JPH01246328A - スカンジウムの補集方法 - Google Patents
スカンジウムの補集方法Info
- Publication number
- JPH01246328A JPH01246328A JP7390088A JP7390088A JPH01246328A JP H01246328 A JPH01246328 A JP H01246328A JP 7390088 A JP7390088 A JP 7390088A JP 7390088 A JP7390088 A JP 7390088A JP H01246328 A JPH01246328 A JP H01246328A
- Authority
- JP
- Japan
- Prior art keywords
- scandium
- ions
- resin
- iii
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 title claims description 29
- 229910052706 scandium Inorganic materials 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 15
- 229920005989 resin Polymers 0.000 claims abstract description 38
- 239000011347 resin Substances 0.000 claims abstract description 38
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- -1 scandium (III) ions Chemical class 0.000 claims description 29
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 20
- 150000002500 ions Chemical class 0.000 abstract description 20
- 239000002253 acid Substances 0.000 abstract description 19
- 150000002148 esters Chemical class 0.000 abstract description 12
- 239000002904 solvent Substances 0.000 abstract description 5
- 229910021645 metal ion Inorganic materials 0.000 description 26
- 239000000243 solution Substances 0.000 description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- 239000003960 organic solvent Substances 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000002184 metal Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- ZXOKVTWPEIAYAB-UHFFFAOYSA-N dioxido(oxo)tungsten Chemical compound [O-][W]([O-])=O ZXOKVTWPEIAYAB-UHFFFAOYSA-N 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 125000005600 alkyl phosphonate group Chemical group 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- 229910000616 Ferromanganese Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 2
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229920006222 acrylic ester polymer Polymers 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7390088A JPH01246328A (ja) | 1988-03-28 | 1988-03-28 | スカンジウムの補集方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7390088A JPH01246328A (ja) | 1988-03-28 | 1988-03-28 | スカンジウムの補集方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01246328A true JPH01246328A (ja) | 1989-10-02 |
| JPH0474418B2 JPH0474418B2 (cg-RX-API-DMAC7.html) | 1992-11-26 |
Family
ID=13531538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7390088A Granted JPH01246328A (ja) | 1988-03-28 | 1988-03-28 | スカンジウムの補集方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01246328A (cg-RX-API-DMAC7.html) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005152756A (ja) * | 2003-11-25 | 2005-06-16 | Japan Atom Energy Res Inst | スカンジウムを捕集回収する方法 |
| JP2007327126A (ja) * | 2006-06-09 | 2007-12-20 | Japan Atomic Energy Agency | 固体高分子材料中のスカンジウムを溶出回収する方法 |
| WO2015025558A1 (ja) | 2013-08-22 | 2015-02-26 | 住友金属鉱山株式会社 | スカンジウム回収方法 |
| JP2015166491A (ja) * | 2014-02-12 | 2015-09-24 | 学校法人金沢工業大学 | スカンジウムの分離法 |
| US9187805B2 (en) | 2012-06-19 | 2015-11-17 | Sumitomo Metal Mining Co., Ltd. | Method for separating and refining scandium |
| EP2995693A1 (en) | 2014-09-10 | 2016-03-16 | Shin-Etsu Chemical Co., Ltd. | Extraction/separation method |
| CN106702180A (zh) * | 2015-07-29 | 2017-05-24 | 王艳良 | 一种钪元素的萃取方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6045261A (ja) * | 1983-08-23 | 1985-03-11 | Hitachi Chem Co Ltd | 磁性トナ−の製造法 |
| JPS60251126A (ja) * | 1984-04-02 | 1985-12-11 | ロ−ヌ−プ−ラン・スペシアリテ・シミ−ク | 液−液抽出による希土類の分離方法 |
| JPS6135253A (ja) * | 1984-07-27 | 1986-02-19 | Usac Electronics Ind Co Ltd | 改ざん防止文字の印刷装置 |
| JPS61210132A (ja) * | 1985-03-14 | 1986-09-18 | Inoue Japax Res Inc | 金属精製分離方法 |
| JPS62253739A (ja) * | 1986-02-14 | 1987-11-05 | ロ−ヌ−プ−ラン・シミ | 希土類元素から鉛を除去する方法 |
-
1988
- 1988-03-28 JP JP7390088A patent/JPH01246328A/ja active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6045261A (ja) * | 1983-08-23 | 1985-03-11 | Hitachi Chem Co Ltd | 磁性トナ−の製造法 |
| JPS60251126A (ja) * | 1984-04-02 | 1985-12-11 | ロ−ヌ−プ−ラン・スペシアリテ・シミ−ク | 液−液抽出による希土類の分離方法 |
| JPS6135253A (ja) * | 1984-07-27 | 1986-02-19 | Usac Electronics Ind Co Ltd | 改ざん防止文字の印刷装置 |
| JPS61210132A (ja) * | 1985-03-14 | 1986-09-18 | Inoue Japax Res Inc | 金属精製分離方法 |
| JPS62253739A (ja) * | 1986-02-14 | 1987-11-05 | ロ−ヌ−プ−ラン・シミ | 希土類元素から鉛を除去する方法 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005152756A (ja) * | 2003-11-25 | 2005-06-16 | Japan Atom Energy Res Inst | スカンジウムを捕集回収する方法 |
| JP2007327126A (ja) * | 2006-06-09 | 2007-12-20 | Japan Atomic Energy Agency | 固体高分子材料中のスカンジウムを溶出回収する方法 |
| US9187805B2 (en) | 2012-06-19 | 2015-11-17 | Sumitomo Metal Mining Co., Ltd. | Method for separating and refining scandium |
| WO2015025558A1 (ja) | 2013-08-22 | 2015-02-26 | 住友金属鉱山株式会社 | スカンジウム回収方法 |
| US9404169B2 (en) | 2013-08-22 | 2016-08-02 | Sumitomo Metal Mining Co., Ltd. | Method for recovering scandium |
| JP2015166491A (ja) * | 2014-02-12 | 2015-09-24 | 学校法人金沢工業大学 | スカンジウムの分離法 |
| EP2995693A1 (en) | 2014-09-10 | 2016-03-16 | Shin-Etsu Chemical Co., Ltd. | Extraction/separation method |
| US9822428B2 (en) | 2014-09-10 | 2017-11-21 | Shin-Etsu Chemical Co., Ltd. | Extraction/separation method |
| CN106702180A (zh) * | 2015-07-29 | 2017-05-24 | 王艳良 | 一种钪元素的萃取方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0474418B2 (cg-RX-API-DMAC7.html) | 1992-11-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |