JPH0351459B2 - - Google Patents

Info

Publication number
JPH0351459B2
JPH0351459B2 JP59077633A JP7763384A JPH0351459B2 JP H0351459 B2 JPH0351459 B2 JP H0351459B2 JP 59077633 A JP59077633 A JP 59077633A JP 7763384 A JP7763384 A JP 7763384A JP H0351459 B2 JPH0351459 B2 JP H0351459B2
Authority
JP
Japan
Prior art keywords
macroparticles
particles
coating
water
spray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP59077633A
Other languages
English (en)
Japanese (ja)
Other versions
JPS59222224A (ja
Inventor
Ii Baaguna Horashio
Jatsuku Kaakurando Josefu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of JPS59222224A publication Critical patent/JPS59222224A/ja
Publication of JPH0351459B2 publication Critical patent/JPH0351459B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/282Porous sorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3289Coatings involving more than one layer of same or different nature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3291Characterised by the shape of the carrier, the coating or the obtained coated product
    • B01J20/3295Coatings made of particles, nanoparticles, fibers, nanofibers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0221Coating of particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30Scanning electron microscopy; Transmission electron microscopy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated
    • Y10T428/2993Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y10T428/2996Glass particles or spheres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicon Compounds (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
JP59077633A 1983-04-22 1984-04-19 表面多孔性マクロ粒子の製造法 Granted JPS59222224A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/487,894 US4477492A (en) 1983-04-22 1983-04-22 Process for preparing superficially porous supports for chromatography and catalysts
US487894 1983-04-22

Publications (2)

Publication Number Publication Date
JPS59222224A JPS59222224A (ja) 1984-12-13
JPH0351459B2 true JPH0351459B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1991-08-06

Family

ID=23937551

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59077633A Granted JPS59222224A (ja) 1983-04-22 1984-04-19 表面多孔性マクロ粒子の製造法

Country Status (5)

