JPH0149289B2 - - Google Patents
Info
- Publication number
- JPH0149289B2 JPH0149289B2 JP58157092A JP15709283A JPH0149289B2 JP H0149289 B2 JPH0149289 B2 JP H0149289B2 JP 58157092 A JP58157092 A JP 58157092A JP 15709283 A JP15709283 A JP 15709283A JP H0149289 B2 JPH0149289 B2 JP H0149289B2
- Authority
- JP
- Japan
- Prior art keywords
- contact
- component
- compound
- catalyst component
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 49
- 239000011777 magnesium Substances 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 32
- 229910052749 magnesium Inorganic materials 0.000 claims description 20
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 19
- 150000003377 silicon compounds Chemical class 0.000 claims description 16
- 150000003609 titanium compounds Chemical class 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 239000004711 α-olefin Substances 0.000 claims description 8
- 150000004820 halides Chemical class 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 38
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 29
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- -1 aluminum halide Chemical class 0.000 description 27
- 150000002430 hydrocarbons Chemical group 0.000 description 24
- 229930195733 hydrocarbon Natural products 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 239000007787 solid Substances 0.000 description 17
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- 239000004215 Carbon black (E152) Substances 0.000 description 15
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 239000010936 titanium Substances 0.000 description 9
- 150000001336 alkenes Chemical class 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 125000004429 atom Chemical group 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 150000008064 anhydrides Chemical class 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 150000002681 magnesium compounds Chemical class 0.000 description 6
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 150000001649 bromium compounds Chemical class 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910001507 metal halide Inorganic materials 0.000 description 5
- 150000005309 metal halides Chemical class 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 150000001733 carboxylic acid esters Chemical class 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 150000004694 iodide salts Chemical class 0.000 description 4
- XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 4
- 239000005052 trichlorosilane Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 3
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 3
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 230000037048 polymerization activity Effects 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000005049 silicon tetrachloride Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- RXGUIWHIADMCFC-UHFFFAOYSA-N 2-Methylpropyl 2-methylpropionate Chemical compound CC(C)COC(=O)C(C)C RXGUIWHIADMCFC-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 2
- SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- 238000012661 block copolymerization Methods 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical group CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- BUMGIEFFCMBQDG-UHFFFAOYSA-N dichlorosilicon Chemical compound Cl[Si]Cl BUMGIEFFCMBQDG-UHFFFAOYSA-N 0.000 description 2
- NBBQQQJUOYRZCA-UHFFFAOYSA-N diethoxymethylsilane Chemical compound CCOC([SiH3])OCC NBBQQQJUOYRZCA-UHFFFAOYSA-N 0.000 description 2
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 2
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 2
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N hydroxymethyl benzene Natural products OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- AQRLNPVMDITEJU-UHFFFAOYSA-N triethylsilane Chemical compound CC[SiH](CC)CC AQRLNPVMDITEJU-UHFFFAOYSA-N 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- YGMHIBLUWGDWKP-UHFFFAOYSA-N (4-methoxybenzoyl) 4-methoxybenzoate Chemical compound C1=CC(OC)=CC=C1C(=O)OC(=O)C1=CC=C(OC)C=C1 YGMHIBLUWGDWKP-UHFFFAOYSA-N 0.000 description 1
- BJMLLSSSTGHJJE-UHFFFAOYSA-N (4-methylbenzoyl) 4-methylbenzoate Chemical compound C1=CC(C)=CC=C1C(=O)OC(=O)C1=CC=C(C)C=C1 BJMLLSSSTGHJJE-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- IBTLFDCPAJLATQ-UHFFFAOYSA-N 1-prop-2-enoxybutane Chemical compound CCCCOCC=C IBTLFDCPAJLATQ-UHFFFAOYSA-N 0.000 description 1
- UZGKAASZIMOAMU-UHFFFAOYSA-N 124177-85-1 Chemical class NP(=O)=O UZGKAASZIMOAMU-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- SHDZTIZBSYDZSH-UHFFFAOYSA-N 2-methylprop-2-enoyl bromide Chemical compound CC(=C)C(Br)=O SHDZTIZBSYDZSH-UHFFFAOYSA-N 0.000 description 1
- RWUMREWUNMCLCM-UHFFFAOYSA-N 2-methylprop-2-enoyl iodide Chemical compound CC(=C)C(I)=O RWUMREWUNMCLCM-UHFFFAOYSA-N 0.000 description 1
- NMVXHZSPDTXJSJ-UHFFFAOYSA-L 2-methylpropylaluminum(2+);dichloride Chemical compound CC(C)C[Al](Cl)Cl NMVXHZSPDTXJSJ-UHFFFAOYSA-L 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- YHCCCMIWRBJYHG-UHFFFAOYSA-N 3-(2-ethylhexoxymethyl)heptane Chemical compound CCCCC(CC)COCC(CC)CCCC YHCCCMIWRBJYHG-UHFFFAOYSA-N 0.000 description 1
- OJPSFJLSZZTSDF-UHFFFAOYSA-N 3-ethoxyprop-1-ene Chemical compound CCOCC=C OJPSFJLSZZTSDF-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- ZQVKTHRQIXSMGY-UHFFFAOYSA-N 4-Ethylbenzoic acid Chemical compound CCC1=CC=C(C(O)=O)C=C1 ZQVKTHRQIXSMGY-UHFFFAOYSA-N 0.000 description 1
- ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 1
- QTDXSEZXAPHVBI-UHFFFAOYSA-N 4-methylcyclohexane-1-carboxylic acid Chemical compound CC1CCC(C(O)=O)CC1 QTDXSEZXAPHVBI-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Chemical group 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 101000837626 Homo sapiens Thyroid hormone receptor alpha Proteins 0.000 description 1
- 229910021617 Indium monochloride Inorganic materials 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910019440 Mg(OH) Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910018287 SbF 5 Inorganic materials 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 102100028702 Thyroid hormone receptor alpha Human genes 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- VJDDQSBNUHLBTD-GGWOSOGESA-N [(e)-but-2-enoyl] (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(=O)\C=C\C VJDDQSBNUHLBTD-GGWOSOGESA-N 0.000 description 1
- FXXACINHVKSMDR-UHFFFAOYSA-N acetyl bromide Chemical compound CC(Br)=O FXXACINHVKSMDR-UHFFFAOYSA-N 0.000 description 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 1
- 239000012346 acetyl chloride Substances 0.000 description 1
- LEKJTGQWLAUGQA-UHFFFAOYSA-N acetyl iodide Chemical compound CC(I)=O LEKJTGQWLAUGQA-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- MXMOTZIXVICDSD-UHFFFAOYSA-N anisoyl chloride Chemical compound COC1=CC=C(C(Cl)=O)C=C1 MXMOTZIXVICDSD-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
- 150000001463 antimony compounds Chemical group 0.000 description 1
- VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical group [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- FYXKZNLBZKRYSS-UHFFFAOYSA-N benzene-1,2-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC=C1C(Cl)=O FYXKZNLBZKRYSS-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- AQIHMSVIAGNIDM-UHFFFAOYSA-N benzoyl bromide Chemical compound BrC(=O)C1=CC=CC=C1 AQIHMSVIAGNIDM-UHFFFAOYSA-N 0.000 description 1
- WPCXDBCEDWUSOU-UHFFFAOYSA-N benzoyl iodide Chemical compound IC(=O)C1=CC=CC=C1 WPCXDBCEDWUSOU-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- WEDLYHNDZPHFLT-UHFFFAOYSA-M bis(2-methylpropyl)-phenoxyalumane Chemical compound [O-]C1=CC=CC=C1.CC(C)C[Al+]CC(C)C WEDLYHNDZPHFLT-UHFFFAOYSA-M 0.000 description 1
