JPH01158050A

JPH01158050A - エポキシ樹脂積層板

エポキシ樹脂積層板

Info

Publication number: JPH01158050A
Authority: JP; Japan
Prior art keywords: epoxy resin; glass fiber; base material; nonwoven fabric; resin laminate
Prior art date: 1987-06-05
Legal status : Granted

Application number

JP5556088A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0548773B2 (enrdf_load_stackoverflow

Inventor

Masayuki Noda

雅之野田

Kenichi Kariya

刈屋　憲一

Takahiro Yamaguchi

貴寛山口

Katsuharu Takahashi

克治高橋

Current Assignee

Resonac Corp

Original Assignee

Shin Kobe Electric Machinery Co Ltd

Priority date

1987-06-05

Filing date

1988-03-09

Publication date

1989-06-21

1988-03-09 Application filed by Shin Kobe Electric Machinery Co Ltd filed Critical Shin Kobe Electric Machinery Co Ltd

1988-03-09 Priority to JP5556088A priority Critical patent/JPH01158050A/ja

1988-06-02 Priority to US07/201,684 priority patent/US4913955A/en

1988-06-03 Priority to EP19880305112 priority patent/EP0294232A3/en

1988-06-03 Priority to CA 568626 priority patent/CA1289048C/en

1988-06-04 Priority to CN198888104318A priority patent/CN88104318A/zh

1989-06-21 Publication of JPH01158050A publication Critical patent/JPH01158050A/ja

1993-07-22 Publication of JPH0548773B2 publication Critical patent/JPH0548773B2/ja

Status Granted legal-status Critical Current

Links

239000003822 epoxy resin Substances 0.000 title claims abstract description 55
229920000647 polyepoxide Polymers 0.000 title claims abstract description 55
239000003365 glass fiber Substances 0.000 claims abstract description 78
239000002759 woven fabric Substances 0.000 claims abstract description 36
239000000203 mixture Substances 0.000 claims abstract description 32
229920003006 Polybutadiene acrylonitrile Polymers 0.000 claims abstract description 15
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 14
239000011888 foil Substances 0.000 claims abstract description 8
229910052751 metal Inorganic materials 0.000 claims abstract description 7
239000002184 metal Substances 0.000 claims abstract description 7
239000004745 nonwoven fabric Substances 0.000 claims description 50
239000000463 material Substances 0.000 claims description 33
239000000835 fiber Substances 0.000 claims description 18
239000004744 fabric Substances 0.000 claims description 12
230000001588 bifunctional effect Effects 0.000 claims description 6
239000002131 composite material Substances 0.000 claims 1
239000000126 substance Substances 0.000 abstract description 7
239000000758 substrate Substances 0.000 abstract description 4
239000000853 adhesive Substances 0.000 abstract description 2
230000001070 adhesive effect Effects 0.000 abstract description 2
238000005470 impregnation Methods 0.000 abstract 2
230000000052 comparative effect Effects 0.000 description 55
229920006231 aramid fiber Polymers 0.000 description 36
239000002966 varnish Substances 0.000 description 21
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 13
239000011889 copper foil Substances 0.000 description 13
239000004593 Epoxy Substances 0.000 description 11
238000001035 drying Methods 0.000 description 9
238000010998 test method Methods 0.000 description 8
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 7
239000003063 flame retardant Substances 0.000 description 7
238000005452 bending Methods 0.000 description 6
238000000034 method Methods 0.000 description 6
QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
229910052794 bromium Inorganic materials 0.000 description 4
238000002156 mixing Methods 0.000 description 4
229920000728 polyester Polymers 0.000 description 4
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
239000000539 dimer Substances 0.000 description 3
238000009472 formulation Methods 0.000 description 3
229920005989 resin Polymers 0.000 description 3
239000011347 resin Substances 0.000 description 3
238000005476 soldering Methods 0.000 description 3
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
239000001361 adipic acid Substances 0.000 description 2
235000011037 adipic acid Nutrition 0.000 description 2
LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
238000010586 diagram Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000010292 electrical insulation Methods 0.000 description 2
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
238000003475 lamination Methods 0.000 description 2
239000004843 novolac epoxy resin Substances 0.000 description 2
QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
230000005856 abnormality Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
QEZIKGQWAWNWIR-UHFFFAOYSA-N antimony(3+) antimony(5+) oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[Sb+3].[Sb+5] QEZIKGQWAWNWIR-UHFFFAOYSA-N 0.000 description 1
239000004760 aramid Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000002542 deteriorative effect Effects 0.000 description 1
238000007667 floating Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
210000003127 knee Anatomy 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
238000000465 moulding Methods 0.000 description 1
229920003986 novolac Polymers 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
-1 polypropylene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
238000007639 printing Methods 0.000 description 1
229910000679 solder Inorganic materials 0.000 description 1