Country Link
US (1) US4477492A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0123293B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JPS59222224A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA1215704A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE3464857D1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5441635A (en) * 1986-07-05 1995-08-15 Asahi Kogaku Kogyo Kabushiki Kaisha Packing material for liquid chromatography
US5039408A (en) * 1986-07-05 1991-08-13 Asahi Kogaku Kogyo K.K. Packing material for liquid chromatography
US6306297B1 (en) 1968-07-08 2001-10-23 Asahi Kogaku Kogyo Kabushiki Kaisha Packing material for liquid chromatography and process for producing the same
SE8402916L (sv) * 1984-01-30 1985-07-31 Eka Ab Katalytisk avgasrenare och sett att framstella denna
SE8400426L (sv) * 1984-01-30 1985-07-31 Eka Ab Sett att framstella fina partiklar med en ytbeleggning av metall eller metallforening, serskilt ett katalytiskt aktivt emne
EP0169877A1 (en) * 1984-01-30 1986-02-05 Eka Nobel Aktiebolag Filler or a support for catalytically active substances, a process for producing said filler or support, a catalyst produced from said support, and the use of said catalyst
US4874518A (en) * 1985-11-01 1989-10-17 E. I. Du Pont De Nemours And Company Porous silica microspheres having a silanol enriched surface
US5108595A (en) * 1985-11-01 1992-04-28 E. I. Du Pont De Nemours And Company Porous silica microspheres having silanol-enriched and silanized surfaces
US5032266A (en) * 1985-11-01 1991-07-16 E. I. Du Pont De Nemours And Company Porous silica microspheres having silanol-enriched and silanized surfaces
US4781968A (en) * 1986-02-28 1988-11-01 Digital Equipment Corporation Micro-electronics devices and methods of manufacturing same
JPH0762674B2 (ja) * 1986-03-07 1995-07-05 株式会社高研 クロマトグラフイ−用吸着剤、及びその製造方法、並びに該吸着剤を使用したクロマトグラフイ−カラム
EP0239970A3 (en) * 1986-03-31 1988-04-20 Toa Nenryo Kogyo Kabushiki Kaisha Assemblage of hydroxyl apatite particles and liquid chromatography column using the same
FR2599354B1 (fr) * 1986-05-27 1988-08-26 Rhone Poulenc Spec Chim Cogranules silicate, silice, procede d'obtention et utilisation dans les compositions detergentes
USRE35340E (en) * 1986-07-05 1996-10-01 Asahi Kogaku Kogyo K.K. Packing material for liquid chromatography
US4837195A (en) * 1986-12-23 1989-06-06 E. I. Du Pont De Nemours And Company Process for porosity control and rehydroxylations of silica bodies
US5145578A (en) * 1987-07-03 1992-09-08 Shiseido Company Ltd. Packing material for liquid chromatography
CA1329800C (en) * 1987-12-29 1994-05-24 Hiroaki Takayanagi Composite separating agent
GB8802627D0 (en) * 1988-02-05 1988-03-02 Boc Group Inc Liquid-vapour contact columns
DD278482A3 (de) * 1988-06-22 1990-05-09 Univ Berlin Humboldt Vorrichtung und verfahren zur chromatographischen trennung
US4900712A (en) * 1988-09-30 1990-02-13 Prototech Company Catalytic washcoat and method of preparation of the same
DE3841289A1 (de) * 1988-12-08 1990-07-05 Schumacher Gmbh & Co Kg Synthetische, poroese feststoffkoerper
IL89404A (en) * 1989-02-24 1993-05-13 Ormat Turbines 1965 Ltd Method of and apparatus for evaporating and cooling liquid
US4994302A (en) * 1989-06-27 1991-02-19 Digital Equipment Corporation Method of manufacturing thick-film devices
US5228989A (en) * 1989-07-06 1993-07-20 Perseptive Biosystems, Inc. Perfusive chromatography
FR2650514B1 (fr) * 1989-08-04 1991-11-22 Lvmh Rech Procede de fabrication de poudres ordonnees par pulverisation a partir d'au moins deux populations de particules, et poudres ordonnees ainsi obtenues
US5876758A (en) * 1989-08-04 1999-03-02 Lvmh Recherche Solid complex particles comprising a biologically active solid substance, mode of preparation and compositions for topical use containing them and intended to treat biological surfaces
JPH03229634A (ja) * 1990-02-03 1991-10-11 Agency Of Ind Science & Technol 無機微粒子殻徐放性マイクロスフェア
JP2560220B2 (ja) * 1990-03-27 1996-12-04 工業技術院長 徐放性粒状体とその製造方法
EP0484546B1 (en) * 1990-05-24 1995-11-15 Nippon Kayaku Kabushiki Kaisha Method of making microcapsules
US5470512A (en) * 1990-05-24 1995-11-28 Nippon Kayaku Kabushiki Kaisha Process for producing microcapsules
DE4024290A1 (de) * 1990-07-31 1992-02-06 Wulff Guenter Prof Dr Mischbettsaeulen fuer die fluessigchromatographie und verfahren zu ihrer fuellung
KR970702827A (ko) * 1994-04-25 1997-06-10 워렌 리차드 보비 용융 미립자를 포함하는 조성물 및 그 제조방법(compositions comprising fused particulates and methods of making them)
US6045913A (en) * 1995-11-01 2000-04-04 Minnesota Mining And Manufacturing Company At least partly fused particulates and methods of making them by flame fusion
US6254981B1 (en) 1995-11-02 2001-07-03 Minnesota Mining & Manufacturing Company Fused glassy particulates obtained by flame fusion
DE19743518A1 (de) * 1997-10-01 1999-04-15 Roche Diagnostics Gmbh Automatisierbare universell anwendbare Probenvorbereitungsmethode
US6284282B1 (en) 1998-04-29 2001-09-04 Genentech, Inc. Method of spray freeze drying proteins for pharmaceutical administration
DE69911790T2 (de) * 1998-07-03 2004-08-12 Toyota Jidosha K.K., Toyota Verfahren und system zur speicherung von gas und gasadsorbierendes material
FR2781475B1 (fr) * 1998-07-23 2000-09-08 Alsthom Cge Alcatel Utilisation d'un creuset en graphite poreux pour traiter des granules de silice
US6107238A (en) * 1998-09-30 2000-08-22 E. I. Du Pont De Nemours And Company Process for manufacture and use of improved attrition resistant catalyst
US6528029B1 (en) 1999-10-13 2003-03-04 Engelhard Corporation Catalyst compositions employing sol gel particles and methods of using the same
EP1232502B1 (en) * 1999-11-17 2006-01-11 Roche Diagnostics GmbH Magnetic glass particles, method for their preparation and uses thereof
WO2003049849A2 (en) * 2001-12-10 2003-06-19 Hte Aktiengesellschaft The High Throughput Experimentation Company Production and shaping of shaped bodies by means of low-temperature cooling and drying processes
US6749749B2 (en) * 2002-06-26 2004-06-15 Isco, Inc. Separation system, components of a separation system and methods of making and using them
US20050061745A1 (en) * 2002-06-26 2005-03-24 Teledyne Isco, Inc. Separation system, components of a separation system and methods of making and using them
US7473367B2 (en) * 2002-06-26 2009-01-06 Dionex Corporation Monolithic column
US9247765B2 (en) * 2004-01-14 2016-02-02 Omniactive Health Technologies Limited Stable beadlets of lipophilic nutrients
US7309426B2 (en) * 2004-04-23 2007-12-18 Agilent Technologies, Inc. Composition and method for high efficiency chromatography
US7943046B2 (en) * 2004-10-01 2011-05-17 Agilent Technologies, Inc Methods and systems for on-column protein delipidation
US7449116B2 (en) * 2004-10-01 2008-11-11 Agilent Technologies, Inc. Methods and systems for protein separation
JP4979203B2 (ja) * 2005-05-31 2012-07-18 栗田工業株式会社 吸着構造体およびその製造方法
US7749304B2 (en) * 2006-01-30 2010-07-06 General Electric Company Method for storing hydrogen, and related articles and systems
WO2007095158A2 (en) * 2006-02-13 2007-08-23 Advanced Materials Technology, Inc. Process for preparing substrates with porous surface
US20070256976A1 (en) * 2006-04-10 2007-11-08 Boyes Barry E Metal-coated sorbents as a separation medium for HPLC of phosphorus-containing materials
US20070235390A1 (en) * 2006-04-10 2007-10-11 Boyes Barry E Titanium-coated sorbents as a separation medium for HPLC of phosphorus-containing materials
US20070235389A1 (en) * 2006-04-10 2007-10-11 Boyes Barry E Metal-coated superficially porous supports as a medium for HPLC of phosphorus-containing materials
US20080145554A1 (en) * 2006-12-14 2008-06-19 General Electric Thermal spray powders for wear-resistant coatings, and related methods
US8580935B2 (en) * 2007-02-26 2013-11-12 Alltech Associates, Inc. Ultra-fast chromatography
FR2920767B1 (fr) * 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
US8685283B2 (en) 2008-08-29 2014-04-01 Agilent Technologies, Inc. Superficially porous metal oxide particles, methods for making them, and separation devices using them
US9284456B2 (en) 2008-08-29 2016-03-15 Agilent Technologies, Inc. Superficially porous metal oxide particles, methods for making them, and separation devices using them
DE102009005446A1 (de) * 2009-01-21 2010-07-22 Schott Ag Granulat, Verfahren zu dessen Herstellung sowie dessen Verwendung
US7846337B2 (en) * 2009-02-17 2010-12-07 Agilent Technologies, Inc. Superficially porous particles and methods of making and using same
US20100255310A1 (en) * 2009-04-06 2010-10-07 Wu Chen Totally porous particles and methods of making and using same
US11439977B2 (en) 2009-06-01 2022-09-13 Waters Technologies Corporation Hybrid material for chromatographic separations comprising a superficially porous core and a surrounding material
JP6151021B2 (ja) * 2009-06-01 2017-06-21 ウオーターズ・テクノロジーズ・コーポレイシヨン クロマトグラフ分離用ハイブリッド材料
CN101797492B (zh) * 2010-04-16 2012-04-04 北京化工大学 一种层状双羟基复合金属氢氧化物多孔微球的制备方法
EP2598440B1 (en) 2010-07-26 2020-12-30 Waters Technologies Corporation Superficially porous materials comprising a substantially nonporous hybrid core having narrow particle size distribution; process for the preparation thereof; and use thereof for chromatographic separations
CN102091606A (zh) * 2010-12-08 2011-06-15 苏州环球色谱有限责任公司 核壳型液相色谱填料的合成方法
US9610576B2 (en) 2012-09-27 2017-04-04 Agilent Technologies, Inc. Hydrolytically stable ion-exchange stationary phases and uses thereof
CN106563426B (zh) * 2015-10-13 2019-01-08 中国科学院大连化学物理研究所 一种氧化铝纳米层修饰硅胶色谱填料的制备方法
WO2017155884A1 (en) 2016-03-06 2017-09-14 Waters Technologies Corporation Hybrid material for chromatographic separations comprising a superficially porous core and a surrounding material
US10434496B2 (en) 2016-03-29 2019-10-08 Agilent Technologies, Inc. Superficially porous particles with dual pore structure and methods for making the same
CN107500311A (zh) * 2017-09-08 2017-12-22 芜湖悠派护理用品科技股份有限公司 一种改善4a沸石分散性的方法
WO2019140198A1 (en) * 2018-01-12 2019-07-18 Restek Corporation Superficially porous particles and methods for forming superficially porous particles
US11691140B2 (en) 2019-10-24 2023-07-04 Uwm Research Foundation, Inc. Method for the preparation of controlled porosity supports for chromatographic separation
WO2025004942A1 (ja) * 2023-06-30 2025-01-02 東洋紡エムシー株式会社 吸着剤、吸着フィルタ、及びフィルタユニット、並びに吸着フィルタの製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL299290A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1962-10-23
US3444097A (en) * 1965-06-30 1969-05-13 Mobil Oil Corp Hydrocarbon conversion catalyst
US3485658A (en) * 1965-07-22 1969-12-23 Du Pont Plural monolayer coated article and process of making
US3505785A (en) * 1967-06-20 1970-04-14 Du Pont Superficially porous supports for chromatography
JPS5831978B2 (ja) * 1972-08-10 1983-07-09 フジミケンマザイコウギヨウ カブシキガイシヤ キノウブツシツホゴコウゾウタイ
US4053436A (en) * 1975-08-26 1977-10-11 Phillips Petroleum Company Spray dried titanium-containing catalyst for stress crack resistant polymer
US4131542A (en) * 1977-07-19 1978-12-26 E. I. Dupont De Nemours And Company Spray dried silica for chromatography
JPS57122931A (en) * 1981-01-22 1982-07-31 Chiyoda Chem Eng & Constr Co Ltd Fine powder and preparation thereof

Also Published As

Publication number Publication date
DE3464857D1 (en) 1987-08-27
CA1215704A (en) 1986-12-23
JPS59222224A (ja) 1984-12-13
EP0123293A2 (en) 1984-10-31
US4477492A (en) 1984-10-16
EP0123293B1 (en) 1987-07-22
EP0123293A3 (en) 1985-08-07

Similar Documents

Publication Publication Date Title
JPH0351459B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
US4070286A (en) Macroporous microspheroids and a process for their manufacture
US4131542A (en) Spray dried silica for chromatography
CA1088042A (en) Controlled surface porosity particles and a method for their production
US3782075A (en) Completely porous microspheres for chromatographic uses
US4389385A (en) Production of porous gels and ceramic materials
US5256386A (en) Method for preparation of silica particles
US5128291A (en) Porous titania or zirconia spheres
US4913966A (en) Porous structures
JP3205559B2 (ja) 球状吸着剤粒子の製造方法
JP2000503594A (ja) 触媒及びその製法
RU2283179C2 (ru) Неорганические микросферические частицы с повышенным сопротивлением истиранию, способ их приготовления, материал катализатора на основе микрочастиц и его использование
US5585082A (en) SOx/NOx sorbent and process of use
JPH0536366B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JPS62503097A (ja) シリカ構造体
US4902413A (en) Organic-based porous microspheres for HPLC
US4986908A (en) Organic-based porous microspheres for HPLC
KR100221174B1 (ko) 구형 흡착 입자의 제조 방법
US2641583A (en) Process for producing silica gel spheres in oil
CN111989293A (zh) 准埃洛石粉末及准埃洛石粉末的制造方法
Xia et al. Preparation of Core–Shell Silica Microspheres with Controllable Shell Thickness for Fast High Performance Liquid Chromatography Separation of Alkyl Benzenes and Intact Proteins
EP0341556A1 (en) Organic-based porous microspheres for HPLC
JPH01199155A (ja) 液体クロマトグラフィー用充填剤
JPH04342418A (ja) 球形ゼオライト触媒の製造方法
Skubiszewska-Zięba et al. Preparation of microspherical granules from aerosilogels: The way of spray drying in overheated water steam