JPH0456061B2 - - Google Patents
Info
- Publication number
- JPH0456061B2 JPH0456061B2 JP62065462A JP6546287A JPH0456061B2 JP H0456061 B2 JPH0456061 B2 JP H0456061B2 JP 62065462 A JP62065462 A JP 62065462A JP 6546287 A JP6546287 A JP 6546287A JP H0456061 B2 JPH0456061 B2 JP H0456061B2
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- weight
- modified polystyrene
- butadiene
- gloss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002245 particle Substances 0.000 claims description 62
- 239000004793 Polystyrene Substances 0.000 claims description 36
- 229920002223 polystyrene Polymers 0.000 claims description 36
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 34
- 229920001971 elastomer Polymers 0.000 claims description 26
- 239000005060 rubber Substances 0.000 claims description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 23
- 229920001400 block copolymer Polymers 0.000 claims description 15
- 239000011342 resin composition Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 8
- 229920005990 polystyrene resin Polymers 0.000 claims description 7
- 239000002775 capsule Substances 0.000 claims description 4
- 210000003850 cellular structure Anatomy 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 2
- 230000007423 decrease Effects 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- 239000005062 Polybutadiene Substances 0.000 description 6
- 229920002857 polybutadiene Polymers 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- 238000004898 kneading Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920005669 high impact polystyrene Polymers 0.000 description 2
- 239000004797 high-impact polystyrene Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 229920000428 triblock copolymer Polymers 0.000 description 2
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 239000005063 High cis polybutadiene Substances 0.000 description 1
- 239000005064 Low cis polybutadiene Substances 0.000 description 1
- 101100208721 Mus musculus Usp5 gene Proteins 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- UREWAKSZTRITCZ-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 UREWAKSZTRITCZ-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 235000019646 color tone Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- MMSLOZQEMPDGPI-UHFFFAOYSA-N p-Mentha-1,3,5,8-tetraene Chemical compound CC(=C)C1=CC=C(C)C=C1 MMSLOZQEMPDGPI-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62065462A JPS63230754A (ja) | 1987-03-19 | 1987-03-19 | 光沢の優れた耐衝撃性ポリスチレン樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62065462A JPS63230754A (ja) | 1987-03-19 | 1987-03-19 | 光沢の優れた耐衝撃性ポリスチレン樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63230754A JPS63230754A (ja) | 1988-09-27 |
| JPH0456061B2 true JPH0456061B2 (ko) | 1992-09-07 |
Family
ID=13287815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62065462A Granted JPS63230754A (ja) | 1987-03-19 | 1987-03-19 | 光沢の優れた耐衝撃性ポリスチレン樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63230754A (ko) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2676261B2 (ja) * | 1988-07-28 | 1997-11-12 | 出光石油化学 株式会社 | ゴム変性スチレン系樹脂組成物 |
| US5079296A (en) * | 1989-07-21 | 1992-01-07 | Polysar Limited | Transparent toughened thermoplastics |
| JPH0689202B2 (ja) * | 1989-11-14 | 1994-11-09 | 出光石油化学株式会社 | 難燃性スチレン系樹脂組成物 |
| JPH0689203B2 (ja) * | 1989-11-14 | 1994-11-09 | 出光石油化学株式会社 | スチレン系樹脂組成物 |
| JPH0689204B2 (ja) * | 1989-11-29 | 1994-11-09 | 出光石油化学株式会社 | スチレン系樹脂組成物 |
| JP2645409B2 (ja) * | 1990-01-26 | 1997-08-25 | 出光石油化学株式会社 | 高光沢耐衝撃性スチレン系樹脂組成物 |
| IT1238693B (it) * | 1990-02-16 | 1993-09-01 | Montedipe Srl | Mescole a base di polimeri vinilaromatici ad elevate caratteristiche meccaniche |
| DE4018230A1 (de) * | 1990-06-07 | 1991-12-12 | Basf Ag | Thermoplastische formmassen |
| IT1255489B (it) * | 1992-08-05 | 1995-11-06 | Enichem Polimeri | Materiale antiurto termoplastico da stampaggio |
| JPH06101429A (ja) * | 1992-09-22 | 1994-04-12 | Mitsubishi Materials Corp | 内燃機関用鉛含浸鉄系焼結合金製バルブシート |
| JPH06101428A (ja) * | 1992-09-22 | 1994-04-12 | Mitsubishi Materials Corp | 内燃機関用銅溶浸鉄系焼結合金製バルブシート |
| JPH06101426A (ja) * | 1992-09-22 | 1994-04-12 | Mitsubishi Materials Corp | 内燃機関用鉄系焼結合金製バルブシート |
| JPH06101427A (ja) * | 1992-09-22 | 1994-04-12 | Mitsubishi Materials Corp | 内燃機関用鉄系焼結合金製バルブシート |
| JPH06101430A (ja) * | 1992-09-24 | 1994-04-12 | Mitsubishi Materials Corp | 内燃機関用鉛含浸鉄系焼結合金製バルブシート |
| CN1083463C (zh) * | 1994-11-30 | 2002-04-24 | 切夫里昂化学公司 | 改进了光泽和抗冲击性的苯乙烯聚合物树脂 |
| JPH08199021A (ja) * | 1995-01-26 | 1996-08-06 | Daicel Chem Ind Ltd | 成形性に優れたゴム変性スチレン系樹脂組成物 |
| US6011117A (en) * | 1997-02-11 | 2000-01-04 | Basf Corporation | High gloss, high impact polystyrene composition |
| KR100405304B1 (ko) * | 1999-12-29 | 2003-11-12 | 주식회사 엘지화학 | 폴리스티렌계 열가소성 수지 조성물 및 이를 이용한고내충격·고투명 시트의 제조방법 |
| JP7019298B2 (ja) * | 2017-02-13 | 2022-02-15 | 東京インキ株式会社 | プラスチックシンチレータ用シートまたはペレット |
-
1987
- 1987-03-19 JP JP62065462A patent/JPS63230754A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63230754A (ja) | 1988-09-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |