JPH0248097B2 - Karaashashinkankozairyo - Google Patents
KaraashashinkankozairyoInfo
- Publication number
- JPH0248097B2 JPH0248097B2 JP14609683A JP14609683A JPH0248097B2 JP H0248097 B2 JPH0248097 B2 JP H0248097B2 JP 14609683 A JP14609683 A JP 14609683A JP 14609683 A JP14609683 A JP 14609683A JP H0248097 B2 JPH0248097 B2 JP H0248097B2
- Authority
- JP
- Japan
- Prior art keywords
- coupler
- nucleus
- acid
- color
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 17
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 10
- 239000004332 silver Substances 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 125000000962 organic group Chemical group 0.000 claims description 3
- 239000000975 dye Substances 0.000 description 33
- 239000000839 emulsion Substances 0.000 description 22
- 239000010410 layer Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 20
- 230000015572 biosynthetic process Effects 0.000 description 12
- 238000003786 synthesis reaction Methods 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 108010010803 Gelatin Proteins 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 8
- 238000004061 bleaching Methods 0.000 description 7
- 239000000084 colloidal system Substances 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 125000001309 chloro group Chemical group Cl* 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 230000001235 sensitizing effect Effects 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000000862 absorption spectrum Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 150000001565 benzotriazoles Chemical group 0.000 description 2
- 150000001661 cadmium Chemical class 0.000 description 2
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 150000004780 naphthols Chemical class 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 1
- AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical class C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- ADAKRBAJFHTIEW-UHFFFAOYSA-N 1-chloro-4-isocyanatobenzene Chemical compound ClC1=CC=C(N=C=O)C=C1 ADAKRBAJFHTIEW-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical class [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- HAZJTCQWIDBCCE-UHFFFAOYSA-N 1h-triazine-6-thione Chemical class SC1=CC=NN=N1 HAZJTCQWIDBCCE-UHFFFAOYSA-N 0.000 description 1
- 150000001473 2,4-thiazolidinediones Chemical class 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- FWODUXONZIHDDF-UHFFFAOYSA-N 2-[2,4-bis(2,4,4-trimethylpentan-2-yl)phenoxy]octanoyl chloride Chemical compound C(C)(C)(CC(C)(C)C)C1=C(OC(C(=O)Cl)CCCCCC)C=CC(=C1)C(C)(C)CC(C)(C)C FWODUXONZIHDDF-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- PHPYXVIHDRDPDI-UHFFFAOYSA-N 2-bromo-1h-benzimidazole Chemical class C1=CC=C2NC(Br)=NC2=C1 PHPYXVIHDRDPDI-UHFFFAOYSA-N 0.000 description 1
- AYPSHJCKSDNETA-UHFFFAOYSA-N 2-chloro-1h-benzimidazole Chemical class C1=CC=C2NC(Cl)=NC2=C1 AYPSHJCKSDNETA-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 1
- KRTDQDCPEZRVGC-UHFFFAOYSA-N 2-nitro-1h-benzimidazole Chemical class C1=CC=C2NC([N+](=O)[O-])=NC2=C1 KRTDQDCPEZRVGC-UHFFFAOYSA-N 0.000 description 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 1
- SEEZWGFVHCMHJF-UHFFFAOYSA-N 2-nitrosophenol Chemical class OC1=CC=CC=C1N=O SEEZWGFVHCMHJF-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical class O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical class NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 description 1
- CBHTTYDJRXOHHL-UHFFFAOYSA-N 2h-triazolo[4,5-c]pyridazine Chemical class N1=NC=CC2=C1N=NN2 CBHTTYDJRXOHHL-UHFFFAOYSA-N 0.000 description 1
- OWIRCRREDNEXTA-UHFFFAOYSA-N 3-nitro-1h-indazole Chemical class C1=CC=C2C([N+](=O)[O-])=NNC2=C1 OWIRCRREDNEXTA-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- YLNKRLLYLJYWEN-UHFFFAOYSA-N 4-(2,2-dibutoxyethoxy)-4-oxobutanoic acid Chemical compound CCCCOC(OCCCC)COC(=O)CCC(O)=O YLNKRLLYLJYWEN-UHFFFAOYSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- FFAJEKUNEVVYCW-UHFFFAOYSA-N 4-n-ethyl-4-n-(2-methoxyethyl)-2-methylbenzene-1,4-diamine Chemical compound COCCN(CC)C1=CC=C(N)C(C)=C1 FFAJEKUNEVVYCW-UHFFFAOYSA-N 0.000 description 1
- UTMDJGPRCLQPBT-UHFFFAOYSA-N 4-nitro-1h-1,2,3-benzotriazole Chemical class [O-][N+](=O)C1=CC=CC2=NNN=C12 UTMDJGPRCLQPBT-UHFFFAOYSA-N 0.000 description 1
- GIQKIFWTIQDQMM-UHFFFAOYSA-N 5h-1,3-oxazole-2-thione Chemical compound S=C1OCC=N1 GIQKIFWTIQDQMM-UHFFFAOYSA-N 0.000 description 1
- 241000208140 Acer Species 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- IVBQSOKTYJPNSA-UHFFFAOYSA-N CCCCC(C(Cl)=O)OC1=CC=C(C(C)(C)CC(C)(C)C)C=C1C(C)(C)CC(C)(C)C Chemical compound CCCCC(C(Cl)=O)OC1=CC=C(C(C)(C)CC(C)(C)C)C=C1C(C)(C)CC(C)(C)C IVBQSOKTYJPNSA-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical class C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 description 1
- WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical class C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- FWNZSQVVCQVDOJ-UHFFFAOYSA-N butyl octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCC FWNZSQVVCQVDOJ-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical compound SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- LOCAIGRSOJUCTB-UHFFFAOYSA-N indazol-3-one Chemical class C1=CC=C2C(=O)N=NC2=C1 LOCAIGRSOJUCTB-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine group Chemical group N1=CCC2=CC=CC=C12 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 229910001867 inorganic solvent Inorganic materials 0.000 description 1
- 239000003049 inorganic solvent Substances 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- UKVIEHSSVKSQBA-UHFFFAOYSA-N methane;palladium Chemical compound C.[Pd] UKVIEHSSVKSQBA-UHFFFAOYSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- MVXLHYKEKXUFFZ-UHFFFAOYSA-N phenyl n-(3,4-dichlorophenyl)carbamate Chemical compound C1=C(Cl)C(Cl)=CC=C1NC(=O)OC1=CC=CC=C1 MVXLHYKEKXUFFZ-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003142 primary aromatic amines Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- HBCQSNAFLVXVAY-UHFFFAOYSA-N pyrimidine-2-thiol Chemical class SC1=NC=CC=N1 HBCQSNAFLVXVAY-UHFFFAOYSA-N 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003236 pyrrolines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- SRFKWQSWMOPVQK-UHFFFAOYSA-K sodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(2+) Chemical compound [Na+].[Fe+2].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O SRFKWQSWMOPVQK-UHFFFAOYSA-K 0.000 description 1
- UWSAIOMORQUEHN-UHFFFAOYSA-L sodium;2-[2-[carboxylatomethyl(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(5+) Chemical compound [Na+].[Fe+5].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O UWSAIOMORQUEHN-UHFFFAOYSA-L 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/34—Couplers containing phenols
- G03C7/346—Phenolic couplers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C275/40—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by nitrogen atoms not being part of nitro or nitroso groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯æ°æã·ã¢ã³è²çŽ 圢æã«ãã©ãŒãå«æã
ãã«ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ææã«é²å ãäžããã
ãšãçºè²çŸåããããšã«ããé žåãããè³éŠæäž
çŽã¢ãã³çŸåäž»è¬ãšè²çŽ 圢æã«ãã©ãŒãšãåå¿
ããè²ç»åã圢æããããäžè¬ã«ãã®æ¹æ³ã«ãã
ãŠã¯ãæžè²æ³ã«ããè²åçŸæ³ã䜿ãããéãç·ã
èµ€ãåçŸããããã«ã¯ãããããè£è²ã®é¢ä¿ã«ã
ãã€ãšããŒãããŒã³ããã·ã¢ã³ã®è²ç»åã圢æã
ããã ã·ã¢ã³è²ç»å圢æã«ãã©ãŒãšããŠã¯ããšããŒã«
é¡ããããã¯ããããŒã«é¡ãã«ãã©ãŒãšããŠå€ã
çšããããŠããããšãããåŸæ¥çšããããŠããã
ãšããŒã«é¡ããã³ããããŒã«é¡ããåŸãããè²ç»
åã«ã¯ããã€ãã®åé¡ç¹ãæ®ãããŠãããäŸãã°
ç±³åœç¹èš±2637531ããã³2423730å·æ现æžã«èšèŒã®
ïŒâã¢ã·ã«ã¢ããããšããŒã«ã·ã¢ã³ã«ãã©ãŒã«ã
ãåŸãããè²ç»åã¯ãäžè¬ã«ç±å ç¢æ§ãå£ããç±³
åœç¹èš±2369929ããã³2772162å·æ现æžã«èšèŒã®
ïŒïŒïŒâãžã¢ã·ã«ã¢ããããšããŒã«ã«ããåŸãã
ãè²ç»åã¯äžè¬ã«å å ç¢æ§ãå£ããïŒâãããã
ã·âïŒâãããã¢ããã·ã¢ã³ã«ãã©ãŒã¯ãäžè¬ã«
å ããã³ç±å ç¢æ§ã®äž¡é¢ã§äžååã§ããã äžæ¹ãç±³åœç¹èš±3446622ã3996253ã3758308ã
3880611å·ããã³ç¹éæ56â65134ãå57â
204543ãå57â204544ãå57â204545ãå58â
32249å·ãå58â33250ãå58â33251ãå58â
33252å·çã«èšèŒãããŠããïŒäœã«ãŠã¬ã€ãåºã
æããããšããŒã«ã·ã¢ã³ã«ãã©ãŒã¯ãå ã«è¿°ã¹ã
ä»ã®äžè¬çãªã·ã¢ã³ã«ãã©ãŒã«æ¯èŒããŠå å ç¢æ§
ãè¯ããšãããŠããããé·æã®ä¿åãèãããšãŸ
ã ååãšã¯èšããªãããŸããããã®ã«ãã©ãŒã®å€
ãã¯ãçºè²ã åã®å åã¹ãã¯ãã«ã®åžå極倧ãèµ€
é åã®æ¯èŒççæ³¢åŽã®ãšããã«ãã€ãããæ¯èŒç
åºãåžåæ²ç·ãæããŠãããããããã¯ç·é åã«
ãããªãåžåãæããŠããããããã«ã¯åžå極倧
ãçš®ã ã®æ¡ä»¶ã«ããå€åãããããããè²åçŸäž
奜ãŸãããªããã®ãå€ããããã«ãããã®ã«ãã©
ãŒã®å€ãã¯é«æ²žç¹ææ©æº¶åªã«å¯Ÿãã溶解æ§ãäœ
ããåççšä¹³å€ã«æ·»å ãããšãã«æ¶åºãããããš
ããæ¬ ç¹ãæããŠããã ãããã€ãŠæ¬çºæã®ç®çã¯ããããã®æ¬ ç¹ãæ¹
è¯ããå ããã³ç±ã«å¯Ÿããå ç¢æ§ã«ããããè²å
çŸäžå¥œãŸããåžåãæãããªããã€é«æ²žç¹ææ©æº¶
åªã«å¯ŸããŠæº¶è§£ãããããšããããããã·ã¢ã³è²
çŽ åœ¢æã«ãã©ãŒãçšããã«ã©ãŒåçæå ææãæ
äŸããããšã«ããã ãŸãæ¬çºæã®ä»ã®ç®çã¯ãçºè²çŸåäžã§ã®è²çŽ
圢æé床ããã³æ倧çºè²æ¿åºŠãé«ããç¹ã«ãã³ãž
ã«ã¢ã«ã³ãŒã«ãé€ããçºè²çŸåäžã§ãããããå
åã«é«ãã«ãã©ãŒãæäŸããããšã§ãããäžæ¹ã§
ã¯é žååã®åŒ±ãæŒçœæ¶²ãããã¯ç²åŽããæŒçœæ¶²ã§
åŠçããå Žåã«ãããŠãæ¿åºŠã®äœäžãã»ãšãã©ãª
ãã«ãã©ãŒãæäŸããããšã«ããã æ¬çºæã®ç®çã¯ã次ã®äžè¬åŒããã«ãã瀺ã
ããã«ãã©ãŒããã³ããããå«ãããã²ã³åéã«
ã©ãŒæå ææã«ããéæãããã åŒäžãR1ãšR2ã¯ããããççŽ æ°ïŒä»¥äžã®ç¬¬ïŒ
ã¢ã«ãã«åºãè¡šãããR3ã¯æ°ŽçŽ ååãããã²ã³
ååããŸãã¯ïŒäŸ¡ã®ææ©åºãè¡šãããR4ã¯ã¢ã«
ãã«åºãè¡šãããã¯ããã²ã³ååãè¡šããã
ã¯æ°ŽçŽ ååãŸãã¯ããã²ã³ååãè¡šãããïœã¯ïŒ
ãïŒã®æŽæ°ãè¡šãããïœãïŒä»¥äžã®ãšãã¯åã
ã§ãç°ãªã€ãŠããŠãããã 以äžR1ãR2ãR3ãR4ãããããã³ïœã«ã€
ããŠè©³è¿°ããã äžè¬åŒããã«ãããŠãR1ãR2ã¯ããããç
çŽ æ°ïŒä»¥äžã®ç¬¬ïŒã¢ã«ãã«åºãè¡šãããã奜ãŸã
ãã¯ççŽ æ°ïŒã22ã§ãããäžã§ãççŽ æ°ïŒïŒïœâ
ãªã¯ãã«åºïŒãç¹ã«å¥œãŸããã R3ã¯æ°ŽçŽ ååãããã²ã³ååããŸãã¯ïŒäŸ¡ã®
ææ©åºãè¡šãããããã奜ãŸããã¯æ°ŽçŽ ååãã¯
ãã«ååãäœçŽã¢ã«ãã«åºããŸãã¯äœçŽã¢ã«ã³ã
ã·åºã§ããã R4ã¯ã¢ã«ãã«åºãè¡šãããã奜ãŸããã¯ççŽ
æ°ïŒã22ã§ãããäžã§ãççŽ æ°ïŒã12ã®çŽéã®ã¢
ã«ãã«åºãç¹ã«å¥œãŸããã ã¯æ°ŽçŽ ååããŸãã¯ããã²ã³ååãè¡šãã
ãã奜ãŸããã¯æ°ŽçŽ ååãŸãã¯ã¯ãã«ååã§ã
ãã ã¯ããã²ã³ååãè¡šãããã奜ãŸããã¯ãã
çŽ ååãŸãã¯ã¯ãã«ååã§ãããäžã§ãã¯ãã«å
åãç¹ã«å¥œãŸããããŸã眮æåºïŒžã®æ°ïœã¯ïŒãïŒ
ã§ãããããã奜ãŸããã¯ïœïŒïŒãïŒã§ãããã
ã®çœ®æäœçœ®ã¯ãŠã¬ã€ãåºã«å¯ŸããŠãïŒäœãïŒäœã
ïŒäœã奜ãŸãããäžã§ãïŒäœïŒïœïŒïŒã®å ŽåïŒã
ãããã¯ïŒãïŒâäœïŒïœïŒïŒã®å ŽåïŒãç¹ã«å¥œãŸ
ããã åèšäžè¬åŒããã§ç€ºãããã«ãã©ãŒïŒä»¥äžæ¬
çºæã®ã«ãã©ãŒãšããïŒã¯ãããšããŒã«ã®ïŒäœã«
ããã²ã³ååã§çœ®æãããããšãã«ãŠã¬ã€ãåºã
æããïŒäœã«äžè¬åŒããã§èŠå®ããã¢ã·ã«ã¢ã
ãåºãæããŠããããšãç¹åŸŽã§ããããã®ãã
çš®ã ã®å¥œé©ãªç¹æ§ãåŸããããã®ãšèããããã ããªãã¡ãæ¬çºæã®ã«ãã©ãŒããåŸãããè²ç»
åã¯ãåå åžåç¹æ§ãè¯å¥œã§ãããç±ããã³å ã«
察ããå ç¢æ§ã«ããããŠãããæ¬çºæã®ã«ãã©ãŒ
ã¯é«æ²žç¹ææ©æº¶å€ã«å¯Ÿãã溶解æ§ã«ãããããã
ã«ã¯é žååã®åŒ±ãæŒçœæ¶²ãããã¯ç²åŽããæŒçœæ¶²
ã§åŠçããå Žåã§ãçºè²æ¿åºŠã®äœäžãã»ãšãã©ãª
ããšããæ§è³ªãæããŠããã äžæ¹ãåèšå ¬ç¥ã®ã·ã¢ã³ã«ãã©ãŒã®æè¡ãèšèŒ
ããç±³åœç¹èš±3446622ã3996253ã3758308ã
3880611å·ãç¹éæ56â15134å·ãå57â204543ã
å57â204544ãå57â204545ãå58â33249ãå
58â33250ãå58â33251ãå58â33252å·æ现æž
ã«ã¯æ¬çºæã®ã«ãã©ãŒã«ã€ããŠã¯ç€ºåãããããŠ
ããããæ¬çºæã®ã«ãã©ãŒãçºæ®ãããå¹æã¯å š
ãé©ãã¹ããã®ããã€ãã 次ã«æ¬çºæã®ç¯å²ã«å«ãŸããå ·äœçãªã«ãã©ãŒ
ãäŸç€ºããããæ¬çºæã«çšããããæ¬çºæã®ã«ã
ã©ãŒã¯ãããã«éå®ããããã®ã§ã¯ãªãã
ãã«ã©ãŒåçæå ææã«é¢ãããã®ã§ããã ããã²ã³åéåçæå ææã«é²å ãäžããã
ãšãçºè²çŸåããããšã«ããé žåãããè³éŠæäž
çŽã¢ãã³çŸåäž»è¬ãšè²çŽ 圢æã«ãã©ãŒãšãåå¿
ããè²ç»åã圢æããããäžè¬ã«ãã®æ¹æ³ã«ãã
ãŠã¯ãæžè²æ³ã«ããè²åçŸæ³ã䜿ãããéãç·ã
èµ€ãåçŸããããã«ã¯ãããããè£è²ã®é¢ä¿ã«ã
ãã€ãšããŒãããŒã³ããã·ã¢ã³ã®è²ç»åã圢æã
ããã ã·ã¢ã³è²ç»å圢æã«ãã©ãŒãšããŠã¯ããšããŒã«
é¡ããããã¯ããããŒã«é¡ãã«ãã©ãŒãšããŠå€ã
çšããããŠããããšãããåŸæ¥çšããããŠããã
ãšããŒã«é¡ããã³ããããŒã«é¡ããåŸãããè²ç»
åã«ã¯ããã€ãã®åé¡ç¹ãæ®ãããŠãããäŸãã°
ç±³åœç¹èš±2637531ããã³2423730å·æ现æžã«èšèŒã®
ïŒâã¢ã·ã«ã¢ããããšããŒã«ã·ã¢ã³ã«ãã©ãŒã«ã
ãåŸãããè²ç»åã¯ãäžè¬ã«ç±å ç¢æ§ãå£ããç±³
åœç¹èš±2369929ããã³2772162å·æ现æžã«èšèŒã®
ïŒïŒïŒâãžã¢ã·ã«ã¢ããããšããŒã«ã«ããåŸãã
ãè²ç»åã¯äžè¬ã«å å ç¢æ§ãå£ããïŒâãããã
