JPH0149828B2 - - Google Patents
Info
- Publication number
- JPH0149828B2 JPH0149828B2 JP62193138A JP19313887A JPH0149828B2 JP H0149828 B2 JPH0149828 B2 JP H0149828B2 JP 62193138 A JP62193138 A JP 62193138A JP 19313887 A JP19313887 A JP 19313887A JP H0149828 B2 JPH0149828 B2 JP H0149828B2
- Authority
- JP
- Japan
- Prior art keywords
- aminophosphazene
- flame retardant
- fibers
- flame
- trimer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003063 flame retardant Substances 0.000 claims description 44
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 43
- 239000000835 fiber Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- 229920000742 Cotton Polymers 0.000 claims description 23
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 239000003377 acid catalyst Substances 0.000 claims description 11
- 238000003672 processing method Methods 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- PMZIUAOBHNJYQT-UHFFFAOYSA-N (1-hydroxy-2-methylpropan-2-yl)azanium;chloride Chemical compound Cl.CC(C)(N)CO PMZIUAOBHNJYQT-UHFFFAOYSA-N 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 5
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 229920000297 Rayon Polymers 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 239000002964 rayon Substances 0.000 claims description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
- -1 methylol group Chemical group 0.000 claims description 3
- 210000002268 wool Anatomy 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims 1
- 235000009120 camo Nutrition 0.000 claims 1
- 235000005607 chanvre indien Nutrition 0.000 claims 1
- 239000000446 fuel Substances 0.000 claims 1
- 239000011487 hemp Substances 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 31
- 239000004744 fabric Substances 0.000 description 28
- 239000013638 trimer Substances 0.000 description 28
- 239000007788 liquid Substances 0.000 description 19
- 238000005470 impregnation Methods 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 230000037303 wrinkles Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000013256 coordination polymer Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- BSBSDQUZDZXGFN-UHFFFAOYSA-N cythioate Chemical compound COP(=S)(OC)OC1=CC=C(S(N)(=O)=O)C=C1 BSBSDQUZDZXGFN-UHFFFAOYSA-N 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000012757 flame retardant agent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 2
- 229940039790 sodium oxalate Drugs 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- PFSIHPSJOVKKDE-UHFFFAOYSA-N 1-amino-2-methylpropan-1-ol;hydrochloride Chemical compound Cl.CC(C)C(N)O PFSIHPSJOVKKDE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 101100420769 Drosophila melanogaster scaf gene Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000004069 aziridinyl group Chemical group 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- CBPKIOGAUWKEFT-UHFFFAOYSA-N bis(2,3-dibromopropyl) hydrogen phosphate Chemical compound BrCC(Br)COP(=O)(O)OCC(Br)CBr CBPKIOGAUWKEFT-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WLKALBXHGZQMSK-UHFFFAOYSA-N n-dimethoxyphosphoryl-n-(hydroxymethyl)propanamide Chemical compound CCC(=O)N(CO)P(=O)(OC)OC WLKALBXHGZQMSK-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- YIEDHPBKGZGLIK-UHFFFAOYSA-L tetrakis(hydroxymethyl)phosphanium;sulfate Chemical compound [O-]S([O-])(=O)=O.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO YIEDHPBKGZGLIK-UHFFFAOYSA-L 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19313887A JPS6440674A (en) | 1987-07-31 | 1987-07-31 | Fire retardant processing of fiber with aminophosphazene derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19313887A JPS6440674A (en) | 1987-07-31 | 1987-07-31 | Fire retardant processing of fiber with aminophosphazene derivative |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6440674A JPS6440674A (en) | 1989-02-10 |
| JPH0149828B2 true JPH0149828B2 (sl) | 1989-10-26 |
Family
ID=16302911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19313887A Granted JPS6440674A (en) | 1987-07-31 | 1987-07-31 | Fire retardant processing of fiber with aminophosphazene derivative |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6440674A (sl) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5914073A (ja) * | 1982-07-15 | 1984-01-24 | Omron Tateisi Electronics Co | 個人認証方法 |
| JPS61215687A (ja) * | 1985-03-20 | 1986-09-25 | Gunze Ltd | ノンホルムアルデヒドの洗濯耐久性防炎加工方法 |
| JPS61266668A (ja) * | 1985-05-15 | 1986-11-26 | 日東紡績株式会社 | 防炎加工方法 |
| JPS61266670A (ja) * | 1985-05-15 | 1986-11-26 | 日東紡績株式会社 | 防炎加工剤及び防炎加工方法 |
| JPS61266669A (ja) * | 1985-05-15 | 1986-11-26 | 日東紡績株式会社 | 新規な防炎加工方法 |
| JPS61296177A (ja) * | 1985-06-25 | 1986-12-26 | 新技術事業団 | セルロ−ス系物質の難燃化方法 |
| JPS6278271A (ja) * | 1985-10-02 | 1987-04-10 | 日東紡績株式会社 | セルロ−ス系繊維を含む織・編物の防炎加工方法 |
-
1987
- 1987-07-31 JP JP19313887A patent/JPS6440674A/ja active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5914073A (ja) * | 1982-07-15 | 1984-01-24 | Omron Tateisi Electronics Co | 個人認証方法 |
| JPS61215687A (ja) * | 1985-03-20 | 1986-09-25 | Gunze Ltd | ノンホルムアルデヒドの洗濯耐久性防炎加工方法 |
| JPS61266668A (ja) * | 1985-05-15 | 1986-11-26 | 日東紡績株式会社 | 防炎加工方法 |
| JPS61266670A (ja) * | 1985-05-15 | 1986-11-26 | 日東紡績株式会社 | 防炎加工剤及び防炎加工方法 |
| JPS61266669A (ja) * | 1985-05-15 | 1986-11-26 | 日東紡績株式会社 | 新規な防炎加工方法 |
| JPS61296177A (ja) * | 1985-06-25 | 1986-12-26 | 新技術事業団 | セルロ−ス系物質の難燃化方法 |
| JPS6278271A (ja) * | 1985-10-02 | 1987-04-10 | 日東紡績株式会社 | セルロ−ス系繊維を含む織・編物の防炎加工方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6440674A (en) | 1989-02-10 |
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