JPH01246140A - 酸化ビスマス（３）の製造方法 - Google Patents
酸化ビスマス（３）の製造方法Info
- Publication number
- JPH01246140A JPH01246140A JP63072708A JP7270888A JPH01246140A JP H01246140 A JPH01246140 A JP H01246140A JP 63072708 A JP63072708 A JP 63072708A JP 7270888 A JP7270888 A JP 7270888A JP H01246140 A JPH01246140 A JP H01246140A
- Authority
- JP
- Japan
- Prior art keywords
- bismuth
- complex
- iii
- acid
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MSBGPEACXKBQSX-UHFFFAOYSA-N (4-fluorophenyl) carbonochloridate Chemical compound FC1=CC=C(OC(Cl)=O)C=C1 MSBGPEACXKBQSX-UHFFFAOYSA-N 0.000 title claims abstract description 13
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 19
- 239000003513 alkali Substances 0.000 claims abstract description 11
- 229910001451 bismuth ion Inorganic materials 0.000 claims abstract description 11
- 239000000243 solution Substances 0.000 claims description 17
- 238000010304 firing Methods 0.000 claims description 9
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 24
- 239000002245 particle Substances 0.000 abstract description 23
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract description 14
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract description 9
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract description 8
- 238000001354 calcination Methods 0.000 abstract description 8
- 235000019260 propionic acid Nutrition 0.000 abstract description 7
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract description 6
- PPNKDDZCLDMRHS-UHFFFAOYSA-N bismuth(III) nitrate Inorganic materials [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 abstract description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract description 3
- 235000019253 formic acid Nutrition 0.000 abstract description 3
- 235000011054 acetic acid Nutrition 0.000 abstract description 2
- 150000001621 bismuth Chemical class 0.000 abstract description 2
- 229910000380 bismuth sulfate Inorganic materials 0.000 abstract description 2
- BEQZMQXCOWIHRY-UHFFFAOYSA-H dibismuth;trisulfate Chemical compound [Bi+3].[Bi+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BEQZMQXCOWIHRY-UHFFFAOYSA-H 0.000 abstract description 2
- 239000010419 fine particle Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 27
- 229910000416 bismuth oxide Inorganic materials 0.000 description 20
- 238000000034 method Methods 0.000 description 12
- 229940049676 bismuth hydroxide Drugs 0.000 description 11
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 description 11
- 239000002244 precipitate Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000004455 differential thermal analysis Methods 0.000 description 6
- 238000007796 conventional method Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229910052797 bismuth Inorganic materials 0.000 description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
- 239000012776 electronic material Substances 0.000 description 4
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 4
- 230000001788 irregular Effects 0.000 description 4
- 238000001000 micrograph Methods 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RMXQRHVIUMSGLJ-UHFFFAOYSA-N O.[Bi]=O Chemical compound O.[Bi]=O RMXQRHVIUMSGLJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 1
- JDIBGQFKXXXXPN-UHFFFAOYSA-N bismuth(3+) Chemical compound [Bi+3] JDIBGQFKXXXXPN-UHFFFAOYSA-N 0.000 description 1
- OYDUVCKHBASGOB-UHFFFAOYSA-N bismuth;propanoic acid Chemical compound [Bi].CCC(O)=O OYDUVCKHBASGOB-UHFFFAOYSA-N 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- -1 for example Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- CJJMLLCUQDSZIZ-UHFFFAOYSA-N oxobismuth Chemical compound [Bi]=O CJJMLLCUQDSZIZ-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G29/00—Compounds of bismuth
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
- C01P2004/52—Particles with a specific particle size distribution highly monodisperse size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63072708A JPH01246140A (ja) | 1988-03-25 | 1988-03-25 | 酸化ビスマス（３）の製造方法 |
| US07/319,756 US4873073A (en) | 1988-03-25 | 1989-03-07 | Method for production of bismuth (III) oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63072708A JPH01246140A (ja) | 1988-03-25 | 1988-03-25 | 酸化ビスマス（３）の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01246140A true JPH01246140A (ja) | 1989-10-02 |
