JPH03262514A - 塩素ガスの濃縮方法 - Google Patents

塩素ガスの濃縮方法

Info

Publication number
JPH03262514A
JPH03262514A JP2411061A JP41106190A JPH03262514A JP H03262514 A JPH03262514 A JP H03262514A JP 2411061 A JP2411061 A JP 2411061A JP 41106190 A JP41106190 A JP 41106190A JP H03262514 A JPH03262514 A JP H03262514A
Authority
JP
Japan
Prior art keywords
chlorine
gas
adsorbing
introduction
adsorbent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2411061A
Other languages
English (en)
Other versions
JP3072129B2 (ja
Inventor
Hiroyuki Ito
洋之 伊藤
Yoshitsugu Jinno
神野 嘉嗣
Shinji Takenaka
竹中 慎司
Yukihiro Yoshikawa
幸宏 吉川
Isao Kikuchi
菊地 功
Teruo Hirayama
平山 照夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Toatsu Chemicals Inc
Original Assignee
Mitsui Toatsu Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc
Publication of JPH03262514A publication Critical patent/JPH03262514A/ja
Application granted granted Critical
Publication of JP3072129B2 publication Critical patent/JP3072129B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00Halogens; Halogen acids
    • C01B7/01Chlorine; Hydrogen chloride
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00Halogens; Halogen acids
    • C01B7/01Chlorine; Hydrogen chloride
    • C01B7/07Purification ; Separation
    • C01B7/0743Purification ; Separation of gaseous or dissolved chlorine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/12Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/22Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/202Single element halogens
    • B01D2257/2025Chlorine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/403Further details for adsorption processes and devices using three beds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】
[0001]
【産業上の利用分野】
本発明は圧力スイング吸着法を利用 [0002]
【従来の技術】
塩素は非常に重要な工業中間原料で 塩素の分離や濃縮のための設備が存在 [0003] 従来塩素を含むガスより塩素を分離 液体塩素としガスより分離する方法や た溶剤をストリッピングすることによ [0004] 塔内が真空ポンプ10で排気されて減圧状態となり、吸
着剤に吸着された塩素が脱着され、吸着剤が再生される
(再生工程)。 [0034] この再生工程で製品としての塩素濃度の高いガスを真空
ポンプ10の吐出口から得ることができ、この塩素を高
濃度に含有したガスは下流の消費工程に送られる[00
35] この時第2の吸着塔4bでは、原料ガスが切換弁15を
経て導入され、この塔の出口から処理済ガスが吐出し、
切換弁16、弁6を経てブロワ7に送られ、さらに消費
工程へ送られる。 [0036] また第3の吸着塔4Cでは第2の吸着塔4bから吐出さ
れる処理済ガスの一部が流量調節機構8、切換弁17を
経て導入され、この塔内の圧力が処理済ガスによって高
められる充圧工程が実施されている。 [0068] 通気完了後原料ガスの供給を停止し、真空ポンプで吸着
カラムを60mmHg abs。 の圧力に5分間おき、塩素ガスを脱着させて脱着したガ
スを分析したところ塩素濃度79%であった。 [0069] この脱着後の吸着カラムに再び初めと同様の組成のガス
を同条件で通気したところ、やはり6分間は流出するガ
スの塩素濃度は200〜500ppmであった。 [0070]
【発明の効果】
本発明は圧力スイング吸着法を適用することにより、塩
素を含有するガスから塩素を容易に分離、濃縮する方法
を提供するもので、その工業的価値は非常に太きい。 [0071] 本発明は比較的うすい濃度で含まれる塩素ガスから、吸
着剤を用いて比較的高再生も要しない方法である。 [0072] 本発明は塩素を利用する設備において付属設備として実
施される。
【図面の簡単な説明】
【図1】 本発明を時に連続的に行なうために複数の吸着塔を用い
る設備の模式図である
【符号の説明】
原料ガス供給管 圧縮機 4a。 4b。 吸着塔 弁 ブ ロワ− 流量調節機構 真空ポンプ

Claims (5)