ã·âïŒâãããã¢ããã·ã¢ã³ã«ãã©ãŒã¯ãäžè¬ã«
å ããã³ç±å ç¢æ§ã®äž¡é¢ã§äžååã§ããã äžæ¹ãç±³åœç¹èš±3446622ã3996253ã3758308ã
3880611å·ããã³ç¹éæ56â65134ãå57â
204543ãå57â204544ãå57â204545ãå58â
32249å·ãå58â33250ãå58â33251ãå58â
33252å·çã«èšèŒãããŠããïŒäœã«ãŠã¬ã€ãåºã
æããããšããŒã«ã·ã¢ã³ã«ãã©ãŒã¯ãå ã«è¿°ã¹ã
ä»ã®äžè¬çãªã·ã¢ã³ã«ãã©ãŒã«æ¯èŒããŠå å ç¢æ§
ãè¯ããšãããŠããããé·æã®ä¿åãèãããšãŸ
ã ååãšã¯èšããªãããŸããããã®ã«ãã©ãŒã®å€
ãã¯ãçºè²ã åã®å åã¹ãã¯ãã«ã®åžå極倧ãèµ€
é åã®æ¯èŒççæ³¢åŽã®ãšããã«ãã€ãããæ¯èŒç
åºãåžåæ²ç·ãæããŠãããããããã¯ç·é åã«
ãããªãåžåãæããŠããããããã«ã¯åžå極倧
ãçš®ã ã®æ¡ä»¶ã«ããå€åãããããããè²åçŸäž
奜ãŸãããªããã®ãå€ããããã«ãããã®ã«ãã©
ãŒã®å€ãã¯é«æ²žç¹ææ©æº¶åªã«å¯Ÿãã溶解æ§ãäœ
ããåççšä¹³å€ã«æ·»å ãããšãã«æ¶åºãããããš
ããæ¬ ç¹ãæããŠããã ãããã€ãŠæ¬çºæã®ç®çã¯ããããã®æ¬ ç¹ãæ¹
è¯ããå ããã³ç±ã«å¯Ÿããå ç¢æ§ã«ããããè²å
çŸäžå¥œãŸããåžåãæãããªããã€é«æ²žç¹ææ©æº¶
åªã«å¯ŸããŠæº¶è§£ãããããšããããããã·ã¢ã³è²
çŽ åœ¢æã«ãã©ãŒãçšããã«ã©ãŒåçæå ææãæ
äŸããããšã«ããã ãŸãæ¬çºæã®ä»ã®ç®çã¯ãçºè²çŸåäžã§ã®è²çŽ
圢æé床ããã³æ倧çºè²æ¿åºŠãé«ããç¹ã«ãã³ãž
ã«ã¢ã«ã³ãŒã«ãé€ããçºè²çŸåäžã§ãããããå
åã«é«ãã«ãã©ãŒãæäŸããããšã§ãããäžæ¹ã§
ã¯é žååã®åŒ±ãæŒçœæ¶²ãããã¯ç²åŽããæŒçœæ¶²ã§
åŠçããå Žåã«ãããŠãæ¿åºŠã®äœäžãã»ãšãã©ãª
ãã«ãã©ãŒãæäŸããããšã«ããã æ¬çºæã®ç®çã¯ã次ã®äžè¬åŒããã«ãã瀺ã
ããã«ãã©ãŒããã³ããããå«ãããã²ã³åéã«
ã©ãŒæå ææã«ããéæãããã åŒäžãR1ãšR2ã¯ããããççŽ æ°ïŒä»¥äžã®ç¬¬ïŒ
ã¢ã«ãã«åºãè¡šãããR3ã¯æ°ŽçŽ ååãããã²ã³
ååããŸãã¯ïŒäŸ¡ã®ææ©åºãè¡šãããR4ã¯ã¢ã«
ãã«åºãè¡šãããã¯ããã²ã³ååãè¡šããã
ã¯æ°ŽçŽ ååãŸãã¯ããã²ã³ååãè¡šãããïœã¯ïŒ
ãïŒã®æŽæ°ãè¡šãããïœãïŒä»¥äžã®ãšãã¯åã
ã§ãç°ãªã€ãŠããŠãããã 以äžR1ãR2ãR3ãR4ãããããã³ïœã«ã€
ããŠè©³è¿°ããã äžè¬åŒããã«ãããŠãR1ãR2ã¯ããããç
çŽ æ°ïŒä»¥äžã®ç¬¬ïŒã¢ã«ãã«åºãè¡šãããã奜ãŸã
ãã¯ççŽ æ°ïŒã22ã§ãããäžã§ãççŽ æ°ïŒïŒïœâ
ãªã¯ãã«åºïŒãç¹ã«å¥œãŸããã R3ã¯æ°ŽçŽ ååãããã²ã³ååããŸãã¯ïŒäŸ¡ã®
ææ©åºãè¡šãããããã奜ãŸããã¯æ°ŽçŽ ååãã¯
ãã«ååãäœçŽã¢ã«ãã«åºããŸãã¯äœçŽã¢ã«ã³ã
ã·åºã§ããã R4ã¯ã¢ã«ãã«åºãè¡šãããã奜ãŸããã¯ççŽ
æ°ïŒã22ã§ãããäžã§ãççŽ æ°ïŒã12ã®çŽéã®ã¢
ã«ãã«åºãç¹ã«å¥œãŸããã ã¯æ°ŽçŽ ååããŸãã¯ããã²ã³ååãè¡šãã
ãã奜ãŸããã¯æ°ŽçŽ ååãŸãã¯ã¯ãã«ååã§ã
ãã ã¯ããã²ã³ååãè¡šãããã奜ãŸããã¯ãã
çŽ ååãŸãã¯ã¯ãã«ååã§ãããäžã§ãã¯ãã«å
åãç¹ã«å¥œãŸããããŸã眮æåºïŒžã®æ°ïœã¯ïŒãïŒ
ã§ãããããã奜ãŸããã¯ïœïŒïŒãïŒã§ãããã
ã®çœ®æäœçœ®ã¯ãŠã¬ã€ãåºã«å¯ŸããŠãïŒäœãïŒäœã
ïŒäœã奜ãŸãããäžã§ãïŒäœïŒïœïŒïŒã®å ŽåïŒã
ãããã¯ïŒãïŒâäœïŒïœïŒïŒã®å ŽåïŒãç¹ã«å¥œãŸ
ããã åèšäžè¬åŒããã§ç€ºãããã«ãã©ãŒïŒä»¥äžæ¬
çºæã®ã«ãã©ãŒãšããïŒã¯ãããšããŒã«ã®ïŒäœã«
ããã²ã³ååã§çœ®æãããããšãã«ãŠã¬ã€ãåºã
æããïŒäœã«äžè¬åŒããã§èŠå®ããã¢ã·ã«ã¢ã
ãåºãæããŠããããšãç¹åŸŽã§ããããã®ãã
çš®ã ã®å¥œé©ãªç¹æ§ãåŸããããã®ãšèããããã ããªãã¡ãæ¬çºæã®ã«ãã©ãŒããåŸãããè²ç»
åã¯ãåå åžåç¹æ§ãè¯å¥œã§ãããç±ããã³å ã«
察ããå ç¢æ§ã«ããããŠãããæ¬çºæã®ã«ãã©ãŒ
ã¯é«æ²žç¹ææ©æº¶å€ã«å¯Ÿãã溶解æ§ã«ãããããã
ã«ã¯é žååã®åŒ±ãæŒçœæ¶²ãããã¯ç²åŽããæŒçœæ¶²
ã§åŠçããå Žåã§ãçºè²æ¿åºŠã®äœäžãã»ãšãã©ãª
ããšããæ§è³ªãæããŠããã äžæ¹ãåèšå ¬ç¥ã®ã·ã¢ã³ã«ãã©ãŒã®æè¡ãèšèŒ
ããç±³åœç¹èš±3446622ã3996253ã3758308ã
3880611å·ãç¹éæ56â15134å·ãå57â204543ã
å57â204544ãå57â204545ãå58â33249ãå
58â33250ãå58â33251ãå58â33252å·æ现æž
ã«ã¯æ¬çºæã®ã«ãã©ãŒã«ã€ããŠã¯ç€ºåãããããŠ
ããããæ¬çºæã®ã«ãã©ãŒãçºæ®ãããå¹æã¯å š
ãé©ãã¹ããã®ããã€ãã 次ã«æ¬çºæã®ç¯å²ã«å«ãŸããå ·äœçãªã«ãã©ãŒ
ãäŸç€ºããããæ¬çºæã«çšããããæ¬çºæã®ã«ã
ã©ãŒã¯ãããã«éå®ããããã®ã§ã¯ãªãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
以äžã«æ¬çºæã®ã«ãã©ãŒã®ä»£è¡šçãªåæã«ãŒã
ããã³åæäŸã瀺ãã åæäŸ ïŒ ïŒäŸç€ºã«ãã©ãŒïŒã®åæïŒ ïŒâã¢ããâïŒâãããããšããŒã«170ïœãã
ã«ãšã³1.5ã®ãã«ãšã³ã«åæ£ããã宀枩äžã«ã
ïœâã¯ãã«ããšãã«ã€ãœã·ã¢ããŒã150ïœããã«
ãšã³300mlã«æº¶è§£ãã溶液ã滎äžããã滎äžçµäº
åŸãïŒæéå ç±éæµããããã®åŸã宀枩ãŸã§å·åŽ
ããçµæ¶ãåããã¡ã¿ããŒã«æŽæµãè¡ãªãã也
ç¥ããŠæ·¡é»è²ã®åºäœ280ïœãåŸãã ãã®ïŒâïŒïŒâã¯ãã«ããšãã«ïŒãŠã¬ã€ãâïŒ
âãããããšããŒã«30.8ïœããã©ãžãŠã âççŽ è§Š
åªïŒïœãšå ±ã«ãžã¡ãã«ã¢ã»ãã¢ãã250mlã«å ãã
ãªãŒãã¯ã¬ãŒãã«ãŠæ¥è§Šéå ãè¡ãªã€ããçè«é
ã®æ°ŽçŽ ãæ¶è²»ããåŸã觊åªãå¥ããåŸããã
液ïŒåå¿æ¶²ïŒã«ãïŒâïŒïŒïŒïŒâãžâtertâãªã¯
ãã«ããšããã·ïŒãããµãã€ã«ã¯ããªã49ïœãå
ãã60âã§ïŒæéåå¿ããããåå¿çµäºåŸãæ··å
ç©ãæ°Žã«ãããé ¢é žãšãã«ã§æœåºããæ°ŽæŽããã®
ã¡ã溶åªãçå»ããåŸãããæ®æž£ã«ïœâãããµã³
ãå ããçµæ¶ãåããŠäŸç€ºã«ãã©ãŒïŒã52ïœåŸ
ããïŒm.p.165ã167âïŒ å çŽ åæå€ ïŒ£ïŒ70.90 ïŒ8.60 ïŒ6.06 ClïŒ
5.01 èšç®å€ ïŒ71.12 ïŒ8.44 ïŒ6.07 ClïŒ
5.12 åæäŸ ïŒ ïŒäŸç€ºã«ãã©ãŒïŒã®åæïŒ ïŒâã¢ããâïŒâãããããšããŒã«170ïœãšã
ãšãã«ïŒïŒïŒâãžã¯ãã«âããšãã«ã«ã«ãã¡ãŒã
282ïœãããªãšãã«ã¢ãã³15mlãã¢ã»ããããªã«
800mlã«å ããã¹ããŒã ãã¹äžã§éæµãïŒæéç¶
ãããåå¿çµäºåŸã宀枩ãŸã§å·åŽããæåºããçµ
æ¶ãåããã¢ã»ããããªã«ã§æŽæµããŠïŒâïŒïŒïŒ
ïŒâãžã¯ãã«ããšãã«ïŒãŠã¬ã€ãâïŒâãããã
ãšããŒã«238ïœãåŸãã ãã®çµæ¶34.2ïœãåæäŸïŒãšåæ§ã«ããŠãªãŒã
ã¯ã¬ãŒãã§æ¥è§Šéå ãè¡ãªããåŸãããåå¿æ¶²
ïŒæ¶²ïŒã«ïŒâïŒïŒïŒïŒâãžâtertâãªã¯ãã«ããš
ããã·ïŒãªã¯ã¿ãã€ã«ã¯ããªã52ïœãå ããåæ
äŸïŒãšåæ§ã«ããŠäŸç€ºã«ãã©ãŒïŒã38ïœåŸãã
ïŒm.p.147âïŒâïŒ å çŽ åæå€ ïŒ£ïŒ68.45 ïŒ8.19 ïŒ5.46 ClïŒ
9.26 èšç®å€ ïŒ68.42 ïŒ8.14 ïŒ5.57 ClïŒ
9.39 ä»ã®ã«ãã©ãŒãåæäŸïŒåã¯åæäŸïŒãšåæ§ã«
ããŠåæã§ããã æ¬çºæãçšããŠäœãããåçä¹³å€ã«ã¯æ¬çºæ以
å€ã®è²å圢æã«ãã©ãŒãå«ãã§ããããã«ãã©ãŒ
ã¯ååäžã«ãã©ã¹ãåºãšãã°ããçæ°Žåºãæãã
éæ¡æ£ã®ãã®ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«
察ãïŒåœéæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãã
ãããŸãè²è£æ£ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒã
ãããã¯çŸåã«ãšããªã€ãŠçŸåæå¶å€ãæŸåºãã
ã«ãã©ãŒïŒããããDIRã«ãã©ãŒïŒãå«ãã§ãã
ããã«ãã©ãŒã¯ã«ãããªã³ã°åå¿ã®çæç©ãç¡è²
ã§ãããããªã«ãã©ãŒã§ãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»åã³ãããã€ã«
ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ããã ããŒã³ãçºè²ã«ãã©ãŒãšããŠã¯ãã©ãŸãã³ç³»å
åç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«å
åç©ãªã©ãçšããããšãã§ããç¹ã«ãã©ãŸãã³ç³»
ååç©ã¯æå©ã§ããã ã·ã¢ã³çºè²ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãã æ¬çºæã®ã«ãã©ãŒã¯åäžå±€ã«äºçš®ä»¥äžå«ãããš
ãã§ãããåäžã®ååç©ãç°ãªãïŒã€ä»¥äžã®å±€ã«
å«ãã§ãããã æ¬çºæã®ã«ãã©ãŒã¯ãäžè¬ã«ä¹³å€å±€äžã®éïŒã¢
ã«åœãïŒÃ10-3ã¢ã«ãªããïŒÃ10-1ã¢ã«ã奜ãŸã
ãã¯ïŒÃ10-2ã¢ã«ãªããïŒÃ10-1ã¢ã«æ·»å ãã
ããäžèšã®ã«ãã©ãŒãšäœµçšãããå Žåã¯åãè²ã«
çºè²ããã«ãã©ãŒã®å šéšã®æ·»å éãäžèšã®ç¯å²å
ã«å ¥ãã®ã奜ãŸããã æ¬çºæã®ã«ãã©ãŒããã³ãã®ä»ã®äžèšã®ã«ãã©
ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯å ¬ç¥ã®æ¹
æ³ããšãã°ç±³åœç¹èš±ç¬¬2322027å·ã«èšèŒã®æ¹æ³ãª