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical group C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- VJVUKRSEEMNRCM-UHFFFAOYSA-L butan-1-olate titanium(4+) dichloride Chemical compound [Cl-].[Cl-].CCCCO[Ti+2]OCCCC VJVUKRSEEMNRCM-UHFFFAOYSA-L 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- YHASWHZGWUONAO-UHFFFAOYSA-N butanoyl butanoate Chemical compound CCCC(=O)OC(=O)CCC YHASWHZGWUONAO-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- DVECBJCOGJRVPX-UHFFFAOYSA-N butyryl chloride Chemical compound CCCC(Cl)=O DVECBJCOGJRVPX-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- XOYLJNJLGBYDTH-UHFFFAOYSA-M chlorogallium Chemical compound [Ga]Cl XOYLJNJLGBYDTH-UHFFFAOYSA-M 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- LDLKUPVDJGDYCK-UHFFFAOYSA-N cyclohexanecarbonyl bromide Chemical compound BrC(=O)C1CCCCC1 LDLKUPVDJGDYCK-UHFFFAOYSA-N 0.000 description 1
- RVOJTCZRIKWHDX-UHFFFAOYSA-N cyclohexanecarbonyl chloride Chemical compound ClC(=O)C1CCCCC1 RVOJTCZRIKWHDX-UHFFFAOYSA-N 0.000 description 1
- JOHUAELJNSBTGS-UHFFFAOYSA-N cyclohexanecarbonyl cyclohexanecarboxylate Chemical class C1CCCCC1C(=O)OC(=O)C1CCCCC1 JOHUAELJNSBTGS-UHFFFAOYSA-N 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- OXARPLABDJXAQJ-UHFFFAOYSA-N cyclohexene-1-carbonyl chloride Chemical compound ClC(=O)C1=CCCCC1 OXARPLABDJXAQJ-UHFFFAOYSA-N 0.000 description 1
- ASXSAXVMISQWOC-UHFFFAOYSA-N cyclohexene-1-carbonyl cyclohexene-1-carboxylate Chemical class C=1CCCCC=1C(=O)OC(=O)C1=CCCCC1 ASXSAXVMISQWOC-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 1
- KWOIDDOVDJYZLT-UHFFFAOYSA-L dichlorotitanium;phenol Chemical compound Cl[Ti]Cl.OC1=CC=CC=C1.OC1=CC=CC=C1 KWOIDDOVDJYZLT-UHFFFAOYSA-L 0.000 description 1
- YSAVZVORKRDODB-WDSKDSINSA-N diethyl tartrate Chemical compound CCOC(=O)[C@@H](O)[C@H](O)C(=O)OCC YSAVZVORKRDODB-WDSKDSINSA-N 0.000 description 1
- UWAMTZZJXXCIOH-UHFFFAOYSA-M diethyl(phenoxy)alumane Chemical compound CC[Al+]CC.[O-]C1=CC=CC=C1 UWAMTZZJXXCIOH-UHFFFAOYSA-M 0.000 description 1
- JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 description 1
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- TUTOKIOKAWTABR-UHFFFAOYSA-N dimethylalumane Chemical compound C[AlH]C TUTOKIOKAWTABR-UHFFFAOYSA-N 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- XOCWTYIVWYOSGQ-UHFFFAOYSA-N dipropylalumane Chemical compound C(CC)[AlH]CCC XOCWTYIVWYOSGQ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940052296 esters of benzoic acid for local anesthesia Drugs 0.000 description 1
- MNFTYNIMQNJVJI-UHFFFAOYSA-N ethoxy(dipropyl)alumane Chemical compound CC[O-].CCC[Al+]CCC MNFTYNIMQNJVJI-UHFFFAOYSA-N 0.000 description 1
- XGAIERUWZADBAO-UHFFFAOYSA-N ethoxy-bis(2-methylpropyl)alumane Chemical compound CCO[Al](CC(C)C)CC(C)C XGAIERUWZADBAO-UHFFFAOYSA-N 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- JJOYCHKVKWDMEA-UHFFFAOYSA-N ethyl cyclohexanecarboxylate Chemical compound CCOC(=O)C1CCCCC1 JJOYCHKVKWDMEA-UHFFFAOYSA-N 0.000 description 1
- NARCMUVKZHPJHP-UHFFFAOYSA-L ethyl(diiodo)alumane Chemical compound [I-].[I-].CC[Al+2] NARCMUVKZHPJHP-UHFFFAOYSA-L 0.000 description 1
- JFICPAADTOQAMU-UHFFFAOYSA-L ethylaluminum(2+);dibromide Chemical compound CC[Al](Br)Br JFICPAADTOQAMU-UHFFFAOYSA-L 0.000 description 1
- 229920005676 ethylene-propylene block copolymer Polymers 0.000 description 1
- 229920005674 ethylene-propylene random copolymer Polymers 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229940093920 gynecological arsenic compound Drugs 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APHGZSBLRQFRCA-UHFFFAOYSA-M indium(1+);chloride Chemical compound [In]Cl APHGZSBLRQFRCA-UHFFFAOYSA-M 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
- BQBCXNQILNPAPX-UHFFFAOYSA-N methoxy(dimethyl)alumane Chemical compound [O-]C.C[Al+]C BQBCXNQILNPAPX-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 1
- XBKBZMOLSULOEA-UHFFFAOYSA-L methylaluminum(2+);dibromide Chemical compound C[Al](Br)Br XBKBZMOLSULOEA-UHFFFAOYSA-L 0.000 description 1
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical compound C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 description 1
- 239000005048 methyldichlorosilane Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- DUCKXCGALKOSJF-UHFFFAOYSA-N pentanoyl pentanoate Chemical compound CCCCC(=O)OC(=O)CCCC DUCKXCGALKOSJF-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 125000004344 phenylpropyl group Chemical group 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002102 polyvinyl toluene Polymers 0.000 description 1
- VWQXLMJSFGLQIT-UHFFFAOYSA-N prop-2-enoyl bromide Chemical compound BrC(=O)C=C VWQXLMJSFGLQIT-UHFFFAOYSA-N 0.000 description 1
- GLFSWJDJMXUVEV-UHFFFAOYSA-N prop-2-enoyl iodide Chemical compound IC(=O)C=C GLFSWJDJMXUVEV-UHFFFAOYSA-N 0.000 description 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- RZWZRACFZGVKFM-UHFFFAOYSA-N propanoyl chloride Chemical compound CCC(Cl)=O RZWZRACFZGVKFM-UHFFFAOYSA-N 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- GBECUEIQVRDUKB-UHFFFAOYSA-M thallium monochloride Chemical compound [Tl]Cl GBECUEIQVRDUKB-UHFFFAOYSA-M 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- VJDDQSBNUHLBTD-UHFFFAOYSA-N trans-crotonic acid-anhydride Natural products CC=CC(=O)OC(=O)C=CC VJDDQSBNUHLBTD-UHFFFAOYSA-N 0.000 description 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
æè¡åé
æ¬çºæã¯ãªã¬ãã€ã³éåçšè§Šåªæåã«é¢ããã
ãã«è©³ããã¯é«ç«äœèŠåæ§ã§åµ©å¯åºŠã®é«ããªã¬ã
ã€ã³éåäœãé«åçã§è£œé ãåŸã觊åªæåã«é¢ã
ãã èæ¯æè¡ ããã²ã³ãå«ãŸãªããã°ãã·ãŠã ååç©ãšãã¿
ã³ååç©ãšã®æ¥è§Šç©ãããªã¬ãã€ã³éåçšè§Šåªæ
åãšããŠæå¹ã§ããããšã¯ç¥ãããŠãããããã®
觊åªæ§èœã¯äœãããã®æ¹è¯æ³ãšããŠãäžè¬åŒSiXl
R4-lã®ããã²ã³åã·ã©ã³åã¯è©²ããã²ã³åã·ã©ã³
ãšé»åäŸäžæ§ååç©ã®ååšäžãMgïŒORïŒ2ãšåã
ãã²ã³åãã¿ã³ãæ¥è§Šãããæ¹æ³ïŒç¹éæ52â
98076å·å ¬å ±ïŒãMgââçµåãæãããã°ã
ã·ãŠã ååç©ãšäžè¬åŒXnSiRoã®ã±ã€çŽ ååç©ã®
ãããªããã²ã³åå€ãæ¥è§Šãããéãåã¯æ¥è§Šã
ããåŸãé»åäŸäžæ§ååç©ãååšãããŠæ¥è§Šãã
ãæ¹æ³ïŒç¹éæ53â43094å·å ¬å ±ïŒçã§è§Šåªæå
ã補é ããè©Šã¿ããªãããŠããããŸãããã²ã³å
ã¢ã«ãããŠã ãSiâçµåãæããææ©ååç©ã
ãã³ãã°ãã·ãŠã ã¢ã«ã³ã©ãŒãã®åºäœç¶çæç©ã«
å°ãªããšãïŒåã®ããã²ã³ååãæããïŒäŸ¡ã®ã
ã¿ã³ååç©ãæ¥è§Šãããæ¹æ³ïŒç¹éæ53â78287
å·å ¬å ±ïŒãããã°ãã·ãŠã ååç©ããã¿ã³ååç©
ããã³ã±ã€çŽ ååç©ãåå¿ãããŠåŸãããåå¿ç©
ãšãå°ãªããšãïŒçš®ã®ããã²ã³åã¢ã«ãããŠã å
åç©ãšãåå¿ãããæ¹æ³ïŒç¹éæ56â155205å·å ¬
å ±ïŒã®ããã«ããã²ã³åã¢ã«ãããŠã ãå¿ é åå¿
æåãšããŠåºäœè§Šåªæåã補é ããè©Šã¿ããªãã
ãŠããã ããããªããããããã®æ¹æ³ã§åŸããã觊åªæ
åã¯ã觊åªæŽ»æ§ãäœããç«äœèŠåæ§ã«å£ãååŸã
ããéåäœã®åµ©å¯åºŠãäœãçã®åé¡ç¹ãããã ããã«ããã°ãã·ãŠã ååç©ãé»åäŸäžæ§åå
ç©ãSiâçµåãæããã±ã€çŽ ååç©åã³ãã¿ã³
ããã²ã³ååç©ãæ¥è§ŠããŠãªããªã¬ãã€ã³éå觊
åªæåãç¥ãããŠããïŒç¹éæ57â92009å·å ¬å ±ïŒ
ããå®è³ªçã«ã¯ããã°ãã·ãŠã ååç©ã¯ããã²ã³
åãã°ãã·ãŠã ã§ããããã€ã±ã€çŽ ååç©ãšãã¿
ã³ããã²ã³ååç©ã¯åæã«çšããŠæ¥è§Šããããã®
ã§ãã€ãŠããã®æ§èœãæºè¶³ãããã®ã§ã¯ãªãã çºæã®é瀺 çºæã®ç®ç æ¬çºæã¯ãåºçºåæãšããŠããã²ã³ãå«ãŸãªã
ãã°ãã·ãŠã ååç©ãçšããŠé«ç«äœèŠåæ§åã³é«
掻æ§ã瀺ãã嵩å¯åºŠã®é«ããªã¬ãã€ã³éåäœã補
é ãåŸã觊åªæåãæäŸããããšãç®çãšããã
ã®ã§ãããæ¬çºæè ãã¯éæç 究ãè¡ã€ãçµæã
ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ããšæ°ŽçŽ âçªçŽ çµåã
æããçªçŽ ååç©ãšã®åå¿ç©ãšé»åäŸäžæ§ååç©
ãšã®æ¥è§Šç©ããããã²ã³åãã¿ã³ååç©ãšïŒå以
äžæ¥è§Šãããããããã®ããã²ã³åãã¿ã³ååç©
ã®åæ¥è§Šã®éã«åšæè¡šã®ïœïŒïœïŒïœæã®å
çŽ ã®ããã²ã³åç©ãšæ¥è§ŠãããŠåŸãåºåç©ããæ¬
çºæã®ç®çãéæãåŸãããšãèŠåºããŠæ¬çºæã«
å°ã€ãã çºæã®èŠæš ããªãã¡ãæ¬çºæã¯ãã°ãã·ãŠã ãžã¢ã«ã³ãã·
ããšäžè¬åŒHmRnSiXrãäœããã¯çåæ°ŽçŽ åºã
R1Oâè¥ããã¯R2R3Nâãã¯ããã²ã³ååã
瀺ããïŒïœïŒïŒïŒïœïŒïŒïœïŒïœïŒïœïŒïŒ
ã§ãããR1ïŒR2åã³R3ã¯ããããçåæ°ŽçŽ åºã
瀺ãããã®çªçŽ ååç©ãšã®åå¿ç©ãé»åäŸäžæ§å
åç©ãšæ¥è§ŠãããŠåŸãããæ¥è§Šç©ããäžè¬åŒ
TiXnïŒORïŒ4-oãäœããã¯ããã²ã³ååãã¯
çåæ°ŽçŽ åºã瀺ããïŒïŒïœïŒã§ããããã®ãã
ã²ã³åãã¿ã³ååç©ãšïŒå以äžæ¥è§Šãããããšã
ããªãããã€åããã²ã³åãã¿ã³ååç©ã®æ¥è§Šã®
éã«ãå çŽ ã®åšæè¡šïœïŒïœåã³ïœæã®å çŽ
ã®çŸ€ããéžã°ããå çŽ ã®ããã²ã³åç©ãšæ¥è§ŠããŠ
ãªãαâãªã¬ãã€ã³éåçšè§ŠåªæåãèŠæšãšã
ãã 觊åªæå調補ã®åæ æ¬çºæã®è§Šåªæåã調補ããéã«çšããååæ
ã«ã€ããŠèª¬æããã (A) ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ã æ¬çºæã§çšãããããã°ãã·ãŠã ãžã¢ã«ã³ãã·
ãã¯ãäžè¬åŒMgïŒORïŒïŒORâ²ïŒã§è¡šãããããã®
ã§ãããåŒã«ãããŠïŒ²åã³Râ²ã¯ççŽ æ°ïŒã20åã
æãŸããã¯ïŒã10åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·
ã¯ãã¢ã«ãã«ãã¢ãªãŒã«ãã¢ã«ã¢ã«ãã«åºã§ã
ããåããšRâ²ã¯åãã§ãç°ã€ãŠãããã ãããååç©ãäŸç€ºãããšãMgïŒOCH3ïŒ2ïŒ
MgïŒOC2H5ïŒ2ïŒMgïŒOCH3ïŒïŒOC2H5ïŒïŒMgïŒOiâ
C3H7ïŒ2ïŒMgïŒOC3H7ïŒ2ïŒMgïŒOC4H9ïŒ2ïŒMgïŒOi
âC4H9ïŒ2ïŒMgïŒOC4H9ïŒïŒOiâC4H9ïŒïŒMg
ïŒOC4H9ïŒïŒOsecâC4H9ïŒïŒMgïŒOC6H13ïŒ2ïŒMg