    【特許請求の範囲】
  1. 【請求項1】塩素を吸着しうる吸着剤を充填した吸着塔
    に、塩素を含有するガスを導入して塩素を吸着させ、そ
    の後ガスの導入を停止し、ガス導入時よりも低い圧力下
    で脱着を行ない、導入ガスの塩素濃度より高い塩素濃度
    のガスを得るとともに吸着剤を再生することを特徴とす
    る塩素ガスの濃縮方法。
  2. 【請求項2】塩素を吸着しうる吸着剤がゼオライトであ
    る請求項1記載の方法。
  3. 【請求項3】塩素を吸着しうる吸着剤が非ゼオライト系
    多孔質酸性酸化物である請求項1記載の方法。
  4. 【請求項4】塩素を吸着しうる吸着剤が活性炭である請
    求項1記載の方法。
  5. 【請求項5】活性炭が分子ふるいカーボンである請求項
    4記載の方法。
JP02411061A 1989-12-16 1990-12-17 塩素ガスの濃縮方法 Expired - Lifetime JP3072129B2 (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP32489389 1989-12-16
JP1-324893 1989-12-16
JP7550090 1990-03-27
JP2-75500 1990-03-27

Publications (2)

Publication Number Publication Date
JPH03262514A true JPH03262514A (ja) 1991-11-22
JP3072129B2 JP3072129B2 (ja) 2000-07-31

Family

ID=26416630

Family Applications (1)

Application Number Title Priority Date Filing Date
JP02411061A Expired - Lifetime JP3072129B2 (ja) 1989-12-16 1990-12-17 塩素ガスの濃縮方法

Country Status (9)

Country Link
US (1) US5302187A (ja)
EP (1) EP0458990B1 (ja)
JP (1) JP3072129B2 (ja)
KR (1) KR940001410B1 (ja)
CN (1) CN1026774C (ja)
BR (1) BR9007125A (ja)
CA (1) CA2046325A1 (ja)
DE (1) DE69018625T2 (ja)
WO (1) WO1991008824A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007066810A1 (ja) 2005-12-08 2007-06-14 Sumitomo Chemical Company, Limited 塩素の製造方法
WO2008029940A1 (fr) 2006-09-06 2008-03-13 Sumitomo Chemical Company, Limited Procédé de mise en fonctionnement
WO2010067751A1 (ja) 2008-12-09 2010-06-17 住友化学株式会社 塩素の製造方法
WO2010073888A1 (ja) 2008-12-22 2010-07-01 住友化学株式会社 塩素の製造方法

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5296017A (en) * 1991-05-28 1994-03-22 Mitsui Toatsu Chemicals, Inc. Method and apparatus for concentrating chlorine gas
DE69213342T2 (de) * 1991-06-06 1997-01-02 Mitsui Toatsu Chemicals Verfahren und Apparat zur industriellen Herstellung von Chlor
US5376164A (en) * 1993-08-09 1994-12-27 Uop Pressure swing adsorption process for chlorine plant offgas
US5500035A (en) * 1993-08-09 1996-03-19 Uop Pressure swing adsorption process for chlorine plant offgas
US5453113A (en) * 1994-04-11 1995-09-26 Uop Process for separation and recovery of methyl chloride from vent streams containing isobutane
DE19536976A1 (de) * 1995-10-04 1997-04-10 Basf Ag Verfahren zur selektiven Abtrennung und Wiedergewinnung von Chlor aus Gasgemischen
US5762686A (en) * 1996-09-04 1998-06-09 Special Gas System, Inc. Process for determining amount of argon contamination in oxygen and related apparatus therefor
US5676735A (en) * 1996-10-31 1997-10-14 Advanced Technology Materials, Inc. Reclaiming system for gas recovery from decommissioned gas storage and dispensing vessels and recycle of recovered gas
US5867239A (en) 1997-10-17 1999-02-02 Minnesota Mining And Manufacturing Company Wide angle optical retarder
US5985226A (en) * 1998-01-07 1999-11-16 Occidental Chemcial Corporation Method of recovering chlorine from a gas mixture
KR101335397B1 (ko) * 2006-02-03 2013-12-02 지알티, 인코포레이티드 할로겐으로부터 가벼운 기체를 분리하는 방법
CN101961588B (zh) * 2009-07-23 2013-03-27 江苏新河农用化工有限公司 一种百菌清氯化尾气中氯气的回收方法
US20110315140A1 (en) * 2010-06-29 2011-12-29 Precision Medical, Inc. Portable oxygen concentrator
JP6107466B2 (ja) * 2012-06-28 2017-04-05 セントラル硝子株式会社 トランス−1,3,3,3−テトラフルオロプロペンの精製方法
CN108671747A (zh) * 2018-05-18 2018-10-19 苏州朗道节能技术有限公司 一种从光纤预制棒烧结炉排放废气里回收提纯氦气的方法和系统
CN110775943B (zh) * 2018-07-31 2023-04-07 中国科学院大连化学物理研究所 一种高压氯气产生装置
CN112678775B (zh) * 2019-10-17 2022-12-06 新疆晶硕新材料有限公司 一种白炭黑尾气净化回收的方法及装置
CN113731102A (zh) * 2020-12-22 2021-12-03 李保军 一种常温提取超高纯度气体的方法及生产装置
CN116059782B (zh) * 2021-10-31 2024-10-01 中国石油化工股份有限公司 一种含so2真空再生气进制硫装置的方法及系统

