
é žãããªãŠã ãäºç¡«é žãããªãŠã çãå«ã¿ãæŽã«
çš®ã ã®æ·»å å€äŸãã°ããã²ã³åã¢ã«ã«ãªéå±äŸã
ã°èåã«ãªãŠã ããããã¯çŸå調ç¯å€äŸãã°ã·ã
ã©ãžã³é žçãå«æããŠãè¯ãã æ¬çºæã®ããã²ã³åéåçæå ææã¯ã芪氎æ§
ã³ãã€ãå±€äžã«ãåèšã®çºè²çŸåäž»è¬ããçºè²çŸ
åäž»è¬ãã®ãã®ãšããŠããããã¯ããã®ãã¬ã«ãŒ
ãµãŒãšããŠå«æããŠããŠããããçºè²çŸåäž»è¬ã
ã¬ã«ãŒãµãŒã¯ãã¢ã«ã«ãªæ§æ¡ä»¶äžãçºè²çŸåäž»è¬
ãçæãããååç©ã§ãããè³éŠæã¢ã«ãããèª
å°äœãšã®ã·ããããŒã¹åãã¬ã«ãŒãµãŒãå€äŸ¡éå±
ã€ãªã³é¯äœãã¬ã«ãŒãµãŒããã¿ã«é žã€ããèªå°äœ
ãã¬ã«ãŒãµãŒããªã³é žã¢ããèªå°äœãã¬ã«ãŒãµ
ãŒãã·ãŠã¬ãŒã¢ãã³åå¿ç©ãã¬ã«ãŒãµãŒããŠã¬ã¿
ã³åãã¬ã«ãŒãµãŒãæããããããããè³éŠæ第
ïŒçŽã¢ãã³çºè²çŸåäž»è¬ã®ãã¬ã«ãŒãµãŒã¯ãäŸã
ã°ç±³åœç¹èš±ç¬¬3342599å·ãå第2507114å·ãå第
2695234å·ãå第3719492å·ãè±åœç¹èš±ç¬¬803783å·
æ现æžãç¹éæ53â135628å·ãå54â79035å·ã®
åå ¬å ±ããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒèª15159
å·ãå12146å·ãå13924å·ã«èšèŒãããŠããã ãããã®è³éŠæ第ïŒçŽã¢ãã³çºè²çŸåäž»è¬åã¯
ãã®ãã¬ã«ãŒãµãŒã¯ãçŸååŠçããéã«ååãªçº
è²ãåŸãããéãæ·»å ããŠããå¿ èŠãããããã®
éã¯æå ææã®çš®é¡çã«ãã€ãŠå€§åç°ãªãããã
ãããæå æ§ããã²ã³åéïŒã¢ã«åœã0.1ã¢ã«ã
ãïŒã¢ã«ã®éã奜ãŸããã¯0.5ã¢ã«ããïŒã¢ã«ã®
ç¯å²ã§çšããããããããã®çºè²çŸåäž»è¬ãŸãã¯
ãã®ãã¬ã«ãŒãµãŒã¯ãåç¬ã§ãŸãã¯ãçµåããŠçš
ããããšãã§ããããããã®çŸåäž»è¬ãŸãã¯ãã®
ãã¬ã«ãŒãµãŒçã®æ·»å å€ãåçæå ææäžã«å èµ
ããã«ã¯ãæ°Žãã¡ã¿ããŒã«ããšã¿ããŒã«ãã¢ã»ã
ã³çã®é©åœãªæº¶åªã«æº¶è§£ããŠå ããããšãã§ãã
åããžããã«ãã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒ
ããããªã¯ã¬ãžã«ããªã¹ããšãŒãçã®é«æ²žç¹ææ©
溶åªãçšããä¹³ååæ£æ¶²ãšããŠå ããããšãã§
ãããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒèª14850å·ã«
èšèŒãããŠããããã«ãã©ããã¯ã¹ããªããŒã«å«
浞ãããŠæ·»å ããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã«ã¯éåžžã
çºè²çŸååŸã«æŒçœããã³å®çããŸãã¯æŒçœå®çã
ãªãã³ã«æ°ŽæŽãè¡ãªããããæŒçœå€ãšããŠã¯ãå€
ãã®ååç©ãçšããããããäžã§ãéïŒïŒãã³
ãã«ãïŒïŒãé«ïŒïŒããªã©å€äŸ¡éå±ååç©ããš
ãããããããã®å€äŸ¡éå±ã«ããªã³ãšææ©é žã®é¯
å¡©ãäŸãã°ããšãã¬ã³ãžã¢ãã³åé ¢é žããããªã
äžé ¢é žãâããããã·ãšãã«ãšãã¬ã³ãžã¢ãã³
äºé ¢é žã®ãããªã¢ããããªã«ã«ãã³é žãããã³
é žãé ç³é žããªã³ãŽé žããžã°ãªã³ãŒã«é žããžããª
ã°ãªã³ãŒã«é žãªã©ã®éå±é¯å¡©ãããã¯ããšãªã·ã¢
ã³é žå¡©é¡ãéã¯ãã é žå¡©ãªã©ãåç¬ãŸãã¯é©åœãª
çµåããã§çšããããã 以äžã«å®æœäŸãæããŠæ¬çºæãæŽã«å ·äœçã«èš
èŒããã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®æº¶æ¶²éåã«ããããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹(A)ïŒ(B)ïŒ(D)ïŒ(F)ããã³
ïŒïŒ§ïŒãªãã³ã«äžèšã®æ¯èŒçšããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹(1)ïŒ(2)ããã³(3)溶液ã®åã ããŒã³ã¿è²
çŽ åœ¢æã«ãã©ãŒéšäœãïŒÃ10-3ã¢ã«å«ãéãæ²è
åéïŒÃ10-2ã¢ã«ããã³ãŒã©ãã³10ïœãå«ãé«æ
床æ²èåéä¹³å€100ïœã«æ·»å ããããªã¢ã»ããŒã
ãã€ã«ã æ¯æäœäžã«2.4ïœïŒm2ã®å¡åžéã§å¡åžãã
也ç¥ããŠå®å®ãªå¡èãæããæå ææã®è©Šæ(1)ã
(8)ãäœæããã ïŒæ¯èŒçšããªããŒã«ãã©ãŒïŒ äžèšã«ããäœæãããåè©Šæãéåžžã®æ¹æ³ã§ã
ããããŠãšããžé²å ããåŸãäžèšã®çŸååŠçãè¡
ã€ãã åŠçå·¥çšïŒ38âïŒ åŠçæé çºè²çŸå ïŒå15ç§ æŒ çœ ïŒå30ç§ æ°Ž æŽ ïŒå15ç§ å® ç ïŒå30ç§ æ°Ž æŽ ïŒå15ç§ å®å®æµŽ ïŒå30ç§ ååŠçå·¥çšã«ãããŠäœ¿çšããåŠç液çµæã¯äžèš
ã®åŠãã§ãã€ãã çºè²çŸå液çµæ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡© 4.75ïœ ç¡æ°Žäºç¡«é žãããªãŠã 4.25ïœ ããããã·ã¢ãã³ïŒïŒïŒç¡«é žå¡© 2.0ïœ ç¡æ°Žçé žã«ãªãŠã 37.5ïœ èåãããªãŠã 1.3ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
2.5ïœ æ°Žé žåã«ãªãŠã 1.0ïœ æ°Žãå ããŠïŒãšãæ°Žé žåã«ãªãŠã ãçšããŠPH
10.0ã«èª¿æŽããã æŒçœæ¶²çµæ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°· é ¢ é ž 10.0ml æ°Žãå ããŠïŒãšãã¢ã³ã¢ãã¢æ°ŽãçšããŠPH
6.0ã«èª¿æŽããã å®ç液çµæ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ50ïŒ æ°Žæº¶æ¶²ïŒ 162ml ç¡æ°Žäºç¡«é žãããªãŠã 12.4ïœ æ°Žãå ããŠïŒãšãé ¢é žãçšããŠPH6.5ã«èª¿æŽ
