JPH0218351B2 - - Google Patents
Info
- Publication number
- JPH0218351B2 JPH0218351B2 JP14495181A JP14495181A JPH0218351B2 JP H0218351 B2 JPH0218351 B2 JP H0218351B2 JP 14495181 A JP14495181 A JP 14495181A JP 14495181 A JP14495181 A JP 14495181A JP H0218351 B2 JPH0218351 B2 JP H0218351B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- acid
- parts
- amino
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 propionylamino group Chemical group 0.000 claims description 31
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 22
- 229910052801 chlorine Inorganic materials 0.000 claims description 22
- 239000000460 chlorine Substances 0.000 claims description 22
- 238000004043 dyeing Methods 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 9
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 229920003043 Cellulose fiber Polymers 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical group 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 125000004957 naphthylene group Chemical group 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 43
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 14
- 239000000203 mixture Substances 0.000 description 13
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 description 10
- 238000005406 washing Methods 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 8
- 239000013078 crystal Substances 0.000 description 8
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000985 reactive dye Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000010446 mirabilite Substances 0.000 description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 3
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 150000004982 aromatic amines Chemical class 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 239000000661 sodium alginate Substances 0.000 description 3
- 235000010413 sodium alginate Nutrition 0.000 description 3
- 229940005550 sodium alginate Drugs 0.000 description 3
- 229940001496 tribasic sodium phosphate Drugs 0.000 description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 239000012954 diazonium Substances 0.000 description 2
- 150000001989 diazonium salts Chemical class 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 2
- 238000010016 exhaust dyeing Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- JAOYIHAJKMNPSV-UHFFFAOYSA-N 2-amino-5-(propanoylamino)benzene-1,4-disulfonic acid Chemical compound CCC(=O)NC1=CC(S(O)(=O)=O)=C(N)C=C1S(O)(=O)=O JAOYIHAJKMNPSV-UHFFFAOYSA-N 0.000 description 1
- KZKGEEGADAWJFS-UHFFFAOYSA-N 2-amino-5-methoxybenzenesulfonic acid Chemical compound COC1=CC=C(N)C(S(O)(=O)=O)=C1 KZKGEEGADAWJFS-UHFFFAOYSA-N 0.000 description 1
- 125000000143 2-carboxyethyl group Chemical group [H]OC(=O)C([H])([H])C([H])([H])* 0.000 description 1
- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- ITQJQEXFJIPBSO-UHFFFAOYSA-N 3-ethoxybenzenesulfonic acid Chemical compound CCOC1=CC=CC(S(O)(=O)=O)=C1 ITQJQEXFJIPBSO-UHFFFAOYSA-N 0.000 description 1
- CDZWHCZLBLCDFR-UHFFFAOYSA-N 3-methoxybenzenesulfonic acid Chemical compound COC1=CC=CC(S(O)(=O)=O)=C1 CDZWHCZLBLCDFR-UHFFFAOYSA-N 0.000 description 1
- NEECEUZBAHTVIN-UHFFFAOYSA-N 4-amino-3-chlorobenzenesulfonic acid Chemical class NC1=CC=C(S(O)(=O)=O)C=C1Cl NEECEUZBAHTVIN-UHFFFAOYSA-N 0.000 description 1
- WPGPEDWUUSPWOW-UHFFFAOYSA-N NC1=C(C=C(C=C1)S(=O)(=O)O)OCC.NC1=C(C=C(C=C1)S(=O)(=O)O)OC.NC1=C(C=C(C=C1)S(=O)(=O)O)CC.NC1=C(C=C(C=C1)S(=O)(=O)O)C.NC=1C=C(C=CC1Br)S(=O)(=O)O Chemical compound NC1=C(C=C(C=C1)S(=O)(=O)O)OCC.NC1=C(C=C(C=C1)S(=O)(=O)O)OC.NC1=C(C=C(C=C1)S(=O)(=O)O)CC.NC1=C(C=C(C=C1)S(=O)(=O)O)C.NC=1C=C(C=CC1Br)S(=O)(=O)O WPGPEDWUUSPWOW-UHFFFAOYSA-N 0.000 description 1
- SMUVMDDNOOIITH-UHFFFAOYSA-N NC1=C(C=CC(=C1)OCC)S(=O)(=O)O.NC1=C(C=CC(=C1)OC)S(=O)(=O)O.NC1=C(C=C(C(=C1)C)Cl)S(=O)(=O)O.NC1=C(C=C(C(=C1)Cl)C)S(=O)(=O)O Chemical compound NC1=C(C=CC(=C1)OCC)S(=O)(=O)O.NC1=C(C=CC(=C1)OC)S(=O)(=O)O.NC1=C(C=C(C(=C1)C)Cl)S(=O)(=O)O.NC1=C(C=C(C(=C1)Cl)C)S(=O)(=O)O SMUVMDDNOOIITH-UHFFFAOYSA-N 0.000 description 1
- XLUFRSHKFVSOIH-UHFFFAOYSA-N NC=1C=C(C=CC1Cl)S(=O)(=O)O.NC=1C=C(C=CC1OCC)S(=O)(=O)O.NC=1C=C(C=CC1OC)S(=O)(=O)O.NC=1C=C(C=CC1CC)S(=O)(=O)O.NC=1C=C(C=CC1C)S(=O)(=O)O Chemical compound NC=1C=C(C=CC1Cl)S(=O)(=O)O.NC=1C=C(C=CC1OCC)S(=O)(=O)O.NC=1C=C(C=CC1OC)S(=O)(=O)O.NC=1C=C(C=CC1CC)S(=O)(=O)O.NC=1C=C(C=CC1C)S(=O)(=O)O XLUFRSHKFVSOIH-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QQNXPCCFPQRLMK-UHFFFAOYSA-N S(O)(O)(=O)=O.OCCS(=O)(=O)CCO Chemical compound S(O)(O)(=O)=O.OCCS(=O)(=O)CCO QQNXPCCFPQRLMK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14495181A JPS5846185A (ja) | 1981-09-14 | 1981-09-14 | セルロ−ズ系繊維の染色法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14495181A JPS5846185A (ja) | 1981-09-14 | 1981-09-14 | セルロ−ズ系繊維の染色法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5846185A JPS5846185A (ja) | 1983-03-17 |
| JPH0218351B2 true JPH0218351B2 (ko) | 1990-04-25 |
Family
ID=15373979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14495181A Granted JPS5846185A (ja) | 1981-09-14 | 1981-09-14 | セルロ−ズ系繊維の染色法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5846185A (ko) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59179888A (ja) * | 1983-03-24 | 1984-10-12 | 住友化学工業株式会社 | セルロ−ズ系繊維の染色法 |
| JPS61171770A (ja) * | 1985-01-25 | 1986-08-02 | Sumitomo Chem Co Ltd | モノアゾ化合物およびそれを用いる染色又は捺染方法 |
| DE3510179A1 (de) * | 1985-03-21 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Wasserloesliche mono- und disazoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe |
| DE3510180A1 (de) * | 1985-03-21 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Wasserloesliche azoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe |
| DE3624136A1 (de) * | 1985-09-30 | 1987-04-09 | Hoechst Ag | Wasserloesliche azoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe |
| US5003053A (en) * | 1987-02-14 | 1991-03-26 | Hoechst Aktiengesellschaft | Water-soluble monoazo compounds containing a p-aminophenylamino- and chloro- or fluoro-substituted triazinylamino group and a fiber-reactive group selected from the vinylsulfone series, suitable as dyestuffs |
-
1981
- 1981-09-14 JP JP14495181A patent/JPS5846185A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5846185A (ja) | 1983-03-17 |
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