ã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãš
ã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«ã¿ã¬ãŒ
ããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«ããªã¹ã
ãšãŒããããªããšãã«ããªã¹ããšãŒããããªã¯ã¬
ãžã«ããªã¹ããšãŒãããªã¯ãã«ããã«ããªã¹ããš
ãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒããšãã°ã¢ã»ã«ã¯ãš
ã³é žããªããã«ïŒãå®æ¯éŠé žãšã¹ãã«ïŒããšãã°
å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒããšãã°
ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé žãšã¹ãã«é¡
ïŒããšãã°ãžãããã·ãšãã«ãµã¯ã·ããŒãããžãª
ã¯ãã«ã¢ãŒã¬ãŒãïŒãªã©ããŸãã¯æ²žç¹çŽ30âä¹è³
150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ãé ¢é žã
ãã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒããããããª
ã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ãã«ã€ãœ
ããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ããŒãã
ã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã«æº¶è§£ããã®ã¡ã
芪氎æ§ã³ãã€ãã«å解ããããäžèšã®é«æ²žç¹ææ©
溶åªãšäœæ²žç¹ç¡æ©æº¶åªãšãæ··åããŠçšããŠãã
ãã ãŸãç¹å ¬æ51â39853ãç¹éæ51â59943ã«èšèŒ
ãããŠããéåç©ã«ããå解æ³ã䜿çšããããšã
ã§ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ïŒããšãã°ç±³åœç¹èš±3533794å·ã«èšèŒã®ãã®ïŒã
ïŒâãã¢ãŸãªãã³ååç©ïŒããšãã°ç±³åœç¹èš±
3314794å·ãå3352681å·ã«èšèŒã®ãã®ïŒããã³ãŸ
ããšãã³ååç©ïŒããšãã°ç¹éæ46â2784å·ã«èš
èŒã®ãã®ïŒãã±ã€ãé žãšã¹ãã«ååç©ïŒããšãã°
ç±³åœç¹èš±3705805å·ãå3707375å·ã«èšèŒã®ãã®ïŒã
ãã¿ãžãšã³ååç©ïŒããšãã°ç±³åœç¹èš±4045229å·
ã«èšèŒã®ãã®ïŒããããã¯ãã³ãŸãªãã·ãŸãŒã«å
åç©ïŒããšãã°ç±³åœç¹èš±3700455å·ã«èšèŒã®ãã®ïŒ
ãçšããããšãã§ãããããã«ç±³åœç¹èš±3499762
å·ãç¹éæ54â48535å·ã«èšèŒã®ãã®ãçšããã
ãšãã§ããã玫å€ç·åžåæ§ã®ã«ãã©ãŒïŒããšãã°
αâããããŒã«ç³»ã®ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒïŒã
玫å€ç·åžåæ§ã®ããªããŒãªã©ãçšããŠããããã
ããã®çŽ«æ Œç·åžåå€ã¯ç¹å®ã®å±€ã«åªæãããŠãã
ãã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et aiè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿æŽããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ãããããçšããŠãããã åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®
çæããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããª
ãã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³
ãçšããããšãã§ããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã®ä»¥
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒã¹ç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ããé ž
åŠçãŒã©ãã³ãBull.Soc.Sci.Phot.Japan.No.16ã
30é ïŒ1966ïŒã«èšèŒããããããªé µçŽ åŠçãŒã©ã
ã³ãçšããŠãããããŸãããŒã©ãã³ã®å æ°Žå解ç©
ãé µçŽ å解ç©ãçšããããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯ãæå ææã®
補é å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªã
é²æ¢ããããã¯åçæ§èœãå®å®åãããç®çã§ã
çš®ã ã®ååç©ãå«æãããããšãã§ãããããªã
ã¡ã¢ãŸãŒã«é¡ããšãã°ãã³ãŸãã¢ãŸãªãŠã å¡©ãã
ããã€ã³ããŸãŒã«é¡ãããããã³ãºã€ãããŸãŒã«
é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ãããã¢ãã³ãº
ã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãŸãŒã«é¡ãã¡ã«
ã«ãããã³ãŸãã¢ãŸãŒã«é¡ãã¡ã«ã«ãããã³ãºã€
ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãžã¢ãŸãŒã«é¡ãã¢
ããããªã¢ãŸãŒã«é¡ããã³ãŸããªã¢ãŸãŒã«é¡ãã
ãããã³ãŸããªã¢ãŸãŒã«é¡ãã¡ã«ã«ããããã©ãŸ
ãŒã«é¡ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«ãããã
ã©ãŸãŒã«ïŒãªã©ïŒã¡ã«ã«ããããªããžã³é¡ïŒã¡ã«
ã«ããããªã¢ãžã³é¡ïŒããšãã°ãªããµãŸãªã³ããª
ã³ã®ãããªããªã±ãååç©ïŒã¢ã¶ã€ã³ãã³é¡ãã
ãšãã°ããªã¢ã¶ã€ã³ãã³é¡ãããã©ã¢ã¶ã€ã³ãã³
é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒãïŒã3aãïŒïŒ
ããã©ã¶ã€ã³ãã³é¡ããã³ã¿ã¢ã¶ã€ã³ãã³é¡ãª
ã©ïŒãã³ãŒã³ããªã¹ã«ããªã³é žããã³ãŒã³ã¹ã«ã
ã€ã³é žããã³ãŒã³ã¹ã«ããªã³é žã¢ããçã®ãããª
ã«ããªé²æ¢å€ãŸãã¯å®å®å€ãšããŠç¥ãããå€ãã®
ååç©ãå ããããšãã§ããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯æ床äž
æãã³ã³ãã©ã¹ãäžæããŸãã¯çŸåä¿é²ã®ç®ç
ã§ãäŸãã°ããªã¢ã«ãã¬ã³ãªãã·ããŸãã¯ãã®ãš
ãŒãã«ããšã¹ãã«ãã¢ãã³ãªã©ã®èªå°äœãããªãš
ãŒãã«ååç©ãããªã¢ã«ããªãªã³é¡ãåçŽã¢ã³ã¢
ããŠã å¡©ååç©ããŠã¬ã¿ã³èªå°äœãå°¿çŽ èªå°äœã
ã€ãããŸãŒã«èªå°äœãïŒâãã©ãŸãªãã³é¡çãå«
ãã§ãããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå å¢æãããŠãããçšãããã
è²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€
åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããã
âã©âã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããª
ã«è²çŽ ãããã³ãããªããœããŒã«è²çŽ ãå å«ãã
ããç¹ã«æçšãªç¹è²ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±ããè²çŽ
ã§ããããããã®è²çŽ é¡ã«ã¯å¡©åºæ§ç°ç¯ç°æ žãšã
ãŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããã
ãé©çšã§ãããããªãã¡ããããªã³æ žããªããµãŸ
ãªã³æ žãããªãŸãªã³æ žããããŒã«æ žããªããµãŸãŒ
ã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸ
ãŒã«æ žãããã©ãŸãŒã«æ žãããªãžã³æ žãªã©ïŒãã
ãã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³
ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãã
ãªãã¡ãã€ã³ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³
æ žãã€ã³ããŒã«æ žããã³ãºãªããµãŸãŒã«æ žããã
ããªããµãŸãŒã«æ žããã³ãŸãã¢ãŸãŒã«æ žãããã
ãã¢ãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€
ãããŸãŒã«æ žããããªã³æ žãªã©ãé©çšã§ãããã
ããã®æ žã¯ççŽ ååäžçœ®æãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³â2.4âãžãªã³æ žããâããã³æ žãããªãã«
ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšãã
ããšãã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšããããã å¢æè²çŽ ãšãšãã«ããã®èªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããããšãã°å«ããçŽ ç°ç¯ç°åºã§çœ®æã
ããã¢ããã¹ãã«ãã³ååç©ãè³éŠæææ©é žãã«
ã ã¢ã«ãããçž®åç©ãã«ãããŠã å¡©ãã¢ã¶ã€ã³ã
ã³ååç©ãªã©ãå«ãã§ãããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«ãã€ã«ã¿ãŒææãšããŠããããã¯ã€ã©
ãžãšãŒã·ãšã³é²æ¢ãã®ä»çš®ã ã®ç®çã§æ°Žæº¶æ§ææ
ãå«æããŠããããã®ãããªææã«ã¯ãªããœããŒ
ã«ææããããªããœããŒã«ææãã¹ããªã«ææã
ã¡ãã·ã¢ãã³ææãã·ã¢ãã³ææåã³ã¢ãŸææã
å å«ããããäžã§ããªããœããŒã«ææïŒãããªã
ãœããŒã«ææåã³ã¡ãã·ã¢ãã³ææãæçšã§ã
ãã æ¬çºæãçšããŠã€ããããæå ææã«ãããŠã
åçä¹³å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ãã¹ã
ã«ãã³ç³»ãããªã¢ãžã³ç³»ããªããµãŸãŒã«ç³»ããã
ã¯ã¯ããªã³ç³»ãªã©ã®å¢çœå€ãå«ãã§ãããããã
ãã¯æ°Žæº¶æ§ã®ãã®ã§ãããããŸãæ°Žäžæº¶æ§ã®å¢çœ
å€ãåæ£ç©ã®åœ¢ã§çšããŠãããã æ¬çºæãå®æœããã«éããŠäžèšã®å ¬ç¥ã®éè²é²
æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšãã
è²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããšã
ã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ãäŸãã°ãã
ãã€ãããã³èªå°äœã没é£åé žèªå°äœãïœâã¢ã«
ã³ãã·ããšããŒã«é¡ãïœâãªãã·ããšããŒã«èªå°
äœããã¹ããšããŒã«é¡çãããã æ¬çºæãçšããŠäœãããæå ææã¯è²ã«ããªé²
æ¢å€ãšããŠããã€ãããã³èªå°äœãã¢ããããšã
ãŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é žèª
å°äœãªã©ãå«æããŠãããã æ¬çºæã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªãå
å æ床ãæããå€å±€å€è²åçææã«ãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãç·ææ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ã
åã å°ãªããšãäžã€æããããããã®å±€ã®é åºã¯
å¿ èŠã«å¿ããŠä»»æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·
ã¢ã³åœ¢æã«ãã©ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã圢
æã«ãã©ãŒããéææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ã
ã©ãŒãããããå«ãã®ãéåžžã§ããããå Žåã«ã
ãç°ãªãçµåãããšãããšãã§ããã æ¬çºæã®æå ææã®åçåŠçã«ã¯ãå ¬ç¥ã®æ¹æ³
ã®ããããçšããããšãã§ãããåŠç液ã«ã¯å ¬ç¥
ã®ãã®ãçšããããšãã§ãããåŠç枩床ã¯æ®é18
âãã50âã®éã«éžã°ãããã18âããäœã枩床
ãŸãã¯50âãããã枩床ãšããŠãããã ã«ã©ãŒçŸå液ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšãã§
ããã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠããã ã«ã©ãŒçŸå液ã¯ãã®ã»ãã¢ã«ã«ãªéå±ã®äºç¡«é ž
å¡©ãçé žå¡©ãããŠé žå¡©ããã³ãªã³é žå¡©ã®åŠãPHç·©
è¡å€ãèåç©ãæ²åç©ããã³ææ©ã«ããªé²æ¢å€ã®
åŠãçŸåæå¶å€ãªããã«ããªé²æ¢å€ãªã©ãå«ãã
ãšãã§ããããŸãå¿ èŠã«å¿ããŠã硬氎è»åå€ãã
ãããã·ã«ã¢ãã³ã®åŠãä¿æå€ããã³ãžã«ã¢ã«ã³
ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãææ©æº¶å€ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãåçŽã¢ã³ã¢ããŠã å¡©ãã¢
ãã³é¡ã®åŠãçŸåä¿é²å€ãè²çŽ 圢æã«ãã©ãŒã競
äºã«ãã©ãŒããããªãŠã ãããã€ãã©ã€ãã®åŠã
ãã¶ããå€ãïŒâããšãã«âïŒâãã©ãŸãªãã³ã®
åŠãè£å©çŸåè¬ãç²æ§ä»äžå€ãç±³åœç¹èš±4083723
å·ã«èšèŒã®ããªã«ã«ãã³é žç³»ãã¬ãŒãå€ã西ç¬å ¬
éïŒOLSïŒ2622950å·ã«èšèŒã®é žåé²æ¢å€ãªã©ã
å«ãã§ãããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«è¡ãªãããŠããããæŒçœå€ãšããŠã¯
éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé ïŒïŒ
ãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³é¡ãã
ãããœååç©ãªã©ãçšãããããããšãã°ããšãª
ã·ã¢ã³ååç©ãéã¯ãã é žå¡©ãéïŒïŒãŸãã¯ã³
ãã«ãïŒïŒã®ææ©é¯å¡©ãããšãã°ãšãã¬ã³ãžã¢
ãã³åé ¢é žããããªãããªé ¢é žãïŒïŒïŒâãžã¢ã
ãâïŒâãããããŒã«åé ¢é žãªã©ã®ã¢ããããªã«
ã«ãã³é žé¡ãããã¯ã¯ãšã³é žãé ç³é žããªã³ãŽé ž
ãªã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ãéãã³ã¬ã³é ž
å¡©ïŒããããœããšããŒã«ãªã©ãçšããããšãã§ã
ãããããã®ãã¡ããšãªã·ã¢ã³åã«ãªããšãã¬ã³
ãžã¢ãã³åé ¢é žéïŒïŒãããªãŠã ããã³ãšãã¬
ã³ãžã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ããŠã ã¯ç¹ã«æ
çšã§ããããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒé¯å¡©
ã¯ç¬ç«ã®æŒçœå€ã«ãããŠããäžæµŽæŒçœå®ç液ã«ã
ããŠãæçšã§ããã æŒçœãŸãã¯æŒçœå®ç液ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
35732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã 以äžãæ¬çºæã®å®æœäŸãæ²ããŠå ·äœçã«èª¬æã
ãããæ¬çºæã¯ãããã«éå®ããããã®ã§ã¯ãª
ãã å®æœäŸ ã»ã«ããŒã¹ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«
äžèšã®é ã§ä¹³å€å±€ããã³ä¿è·å±€ãå¡åžããŠè©Šæ
ããäœè£œããã æ¬çºæã®ã«ãã©ãŒïŒ100ïœã«ããžããã«ãã¿ã¬
ãŒã50c.c.ããã³é ¢é žãšãã«100c.c.ãå ã60âã§å
ç±æº¶è§£ãããã®æº¶æ¶²ããŒã©ãã³100ïœããã³ãã
ã·ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã 10ïœãå«ã50
âã®æ°Žæº¶æ¶²1000mlã«æ··åãããã¢ãžãã€ã¶ãŒã«ã
ã€ãŠé«éæ¹æããŠåŸ®çŽ°ãªã«ãã©ãŒåæ£ç©ãåŸãã ãã®ã«ãã©ãŒåæ£ç©350ïœã«éã80ïœãæ²åé
ãšèåéã®ã¢ã«æ¯ãïŒå¯Ÿ94ã§ããæ²èåéä¹³å€ïŒ
Kgãå ããäžèšæ¯æäœäžã«ã«ãã©ãŒå¡åžéãïŒÃ
10-4ã¢ã«ïŒm2ã«ãªãããã«å¡åžããã ãã®å±€ã®äžã«ä¹Ÿç¥èå1ÎŒã®ãŒã©ãã³ä¿è·å±€ã
å¡åžããŠè©Šæãäœè£œããã åæ§ã®æ¹æ³ã«ããã«ãã©ãŒïŒã®ä»£ãã«æ¬çºæã®
ã«ãã©ãŒïŒïŒïŒïŒïŒãçšããŠãã«ãã©ãŒå¡åžé
ïŒã¢ã«ïŒm2ïŒããã³ã«ãã©ãŒãšéã®æ··åæ¯çãè©Š
æãšåãã«ãªãããã«ããŠè©Šæãããäœ
補ããã æŽã«æ¯èŒã«ãã©ãŒãšããŠæ¬çºæå€ã®ã«ãã©ãŒïŒ
ïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒãçšããŠè©Šæãšå šãåã
æ¹æ³ã§è©Šæãããäœè£œããã ãããã®è©Šæã«å åŠã¯ãµããéããŠé²å ãäžã
ãã®ã¡äžèšã®åŠçå·¥çšã«ãŠ38âã§çŸååŠçãè¡ãª
ã€ãã ïŒ ã«ã©ãŒçŸåâŠïŒå15ç§ ïŒ æŒ çœâŠïŒå30ç§ ïŒ æ°Ž æŽâŠïŒå15ç§ ïŒ å® çâŠïŒå30ç§ ïŒ æ°Ž æŽâŠïŒå15ç§ ïŒ å® å®âŠïŒå15ç§ åå·¥çšã«çšããåŠç液çµæã¯äžèšã®éãã§ã
ãã ã«ã©ãŒçŸå液 ãããªãäžé ¢é žãããªãŠã 1.0ïœ äºç¡«é žãããªãŠã 4.0ïœ çé žãããªãŠã 30.0ïœ èåã«ãª 1.4ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβâããããã·ãšãã«
ã¢ããïŒâïŒâã¡ãã«ã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ããŠ ïŒ æŒçœæ¶² èåã¢ã³ã¢ããŠã 160.0ïœ ã¢ã³ã¢ãã¢æ°ŽïŒ28ïŒ ïŒ 25.0c.c. ãšãã¬ã³ãžã¢ãã³âåé ¢é žãããªãŠã éå¡©
130.0ïœ æ°·é ¢é ž 14.0c.c. æ°Žãå ããŠ ïŒ å®ç液 ããã©ããªãªã³é žã¢ã³ã¢ããŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ ïŒ 175.0c.c. éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ããŠ ïŒ å®å®æ¶² ãã«ããªã³ 8.0c.c. æ°Žãå ããŠ ïŒ åŠçæžè©Šæã®æ¿åºŠãèµ€è²å ã«ãã枬å®ãããçž
察æ床ãšæ倧æ¿åºŠãè¡šïŒã«ç€ºãã ãŸãåŠçæžè©Šæã®å¯èŠåžåã¹ãã¯ãã«ã®æž¬å®ã
è¡ãªããåžå極倧波é·ïŒÎ»maxïŒããã³ãåžå極
倧æ¿åºŠãïŒã«èŠæ Œåããæã®600nïœã«ãããåž
å 床ã®å€ïŒODat600nïœïŒãããããŠè¡šïŒã«ç€ºã
ãã
ããã³åæäŸã瀺ãã åæäŸ ïŒ ïŒäŸç€ºã«ãã©ãŒïŒã®åæïŒ ïŒâã¢ããâïŒâãããããšããŒã«170ïœãã
ã«ãšã³1.5ã®ãã«ãšã³ã«åæ£ããã宀枩äžã«ã
ïœâã¯ãã«ããšãã«ã€ãœã·ã¢ããŒã150ïœããã«
ãšã³300mlã«æº¶è§£ãã溶液ã滎äžããã滎äžçµäº
åŸãïŒæéå ç±éæµããããã®åŸã宀枩ãŸã§å·åŽ
ããçµæ¶ãåããã¡ã¿ããŒã«æŽæµãè¡ãªãã也
ç¥ããŠæ·¡é»è²ã®åºäœ280ïœãåŸãã ãã®ïŒâïŒïŒâã¯ãã«ããšãã«ïŒãŠã¬ã€ãâïŒ
âãããããšããŒã«30.8ïœããã©ãžãŠã âççŽ è§Š
åªïŒïœãšå ±ã«ãžã¡ãã«ã¢ã»ãã¢ãã250mlã«å ãã
ãªãŒãã¯ã¬ãŒãã«ãŠæ¥è§Šéå ãè¡ãªã€ããçè«é
ã®æ°ŽçŽ ãæ¶è²»ããåŸã觊åªãå¥ããåŸããã
液ïŒåå¿æ¶²ïŒã«ãïŒâïŒïŒïŒïŒâãžâtertâãªã¯
ãã«ããšããã·ïŒãããµãã€ã«ã¯ããªã49ïœãå
ãã60âã§ïŒæéåå¿ããããåå¿çµäºåŸãæ··å
ç©ãæ°Žã«ãããé ¢é žãšãã«ã§æœåºããæ°ŽæŽããã®
ã¡ã溶åªãçå»ããåŸãããæ®æž£ã«ïœâãããµã³
ãå ããçµæ¶ãåããŠäŸç€ºã«ãã©ãŒïŒã52ïœåŸ
ããïŒm.p.165ã167âïŒ å çŽ åæå€ ïŒ£ïŒ70.90 ïŒ8.60 ïŒ6.06 ClïŒ
5.01 èšç®å€ ïŒ71.12 ïŒ8.44 ïŒ6.07 ClïŒ
5.12 åæäŸ ïŒ ïŒäŸç€ºã«ãã©ãŒïŒã®åæïŒ ïŒâã¢ããâïŒâãããããšããŒã«170ïœãšã
ãšãã«ïŒïŒïŒâãžã¯ãã«âããšãã«ã«ã«ãã¡ãŒã
282ïœãããªãšãã«ã¢ãã³15mlãã¢ã»ããããªã«
800mlã«å ããã¹ããŒã ãã¹äžã§éæµãïŒæéç¶
ãããåå¿çµäºåŸã宀枩ãŸã§å·åŽããæåºããçµ