ããã å®å®å液çµæ ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 5.0ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã åŸãããããŒã³ã¿è²ç»åã®æ¿åºŠãããŒã³ã¿ãã€
ã«ã¿ãŒãéãæ¿åºŠæž¬å®ããã«ããªãçžå¯Ÿæ床ãã
ã³æé«æ¿åºŠãç®åºããåŸãããçµæãäžèšç¬¬ïŒè¡š
ã«ç€ºããã è¡šã«ãããçžå¯Ÿæ床ã¯ã«ããªïŒ0.2ã®æ¿åºŠãåŸ
ãã®ã«èŠããé²å éã®éæ°ã®çžå¯Ÿå€ã§ããã
ãè¡šããã æ¬çºæã«ãããããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©
ããã¯ã¹ã¯åç¬ã§ããããã¯äžè¬ã«ããç¥ããã
ã«ãã©ãŒãšæ··åããŠçšããããšãã§ãããæ¬çºæ
ã®ããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãšåã
è²çŽ ç»å圢ææ§ã«ãã©ãŒã§ãããããŸãç°ãªãè²
çŽ ç»å圢ææ§ã«ãã©ãŒã§ãããããŸãè²è£æ£çšå¹
æããã€ã«ã©ãŒãã«ãã©ãŒãããã¯çŸåæå¶å€æŸ
åºïŒDIRïŒã«ãã©ãŒãã«ãããªã³ã°åå¿ã«ãã€ãŠ
圢æãããçæç©ãç¡è²ã§ããïŒã¯ã€ã¹ïŒã«ãã©
ãŒãæ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒãšäœµçšã
ãŠäœ¿çšããããšãã§ãããæ··åãããã«ãã©ãŒã¯
ååäžã«ãã©ã¹ãåºãšåŒã°ããçæ°Žæ§åºãæãã
éæ¡æ£æ§ã®ã«ãã©ãŒãæãŸããããç±³åœç¹èš±ç¬¬
4080211å·ãå第3163625å·ãå第3451820å·ãå
第4215195å·ãè±åœç¹èš±ç¬¬1247688å·ãç¹éæ57â
94752å·ãå58â28745å·ãå58â42044å·ãå58
â43955å·ãåå ¬å ±æ现æžã«èšèŒãããŠããããª
ããŒã«ãã©ãŒãã¹ã«ãã³é žåºãŸãã¯ã«ã«ãã³é žåº
ãæãã氎溶æ§ããªããŒã«ãã©ãŒã§ãããã ãŸã䜵çšãããããŒã³ã¿è²çŽ ç»å圢ææ§ã«ãã©
ãŒã®äŸãšããŠã¯ãç±³åœç¹èš±ç¬¬2600788å·ãå第
2983608å·ãå第3062653å·ãå第3127269å·ãå
3311476å·ãå第3419391å·ãå第3519429å·ãå
第3558319å·ãå第3582322å·ãå第3615506å·ã
å第3834908å·ãå第3891445å·ã西ç¬ç¹èš±ç¬¬
1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å第2417945å·ãå第2418959å·ãå第2424467å·ã
ç¹å ¬æ40â6031å·ãç¹éæ51â20826å·ãå52â
58922å·ãå49â129538å·ãå49â74027å·ãå50
â159336å·ãå52â42121å·ãå49â74028å·ãå
50â60233å·ãå51â26541å·ãå53â35122å·ã«
èšèŒãããŠããã«ãã©ãŒãæããããã ãŸã䜵çšãããã«ã©ãŒãã«ãã©ãŒã®äŸãšããŠ
ã¯ãç±³åœç¹èš±ç¬¬3148062å·ãå第3227554å·ãå第
3733201å·ãå第3617291å·ãå第3703375å·ãå
第3615506å·ãå第3265506å·ãå第3620745å·ã
å第3632345å·ãå第3869291å·ãå第3642485å·ã
å第3770436å·ãå第3808945å·ãè±åœç¹èš±ç¬¬
1201110å·ãå第1236767å·ã«èšèŒãããŠããã«ã©
ãŒãã«ãã©ãŒãæããããã äžèšã®ã«ãã©ãŒãç±³åœç¹èš±ç¬¬2269158å·ãå第
2304940å·ãå第2322027å·ãå第2772163å·ãå
第2801171å·ãè±åœç¹èš±ç¬¬1151590å·çã«èšèŒã®æ¹
æ³ã§èŠªæ°Žæ§ã³ãã€ãã«åæ£ããã®åæ£ç©ãç¹å ¬æ
48â30494å·ãå51â39853å·å ¬å ±æ现æžã«èšèŒã
ããæ¹æ³ã§æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹ã«å«æµžïŒããŒãïŒããŠäœ¿çšããããšã
ã§ãããããã§å«æµžïŒããŒãïŒãšã¯ãçæ°Žæ§ããŒ
ã³ã¿ã«ãã©ãŒãããŒã³ã¿ããªããŒã«ãã©ãŒã®ã©ã
ãã¯ã¹å éšã«å«ãŸããç¶æ ããããã¯ããŒã³ã¿ã«
ãã©ãŒã®ã©ããã¯ã¹è¡šé¢ã«æ²ç©ããŠããç¶æ ãæ
å³ãããããããå«æµžïŒããŒãïŒããããªãæ©æ§
ã§èµ·ãããã¯æ£ç¢ºã«ã¯ããã€ãŠããªãã æ¬çºæã®ããŒã³ã¿ããªããŒã«ãã©ãŒã¯ãç±³åœç¹
èš±2336327å·ãå2728659å·ãå2336327å·ãå
2403721å·ãå2701197å·ãå3700453å·ãªã©ã«èš
èŒã®ã¹ãã€ã³é²æ¢å€ãè±åœç¹èš±1326889å·ãç±³åœ
ç¹èš±3432300å·ãå3698909å·ãå3574627å·ãå
3573050å·ãå3764337å·ãªã©ã«èšèŒã®è²çŽ åå®å®
å€ã西ç¬åœå ¬é2529350å·ãå2448063å·ãå
2610546å·ãç±³åœç¹èš±3928041å·ãå3958993å·ã
å3961959å·ãå4049455å·ãå4052213å·ãå
3379529å·ãå3043690å·ãå3364022å·ãå
3297445å·ãå3287129å·ããªã©ã«èšèŒã®DIRåå
ç©ã䜵çšããŠäœ¿çšããããšãã§ããã äžèšã®äžè¬ã«ããç¥ãããã«ãã©ãŒãããã²ã³
åéä¹³å€å±€ã«å°å ¥ããã«ã¯ãåŸæ¥å ¬ç¥ã®æ¹æ³ãçš
ããããšãã§ãããäŸãã°ããªã¯ã¬ãžã«ããªã¹ã
ãšãŒãããžããã«ãã¿ã¬ãŒãçã®æ²žç¹175â以äž
ã®é«æ²žç¹ææ©æº¶åªãŸãã¯é ¢é žããã«ãããããªã³
é žããã«çã®äœæ²žç¹æº¶åªã®ããããåç¬ãŸãã¯å¿
èŠã«å¿ããŠãããã®æ··å溶åªã«äžèšã«ãã©ãŒã溶
解ããåŸãçé¢æŽ»æ§å€ãå«ããŒã©ãã³æ°Žæº¶æ¶²ãšæ··
åãã次ã«é«é床å転ãããµãŒãŸãã¯ã³ãã€ãã
ã«ã§ä¹³åããåŸãããã²ã³åéã«æ·»å ããŠæ¬çºæ
ã«äœ¿çšããããã²ã³åéä¹³å€ã調æŽããããšãåº
æ¥ãã ãããŠãæ¬çºæã«äœ¿çšããããã²ã³åéä¹³å€äž
ã«æ·»å ããå Žåãéåžžãããã²ã³åéïŒã¢ã«åœã
0.07ã0.7ã¢ã«ã奜ãŸããã¯0.1ã¢ã«ã0.4ã¢ã«ã®é
ã§æ·»å ããããã«ãã©ãŒããã¹ã«ãã³é žãã«ã«ã
ã³é žãªã©ã®é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æº¶
液ãšããŠèŠªæ°Žæ§ã³ãã€ãäžã«æ·»å ãããã æ¬çºæã«ä¿ãããã²ã³åéä¹³å€å±€ã«çšãããã
ã²ã³åéãšããŠã¯ãå¡©åéãèåéãæ²åéãå¡©
èåéãæ²èåéãå¡©æ²èåéçã®éåžžã®ããã²
ã³åéåçä¹³å€ã«äœ¿çšãããä»»æã®ãã®ãå å«ã
ããã ãããã®ããã²ã³åéç²åã¯ãç²ç²ã®ãã®ã§ã
埮ç²ã®ãã®ã§ããããç²åŸã®ååžã¯çããŠãåºã
ãŠãããããŸãããããã®ããã²ã³åéç²åã®çµ
æ¶ã¯ãæ£åžžæ¶ãåæ¶ã§ãããã100é¢ãšïŒ»111
é¢ã®æ¯çã¯ä»»æã®ãã®ã䜿çšã§ãããæŽã«ããã
ãã®ããã²ã³åéç²åã®çµæ¶æ§é ã¯ãå éšããå€
éšãŸã§åäžãªãã®ã§ãã€ãŠããå éšãšå€éšãç°è³ª
ã®å±€ç¶æ§é ããããã®ã§ãã€ãŠãããããŸããã
ããã®ããã²ã³åéã¯æœåãäž»ãšããŠè¡šé¢ã«åœ¢æ
ããåã®ãã®ã§ããç²åå éšã«åœ¢æããåã®ãã®
ã§ãããããããã®ããã²ã³åéç²åã¯ãåœæ¥ç
ã«ãããŠæ £çšãããŠããå ¬ç¥ã®æ¹æ³ã«ãã€ãŠèª¿è£œ
ããããšãã§ããã æ¬çºæã«ãããŠçšããããããã²ã³åéä¹³å€ã¯
å¯æº¶æ§å¡©é¡ãé€å»ããã®ã奜ãŸããããæªé€å»ã®
ãã®ã䜿çšã§ããããŸããå¥ã ã«èª¿è£œããïŒçš®ä»¥
äžã®ããã²ã³åéä¹³å€ãæ··åããŠäœ¿çšããããšã
ã§ããã æ¬çºæã«ä¿ãããã²ã³åéä¹³å€å±€ã®ãã€ã³ããŒ
ãšããŠã¯ãåŸæ¥ç¥ããããã®ãçšããããäŸãã°
ãŒã©ãã³ãããšãã«ã«ã«ããã«åãŒã©ãã³ãã¢ã·
ã«åãŒã©ãã³ããã¿ã«åãŒã©ãã³çã®ãŒã©ãã³èª
å°äœçãããªããã«ã¢ã«ã³ãŒã«ãããªããã«ãã
ãªãã³ãããªã¢ã¯ãªã«é žã¢ããçã®é«ååéé»è§£
質ãã¢ã«ã®ã³é žå¡©ãããªã¢ã¯ãªã«é žå¡©çã®é žæ§é«
ååç©è³ªããããã³è»¢äœåå¿ã«ãã€ãŠåŠçããã
ãªã¢ã¯ãªã«ã¢ãããã¢ã¯ãªã«é žãšïŒ®âããã«ã€ã
ããŸãŒã«ã®å ±éåç©çã®é«ååäž¡æ§é»è§£è³ªãç±³åœ
ç¹èš±4215195å·ã«èšèŒã®æ¶æ©æ§ããªããŒçãæã
ããããååæ£ãããçæ°Žæ§é«ååç©è³ªãäŸãã°
ããªã¢ã¯ãªã«é žããã«ãšã¹ãã«ãããªã¢ã¯ãªã«é ž
ãšãã«ãšã¹ãã«çã®ã©ããã¯ã¹ãå«ãã§ããŠãã
ãããããã®ãã€ã³ããŒã¯å¿ èŠã«å¿ããŠïŒã€ä»¥äž
ã®çžæº¶æ§æ··åç©ãšããŠäœ¿çšããããšãã§ããã äžè¿°ã®ããã²ã³åéç²åããã€ã³ããŒæ¶²äžã«å
æ£ããããããã²ã³åéåçä¹³å€ã¯ãååŠå¢æå€
ã«ããå¢æããããšãã§ãããæ¬çºæã«ãããŠæ
å©ã«äœµçšããŠäœ¿çšã§ããååŠå¢æå€ã¯ã貎éå±å¢
æå€ãç¡«é»å¢æå€ãã»ã¬ã³å¢æå€åã³éå å¢æå€
ã®ïŒçš®ã«å€§å¥ãããã 貎éå±å¢æå€ãšããŠã¯ãéååç©ããã³ã«ãã
ãŠã ãããžãŠã ããã©ãžãŠã ãã€ãªãžãŠã ãçœé
ãªã©ã®ååç©ãçšããããšãã§ããã ãªããéååç©ã䜿çšãããšãã«ã¯æŽã«ã¢ã³ã¢
ããŠã ããªã·ã¢ããŒãããããªãŠã ããªã·ã¢ããŒ
ãã䜵çšããããšãã§ããã ç¡«é»å¢æå€ãšããŠã¯ã掻æ§ãŒã©ãã³ã®ã»ããç¡«
é»ååç©ãçšããããšãã§ããã ã»ã¬ã³å¢æå€ãšããŠã¯ã掻æ§åã³äžæŽ»æ§ã»ã¬ã³
ååç©ãçšããããšãã§ããã éå å¢æå€ã«ã¯ã第ïŒã¹ãºå¡©ãããªã¢ãã³ãã
ã¹ã¢ã«ãã«ã¢ããã¹ã«ãã€ããã·ã©ã³ååç©ãã€
ããã¢ããã¡ã¿ã³ã¹ã«ãã€ã³é žãããã©ãžããŠã
å¡©ãããã©ãžã³èªå°äœãããã ããã«åããã®ããã²ã³åéã¯ææã®æ³¢é·åã«
å åŠçã«å¢æããããšãã§ããäŸãã°ã¢ãã¡ãã³
è²çŽ ãããªã¡ãã³è²çŽ çã®ã·ã¢ãã³è²çŽ ãããã¯
ã¡ãã·ã¢ãã³è²çŽ çã®å åŠå¢æå€ã§åç¬ãããã¯
䜵çšããŠå åŠçã«å¢æããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã«ã¯ãåè¿°
ããæ·»å å€ä»¥å€ã«å®å®å€ãçŸåä¿é²å€ã硬èå€ã
çé¢æŽ»æ§å€ãæ±æé²æ¢å€ã最æ»å€ã玫å€ç·åžå
å€ããã«ããªã³ã¹ã«ãã³ãžã€ãŒãã®ä»åçæå æ
æã«æçšãªåçš®ã®æ·»å å€ãçšããããã æ¬çºæã®ããã²ã³åéåçæå ææã¯ããã²ã³
åéä¹³å€å±€ã®ä»ã«ä¿è·å±€ãäžéå±€ããã€ã«ã¿ãŒ
å±€ããã¬ãŒã·ãšã³é²æ¢å±€ããããã³ã°å±€çã®è£å©
å±€ãé©å®èšããããšãã§ããã æ¯æäœãšããŠã¯ãã©ã¹ããã¯ãã€ã«ã ããã©ã¹
ããã¯ã©ãããŒãçŽããã©ã€ã¿çŽãåæçŽãçåŸ
æ¥ç¥ããããã®ãåçæå ææã®äœ¿çšç®çã«å¿ã
ãŠé©å®éžæããã°ããããããã®æ¯æäœã¯äžè¬ã«
åçä¹³å€å±€ãšã®æ¥çã匷åããããã«äžåŒå å·¥ã
æœãããã ããããŠæ§æãããæ¬çºæã®ããã²ã³åéåç
æå ææã¯ãé²å ããåŸãçºè²çŸåããããã«
çš®ã ã®åçåŠçæ¹æ³ãçšãããããæ¬çºæã«çšã
ããã奜ãŸããçºè²çŸå液ã¯ãè³éŠæ第ïŒçŽã¢ã
ã³ç³»çºè²çŸåäž»è¬ãäž»æåãšãããã®ã§ãããã
ã®çºè²çŸåäž»è¬ã®å ·äœäŸãšããŠã¯ãïœâããšãã¬
ã³ãžã¢ãã³ç³»ã®ãã®ã代衚çã§ãããäŸãã°ãžãš
ãã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãã¢ãã¡ã
ã«âïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ããžã¡ãã«â
ïœâããšãã¬ã³ãžã¢ãã³å¡©é žå¡©ãïŒâã¢ããâïŒ
âãžãšãã«ã¢ãããã«ãšã³å¡©é žå¡©ãïŒâã¢ããâ
