JP7616997B2 - 発泡性の、貯蔵安定なポリマービーズ - Google Patents
発泡性の、貯蔵安定なポリマービーズ Download PDFInfo
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- JP7616997B2 JP7616997B2 JP2021532101A JP2021532101A JP7616997B2 JP 7616997 B2 JP7616997 B2 JP 7616997B2 JP 2021532101 A JP2021532101 A JP 2021532101A JP 2021532101 A JP2021532101 A JP 2021532101A JP 7616997 B2 JP7616997 B2 JP 7616997B2
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- Prior art keywords
- beads
- range
- expandable beads
- expandable
- polyethylene
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- 238000002156 mixing Methods 0.000 claims description 10
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- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
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- WDIWAJVQNKHNGJ-UHFFFAOYSA-N trimethyl(propan-2-yl)silane Chemical compound CC(C)[Si](C)(C)C WDIWAJVQNKHNGJ-UHFFFAOYSA-N 0.000 description 1
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
- B29B9/065—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion under-water, e.g. underwater pelletizers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J9/0066—Use of inorganic compounding ingredients
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J9/16—Making expandable particles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/14—Copolymers of propene
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
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| HUE070883T2 (hu) * | 2020-12-28 | 2025-07-28 | Sabic Global Technologies Bv | Nagy folyóképességû termoplasztikus polimer kompozitot tartalmazó, üvegszál erõsítésû termoplasztikus polimer kompozit |
| US20240299232A1 (en) * | 2021-06-23 | 2024-09-12 | Motivo, Inc. | Ambulation aid formed from air-infused particles |
| WO2024204000A1 (ja) * | 2023-03-27 | 2024-10-03 | 株式会社カネカ | ポリプロピレン系発泡粒子、ポリプロピレン系発泡成形体、および、それらの製造方法 |
| TWI896084B (zh) * | 2024-04-17 | 2025-09-01 | 禾義國際包裝材料有限公司 | 球形聚丙烯發泡粒子及精密成型體製備方法 |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000086801A (ja) | 1998-09-14 | 2000-03-28 | Toppan Printing Co Ltd | パルプビーズ及びこれを用いたパルプ成形体 |
| WO2006030946A1 (ja) | 2004-09-13 | 2006-03-23 | Kureha Corporation | 熱発泡性マイクロスフェアー、その製造方法、その使用、それを含む組成物、及び物品 |
| JP2006517238A (ja) | 2002-11-18 | 2006-07-20 | パイロ・テクノロジーズ・リミテッド | フェノール系シンタクチックフォーム組成物 |
| JP2010132860A (ja) | 2008-08-07 | 2010-06-17 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル及び発泡成形体 |
| US20110166242A1 (en) | 2008-09-30 | 2011-07-07 | Yasuhiro Kawaguchi | Masterbatch for foam molding and molded foam |
| JP2016191022A (ja) | 2015-03-31 | 2016-11-10 | 理研ビタミン株式会社 | 発泡樹脂成形体 |
| US20170037214A1 (en) | 2015-08-07 | 2017-02-09 | Hyundai Motor Company | Foamable masterbatch and polyolefin resin composition with excellent expandability and direct metallizing property |
| JP2017061679A (ja) | 2015-09-11 | 2017-03-30 | サンコ・インク・カンパニー・リミテッドSunko Ink Co., Ltd. | 発泡熱可塑性ポリウレタンおよびそのマイクロ波成形品 |
| US20170267817A1 (en) | 2014-08-22 | 2017-09-21 | 3M Innovative Properties Company | Method and composition including thermoplastic particles and hollow microspheres and articles made from them |
| JP2018172543A (ja) | 2017-03-31 | 2018-11-08 | 株式会社カネカ | 発泡性熱可塑性樹脂粒子の製造方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3615972A (en) | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
| US3945956A (en) | 1975-06-23 | 1976-03-23 | The Dow Chemical Company | Polymerization of styrene acrylonitrile expandable microspheres |
| JPH0689168B2 (ja) * | 1986-05-30 | 1994-11-09 | 積水化成品工業株式会社 | 発泡性ポリエチレン系樹脂の製造方法 |
| SE9003600L (sv) | 1990-11-12 | 1992-05-13 | Casco Nobel Ab | Expanderbara termoplastiska mikrosfaerer samt foerfarande foer framstaellning daerav |
| JP3659979B2 (ja) | 1992-04-15 | 2005-06-15 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製法 |
