JP7687618B2 - メタンを製造する方法 - Google Patents

メタンを製造する方法 Download PDF

Info

Publication number
JP7687618B2
JP7687618B2 JP2021543805A JP2021543805A JP7687618B2 JP 7687618 B2 JP7687618 B2 JP 7687618B2 JP 2021543805 A JP2021543805 A JP 2021543805A JP 2021543805 A JP2021543805 A JP 2021543805A JP 7687618 B2 JP7687618 B2 JP 7687618B2
Authority
JP
Japan
Prior art keywords
gas
catalyst
reactor
reaction
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2021543805A
Other languages
English (en)
Japanese (ja)
Other versions
JPWO2021045101A1 (https=
Inventor
長寿 福原
雅夫 須藤
弘 赤間
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AMANO INSTITUTE OF TECHNOLOGY
Shizuoka University NUC
Original Assignee
AMANO INSTITUTE OF TECHNOLOGY
Shizuoka University NUC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AMANO INSTITUTE OF TECHNOLOGY, Shizuoka University NUC filed Critical AMANO INSTITUTE OF TECHNOLOGY
Publication of JPWO2021045101A1 publication Critical patent/JPWO2021045101A1/ja
Application granted granted Critical
Publication of JP7687618B2 publication Critical patent/JP7687618B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0438—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being placed next to each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00—Aliphatic saturated hydrocarbons
    • C07C9/02—Aliphatic saturated hydrocarbons with one to four carbon atoms
    • C07C9/04—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00309—Controlling the temperature by indirect heat exchange with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
JP2021543805A 2019-09-03 2020-09-02 メタンを製造する方法 Active JP7687618B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2019160190 2019-09-03
JP2019160190 2019-09-03
PCT/JP2020/033257 WO2021045101A1 (ja) 2019-09-03 2020-09-02 メタンを製造する方法、及び製造システム

Publications (2)

Publication Number Publication Date
JPWO2021045101A1 JPWO2021045101A1 (https=) 2021-03-11
JP7687618B2 true JP7687618B2 (ja) 2025-06-03

Family

ID=74852421

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2021543805A Active JP7687618B2 (ja) 2019-09-03 2020-09-02 メタンを製造する方法

Country Status (6)

Country Link
US (1) US12319633B2 (https=)
EP (1) EP4026822A4 (https=)
JP (1) JP7687618B2 (https=)
KR (1) KR102883858B1 (https=)
CN (1) CN114341083A (https=)
WO (1) WO2021045101A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7291664B2 (ja) * 2020-05-12 2023-06-15 株式会社豊田中央研究所 炭化水素製造装置、および、炭化水素製造方法
AU2022344073B2 (en) * 2021-09-13 2025-04-10 Ihi Corporation Hydrocarbon production equipment, hydrocarbon production system, controller for hydrocarbon production device, and method for producing hydrocarbon
JP2023172767A (ja) * 2022-05-24 2023-12-06 トヨタ自動車株式会社 メタン化触媒の処理方法及びメタンの製造方法並びにメタン化触媒
EP4691639A1 (en) * 2023-03-31 2026-02-11 NGK Insulators, Ltd. Honeycomb structure
WO2025204754A1 (ja) * 2024-03-29 2025-10-02 日本碍子株式会社 メタン製造方法
WO2025204753A1 (ja) * 2024-03-29 2025-10-02 日本碍子株式会社 メタン製造方法
JP2025175543A (ja) * 2024-05-20 2025-12-03 日本特殊陶業株式会社 反応装置

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013515684A (ja) 2009-12-23 2013-05-09 ソーラー フューエル ゲゼルシャフト ミット ベシュレンクテル ハフツング メタンリッチ生成ガスを生成するための方法、およびその目的のために使用可能な反応器システム
JP2015007039A (ja) 2013-06-18 2015-01-15 中国石油化工股▲ふん▼有限公司 コークス炉ガスによりメタノール及び合成天然ガスを同時生産する方法並びに該方法を達成するためのプラント
WO2015159044A1 (en) 2014-04-16 2015-10-22 Johnson Matthey Public Limited Company Process
JP2019155227A (ja) 2018-03-08 2019-09-19 日立化成株式会社 Ｃｏ２メタン化触媒及びこれを用いた二酸化炭素の還元方法
JP2020033280A (ja) 2018-08-28 2020-03-05 国立大学法人静岡大学 メタンを製造する方法、及び製造システム
JP2020037535A (ja) 2018-09-05 2020-03-12 日立化成株式会社 二酸化炭素メタン化システム

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1042366A (en) * 1963-02-11 1966-09-14 Foster Wheeler Ltd Improvements in catalysed exothermic reactions
US3852180A (en) * 1972-02-04 1974-12-03 Skf Ind Trading & Dev Apparatus for co{11 {11 conversion to methane
JPH10185170A (ja) * 1996-12-25 1998-07-14 Ebara Corp 燃焼装置
CN100500551C (zh) 2005-12-05 2009-06-17 西南化工研究设计院 一种用煤层气制备氢气的方法
CN102416324B (zh) * 2011-10-19 2014-03-12 武汉凯迪工程技术研究总院有限公司 二氧化碳甲烷化催化剂及其制备方法和用途
JP2018168205A (ja) 2017-03-29 2018-11-01 株式会社日立製作所 メタン製造方法および設備
JP7052401B2 (ja) 2018-02-20 2022-04-12 株式会社豊田中央研究所 メタン製造装置、および、メタン製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013515684A (ja) 2009-12-23 2013-05-09 ソーラー フューエル ゲゼルシャフト ミット ベシュレンクテル ハフツング メタンリッチ生成ガスを生成するための方法、およびその目的のために使用可能な反応器システム
JP2015007039A (ja) 2013-06-18 2015-01-15 中国石油化工股▲ふん▼有限公司 コークス炉ガスによりメタノール及び合成天然ガスを同時生産する方法並びに該方法を達成するためのプラント
WO2015159044A1 (en) 2014-04-16 2015-10-22 Johnson Matthey Public Limited Company Process
JP2019155227A (ja) 2018-03-08 2019-09-19 日立化成株式会社 Ｃｏ２メタン化触媒及びこれを用いた二酸化炭素の還元方法
JP2020033280A (ja) 2018-08-28 2020-03-05 国立大学法人静岡大学 メタンを製造する方法、及び製造システム
JP2020037535A (ja) 2018-09-05 2020-03-12 日立化成株式会社 二酸化炭素メタン化システム

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
FUKUHARA, Choji et al.，Auto-methanation for transition-metal catalysts loaded on various oxide supports: A novel route for，Chemical Engineering Science，2020年，219，115589
FUKUHARA, Choji et al.，Auto-methanation of Carbon Dioxide: A Novel Route for Transforming CO2 over Ni-based Catalyst，Chemistry Letters，2019年，48(3)，196-199
FUKUHARA, Choji et al.，Auto-methanation Performance of Structured Ni-type Catalyst for CO2 Transformation，Chemistry Letters，2019年，48(5)，441-444
平田 望 外４名，Ru/CeO2触媒によるCO2の auto-methanation，触媒討論会講演予稿集，Vol.125th，2020年，1P27
福原長寿 外５名，室温雰囲気下におけるNi系担持金属触媒上でのCO2の auto-methanation，触媒討論会討論会Ａ予稿集，Vol.124th，2019年，3H09
赤間 弘 外４名，二酸化炭素の auto-methanation における生成水と酸素濃度の及ぼす影響，触媒討論会討論会Ａ予稿集，Vol.124th，2019年，3H11

Also Published As

Publication number Publication date
US20220298086A1 (en) 2022-09-22
EP4026822A1 (en) 2022-07-13
KR102883858B1 (ko) 2025-11-11
JPWO2021045101A1 (https=) 2021-03-11
EP4026822A4 (en) 2023-10-11
KR20220053579A (ko) 2022-04-29
WO2021045101A1 (ja) 2021-03-11
US12319633B2 (en) 2025-06-03
CN114341083A (zh) 2022-04-12

Similar Documents

Publication Publication Date Title
JP7687618B2 (ja) メタンを製造する方法
JP3473898B2 (ja) 水素精製装置
JP7226729B2 (ja) メタンを製造する方法、及び製造システム
CN101605718B (zh) 用于热集成氢生成系统的处理方法和设备
JP2005529824A (ja) 水−気体転化用白金族金属触媒のメタン化活性の抑制
JP4185952B2 (ja) 一酸化炭素除去触媒及びその製造方法並びに一酸化炭素除去装置
JP2006503703A (ja) 非発火性銅−アルミナ触媒の製造方法
JP5702910B2 (ja) Ｐｔ−Ｒｅバイメタル水性ガスシフト触媒の処理条件
EP1485202B1 (en) Process for the preferential oxidation of carbon monoxide using a catalyst containing ruthenium and zinc oxide
CN104159665B (zh) 催化剂、催化剂的制造方法和使用了该催化剂的含氢气体的制造方法、氢发生装置、燃料电池系统、以及负载硅的CeZr系氧化物
JP2005067917A (ja) Ｃｏ除去触媒装置及びｃｏ選択除去方法
TWI501920B (zh) Production method and apparatus for hydrogen
JP4377700B2 (ja) 合成ガス製造用触媒およびこれを用いた合成ガスの製造方法
JP4663095B2 (ja) 水素精製装置
Akama et al. Multi-stage spiral-type structured catalyst system for direct large-scale methanation of industrial CO 2 emissions: a feasibility study
JP4799312B2 (ja) 合成ガス製造触媒
JP3773967B2 (ja) 燃料電池用水素含有ガスの製造方法
WO2025243936A1 (ja) 反応装置
KR101869580B1 (ko) 수소 가스의 제조 방법
JP4209868B2 (ja) 燃料電池用水素含有ガスの製造方法
JP2024092355A (ja) 金属触媒の後処理方法
JP2008024566A (ja) 水素製造方法及び水素製造装置
JP2007320779A (ja) アンモニア合成用素ガスの製造方法および製造装置
TW201500277A (zh) 氫之製造方法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20220204

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20230803

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20241015

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20241213

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20250107

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20250312

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20250317

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20250430

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20250514

R150 Certificate of patent or registration of utility model

Ref document number: 7687618

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150