ïŒOC3H17ïŒ2ïŒMgïŒOC6H11ïŒ2ïŒMgïŒOC6H5ïŒ2ïŒMg
ïŒOC6H4CH3ïŒ2ïŒMgïŒOCH2C6H5ïŒ2çãæããã
ãšãã§ããã ããããã°ãã·ãŠã ãžã¢ã«ã³ãã·ãã¯äœ¿çšãã
éã«ã也ç¥ããã®ãæãŸãããç¹ã«æžå§äžã§ã®å
ç±ä¹Ÿç¥ãæãŸãããããã«ãããããã°ãã·ãŠã
ãžã¢ã«ã³ãã·ãã¯ãåžè²©åãçšããŠããããå ¬ç¥
ã®æ¹æ³ã§åæãããã®ãçšããŠãããã ãã®ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ãã¯ãç¡æ©æã
ã¯ææ©ã®äžæŽ»æ§ãªåºäœç©è³ªãšäºãæ¥è§ŠãããŠäœ¿çš
ããããšãå¯èœã§ããã ç¡æ©ã®åºäœç©è³ªãšããŠã¯ãç¡«é žå¡©ãæ°Žé žåç©ã
çé žå¡©ããªã³é žå¡©ãã±ã€é žå¡©ã®ãããªéå±ååç©
ãé©ããŠãããäŸãã°ãMgïŒOHïŒ2ïŒBaCO3ïŒ
Ca3ïŒPO4ïŒ2çãæããããã ææ©ã®åºäœç©è³ªãšããŠã¯ãããŠã¬ã³ãã¢ã³ãã©
ã»ã³ãããã¿ã¬ã³ããžããšãã«ã®ãããªè³éŠæç
åæ°ŽçŽ çã®äœååéååç©ãæãããããåãã
ãªãšãã¬ã³ãããªãããã¬ã³ãããªããã«ãã«ãš
ã³ãããªã¹ãã¬ã³ãããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã
ããªã¢ãããããªãšã¹ãã«ãããªå¡©åããã«çã®
é«ååéååç©ãçšããããšãã§ããã (B) çªçŽ ååç© æ¬çºæã§çšããããçªçŽ ååç©ã¯ãäžè¬åŒHn
RoSiXrã§è¡šãããããåŒã«ãããŠãã¯çå
æ°ŽçŽ åºãRâ²OâïŒRâ²ã¯çåæ°ŽçŽ åºïŒãR2R3Nâ
ïŒR2ïŒR3ã¯çåæ°ŽçŽ åºïŒã§ãããã¯ããã²ã³å
åãïŒïœïŒïŒïŒïœïŒïŒïœïŒïœïŒïœïŒïŒã
ãããã瀺ããåãïœãïŒãè¶ ããå Žåã¯åã
ã§ãç°ã€ãŠãããã ïŒR1ïŒR2ïŒR3ã§ç€ºãããçåæ°ŽçŽ åºãšããŠ
ã¯ãççŽ æ°ïŒã16åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·
ã¯ãã¢ã«ãã«ãã¢ãªãŒã«ãã¢ã«ã¢ã«ãã«çãæã
ãããšãã§ãããã¢ã«ãã«ãšããŠã¯ãã¡ãã«ããš
ãã«ããããã«ãïœãŒããã«ãã€ãœããã«ãïœãŒ
ããã·ã«ãïœãŒãªã¯ãã«ãïŒãŒãšãã«ããã·ã«ã
ïœãŒãã·ã«çããã¢ã«ã±ãã«ãšããŠã¯ãããã«ã
ã¢ãªã«ãã€ãœããããã«ãããããã«ããããã«
çããã·ã¯ãã¢ã«ãã«ãšããŠã¯ãã·ã¯ããã³ã
ã«ãã·ã¯ãããã·ã«çããã¢ãªãŒã«ãšããŠã¯ãã
ãšãã«ãããªã«ããã·ãªã«çããã¢ã«ã¢ã«ãã«ãš
ããŠã¯ããã³ãžã«ãããšããã«ãããšãã«ããã
ã«çãæããããã ãããã®äžã§ãã¡ãã«ããšãã«ããããã«ãã€
ãœãããã«ãïœãŒããã«ãã€ãœããã«ãïœãŒãã
ã«çã®äœçŽã¢ã«ãã«åã³ããšãã«ãããªã«çã®ã¢
ãªãŒã«ãæãŸããã ã¯å¡©çŽ ãèçŽ ããšãŠçŽ çã®ããã²ã³ååã§ã
ããæãŸããã¯å¡©çŽ ååã§ããã çªçŽ ååç©ãäŸç€ºãããšãHSiCl3ïŒH2SiCl2ïŒ
H3SiClïŒHCH3SiCl2ïŒHC2H5SiCl2ïŒïŒšïŒïœâ
C4H9ïŒSiCl2ïŒHC6H5SiCl2ïŒïŒšïŒCH3ïŒ2SiClïŒïŒš
ïŒïœâC3H7ïŒ2SiClïŒH2C2H5SiClïŒH2ïŒïœâC4H9ïŒ
SiClïŒH2ïŒC6H4CH3ïŒSiClïŒHSiïŒCH3ïŒ3ïŒ
HSiCH3ïŒOCH3ïŒ2ïŒHSiCH3ïŒOC2H5ïŒ2ïŒHSi
ïŒOCH3ïŒ3ïŒïŒC2H5ïŒ2SiH2ïŒHSiïŒCH3ïŒ2ïŒOC2H5ïŒïŒ
HSiïŒCH3ïŒ2ãïŒCH3ïŒ2ãïŒHSiCH3ïŒC2H5ïŒ2ïŒ
HSiC2H5ïŒOC2H5ïŒ2ïŒHSiCH3ãïŒCH3ïŒ2ã2ïŒ
C6H5SiH3ïŒHSiïŒC2H5ïŒ3ïŒHSiïŒOC2H5ïŒ3ïŒHSi
ïŒCH3ïŒ2ãïŒC2H5ïŒ2ãïŒHSiãïŒCH3ïŒ2ã3ïŒ
C6H5CH3SiH2ïŒC6H5ïŒCH3ïŒ2SiHïŒïŒïœâ
C3H7ïŒ3SiHïŒHSiClïŒC6H5ïŒ2ïŒH2SiïŒC6H5ïŒ2ïŒ
HSiïŒC6H5ïŒ2CH3ïŒïŒïœâC5H11OïŒ3SiHïŒHSi
ïŒC6H5ïŒ3ïŒïŒïœâC5H11ïŒ3SiHçãæããããšãã§
ããã ãããã®äžã§ããåèšäžè¬åŒäžïŒ²ãçåæ°ŽçŽ ã
ïœãïŒãïŒã®æ°ãïœãïŒãïŒã®æ°ã®ããã²ã³åçª
çŽ ååç©ãããªãã¡HSiCl3ïŒH2SiCl2ïŒH3SiClïŒ
HCH3SiCl2ïŒHC2H5SiCl2ïŒïŒšïŒïœâC4H9ïŒ
SiCl2ïŒHC6H5SiCl2ïŒïŒšïŒCH3ïŒ2SiClïŒïŒšïŒïœâ
C3H7ïŒ2SiClïŒH2C2H5SiClïŒH2ïŒïœâC4H9ïŒ
SiClïŒH2ïŒC6H4CH3ïŒSiClïŒHSiClïŒC6H5ïŒ2çã
æãŸãããç¹ã«HSiCl3ïŒHCH3SiCl2ïŒïŒš
ïŒCH3ïŒ2SiClçãæãŸãããããã«äžè¬åŒäžïœïŒ
ïŒã®å ŽåãäŸãã°HSiïŒC2H5ïŒ3ïŒHSiCH3
ïŒOC2H5ïŒ2çã奜ãŸããçšããããã (C) é»åäŸäžæ§ååç© é»åäŸäžæ§ååç©ãšããŠã¯ãã«ã«ãã³é žé¡ãã«
ã«ãã³é žç¡æ°Žç©ãã«ã«ãã³é žãšã¹ãã«é¡ãã«ã«ã
ã³é žããã²ã³åç©ãã¢ã«ã³ãŒã«é¡ããšãŒãã«é¡ã
ã±ãã³é¡ãã¢ãã³é¡ãã¢ããé¡ããããªã«é¡ãã¢
ã«ãããé¡ãã¢ã«ã³ã¬ãŒãé¡ãææ©åºãšççŽ ãã
ãã¯é žçŽ ãä»ããŠçµåããçããçŽ ããã³ã¢ã³ã
ã¢ã³ååç©ããã¹ãã¢ããé¡ãããªãšãŒãã«é¡ã
ããªãšã¹ãã«é¡ãçé žãšã¹ãã«é¡ãæãããã
ãããããã®ãã¡å¥œãŸããã䜿çšããããã®ãšã
ãŠã¯ã«ã«ãã³é žãšã¹ãã«é¡ãã«ã«ãã³é žç¡æ°Žç©ã
ã«ã«ãã³é žããã²ã³åç©ãã¢ã«ã³ãŒã«é¡ããšãŒã
ã«é¡ã§ããã ã«ã«ãã³é žãšã¹ãã«ã®å ·äœäŸãšããŠã¯ãã®é žã
ãã«ãé ¢é žãšãã«ãé ¢é žããã«ãã¢ã¯ãªã«é žãšã
ã«ãé ªé žãšãã«ãã€ãœé ªé žã€ãœããã«ãã¡ã¿ã¯ãª
ã«é žã¡ãã«ããã¬ã€ã³é žãžãšãã«ãé ç³é žãžãšã
ã«ãã·ã¯ããããµã³ã«ã«ãã³é žãšãã«ãå®æ¯éŠé ž
ãšãã«ãâã¡ããã·å®æ¯éŠé žãšãã«ãâã¡ã
ã«å®æ¯éŠé žã¡ãã«ãâ第äžçŽããã«å®æ¯éŠé žãš
ãã«ããã¿ã«é žãžããã«ããã¿ã«é žãžã¢ãªã«ãα
âããããšé žãšãã«çãæãããããããããã«
éå®ããããã®ã§ã¯ãªãããããã®äžã§ãè³éŠæ
ã«ã«ãã³é žã®ã¢ã«ãã«ãšã¹ãã«ãç¹ã«å®æ¯éŠé žãŸ
ãã¯ïŒ°âã¡ãã«å®æ¯éŠé žãïœâã¡ããã·å®æ¯éŠé ž
ãªã©ã®æ žçœ®æå®æ¯éŠé žã®ççŽ æ°ïŒãïŒåã®ã¢ã«ã
ã«ãšã¹ãã«ã奜ãŸããçšãããããã«ã«ãã³é žç¡
æ°Žç©ã®å ·äœçãªäŸãšããŠã¯ãç¡æ°Žé ¢é žãç¡æ°Žãã
ããªã³é žãç¡æ°Žé ªé žãç¡æ°Žåèé žãç¡æ°Žã«ããã³
é žçã®èèªæã¢ãã«ã«ãã³é žç¡æ°Žç©ãç¡æ°Žã¢ã¯ãª
ã«é žãç¡æ°Žã¯ããã³é žãç¡æ°Žã¡ã¿ã¯ãªã«é žçã®è
èªæãªã¬ãã€ã³ã¢ãã«ã«ãã³é žç¡æ°Žç©ãã·ã¯ãã
ããµã³ã¢ãã«ã«ãã³é žç¡æ°Žç©ãã·ã¯ãããã»ã³ã¢
ãã«ã«ãã³é žç¡æ°Žç©é¡ãã·ã¹âïŒïŒïŒâã·ã¯ãã
ããµã³ç¡æ°Žãžã«ã«ãã³é žé¡ãã·ã¹âïŒâã·ã¯ãã
ãã»ã³âïŒïŒïŒâç¡æ°Žãžã«ã«ãã³é žçã®èç°åŒã«
ã«ãã³é žç¡æ°Žç©ãç¡æ°Žå®æ¯éŠé žãç¡æ°ŽïŒ°âãã«ã€
ã«é žãç¡æ°ŽïŒ°âãšãã«å®æ¯éŠé žãç¡æ°ŽïŒ°âã¡ãã
ã·å®æ¯éŠé žçã®è³éŠæã¢ãã«ã«ãã³é žç¡æ°Žç©åã³
ç¡æ°Žãã¿ã«é žçã®è³éŠæãžã«ã«ãã³é žç¡æ°Žç©ãæ
ããããšãã§ãããã«ã«ãã³é žããã²ã³åç©ã®å ·
äœäŸãšããŠã¯ãå¡©åã¢ã»ãã«ãå¡©åããããªã
ã«ãå¡©åïœâãããªã«çã®é žå¡©åç©ãèåã¢ã»ã
ã«ãèåïœâãããªã«çã®é žèåç©ããšãŠåã¢ã»
ãã«ããšãŠåïœâãããªã«çã®é žãšãŠåç©çã®è
èªæã¢ãã«ã«ãã³é žããã²ã³åç©åã³å¡©åã¢ã¯ãª
ã«ãå¡©åã¯ãããã«ãå¡©åã¡ã¿ã¯ãªã«çã®é žå¡©å
ç©ãèåã¢ã¯ãªã«ãèåã¡ã¿ã¯ãªã«çã®é žèå
ç©ããšãŠåã¢ã¯ãªã«ããšãŠåã¡ã¿ã¯ãªã«çã®é žãš
ãŠåç©çã®èèªæãªã¬ãã€ã³ã¢ãã«ã«ãã³é žãã
ã²ã³åç©ãã·ã¯ããããµã³ã«ã«ãã³é žå¡©åç©ãã·
ã¹âïŒâã¡ãã«ã·ã¯ããããµã³ã«ã«ãã³é žå¡©å
ç©ãïŒâã·ã¯ãããã»ã³ã«ã«ãã³é žå¡©åç©ãã·ã¯
ããããµã³ã«ã«ãã³é žèåç©ãã·ã¹âïŒâã¡ãã«
ããã»ã³ã«ã«ãã³é žèåç©çã®èç°åŒã«ã«ãã³é ž
ã®é žããã²ã³åç©ãå¡©åãã³ãŸã€ã«ãâãã«ã€
ã«é žå¡©åç©ãâãšãã«å®æ¯éŠé žå¡©åç©ãâã¡
ããã·å®æ¯éŠé žå¡©åç©çã®é žå¡©åç©ãèåãã³ãŸ
ã€ã«çã®é žèåç©ããšãŠåãã³ãŸã€ã«çã®é žãšãŠ
åç©çã®è³éŠæã¢ãã«ã«ãã³é žããã²ã³åç©åã³
ãã¿ã«é žãžã¯ããªãçã®è³éŠæãžã«ã«ãã³é žãã
ã²ã³åç©ãæããããšãã§ãããã¢ã«ã³âã«é¡
ã¯ãäžè¬åŒROHã§è¡šãããããåŒã«ãããŠïŒ²ã¯
ççŽ æ°ïŒã12åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·ã¯ã
ã¢ã«ãã«ãã¢ãªâã«ãã¢ã«ã¢ã«ãã«ã§ããããã®
å ·äœäŸãšããŠã¯ãã¡ã¿ãâã«ããšã¿ãâã«ããã
ããâã«ãã€ãœããããâã«ããã¿ãâã«ãã€ãœ
ãã¿ãâã«ããã³ã¿ãâã«ããããµãâã«ããªã¯
ã¿ãâã«ãïŒâãšãã«ãããµãâã«ãã·ã¯ããã
ãµãâã«ããã³ãžã«ã¢ã«ã³âã«ãã¢ãªã«ã¢ã«ã³â
ã«ãããšãâã«ãã¯ã¬ãŸâã«ããã·ã¬ãâã«ããš
ãã«ããšãâã«ãã€ãœãããã«ããšãâã«ãâ
ã¿âã·ã€ãªâããã«ããšãâã«ãïœâãªã¯ãã«ã
ãšãâã«ããããâã«çã§ããããšâãã«é¡ã¯ã
äžè¬åŒRORâ²ã§è¡šãããããåŒã«ãããŠïŒ²ïŒRâ²ã¯
ççŽ æ°ïŒã12åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·ã¯ã
ã¢ã«ãã«ãã¢ãªâã«ãã¢ã«ã¢ã«ãã«ã§ããããš
Râ²ã¯åãã§ãç°ã€ãŠãããããã®å ·äœäŸãšããŠ
ã¯ããžãšãã«ãšâãã«ããžã€ãœãããã«ãšâã
ã«ããžããã«ãšâãã«ããžã€ãœããã«ãšâãã«ã
ãžã€ãœã¢ãã«ãšâãã«ããžâïŒâãšãã«ããã·ã«
ãšâãã«ããžã¢ãªã«ãšâãã«ããšãã«ã¢ãªã«ãšâ
ãã«ãããã«ã¢ãªã«ãšâãã«ããžããšãã«ãšâã
ã«ãã¢ããœâã«ããšãã«ããšãã«ãšâãã«çã§ã
ãã (D) ããã²ã³åãã¿ã³ååç© æ¬çºæã§çšããããããã²ã³åãã¿ã³ååç©
ã¯ãäžè¬åŒTiXnïŒORïŒ4-oã§è¡šããããããã®åŒ
ã«ãããŠãã¯å¡©çŽ ãèçŽ çã®ããã²ã³ååã瀺
ããã¯å¥œãŸããã¯ççŽ æ°ïŒãïŒåã®ãã¢ã«ãã«
åºãã¢ãªãŒã«åºçã®çåæ°ŽçŽ åºã瀺ããåãïœã¯
ïŒïŒïœïŒã®ç¯å²ã®ä»»æã®æ°ã§ãããããããã
ã²ã³åãã¿ã³ååç©ãšããŠã¯ãåå¡©åãã¿ã³ãã
ãªã¯ãã«ãšããã·ãã¿ã³ããžã¯ãã«ãžãããã·ã
ã¿ã³ããžã¯ãã«ãžããšããã·ãã¿ã³çã®å䟡ã®ã
ã¿ã³ããã²ã³ååç©ãæããããç¹ã«åå¡©åãã¿
ã³ãæãŸããã (E) ïœïŒïœïŒïœæå çŽ ã®ããã²ã³åç© å çŽ ã®åšæè¡šïœãïœåã³ïœæã®å çŽ ãã
éžã°ããå çŽ ã®ããã²ã³åç©ïŒä»¥äžãéå±ãã©ã€
ããšãããïŒãšããŠã¯ãïŒAlïŒGaïŒInïŒTlïŒ
SiïŒGeïŒSnïŒPbïŒAsïŒSbïŒBiã®å¡©åç©ãåŒå
ç©ãèåç©ããšãŠåç©ãæããããç¹ã«BCl3ïŒ
BBr3ïŒBI3ïŒAlCl3ïŒAlBr3ïŒAlI3ïŒGaCl3ïŒ
GaBr3ïŒInCl3ïŒTlCl3ïŒSiCl4ïŒSnCl4ïŒSbCl5ïŒ
SbF5çã奜é©ã§ããã 觊åªæåã®èª¿è£œæ³ æ¬çºæã®è§Šåªæåã¯ããã°ãã·ãŠã ãžã¢ã«ã³
ãã·ãïŒïŒ¡æåïŒãšçªçŽ ååç©ïŒïŒ¢æåïŒãšã®å
å¿ç©ããé»åäŸäžæ§ååç©ïŒïŒ£æåïŒãšæ¥è§Šã
ããããã²ã³åãã¿ã³ååç©ïŒïŒ€æåïŒãšïŒå
以äžæ¥è§Šããããã€åããã²ã³åãã¿ã³ååç©
ã«ããæ¥è§Šã®éã«éå±ãã©ã€ãïŒïŒ¥æåïŒãšæ¥è§Š
ãããããšã«ãã€ãŠåŸãããã次ã«ãã®èª¿æŽæ³ã«
ã€ããŠèª¬æããã ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ããšçªçŽ ååç©ãš
ã®åå¿ ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ãïŒïŒ¡æåïŒãšçªçŽ
ååç©ïŒïŒ¢æåïŒãšã®åå¿ã¯ãäž¡è ãæ¥è§Šããã
ããšã«ãã€ãŠãªãããããæãŸããã¯ãçåæ°ŽçŽ
ã®ååšäžäž¡è ãæ··åæ¹æããæ¹æ³ã§ããã çåæ°ŽçŽ ãšããŠã¯ããããµã³ãããã¿ã³ããªã¯
ã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³ãã
ã·ã¬ã³çã®ççŽ æ°ïŒã12åã®é£œåèèªæã飜åè
ç°åŒåã³è³éŠæçåæ°ŽçŽ ãæãŸããã æåãšïŒ¢æåãšã®æ¥è§Šå²åã¯ãæåïŒã¢ã«
åœããæå0.5ã10ã¢ã«ãæãŸããã¯ïŒãïŒã¢
ã«ã§ãããäž¡è ã®æ¥è§Šã¯ãéåžžïŒã200âã§0.5ã
100æéè¡ãªããããæååã³ïŒ¢æåã¯äžçš®ã«
éããåæã«äºçš®ä»¥äžçšããŠãããã çåæ°ŽçŽ ã®äœ¿çšéã¯ãä»»æã§ããããæå
1gã«å¯ŸããŠ100ml以äžãæãŸããã æåã«ããã²ã³åçªçŽ ååç©ãçšããå Žåã
æåãšã®æ¥è§Šã«ãããã¬ã¹ãçºçããåå¿ãè¡
ãªãããŠããããšãèªããããããçºçããã¬ã¹
ã®çµæããããã®åå¿ã¯ãã°ãã·ãŠã ãžã¢ã«ã³ã
ã·ããåã«ããã²ã³åããã ããšã¯èãã«ããã
åå¿ç©ã®åæçµæãããçªçŽ ååãäœãããã®åœ¢
ã§çµåããååç©ãçæãããã®ãšèããããã
åå¿ç©äžã«å«ãŸããçªçŽ ååã®éã¯ã65âã®äžæŽ»
æ§æº¶åªãç¹ã«ïœâãããµã³åã¯ïœâããã¿ã³ãã«
溶解ããªãéãšããŠïŒééïŒ ä»¥äžã§ããã æåãšïŒ¢æåã®æ¥è§Šç©ã¯ãåå¿ç³»ããåé¢ã
ãã次ã®æ¥è§Šã«äŸãããããå¿ èŠã«å¿ããŠæ¬¡ã®æ¥
觊ã®åã«ãæåãšïŒ¢æåã®æ¥è§Šã®éã«çšããã
ãçåæ°ŽçŽ ã®ãããªäžæŽ»æ§ãªçåæ°ŽçŽ ã§æŽæµãã
ããšãã§ãããæŽæµã¯å ç±äžã§è¡ã€ãŠãããã é»åäŸäžæ§ååç©ãšã®æ¥è§Š äžèšã§åŸãããåå¿ç©ãšé»åäŸäžæ§ååç©