æ¶ãåããã¢ã»ããããªã«ã§æŽæµããŠïŒâïŒïŒïŒ
ïŒâãžã¯ãã«ããšãã«ïŒãŠã¬ã€ãâïŒâãããã
ãšããŒã«238ïœãåŸãã ãã®çµæ¶34.2ïœãåæäŸïŒãšåæ§ã«ããŠãªãŒã
ã¯ã¬ãŒãã§æ¥è§Šéå ãè¡ãªããåŸãããåå¿æ¶²
ïŒæ¶²ïŒã«ïŒâïŒïŒïŒïŒâãžâtertâãªã¯ãã«ããš
ããã·ïŒãªã¯ã¿ãã€ã«ã¯ããªã52ïœãå ããåæ
äŸïŒãšåæ§ã«ããŠäŸç€ºã«ãã©ãŒïŒã38ïœåŸãã
ïŒm.p.147âïŒâïŒ å çŽ åæå€ ïŒ£ïŒ68.45 ïŒ8.19 ïŒ5.46 ClïŒ
9.26 èšç®å€ ïŒ68.42 ïŒ8.14 ïŒ5.57 ClïŒ
9.39 ä»ã®ã«ãã©ãŒãåæäŸïŒåã¯åæäŸïŒãšåæ§ã«
ããŠåæã§ããã æ¬çºæãçšããŠäœãããåçä¹³å€ã«ã¯æ¬çºæ以
å€ã®è²å圢æã«ãã©ãŒãå«ãã§ããããã«ãã©ãŒ
ã¯ååäžã«ãã©ã¹ãåºãšãã°ããçæ°Žåºãæãã
éæ¡æ£ã®ãã®ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«
察ãïŒåœéæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãã
ãããŸãè²è£æ£ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒã
ãããã¯çŸåã«ãšããªã€ãŠçŸåæå¶å€ãæŸåºãã
ã«ãã©ãŒïŒããããDIRã«ãã©ãŒïŒãå«ãã§ãã
ããã«ãã©ãŒã¯ã«ãããªã³ã°åå¿ã®çæç©ãç¡è²
ã§ãããããªã«ãã©ãŒã§ãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»åã³ãããã€ã«
ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ããã ããŒã³ãçºè²ã«ãã©ãŒãšããŠã¯ãã©ãŸãã³ç³»å
åç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«å
åç©ãªã©ãçšããããšãã§ããç¹ã«ãã©ãŸãã³ç³»
ååç©ã¯æå©ã§ããã ã·ã¢ã³çºè²ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãã æ¬çºæã®ã«ãã©ãŒã¯åäžå±€ã«äºçš®ä»¥äžå«ãããš
ãã§ãããåäžã®ååç©ãç°ãªãïŒã€ä»¥äžã®å±€ã«
å«ãã§ãããã æ¬çºæã®ã«ãã©ãŒã¯ãäžè¬ã«ä¹³å€å±€äžã®éïŒã¢
ã«åœãïŒÃ10-3ã¢ã«ãªããïŒÃ10-1ã¢ã«ã奜ãŸã
ãã¯ïŒÃ10-2ã¢ã«ãªããïŒÃ10-1ã¢ã«æ·»å ãã
ããäžèšã®ã«ãã©ãŒãšäœµçšãããå Žåã¯åãè²ã«
çºè²ããã«ãã©ãŒã®å šéšã®æ·»å éãäžèšã®ç¯å²å
ã«å ¥ãã®ã奜ãŸããã æ¬çºæã®ã«ãã©ãŒããã³ãã®ä»ã®äžèšã®ã«ãã©
ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯å ¬ç¥ã®æ¹
æ³ããšãã°ç±³åœç¹èš±ç¬¬2322027å·ã«èšèŒã®æ¹æ³ãª
ã©ãçšãããããããšãã°ãã¿ãŒã«é žã¢ã«ãã«ãš
ã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«ã¿ã¬ãŒ
ããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«ããªã¹ã
ãšãŒããããªããšãã«ããªã¹ããšãŒããããªã¯ã¬
ãžã«ããªã¹ããšãŒãããªã¯ãã«ããã«ããªã¹ããš
ãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒããšãã°ã¢ã»ã«ã¯ãš
ã³é žããªããã«ïŒãå®æ¯éŠé žãšã¹ãã«ïŒããšãã°
å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒããšãã°
ãžãšãã«ã©ãŠãªã«ã¢ããïŒãèèªé žãšã¹ãã«é¡
ïŒããšãã°ãžãããã·ãšãã«ãµã¯ã·ããŒãããžãª
ã¯ãã«ã¢ãŒã¬ãŒãïŒãªã©ããŸãã¯æ²žç¹çŽ30âä¹è³
150âã®ææ©æº¶åªãããšãã°é ¢é žãšãã«ãé ¢é žã
ãã«ã®ããšãäœçŽã¢ã«ãã«ã¢ã»ããŒããããããª
ã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ãã«ã€ãœ
ããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ããŒãã
ã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã«æº¶è§£ããã®ã¡ã
芪氎æ§ã³ãã€ãã«å解ããããäžèšã®é«æ²žç¹ææ©
溶åªãšäœæ²žç¹ç¡æ©æº¶åªãšãæ··åããŠçšããŠãã
ãã ãŸãç¹å ¬æ51â39853ãç¹éæ51â59943ã«èšèŒ
ãããŠããéåç©ã«ããå解æ³ã䜿çšããããšã
ã§ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®ããšã
é žåºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠ
芪氎æ§ã³ãã€ãäžã«å°å ¥ãããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«çŽ«å€ç·åžåå€ãå«ãã§ãããããšãã°
ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«åå
ç©ïŒããšãã°ç±³åœç¹èš±3533794å·ã«èšèŒã®ãã®ïŒã
ïŒâãã¢ãŸãªãã³ååç©ïŒããšãã°ç±³åœç¹èš±
3314794å·ãå3352681å·ã«èšèŒã®ãã®ïŒããã³ãŸ
ããšãã³ååç©ïŒããšãã°ç¹éæ46â2784å·ã«èš
èŒã®ãã®ïŒãã±ã€ãé žãšã¹ãã«ååç©ïŒããšãã°
ç±³åœç¹èš±3705805å·ãå3707375å·ã«èšèŒã®ãã®ïŒã
ãã¿ãžãšã³ååç©ïŒããšãã°ç±³åœç¹èš±4045229å·
ã«èšèŒã®ãã®ïŒããããã¯ãã³ãŸãªãã·ãŸãŒã«å
åç©ïŒããšãã°ç±³åœç¹èš±3700455å·ã«èšèŒã®ãã®ïŒ
ãçšããããšãã§ãããããã«ç±³åœç¹èš±3499762
å·ãç¹éæ54â48535å·ã«èšèŒã®ãã®ãçšããã
ãšãã§ããã玫å€ç·åžåæ§ã®ã«ãã©ãŒïŒããšãã°
αâããããŒã«ç³»ã®ã·ã¢ã³è²çŽ 圢æã«ãã©ãŒïŒã
玫å€ç·åžåæ§ã®ããªããŒãªã©ãçšããŠããããã
ããã®çŽ«æ Œç·åžåå€ã¯ç¹å®ã®å±€ã«åªæãããŠãã
ãã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et aiè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿æŽããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ãããããçšããŠãããã åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®
çæããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããª
ãã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³
ãçšããããšãã§ããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã®ä»¥
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒã¹ç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ããé ž
åŠçãŒã©ãã³ãBull.Soc.Sci.Phot.Japan.No.16ã
30é ïŒ1966ïŒã«èšèŒããããããªé µçŽ åŠçãŒã©ã
ã³ãçšããŠãããããŸãããŒã©ãã³ã®å æ°Žå解ç©
ãé µçŽ å解ç©ãçšããããšãã§ããã æ¬çºæã«çšããããåçä¹³å€ã«ã¯ãæå ææã®
補é å·¥çšãä¿åäžãããã¯åçåŠçäžã®ã«ããªã
é²æ¢ããããã¯åçæ§èœãå®å®åãããç®çã§ã
çš®ã ã®ååç©ãå«æãããããšãã§ãããããªã
ã¡ã¢ãŸãŒã«é¡ããšãã°ãã³ãŸãã¢ãŸãªãŠã å¡©ãã
ããã€ã³ããŸãŒã«é¡ãããããã³ãºã€ãããŸãŒã«
é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ãããã¢ãã³ãº
ã€ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãŸãŒã«é¡ãã¡ã«
ã«ãããã³ãŸãã¢ãŸãŒã«é¡ãã¡ã«ã«ãããã³ãºã€
ãããŸãŒã«é¡ãã¡ã«ã«ãããã¢ãžã¢ãŸãŒã«é¡ãã¢
ããããªã¢ãŸãŒã«é¡ããã³ãŸããªã¢ãŸãŒã«é¡ãã
ãããã³ãŸããªã¢ãŸãŒã«é¡ãã¡ã«ã«ããããã©ãŸ
ãŒã«é¡ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«ãããã
ã©ãŸãŒã«ïŒãªã©ïŒã¡ã«ã«ããããªããžã³é¡ïŒã¡ã«
ã«ããããªã¢ãžã³é¡ïŒããšãã°ãªããµãŸãªã³ããª
ã³ã®ãããªããªã±ãååç©ïŒã¢ã¶ã€ã³ãã³é¡ãã
ãšãã°ããªã¢ã¶ã€ã³ãã³é¡ãããã©ã¢ã¶ã€ã³ãã³
é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒãïŒã3aãïŒïŒ
ããã©ã¶ã€ã³ãã³é¡ããã³ã¿ã¢ã¶ã€ã³ãã³é¡ãª
ã©ïŒãã³ãŒã³ããªã¹ã«ããªã³é žããã³ãŒã³ã¹ã«ã
ã€ã³é žããã³ãŒã³ã¹ã«ããªã³é žã¢ããçã®ãããª
ã«ããªé²æ¢å€ãŸãã¯å®å®å€ãšããŠç¥ãããå€ãã®
ååç©ãå ããããšãã§ããã æ¬çºæã®åçæå ææã®åçä¹³å€å±€ã«ã¯æ床äž
æãã³ã³ãã©ã¹ãäžæããŸãã¯çŸåä¿é²ã®ç®ç
ã§ãäŸãã°ããªã¢ã«ãã¬ã³ãªãã·ããŸãã¯ãã®ãš
ãŒãã«ããšã¹ãã«ãã¢ãã³ãªã©ã®èªå°äœãããªãš
ãŒãã«ååç©ãããªã¢ã«ããªãªã³é¡ãåçŽã¢ã³ã¢
ããŠã å¡©ååç©ããŠã¬ã¿ã³èªå°äœãå°¿çŽ èªå°äœã
ã€ãããŸãŒã«èªå°äœãïŒâãã©ãŸãªãã³é¡çãå«
ãã§ãããã æ¬çºæã«çšããããåçä¹³å€ã¯ãã¡ãã³è²çŽ é¡
ãã®ä»ã«ãã€ãŠåå å¢æãããŠãããçšãããã
è²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€
åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããã
âã©âã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããª
ã«è²çŽ ãããã³ãããªããœããŒã«è²çŽ ãå å«ãã
ããç¹ã«æçšãªç¹è²ã¯ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«å±ããè²çŽ
