JP7781149B2 - 多管式反応器におけるエタノールの脱水素方法 - Google Patents

多管式反応器におけるエタノールの脱水素方法

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Publication number
JP7781149B2
JP7781149B2 JP2023518758A JP2023518758A JP7781149B2 JP 7781149 B2 JP7781149 B2 JP 7781149B2 JP 2023518758 A JP2023518758 A JP 2023518758A JP 2023518758 A JP2023518758 A JP 2023518758A JP 7781149 B2 JP7781149 B2 JP 7781149B2
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effluent
ethanol
feedstock
heat transfer
transfer fluid
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Japanese (ja)
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JP2023542375A (ja
JP2023542375A5 (enExample
Inventor
ジャン－クリストフ ガベル
ヴァンサン クパール
レジャーヌ ダスティルン
ミカエル メジャン
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/065—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/2076—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)- moiety is eliminated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/12—Alkadienes
    • C07C11/16—Alkadienes with four carbon atoms
    • C07C11/167—1, 3-Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/06—Acetaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00539—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1229—Ethanol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2023518758A 2020-09-25 2021-09-13 多管式反応器におけるエタノールの脱水素方法 Active JP7781149B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR2009759A FR3114590B1 (fr) 2020-09-25 2020-09-25 Procédé de deshydrogenation de l’éthanol en reacteur multitubulaire
FR2009759 2020-09-25
PCT/EP2021/075135 WO2022063620A1 (fr) 2020-09-25 2021-09-13 Procédé de deshydrogenation de l'éthanol en reacteur multitubulaire

Publications (3)

Publication Number Publication Date
JP2023542375A JP2023542375A (ja) 2023-10-06
JP2023542375A5 JP2023542375A5 (enExample) 2024-09-24
JP7781149B2 true JP7781149B2 (ja) 2025-12-05

Family

ID=74592052

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2023518758A Active JP7781149B2 (ja) 2020-09-25 2021-09-13 多管式反応器におけるエタノールの脱水素方法

Country Status (10)

Country Link
US (1) US12577187B2 (enExample)
EP (1) EP4217335B1 (enExample)
JP (1) JP7781149B2 (enExample)
KR (1) KR20230074244A (enExample)
CN (1) CN116323539A (enExample)
CA (1) CA3191087A1 (enExample)
FR (1) FR3114590B1 (enExample)
HU (1) HUE071780T2 (enExample)
PL (1) PL4217335T3 (enExample)
WO (1) WO2022063620A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117504733A (zh) * 2023-11-13 2024-02-06 陕西延长石油（集团）有限责任公司 一种乙醇脱氢制乙醛的系统及方法
WO2026085015A1 (en) * 2024-10-14 2026-04-23 Battelle Memorial Institute Method of using hydrogen to extend catalyst life for ethanol to butadiene conversions

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009542772A (ja) 2006-07-11 2009-12-03 ビーエーエスエフ ソシエタス・ヨーロピア アルコールの脱水素法
JP2014523337A (ja) 2011-06-06 2014-09-11 アルケマ フランス インサイチュ注入を用いるプレート式反応器
JP2015061726A (ja) 2007-07-05 2015-04-02 サウディ ベーシック インダストリーズ コーポレイション 吸熱反応を行うプロセス
JP2017532318A (ja) 2014-09-19 2017-11-02 イエフペ エネルジ ヌヴェルＩｆｐ Ｅｎｅｒｇｉｅｓ Ｎｏｕｖｅｌｌｅｓ 低水かつ低エネルギー消費の２反応工程におけるエタノールからのブタジエンおよび水素の製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5227563A (en) 1988-12-26 1993-07-13 Mitsui Petrochemical Industries, Ltd. Preparation of propylene by dehydration of isopropanol in the presence of a pseudo-boehmite derived gamma alumina catalyst
JP6556549B2 (ja) * 2015-08-04 2019-08-07 Ｊｘｔｇエネルギー株式会社 アルデヒドの製造方法及び脱水素触媒
US10851028B2 (en) 2016-09-09 2020-12-01 Total Research & Technology Feluy Process for dehydration of mono-alcohol(s) using a modified crystalline aluminosilicate
JP2018052768A (ja) * 2016-09-28 2018-04-05 富士電機株式会社 水素製造システム起動方法及び水素製造システム
FR3089973B1 (fr) 2018-12-14 2020-12-25 Ifp Energies Now Procédé de déshydratation de l'éthanol en éthylène à basse consommation énergétique
FR3090632B1 (fr) 2018-12-21 2020-12-25 Ifp Energies Now Procédé de production de butadiène à partir d’éthanol avec régénération in situ optimisée du catalyseur de la deuxième étape réactionnelle

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009542772A (ja) 2006-07-11 2009-12-03 ビーエーエスエフ ソシエタス・ヨーロピア アルコールの脱水素法
JP2015061726A (ja) 2007-07-05 2015-04-02 サウディ ベーシック インダストリーズ コーポレイション 吸熱反応を行うプロセス
JP2014523337A (ja) 2011-06-06 2014-09-11 アルケマ フランス インサイチュ注入を用いるプレート式反応器
JP2017532318A (ja) 2014-09-19 2017-11-02 イエフペ エネルジ ヌヴェルＩｆｐ Ｅｎｅｒｇｉｅｓ Ｎｏｕｖｅｌｌｅｓ 低水かつ低エネルギー消費の２反応工程におけるエタノールからのブタジエンおよび水素の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Chemical Engineering Science，1992年，Vol. 47, No. 9-11，2571-2576

Also Published As

Publication number Publication date
WO2022063620A1 (fr) 2022-03-31
US12577187B2 (en) 2026-03-17
KR20230074244A (ko) 2023-05-26
JP2023542375A (ja) 2023-10-06
FR3114590A1 (fr) 2022-04-01
US20230373892A1 (en) 2023-11-23
PL4217335T3 (pl) 2025-09-08
CA3191087A1 (fr) 2022-03-31
FR3114590B1 (fr) 2022-09-09
BR112023005367A2 (pt) 2023-05-09
EP4217335B1 (fr) 2025-03-05
EP4217335A1 (fr) 2023-08-02
CN116323539A (zh) 2023-06-23
HUE071780T2 (hu) 2025-09-28

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