ïŒïŒ£æåïŒãšã®æ¥è§Šã¯ãäž¡è ãäžæŽ»æ§ã¯çåæ°ŽçŽ
ã®ååšäžåã¯äžååšäžã«ãæ··åæ¹æããæ¹æ³ãæ©
械çã«å ±ç²ç ããæ¹æ³çã«ããéæããããäžæŽ»
æ§ãªçåæ°ŽçŽ ãšããŠã¯ããããµã³ãããã¿ã³ããª
ã¯ã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³ã
ãã·ã¬ã³çãæããããã æ©æ¢°çå ±ç²ç ã«ããæ¥è§Šã®å Žåã®æ¥è§Šæž©åºŠã¯ã
ïŒã100âãæ¥è§Šæéã¯0.1ã100æéã§ãããåã
åã«æ¹æããæ¥è§Šæ¹æ³ã®å Žåã®æ¥è§Šæž©åºŠã¯ãïŒã
150âãæ¥è§Šæéã¯0.5ã10æéã§ããã é»åäŸäžæ§ååç©ã¯ããã°ãã·ãŠã ãžã¢ã«ã³ã
ã·ããšçªçŽ ååç©ãšã®æ¥è§Šç©äžã®ãã°ãã·ãŠã ïŒ
ã°ã©ã åååœã0.01ã10ã°ã©ã ã¢ã«ãç¹ã«0.05ã
ïŒã°ã©ã ã¢ã«ã®ç¯å²ã§çšããã®ãæãŸããã ããã²ã³åãã¿ã³ååç©ãšã®æ¥è§Š äžèšã§åŸãããæ¥è§Šç©ã¯ã次ãã§ããã²ã³å
ãã¿ã³ååç©ïŒïŒ€æåïŒãšïŒå以äžæ¥è§Šãããã
äž¡è ã¯ãã®ãŸãŸæ¥è§ŠãããŠãããããçåæ°ŽçŽ ã®
ååšäžãäž¡è ãæ··åæ¹æããæ¹æ³ãæãŸãããç
åæ°ŽçŽ ãšããŠã¯ããããµã³ãããã¿ã³ããªã¯ã¿
ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³ããã·
ã¬ã³çãæããããã 該æ¥è§Šç©ãšïŒ€æåãšã®æ¥è§Šå²åã¯è©²æ¥è§Šç©äžã®
ãã°ãã·ãŠã ïŒã°ã©ã åååœããæå0.1ã°ã©
ã ã¢ã«ä»¥äžãæãŸããã¯ïŒã50ã°ã©ã ã¢ã«ã§ã
ãã äž¡è ã®æ¥è§Šæ¡ä»¶ã¯ãçåæ°ŽçŽ ã®ååšäžã§è¡ãå Ž
åãïŒã200âã§0.5ã20æéãæãŸããã¯60ã
150âã§ïŒãïŒæéã§ããã çåæ°ŽçŽ ã®äœ¿çšéã¯ã該æ¥è§Šç©ã液äœç©è³ªïŒç
åæ°ŽçŽ åã³æ¶²ç¶ã®ïœæåïŒ1låœãã10ã300gãšãª
ãããã«çšããã®ãæãŸããã ïŒåç®ä»¥åŸã®ïŒ€æåãšã®æ¥è§Šã¯ãäžèšã§è¿°ã¹ã
ããã²ã³åçåæ°ŽçŽ ã«ããæ¥è§Šã§çšãããããã
ã²ã³åçåæ°ŽçŽ ãšåé¢ããåŸãäžèšãšåæ§ã«ããŠ
è¡ãªãããã éå±ãã©ã€ããšã®æ¥è§Š ïŒå以äžã®ïŒ€æåãšã®åæ¥è§Šã®éã«è¡ãªããã
éå±ãã©ã€ãïŒïŒ¥æåïŒãšã®æ¥è§Šã¯ãäžèšã§çš
ããããæåïŒåã³çåæ°ŽçŽ ïŒããåé¢ããåº
åç©ãæåãšæ¥è§Šãããããšã«ãã€ãŠãªãã
ãã 該åºåç©ãšïŒ¥æåã®æ¥è§Šã¯ãäž¡è ããã®ãŸãŸæ¥
觊ãããããšãå¯èœã§ãããåçåæ°ŽçŽ ã®ååšäž
è¡ã€ãŠãããããã®æ¥è§Šæ¹æ³ã¯ãæ©æ¢°çã«å ±ç²ç
ããæ¹æ³ãæ··åæ¹æããæ¹æ³ãæ¡çšã§ããã 該åºåç©ãšïŒ¥æåã®æ¥è§Šå²åã¯ã該åºåç©äžã®
ãã°ãã·ãŠã 1gåååœããæåã0.1ã¢ã«ä»¥äžã
æãŸããã¯0.5ã150ã¢ã«ã§ãããäž¡è ã®æ¥è§Šæ¡ä»¶
ã¯ãïŒã200âã§0.1ã15æéãæãŸããã¯25ã90
âã§0.5ãïŒæéã§ããã äžèšã®ããã«ããŠåŸãããåºäœç¶ç©è³ªã¯ãå¿ èŠ
ã«å¿ããŠãããµã³ãããã¿ã³ããªã¯ã¿ã³ãã·ã¯ã
ãããµã³ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®äž
掻æ§ãªçåæ°ŽçŽ ã§æŽæµãã也ç¥ããããšã«ãã€ãŠ
æ¬çºæã®è§Šåªæåãšããã æ¬çºæã®è§Šåªæåã¯ããããïŒBETïŒæ³ã§æ¶²
äœçªçŽ ã®åžç枩床ã«ãããŠæž¬å®ããæ¯è¡šé¢ç©ã50
ã650m2ïŒïœã现å容ç©ã0.05ã0.40ccïŒïœã§ã
ãããã®ç²åºŠååžãçããŠå€§ãããæã€ãŠããã
åããã®çµæã¯ãã°ãã·ãŠã ååã10ã25éé
ïŒ ããã¿ã³ååãïŒã10ééïŒ ãããã²ã³ååã
40ã60ééïŒ ãçªçŽ ååã1.5ã8.5ééïŒ ã§ã
ãããã®ä»ææ©ååç©çãå«ããåã觊åªæåã
調補ããéã«çšããéå±ãã©ã€ããé»åäŸäžæ§å
åç©åã³ïŒåã¯ãããã®å€æç©è³ªãå°éå«ãŸãã
å Žåãããã ãªã¬ãã€ã³ã®éåè§Šåª æ¬çºæã®è§Šåªæåã¯ãææ©ã¢ã«ãããŠã ååç©
ãšçµåããŠÎ±âãªã¬ãã€ã³ã®åç¬éååã¯ä»ã®ãª
ã¬ãã€ã³ãšã®å ±éåçšã®è§Šåªãšããã ææ©ã¢ã«ãããŠã ååç© Î±âãªã¬ãã€ã³ãéåããéã«è§Šåªæåãšçµå
ããææ©ã¢ã«ãããŠã ååç©ã¯ãäžè¬åŒRo
AlX3-oïŒäœããã¯ã¢ã«ãã«åºåã¯ã¢ãªãŒã«åºã
ã¯ããã²ã³ååãã¢ã«ã³ãã·åºåã¯æ°ŽçŽ ååã
瀺ããïœã¯ïŒïœïŒã®ç¯å²ã®ä»»æã®æ°ã§ãããïŒ
ã§ç€ºããããã®ã§ãããäŸãã°ããªã¢ã«ãã«ã¢ã«
ãããŠã ããžã¢ã«ãã«ã¢ã«ãããŠã ã¢ããã©ã€
ããã¢ãã¢ã«ãã«ã¢ã«ãããŠã ãžãã©ã€ããã¢ã«
ãã«ã¢ã«ãããŠã ã»ã¹ããã©ã€ãããžã¢ã«ãã«ã¢
ã«ãããŠã ã¢ãã¢ã«ã³ãã·ãåã³ãžã¢ã«ãã«ã¢ã«
ãããŠã ã¢ããã€ãã©ã€ããªã©ã®ççŽ æ°ïŒãªãã
18åã奜ãŸããã¯ççŽ æ°ïŒãªããïŒåã®ã¢ã«ãã«
ã¢ã«ãããŠã ååç©åã¯ãã®æ··åç©ãããã¯é¯å
åç©ãç¹ã«å¥œãŸãããå ·äœçã«ã¯ãããªã¡ãã«ã¢
ã«ãããŠã ãããªãšãã«ã¢ã«ãããŠã ãããªãã
ãã«ã¢ã«ãããŠã ãããªã€ãœããã«ã¢ã«ãããŠ
ã ãããªããã·ã«ã¢ã«ãããŠã ãªã©ã®ããªã¢ã«ã
ã«ã¢ã«ãããŠã ããžã¡ãã«ã¢ã«ãããŠã ã¯ããª
ãããžãšãã«ã¢ã«ãããŠã ã¯ããªãããžãšãã«ã¢
ã«ãããŠã ããããããžãšãã«ã¢ã«ãããŠã ã¢ã€
ãªãã€ãããžã€ãœããã«ã¢ã«ãããŠã ã¯ããªããª
ã©ã®ãžã¢ã«ãã«ã¢ã«ãããŠã ã¢ããã©ã€ããã¡ã
ã«ã¢ã«ãããŠã ãžã¯ããªãããšãã«ã¢ã«ãããŠã
ãžã¯ããªããã¡ãã«ã¢ã«ãããŠã ãžããããããš
ãã«ã¢ã«ãããŠã ãžããããããšãã«ã¢ã«ãããŠ
ã ãžã¢ã€ãªãã€ããã€ãœããã«ã¢ã«ãããŠã ãžã¯
ããªããªã©ã®ã¢ãã¢ã«ãã«ã¢ã«ãããŠã ãžãã©ã€
ãããšãã«ã¢ã«ãããŠã ã»ã¹ãã¯ããªããªã©ã®ã¢
ã«ãã«ã¢ã«ãããŠã ã»ã¹ããã©ã€ãããžã¡ãã«ã¢
ã«ãããŠã ã¡ããã·ãããžãšãã«ã¢ã«ãããŠã ãš
ããã·ãããžãšãã«ã¢ã«ãããŠã ããšããã·ãã
ãžãããã«ã¢ã«ãããŠã ãšããã·ãããžã€ãœãã
ã«ã¢ã«ãããŠã ãšããã·ãããžã€ãœããã«ã¢ã«ã
ããŠã ããšããã·ããªã©ã®ãžã¢ã«ãã«ã¢ã«ãããŠ
ã ã¢ãã¢ã«ã³ãã·ãããžã¡ãã«ã¢ã«ãããŠã ãã€
ãã©ã€ãããžãšãã«ã¢ã«ãããŠã ãã€ãã©ã€ãã
ãžãããã«ã¢ã«ãããŠã ãã€ãã©ã€ãããžã€ãœã
ãã«ã¢ã«ãããŠã ãã€ãã©ã€ããªã©ã®ãžã¢ã«ãã«
ã¢ã«ãããŠã ãã€ãã©ã€ããæããããã ãããã®äžã§ããããªã¢ã«ãã«ã¢ã«ãããŠã
ããç¹ã«ããªãšãã«ã¢ã«ãããŠã ãããªã€ãœãã
ã«ã¢ã«ãããŠã ãæãŸãããåããããããªã¢ã«
ãã«ã¢ã«ãããŠã ã¯ããã®ä»ã®ææ©ã¢ã«ãããŠã
ååç©ãäŸãã°ãå·¥æ¥çã«å ¥æãæããžãšãã«ã¢
ã«ãããŠã ã¯ããªãããšãã«ã¢ã«ãããŠã ãžã¯ã
ãªãããšãã«ã¢ã«ãããŠã ã»ã¹ãã¯ããªãããžãš
ãã«ã¢ã«ãããŠã ãšããã·ãããžãšãã«ã¢ã«ãã
ãŠã ãã€ãã©ã€ãåã¯ãããã®æ··åç©è¥ããã¯é¯
ååç©çãšäœµçšããããšãã§ããã ããã«ãææ©ã¢ã«ãããŠã ååç©ã¯ãåç¬ã§çš
ããŠãããããé»åäŸäžæ§ååç©ãšçµåããŠçšã
ãŠããããé»åäŸäžæ§ååç©ãšããŠã¯ãåèšè§Šåª
æå調補æã«çšããããé»åäŸäžæ§ååç©ãªã
ã°ãã©ã®ååç©ãçšããããšãã§ããããäžã§ã
ã«ã«ãã³é žãšã¹ãã«é¡ãã¢ã«ã³ãŒã«é¡ããšâãã«
é¡ãã±ãã³é¡ãæãŸããããããé»åäŸäžæ§åå
ç©ã¯ãææ©ã¢ã«ãããŠã ååç©ã觊åªæåãšçµå
ããŠçšããéã«çšããŠããããäºãææ©ã¢ã«ãã
ãŠã ååç©ãšæ¥è§Šãããäžã§çšããŠãããã æ¬çºæã®è§Šåªæåã«å¯Ÿããææ©ã¢ã«ãããŠã å
åç©ã®äœ¿çšéã¯ã該觊åªæåäžã®ãã¿ã³ïŒã°ã©ã
åååœããéåžžïŒã2000ã°ã©ã ã¢ã«ãç¹ã«20ã
500ã°ã©ã ã¢ã«ãæãŸããã åãææ©ã¢ã«ãããŠã ååç©ãšé»åäŸäžæ§åå
ç©ã®æ¯çã¯ãé»åäŸäžæ§ååç©ïŒã¢ã«ã«å¯ŸããŠæ
æ©ã¢ã«ãããŠã ååç©ãã¢ã«ãããŠã ãšããŠ0.1
ã40ã奜ãŸããã¯ïŒã25ã°ã©ã ååã®ç¯å²ã§éžã°
ããã ãªã¬ãã€ã³ã®éå äžèšã®ããã«ããŠåŸããã觊åªæåãšææ©ã¢ã«
ãããŠã ååç©ïŒåã³é»åäŸäžæ§ååç©ïŒãããª
ã觊åªã¯ãαâãªã¬ãã€ã³ãç¹ã«ççŽ æ°ïŒãªãã
ïŒåã®Î±âãªã¬ãã€ã³ãäŸãã°ãããã¬ã³ãïŒâ
ããã³ãïŒâã¡ãã«âïŒâãã³ãã³ãïŒâãããµ
ã³çã®åç¬éååã¯äžèšã®Î±âãªã¬ãã€ã³çžäºå
ã³ïŒåã¯ãšãã¬ã³ãšã®ã©ã³ãã åã³ãããã¯å ±é
åã®è§Šåªããšãã¬ã³ã®åç¬éååã¯ãšãã¬ã³ãšç
çŽ æ°ïŒã10åã®Î±âãªã¬ãã€ã³ãäŸãã°ãããã¬
ã³ãïŒâããã³ãïŒâã¡ãã«âïŒâãã³ãã³ãïŒ
âããã»ã³ãïŒâãªã¯ãã³çãšã®ã©ã³ãã è¥ãã
ã¯ãããã¯å ±éåã®è§ŠåªãšããŠæ¥µããŠåªããæ§èœ
ã瀺ãã éååå¿ã¯ãæ°çžã液çžã®ãããã§ãããã液
çžã§éåãããå Žåã¯ããã«ãã«ãã¿ã³ãã€ãœã
ã¿ã³ããã«ãã«ãã³ã¿ã³ãã€ãœãã³ã¿ã³ããããµ
ã³ãããã¿ã³ããªã¯ã¿ã³ãã·ã¯ããããµã³ããã³
ãŒã³ããã«ãšã³ããã·ã¬ã³çã®äžæŽ»æ§çåæ°ŽçŽ äž
åã³æ¶²ç¶ã¢ãããŒäžã§è¡ãããšãã§ãããéåæž©
床ã¯ãéåžžâ80âãïŒ150âã奜ãŸããã¯40ã120
âã®ç¯å²ã§ãããéåå§åã¯ãäŸãã°ïŒã60æ°å§
ã§ãããåãåŸãããéåäœã®ååéã®èª¿ç¯ã¯ã
æ°ŽçŽ è¥ããã¯ä»ã®å ¬ç¥ã®ååé調ç¯å€ãååšãã
ããããšã«ããè¡ãªããããåãå ±éåã«ãããŠ
ãªã¬ãã€ã³ã«å ±éåãããä»ã®ãªã¬ãã€ã³ã®é
ã¯ããªã¬ãã€ã³ã«å¯ŸããŠéåžž30ééïŒ è¿ãç¹ã«
0.3ã15ééïŒ ã®ç¯å²ã§éžã°ãããæ¬çºæã®è§Šåª
ç³»ã«ããéååå¿ã¯ãé£ç¶åã¯ãããåŒåå¿ã§è¡
ãªãããã®æ¡ä»¶ã¯éåžžçšããããæ¡ä»¶ã§ããã
åãå ±éååå¿ã¯äžæ®µã§è¡ã€ãŠããããäºæ®µä»¥äž
ã§è¡ã€ãŠãããã çºæã®å¹æ æ¬çºæã®è§Šåªæåã¯ãããªãªã¬ãã€ã³ãç¹ã«ã¢
ã€ãœã¿ã¯ããã¯ããªãããã¬ã³ããšãã¬ã³ãšãã
ãã¬ã³ãšã®ã©ã³ãã å ±éåäœåã³ãšãã¬ã³ãšãã
ãã¬ã³ãšã®ãããã¯å ±éåäœã補é ããå Žåã®è§Š
åªæåãšããŠæå¹ã§ããã æ¬çºæã®è§Šåªæåãçšããéå觊åªã¯ãéå掻
æ§åã³ç«äœèŠåæ§ãé«ããããããã®é«ãéå掻
æ§ãéåæã«é·æéæç¶ããããšãã§ãããšå ±
ã«ãåŸããããªã¬ãã€ã³éåäœç²æ«ã¯åµ©å¯åºŠãé«
ããåããã®éåäœç²æ«ã¯æµåæ§ã«å¯ãã§ããã å®æœäŸ 次ã«ãæ¬çºæãå®æœäŸåã³å¿çšäŸã«ããå ·äœç
ã«èª¬æãããäœããæ¬çºæã¯å®æœäŸã®ã¿ã«ããé
å®ããããã®ã§ã¯ãªãããªããå®æœäŸåã³å¿çšäŸ
ã«ç€ºããããŒã»ã³ãïŒïŒ ïŒã¯ãç¹ã«æããªãéã
ééã«ããã 觊åªæåã®æ¯è¡šé¢ç©ïŒS.A.ïŒåã³çŽ°å容ç©ïŒP.
V.ïŒã¯ãCARLO ERBA補SORPTOMATIC
1810åè£ çœ®ãçšããŠæž¬å®ãããéå掻æ§Kcã¯è§Š
åªæå1gåœãã®ããªããŒçæéïŒïœïŒãKtã¯è§Šåª
æåäžã®Ti1gåœãã®ããªããŒçæéïŒKgïŒã§ã
ãã ããªããŒäžã®çµæ¶æ§ããªããŒã®å²åã瀺ããã
ã¿ã³äžæº¶åïŒä»¥äžH.I.ãšç¥ç§°ãããïŒã¯ãæ¹è¯å
ãœãã¯ã¹ã¬ãŒæœåºåšã§æ²žéš°ïœâããã¿ã³ã«ããïŒ
æéæœåºããå Žåã®æ®éã§ãããã¡ã«ããããŒã¬
ã€ãïŒMFRïŒåã³ã¡ã«ãã€ã³ããã¯ã¹ïŒMIïŒã¯
ASTMâD1238ã«åŸã€ãŠæž¬å®ãããå嵩å¯åºŠã¯
ASTMâD1895â69ã¡ãœããã«åŸã€ãŠæž¬å®ã
ãã å®æœäŸ ïŒ ãã°ãã·ãŠã ãžãšããã·ããšããªã¯ãã«ã·ã©ã³
ã®åå¿ éæµåçž®åšã滎äžããŒãåã³æ¹ææ©ãåä»ãã
2lã®ã¬ã©ã¹è£œåå¿åšãååã«çªçŽ ã¬ã¹ã§çœ®æã
ãããã®åå¿åšã«åžè²©ã®ãã°ãã·ãŠã ãžãšããã·
ã120gïŒ1.05ã¢ã«ïŒåã³ïœâããã¿ã³680mlãå ¥ã
ãåŸã宀枩ã§æ¹æããªããããªã¯ãã«ã·ã©ã³
356gïŒ2.63ã¢ã«ïŒãšïœâããã¿ã³250mlã®æ··å溶液
ã滎äžããŒããã45åéã§æ»ŽäžããæŽã«70âã§ïŒ
æéæ¹æããããã®éåå¿ç³»ãããäž»ãšããŠãšã
ã¬ã³ããšãã«ã¯ããªãã¬ã¹ãçºçãããåŸããã
åºäœã70âã§å¥ãã65âã®ïœâãããµã³600ml
ãš10åéæ¹æäžæ¥è§ŠãããŠæŽæµããåŸãäžæŸæ¶²ã
ãã«ã³ããŒã·ãšã³ã«ããé€å»ãããæŽã«ããã®ïœ
âãããµã³ã«ããæŽæµãïŒåç¹°ãè¿ããåŸãæžå§
äž60âã§ïŒæé也ç¥ããŠãåºäœæåïŒïŒ177g
ãåŸããåºäœæåïŒïŒã¯ããã°ãã·ãŠã ã12.7
ïŒ ãçªçŽ ã14.2ïŒ ãå¡©çŽ ã46.0ïŒ å«ã¿ããã®æ¯è¡š
é¢ç©ã¯25m2ïŒïœã现å容ç©ã¯0.06c.c.ïŒïœã§ãã€
ãã å®æ¯éŠé žãšãã«ãšã®æ¥è§Š åºäœæåïŒïŒ15gããçŽåŸ12mmã®ã¹ãã³ã¬ã¹
ïŒSUS316ïŒè£œããŒã«100åãå容ããå 容ç©300
mlã®ã¹ãã³ã¬ã¹ïŒSUS316ïŒè£œãã«ãããã«ãçª
çŽ ã¬ã¹é°å²æ°äžã§å ¥ãã次ãã§å®æ¯éŠé žãšãã«
3.8gãå ãããã®ãã«ããããæ¯ãšãåšã«è£ çã
ãåŸãïŒæéæ¯ãšãããŠç²ç åŠçãè¡ããåºäœæ
åïŒïŒãåŸãã åå¡©åãã¿ã³åã³åå¡©åã±ã€çŽ ãšã®æ¥è§Š åºäœæåïŒïŒ7gããæ¹ææ©ãåä»ãã200ml
ã®ã¬ã©ã¹è£œåå¿åšã«çªçŽ ã¬ã¹é°å²æ°äžã§å ¥ãã次
ãã§ãã«ãšã³40mlãåå¡©åãã¿ã³60mlãå ãã90
âã§ïŒæéæ¹æããããã«ã³ããŒã·ãšã³ã«ããäž
æŸæ¶²ãé€å»ããåŸããã«ãšã³85mlãåå¡©åã±ã€çŽ
6.3gãå ãã60âã§ïŒæéæ¥è§Šããããå90mlã®
ãã«ãšã³ã«ãŠ60âã§ïŒåæŽæµããåŸããã«ãšã³40