ã§ããããããã®è²çŽ é¡ã«ã¯å¡©åºæ§ç°ç¯ç°æ žãšã
ãŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ žã®ãããã
ãé©çšã§ãããããªãã¡ããããªã³æ žããªããµãŸ
ãªã³æ žãããªãŸãªã³æ žããããŒã«æ žããªããµãŸãŒ
ã«æ žããã¢ãŸãŒã«æ žãã»ã¬ããŸãŒã«æ žãã€ãããŸ
ãŒã«æ žãããã©ãŸãŒã«æ žãããªãžã³æ žãªã©ïŒãã
ãã®æ žã«èç°åŒçåæ°ŽçŽ ç°ãèåããæ žïŒããã³
ãããã®æ žã«è³éŠæçåæ°ŽçŽ ç°ãèåããæ žãã
ãªãã¡ãã€ã³ãã¬ãã³æ žããã³ãºã€ã³ãã¬ãã³
æ žãã€ã³ããŒã«æ žããã³ãºãªããµãŸãŒã«æ žããã
ããªããµãŸãŒã«æ žããã³ãŸãã¢ãŸãŒã«æ žãããã
ãã¢ãŸãŒã«æ žããã³ãŸã»ã¬ããŸãŒã«æ žããã³ãºã€
ãããŸãŒã«æ žããããªã³æ žãªã©ãé©çšã§ãããã
ããã®æ žã¯ççŽ ååäžçœ®æãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³â2.4âãžãªã³æ žããâããã³æ žãããªãã«
ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšãã
ããšãã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšããããã å¢æè²çŽ ãšãšãã«ããã®èªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããããšãã°å«ããçŽ ç°ç¯ç°åºã§çœ®æã
ããã¢ããã¹ãã«ãã³ååç©ãè³éŠæææ©é žãã«
ã ã¢ã«ãããçž®åç©ãã«ãããŠã å¡©ãã¢ã¶ã€ã³ã
ã³ååç©ãªã©ãå«ãã§ãããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«ãã€ã«ã¿ãŒææãšããŠããããã¯ã€ã©
ãžãšãŒã·ãšã³é²æ¢ãã®ä»çš®ã ã®ç®çã§æ°Žæº¶æ§ææ
ãå«æããŠããããã®ãããªææã«ã¯ãªããœããŒ
ã«ææããããªããœããŒã«ææãã¹ããªã«ææã
ã¡ãã·ã¢ãã³ææãã·ã¢ãã³ææåã³ã¢ãŸææã
å å«ããããäžã§ããªããœããŒã«ææïŒãããªã
ãœããŒã«ææåã³ã¡ãã·ã¢ãã³ææãæçšã§ã
ãã æ¬çºæãçšããŠã€ããããæå ææã«ãããŠã
åçä¹³å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ãã¹ã
ã«ãã³ç³»ãããªã¢ãžã³ç³»ããªããµãŸãŒã«ç³»ããã
ã¯ã¯ããªã³ç³»ãªã©ã®å¢çœå€ãå«ãã§ãããããã
ãã¯æ°Žæº¶æ§ã®ãã®ã§ãããããŸãæ°Žäžæº¶æ§ã®å¢çœ
å€ãåæ£ç©ã®åœ¢ã§çšããŠãããã æ¬çºæãå®æœããã«éããŠäžèšã®å ¬ç¥ã®éè²é²
æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«çšãã
è²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšããããšã
ã§ãããå ¬ç¥ã®éè²é²æ¢å€ãšããŠã¯ãäŸãã°ãã
ãã€ãããã³èªå°äœã没é£åé žèªå°äœãïœâã¢ã«
ã³ãã·ããšããŒã«é¡ãïœâãªãã·ããšããŒã«èªå°
äœããã¹ããšããŒã«é¡çãããã æ¬çºæãçšããŠäœãããæå ææã¯è²ã«ããªé²
æ¢å€ãšããŠããã€ãããã³èªå°äœãã¢ããããšã
ãŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ãã³é žèª
å°äœãªã©ãå«æããŠãããã æ¬çºæã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªãå
å æ床ãæããå€å±€å€è²åçææã«ãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãç·ææ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ã
åã å°ãªããšãäžã€æããããããã®å±€ã®é åºã¯
å¿ èŠã«å¿ããŠä»»æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·
ã¢ã³åœ¢æã«ãã©ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã圢
æã«ãã©ãŒããéææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ã
ã©ãŒãããããå«ãã®ãéåžžã§ããããå Žåã«ã
ãç°ãªãçµåãããšãããšãã§ããã æ¬çºæã®æå ææã®åçåŠçã«ã¯ãå ¬ç¥ã®æ¹æ³
ã®ããããçšããããšãã§ãããåŠç液ã«ã¯å ¬ç¥
ã®ãã®ãçšããããšãã§ãããåŠç枩床ã¯æ®é18
âãã50âã®éã«éžã°ãããã18âããäœã枩床
ãŸãã¯50âãããã枩床ãšããŠãããã ã«ã©ãŒçŸå液ã¯ãäžè¬ã«çºè²çŸåäž»è¬ãå«ãã¢
ã«ã«ãªæ§æ°Žæº¶æ¶²ããæããçºè²çŸåäž»è¬ã¯å ¬ç¥ã®
äžçŽè³éŠæã¢ãã³çŸåå€ãäŸãã°ããšãã¬ã³ãžã¢
ãã³é¡ïŒäŸãã°ïŒâã¢ããâïŒïŒ®âãžãšãã«ã¢
ããªã³ãïŒâã¡ãã«âïŒâã¢ããâïŒïŒ®âãžãš
ãã«ã¢ããªã³ãïŒâã¢ããââãšãã«ââβ
âããããã·ãšãã«ã¢ããªã³ãïŒâã¡ãã«âïŒâ
ã¢ããââãšãã«ââβâããããã·ãšãã«
ã¢ããªã³ãïŒâã¡ãã«âïŒâã¢ããââãšãã«
ââβâã¡ã¿ã³ã¹ã«ãã¢ãããšãã«ã¢ããªã³ã
ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââβâ
ã¡ããã·ãšãã«ã¢ããªã³ãªã©ïŒãçšããããšãã§
ããã ãã®ä»L.F.A.MasonèPhotographic
Processing ChemistryïŒFocal Pressåã1966幎ïŒ
ã®226ã229é ãç±³åœç¹èš±2193015å·ãå2592364
å·ãç¹éæ48â64933å·ãªã©ã«èšèŒã®ãã®ãçšã
ãŠããã ã«ã©ãŒçŸå液ã¯ãã®ã»ãã¢ã«ã«ãªéå±ã®äºç¡«é ž
å¡©ãçé žå¡©ãããŠé žå¡©ããã³ãªã³é žå¡©ã®åŠãPHç·©
è¡å€ãèåç©ãæ²åç©ããã³ææ©ã«ããªé²æ¢å€ã®
åŠãçŸåæå¶å€ãªããã«ããªé²æ¢å€ãªã©ãå«ãã
ãšãã§ããããŸãå¿ èŠã«å¿ããŠã硬氎è»åå€ãã
ãããã·ã«ã¢ãã³ã®åŠãä¿æå€ããã³ãžã«ã¢ã«ã³
ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ã®åŠãææ©æº¶å€ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãåçŽã¢ã³ã¢ããŠã å¡©ãã¢
ãã³é¡ã®åŠãçŸåä¿é²å€ãè²çŽ 圢æã«ãã©ãŒã競
äºã«ãã©ãŒããããªãŠã ãããã€ãã©ã€ãã®åŠã
ãã¶ããå€ãïŒâããšãã«âïŒâãã©ãŸãªãã³ã®
åŠãè£å©çŸåè¬ãç²æ§ä»äžå€ãç±³åœç¹èš±4083723
å·ã«èšèŒã®ããªã«ã«ãã³é žç³»ãã¬ãŒãå€ã西ç¬å ¬
éïŒOLSïŒ2622950å·ã«èšèŒã®é žåé²æ¢å€ãªã©ã
å«ãã§ãããã çºè²çŸååŸã®åçä¹³å€å±€ã¯éåžžãæŒçœåŠçãã
ããæŒçœåŠçã¯å®çåŠçãšåæã«è¡ãªãããŠãã
ãããåå¥ã«è¡ãªãããŠããããæŒçœå€ãšããŠã¯
éïŒïŒãã³ãã«ãïŒïŒãã¯ãã ïŒïŒãé ïŒïŒ
ãªã©ã®å€äŸ¡éå±ã®ååç©ãéé žé¡ãããã³é¡ãã
ãããœååç©ãªã©ãçšãããããããšãã°ããšãª
ã·ã¢ã³ååç©ãéã¯ãã é žå¡©ãéïŒïŒãŸãã¯ã³
ãã«ãïŒïŒã®ææ©é¯å¡©ãããšãã°ãšãã¬ã³ãžã¢
ãã³åé ¢é žããããªãããªé ¢é žãïŒïŒïŒâãžã¢ã
ãâïŒâãããããŒã«åé ¢é žãªã©ã®ã¢ããããªã«
ã«ãã³é žé¡ãããã¯ã¯ãšã³é žãé ç³é žããªã³ãŽé ž
ãªã©ã®ææ©é žã®é¯å¡©ïŒéç¡«é žå¡©ãéãã³ã¬ã³é ž
å¡©ïŒããããœããšããŒã«ãªã©ãçšããããšãã§ã
ãããããã®ãã¡ããšãªã·ã¢ã³åã«ãªããšãã¬ã³
ãžã¢ãã³åé ¢é žéïŒïŒãããªãŠã ããã³ãšãã¬
ã³ãžã¢ãã³åé ¢é žéïŒïŒã¢ã³ã¢ããŠã ã¯ç¹ã«æ
çšã§ããããšãã¬ã³ãžã¢ãã³åé ¢é žéïŒïŒé¯å¡©
ã¯ç¬ç«ã®æŒçœå€ã«ãããŠããäžæµŽæŒçœå®ç液ã«ã
ããŠãæçšã§ããã æŒçœãŸãã¯æŒçœå®ç液ã«ã¯ãç±³åœç¹èš±3042520
å·ãå3241966å·ãç¹å ¬æ45â8506å·ãç¹å ¬æ45
â8836å·ãªã©ã«èšèŒã®æŒçœä¿é²å€ãç¹éæ53â
35732å·ã«èšèŒã®ããªãŒã«ååç©ã®ä»ãçš®ã ã®æ·»
å å€ãå ããããšãã§ããã 以äžãæ¬çºæã®å®æœäŸãæ²ããŠå ·äœçã«èª¬æã
ãããæ¬çºæã¯ãããã«éå®ããããã®ã§ã¯ãª
ãã å®æœäŸ ã»ã«ããŒã¹ããªã¢ã»ããŒããã€ã«ã æ¯æäœäžã«
äžèšã®é ã§ä¹³å€å±€ããã³ä¿è·å±€ãå¡åžããŠè©Šæ
ããäœè£œããã æ¬çºæã®ã«ãã©ãŒïŒ100ïœã«ããžããã«ãã¿ã¬
ãŒã50c.c.ããã³é ¢é žãšãã«100c.c.ãå ã60âã§å
ç±æº¶è§£ãããã®æº¶æ¶²ããŒã©ãã³100ïœããã³ãã
ã·ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã 10ïœãå«ã50
âã®æ°Žæº¶æ¶²1000mlã«æ··åãããã¢ãžãã€ã¶ãŒã«ã
ã€ãŠé«éæ¹æããŠåŸ®çŽ°ãªã«ãã©ãŒåæ£ç©ãåŸãã ãã®ã«ãã©ãŒåæ£ç©350ïœã«éã80ïœãæ²åé
ãšèåéã®ã¢ã«æ¯ãïŒå¯Ÿ94ã§ããæ²èåéä¹³å€ïŒ
Kgãå ããäžèšæ¯æäœäžã«ã«ãã©ãŒå¡åžéãïŒÃ
10-4ã¢ã«ïŒm2ã«ãªãããã«å¡åžããã ãã®å±€ã®äžã«ä¹Ÿç¥èå1ÎŒã®ãŒã©ãã³ä¿è·å±€ã
å¡åžããŠè©Šæãäœè£œããã åæ§ã®æ¹æ³ã«ããã«ãã©ãŒïŒã®ä»£ãã«æ¬çºæã®
ã«ãã©ãŒïŒïŒïŒïŒïŒãçšããŠãã«ãã©ãŒå¡åžé
ïŒã¢ã«ïŒm2ïŒããã³ã«ãã©ãŒãšéã®æ··åæ¯çãè©Š
æãšåãã«ãªãããã«ããŠè©Šæãããäœ
補ããã æŽã«æ¯èŒã«ãã©ãŒãšããŠæ¬çºæå€ã®ã«ãã©ãŒïŒ
ïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒãçšããŠè©Šæãšå šãåã
æ¹æ³ã§è©Šæãããäœè£œããã ãããã®è©Šæã«å åŠã¯ãµããéããŠé²å ãäžã
ãã®ã¡äžèšã®åŠçå·¥çšã«ãŠ38âã§çŸååŠçãè¡ãª