| DE69920664T3 (de) | 1998-01-26 | 2008-09-25 | Kureha Corp. | Expandierbare mikrokugeln und herstellungsverfahren dafür |
| JP4460768B2 (ja) | 1998-02-24 | 2010-05-12 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルとその製造方法及びその利用方法 |
| WO1999046320A1 (en) | 1998-03-13 | 1999-09-16 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microcapsules and method of utilizing the same |
| US7232607B2 (en) | 2000-04-28 | 2007-06-19 | Kureha Corporation | Thermally foamable microsphere and production process thereof |
| US6509384B2 (en) | 2000-04-28 | 2003-01-21 | Akzo Nobel N.V. | Chemical product and method |
| JP5044074B2 (ja) | 2001-06-11 | 2012-10-10 | 株式会社クレハ | 熱発泡性マイクロスフェアー及びその製造方法 |
| EP1592733B1 (en) | 2003-02-11 | 2009-07-08 | Akzo Nobel N.V. | Microspheres |
| US7259189B2 (en) * | 2003-06-12 | 2007-08-21 | Jsp Corporation | Expanded polypropylene resin beads and process for the production thereof |
| US8324286B2 (en) * | 2005-11-21 | 2012-12-04 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expandable microspheres, method for producing the same, and application thereof |
| JP5448459B2 (ja) | 2006-02-10 | 2014-03-19 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 微小球 |
| CN103788502B (zh) * | 2012-10-29 | 2016-05-25 | 中国石油化工股份有限公司 | 一种聚丙烯发泡珠粒成型体及其制备方法 |
| SE541018C2 (en) * | 2014-02-04 | 2019-03-05 | Matsumoto Yushi Seiyaku Kk | Masterbatch comprising heat-expandable microspheres and applications thereof |
| KR102417493B1 (ko) * | 2014-05-23 | 2022-07-05 | 마쓰모토유시세이야쿠 가부시키가이샤 | 열팽창성 미소구, 그 제조 방법 및 용도 |
| KR102418722B1 (ko) * | 2014-11-26 | 2022-07-07 | 마쓰모토유시세이야쿠 가부시키가이샤 | 열팽창성 미소구 및 그 용도 |
| CN205466864U (zh) * | 2016-02-23 | 2016-08-17 | 西华大学 | 一种阻燃剂母粒粗品分离干燥装置 |
| KR102010457B1 (ko) * | 2018-02-13 | 2019-08-13 | 화인케미칼 주식회사 | 저비중 성형 폼 조성물 및 이를 이용한 성형 폼의 제조방법 |
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2019
- 2019-11-20 US US17/299,346 patent/US20220033608A1/en not_active Abandoned
- 2019-11-20 CN CN201980079899.1A patent/CN113166462B/zh active Active
- 2019-11-20 WO PCT/EP2019/081999 patent/WO2020114784A1/en not_active Ceased
- 2019-11-20 JP JP2021532101A patent/JP7616997B2/ja active Active
- 2019-11-20 EP EP19802230.3A patent/EP3898800A1/en active Pending
-
2024
- 2024-11-26 US US18/959,891 patent/US20250084228A1/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000086801A (ja) | 1998-09-14 | 2000-03-28 | Toppan Printing Co Ltd | パルプビーズ及びこれを用いたパルプ成形体 |
| JP2006517238A (ja) | 2002-11-18 | 2006-07-20 | パイロ・テクノロジーズ・リミテッド | フェノール系シンタクチックフォーム組成物 |
| WO2006030946A1 (ja) | 2004-09-13 | 2006-03-23 | Kureha Corporation | 熱発泡性マイクロスフェアー、その製造方法、その使用、それを含む組成物、及び物品 |
| JP2010132860A (ja) | 2008-08-07 | 2010-06-17 | Sekisui Chem Co Ltd | 熱膨張性マイクロカプセル及び発泡成形体 |
| US20110166242A1 (en) | 2008-09-30 | 2011-07-07 | Yasuhiro Kawaguchi | Masterbatch for foam molding and molded foam |
| US20170267817A1 (en) | 2014-08-22 | 2017-09-21 | 3M Innovative Properties Company | Method and composition including thermoplastic particles and hollow microspheres and articles made from them |
| JP2016191022A (ja) | 2015-03-31 | 2016-11-10 | 理研ビタミン株式会社 | 発泡樹脂成形体 |
| US20170037214A1 (en) | 2015-08-07 | 2017-02-09 | Hyundai Motor Company | Foamable masterbatch and polyolefin resin composition with excellent expandability and direct metallizing property |
| JP2017061679A (ja) | 2015-09-11 | 2017-03-30 | サンコ・インク・カンパニー・リミテッドSunko Ink Co., Ltd. | 発泡熱可塑性ポリウレタンおよびそのマイクロ波成形品 |
| JP2018172543A (ja) | 2017-03-31 | 2018-11-08 | 株式会社カネカ | 発泡性熱可塑性樹脂粒子の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3898800A1 (en) | 2021-10-27 |
| JP2022511523A (ja) | 2022-01-31 |
| WO2020114784A1 (en) | 2020-06-11 |
| CN113166462B (zh) | 2023-06-20 |
| CN113166462A (zh) | 2021-07-23 |
| US20220033608A1 (en) | 2022-02-03 |
| US20250084228A1 (en) | 2025-03-13 |
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