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1617305A (en) * 1926-04-19 1927-02-08 Mathieson Alkali Works Inc Recovery of chlorine
US2340398A (en) * 1942-03-21 1944-02-01 Mathieson Alkali Works Inc Chemical manufacture
US2800197A (en) * 1955-12-09 1957-07-23 Nat Distillers Chem Corp Chlorine recovery
US3063218A (en) * 1956-02-23 1962-11-13 Hooker Chemical Corp Chlorine dioxide separation
US3038326A (en) * 1958-06-02 1962-06-12 Phillips Petroleum Co Chromatographic analyzer
US3029575A (en) * 1958-11-03 1962-04-17 Exxon Research Engineering Co Chlorine separation process
US3001607A (en) * 1958-11-04 1961-09-26 Exxon Research Engineering Co Chlorine separation process
DE1100603B (de) * 1959-12-19 1961-03-02 Bayer Ag Verfahren zur Reinigung von Chlor von Chlorkohlenwasserstoffen
BE642740A (ja) * 1963-01-21
US3197942A (en) * 1964-04-07 1965-08-03 Texas Instruments Inc Method for removal of hydrogen halide from a process stream
US3658467A (en) * 1969-07-28 1972-04-25 Atomic Energy Commission System for total iodine retention
BE797640A (fr) * 1972-04-01 1973-07-16 Degussa Procede pour empecher des reactions secondaires lors d'utilisatiion de chlore sous forme de vapeur
US4127395A (en) * 1976-10-18 1978-11-28 Pall Corporation Adsorbent fractionator with fail-safe automatic cycle control and process
DE2652486C2 (de) * 1976-11-18 1987-01-08 Bergwerksverband Gmbh, 4300 Essen Verfahren zur Gewinnung von stickstoffreichen Gasen aus neben N↓2↓ wenigstens O↓2↓ enthaltenden Gasen, wie z.B. Luft
GB2025254B (en) * 1978-07-12 1982-09-02 Linde Ag Separating gas mixtures
JPS5527019A (en) * 1978-08-15 1980-02-26 Toshiba Corp Removal of corrosive gas
SU738644A1 (ru) * 1978-10-19 1980-06-05 Предприятие П/Я М-5817 Поглотитель хлора
GB2073043A (en) * 1980-03-31 1981-10-14 Boc Ltd Separation of a gaseous mixture
SU1189490A1 (ru) * 1983-10-11 1985-11-07 Предприятие П/Я Г-4684 Способ очистки газа от хлора
US4557921A (en) * 1984-06-27 1985-12-10 Ethyl Corporation Purification of halide
JPS61242901A (ja) * 1985-04-17 1986-10-29 Toyo Soda Mfg Co Ltd 臭素回収用吸着剤及び臭素回収方法
JPS61266302A (ja) * 1985-05-17 1986-11-26 Seitetsu Kagaku Co Ltd 濃縮酸素回収方法
US4762537A (en) * 1985-11-07 1988-08-09 Aluminum Company Of America Adsorbent for HCl comprising alumina and acid-treated Y zeolite
DE3843313A1 (de) * 1988-12-22 1990-06-28 Wacker Chemitronic Verfahren zur entfernung von gasfoermigen kontaminierenden, insbesondere dotierstoffverbindungen aus halogensilanverbindungen enthaltenden traegergasen
US4902312A (en) * 1989-01-30 1990-02-20 Allied-Signal Inc. Carbon molecular sieves for purification of chlorofluorocarbons
US4980139A (en) * 1990-02-28 1990-12-25 Union Oil Company Of California Method for removing chlorine from a gas stream