ã€ãã ïŒ ã«ã©ãŒçŸåâŠïŒå15ç§ ïŒ æŒ çœâŠïŒå30ç§ ïŒ æ°Ž æŽâŠïŒå15ç§ ïŒ å® çâŠïŒå30ç§ ïŒ æ°Ž æŽâŠïŒå15ç§ ïŒ å® å®âŠïŒå15ç§ åå·¥çšã«çšããåŠç液çµæã¯äžèšã®éãã§ã
ãã ã«ã©ãŒçŸå液 ãããªãäžé ¢é žãããªãŠã 1.0ïœ äºç¡«é žãããªãŠã 4.0ïœ çé žãããªãŠã 30.0ïœ èåã«ãª 1.4ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβâããããã·ãšãã«
ã¢ããïŒâïŒâã¡ãã«ã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ããŠ ïŒ æŒçœæ¶² èåã¢ã³ã¢ããŠã 160.0ïœ ã¢ã³ã¢ãã¢æ°ŽïŒ28ïŒ ïŒ 25.0c.c. ãšãã¬ã³ãžã¢ãã³âåé ¢é žãããªãŠã éå¡©
130.0ïœ æ°·é ¢é ž 14.0c.c. æ°Žãå ããŠ ïŒ å®ç液 ããã©ããªãªã³é žã¢ã³ã¢ããŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ ïŒ 175.0c.c. éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ããŠ ïŒ å®å®æ¶² ãã«ããªã³ 8.0c.c. æ°Žãå ããŠ ïŒ åŠçæžè©Šæã®æ¿åºŠãèµ€è²å ã«ãã枬å®ãããçž
察æ床ãšæ倧æ¿åºŠãè¡šïŒã«ç€ºãã ãŸãåŠçæžè©Šæã®å¯èŠåžåã¹ãã¯ãã«ã®æž¬å®ã
è¡ãªããåžå極倧波é·ïŒÎ»maxïŒããã³ãåžå極
倧æ¿åºŠãïŒã«èŠæ Œåããæã®600nïœã«ãããåž
å 床ã®å€ïŒODat600nïœïŒãããããŠè¡šïŒã«ç€ºã
ãã
ãè¡šã
è¡šããæãããªããã«æ¬çºæã®ã«ãã©ãŒã¯æ¯èŒ
ã«ãã©ãŒã«æ¯ã¹æ床ãæ倧æ¿åºŠã®åäžã瀺ãããŸ
ãæ¯èŒã«ãã©ãŒïŒïŒïŒã¯çžå¯Ÿæ床ãæ倧æ¿åºŠã¯ã
ãããŠãããã®ã®ãåžåã¹ãã¯ãã«ã®ç¹ã§ã¯
λmaxã®çæ³¢åããã³çæ³¢åŽã®åžåã倧ãããè²
åçŸäžå¥œãŸãããªãããæ¬çºæã«ãã©ãŒã¯åžåã¹
ãã¯ãã«ã®ç¹ãããæºè¶³ã®ãããã®ã§ãã€ãã 次ã«çŸåæžã®åè©Šæã®å ç¢æ§ã®è©Šéšãè¡ãªã€
ããè©Šæã80âã§ææã«14æ¥éæŸçœ®ãããšãã®å
ç¢æ§ã60âã§70ïŒ RHã®ææã«ïŒé±éæŸçœ®ãããš
ãã®å ç¢æ§ã䞊ã³ã«ãã»ãã³è©Šéšæ©ïŒ10äžã«ãã¯
ã¹ïŒã§ïŒæ¥éå ãç §å°ãããšãã®å ç¢æ§ãããã
ãåæ¿åºŠ1.0ã«ãããæ¿åºŠã®äœäžçã調ã¹ããçµ
æãè¡šïŒã«ç€ºãã
ã«ãã©ãŒã«æ¯ã¹æ床ãæ倧æ¿åºŠã®åäžã瀺ãããŸ
ãæ¯èŒã«ãã©ãŒïŒïŒïŒã¯çžå¯Ÿæ床ãæ倧æ¿åºŠã¯ã
ãããŠãããã®ã®ãåžåã¹ãã¯ãã«ã®ç¹ã§ã¯
λmaxã®çæ³¢åããã³çæ³¢åŽã®åžåã倧ãããè²
åçŸäžå¥œãŸãããªãããæ¬çºæã«ãã©ãŒã¯åžåã¹
ãã¯ãã«ã®ç¹ãããæºè¶³ã®ãããã®ã§ãã€ãã 次ã«çŸåæžã®åè©Šæã®å ç¢æ§ã®è©Šéšãè¡ãªã€
ããè©Šæã80âã§ææã«14æ¥éæŸçœ®ãããšãã®å
ç¢æ§ã60âã§70ïŒ RHã®ææã«ïŒé±éæŸçœ®ãããš
ãã®å ç¢æ§ã䞊ã³ã«ãã»ãã³è©Šéšæ©ïŒ10äžã«ãã¯
ã¹ïŒã§ïŒæ¥éå ãç §å°ãããšãã®å ç¢æ§ãããã
ãåæ¿åºŠ1.0ã«ãããæ¿åºŠã®äœäžçã調ã¹ããçµ
æãè¡šïŒã«ç€ºãã
ãè¡šã
æ¬çºæã®ã«ãã©ãŒã圢æããè²åã®å
ç¢æ§ã¯å
åãªãã®ã§ãã€ãã
åãªãã®ã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžèšäžè¬åŒããã§è¡šããããã·ã¢ã³è²çŽ 圢
æã«ãã©ãŒãå«æããããšãç¹åŸŽãšããããã²ã³
åéã«ã©ãŒåçæå ææã äžè¬åŒãã åŒäžãR1ãšR2ã¯ããããççŽ æ°ïŒä»¥äžã®ç¬¬ïŒ
ã¢ã«ãã«åºãè¡šãããR3ã¯æ°ŽçŽ ååãããã²ã³
ååãŸãã¯ïŒäŸ¡ã®ææ©åºãè¡šãããR4ã¯ã¢ã«ã
ã«åºãè¡šãããã¯ããã²ã³ååãè¡šãããã¯
æ°ŽçŽ ååãŸãã¯ããã²ã³ååãè¡šãããïœã¯ïŒã
ïŒã®æŽæ°ãè¡šãããïœãïŒä»¥äžã®ãšãã¯åãã§
ãç°ãªã€ãŠããŠãããã
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14609683A JPH0248097B2 (ja) | 1983-08-10 | 1983-08-10 | Karaashashinkankozairyo |
| DE19843429576 DE3429576A1 (de) | 1983-08-10 | 1984-08-10 | Lichtempfindliche farbphotographische materialien |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14609683A JPH0248097B2 (ja) | 1983-08-10 | 1983-08-10 | Karaashashinkankozairyo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6037557A JPS6037557A (ja) | 1985-02-26 |
| JPH0248097B2 true JPH0248097B2 (ja) | 1990-10-24 |
Family
ID=15400043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14609683A Expired - Lifetime JPH0248097B2 (ja) | 1983-08-10 | 1983-08-10 | Karaashashinkankozairyo |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH0248097B2 (ja) |
| DE (1) | DE3429576A1 (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0727498U (ja) * | 1993-10-28 | 1995-05-23 | æ ªåŒäŒç€ŸçœèåäŒ | å åžäžéšã®ãã䌞ã°ãè£ çœ® |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61251852A (ja) | 1985-04-30 | 1986-11-08 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
| DE3681347D1 (de) | 1985-05-31 | 1991-10-17 | Konishiroku Photo Ind | Verfahren zur herstellung eines direkt positiven farbbildes. |
| AU591540B2 (en) | 1985-12-28 | 1989-12-07 | Konishiroku Photo Industry Co., Ltd. | Method of processing light-sensitive silver halide color photographic material |
| JPS6344659A (ja) * | 1986-08-12 | 1988-02-25 | Konica Corp | çŸåå®å®æ§ãæ¹è¯ãããããã²ã³åéã«ã©âåçæå ææ |
| EP0690344A1 (en) | 1994-06-29 | 1996-01-03 | Konica Corporation | Silver halide color photographic light-sensitive material |
-
1983
- 1983-08-10 JP JP14609683A patent/JPH0248097B2/ja not_active Expired - Lifetime
-
1984
- 1984-08-10 DE DE19843429576 patent/DE3429576A1/de not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0727498U (ja) * | 1993-10-28 | 1995-05-23 | æ ªåŒäŒç€ŸçœèåäŒ | å åžäžéšã®ãã䌞ã°ãè£ çœ® |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3429576A1 (de) | 1985-02-28 |
| JPS6037557A (ja) | 1985-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4334011A (en) | Color photographic light sensitive materials | |
| JPH031655B2 (ja) | ||
| JPH0316011B2 (ja) | ||
| JPS6333694B2 (ja) | ||
| GB2068943A (en) | 5-hydroxy-6-amido carbostyril cyan couplers and silver halide colour photographic light-sensitive materials | |
| JPH0259970B2 (ja) | ||
| JPH034892B2 (ja) | ||
| US4579813A (en) | Silver halide color photographic materials | |
| US4430423A (en) | Color photographic light-sensitive material | |
| JPS6338696B2 (ja) | ||
| US4564586A (en) | Silver halide color photographic light-sensitive material | |
| US4557999A (en) | Silver halide color photographic light-sensitive material | |
| US4818668A (en) | Silver halide color photographic materials | |
| JPH0248097B2 (ja) | Karaashashinkankozairyo | |
| GB2113859A (en) | Silver halide photographic material containing a cyan-forming coupler | |
| US4892810A (en) | Silver halide color photographic light-sensitive material containing cyan dye forming coupler | |
| JPS5933903B2 (ja) | æ°èŠãªã·ã¢ã³ã«ãã©â | |
| JPH0310292B2 (ja) | ||
| US4477558A (en) | Silver halide color photographic light-sensitive material | |
| JPH0583897B2 (ja) | ||
| JPH0259972B2 (ja) | ||
| JPS6342771B2 (ja) | ||
| JPS60213945A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPH0316012B2 (ja) | ||
| JPS59180559A (ja) | ããã²ã³åéã«ã©âåçæå ææ |