ïŒâïŒïŒ®âãšãã«ââããã·ã«ã¢ããïŒâãã«ãš
ã³ãïŒâã¢ããâïŒâïŒïŒ®âãšãã«ââβâã¡
ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒã¢ãããã«ãšã³ç¡«é ž
å¡©ãïŒâïŒïŒ®âãšãã«ââβâã¡ã¿ã³ã¹ã«ãã³
ã¢ãããšãã«ã¢ããïŒã¢ããªã³ãïŒâïŒïŒ®âãšã
ã«ââβâããããã·ãšãã«ã¢ããïŒã¢ããª
ã³ãïŒâã¢ããâïŒâïŒïŒ®âãšãã«âβâã¡ãã
ã·ãšãã«ïŒã¢ãããã«ãšã³çãæããããããã
ãã®çºè²çŸåäž»è¬ã¯åç¬ã§ãããã¯ïŒçš®ä»¥äžã䜵
çšããŠããŸãå¿ èŠã«å¿ããŠçœé»çŸåäž»è¬ãäŸãã°
ãã€ããããã³ãããšããã³çãšäœµçšããŠçšãã
ãããæŽã«çºè²çŸå液ã¯ãäžè¬ã«ã¢ã«ã«ãªå€ãäŸ
ãã°æ°Žé žåãããªãŠã ãæ°Žé žåã¢ã³ã¢ããŠã ãç
é žãããªãŠã ãäºç¡«é žãããªãŠã çãå«ã¿ãæŽã«
çš®ã ã®æ·»å å€äŸãã°ããã²ã³åã¢ã«ã«ãªéå±äŸã
ã°èåã«ãªãŠã ããããã¯çŸå調ç¯å€äŸãã°ã·ã
ã©ãžã³é žçãå«æããŠãè¯ãã æ¬çºæã®ããã²ã³åéåçæå ææã¯ã芪氎æ§
ã³ãã€ãå±€äžã«ãåèšã®çºè²çŸåäž»è¬ããçºè²çŸ
åäž»è¬ãã®ãã®ãšããŠããããã¯ããã®ãã¬ã«ãŒ
ãµãŒãšããŠå«æããŠããŠããããçºè²çŸåäž»è¬ã
ã¬ã«ãŒãµãŒã¯ãã¢ã«ã«ãªæ§æ¡ä»¶äžãçºè²çŸåäž»è¬
ãçæãããååç©ã§ãããè³éŠæã¢ã«ãããèª
å°äœãšã®ã·ããããŒã¹åãã¬ã«ãŒãµãŒãå€äŸ¡éå±
ã€ãªã³é¯äœãã¬ã«ãŒãµãŒããã¿ã«é žã€ããèªå°äœ
ãã¬ã«ãŒãµãŒããªã³é žã¢ããèªå°äœãã¬ã«ãŒãµ
ãŒãã·ãŠã¬ãŒã¢ãã³åå¿ç©ãã¬ã«ãŒãµãŒããŠã¬ã¿
ã³åãã¬ã«ãŒãµãŒãæããããããããè³éŠæ第
ïŒçŽã¢ãã³çºè²çŸåäž»è¬ã®ãã¬ã«ãŒãµãŒã¯ãäŸã
ã°ç±³åœç¹èš±ç¬¬3342599å·ãå第2507114å·ãå第
2695234å·ãå第3719492å·ãè±åœç¹èš±ç¬¬803783å·
æ现æžãç¹éæ53â135628å·ãå54â79035å·ã®
åå ¬å ±ããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒèª15159
å·ãå12146å·ãå13924å·ã«èšèŒãããŠããã ãããã®è³éŠæ第ïŒçŽã¢ãã³çºè²çŸåäž»è¬åã¯
ãã®ãã¬ã«ãŒãµãŒã¯ãçŸååŠçããéã«ååãªçº
è²ãåŸãããéãæ·»å ããŠããå¿ èŠãããããã®
éã¯æå ææã®çš®é¡çã«ãã€ãŠå€§åç°ãªãããã
ãããæå æ§ããã²ã³åéïŒã¢ã«åœã0.1ã¢ã«ã
ãïŒã¢ã«ã®éã奜ãŸããã¯0.5ã¢ã«ããïŒã¢ã«ã®
ç¯å²ã§çšããããããããã®çºè²çŸåäž»è¬ãŸãã¯
ãã®ãã¬ã«ãŒãµãŒã¯ãåç¬ã§ãŸãã¯ãçµåããŠçš
ããããšãã§ããããããã®çŸåäž»è¬ãŸãã¯ãã®
ãã¬ã«ãŒãµãŒçã®æ·»å å€ãåçæå ææäžã«å èµ
ããã«ã¯ãæ°Žãã¡ã¿ããŒã«ããšã¿ããŒã«ãã¢ã»ã
ã³çã®é©åœãªæº¶åªã«æº¶è§£ããŠå ããããšãã§ãã
åããžããã«ãã¿ã¬ãŒãããžãªã¯ãã«ãã¿ã¬ãŒ
ããããªã¯ã¬ãžã«ããªã¹ããšãŒãçã®é«æ²žç¹ææ©
溶åªãçšããä¹³ååæ£æ¶²ãšããŠå ããããšãã§
ãããªãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒèª14850å·ã«
èšèŒãããŠããããã«ãã©ããã¯ã¹ããªããŒã«å«
浞ãããŠæ·»å ããããšãã§ããã æ¬çºæã®ããã²ã³åéåçæå ææã«ã¯éåžžã
çºè²çŸååŸã«æŒçœããã³å®çããŸãã¯æŒçœå®çã
ãªãã³ã«æ°ŽæŽãè¡ãªããããæŒçœå€ãšããŠã¯ãå€
ãã®ååç©ãçšããããããäžã§ãéïŒïŒãã³
ãã«ãïŒïŒãé«ïŒïŒããªã©å€äŸ¡éå±ååç©ããš
ãããããããã®å€äŸ¡éå±ã«ããªã³ãšææ©é žã®é¯
å¡©ãäŸãã°ããšãã¬ã³ãžã¢ãã³åé ¢é žããããªã
äžé ¢é žãâããããã·ãšãã«ãšãã¬ã³ãžã¢ãã³
äºé ¢é žã®ãããªã¢ããããªã«ã«ãã³é žãããã³
é žãé ç³é žããªã³ãŽé žããžã°ãªã³ãŒã«é žããžããª
ã°ãªã³ãŒã«é žãªã©ã®éå±é¯å¡©ãããã¯ããšãªã·ã¢
ã³é žå¡©é¡ãéã¯ãã é žå¡©ãªã©ãåç¬ãŸãã¯é©åœãª
çµåããã§çšããããã 以äžã«å®æœäŸãæããŠæ¬çºæãæŽã«å ·äœçã«èš
èŒããã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®æº¶æ¶²éåã«ããããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹(A)ïŒ(B)ïŒ(D)ïŒ(F)ããã³
ïŒïŒ§ïŒãªãã³ã«äžèšã®æ¯èŒçšããªããŒã«ãã©ãŒã®
ã©ããã¯ã¹(1)ïŒ(2)ããã³(3)溶液ã®åã ããŒã³ã¿è²
çŽ åœ¢æã«ãã©ãŒéšäœãïŒÃ10-3ã¢ã«å«ãéãæ²è
åéïŒÃ10-2ã¢ã«ããã³ãŒã©ãã³10ïœãå«ãé«æ
床æ²èåéä¹³å€100ïœã«æ·»å ããããªã¢ã»ããŒã
ãã€ã«ã æ¯æäœäžã«2.4ïœïŒm2ã®å¡åžéã§å¡åžãã
也ç¥ããŠå®å®ãªå¡èãæããæå ææã®è©Šæ(1)ã
(8)ãäœæããã ïŒæ¯èŒçšããªããŒã«ãã©ãŒïŒ äžèšã«ããäœæãããåè©Šæãéåžžã®æ¹æ³ã§ã
ããããŠãšããžé²å ããåŸãäžèšã®çŸååŠçãè¡
ã€ãã åŠçå·¥çšïŒ38âïŒ åŠçæé çºè²çŸå ïŒå15ç§ æŒ çœ ïŒå30ç§ æ°Ž æŽ ïŒå15ç§ å® ç ïŒå30ç§ æ°Ž æŽ ïŒå15ç§ å®å®æµŽ ïŒå30ç§ ååŠçå·¥çšã«ãããŠäœ¿çšããåŠç液çµæã¯äžèš
ã®åŠãã§ãã€ãã çºè²çŸå液çµæ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡© 4.75ïœ ç¡æ°Žäºç¡«é žãããªãŠã 4.25ïœ ããããã·ã¢ãã³ïŒïŒïŒç¡«é žå¡© 2.0ïœ ç¡æ°Žçé žã«ãªãŠã 37.5ïœ èåãããªãŠã 1.3ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