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007066810A1 (ja) 2005-12-08 2007-06-14 Sumitomo Chemical Company, Limited 塩素の製造方法
WO2008029940A1 (fr) 2006-09-06 2008-03-13 Sumitomo Chemical Company, Limited Procédé de mise en fonctionnement
US8168154B2 (en) 2006-09-06 2012-05-01 Sumitomo Chemical Company, Limited Start-up method for producing chlorine
WO2010067751A1 (ja) 2008-12-09 2010-06-17 住友化学株式会社 塩素の製造方法
WO2010073888A1 (ja) 2008-12-22 2010-07-01 住友化学株式会社 塩素の製造方法

Also Published As

Publication number Publication date
JP3072129B2 (ja) 2000-07-31
EP0458990A4 (en) 1992-05-06
DE69018625D1 (de) 1995-05-18
EP0458990A1 (en) 1991-12-04
CN1053597A (zh) 1991-08-07
DE69018625T2 (de) 1996-03-14
EP0458990B1 (en) 1995-04-12
WO1991008824A1 (fr) 1991-06-27
US5302187A (en) 1994-04-12
BR9007125A (pt) 1992-01-28
CN1026774C (zh) 1994-11-30
KR920700739A (ko) 1992-08-10
CA2046325A1 (en) 1991-06-17
KR940001410B1 (ko) 1994-02-23

Similar Documents

Publication Publication Date Title
JPH03262514A (ja) 塩素ガスの濃縮方法
US3957463A (en) Oxygen enrichment process
RU1816229C (ru) Способ обогащени гели
US5507957A (en) Treating materials with ozone
JP3902416B2 (ja) ガス分離方法
JPH0239294B2 (ja)
US6017382A (en) Method of processing semiconductor manufacturing exhaust gases
KR20140109356A (ko) 흡착 작업으로부터 nf3를 회수하는 방법
GB2109266A (en) Pressure swing process for the separation of gas mixtures by adsorption
KR0173399B1 (ko) 압력변동흡착식 고순도 이산화탄소 제조방법
JP3080687B2 (ja) 塩素ガスの濃縮方法
CA1182765A (en) Repressurization for pressure swing adsorption system
JPH04227018A (ja) 高純度不活性ガスの製造方法
JPS62117612A (ja) 吸着塔の再生方法
KR100228239B1 (ko) 제품질소 농도에 따른 압력변동흡착식 질소제조장치와 방법
KR100270100B1 (ko) 활성탄소섬유를 이용한 이산화탄소의 흡착.분리공정
JPH0239292B2 (ja)
JPH0239293B2 (ja)
JPH0731826A (ja) ガス濃縮装置
JP2909254B2 (ja) 塩素ガスの濃縮方法
JPH05301011A (ja) 塩化水素ガスの濃縮方法
JP2909253B2 (ja) 塩素ガスの濃縮方法
JP2001087616A (ja) 高濃度酸素発生装置
JP2004300035A (ja) メタンガスの分離方法および装置
GB2195097A (en) Separation of gas mixtures by pressure swing adsorption

Legal Events

Date Code Title Description
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080526

Year of fee payment: 8

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090526

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100526

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100526

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110526

Year of fee payment: 11

EXPY Cancellation because of completion of term
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110526

Year of fee payment: 11