JPH0453910B2 - - Google Patents
Info
- Publication number
- JPH0453910B2 JPH0453910B2 JP11686985A JP11686985A JPH0453910B2 JP H0453910 B2 JPH0453910 B2 JP H0453910B2 JP 11686985 A JP11686985 A JP 11686985A JP 11686985 A JP11686985 A JP 11686985A JP H0453910 B2 JPH0453910 B2 JP H0453910B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- weight
- fibers
- coating composition
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 claims description 52
- 239000011347 resin Substances 0.000 claims description 52
- 239000000835 fiber Substances 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 38
- 238000000576 coating method Methods 0.000 claims description 35
- 239000011248 coating agent Substances 0.000 claims description 26
- 239000003822 epoxy resin Substances 0.000 claims description 20
- 229920000647 polyepoxide Polymers 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 20
- 239000008199 coating composition Substances 0.000 claims description 19
- 229920001021 polysulfide Polymers 0.000 claims description 19
- 239000005077 polysulfide Substances 0.000 claims description 18
- 150000008117 polysulfides Polymers 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 230000003628 erosive effect Effects 0.000 claims description 9
- 239000002841 Lewis acid Substances 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 8
- 229910010272 inorganic material Inorganic materials 0.000 claims description 8
- 239000011147 inorganic material Substances 0.000 claims description 8
- 150000007517 lewis acids Chemical class 0.000 claims description 8
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 150000004684 trihydrates Chemical class 0.000 claims description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 239000000463 material Substances 0.000 description 21
- 229920000049 Carbon (fiber) Polymers 0.000 description 11
- 239000004917 carbon fiber Substances 0.000 description 11
- 239000002243 precursor Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 6
- 239000006224 matting agent Substances 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 4
- -1 In particular Polymers 0.000 description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000009970 fire resistant effect Effects 0.000 description 3
- 238000007496 glass forming Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920001079 Thiokol (polymer) Polymers 0.000 description 2
- 238000002679 ablation Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000011364 vaporized material Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
- C09D181/04—Polysulfides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/615,586 US4656095A (en) | 1984-05-31 | 1984-05-31 | Ablative composition |
| US615586 | 1984-05-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60262868A JPS60262868A (ja) | 1985-12-26 |
| JPH0453910B2 true JPH0453910B2 (https=) | 1992-08-27 |
Family
ID=24466022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60116869A Granted JPS60262868A (ja) | 1984-05-31 | 1985-05-31 | 融蝕性組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4656095A (https=) |
| JP (1) | JPS60262868A (https=) |
| CA (1) | CA1268887A (https=) |
| DE (1) | DE3519581A1 (https=) |
| FR (1) | FR2565238B1 (https=) |
| GB (1) | GB2159522B (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4743625A (en) * | 1986-07-25 | 1988-05-10 | Lubomir Vajs | Fire retardant mixture for protection of suitable composite products |
| US4965296A (en) * | 1989-03-15 | 1990-10-23 | No Fire Engineering, Inc. | Intumescent fire-retardant and electrically-conductive coating material |
| US4879320A (en) * | 1989-03-15 | 1989-11-07 | Hastings Otis | Intumescent fire-retardant coating material |
