JP7459113B2 - 硬質ポリウレタンフォームの製造 - Google Patents
硬質ポリウレタンフォームの製造 Download PDFInfo
- Publication number
- JP7459113B2 JP7459113B2 JP2021539556A JP2021539556A JP7459113B2 JP 7459113 B2 JP7459113 B2 JP 7459113B2 JP 2021539556 A JP2021539556 A JP 2021539556A JP 2021539556 A JP2021539556 A JP 2021539556A JP 7459113 B2 JP7459113 B2 JP 7459113B2
- Authority
- JP
- Japan
- Prior art keywords
- polyether
- hydrocarbon
- composition
- polyalkylsiloxane
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920005830 Polyurethane Foam Polymers 0.000 title claims description 41
- 238000004519 manufacturing process Methods 0.000 title claims description 30
- 239000011496 polyurethane foam Substances 0.000 title claims description 18
- -1 tributene Chemical compound 0.000 claims description 72
- 229920005862 polyol Polymers 0.000 claims description 68
- 229930195733 hydrocarbon Natural products 0.000 claims description 66
- 150000003077 polyols Chemical class 0.000 claims description 64
- 239000000203 mixture Substances 0.000 claims description 60
- 239000006260 foam Substances 0.000 claims description 54
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 40
- 150000002430 hydrocarbons Chemical class 0.000 claims description 38
- 239000004215 Carbon black (E152) Substances 0.000 claims description 31
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 29
- 229920000570 polyether Polymers 0.000 claims description 29
- 239000012948 isocyanate Substances 0.000 claims description 23
- 150000002513 isocyanates Chemical class 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical group FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 claims description 10
- 239000006261 foam material Substances 0.000 claims description 9
- 238000005187 foaming Methods 0.000 claims description 9
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 8
- 125000004429 atom Chemical group 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 230000004888 barrier function Effects 0.000 claims description 4
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims description 4
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1 -dodecene Natural products CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 2
- 229940069096 dodecene Drugs 0.000 claims description 2
- 239000011810 insulating material Substances 0.000 claims description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 2
- LMBMDLOSPKIWAP-UHFFFAOYSA-N embutramide Chemical compound OCCCC(=O)NCC(CC)(CC)C1=CC=CC(OC)=C1 LMBMDLOSPKIWAP-UHFFFAOYSA-N 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 description 23
- 229920002635 polyurethane Polymers 0.000 description 22
- 239000004604 Blowing Agent Substances 0.000 description 20
- 150000001875 compounds Chemical class 0.000 description 16
- 229920000582 polyisocyanurate Polymers 0.000 description 16
- 125000002947 alkylene group Chemical group 0.000 description 15
- 239000011495 polyisocyanurate Substances 0.000 description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- 229920001228 polyisocyanate Polymers 0.000 description 10
- 239000005056 polyisocyanate Substances 0.000 description 10
- 239000000654 additive Substances 0.000 description 9
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 8
- 229920005906 polyester polyol Polymers 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000012774 insulation material Substances 0.000 description 5
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- 239000002612 dispersion medium Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
- 125000005702 oxyalkylene group Chemical group 0.000 description 4
- 125000006353 oxyethylene group Chemical group 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000005057 refrigeration Methods 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 150000004982 aromatic amines Chemical class 0.000 description 3
- 150000001718 carbodiimides Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000004872 foam stabilizing agent Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229920003986 novolac Polymers 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241001425800 Pipa Species 0.000 description 2
- 229920002396 Polyurea Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 238000010538 cationic polymerization reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 239000013518 molded foam Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- ZXHZWRZAWJVPIC-UHFFFAOYSA-N 1,2-diisocyanatonaphthalene Chemical compound C1=CC=CC2=C(N=C=O)C(N=C=O)=CC=C21 ZXHZWRZAWJVPIC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
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- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
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- 125000002015 acyclic group Chemical group 0.000 description 1
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- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
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- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
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- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
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- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
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- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
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- 239000007859 condensation product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
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- 239000010779 crude oil Substances 0.000 description 1
- 125000004966 cyanoalkyl group Chemical group 0.000 description 1
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- 229920000736 dendritic polymer Polymers 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- ILEDWLMCKZNDJK-UHFFFAOYSA-N esculetin Chemical compound C1=CC(=O)OC2=C1C=C(O)C(O)=C2 ILEDWLMCKZNDJK-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000003106 haloaryl group Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 239000004619 high density foam Substances 0.000 description 1