mlãåå¡©åãã¿ã³60mlãå ãã90âã§ïŒæéæ¹æ
ãããåŸãããåºäœç¶ç©è³ªã90âã§å¥ããå90
mlã®ïœâãããµã³ã«ãŠã宀枩äžã§ïŒåæŽæµãã
åŸãæžå§äžãå枩床ã§ïŒæé也ç¥ããŠããã¿ã³
2.5ïŒ ããã°ãã·ãŠã 17.5ïŒ ãå¡©çŽ 55.8ïŒ ãçªçŽ
3.8ïŒ ãå®æ¯éŠé žãšãã«12.4ïŒ ãããããå«ã觊
åªæåã4.4gåŸããåãæ¯è¡šé¢ç©ã¯265m2ïŒïœã
现å容ç©ã¯0.22c.c.ïŒïœã§ãã€ãã å®æœäŸ ïŒãïŒ å®æœäŸïŒã§çšããåå¡©åã±ã€çŽ ã«ä»£ããŠãåå¡©
åé«ïŒå®æœäŸïŒïŒãäºå¡©åã¢ã³ãã¢ã³ïŒå®æœäŸ
ïŒïŒãäžå¡©åã¢ã«ãããŠã ïŒå®æœäŸïŒïŒãäžå¡©åã
ãŠçŽ ïŒå®æœäŸïŒïŒãããããçšãã以å€ã¯ãå®æœ
äŸïŒãšåæ§ã«ããŠã觊åªæåã調補ãããåŸãã
ã觊åªæåã®çµæã第ïŒè¡šã«ç€ºããã å®æœäŸ ïŒïŒïŒ å®æœäŸïŒã«ãããåºäœæåïŒïŒãšã®æ¥è§Šã«çš
ããå®æ¯éŠé žãšãã«ã«ä»£ããŠãç¡æ°Žå®æ¯éŠé žïŒå®
æœäŸïŒïŒãå¡©åãã³ãŸã€ã«ïŒå®æœäŸïŒïŒãããã
ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«ããŠè§Šåªæå
ã調補ãããåŸããã觊åªæåã®çµæã第ïŒè¡šã«
瀺ããã å®æœäŸ ïŒã11 å®æœäŸïŒã«ãããŠãã°ãã·ãŠã ãžãšããã·ããš
æ¥è§Šããéã«çšããããªã¯ãã«ã·ã©ã³ã®ä»£ãã«ã
ã¡ãã«ãžã¯ãã«ã·ã©ã³ïŒå®æœäŸïŒïŒããžã¡ãã«ã¯
ãã«ã·ã©ã³ïŒå®æœäŸïŒïŒãããªãšãã«ã·ã©ã³ïŒå®
æœäŸ10ïŒããžãšããã·ã¡ãã«ã·ã©ã³ïŒå®æœäŸ11ïŒ
ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«ããŠã觊åªæ
åã調補ãããåŸããã觊åªæåã®çµæã第ïŒè¡š
ã«ç€ºããã å®æœäŸ 12 å®æ¯éŠé žãšãã«ã®ä»£ããã«ããã¿ã«é žãžïœâã
ãã«ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«ããŠè§Šåª
æåã調補ãããåŸããã觊åªæåã®çµæã第ïŒ
è¡šã«ç€ºããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠçšãããã«ãããã«ãçªçŽ ã¬
ã¹é°å²æ°äžãåžè²©ã®ãã°ãã·ãŠã ãžãšããã·ã
31.5gãå®æ¯éŠé žãšãã«7.5mlãå ¥ãããã®ãã«ã
ãããæ¯ãšãåšã«è£ çããŠã15æéæ¯ãšãããã åŸãããç²ç åºäœ9.2gãã200mlã®æ¹ææ©ä»ã
ã¬ã©ã¹å®¹åšã«å ¥ãããã«ãšã³40mlãåå¡©åãã¿ã³
60mlãå ãã90âã§ïŒæéæ¹æãããåŸãããåº
äœç¶ç©è³ªã90âã§å¥ãã90mlã®ïœâãããµã³ã«
ãŠã宀枩äžïŒåæŽæµããåŸãæžå§äžã宀枩ã§ïŒæ
é也ç¥ããŠç¬¬ïŒè¡šã«ç€ºãçµæãæãã觊åªæåã
調補ããã æ¯èŒäŸ ïŒ æ¯èŒäŸïŒã§åŸãããç²ç åºäœ5.3gãã500mlã®
æ¹ææ©ä»ãã¬ã©ã¹å®¹åšã«å ¥ããããã«ïœâããã¿
ã³330mlãå ããã次ã«ãåå¡©åãã¿ã³ïŒmlã宀
æž©äž15åéã§æ»ŽäžããæŽã«ããªã¯ãã«ã·ã©ã³35ml
ãåæ§ã«ããŠæ»ŽäžããåŸã90âã§ïŒæéæ¹æã
ãã åŸãããåºäœç¶ç©è³ªã90âã§å¥ãã150mlã®
ïœâãããµã³ã«ãŠå®€æž©äžãïŒåæŽæµããåŸãæžå§
äžã宀枩ã§ïŒæé也ç¥ããŠã第ïŒè¡šã«ç€ºãçµæã®
觊åªæåã調補ããã
ãã«è©³ããã¯é«ç«äœèŠåæ§ã§åµ©å¯åºŠã®é«ããªã¬ã
ã€ã³éåäœãé«åçã§è£œé ãåŸã觊åªæåã«é¢ã
ãã èæ¯æè¡ ããã²ã³ãå«ãŸãªããã°ãã·ãŠã ååç©ãšãã¿
ã³ååç©ãšã®æ¥è§Šç©ãããªã¬ãã€ã³éåçšè§Šåªæ
åãšããŠæå¹ã§ããããšã¯ç¥ãããŠãããããã®
觊åªæ§èœã¯äœãããã®æ¹è¯æ³ãšããŠãäžè¬åŒSiXl
R4-lã®ããã²ã³åã·ã©ã³åã¯è©²ããã²ã³åã·ã©ã³
ãšé»åäŸäžæ§ååç©ã®ååšäžãMgïŒORïŒ2ãšåã
ãã²ã³åãã¿ã³ãæ¥è§Šãããæ¹æ³ïŒç¹éæ52â
98076å·å ¬å ±ïŒãMgââçµåãæãããã°ã
ã·ãŠã ååç©ãšäžè¬åŒXnSiRoã®ã±ã€çŽ ååç©ã®
ãããªããã²ã³åå€ãæ¥è§Šãããéãåã¯æ¥è§Šã
ããåŸãé»åäŸäžæ§ååç©ãååšãããŠæ¥è§Šãã
ãæ¹æ³ïŒç¹éæ53â43094å·å ¬å ±ïŒçã§è§Šåªæå
ã補é ããè©Šã¿ããªãããŠããããŸãããã²ã³å
ã¢ã«ãããŠã ãSiâçµåãæããææ©ååç©ã
ãã³ãã°ãã·ãŠã ã¢ã«ã³ã©ãŒãã®åºäœç¶çæç©ã«
å°ãªããšãïŒåã®ããã²ã³ååãæããïŒäŸ¡ã®ã
ã¿ã³ååç©ãæ¥è§Šãããæ¹æ³ïŒç¹éæ53â78287
å·å ¬å ±ïŒãããã°ãã·ãŠã ååç©ããã¿ã³ååç©
ããã³ã±ã€çŽ ååç©ãåå¿ãããŠåŸãããåå¿ç©
ãšãå°ãªããšãïŒçš®ã®ããã²ã³åã¢ã«ãããŠã å
åç©ãšãåå¿ãããæ¹æ³ïŒç¹éæ56â155205å·å ¬
å ±ïŒã®ããã«ããã²ã³åã¢ã«ãããŠã ãå¿ é åå¿
æåãšããŠåºäœè§Šåªæåã補é ããè©Šã¿ããªãã
ãŠããã ããããªããããããã®æ¹æ³ã§åŸããã觊åªæ
åã¯ã觊åªæŽ»æ§ãäœããç«äœèŠåæ§ã«å£ãååŸã
ããéåäœã®åµ©å¯åºŠãäœãçã®åé¡ç¹ãããã ããã«ããã°ãã·ãŠã ååç©ãé»åäŸäžæ§åå
ç©ãSiâçµåãæããã±ã€çŽ ååç©åã³ãã¿ã³
ããã²ã³ååç©ãæ¥è§ŠããŠãªããªã¬ãã€ã³éå觊
åªæåãç¥ãããŠããïŒç¹éæ57â92009å·å ¬å ±ïŒ
ããå®è³ªçã«ã¯ããã°ãã·ãŠã ååç©ã¯ããã²ã³
åãã°ãã·ãŠã ã§ããããã€ã±ã€çŽ ååç©ãšãã¿
ã³ããã²ã³ååç©ã¯åæã«çšããŠæ¥è§Šããããã®
ã§ãã€ãŠããã®æ§èœãæºè¶³ãããã®ã§ã¯ãªãã çºæã®é瀺 çºæã®ç®ç æ¬çºæã¯ãåºçºåæãšããŠããã²ã³ãå«ãŸãªã
ãã°ãã·ãŠã ååç©ãçšããŠé«ç«äœèŠåæ§åã³é«
掻æ§ã瀺ãã嵩å¯åºŠã®é«ããªã¬ãã€ã³éåäœã補
é ãåŸã觊åªæåãæäŸããããšãç®çãšããã
ã®ã§ãããæ¬çºæè ãã¯éæç 究ãè¡ã€ãçµæã
ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ããšæ°ŽçŽ âçªçŽ çµåã
æããçªçŽ ååç©ãšã®åå¿ç©ãšé»åäŸäžæ§ååç©
ãšã®æ¥è§Šç©ããããã²ã³åãã¿ã³ååç©ãšïŒå以
äžæ¥è§Šãããããããã®ããã²ã³åãã¿ã³ååç©
ã®åæ¥è§Šã®éã«åšæè¡šã®ïœïŒïœïŒïœæã®å
çŽ ã®ããã²ã³åç©ãšæ¥è§ŠãããŠåŸãåºåç©ããæ¬
çºæã®ç®çãéæãåŸãããšãèŠåºããŠæ¬çºæã«
å°ã€ãã çºæã®èŠæš ããªãã¡ãæ¬çºæã¯ãã°ãã·ãŠã ãžã¢ã«ã³ãã·
ããšäžè¬åŒHmRnSiXrãäœããã¯çåæ°ŽçŽ åºã
R1Oâè¥ããã¯R2R3Nâãã¯ããã²ã³ååã
瀺ããïŒïœïŒïŒïŒïœïŒïŒïœïŒïœïŒïœïŒïŒ
ã§ãããR1ïŒR2åã³R3ã¯ããããçåæ°ŽçŽ åºã
瀺ãããã®çªçŽ ååç©ãšã®åå¿ç©ãé»åäŸäžæ§å
åç©ãšæ¥è§ŠãããŠåŸãããæ¥è§Šç©ããäžè¬åŒ
TiXnïŒORïŒ4-oãäœããã¯ããã²ã³ååãã¯
çåæ°ŽçŽ åºã瀺ããïŒïŒïœïŒã§ããããã®ãã
ã²ã³åãã¿ã³ååç©ãšïŒå以äžæ¥è§Šãããããšã
ããªãããã€åããã²ã³åãã¿ã³ååç©ã®æ¥è§Šã®
éã«ãå çŽ ã®åšæè¡šïœïŒïœåã³ïœæã®å çŽ
ã®çŸ€ããéžã°ããå çŽ ã®ããã²ã³åç©ãšæ¥è§ŠããŠ
ãªãαâãªã¬ãã€ã³éåçšè§ŠåªæåãèŠæšãšã
ãã 觊åªæå調補ã®åæ æ¬çºæã®è§Šåªæåã調補ããéã«çšããååæ
ã«ã€ããŠèª¬æããã (A) ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ã æ¬çºæã§çšãããããã°ãã·ãŠã ãžã¢ã«ã³ãã·
ãã¯ãäžè¬åŒMgïŒORïŒïŒORâ²ïŒã§è¡šãããããã®
ã§ãããåŒã«ãããŠïŒ²åã³Râ²ã¯ççŽ æ°ïŒã20åã
æãŸããã¯ïŒã10åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·
ã¯ãã¢ã«ãã«ãã¢ãªãŒã«ãã¢ã«ã¢ã«ãã«åºã§ã
ããåããšRâ²ã¯åãã§ãç°ã€ãŠãããã ãããååç©ãäŸç€ºãããšãMgïŒOCH3ïŒ2ïŒ
MgïŒOC2H5ïŒ2ïŒMgïŒOCH3ïŒïŒOC2H5ïŒïŒMgïŒOiâ
C3H7ïŒ2ïŒMgïŒOC3H7ïŒ2ïŒMgïŒOC4H9ïŒ2ïŒMgïŒOi
âC4H9ïŒ2ïŒMgïŒOC4H9ïŒïŒOiâC4H9ïŒïŒMg
ïŒOC4H9ïŒïŒOsecâC4H9ïŒïŒMgïŒOC6H13ïŒ2ïŒMg
ïŒOC3H17ïŒ2ïŒMgïŒOC6H11ïŒ2ïŒMgïŒOC6H5ïŒ2ïŒMg
ïŒOC6H4CH3ïŒ2ïŒMgïŒOCH2C6H5ïŒ2çãæããã
ãšãã§ããã ããããã°ãã·ãŠã ãžã¢ã«ã³ãã·ãã¯äœ¿çšãã
éã«ã也ç¥ããã®ãæãŸãããç¹ã«æžå§äžã§ã®å
ç±ä¹Ÿç¥ãæãŸãããããã«ãããããã°ãã·ãŠã
ãžã¢ã«ã³ãã·ãã¯ãåžè²©åãçšããŠããããå ¬ç¥
ã®æ¹æ³ã§åæãããã®ãçšããŠãããã ãã®ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ãã¯ãç¡æ©æã
ã¯ææ©ã®äžæŽ»æ§ãªåºäœç©è³ªãšäºãæ¥è§ŠãããŠäœ¿çš
ããããšãå¯èœã§ããã ç¡æ©ã®åºäœç©è³ªãšããŠã¯ãç¡«é žå¡©ãæ°Žé žåç©ã
çé žå¡©ããªã³é žå¡©ãã±ã€é žå¡©ã®ãããªéå±ååç©
ãé©ããŠãããäŸãã°ãMgïŒOHïŒ2ïŒBaCO3ïŒ
Ca3ïŒPO4ïŒ2çãæããããã ææ©ã®åºäœç©è³ªãšããŠã¯ãããŠã¬ã³ãã¢ã³ãã©
ã»ã³ãããã¿ã¬ã³ããžããšãã«ã®ãããªè³éŠæç
åæ°ŽçŽ çã®äœååéååç©ãæãããããåãã
ãªãšãã¬ã³ãããªãããã¬ã³ãããªããã«ãã«ãš
ã³ãããªã¹ãã¬ã³ãããªã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãã
ããªã¢ãããããªãšã¹ãã«ãããªå¡©åããã«çã®
é«ååéååç©ãçšããããšãã§ããã (B) çªçŽ ååç© æ¬çºæã§çšããããçªçŽ ååç©ã¯ãäžè¬åŒHn
RoSiXrã§è¡šãããããåŒã«ãããŠãã¯çå
æ°ŽçŽ åºãRâ²OâïŒRâ²ã¯çåæ°ŽçŽ åºïŒãR2R3Nâ
ïŒR2ïŒR3ã¯çåæ°ŽçŽ åºïŒã§ãããã¯ããã²ã³å
åãïŒïœïŒïŒïŒïœïŒïŒïœïŒïœïŒïœïŒïŒã
ãããã瀺ããåãïœãïŒãè¶ ããå Žåã¯åã
ã§ãç°ã€ãŠãããã ïŒR1ïŒR2ïŒR3ã§ç€ºãããçåæ°ŽçŽ åºãšããŠ
ã¯ãççŽ æ°ïŒã16åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·
ã¯ãã¢ã«ãã«ãã¢ãªãŒã«ãã¢ã«ã¢ã«ãã«çãæã
ãããšãã§ãããã¢ã«ãã«ãšããŠã¯ãã¡ãã«ããš
ãã«ããããã«ãïœãŒããã«ãã€ãœããã«ãïœãŒ
ããã·ã«ãïœãŒãªã¯ãã«ãïŒãŒãšãã«ããã·ã«ã
ïœãŒãã·ã«çããã¢ã«ã±ãã«ãšããŠã¯ãããã«ã
ã¢ãªã«ãã€ãœããããã«ãããããã«ããããã«
çããã·ã¯ãã¢ã«ãã«ãšããŠã¯ãã·ã¯ããã³ã
ã«ãã·ã¯ãããã·ã«çããã¢ãªãŒã«ãšããŠã¯ãã
ãšãã«ãããªã«ããã·ãªã«çããã¢ã«ã¢ã«ãã«ãš
ããŠã¯ããã³ãžã«ãããšããã«ãããšãã«ããã
ã«çãæããããã ãããã®äžã§ãã¡ãã«ããšãã«ããããã«ãã€
ãœãããã«ãïœãŒããã«ãã€ãœããã«ãïœãŒãã
ã«çã®äœçŽã¢ã«ãã«åã³ããšãã«ãããªã«çã®ã¢
ãªãŒã«ãæãŸããã ã¯å¡©çŽ ãèçŽ ããšãŠçŽ çã®ããã²ã³ååã§ã
ããæãŸããã¯å¡©çŽ ååã§ããã çªçŽ ååç©ãäŸç€ºãããšãHSiCl3ïŒH2SiCl2ïŒ
H3SiClïŒHCH3SiCl2ïŒHC2H5SiCl2ïŒïŒšïŒïœâ
C4H9ïŒSiCl2ïŒHC6H5SiCl2ïŒïŒšïŒCH3ïŒ2SiClïŒïŒš
ïŒïœâC3H7ïŒ2SiClïŒH2C2H5SiClïŒH2ïŒïœâC4H9ïŒ
SiClïŒH2ïŒC6H4CH3ïŒSiClïŒHSiïŒCH3ïŒ3ïŒ
HSiCH3ïŒOCH3ïŒ2ïŒHSiCH3ïŒOC2H5ïŒ2ïŒHSi
ïŒOCH3ïŒ3ïŒïŒC2H5ïŒ2SiH2ïŒHSiïŒCH3ïŒ2ïŒOC2H5ïŒïŒ
HSiïŒCH3ïŒ2ãïŒCH3ïŒ2ãïŒHSiCH3ïŒC2H5ïŒ2ïŒ
HSiC2H5ïŒOC2H5ïŒ2ïŒHSiCH3ãïŒCH3ïŒ2ã2ïŒ
C6H5SiH3ïŒHSiïŒC2H5ïŒ3ïŒHSiïŒOC2H5ïŒ3ïŒHSi
ïŒCH3ïŒ2ãïŒC2H5ïŒ2ãïŒHSiãïŒCH3ïŒ2ã3ïŒ
C6H5CH3SiH2ïŒC6H5ïŒCH3ïŒ2SiHïŒïŒïœâ
C3H7ïŒ3SiHïŒHSiClïŒC6H5ïŒ2ïŒH2SiïŒC6H5ïŒ2ïŒ
HSiïŒC6H5ïŒ2CH3ïŒïŒïœâC5H11OïŒ3SiHïŒHSi
ïŒC6H5ïŒ3ïŒïŒïœâC5H11ïŒ3SiHçãæããããšãã§
ããã ãããã®äžã§ããåèšäžè¬åŒäžïŒ²ãçåæ°ŽçŽ ã
ïœãïŒãïŒã®æ°ãïœãïŒãïŒã®æ°ã®ããã²ã³åçª
çŽ ååç©ãããªãã¡HSiCl3ïŒH2SiCl2ïŒH3SiClïŒ
HCH3SiCl2ïŒHC2H5SiCl2ïŒïŒšïŒïœâC4H9ïŒ
SiCl2ïŒHC6H5SiCl2ïŒïŒšïŒCH3ïŒ2SiClïŒïŒšïŒïœâ
C3H7ïŒ2SiClïŒH2C2H5SiClïŒH2ïŒïœâC4H9ïŒ
SiClïŒH2ïŒC6H4CH3ïŒSiClïŒHSiClïŒC6H5ïŒ2çã
æãŸãããç¹ã«HSiCl3ïŒHCH3SiCl2ïŒïŒš
ïŒCH3ïŒ2SiClçãæãŸãããããã«äžè¬åŒäžïœïŒ
ïŒã®å ŽåãäŸãã°HSiïŒC2H5ïŒ3ïŒHSiCH3
ïŒOC2H5ïŒ2çã奜ãŸããçšããããã (C) é»åäŸäžæ§ååç© é»åäŸäžæ§ååç©ãšããŠã¯ãã«ã«ãã³é žé¡ãã«
ã«ãã³é žç¡æ°Žç©ãã«ã«ãã³é žãšã¹ãã«é¡ãã«ã«ã
ã³é žããã²ã³åç©ãã¢ã«ã³ãŒã«é¡ããšãŒãã«é¡ã
ã±ãã³é¡ãã¢ãã³é¡ãã¢ããé¡ããããªã«é¡ãã¢
ã«ãããé¡ãã¢ã«ã³ã¬ãŒãé¡ãææ©åºãšççŽ ãã
ãã¯é žçŽ ãä»ããŠçµåããçããçŽ ããã³ã¢ã³ã
ã¢ã³ååç©ããã¹ãã¢ããé¡ãããªãšãŒãã«é¡ã
ããªãšã¹ãã«é¡ãçé žãšã¹ãã«é¡ãæãããã
ãããããã®ãã¡å¥œãŸããã䜿çšããããã®ãšã
ãŠã¯ã«ã«ãã³é žãšã¹ãã«é¡ãã«ã«ãã³é žç¡æ°Žç©ã
ã«ã«ãã³é žããã²ã³åç©ãã¢ã«ã³ãŒã«é¡ããšãŒã
ã«é¡ã§ããã ã«ã«ãã³é žãšã¹ãã«ã®å ·äœäŸãšããŠã¯ãã®é žã
ãã«ãé ¢é žãšãã«ãé ¢é žããã«ãã¢ã¯ãªã«é žãšã
ã«ãé ªé žãšãã«ãã€ãœé ªé žã€ãœããã«ãã¡ã¿ã¯ãª
ã«é žã¡ãã«ããã¬ã€ã³é žãžãšãã«ãé ç³é žãžãšã
ã«ãã·ã¯ããããµã³ã«ã«ãã³é žãšãã«ãå®æ¯éŠé ž
ãšãã«ãâã¡ããã·å®æ¯éŠé žãšãã«ãâã¡ã
ã«å®æ¯éŠé žã¡ãã«ãâ第äžçŽããã«å®æ¯éŠé žãš
ãã«ããã¿ã«é žãžããã«ããã¿ã«é žãžã¢ãªã«ãα
âããããšé žãšãã«çãæãããããããããã«
éå®ããããã®ã§ã¯ãªãããããã®äžã§ãè³éŠæ
ã«ã«ãã³é žã®ã¢ã«ãã«ãšã¹ãã«ãç¹ã«å®æ¯éŠé žãŸ
ãã¯ïŒ°âã¡ãã«å®æ¯éŠé žãïœâã¡ããã·å®æ¯éŠé ž
ãªã©ã®æ žçœ®æå®æ¯éŠé žã®ççŽ æ°ïŒãïŒåã®ã¢ã«ã
ã«ãšã¹ãã«ã奜ãŸããçšãããããã«ã«ãã³é žç¡
æ°Žç©ã®å ·äœçãªäŸãšããŠã¯ãç¡æ°Žé ¢é žãç¡æ°Žãã
ããªã³é žãç¡æ°Žé ªé žãç¡æ°Žåèé žãç¡æ°Žã«ããã³
é žçã®èèªæã¢ãã«ã«ãã³é žç¡æ°Žç©ãç¡æ°Žã¢ã¯ãª
ã«é žãç¡æ°Žã¯ããã³é žãç¡æ°Žã¡ã¿ã¯ãªã«é žçã®è
èªæãªã¬ãã€ã³ã¢ãã«ã«ãã³é žç¡æ°Žç©ãã·ã¯ãã
ããµã³ã¢ãã«ã«ãã³é žç¡æ°Žç©ãã·ã¯ãããã»ã³ã¢
ãã«ã«ãã³é žç¡æ°Žç©é¡ãã·ã¹âïŒïŒïŒâã·ã¯ãã
ããµã³ç¡æ°Žãžã«ã«ãã³é žé¡ãã·ã¹âïŒâã·ã¯ãã
ãã»ã³âïŒïŒïŒâç¡æ°Žãžã«ã«ãã³é žçã®èç°åŒã«
ã«ãã³é žç¡æ°Žç©ãç¡æ°Žå®æ¯éŠé žãç¡æ°ŽïŒ°âãã«ã€
ã«é žãç¡æ°ŽïŒ°âãšãã«å®æ¯éŠé žãç¡æ°ŽïŒ°âã¡ãã
ã·å®æ¯éŠé žçã®è³éŠæã¢ãã«ã«ãã³é žç¡æ°Žç©åã³
ç¡æ°Žãã¿ã«é žçã®è³éŠæãžã«ã«ãã³é žç¡æ°Žç©ãæ
ããããšãã§ãããã«ã«ãã³é žããã²ã³åç©ã®å ·
äœäŸãšããŠã¯ãå¡©åã¢ã»ãã«ãå¡©åããããªã
ã«ãå¡©åïœâãããªã«çã®é žå¡©åç©ãèåã¢ã»ã
ã«ãèåïœâãããªã«çã®é žèåç©ããšãŠåã¢ã»
ãã«ããšãŠåïœâãããªã«çã®é žãšãŠåç©çã®è
èªæã¢ãã«ã«ãã³é žããã²ã³åç©åã³å¡©åã¢ã¯ãª
ã«ãå¡©åã¯ãããã«ãå¡©åã¡ã¿ã¯ãªã«çã®é žå¡©å
ç©ãèåã¢ã¯ãªã«ãèåã¡ã¿ã¯ãªã«çã®é žèå
ç©ããšãŠåã¢ã¯ãªã«ããšãŠåã¡ã¿ã¯ãªã«çã®é žãš
ãŠåç©çã®èèªæãªã¬ãã€ã³ã¢ãã«ã«ãã³é žãã
ã²ã³åç©ãã·ã¯ããããµã³ã«ã«ãã³é žå¡©åç©ãã·
ã¹âïŒâã¡ãã«ã·ã¯ããããµã³ã«ã«ãã³é žå¡©å
ç©ãïŒâã·ã¯ãããã»ã³ã«ã«ãã³é žå¡©åç©ãã·ã¯
ããããµã³ã«ã«ãã³é žèåç©ãã·ã¹âïŒâã¡ãã«
ããã»ã³ã«ã«ãã³é žèåç©çã®èç°åŒã«ã«ãã³é ž
ã®é žããã²ã³åç©ãå¡©åãã³ãŸã€ã«ãâãã«ã€
ã«é žå¡©åç©ãâãšãã«å®æ¯éŠé žå¡©åç©ãâã¡
ããã·å®æ¯éŠé žå¡©åç©çã®é žå¡©åç©ãèåãã³ãŸ
ã€ã«çã®é žèåç©ããšãŠåãã³ãŸã€ã«çã®é žãšãŠ
åç©çã®è³éŠæã¢ãã«ã«ãã³é žããã²ã³åç©åã³
ãã¿ã«é žãžã¯ããªãçã®è³éŠæãžã«ã«ãã³é žãã
ã²ã³åç©ãæããããšãã§ãããã¢ã«ã³âã«é¡
ã¯ãäžè¬åŒROHã§è¡šãããããåŒã«ãããŠïŒ²ã¯
ççŽ æ°ïŒã12åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·ã¯ã
ã¢ã«ãã«ãã¢ãªâã«ãã¢ã«ã¢ã«ãã«ã§ããããã®
å ·äœäŸãšããŠã¯ãã¡ã¿ãâã«ããšã¿ãâã«ããã
ããâã«ãã€ãœããããâã«ããã¿ãâã«ãã€ãœ
ãã¿ãâã«ããã³ã¿ãâã«ããããµãâã«ããªã¯
ã¿ãâã«ãïŒâãšãã«ãããµãâã«ãã·ã¯ããã
ãµãâã«ããã³ãžã«ã¢ã«ã³âã«ãã¢ãªã«ã¢ã«ã³â
ã«ãããšãâã«ãã¯ã¬ãŸâã«ããã·ã¬ãâã«ããš
ãã«ããšãâã«ãã€ãœãããã«ããšãâã«ãâ
ã¿âã·ã€ãªâããã«ããšãâã«ãïœâãªã¯ãã«ã
ãšãâã«ããããâã«çã§ããããšâãã«é¡ã¯ã
äžè¬åŒRORâ²ã§è¡šãããããåŒã«ãããŠïŒ²ïŒRâ²ã¯
ççŽ æ°ïŒã12åã®ã¢ã«ãã«ãã¢ã«ã±ãã«ãã·ã¯ã
ã¢ã«ãã«ãã¢ãªâã«ãã¢ã«ã¢ã«ãã«ã§ããããš
Râ²ã¯åãã§ãç°ã€ãŠãããããã®å ·äœäŸãšããŠ
ã¯ããžãšãã«ãšâãã«ããžã€ãœãããã«ãšâã
ã«ããžããã«ãšâãã«ããžã€ãœããã«ãšâãã«ã
ãžã€ãœã¢ãã«ãšâãã«ããžâïŒâãšãã«ããã·ã«
ãšâãã«ããžã¢ãªã«ãšâãã«ããšãã«ã¢ãªã«ãšâ
ãã«ãããã«ã¢ãªã«ãšâãã«ããžããšãã«ãšâã
ã«ãã¢ããœâã«ããšãã«ããšãã«ãšâãã«çã§ã
ãã (D) ããã²ã³åãã¿ã³ååç© æ¬çºæã§çšããããããã²ã³åãã¿ã³ååç©
ã¯ãäžè¬åŒTiXnïŒORïŒ4-oã§è¡šããããããã®åŒ
ã«ãããŠãã¯å¡©çŽ ãèçŽ çã®ããã²ã³ååã瀺
ããã¯å¥œãŸããã¯ççŽ æ°ïŒãïŒåã®ãã¢ã«ãã«
åºãã¢ãªãŒã«åºçã®çåæ°ŽçŽ åºã瀺ããåãïœã¯
ïŒïŒïœïŒã®ç¯å²ã®ä»»æã®æ°ã§ãããããããã
ã²ã³åãã¿ã³ååç©ãšããŠã¯ãåå¡©åãã¿ã³ãã
ãªã¯ãã«ãšããã·ãã¿ã³ããžã¯ãã«ãžãããã·ã
ã¿ã³ããžã¯ãã«ãžããšããã·ãã¿ã³çã®å䟡ã®ã
ã¿ã³ããã²ã³ååç©ãæããããç¹ã«åå¡©åãã¿
ã³ãæãŸããã (E) ïœïŒïœïŒïœæå çŽ ã®ããã²ã³åç© å çŽ ã®åšæè¡šïœãïœåã³ïœæã®å çŽ ãã
éžã°ããå çŽ ã®ããã²ã³åç©ïŒä»¥äžãéå±ãã©ã€
ããšãããïŒãšããŠã¯ãïŒAlïŒGaïŒInïŒTlïŒ
SiïŒGeïŒSnïŒPbïŒAsïŒSbïŒBiã®å¡©åç©ãåŒå
ç©ãèåç©ããšãŠåç©ãæããããç¹ã«BCl3ïŒ
BBr3ïŒBI3ïŒAlCl3ïŒAlBr3ïŒAlI3ïŒGaCl3ïŒ
GaBr3ïŒInCl3ïŒTlCl3ïŒSiCl4ïŒSnCl4ïŒSbCl5ïŒ
SbF5çã奜é©ã§ããã 觊åªæåã®èª¿è£œæ³ æ¬çºæã®è§Šåªæåã¯ããã°ãã·ãŠã ãžã¢ã«ã³
ãã·ãïŒïŒ¡æåïŒãšçªçŽ ååç©ïŒïŒ¢æåïŒãšã®å
å¿ç©ããé»åäŸäžæ§ååç©ïŒïŒ£æåïŒãšæ¥è§Šã
ããããã²ã³åãã¿ã³ååç©ïŒïŒ€æåïŒãšïŒå
以äžæ¥è§Šããããã€åããã²ã³åãã¿ã³ååç©
ã«ããæ¥è§Šã®éã«éå±ãã©ã€ãïŒïŒ¥æåïŒãšæ¥è§Š
ãããããšã«ãã€ãŠåŸãããã次ã«ãã®èª¿æŽæ³ã«
ã€ããŠèª¬æããã ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ããšçªçŽ ååç©ãš
ã®åå¿ ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ãïŒïŒ¡æåïŒãšçªçŽ
ååç©ïŒïŒ¢æåïŒãšã®åå¿ã¯ãäž¡è ãæ¥è§Šããã
ããšã«ãã€ãŠãªãããããæãŸããã¯ãçåæ°ŽçŽ
ã®ååšäžäž¡è ãæ··åæ¹æããæ¹æ³ã§ããã çåæ°ŽçŽ ãšããŠã¯ããããµã³ãããã¿ã³ããªã¯
ã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³ãã
ã·ã¬ã³çã®ççŽ æ°ïŒã12åã®é£œåèèªæã飜åè
ç°åŒåã³è³éŠæçåæ°ŽçŽ ãæãŸããã æåãšïŒ¢æåãšã®æ¥è§Šå²åã¯ãæåïŒã¢ã«
åœããæå0.5ã10ã¢ã«ãæãŸããã¯ïŒãïŒã¢
ã«ã§ãããäž¡è ã®æ¥è§Šã¯ãéåžžïŒã200âã§0.5ã
100æéè¡ãªããããæååã³ïŒ¢æåã¯äžçš®ã«
éããåæã«äºçš®ä»¥äžçšããŠãããã çåæ°ŽçŽ ã®äœ¿çšéã¯ãä»»æã§ããããæå
1gã«å¯ŸããŠ100ml以äžãæãŸããã æåã«ããã²ã³åçªçŽ ååç©ãçšããå Žåã
æåãšã®æ¥è§Šã«ãããã¬ã¹ãçºçããåå¿ãè¡
ãªãããŠããããšãèªããããããçºçããã¬ã¹
ã®çµæããããã®åå¿ã¯ãã°ãã·ãŠã ãžã¢ã«ã³ã
ã·ããåã«ããã²ã³åããã ããšã¯èãã«ããã
åå¿ç©ã®åæçµæãããçªçŽ ååãäœãããã®åœ¢
ã§çµåããååç©ãçæãããã®ãšèããããã
åå¿ç©äžã«å«ãŸããçªçŽ ååã®éã¯ã65âã®äžæŽ»
æ§æº¶åªãç¹ã«ïœâãããµã³åã¯ïœâããã¿ã³ãã«
溶解ããªãéãšããŠïŒééïŒ ä»¥äžã§ããã æåãšïŒ¢æåã®æ¥è§Šç©ã¯ãåå¿ç³»ããåé¢ã
ãã次ã®æ¥è§Šã«äŸãããããå¿ èŠã«å¿ããŠæ¬¡ã®æ¥
觊ã®åã«ãæåãšïŒ¢æåã®æ¥è§Šã®éã«çšããã
ãçåæ°ŽçŽ ã®ãããªäžæŽ»æ§ãªçåæ°ŽçŽ ã§æŽæµãã
ããšãã§ãããæŽæµã¯å ç±äžã§è¡ã€ãŠãããã é»åäŸäžæ§ååç©ãšã®æ¥è§Š äžèšã§åŸãããåå¿ç©ãšé»åäŸäžæ§ååç©
ïŒïŒ£æåïŒãšã®æ¥è§Šã¯ãäž¡è ãäžæŽ»æ§ã¯çåæ°ŽçŽ
ã®ååšäžåã¯äžååšäžã«ãæ··åæ¹æããæ¹æ³ãæ©
械çã«å ±ç²ç ããæ¹æ³çã«ããéæããããäžæŽ»
æ§ãªçåæ°ŽçŽ ãšããŠã¯ããããµã³ãããã¿ã³ããª
ã¯ã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³ã
ãã·ã¬ã³çãæããããã æ©æ¢°çå ±ç²ç ã«ããæ¥è§Šã®å Žåã®æ¥è§Šæž©åºŠã¯ã
ïŒã100âãæ¥è§Šæéã¯0.1ã100æéã§ãããåã
åã«æ¹æããæ¥è§Šæ¹æ³ã®å Žåã®æ¥è§Šæž©åºŠã¯ãïŒã
150âãæ¥è§Šæéã¯0.5ã10æéã§ããã é»åäŸäžæ§ååç©ã¯ããã°ãã·ãŠã ãžã¢ã«ã³ã
ã·ããšçªçŽ ååç©ãšã®æ¥è§Šç©äžã®ãã°ãã·ãŠã ïŒ
ã°ã©ã åååœã0.01ã10ã°ã©ã ã¢ã«ãç¹ã«0.05ã
ïŒã°ã©ã ã¢ã«ã®ç¯å²ã§çšããã®ãæãŸããã ããã²ã³åãã¿ã³ååç©ãšã®æ¥è§Š äžèšã§åŸãããæ¥è§Šç©ã¯ã次ãã§ããã²ã³å
ãã¿ã³ååç©ïŒïŒ€æåïŒãšïŒå以äžæ¥è§Šãããã
äž¡è ã¯ãã®ãŸãŸæ¥è§ŠãããŠãããããçåæ°ŽçŽ ã®
ååšäžãäž¡è ãæ··åæ¹æããæ¹æ³ãæãŸãããç
åæ°ŽçŽ ãšããŠã¯ããããµã³ãããã¿ã³ããªã¯ã¿
ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³ããã·
ã¬ã³çãæããããã 該æ¥è§Šç©ãšïŒ€æåãšã®æ¥è§Šå²åã¯è©²æ¥è§Šç©äžã®
ãã°ãã·ãŠã ïŒã°ã©ã åååœããæå0.1ã°ã©
ã ã¢ã«ä»¥äžãæãŸããã¯ïŒã50ã°ã©ã ã¢ã«ã§ã
ãã äž¡è ã®æ¥è§Šæ¡ä»¶ã¯ãçåæ°ŽçŽ ã®ååšäžã§è¡ãå Ž
åãïŒã200âã§0.5ã20æéãæãŸããã¯60ã
150âã§ïŒãïŒæéã§ããã çåæ°ŽçŽ ã®äœ¿çšéã¯ã該æ¥è§Šç©ã液äœç©è³ªïŒç
åæ°ŽçŽ åã³æ¶²ç¶ã®ïœæåïŒ1låœãã10ã300gãšãª
ãããã«çšããã®ãæãŸããã ïŒåç®ä»¥åŸã®ïŒ€æåãšã®æ¥è§Šã¯ãäžèšã§è¿°ã¹ã
ããã²ã³åçåæ°ŽçŽ ã«ããæ¥è§Šã§çšãããããã
ã²ã³åçåæ°ŽçŽ ãšåé¢ããåŸãäžèšãšåæ§ã«ããŠ
è¡ãªãããã éå±ãã©ã€ããšã®æ¥è§Š ïŒå以äžã®ïŒ€æåãšã®åæ¥è§Šã®éã«è¡ãªããã
éå±ãã©ã€ãïŒïŒ¥æåïŒãšã®æ¥è§Šã¯ãäžèšã§çš
ããããæåïŒåã³çåæ°ŽçŽ ïŒããåé¢ããåº
åç©ãæåãšæ¥è§Šãããããšã«ãã€ãŠãªãã
ãã 該åºåç©ãšïŒ¥æåã®æ¥è§Šã¯ãäž¡è ããã®ãŸãŸæ¥
觊ãããããšãå¯èœã§ãããåçåæ°ŽçŽ ã®ååšäž
è¡ã€ãŠãããããã®æ¥è§Šæ¹æ³ã¯ãæ©æ¢°çã«å ±ç²ç
ããæ¹æ³ãæ··åæ¹æããæ¹æ³ãæ¡çšã§ããã 該åºåç©ãšïŒ¥æåã®æ¥è§Šå²åã¯ã該åºåç©äžã®
ãã°ãã·ãŠã 1gåååœããæåã0.1ã¢ã«ä»¥äžã
æãŸããã¯0.5ã150ã¢ã«ã§ãããäž¡è ã®æ¥è§Šæ¡ä»¶
ã¯ãïŒã200âã§0.1ã15æéãæãŸããã¯25ã90
âã§0.5ãïŒæéã§ããã äžèšã®ããã«ããŠåŸãããåºäœç¶ç©è³ªã¯ãå¿ èŠ
ã«å¿ããŠãããµã³ãããã¿ã³ããªã¯ã¿ã³ãã·ã¯ã
ãããµã³ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®äž
掻æ§ãªçåæ°ŽçŽ ã§æŽæµãã也ç¥ããããšã«ãã€ãŠ
æ¬çºæã®è§Šåªæåãšããã æ¬çºæã®è§Šåªæåã¯ããããïŒBETïŒæ³ã§æ¶²
äœçªçŽ ã®åžç枩床ã«ãããŠæž¬å®ããæ¯è¡šé¢ç©ã50
ã650m2ïŒïœã现å容ç©ã0.05ã0.40ccïŒïœã§ã
ãããã®ç²åºŠååžãçããŠå€§ãããæã€ãŠããã
åããã®çµæã¯ãã°ãã·ãŠã ååã10ã25éé
ïŒ ããã¿ã³ååãïŒã10ééïŒ ãããã²ã³ååã
40ã60ééïŒ ãçªçŽ ååã1.5ã8.5ééïŒ ã§ã
ãããã®ä»ææ©ååç©çãå«ããåã觊åªæåã
調補ããéã«çšããéå±ãã©ã€ããé»åäŸäžæ§å
åç©åã³ïŒåã¯ãããã®å€æç©è³ªãå°éå«ãŸãã
å Žåãããã ãªã¬ãã€ã³ã®éåè§Šåª æ¬çºæã®è§Šåªæåã¯ãææ©ã¢ã«ãããŠã ååç©
ãšçµåããŠÎ±âãªã¬ãã€ã³ã®åç¬éååã¯ä»ã®ãª
ã¬ãã€ã³ãšã®å ±éåçšã®è§Šåªãšããã ææ©ã¢ã«ãããŠã ååç© Î±âãªã¬ãã€ã³ãéåããéã«è§Šåªæåãšçµå
ããææ©ã¢ã«ãããŠã ååç©ã¯ãäžè¬åŒRo
AlX3-oïŒäœããã¯ã¢ã«ãã«åºåã¯ã¢ãªãŒã«åºã
ã¯ããã²ã³ååãã¢ã«ã³ãã·åºåã¯æ°ŽçŽ ååã
瀺ããïœã¯ïŒïœïŒã®ç¯å²ã®ä»»æã®æ°ã§ãããïŒ
ã§ç€ºããããã®ã§ãããäŸãã°ããªã¢ã«ãã«ã¢ã«
ãããŠã ããžã¢ã«ãã«ã¢ã«ãããŠã ã¢ããã©ã€
ããã¢ãã¢ã«ãã«ã¢ã«ãããŠã ãžãã©ã€ããã¢ã«
ãã«ã¢ã«ãããŠã ã»ã¹ããã©ã€ãããžã¢ã«ãã«ã¢
ã«ãããŠã ã¢ãã¢ã«ã³ãã·ãåã³ãžã¢ã«ãã«ã¢ã«
ãããŠã ã¢ããã€ãã©ã€ããªã©ã®ççŽ æ°ïŒãªãã
18åã奜ãŸããã¯ççŽ æ°ïŒãªããïŒåã®ã¢ã«ãã«
ã¢ã«ãããŠã ååç©åã¯ãã®æ··åç©ãããã¯é¯å
åç©ãç¹ã«å¥œãŸãããå ·äœçã«ã¯ãããªã¡ãã«ã¢
ã«ãããŠã ãããªãšãã«ã¢ã«ãããŠã ãããªãã
ãã«ã¢ã«ãããŠã ãããªã€ãœããã«ã¢ã«ãããŠ
ã ãããªããã·ã«ã¢ã«ãããŠã ãªã©ã®ããªã¢ã«ã
ã«ã¢ã«ãããŠã ããžã¡ãã«ã¢ã«ãããŠã ã¯ããª
ãããžãšãã«ã¢ã«ãããŠã ã¯ããªãããžãšãã«ã¢
ã«ãããŠã ããããããžãšãã«ã¢ã«ãããŠã ã¢ã€
ãªãã€ãããžã€ãœããã«ã¢ã«ãããŠã ã¯ããªããª
ã©ã®ãžã¢ã«ãã«ã¢ã«ãããŠã ã¢ããã©ã€ããã¡ã