| US5070119A (en) * | 1990-09-28 | 1991-12-03 | Ppg Industries, Inc. | Flexible intumescent coating composition |
| US5108832A (en) * | 1990-09-28 | 1992-04-28 | Ppg Industries, Inc. | Flexible intumescent coating composition |
| GB9126902D0 (en) * | 1991-12-19 | 1992-02-19 | Morton Int Ltd | Polysulphide-modified epoxy resins |
| US5703178A (en) * | 1995-11-30 | 1997-12-30 | Ameron International Corporation | Heat ablative coating composition |
| US6054521A (en) * | 1996-12-09 | 2000-04-25 | Cordant Technologies Inc. | Erosion resistant-low signature liner for solid propellant rocket motors |
| CA2309211C (en) * | 1997-11-07 | 2008-09-02 | Alfredo Reyes Jr. | Chromate-free, one-part, non-curing corrosion inhibitive sealant with resistance to aviation fuel |
| IT1317893B1 (it) * | 2000-08-04 | 2003-07-15 | Quintilio Lupi | Rivestimento per un elemento per levigare e/o lucidare, in particolareuna mola, mola provvista di detto rivestimento, procedimento per |
| US6503596B1 (en) | 2000-11-30 | 2003-01-07 | Michael L. Fellman | Composite firewall structure |
| US20040224857A1 (en) * | 2003-03-19 | 2004-11-11 | Hendrik John | Method and composition for controlling galling |
| US7578452B2 (en) * | 2003-08-27 | 2009-08-25 | Honeywell International Inc. | Ablative composite assemblies and joining methods thereof |
| CN101107315B (zh) * | 2005-01-28 | 2010-08-25 | 陶氏环球技术公司 | 与热塑性塑料结合使用芳族聚酰胺纤维以改进耐洗除性和改进例如冲击性和膨胀性的物理性能 |
| US20090220700A1 (en) * | 2008-02-28 | 2009-09-03 | Carl Peres | Coating Composition And Method Of Application |
| FR2959238B1 (fr) * | 2010-04-22 | 2014-03-14 | Astrium Sas | Materiau de protection thermique |
| CN103347954A (zh) | 2011-01-24 | 2013-10-09 | 阿克佐诺贝尔国际涂料股份有限公司 | 高耐热组合物 |
| AU2013298680C1 (en) | 2012-07-30 | 2016-11-10 | Akzo Nobel Coatings International B.V. | High heat resistant composition |
| EP2957606A1 (de) | 2014-06-18 | 2015-12-23 | HILTI Aktiengesellschaft | Brandschutz-Zusammensetzung und deren Verwendung |
| US11073366B2 (en) | 2019-12-24 | 2021-07-27 | Northrop Grumman Systems Corporation | Liners for flares and related methods |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3875106A (en) * | 1966-10-10 | 1975-04-01 | Mc Donnell Douglas Corp | Ablation compositions and coatings |
| US3600341A (en) * | 1966-11-08 | 1971-08-17 | Us Air Force | Ablative char-forming compositions containing an intractable polyphenylene polymer |
| GB1237220A (en) * | 1967-11-21 | 1971-06-30 | Courtaulds Ltd | Moulding composition |
| US4001126A (en) * | 1972-05-17 | 1977-01-04 | Universal Propulsion Co. | Heat protective material and method of making the material |
| US4289680A (en) * | 1974-12-09 | 1981-09-15 | Ishikawa Giken Kogyo Kabushiki Kaisha | Heat resistant and fire-proof synthetic resin material containing inorganic substances and process of producing same |
| US4595714A (en) * | 1981-03-13 | 1986-06-17 | Fiber Materials, Inc. | Ablative coating composition and product |
-
1984
- 1984-05-31 US US06/615,586 patent/US4656095A/en not_active Expired - Lifetime
-
1985
- 1985-05-09 CA CA000481181A patent/CA1268887A/en not_active Expired - Fee Related
- 1985-05-09 GB GB8511771A patent/GB2159522B/en not_active Expired
- 1985-05-30 FR FR8508141A patent/FR2565238B1/fr not_active Expired - Lifetime
- 1985-05-31 DE DE19853519581 patent/DE3519581A1/de not_active Withdrawn
- 1985-05-31 JP JP60116869A patent/JPS60262868A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB2159522B (en) | 1988-03-16 |
| FR2565238A1 (fr) | 1985-12-06 |
| GB8511771D0 (en) | 1985-06-19 |
| CA1268887A (en) | 1990-05-08 |
| DE3519581A1 (de) | 1985-12-05 |
| GB2159522A (en) | 1985-12-04 |
| FR2565238B1 (fr) | 1993-11-05 |
| JPS60262868A (ja) | 1985-12-26 |
| US4656095A (en) | 1987-04-07 |
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