2.5ïœ æ°Žé žåã«ãªãŠã 1.0ïœ æ°Žãå ããŠïŒãšãæ°Žé žåã«ãªãŠã ãçšããŠPH
10.0ã«èª¿æŽããã æŒçœæ¶²çµæ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°· é ¢ é ž 10.0ml æ°Žãå ããŠïŒãšãã¢ã³ã¢ãã¢æ°ŽãçšããŠPH
6.0ã«èª¿æŽããã å®ç液çµæ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ50ïŒ æ°Žæº¶æ¶²ïŒ 162ml ç¡æ°Žäºç¡«é žãããªãŠã 12.4ïœ æ°Žãå ããŠïŒãšãé ¢é žãçšããŠPH6.5ã«èª¿æŽ
ããã å®å®å液çµæ ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 5.0ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã åŸãããããŒã³ã¿è²ç»åã®æ¿åºŠãããŒã³ã¿ãã€
ã«ã¿ãŒãéãæ¿åºŠæž¬å®ããã«ããªãçžå¯Ÿæ床ãã
ã³æé«æ¿åºŠãç®åºããåŸãããçµæãäžèšç¬¬ïŒè¡š
ã«ç€ºããã è¡šã«ãããçžå¯Ÿæ床ã¯ã«ããªïŒ0.2ã®æ¿åºŠãåŸ
ãã®ã«èŠããé²å éã®éæ°ã®çžå¯Ÿå€ã§ããã
ãè¡šã
äžèšè¡šãããæãããªããã«ãæ¬çºæã«ä¿ãã
ããªããŒããŒã³ã¿ã«ãã©ãŒã®ã©ããã¯ã¹ãçšãã
è©ŠæïŒãïŒã¯äœããæ¯èŒçšããªããŒã«ãã©ãŒãçš
ããè©ŠæïŒãïŒã«æ¯ã¹ãŠçºè²æ§ã«åªããã«ããªã®
çºçãå°ãªãããšãããã€ãã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®ä¹³åéåã«ããããªããŒ
ããŒã³ã¿ã«ãã©ãŒã®ã©ããã¯ã¹ïŒAâ²ïŒïŒïŒBâ²ïŒïŒ
ïŒDâ²ïŒããã³ïŒFâ²ïŒãªãã³ã«äžèšã®æ¯èŒçšããªã
ãŒã«ãã©ãŒ(4)ïŒ(5)ããã³(6)溶液ã®åã ããŒã³ã¿è²
çŽ åœ¢æã«ãã©ãŒéšäœãïŒÃ10-3ã¢ã«å«ãéãå®æœ
äŸïŒãšåæ§ã«æ²èåéïŒÃ10-2ã¢ã«ããã³ãŒã©ã
ã³10ïœãå«ãé«æ床æ²èåéä¹³å€100ïœã«æ·»å ãã
ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«2.4ïœïŒm2ã®
å¡åžéã§å¡åžã也ç¥ããŠå®å®ãªå¡èãæããæå
ææã®è©ŠæïŒã15ãäœæããã ïŒæ¯èŒçšããªããŒããŒã³ã¿ã«ãã©ãŒïŒ äžèšã«ããäœæãããåè©Šæãå®æœäŸïŒãšåæ§
ã®é²å ããã³åŠçæ¹æ³ã§çŸååŠçããåŸãããçµ
æãäžèšç¬¬ïŒè¡šã«ç€ºããã
ããªããŒããŒã³ã¿ã«ãã©ãŒã®ã©ããã¯ã¹ãçšãã
è©ŠæïŒãïŒã¯äœããæ¯èŒçšããªããŒã«ãã©ãŒãçš
ããè©ŠæïŒãïŒã«æ¯ã¹ãŠçºè²æ§ã«åªããã«ããªã®
çºçãå°ãªãããšãããã€ãã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®ä¹³åéåã«ããããªããŒ
ããŒã³ã¿ã«ãã©ãŒã®ã©ããã¯ã¹ïŒAâ²ïŒïŒïŒBâ²ïŒïŒ
ïŒDâ²ïŒããã³ïŒFâ²ïŒãªãã³ã«äžèšã®æ¯èŒçšããªã
ãŒã«ãã©ãŒ(4)ïŒ(5)ããã³(6)溶液ã®åã ããŒã³ã¿è²
çŽ åœ¢æã«ãã©ãŒéšäœãïŒÃ10-3ã¢ã«å«ãéãå®æœ
äŸïŒãšåæ§ã«æ²èåéïŒÃ10-2ã¢ã«ããã³ãŒã©ã
ã³10ïœãå«ãé«æ床æ²èåéä¹³å€100ïœã«æ·»å ãã
ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«2.4ïœïŒm2ã®
å¡åžéã§å¡åžã也ç¥ããŠå®å®ãªå¡èãæããæå
ææã®è©ŠæïŒã15ãäœæããã ïŒæ¯èŒçšããªããŒããŒã³ã¿ã«ãã©ãŒïŒ äžèšã«ããäœæãããåè©Šæãå®æœäŸïŒãšåæ§
ã®é²å ããã³åŠçæ¹æ³ã§çŸååŠçããåŸãããçµ
æãäžèšç¬¬ïŒè¡šã«ç€ºããã
ãè¡šã
äžèšè¡šã«ããæãããªããã«æ¬çºæã«ä¿ããã
ãªããŒããŒã³ã¿ã«ãã©ãŒã®ã©ããã¯ã¹ãçšããè©Š
æïŒã12ã¯äœããæ¯èŒçšããªããŒã«ãã©ãŒãçšã
ãè©Šæ13ã15ã«æ¯ã¹ãŠçºè²æ§ã«åªãããã€ã«ããª
ã®çºçãå°ãªãããšããããã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®æº¶æ¶²éåã«ããããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹(A)ïŒ(B)ïŒ(D)ïŒ(F)ããã³
ïŒïŒ§ïŒãªãã³ã«å®æœäŸïŒã«ãŠçšããããæ¯èŒçšã®
ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(1)ïŒ(2)ããã³(3)溶
液ã®åã ããŒã³ã¿è²çŽ 圢æã«ãã©ãŒéšäœã7.5Ã
10-3ã¢ã«å«ãéãå¡©èåéïŒÃ10-2ã¢ã«ãšãŒã©ã
ã³10ïœãå«ãä¹³å€100ïœãšãæ··åãã硬èå€ãšã
ãŠïŒâããããã·âïŒïŒïŒâãžã¯ããâïœâããª
ã¢ãžã³ãããªãŠã ïŒïŒ 氎溶液10mlãå ããããªãš
ãã¬ã³ã§ã¬ãžã³ã³ãŒãããæ¯æäœäžã«å¡åžãã也
ç¥ããŠã«ã©ãŒæå ææã®è©Šæ16ã23ãäœæããã
åè©Šæã®å¡åžééã¯0.5ïœïŒm2ã§ãã€ãã ãããã®åè©Šæãéåžžã®æ¹æ³ã§ãŠãšããžé²å
ããäžèšã®å·¥çšããã³åŠçåŠæ¹ã«åŸã€ãŠåŠçã
ãã åŠçå·¥çš åŠçæé ã«ã©ãŒçŸå ïŒå30ç§ æŒçœå®ç ïŒå30ç§ æ°Ž æŽ ïŒåïŒç§ ã«ã©ãŒåççšçŸå液 ãã³ãžã«ã¢ã«ã³ãŒã« 15.0ml ãããµã¡ã¿ãªã³é žãããªãŠã 2.50ïœ ç¡æ°Žäºç¡«é žãããªãŠã 1.85ïœ èåã«ãªãŠã 0.60ïœ ããŠç ïŒNa2B4O7ã»10H2ïŒ¯ïŒ 39.10ïœ ïŒ®âãšãã«ââïŒâïŒã¡ã¿ã³ã¹ã«ãã³ã¢ãã
ãšãã«ïŒïŒœâïŒâã¡ãã«âïŒâ㢠ããã¢ããªã³ç¡«
é žå¡© 5.00ïœ æ°Žãå ããŠïŒã«ä»äžããæ°Žé žåãããªãŠã ã§
