KR20220139378A - 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법 - Google Patents

전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법 Download PDF

Info

Publication number
KR20220139378A
KR20220139378A KR1020227031337A KR20227031337A KR20220139378A KR 20220139378 A KR20220139378 A KR 20220139378A KR 1020227031337 A KR1020227031337 A KR 1020227031337A KR 20227031337 A KR20227031337 A KR 20227031337A KR 20220139378 A KR20220139378 A KR 20220139378A
Authority
KR
South Korea
Prior art keywords
borate
tetrakis
alternatively
hydrocarbyl
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020227031337A
Other languages
English (en)
Korean (ko)
Inventor
루 시에
나라야나스와미 다르마라잔
페이준 지앙
준 시
존 알 하가도른
조 앤 엠 캐니치
사라 제이 매틀러
알렉산드라 케이 발데즈
Original Assignee
엑손모빌 케미칼 패턴츠 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엑손모빌 케미칼 패턴츠 인코포레이티드 filed Critical 엑손모빌 케미칼 패턴츠 인코포레이티드
Publication of KR20220139378A publication Critical patent/KR20220139378A/ko
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/64141—Dianionic ligand
    • C08F4/64158—ONO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168—Tetra- or multi-dentate ligand
    • C08F4/64186—Dianionic ligand
    • C08F4/64193—OOOO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020227031337A 2020-02-11 2020-08-11 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법 Pending KR20220139378A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202062972962P 2020-02-11 2020-02-11
US62/972,962 2020-02-11
PCT/US2020/045819 WO2021162745A1 (en) 2020-02-11 2020-08-11 Propylene copolymers obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof

Publications (1)

Publication Number Publication Date
KR20220139378A true KR20220139378A (ko) 2022-10-14

Family

ID=77292754

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020227031337A Pending KR20220139378A (ko) 2020-02-11 2020-08-11 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법

Country Status (6)

Country Link
US (1) US20230348640A1 (enExample)
EP (1) EP4103630A4 (enExample)
JP (1) JP7684981B2 (enExample)
KR (1) KR20220139378A (enExample)
CN (1) CN115315453B (enExample)
WO (1) WO2021162745A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4103628A4 (en) * 2020-02-11 2024-06-12 ExxonMobil Chemical Patents Inc. PROPYLENE POLYMERS WITH TRANSITION METAL (BIS)PHENOLATE CATALYST COMPLEXES AND HOMOGENEOUS PROCESS FOR THEIR PRODUCTION
WO2022076216A1 (en) 2020-10-08 2022-04-14 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
KR20230175305A (ko) * 2021-04-25 2023-12-29 차이나 페트로리움 앤드 케미컬 코포레이션 프로필렌계 공중합체, 이의 제조 공정 및 용도, 및 이를 함유하는 폴리프로필렌 조성물
CA3241034A1 (en) 2021-12-17 2023-06-22 Exxonmobil Chemical Patents Inc. Processes for making propylene-based copolymers having broad cds and mwds
WO2025117332A1 (en) * 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Methods for producing impact copolymers using dianionic complexes containing eight-membered chelate rings
WO2026075864A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymers and processes for production thereof
WO2026075862A1 (en) * 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company High melt strength propylene based elastomers compositions for elastic blown or cast films
WO2026075861A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymers and processes for production thereof
WO2026075865A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymer compositions and films thereof
WO2026075859A1 (en) 2024-10-02 2026-04-09 ExxonMobil Technology and Engineering Company Polypropylene copolymer blends and roofing membranes thereof