| JPH0457613B2 JPH0457613B2 (cg-RX-API-DMAC7.html) | 1992-09-14 |
Family
ID=13497122
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63072708A Granted JPH01246140A (ja) | 1988-03-25 | 1988-03-25 | 酸化ビスマス（３）の製造方法 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4873073A (cg-RX-API-DMAC7.html) |
| JP (1) | JPH01246140A (cg-RX-API-DMAC7.html) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH111322A (ja) * | 1997-06-10 | 1999-01-06 | Dowa Mining Co Ltd | 酸化ビスマス粉およびその製造方法 |
| WO2013191075A1 (ja) * | 2012-06-21 | 2013-12-27 | 東亞合成株式会社 | 非晶質無機陰イオン交換体、電子部品封止用樹脂組成物および非晶質ビスマス化合物の製造方法 |
| CN115057473A (zh) * | 2022-06-13 | 2022-09-16 | 哈尔滨工程大学 | 一种氧空位型超薄氧化铋纳米片的制备方法及利用其低频超声诱导产生热效应的方法 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5523285A (en) * | 1994-09-30 | 1996-06-04 | The United States Of America As Represented By The United States Department Of Energy | Rapid formation of phase-clean 110 K (Bi-2223) powders derived via freeze-drying process |
| US8285590B2 (en) * | 2000-06-23 | 2012-10-09 | Ecomsystems, Inc. | Systems and methods for computer-created advertisements |
| US7118726B2 (en) * | 2002-12-13 | 2006-10-10 | Clark Manufacturing, Llc | Method for making oxide compounds |
| TW200704183A (en) | 2005-01-27 | 2007-01-16 | Matrix Tv | Dynamic mosaic extended electronic programming guide for television program selection and display |
| US8875196B2 (en) | 2005-08-13 | 2014-10-28 | Webtuner Corp. | System for network and local content access |
| KR100844088B1 (ko) | 2007-04-25 | 2008-07-04 | 주식회사 단석산업 | 산화비스무스의 제조방법 |
| US8296183B2 (en) * | 2009-11-23 | 2012-10-23 | Ecomsystems, Inc. | System and method for dynamic layout intelligence |
| WO2012158904A1 (en) | 2011-05-17 | 2012-11-22 | Webtuner Corporation | System and method for scalable, high accuracy, sensor and id based audience measurement system |
| US9256884B2 (en) | 2011-05-24 | 2016-02-09 | Webtuner Corp | System and method to increase efficiency and speed of analytics report generation in audience measurement systems |
| CN103703786A (zh) | 2011-05-26 | 2014-04-02 | 韦伯图纳公司 | 高度可伸缩的具有客户端事件预处理的观众测量系统 |
| CN111569858B (zh) * | 2020-04-27 | 2023-04-28 | 沈阳工业大学 | 一种德尔塔氧化铋催化材料的制备方法及其应用 |
| CN114804984B (zh) * | 2022-04-28 | 2023-06-09 | 西安近代化学研究所 | 一种沉积氧化铋的硼燃料及制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1318336A (en) * | 1919-10-07 | Making oxids of bismuth | ||
| US1354806A (en) * | 1919-01-04 | 1920-10-05 | Ellis Foster Co | Making bismuth oxid |
| SU666134A1 (ru) * | 1978-01-03 | 1979-06-05 | Предприятие П/Я В-8130 | Способ получени окиси висмута |
| SU1122728A1 (ru) * | 1983-11-01 | 1984-11-07 | Институт химии твердого тела и переработки минерального сырья СО АН СССР | Способ получени окиси висмута из оксисоединений |
| JPS61136922A (ja) * | 1984-12-10 | 1986-06-24 | Sumitomo Metal Mining Co Ltd | 微粒状酸化ビスマスの製造方法 |
| JPH11335A (ja) * | 1997-06-10 | 1999-01-06 | Jms Co Ltd | 血管吻合補助具 |
-
1988
- 1988-03-25 JP JP63072708A patent/JPH01246140A/ja active Granted
-
1989
- 1989-03-07 US US07/319,756 patent/US4873073A/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH111322A (ja) * | 1997-06-10 | 1999-01-06 | Dowa Mining Co Ltd | 酸化ビスマス粉およびその製造方法 |
| WO2013191075A1 (ja) * | 2012-06-21 | 2013-12-27 | 東亞合成株式会社 | 非晶質無機陰イオン交換体、電子部品封止用樹脂組成物および非晶質ビスマス化合物の製造方法 |
| KR20150023041A (ko) | 2012-06-21 | 2015-03-04 | 도아고세이가부시키가이샤 | 비정질 무기 음이온 교환체, 전자 부품 밀봉용 수지 조성물 및 비정질 비스무트 화합물의 제조 방법 |
| JPWO2013191075A1 (ja) * | 2012-06-21 | 2016-05-26 | 東亞合成株式会社 | 非晶質無機陰イオン交換体、電子部品封止用樹脂組成物および非晶質ビスマス化合物の製造方法 |
| US9849449B2 (en) | 2012-06-21 | 2017-12-26 | Toagosei Co., Ltd. | Amorphous inorganic anion exchanger, resin composition for electronic component sealing, and process for producing amorphous bismuth compound |
| CN115057473A (zh) * | 2022-06-13 | 2022-09-16 | 哈尔滨工程大学 | 一种氧空位型超薄氧化铋纳米片的制备方法及利用其低频超声诱导产生热效应的方法 |
| CN115057473B (zh) * | 2022-06-13 | 2023-10-10 | 哈尔滨工程大学 | 一种氧空位型超薄氧化铋纳米片的制备方法及利用其低频超声诱导产生热效应的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0457613B2 (cg-RX-API-DMAC7.html) | 1992-09-14 |
| US4873073A (en) | 1989-10-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |