JP7684981B2 - 遷移金属ビス（フェノラート）触媒錯体を用いて得られるプロピレンコポリマー及びその生成のための均一プロセス - Google Patents

遷移金属ビス（フェノラート）触媒錯体を用いて得られるプロピレンコポリマー及びその生成のための均一プロセス Download PDF

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JP7684981B2
JP7684981B2 JP2022548993A JP2022548993A JP7684981B2 JP 7684981 B2 JP7684981 B2 JP 7684981B2 JP 2022548993 A JP2022548993 A JP 2022548993A JP 2022548993 A JP2022548993 A JP 2022548993A JP 7684981 B2 JP7684981 B2 JP 7684981B2
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JP2023513765A5 (enExample
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ル シエ
ナラヤナスワミ ダーマラジャン
ペイジュン ジアン
ジュン シ
ジョン アール ハガドーン
ジョ アン エム キャニッチ
サラ ジェイ マトラー
アレクサンドラ ケイ ヴァルデス
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エクソンモービル ケミカル パテンツ インコーポレイテッド
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/64141—Dianionic ligand
    • C08F4/64158—ONO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168—Tetra- or multi-dentate ligand
    • C08F4/64186—Dianionic ligand
    • C08F4/64193—OOOO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2022548993A 2020-02-11 2020-08-11 遷移金属ビス（フェノラート）触媒錯体を用いて得られるプロピレンコポリマー及びその生成のための均一プロセス Active JP7684981B2 (ja)

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US202062972962P 2020-02-11 2020-02-11
US62/972,962 2020-02-11
PCT/US2020/045819 WO2021162745A1 (en) 2020-02-11 2020-08-11 Propylene copolymers obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof

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JP2023513765A JP2023513765A (ja) 2023-04-03
JP2023513765A5 JP2023513765A5 (enExample) 2023-08-17
JP7684981B2 true JP7684981B2 (ja) 2025-05-28

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US (1) US20230348640A1 (enExample)
EP (1) EP4103630A4 (enExample)
JP (1) JP7684981B2 (enExample)
KR (1) KR20220139378A (enExample)
CN (1) CN115315453B (enExample)
WO (1) WO2021162745A1 (enExample)

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EP4103628A4 (en) * 2020-02-11 2024-06-12 ExxonMobil Chemical Patents Inc. PROPYLENE POLYMERS WITH TRANSITION METAL (BIS)PHENOLATE CATALYST COMPLEXES AND HOMOGENEOUS PROCESS FOR THEIR PRODUCTION
WO2022076216A1 (en) 2020-10-08 2022-04-14 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
KR20230175305A (ko) * 2021-04-25 2023-12-29 차이나 페트로리움 앤드 케미컬 코포레이션 프로필렌계 공중합체, 이의 제조 공정 및 용도, 및 이를 함유하는 폴리프로필렌 조성물
CA3241034A1 (en) 2021-12-17 2023-06-22 Exxonmobil Chemical Patents Inc. Processes for making propylene-based copolymers having broad cds and mwds
WO2025117332A1 (en) * 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Methods for producing impact copolymers using dianionic complexes containing eight-membered chelate rings
WO2026075864A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymers and processes for production thereof
WO2026075862A1 (en) * 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company High melt strength propylene based elastomers compositions for elastic blown or cast films
WO2026075861A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymers and processes for production thereof
WO2026075865A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymer compositions and films thereof
WO2026075859A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymer blends and roofing membranes thereof

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JP2002519486A (ja) 1998-07-02 2002-07-02 エクソンモービル・ケミカル・パテンツ・インク プロピレン−オレフィンコポリマー
JP2008544003A (ja) 2005-06-13 2008-12-04 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンを共重合するための方法
JP2015013995A (ja) 2007-07-13 2015-01-22 ダウ グローバル テクノロジーズ エルエルシー 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー
JP2022520575A (ja) 2019-02-12 2022-03-31 エクソンモービル ケミカル パテンツ インコーポレイテッド 遷移金属ビス（フェノレート）錯体およびオレフィン重合のための触媒としてのその使用
JP2023513582A (ja) 2020-02-11 2023-03-31 エクソンモービル ケミカル パテンツ インコーポレイテッド 遷移金属ビス（フェノラート）触媒錯体を用いて得られるエチレン－アルファオレフィン－ジエンモノマーのコポリマー及びその生成のための均一プロセス
JP2023513581A (ja) 2020-02-11 2023-03-31 エクソンモービル ケミカル パテンツ インコーポレイテッド 遷移金属ビス（フェノラート）触媒錯体を用いて得られるポリエチレン組成物及びその生成のための均一プロセス

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Publication number Priority date Publication date Assignee Title
JP2002519486A (ja) 1998-07-02 2002-07-02 エクソンモービル・ケミカル・パテンツ・インク プロピレン−オレフィンコポリマー
JP2008544003A (ja) 2005-06-13 2008-12-04 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンを共重合するための方法
JP2015013995A (ja) 2007-07-13 2015-01-22 ダウ グローバル テクノロジーズ エルエルシー 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー
JP2022520575A (ja) 2019-02-12 2022-03-31 エクソンモービル ケミカル パテンツ インコーポレイテッド 遷移金属ビス（フェノレート）錯体およびオレフィン重合のための触媒としてのその使用
JP2023513582A (ja) 2020-02-11 2023-03-31 エクソンモービル ケミカル パテンツ インコーポレイテッド 遷移金属ビス（フェノラート）触媒錯体を用いて得られるエチレン－アルファオレフィン－ジエンモノマーのコポリマー及びその生成のための均一プロセス
JP2023513581A (ja) 2020-02-11 2023-03-31 エクソンモービル ケミカル パテンツ インコーポレイテッド 遷移金属ビス（フェノラート）触媒錯体を用いて得られるポリエチレン組成物及びその生成のための均一プロセス

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EP4103630A4 (en) 2024-06-05
US20230348640A1 (en) 2023-11-02
CN115315453B (zh) 2024-08-30
WO2021162745A1 (en) 2021-08-19
EP4103630A1 (en) 2022-12-21
KR20220139378A (ko) 2022-10-14
JP2023513765A (ja) 2023-04-03
CN115315453A (zh) 2022-11-08

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