ã«ã¢ã«ãããŠã ãžã¯ããªãããšãã«ã¢ã«ãããŠã
ãžã¯ããªããã¡ãã«ã¢ã«ãããŠã ãžããããããš
ãã«ã¢ã«ãããŠã ãžããããããšãã«ã¢ã«ãããŠ
ã ãžã¢ã€ãªãã€ããã€ãœããã«ã¢ã«ãããŠã ãžã¯
ããªããªã©ã®ã¢ãã¢ã«ãã«ã¢ã«ãããŠã ãžãã©ã€
ãããšãã«ã¢ã«ãããŠã ã»ã¹ãã¯ããªããªã©ã®ã¢
ã«ãã«ã¢ã«ãããŠã ã»ã¹ããã©ã€ãããžã¡ãã«ã¢
ã«ãããŠã ã¡ããã·ãããžãšãã«ã¢ã«ãããŠã ãš
ããã·ãããžãšãã«ã¢ã«ãããŠã ããšããã·ãã
ãžãããã«ã¢ã«ãããŠã ãšããã·ãããžã€ãœãã
ã«ã¢ã«ãããŠã ãšããã·ãããžã€ãœããã«ã¢ã«ã
ããŠã ããšããã·ããªã©ã®ãžã¢ã«ãã«ã¢ã«ãããŠ
ã ã¢ãã¢ã«ã³ãã·ãããžã¡ãã«ã¢ã«ãããŠã ãã€
ãã©ã€ãããžãšãã«ã¢ã«ãããŠã ãã€ãã©ã€ãã
ãžãããã«ã¢ã«ãããŠã ãã€ãã©ã€ãããžã€ãœã
ãã«ã¢ã«ãããŠã ãã€ãã©ã€ããªã©ã®ãžã¢ã«ãã«
ã¢ã«ãããŠã ãã€ãã©ã€ããæããããã ãããã®äžã§ããããªã¢ã«ãã«ã¢ã«ãããŠã
ããç¹ã«ããªãšãã«ã¢ã«ãããŠã ãããªã€ãœãã
ã«ã¢ã«ãããŠã ãæãŸãããåããããããªã¢ã«
ãã«ã¢ã«ãããŠã ã¯ããã®ä»ã®ææ©ã¢ã«ãããŠã
ååç©ãäŸãã°ãå·¥æ¥çã«å ¥æãæããžãšãã«ã¢
ã«ãããŠã ã¯ããªãããšãã«ã¢ã«ãããŠã ãžã¯ã
ãªãããšãã«ã¢ã«ãããŠã ã»ã¹ãã¯ããªãããžãš
ãã«ã¢ã«ãããŠã ãšããã·ãããžãšãã«ã¢ã«ãã
ãŠã ãã€ãã©ã€ãåã¯ãããã®æ··åç©è¥ããã¯é¯
ååç©çãšäœµçšããããšãã§ããã ããã«ãææ©ã¢ã«ãããŠã ååç©ã¯ãåç¬ã§çš
ããŠãããããé»åäŸäžæ§ååç©ãšçµåããŠçšã
ãŠããããé»åäŸäžæ§ååç©ãšããŠã¯ãåèšè§Šåª
æå調補æã«çšããããé»åäŸäžæ§ååç©ãªã
ã°ãã©ã®ååç©ãçšããããšãã§ããããäžã§ã
ã«ã«ãã³é žãšã¹ãã«é¡ãã¢ã«ã³ãŒã«é¡ããšâãã«
é¡ãã±ãã³é¡ãæãŸããããããé»åäŸäžæ§åå
ç©ã¯ãææ©ã¢ã«ãããŠã ååç©ã觊åªæåãšçµå
ããŠçšããéã«çšããŠããããäºãææ©ã¢ã«ãã
ãŠã ååç©ãšæ¥è§Šãããäžã§çšããŠãããã æ¬çºæã®è§Šåªæåã«å¯Ÿããææ©ã¢ã«ãããŠã å
åç©ã®äœ¿çšéã¯ã該觊åªæåäžã®ãã¿ã³ïŒã°ã©ã
åååœããéåžžïŒã2000ã°ã©ã ã¢ã«ãç¹ã«20ã
500ã°ã©ã ã¢ã«ãæãŸããã åãææ©ã¢ã«ãããŠã ååç©ãšé»åäŸäžæ§åå
ç©ã®æ¯çã¯ãé»åäŸäžæ§ååç©ïŒã¢ã«ã«å¯ŸããŠæ
æ©ã¢ã«ãããŠã ååç©ãã¢ã«ãããŠã ãšããŠ0.1
ã40ã奜ãŸããã¯ïŒã25ã°ã©ã ååã®ç¯å²ã§éžã°
ããã ãªã¬ãã€ã³ã®éå äžèšã®ããã«ããŠåŸããã觊åªæåãšææ©ã¢ã«
ãããŠã ååç©ïŒåã³é»åäŸäžæ§ååç©ïŒãããª
ã觊åªã¯ãαâãªã¬ãã€ã³ãç¹ã«ççŽ æ°ïŒãªãã
ïŒåã®Î±âãªã¬ãã€ã³ãäŸãã°ãããã¬ã³ãïŒâ
ããã³ãïŒâã¡ãã«âïŒâãã³ãã³ãïŒâãããµ
ã³çã®åç¬éååã¯äžèšã®Î±âãªã¬ãã€ã³çžäºå
ã³ïŒåã¯ãšãã¬ã³ãšã®ã©ã³ãã åã³ãããã¯å ±é
åã®è§Šåªããšãã¬ã³ã®åç¬éååã¯ãšãã¬ã³ãšç
çŽ æ°ïŒã10åã®Î±âãªã¬ãã€ã³ãäŸãã°ãããã¬
ã³ãïŒâããã³ãïŒâã¡ãã«âïŒâãã³ãã³ãïŒ
âããã»ã³ãïŒâãªã¯ãã³çãšã®ã©ã³ãã è¥ãã
ã¯ãããã¯å ±éåã®è§ŠåªãšããŠæ¥µããŠåªããæ§èœ
ã瀺ãã éååå¿ã¯ãæ°çžã液çžã®ãããã§ãããã液
çžã§éåãããå Žåã¯ããã«ãã«ãã¿ã³ãã€ãœã
ã¿ã³ããã«ãã«ãã³ã¿ã³ãã€ãœãã³ã¿ã³ããããµ
ã³ãããã¿ã³ããªã¯ã¿ã³ãã·ã¯ããããµã³ããã³
ãŒã³ããã«ãšã³ããã·ã¬ã³çã®äžæŽ»æ§çåæ°ŽçŽ äž
åã³æ¶²ç¶ã¢ãããŒäžã§è¡ãããšãã§ãããéåæž©
床ã¯ãéåžžâ80âãïŒ150âã奜ãŸããã¯40ã120
âã®ç¯å²ã§ãããéåå§åã¯ãäŸãã°ïŒã60æ°å§
ã§ãããåãåŸãããéåäœã®ååéã®èª¿ç¯ã¯ã
æ°ŽçŽ è¥ããã¯ä»ã®å ¬ç¥ã®ååé調ç¯å€ãååšãã
ããããšã«ããè¡ãªããããåãå ±éåã«ãããŠ
ãªã¬ãã€ã³ã«å ±éåãããä»ã®ãªã¬ãã€ã³ã®é
ã¯ããªã¬ãã€ã³ã«å¯ŸããŠéåžž30ééïŒ è¿ãç¹ã«
0.3ã15ééïŒ ã®ç¯å²ã§éžã°ãããæ¬çºæã®è§Šåª
ç³»ã«ããéååå¿ã¯ãé£ç¶åã¯ãããåŒåå¿ã§è¡
ãªãããã®æ¡ä»¶ã¯éåžžçšããããæ¡ä»¶ã§ããã
åãå ±éååå¿ã¯äžæ®µã§è¡ã€ãŠããããäºæ®µä»¥äž
ã§è¡ã€ãŠãããã çºæã®å¹æ æ¬çºæã®è§Šåªæåã¯ãããªãªã¬ãã€ã³ãç¹ã«ã¢
ã€ãœã¿ã¯ããã¯ããªãããã¬ã³ããšãã¬ã³ãšãã
ãã¬ã³ãšã®ã©ã³ãã å ±éåäœåã³ãšãã¬ã³ãšãã
ãã¬ã³ãšã®ãããã¯å ±éåäœã補é ããå Žåã®è§Š
åªæåãšããŠæå¹ã§ããã æ¬çºæã®è§Šåªæåãçšããéå觊åªã¯ãéå掻
æ§åã³ç«äœèŠåæ§ãé«ããããããã®é«ãéå掻
æ§ãéåæã«é·æéæç¶ããããšãã§ãããšå ±
ã«ãåŸããããªã¬ãã€ã³éåäœç²æ«ã¯åµ©å¯åºŠãé«
ããåããã®éåäœç²æ«ã¯æµåæ§ã«å¯ãã§ããã å®æœäŸ 次ã«ãæ¬çºæãå®æœäŸåã³å¿çšäŸã«ããå ·äœç
ã«èª¬æãããäœããæ¬çºæã¯å®æœäŸã®ã¿ã«ããé
å®ããããã®ã§ã¯ãªãããªããå®æœäŸåã³å¿çšäŸ
ã«ç€ºããããŒã»ã³ãïŒïŒ ïŒã¯ãç¹ã«æããªãéã
ééã«ããã 觊åªæåã®æ¯è¡šé¢ç©ïŒS.A.ïŒåã³çŽ°å容ç©ïŒP.
V.ïŒã¯ãCARLO ERBA補SORPTOMATIC
1810åè£ çœ®ãçšããŠæž¬å®ãããéå掻æ§Kcã¯è§Š
åªæå1gåœãã®ããªããŒçæéïŒïœïŒãKtã¯è§Šåª
æåäžã®Ti1gåœãã®ããªããŒçæéïŒKgïŒã§ã
ãã ããªããŒäžã®çµæ¶æ§ããªããŒã®å²åã瀺ããã
ã¿ã³äžæº¶åïŒä»¥äžH.I.ãšç¥ç§°ãããïŒã¯ãæ¹è¯å
ãœãã¯ã¹ã¬ãŒæœåºåšã§æ²žéš°ïœâããã¿ã³ã«ããïŒ
æéæœåºããå Žåã®æ®éã§ãããã¡ã«ããããŒã¬
ã€ãïŒMFRïŒåã³ã¡ã«ãã€ã³ããã¯ã¹ïŒMIïŒã¯
ASTMâD1238ã«åŸã€ãŠæž¬å®ãããå嵩å¯åºŠã¯
ASTMâD1895â69ã¡ãœããã«åŸã€ãŠæž¬å®ã
ãã å®æœäŸ ïŒ ãã°ãã·ãŠã ãžãšããã·ããšããªã¯ãã«ã·ã©ã³
ã®åå¿ éæµåçž®åšã滎äžããŒãåã³æ¹ææ©ãåä»ãã
2lã®ã¬ã©ã¹è£œåå¿åšãååã«çªçŽ ã¬ã¹ã§çœ®æã
ãããã®åå¿åšã«åžè²©ã®ãã°ãã·ãŠã ãžãšããã·
ã120gïŒ1.05ã¢ã«ïŒåã³ïœâããã¿ã³680mlãå ¥ã
ãåŸã宀枩ã§æ¹æããªããããªã¯ãã«ã·ã©ã³
356gïŒ2.63ã¢ã«ïŒãšïœâããã¿ã³250mlã®æ··å溶液
ã滎äžããŒããã45åéã§æ»ŽäžããæŽã«70âã§ïŒ
æéæ¹æããããã®éåå¿ç³»ãããäž»ãšããŠãšã
ã¬ã³ããšãã«ã¯ããªãã¬ã¹ãçºçãããåŸããã
åºäœã70âã§å¥ãã65âã®ïœâãããµã³600ml
ãš10åéæ¹æäžæ¥è§ŠãããŠæŽæµããåŸãäžæŸæ¶²ã
ãã«ã³ããŒã·ãšã³ã«ããé€å»ãããæŽã«ããã®ïœ
âãããµã³ã«ããæŽæµãïŒåç¹°ãè¿ããåŸãæžå§
äž60âã§ïŒæé也ç¥ããŠãåºäœæåïŒïŒ177g
ãåŸããåºäœæåïŒïŒã¯ããã°ãã·ãŠã ã12.7
ïŒ ãçªçŽ ã14.2ïŒ ãå¡©çŽ ã46.0ïŒ å«ã¿ããã®æ¯è¡š
é¢ç©ã¯25m2ïŒïœã现å容ç©ã¯0.06c.c.ïŒïœã§ãã€
ãã å®æ¯éŠé žãšãã«ãšã®æ¥è§Š åºäœæåïŒïŒ15gããçŽåŸ12mmã®ã¹ãã³ã¬ã¹
ïŒSUS316ïŒè£œããŒã«100åãå容ããå 容ç©300
mlã®ã¹ãã³ã¬ã¹ïŒSUS316ïŒè£œãã«ãããã«ãçª
çŽ ã¬ã¹é°å²æ°äžã§å ¥ãã次ãã§å®æ¯éŠé žãšãã«
3.8gãå ãããã®ãã«ããããæ¯ãšãåšã«è£ çã
ãåŸãïŒæéæ¯ãšãããŠç²ç åŠçãè¡ããåºäœæ
åïŒïŒãåŸãã åå¡©åãã¿ã³åã³åå¡©åã±ã€çŽ ãšã®æ¥è§Š åºäœæåïŒïŒ7gããæ¹ææ©ãåä»ãã200ml
ã®ã¬ã©ã¹è£œåå¿åšã«çªçŽ ã¬ã¹é°å²æ°äžã§å ¥ãã次
ãã§ãã«ãšã³40mlãåå¡©åãã¿ã³60mlãå ãã90
âã§ïŒæéæ¹æããããã«ã³ããŒã·ãšã³ã«ããäž
æŸæ¶²ãé€å»ããåŸããã«ãšã³85mlãåå¡©åã±ã€çŽ
6.3gãå ãã60âã§ïŒæéæ¥è§Šããããå90mlã®
ãã«ãšã³ã«ãŠ60âã§ïŒåæŽæµããåŸããã«ãšã³40
mlãåå¡©åãã¿ã³60mlãå ãã90âã§ïŒæéæ¹æ
ãããåŸãããåºäœç¶ç©è³ªã90âã§å¥ããå90
mlã®ïœâãããµã³ã«ãŠã宀枩äžã§ïŒåæŽæµãã
åŸãæžå§äžãå枩床ã§ïŒæé也ç¥ããŠããã¿ã³
2.5ïŒ ããã°ãã·ãŠã 17.5ïŒ ãå¡©çŽ 55.8ïŒ ãçªçŽ
3.8ïŒ ãå®æ¯éŠé žãšãã«12.4ïŒ ãããããå«ã觊
åªæåã4.4gåŸããåãæ¯è¡šé¢ç©ã¯265m2ïŒïœã
现å容ç©ã¯0.22c.c.ïŒïœã§ãã€ãã å®æœäŸ ïŒãïŒ å®æœäŸïŒã§çšããåå¡©åã±ã€çŽ ã«ä»£ããŠãåå¡©
åé«ïŒå®æœäŸïŒïŒãäºå¡©åã¢ã³ãã¢ã³ïŒå®æœäŸ
ïŒïŒãäžå¡©åã¢ã«ãããŠã ïŒå®æœäŸïŒïŒãäžå¡©åã
ãŠçŽ ïŒå®æœäŸïŒïŒãããããçšãã以å€ã¯ãå®æœ
äŸïŒãšåæ§ã«ããŠã觊åªæåã調補ãããåŸãã
ã觊åªæåã®çµæã第ïŒè¡šã«ç€ºããã å®æœäŸ ïŒïŒïŒ å®æœäŸïŒã«ãããåºäœæåïŒïŒãšã®æ¥è§Šã«çš
ããå®æ¯éŠé žãšãã«ã«ä»£ããŠãç¡æ°Žå®æ¯éŠé žïŒå®
æœäŸïŒïŒãå¡©åãã³ãŸã€ã«ïŒå®æœäŸïŒïŒãããã
ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«ããŠè§Šåªæå
ã調補ãããåŸããã觊åªæåã®çµæã第ïŒè¡šã«
瀺ããã å®æœäŸ ïŒã11 å®æœäŸïŒã«ãããŠãã°ãã·ãŠã ãžãšããã·ããš
æ¥è§Šããéã«çšããããªã¯ãã«ã·ã©ã³ã®ä»£ãã«ã
ã¡ãã«ãžã¯ãã«ã·ã©ã³ïŒå®æœäŸïŒïŒããžã¡ãã«ã¯
ãã«ã·ã©ã³ïŒå®æœäŸïŒïŒãããªãšãã«ã·ã©ã³ïŒå®
æœäŸ10ïŒããžãšããã·ã¡ãã«ã·ã©ã³ïŒå®æœäŸ11ïŒ
ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«ããŠã觊åªæ
åã調補ãããåŸããã觊åªæåã®çµæã第ïŒè¡š
ã«ç€ºããã å®æœäŸ 12 å®æ¯éŠé žãšãã«ã®ä»£ããã«ããã¿ã«é žãžïœâã
ãã«ãçšãã以å€ã¯ãå®æœäŸïŒãšåæ§ã«ããŠè§Šåª
æåã調補ãããåŸããã觊åªæåã®çµæã第ïŒ
è¡šã«ç€ºããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠçšãããã«ãããã«ãçªçŽ ã¬
ã¹é°å²æ°äžãåžè²©ã®ãã°ãã·ãŠã ãžãšããã·ã
31.5gãå®æ¯éŠé žãšãã«7.5mlãå ¥ãããã®ãã«ã
ãããæ¯ãšãåšã«è£ çããŠã15æéæ¯ãšãããã åŸãããç²ç åºäœ9.2gãã200mlã®æ¹ææ©ä»ã
ã¬ã©ã¹å®¹åšã«å ¥ãããã«ãšã³40mlãåå¡©åãã¿ã³
60mlãå ãã90âã§ïŒæéæ¹æãããåŸãããåº
äœç¶ç©è³ªã90âã§å¥ãã90mlã®ïœâãããµã³ã«
ãŠã宀枩äžïŒåæŽæµããåŸãæžå§äžã宀枩ã§ïŒæ
é也ç¥ããŠç¬¬ïŒè¡šã«ç€ºãçµæãæãã觊åªæåã
調補ããã æ¯èŒäŸ ïŒ æ¯èŒäŸïŒã§åŸãããç²ç åºäœ5.3gãã500mlã®
æ¹ææ©ä»ãã¬ã©ã¹å®¹åšã«å ¥ããããã«ïœâããã¿
ã³330mlãå ããã次ã«ãåå¡©åãã¿ã³ïŒmlã宀
æž©äž15åéã§æ»ŽäžããæŽã«ããªã¯ãã«ã·ã©ã³35ml
ãåæ§ã«ããŠæ»ŽäžããåŸã90âã§ïŒæéæ¹æã
ãã åŸãããåºäœç¶ç©è³ªã90âã§å¥ãã150mlã®
ïœâãããµã³ã«ãŠå®€æž©äžãïŒåæŽæµããåŸãæžå§
äžã宀枩ã§ïŒæé也ç¥ããŠã第ïŒè¡šã«ç€ºãçµæã®
觊åªæåã調補ããã
ãè¡šã
ãè¡šã
å¿çšäŸ ïŒ
ãããã¬ã³ã®éå
æ¹æåšãèšããå
容ç©1.5ã®ã¹ãã³ã¬ã¹
ïŒSUS32ïŒè£œãªãŒãã¯ã¬ãŒãã«ãçªçŽ ã¬ã¹é°å²æ°
äžãå®æœäŸïŒã§åŸããã觊åªæå19.2mgãïœâã
ãã¿ã³ïŒäžã«ïŒã¢ã«ã®ããªãšãã«ã¢ã«ãããŠã
ïŒä»¥äžTEALãšç¥ç§°ãããïŒãå«ãïœâããã¿ã³æº¶
液ã觊åªæåäžã®ãã¿ã³ïŒã°ã©ã åååœãã¢ã«ã
ããŠã ãšããŠ250ã°ã©ã ååã«çžåœãã2.5mlåã³
該TEALäžã®ã¢ã«ãããŠã ïŒã°ã©ã åååœã0.33
ã¢ã«ã«çžåœããâã¡ããã·å®æ¯éŠé žãšãã«0.38
mlãæ··åãïŒåéä¿æãããã®ãä»èŸŒãã ã次ã
ã§ãååéå¶åŸ¡å€ãšããŠã®æ°ŽçŽ ã¬ã¹0.6䞊ã³ã«
液åãããã¬ã³0.8ãå§å ¥ããåŸãåå¿ç³»ã70
âã«ææž©ããŠãïŒæéããããã¬ã³ã®éåãè¡ã€
ããéåçµäºåŸãæªåå¿ã®ãããã¬ã³ãããŒãž
ããHIïŒããªããŒäžã®çµæ¶æ§ããªããŒã®å²åã瀺
ãããã¿ã³äžæº¶åïŒ96.0ïŒ ãMFRïŒã¡ã«ããããŒ
ã¬ã€ãïŒ1.9ã嵩å¯åºŠ0.39gïŒcm3ã®çœè²ã®ããªãã
ãã¬ã³ç²æ«ã311.0gïŒKcïŒ16.200ãKtïŒ648ïŒåŸ
ãã å¿çšäŸ ïŒã14 å®æœäŸïŒã§åŸããã觊åªæåã«ä»£ããŠãå®æœäŸ
ïŒã12ãæ¯èŒäŸïŒãïŒã§åŸããã觊åªæåãçšã
ã以å€ã¯ãå¿çšäŸïŒãšåæ§ã«ããŠãããã¬ã³ã®é
åãè¡ã€ãããã®çµæã第ïŒè¡šã«ç€ºãã
ïŒSUS32ïŒè£œãªãŒãã¯ã¬ãŒãã«ãçªçŽ ã¬ã¹é°å²æ°
äžãå®æœäŸïŒã§åŸããã觊åªæå19.2mgãïœâã
ãã¿ã³ïŒäžã«ïŒã¢ã«ã®ããªãšãã«ã¢ã«ãããŠã
ïŒä»¥äžTEALãšç¥ç§°ãããïŒãå«ãïœâããã¿ã³æº¶
液ã觊åªæåäžã®ãã¿ã³ïŒã°ã©ã åååœãã¢ã«ã
ããŠã ãšããŠ250ã°ã©ã ååã«çžåœãã2.5mlåã³
該TEALäžã®ã¢ã«ãããŠã ïŒã°ã©ã åååœã0.33
ã¢ã«ã«çžåœããâã¡ããã·å®æ¯éŠé žãšãã«0.38
mlãæ··åãïŒåéä¿æãããã®ãä»èŸŒãã ã次ã
ã§ãååéå¶åŸ¡å€ãšããŠã®æ°ŽçŽ ã¬ã¹0.6䞊ã³ã«
液åãããã¬ã³0.8ãå§å ¥ããåŸãåå¿ç³»ã70
âã«ææž©ããŠãïŒæéããããã¬ã³ã®éåãè¡ã€
ããéåçµäºåŸãæªåå¿ã®ãããã¬ã³ãããŒãž
ããHIïŒããªããŒäžã®çµæ¶æ§ããªããŒã®å²åã瀺
ãããã¿ã³äžæº¶åïŒ96.0ïŒ ãMFRïŒã¡ã«ããããŒ
ã¬ã€ãïŒ1.9ã嵩å¯åºŠ0.39gïŒcm3ã®çœè²ã®ããªãã
ãã¬ã³ç²æ«ã311.0gïŒKcïŒ16.200ãKtïŒ648ïŒåŸ
ãã å¿çšäŸ ïŒã14 å®æœäŸïŒã§åŸããã觊åªæåã«ä»£ããŠãå®æœäŸ
ïŒã12ãæ¯èŒäŸïŒãïŒã§åŸããã觊åªæåãçšã
ã以å€ã¯ãå¿çšäŸïŒãšåæ§ã«ããŠãããã¬ã³ã®é
åãè¡ã€ãããã®çµæã第ïŒè¡šã«ç€ºãã
第ïŒå³ã¯ãæ¬çºæã®è§Šåªæåã®èª¿è£œå·¥çšã瀺ã
ãããŒãã€ãŒãå³ã§ããã
ãããŒãã€ãŒãå³ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãã°ãã·ãŠã ãžã¢ã«ã³ãã·ããšäžè¬åŒ
HmRnSiXrãäœããã¯çåæ°ŽçŽ åºãR1Oâè¥ã
ãã¯R2R3Nâãã¯ããã²ã³ååã瀺ããïŒ
ïœïŒïŒïŒïœïŒïŒïœïŒïœïŒïœïŒïŒã§ããã
R1ïŒR2åã³R3ã¯ããããçåæ°ŽçŽ åºã瀺ãããã®
çªçŽ ååç©ãšã®åå¿ç©ãé»åäŸäžæ§ååç©ãšæ¥è§Š
ãããŠåŸãããæ¥è§Šç©ããäžè¬åŒTiXnïŒORïŒ4-o
ãäœããã¯ããã²ã³ååãã¯çåæ°ŽçŽ åºã瀺
ããïŒïŒïœïŒã§ããããã®ããã²ã³åãã¿ã³å
åç©ãšïŒå以äžæ¥è§Šãããããšãããªãããã€å
ããã²ã³åãã¿ã³ååç©ã®æ¥è§Šã®éã«ãå çŽ ã®åš
æè¡šïœïŒïœåã³ïœæã®å çŽ ã®çŸ€ããéžã°ã
ãå çŽ ã®ããã²ã³åç©ãšæ¥è§ŠããŠãªãαâãªã¬ã
ã€ã³éåçšè§Šåªæåã
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58157092A JPS6049005A (ja) | 1983-08-30 | 1983-08-30 | αâãªã¬ãã€ã³éåçšè§Šåªæå |
US06/642,022 US4552858A (en) | 1983-08-30 | 1984-08-20 | Catalyst component for polymerization of olefins |
CA000462039A CA1221957A (en) | 1983-08-30 | 1984-08-29 | Catalyst component for polymerization of olefins |
DE8484305954T DE3463148D1 (en) | 1983-08-30 | 1984-08-30 | Catalyst component for polymerization of olefins |
EP84305954A EP0140536B1 (en) | 1983-08-30 | 1984-08-30 | Catalyst component for polymerization of olefins |
US06/771,392 US4625003A (en) | 1983-08-30 | 1985-08-30 | Catalyst component for polymerization of olefins (P-1026) |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58157092A JPS6049005A (ja) | 1983-08-30 | 1983-08-30 | αâãªã¬ãã€ã³éåçšè§Šåªæå |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6049005A JPS6049005A (ja) | 1985-03-18 |
JPH0149289B2 true JPH0149289B2 (ja) | 1989-10-24 |
Family
ID=15642069
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58157092A Granted JPS6049005A (ja) | 1983-08-30 | 1983-08-30 | αâãªã¬ãã€ã³éåçšè§Šåªæå |
Country Status (5)
Country | Link |
---|---|
US (1) | US4552858A (ja) |
EP (1) | EP0140536B1 (ja) |
JP (1) | JPS6049005A (ja) |
CA (1) | CA1221957A (ja) |
DE (1) | DE3463148D1 (ja) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0629288B2 (ja) * | 1984-06-21 | 1994-04-20 | æ±çæ ªåŒäŒç€Ÿ | ãªã¬ãã€ã³éåçšè§Šåªæå |
JPH0674292B2 (ja) * | 1984-11-30 | 1994-09-21 | æ±çæ ªåŒäŒç€Ÿ | ãšãã¬ã³éåçšè§Šåªæåã®è£œé æ³ |
JPS61151208A (ja) * | 1984-12-26 | 1986-07-09 | Toa Nenryo Kogyo Kk | ããã³âïŒã®éåæ¹æ³ |
JPH0725807B2 (ja) * | 1985-12-20 | 1995-03-22 | æ±çæ ªåŒäŒç€Ÿ | ãªã¬ãã€ã³éåçšè§Šåªæåã®è£œé æ¹æ³ |
US4814314A (en) * | 1986-09-26 | 1989-03-21 | Mitsubishi Petrochemical Company Limited | Catalyst for olefin polymerization |
JPH0832737B2 (ja) * | 1986-10-08 | 1996-03-29 | æ±éŠãã¿ããŠã æ ªåŒäŒç€Ÿ | ãªã¬ãã€ã³é¡éåçšåºäœè§Šåªæå |
US4876230A (en) * | 1988-09-06 | 1989-10-24 | Shell Oil Company | Magnesium alkoxide polymerization catalyst by boiling in organic solvents |
US4874737A (en) * | 1988-09-06 | 1989-10-17 | Shell Oil Company | Silicate-modified magnesium alkoxide polymerization catalysts |
US4959336A (en) * | 1989-04-07 | 1990-09-25 | Shell Oil Company | Silicate-modified magnesium ethoxide polymerization catalysts |
US5063188A (en) * | 1990-04-06 | 1991-11-05 | Texas Alkyls, Inc. | Catalyst component for ethylene polyermization and copolymerization |
US5182341A (en) * | 1990-04-30 | 1993-01-26 | Masino Albert P | Olefin polymerization method |
US5126302A (en) * | 1990-04-30 | 1992-06-30 | Quantum Chemical Corporation | Olefin polymerization catalyst and methods |
CN100532402C (zh) * | 2001-11-01 | 2009-08-26 | åºå å Žäº§æ ªåŒäŒç€Ÿ | ç¯çèåçšåºäœå¬ååæåãç¯çèåçšå¬åååç¯çèåç©çå¶å€æ¹æ³ |
ES2567259T3 (es) | 2001-11-01 | 2016-04-21 | Idemitsu Kosan Co., Ltd. | Componente catalÃtico sólido para la polimerización de olefinas, catalizador para la polimerización de olefinas y proceso para la producción de un polÃmero olefÃnico |
EP1845112A1 (en) * | 2006-04-12 | 2007-10-17 | Total Petrochemicals Research Feluy | Controlled distribution of active sites in Ziegler-Natta catalysts systems |
US10150822B2 (en) * | 2011-07-26 | 2018-12-11 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization, preparation method therefor and catalyst thereof |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3135809A (en) * | 1960-07-21 | 1964-06-02 | Southern Res Inst | Isomerization process |
LU61816A1 (ja) * | 1970-10-06 | 1972-06-28 | ||
IT1042711B (it) * | 1975-09-19 | 1980-01-30 | Montedison Spa | Compnenti di catalizzatori per la polimerizzazione di olefine |
JPS5298076A (en) * | 1976-02-13 | 1977-08-17 | Mitsubishi Chem Ind Ltd | Preparation of polyolefins |
DE2742585A1 (de) * | 1976-09-28 | 1978-03-30 | Asahi Chemical Ind | Neue polymerisationskatalysatoren und ihre verwendung (i) |
JPS607642B2 (ja) * | 1977-02-16 | 1985-02-26 | æåææ ªåŒäŒç€Ÿ | ããªã¢ã«ãã¢ãªã¬ãã€ã³ã®è£œé çšè§Šåª |
JPS6025441B2 (ja) * | 1976-09-30 | 1985-06-18 | äžäºååŠæ ªåŒäŒç€Ÿ | åºäœè§Šåªæååã³ãªã¬ãã£ã³éåçšè§Šåª |
US4242479A (en) * | 1976-12-23 | 1980-12-30 | Showa Yuka Kabushiki Kaisha | Process for producing an improved ethylenic polymer |
IT1078995B (it) * | 1977-05-24 | 1985-05-08 | Montedison Spa | Catalizzatori per la polimeriazzazione di olefine |
US4159256A (en) * | 1977-06-02 | 1979-06-26 | Asahi Kasei Kogyo Kabushiki Kaisha | Catalyst for polymerizing olefins and polymerization method of olefins carried out therewith |
JPS584726B2 (ja) * | 1978-03-15 | 1983-01-27 | æåææ ªåŒäŒç€Ÿ | ãªã¬ãã€ã³éåçšè§Šåª |
IT1099416B (it) * | 1978-10-23 | 1985-09-18 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione delle olefine |
US4324690A (en) * | 1979-02-15 | 1982-04-13 | Standard Oil Company (Indiana) | Alpha-olefin polymerization catalyst |
US4250287A (en) * | 1980-03-14 | 1981-02-10 | Hercules Incorporated | 1-Olefin polymerization catalyst |
JPS56155205A (en) * | 1980-05-02 | 1981-12-01 | Shindaikiyouwa Sekiyu Kagaku Kk | Production of polyolefin |
IT1150031B (it) * | 1980-07-24 | 1986-12-10 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione dell'etilene |
JPS5763309A (en) * | 1980-10-03 | 1982-04-16 | Idemitsu Kosan Co Ltd | Polymerization of alpha-olefin |
JPS57108107A (en) * | 1980-12-25 | 1982-07-06 | Asahi Chem Ind Co Ltd | Catalyst for olefin polymerization |
JPS5853905A (ja) * | 1981-09-29 | 1983-03-30 | Toa Nenryo Kogyo Kk | ãªã¬ãã€ã³éåçšè§Šåªæå |
US4472521A (en) * | 1982-12-20 | 1984-09-18 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
-
1983
- 1983-08-30 JP JP58157092A patent/JPS6049005A/ja active Granted
-
1984
- 1984-08-20 US US06/642,022 patent/US4552858A/en not_active Expired - Fee Related
- 1984-08-29 CA CA000462039A patent/CA1221957A/en not_active Expired
- 1984-08-30 EP EP84305954A patent/EP0140536B1/en not_active Expired
- 1984-08-30 DE DE8484305954T patent/DE3463148D1/de not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CA1221957A (en) | 1987-05-19 |
EP0140536B1 (en) | 1987-04-15 |
US4552858A (en) | 1985-11-12 |
DE3463148D1 (en) | 1987-05-21 |
JPS6049005A (ja) | 1985-03-18 |
EP0140536A1 (en) | 1985-05-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4565798A (en) | Process for polymerization of olefins | |
JPH0149289B2 (ja) | ||
JPH072775B2 (ja) | ãªã¬ãã€ã³éåçšè§Šåªæåã®è£œé æ³ | |
JPH0149291B2 (ja) | ||
JPH0149288B2 (ja) | ||
EP0145368B1 (en) | Process for producing propylene block copolymers | |
US4678768A (en) | Catalyst component for polymerization of olefins | |
EP0227455A2 (en) | Process for producing catalyst ingredient for use in olefin polymerization | |
US4652541A (en) | Catalyst component for polymerization of olefins | |
JPH0153884B2 (ja) | ||
JPS6247446B2 (ja) | ||
US4625003A (en) | Catalyst component for polymerization of olefins (P-1026) | |
JPH0153883B2 (ja) | ||
JPH023405B2 (ja) | ||
KR930001065B1 (ko) | α-ì¬ë íì ëšë ì€í©ì²Ž ëë ê³µì€í©ì²Žì ì ì¡°ë°©ë² | |
JP2772572B2 (ja) | αâãªã¬ãã£ã³éåçšè§Šåª | |
JPH0322889B2 (ja) | ||
JPS6247443B2 (ja) |