PH10.3ã«èª¿æŽããã æŒçœå®ç液 ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã
61.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žâïŒâã¢ã³ã¢ããŠ
ã 5.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 124.5ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13.3ïœ äºç¡«é žãããªãŠã 2.7ïœ æ°Žãå ããŠïŒã«ä»äžããPHã6.5ã«èª¿æŽããã äžèšã«ããåŠçãè¡ã€ãåŸãå®æœäŸïŒãšåæ§ã«
ããŒã³ã¿è²ç»åã®æ¿åºŠã枬å®ããåŸãããçµæã
äžèšç¬¬ïŒè¡šã«ç€ºããã
ãªããŒããŒã³ã¿ã«ãã©ãŒã®ã©ããã¯ã¹ãçšããè©Š
æïŒã12ã¯äœããæ¯èŒçšããªããŒã«ãã©ãŒãçšã
ãè©Šæ13ã15ã«æ¯ã¹ãŠçºè²æ§ã«åªãããã€ã«ããª
ã®çºçãå°ãªãããšããããã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®æº¶æ¶²éåã«ããããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹(A)ïŒ(B)ïŒ(D)ïŒ(F)ããã³
ïŒïŒ§ïŒãªãã³ã«å®æœäŸïŒã«ãŠçšããããæ¯èŒçšã®
ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(1)ïŒ(2)ããã³(3)溶
液ã®åã ããŒã³ã¿è²çŽ 圢æã«ãã©ãŒéšäœã7.5Ã
10-3ã¢ã«å«ãéãå¡©èåéïŒÃ10-2ã¢ã«ãšãŒã©ã
ã³10ïœãå«ãä¹³å€100ïœãšãæ··åãã硬èå€ãšã
ãŠïŒâããããã·âïŒïŒïŒâãžã¯ããâïœâããª
ã¢ãžã³ãããªãŠã ïŒïŒ 氎溶液10mlãå ããããªãš
ãã¬ã³ã§ã¬ãžã³ã³ãŒãããæ¯æäœäžã«å¡åžãã也
ç¥ããŠã«ã©ãŒæå ææã®è©Šæ16ã23ãäœæããã
åè©Šæã®å¡åžééã¯0.5ïœïŒm2ã§ãã€ãã ãããã®åè©Šæãéåžžã®æ¹æ³ã§ãŠãšããžé²å
ããäžèšã®å·¥çšããã³åŠçåŠæ¹ã«åŸã€ãŠåŠçã
ãã åŠçå·¥çš åŠçæé ã«ã©ãŒçŸå ïŒå30ç§ æŒçœå®ç ïŒå30ç§ æ°Ž æŽ ïŒåïŒç§ ã«ã©ãŒåççšçŸå液 ãã³ãžã«ã¢ã«ã³ãŒã« 15.0ml ãããµã¡ã¿ãªã³é žãããªãŠã 2.50ïœ ç¡æ°Žäºç¡«é žãããªãŠã 1.85ïœ èåã«ãªãŠã 0.60ïœ ããŠç ïŒNa2B4O7ã»10H2ïŒ¯ïŒ 39.10ïœ ïŒ®âãšãã«ââïŒâïŒã¡ã¿ã³ã¹ã«ãã³ã¢ãã
ãšãã«ïŒïŒœâïŒâã¡ãã«âïŒâ㢠ããã¢ããªã³ç¡«
é žå¡© 5.00ïœ æ°Žãå ããŠïŒã«ä»äžããæ°Žé žåãããªãŠã ã§
PH10.3ã«èª¿æŽããã æŒçœå®ç液 ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã
61.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žâïŒâã¢ã³ã¢ããŠ
ã 5.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 124.5ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13.3ïœ äºç¡«é žãããªãŠã 2.7ïœ æ°Žãå ããŠïŒã«ä»äžããPHã6.5ã«èª¿æŽããã äžèšã«ããåŠçãè¡ã€ãåŸãå®æœäŸïŒãšåæ§ã«
ããŒã³ã¿è²ç»åã®æ¿åºŠã枬å®ããåŸãããçµæã
äžèšç¬¬ïŒè¡šã«ç€ºããã
ãè¡šã
äžèšè¡šãããæãããªããã«ãæ¬çºæã«ä¿ãã
ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãçšããè©Šæ16ã
20ã¯ãæ¯èŒçšã®ããªããŒã®ã©ããã¯ã¹ãçšããè©Š
æ21ã23ã«æ¯ã¹ãŠãçºè²æ§ã«åªãããã€ã«ããªã®
çºçãå°ãªãããšãããã€ãã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®ä¹³åéåã«ããããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ïŒAâ²ïŒïŒïŒBâ²ïŒïŒïŒDâ²ïŒïŒïŒF
â²ïŒ
ãªãã³ã«å®æœäŸïŒã«ãããŠçšããããæ¯èŒçšããª
ããŒã«ãã©ãŒã®ã©ããã¯ã¹(4)ïŒ(5)ïŒ(6)溶液ã®åã
ã®ããŒã³ã¿è²çŽ 圢æã«ãã©ãŒéšäœã7.5Ã10-3ã¢
ã«å«ãéãããã²ã³åéïŒÃ10-2ã¢ã«ãšãŒã©ãã³
10ïœãå«ãä¹³å€100ïœãšæ··åãã硬èå€ãšããŠïŒ
âããããã·âïŒïŒïŒâãžã¯ããâïœâããªã¢ãž
ã³ãããªãŠã ã®ïŒïŒ 氎溶液10mlãå ããããªãšã
ã¬ã³ã§ã¬ã³ãžã³ãŒãããæ¯æäœäžã«å¡åžãã也ç¥
ããŠã«ã©ãŒæå ææã補ããè©Šæ24ã30ãšããã
åè©Šæã®å¡åžééã¯0.5ïœïŒm2ã§ãã€ãã åè©Šæãéåžžã®æ¹æ³ã§ãŠãšããžé²å ããå®æœäŸ
ïŒãšåæ§ã«çŸååŠçãããåŸãããããŒã³ã¿è²ç»
åã«ã€ããŠåèšåå®æœäŸãšåæ§ã«æ¿åºŠã枬å®ãã
ãã®çµæãäžèšç¬¬ïŒè¡šã«ç€ºããã
ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãçšããè©Šæ16ã
20ã¯ãæ¯èŒçšã®ããªããŒã®ã©ããã¯ã¹ãçšããè©Š
æ21ã23ã«æ¯ã¹ãŠãçºè²æ§ã«åªãããã€ã«ããªã®
çºçãå°ãªãããšãããã€ãã å®æœäŸ ïŒ æ¬çºæã«ä¿ããåèšã®ä¹³åéåã«ããããªããŒ
ã«ãã©ãŒã®ã©ããã¯ã¹ïŒAâ²ïŒïŒïŒBâ²ïŒïŒïŒDâ²ïŒïŒïŒF
â²ïŒ
ãªãã³ã«å®æœäŸïŒã«ãããŠçšããããæ¯èŒçšããª
ããŒã«ãã©ãŒã®ã©ããã¯ã¹(4)ïŒ(5)ïŒ(6)溶液ã®åã
ã®ããŒã³ã¿è²çŽ 圢æã«ãã©ãŒéšäœã7.5Ã10-3ã¢
ã«å«ãéãããã²ã³åéïŒÃ10-2ã¢ã«ãšãŒã©ãã³
10ïœãå«ãä¹³å€100ïœãšæ··åãã硬èå€ãšããŠïŒ
âããããã·âïŒïŒïŒâãžã¯ããâïœâããªã¢ãž
ã³ãããªãŠã ã®ïŒïŒ 氎溶液10mlãå ããããªãšã
ã¬ã³ã§ã¬ã³ãžã³ãŒãããæ¯æäœäžã«å¡åžãã也ç¥
ããŠã«ã©ãŒæå ææã補ããè©Šæ24ã30ãšããã
åè©Šæã®å¡åžééã¯0.5ïœïŒm2ã§ãã€ãã åè©Šæãéåžžã®æ¹æ³ã§ãŠãšããžé²å ããå®æœäŸ
ïŒãšåæ§ã«çŸååŠçãããåŸãããããŒã³ã¿è²ç»
åã«ã€ããŠåèšåå®æœäŸãšåæ§ã«æ¿åºŠã枬å®ãã
ãã®çµæãäžèšç¬¬ïŒè¡šã«ç€ºããã
ãè¡šã
äžèšã®è¡šããåèšåå®æœäŸãšåæ§ã«æ¬çºæã«ä¿
ããããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãçšããè©Šæ
ã¯çºè²æ§ã«åªãã«ããªãå°ãªãè¯å¥œãªåçç¹æ§ã
æã€ãã®ã§ããããšãããã€ãã å®æœäŸ ïŒ æ¬çºæã®ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(A)ïŒ
(B)ïŒ(F)ïŒïŒAâ²ïŒïŒïŒBâ²ïŒããã³ïŒFâ²ïŒãªãã³ã«å
èš
ã®æ¯èŒçšããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(1)ïŒ(2)ïŒ
(4)ïŒ(5)溶液ã®åã ã®ã«ãã©ãŒéšäœã7.5Ã10-3ã¢
ã«å«ãã©ããã¯ã¹æ¶²ãš8.4Ã10-2ã¢ã«ã®æ²èåé
ããã³ãŒã©ãã³10ïœãå«ãä¹³å€100ïœãæ··åãã
ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«å¡åžãã也ç¥
ããŠæå ææã®è©Šæ31ã40ãåŸãã äžèšåè©Šæãéåžžã®æ¹æ³ã§ãããããŠãšããžé²
å ããã®ã¡äžèšã®çŸååŠçãè¡ãªã€ãã åŠçå·¥çšïŒ38âïŒ åŠçæé 第ïŒçŸå ïŒå 第ïŒæ°ŽæŽ ïŒå å 転 ïŒå çºè²çŸå ïŒå 調 æŽ ïŒå æŒ çœ ïŒå å® ç ïŒå æçµæ°ŽæŽ ïŒå å®å®å 30ç§ ååŠçå·¥çšã«çšããåŠç液ã®çµæã¯æ¬¡ã®éãã§
ããã 第ïŒçŸå液
ããããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ãçšããè©Šæ
ã¯çºè²æ§ã«åªãã«ããªãå°ãªãè¯å¥œãªåçç¹æ§ã
æã€ãã®ã§ããããšãããã€ãã å®æœäŸ ïŒ æ¬çºæã®ããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(A)ïŒ
(B)ïŒ(F)ïŒïŒAâ²ïŒïŒïŒBâ²ïŒããã³ïŒFâ²ïŒãªãã³ã«å
èš
ã®æ¯èŒçšããªããŒã«ãã©ãŒã®ã©ããã¯ã¹(1)ïŒ(2)ïŒ
(4)ïŒ(5)溶液ã®åã ã®ã«ãã©ãŒéšäœã7.5Ã10-3ã¢
ã«å«ãã©ããã¯ã¹æ¶²ãš8.4Ã10-2ã¢ã«ã®æ²èåé
ããã³ãŒã©ãã³10ïœãå«ãä¹³å€100ïœãæ··åãã
ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«å¡åžãã也ç¥
ããŠæå ææã®è©Šæ31ã40ãåŸãã äžèšåè©Šæãéåžžã®æ¹æ³ã§ãããããŠãšããžé²
å ããã®ã¡äžèšã®çŸååŠçãè¡ãªã€ãã åŠçå·¥çšïŒ38âïŒ åŠçæé 第ïŒçŸå ïŒå 第ïŒæ°ŽæŽ ïŒå å 転 ïŒå çºè²çŸå ïŒå 調 æŽ ïŒå æŒ çœ ïŒå å® ç ïŒå æçµæ°ŽæŽ ïŒå å®å®å 30ç§ ååŠçå·¥çšã«çšããåŠç液ã®çµæã¯æ¬¡ã®éãã§
ããã 第ïŒçŸå液
ãè¡šã
å転液
ããããªã³é
ž 12.0ml
ç¡æ°Žå¡©å第äžé« 1.5ïœ
ãã©ã¢ããããšããŒã« 0.5mg
æ°Žé
žåãããªãŠã 5.0ïœ
ãããªãâïŒïŒ®ïŒïŒ®âããªã¡ãã¬ã³ãã¹ãã³
é žïŒâãããªãŠã 氎溶液ïŒ45ïŒ ïŒ 15.0ml æ°Žã§ïŒã«ä»äžããã PHã5.8ã«èª¿æŽããã çºè²çŸå液
é žïŒâãããªãŠã 氎溶液ïŒ45ïŒ ïŒ 15.0ml æ°Žã§ïŒã«ä»äžããã PHã5.8ã«èª¿æŽããã çºè²çŸå液
ãè¡šã
調æŽæ¶²ïŒœ
äºç¡«é
žã«ãªãŠã 15.0ïœ
ãšãã¬ã³ãžã¢ãã³åé
¢é
ž 8.0ïœ
αâã¢ãããªã°ãªã»ããŒã« 0.5ml
æ°Žã§ïŒã«ä»äžããã
PHã6.2ã«èª¿æŽããã
æŒçœæ¶²ïŒœ
ç¡é
žã«ãªãŠã 25.0ïœ
èåã«ãªãŠã 80.0ïœ
ãšãã¬ã³ãžã¢ãã³åé
¢é
žéïŒïŒã¢ã³ã¢ããŠã
110.0ïœ èåæ°ŽçŽ é žïŒ48ïŒ ïŒ 30.0ml ãšãã¬ã³ãžã¢ãã³åé ¢é ž 4.0ïœ æ°Žã§ïŒã«ä»äžããã PHã5.7ã«èª¿æŽããã å®ç液 ããªç¡«é žã¢ã³ã¢ããŠã 55.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žâïŒâãããªãŠã
0.8ïœ ã¡ã¿éäºé žãããªãŠã 7.5ïœ æ°Žé žåãããªãŠã 1.5ïœ æ°Žã§ïŒã«ä»äžããã PHã6.6ã«èª¿æŽããã å®å®æ¶²ïŒœ ãã«ããªã³ïŒ35ïŒ ïŒ 6.0ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žã§ïŒã«ä»äžããã äžèšã«ããåŠçãããåè©Šæã¯åèšå®æœäŸãšå
æ§ã«æ¿åºŠã枬å®ããåŸãããçµæãäžèšç¬¬ïŒè¡šã«
瀺ããã
110.0ïœ èåæ°ŽçŽ é žïŒ48ïŒ ïŒ 30.0ml ãšãã¬ã³ãžã¢ãã³åé ¢é ž 4.0ïœ æ°Žã§ïŒã«ä»äžããã PHã5.7ã«èª¿æŽããã å®ç液 ããªç¡«é žã¢ã³ã¢ããŠã 55.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žâïŒâãããªãŠã
0.8ïœ ã¡ã¿éäºé žãããªãŠã 7.5ïœ æ°Žé žåãããªãŠã 1.5ïœ æ°Žã§ïŒã«ä»äžããã PHã6.6ã«èª¿æŽããã å®å®æ¶²ïŒœ ãã«ããªã³ïŒ35ïŒ ïŒ 6.0ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žã§ïŒã«ä»äžããã äžèšã«ããåŠçãããåè©Šæã¯åèšå®æœäŸãšå
æ§ã«æ¿åºŠã枬å®ããåŸãããçµæãäžèšç¬¬ïŒè¡šã«
瀺ããã
ãè¡šã
äžèšè¡šã®çµæããæ¬çºæã«ä¿ããããªããŒã«ã
ã©ãŒã®ã©ããã¯ã¹ãçšããè©Šæã¯ãå転åŠçãè¡
ã€ãå Žåã§ãæ¯èŒçšããªããŒã«ãã©ãŒãçšããè©Š
æã«æ¯ã¹ãŠçºè²æ§ã«åªããã«ããªã®çºçãå°ãªã
åªããåçç¹æ§ãæããããšããããã çºæã®å¹æ æ¬çºæã«ããããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã
å«æããæå ææã¯ãçºè²æ§ã«åªããã«ããªãå°
ãªãåªããåçç¹æ§ãæãããã®ã§ããã
ã©ãŒã®ã©ããã¯ã¹ãçšããè©Šæã¯ãå転åŠçãè¡
ã€ãå Žåã§ãæ¯èŒçšããªããŒã«ãã©ãŒãçšããè©Š
æã«æ¯ã¹ãŠçºè²æ§ã«åªããã«ããªã®çºçãå°ãªã
åªããåçç¹æ§ãæããããšããããã çºæã®å¹æ æ¬çºæã«ããããªããŒã«ãã©ãŒã®ã©ããã¯ã¹ã
å«æããæå ææã¯ãçºè²æ§ã«åªããã«ããªãå°
ãªãåªããåçç¹æ§ãæãããã®ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«ãäžèšäžè¬åŒïŒ»ïŒœã§ç€ºãããç¹°
è¿ãåäœãæããããŒã³ã¿è²çŽ 圢ææ§ããªããŒã«
ãã©ãŒãå«æããããã²ã³åéä¹³å€å±€ãæããã
ãã²ã³åéã«ã©ãŒåçæå ææã äžè¬åŒïŒ»ïŒœ åŒäžãArã¯ã¢ãªãŒã«åºãŸãã¯è€çŽ ç°åºãè¡š
ãããã¯ãšãã¬ã³æ§äžé£œååºãŸãã¯ãšãã¬ã³æ§
äžé£œååºãæããåºãè¡šãããã¯æ°ŽçŽ ååãŸã
ã¯çºè²çŸåäž»è¬ã®é žåäœãšã®ã«ãããªã³ã°åå¿ã«
ããé¢è±å¯èœãªåºãè¡šããã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16001883A JPS6050534A (ja) | 1983-08-30 | 1983-08-30 | ããã²ã³åéã«ã©âåçæå ææ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16001883A JPS6050534A (ja) | 1983-08-30 | 1983-08-30 | ããã²ã³åéã«ã©âåçæå ææ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6050534A JPS6050534A (ja) | 1985-03-20 |
JPH0511302B2 true JPH0511302B2 (ja) | 1993-02-15 |
Family
ID=15706194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP16001883A Granted JPS6050534A (ja) | 1983-08-30 | 1983-08-30 | ããã²ã³åéã«ã©âåçæå ææ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6050534A (ja) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6023856A (ja) * | 1983-07-20 | 1985-02-06 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âæå ææ |
-
1983
- 1983-08-30 JP JP16001883A patent/JPS6050534A/ja active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6023856A (ja) * | 1983-07-20 | 1985-02-06 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âæå ææ |
Also Published As
Publication number | Publication date |
---|---|
JPS6050534A (ja) | 1985-03-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4409320A (en) | Silver halide color photographic light-sensitive material | |
US4388404A (en) | Silver halide color photographic light-sensitive material | |
US4474870A (en) | Silver halide color photographic light-sensitive material | |
JPH02217842A (ja) | ããã²ã³åéåçæå ææ | |
US4436808A (en) | Silver halide color photographic light-sensitive material | |
JPH0642059B2 (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPS6350691B2 (ja) | ||
JPS6135444A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
US4576911A (en) | Silver halide color photographic light-sensitive material | |
JPH0511302B2 (ja) | ||
JPS61204631A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPS6060646A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPH0322972B2 (ja) | ||
JPH0574814B2 (ja) | ||
JPS6039646A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPS615249A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPS6139044A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPH0523426B2 (ja) | ||
JPS6055341A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPS6053953A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPS60191254A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPH0574811B2 (ja) | ||
JPS619651A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPH0369088B2 (ja) | ||
JPS60225845A (ja) | ããã²ã³åéåçæå ææ |