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1091984A1 (en) 1998-07-02 2001-04-18 Exxon Chemical Patents Inc. Propylene olefin copolymers
KR100844062B1 (ko) * 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조방법
US6841502B2 (en) * 2002-04-24 2005-01-11 Symyx Technologies, Inc. Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom
WO2006134046A1 (en) 2005-06-13 2006-12-21 Basell Polyolefine Gmbh Process for the copolymerization of propylene
US8569422B2 (en) 2007-07-13 2013-10-29 Dow Global Technologies, Llc Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block
US8674040B2 (en) * 2008-07-25 2014-03-18 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
EP2743000A1 (en) * 2012-12-13 2014-06-18 Basell Poliolefine Italia S.r.l. Catalyst system for the preparation of polyolefins
EP3022236B1 (en) * 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
WO2016153682A1 (en) * 2015-03-24 2016-09-29 Exxonmobil Chemical Patents Inc. Bisphenolate transition metal complexes, production and use thereof
CN107922527A (zh) * 2015-08-31 2018-04-17 埃克森美孚化学专利公司 用于聚烯烃反应的具有悬垂烯烃的铝烷基
KR102121437B1 (ko) * 2016-08-23 2020-06-10 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물
WO2018075245A1 (en) * 2016-10-19 2018-04-26 Exxonmobil Chemical Patents Inc. Mixed catalyst systems and methods of using the same
CN113423744B (zh) * 2019-02-12 2023-05-05 埃克森美孚化学专利公司 路易斯碱催化剂及其方法
EP3924395A4 (en) 2019-02-12 2022-06-22 ExxonMobil Chemical Patents Inc. BIS(ARYL-PHENOLATE) LEWIS-BASED CATALYSTS AND METHODS THEREOF
US11214634B2 (en) * 2019-02-12 2022-01-04 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
US11248070B2 (en) * 2019-02-12 2022-02-15 Exxonmobil Chemical Patents Inc. Lewis base catalysts and methods thereof
US11254763B2 (en) * 2019-02-12 2022-02-22 Exxonmobil Chemical Patents Inc. Transition metal bis(phenolate) complexes and their use as catalysts for olefin polymerization
KR102898201B1 (ko) 2020-02-11 2025-12-09 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 에틸렌-알파-올레핀-디엔 단량체 공중합체 및 그의 균질한 제조 방법
WO2021162748A1 (en) 2020-02-11 2021-08-19 Exxonmobil Chemical Patents Inc. Polyethylene compositions obtained using transition metal bis(phenolate) catalyst complexes and homogeneous process for production thereof

Also Published As

Publication number Publication date
EP4103630A4 (en) 2024-06-05
US20230348640A1 (en) 2023-11-02
JP7684981B2 (ja) 2025-05-28
CN115315453B (zh) 2024-08-30
WO2021162745A1 (en) 2021-08-19
EP4103630A1 (en) 2022-12-21
JP2023513765A (ja) 2023-04-03
CN115315453A (zh) 2022-11-08

Similar Documents

Publication Publication Date Title
JP7684981B2 (ja) 遷移金属ビス（フェノラート）触媒錯体を用いて得られるプロピレンコポリマー及びその生成のための均一プロセス
KR102912885B1 (ko) 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 폴리에틸렌 조성물 및 그의 균질한 제조 방법
KR102510732B1 (ko) 큰 알킬기를 갖는 양이온을 함유한 비배위 음이온형 활성제
JP7242879B2 (ja) 遷移金属ビス（フェノレート）錯体およびオレフィン重合のための触媒としてのその使用
CN109312013A (zh) 茂金属催化剂组合物和使用其的聚合方法
KR20220152223A (ko) 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 중합체 및 그의 균질한 제조 방법
CN112236505A (zh) 具有增强的燃料经济性的作为粘度改性剂的乙烯-丙烯支化共聚物
KR102898201B1 (ko) 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 에틸렌-알파-올레핀-디엔 단량체 공중합체 및 그의 균질한 제조 방법
CN114867758B (zh) 茂金属和其方法
JP7629985B2 (ja) 遷移金属ビス（フェノラート）触媒錯体を使用して得られる環含有ポリマー組成物およびその製造方法
WO2026075865A1 (en) Polypropylene copolymer compositions and films thereof
WO2026075864A1 (en) Polypropylene copolymers and processes for production thereof
WO2026075861A1 (en) Polypropylene copolymers and processes for production thereof
WO2026024944A1 (en) Metallocene catalyst compounds for producing polyolefins
US20200190236A1 (en) Poly(alpha-olefin)s and Methods Thereof
WO2026024926A1 (en) Metallocene catalyst compounds for producing polyolefins

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D21 Rejection of application intended

Free format text: ST27 STATUS EVENT CODE: A-1-2-D10-D21-EXM-PE0902 (AS PROVIDED BY THE NATIONAL OFFICE)

PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11 Amendment of application requested

Free format text: ST27 STATUS EVENT CODE: A-2-2-P10-P11-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

D21 Rejection of application intended

Free format text: ST27 STATUS EVENT CODE: A-1-2-D10-D21-EXM-PE0902 (AS PROVIDED BY THE NATIONAL OFFICE)

PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11 Amendment of application requested

Free format text: ST27 STATUS EVENT CODE: A-2-2-P10-P11-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13 Application amended

Free format text: ST27 STATUS EVENT CODE: A-2-2-P10-P13-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000