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- 238000011065 in-situ storage Methods 0.000 description 1
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- 150000002576 ketones Chemical class 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004620 low density foam Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920003208 poly(ethylene sulfide) Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005903 polyol mixture Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000002937 thermal insulation foam Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- KVMPUXDNESXNOH-UHFFFAOYSA-N tris(1-chloropropan-2-yl) phosphate Chemical compound ClCC(C)OP(=O)(OC(C)CCl)OC(C)CCl KVMPUXDNESXNOH-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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Description
MaDbTcQd (式1)
に従い、ここで、
Mは、R11R12R13SiO1/2であり、
Dは、R14R15SiO2/2であり、
Tは、R16SiO3/2であり、
Qは、SiO4/2であり、
R11、R12、R13、R14、R15、R16は、1~12個の炭素原子を有する同一のもしくは異なる炭化水素基、またはHであり、ここで、これらの炭化水素基は、ヘテロ原子で置換されていてもよく、
好ましくは、1~8個の炭素原子を有する同一のもしくは異なる炭化水素基、またはHであり、ここで、これらの炭化水素基は、ヘテロ原子で置換されていてもよく、
特に好ましくは、フェニル基、CH3-基、CH3CH2-基、CH2CH-ClCH2CH2CH2-基、およびH-基であり、
a=2~6であり、
b=0~8であり、
c=0~4であり、
d=0~2であるが、
ただし、a+b+c+d<20、好ましくは<15、特に好ましくは<11である。
nは、互いに独立して、0~500、好ましくは1~300、特に2~150であり、
mは、互いに独立して、0~60、好ましくは1~50、特に1~30であり、
pは、互いに独立して、0~10、好ましくは0または>0~5であり、
kは、互いに独立して、0~10、好ましくは0または>0~5であるが、
ただし、式(1)の1分子について、1分子あたりのT単位の平均数ΣkおよびQ単位の平均数Σpは、それぞれ50以下であり、1分子あたりのD単位の平均数Σnは、2000以下であり、1分子あたりのR1を有するシロキシ単位の平均数Σmは、100以下であり、
Rは、互いに独立して、1~20個のC原子を有する、直鎖状、環状または分岐状の、脂肪族または芳香族の、飽和または不飽和炭化水素基の群からの少なくとも1つの基であるが、好ましくはメチル基であり、
R2は、互いに独立して、R1またはRであり、
R1は、Rとは異なり、互いに独立して、有機基および/またはポリエーテル基であり、
好ましくは、R1は、以下の群:
x=0~100、有利には>0、特に1~50であり、
x’=0または1であり、
y=0~100、有利には>0、特に1~50であり、
R6は、互いに独立して、置換されていてもよく、例えばアルキル基、アリール基またはハロアルキルもしくはハロアリール基で置換されている、1~12個のC原子を有するアルキルまたはアリール基であり、1つのR1基および/または式(1)の1つの分子内に、互いに異なる置換基R1が存在することができ、
R7は、互いに独立して、水素基、または1~4個のC原子を有するアルキル基、-C(O)-R8基(ここで、R8は、アルキル基である)、-CH2-O-R6基、アルキルアリール基、例えば、ベンジル基、または-C(O)NH-R6基を表し、
R8は、1~50個、有利には9~45個、好ましくは13~37個のC原子を有する、直鎖状、環状または分岐状の、置換されていてもよい、例えばハロゲンで置換された炭化水素基であり、
R5は、
Gは、以下の式:
zは、0または1であってよく、
ここで、R1は、架橋していてもよく、これは、式(1)の2つまたは3つのシロキサン構造がR1を介して互いに結合していてもよいことを意味し、この場合、R7またはR8は、相応して二官能性基、すなわちR5と同じであり、
R4は、互いに独立して、R、R1および/またはヘテロ原子で置換された、官能化された、飽和または不飽和の有機基であってよく、これらは、アルキル基、アリール基、クロロアルキル基、クロロアリール基、フルオロアルキル基、シアノアルキル基、アクリルオキシアリール基、アクリルオキシアルキル基、メタクリルオキシアルキル基、メタクリルオキシプロピル基、またはビニル基の群から選択されるが、
ただし、R1、R2、およびR4のうちの少なくとも1つの置換基は、Rと同じではない。
R1は、同じかまたは異なって、
R2は、同じかまたは異なって、-CH3、またはR1であり、
n+m+2=10~150、有利には25~120であり、
m=0~25、有利には0.5~15であり、
w=2~10、有利には3であり、
x+y=1~30、有利には5~25であり、
R6は、同じかまたは異なって、-CH3、-CH2CH3、またはフェニル基であり、
R5は、同じかまたは異なって、H、アルキル基、またはアシル基であり、有利には、-H、-CH3、または-COCH3であり、
ここで、x+yが3より大きい基が少なくとも1つ含まれている必要がある。
a)式3[式中、c+d>0.5である]のPASと、式5[式中、商n/mは、少なくとも4であり、有利には6より大きく、特に好ましくは7より大きい]のPESとの組合せ、
b)式3[式中、c+d>0.5である]のPASと、式5[式中、統計的平均で、シロキサンの総平均モル質量の最大で50%、好ましくは最大で45%、特に好ましくは最大で40%を、シロキサン中の、異なっていてもよいすべてのR1基の合計モル質量が占めている]のPESとの組合せ、
c)式3[式中、c+d>0.5である]のPASと、式5[式中、ポリオキシアルキレン鎖は、その末端に水素またはメチル基を有し、それと同時にオキシエチレン単位のモル分率は、オキシアルキレン単位の最大で70%を占め、すなわちx/(x+y)<0.7であり、かつR5は、水素またはメチル基を表す]のPESとの組合せ、
d)式3[式中、c+d<0.5、特に好ましくはc+d<0.1である]のPASと、式5[式中、商n/mは、少なくとも4であり、有利には6より大きく、特に好ましくは7より大きい]のPESとの組合せ、
e)式3[式中、c+d<0.5、特に好ましくはc+d<0.1である]のPASと、式5[式中、統計的平均で、シロキサンの総平均モル質量の最大で50%、好ましくは最大で45%、特に好ましくは最大で40%を、シロキサン中の、異なっていてもよいすべてのR1基の合計モル質量が占めている]のPESとの組合せ、
または
f)式3[式中、c+d<0.5、特に好ましくはc+d<0.1である]のPASと、式5[式中、ポリオキシアルキレン鎖は、その末端に水素またはメチル基を有し、それと同時にオキシエチレン単位のモル分率は、オキシアルキレン単位の最大で70%を占め、すなわちx/(x+y)<0.7であり、かつR5は、水素またはメチル基を表す]のPESとの組合せ。
a)少なくとも1つのイソシアネート反応性成分、特にポリオール、
b)少なくとも1つのポリイソシアネートおよび/またはポリイソシアネートプレポリマー、
c)(任意に)ポリオールa)およびb)とイソシアネートc)との反応を加速あるいは制御する触媒、
d)本発明による炭化水素HCとポリエーテル修飾シロキサンと任意のポリアルキルシロキサンとの混合物、
e)1つ以上の発泡剤、
f)さらなる添加剤、フィラー、難燃剤など。
中国特許出願公開第103665385号明細書、中国特許出願公開第103657518号明細書、中国特許出願公開第103055759号明細書、中国特許出願公開第103044687号明細書、米国特許出願公開第2008/0125503号明細書、米国特許出願公開第2015/0057384号明細書、欧州特許出願公開第1520870号明細書、欧州特許出願公開第1211279号明細書、欧州特許出願公開第0867464号明細書、欧州特許出願公開第0867465号明細書、欧州特許出願公開第0275563号明細書。上述のこれらの文献は、参照により援用され、本発明の開示内容の一部を成す。
ポリエーテル修飾シロキサン(PES)として、以下の材料を使用した。
国際公開第2011/012390号、例5に記載されているPES No.2
欧州特許出願公開第1544235号明細書、例14に記載されているPES No.3。
Stepanpol PS 2412:Stepan社製ポリエステルポリオール
Terate HT 5511:Invista社製ポリエステルポリオール
TCPP:Fyrol社製トリス(2-クロロイソプロピル)ホスフェート
Kosmos 75、Evonik Nutrition & Care GmbH製、オクタン酸カリウムベースの触媒
Polycat 5、Evonik Nutrition & Care GmbH製、アミン触媒
MDI (44V20):Desmodur 44V20L、Covestro社製、異性体および多官能性ホモログを有するジフェニルメタン 4,4’-ジイソシアネート(MDI)。
発泡を、手動混合法によって行った。このために、本発明による化合物、ポリオール、難燃剤、触媒、水、本発明によるまたは本発明によらないシロキサン界面活性剤、本発明による炭化水素、および任意のポリアルキルシロキサン、ならびに発泡剤をビーカーに量り入れ、ディスク型撹拌子(直径6cm)を用いて1000rpmで30秒間混合した。混合過程で蒸発した発泡剤の量を再秤量によって求め、補充した。次いでイソシアネート(MDI)を加え、反応混合物を、記載された撹拌子を用いて3000rpmで5秒間撹拌した。
Claims (15)
- 硬質ポリウレタンフォームを製造するための組成物であって、前記組成物は、少なくとも1つのイソシアネート成分と、ポリオール成分と、任意に、ウレタン結合またはイソシアヌレート結合の形成を触媒する触媒と、任意に発泡剤と、任意にポリアルキルシロキサンとを含み、前記組成物は、標準圧力で>100℃の沸点を有する炭化水素HCと、ポリエーテル修飾シロキサンとをさらに含み、前記炭化水素HCは、デセン、ドデセン、ドデカン、テトラデカン、トリブテン、トリブタン、テトラブテン、テトラブタン、少なくとも10個の炭素原子を有するアルキルベンゼンおよび/またはオキソ油であり、前記炭化水素HCは、1:5~1:200の重量比でポリエーテル修飾シロキサンと組み合わせて使用され、かつ、ポリオール成分100重量部に対する、炭化水素HCとポリエーテル修飾シロキサンと任意のポリアルキルシロキサンとの総量の重量割合は、0.1~10pphpである、組成物。
- 前記組成物は、ポリアルキルシロキサンをさらに含み、前記ポリアルキルシロキサンは、前記ポリエーテル修飾シロキサンに対して、1:5~1:200の重量比で使用される、請求項1記載の組成物。
- 前記ポリアルキルシロキサンは、20個未満のSi原子を含む、請求項2記載の組成物。
- 前記ポリアルキルシロキサンは、式(1):
MaDbTcQd (式1)
を満たし、ここで、
Mは、R11R12R13SiO1/2であり、
Dは、R14R15SiO2/2であり、
Tは、R16SiO3/2であり、
Qは、SiO4/2であり、
R11、R12、R13、R14、R15、R16は、1~12個の炭素原子を有する同一のもしくは異なる炭化水素基、またはHであり、ここで、前記炭化水素基は、ヘテロ原子で置換されていてもよく、
a=2~6であり、
b=0~8であり、
c=0~4であり、
d=0~2であるが、
ただし、a+b+c+d<20である、請求項1から3までのいずれか1項記載の組成物。 - c+d>0.5である、請求項4記載の組成物。
- d=0でかつc>0.5である、請求項4または5記載の組成物。
- c+d<0.5である、請求項4記載の組成物。
- R16は、R11、R12、R13、R14およびR15とは異なり、
かつ/または
R11、R12およびR13は異なる、請求項4から7までのいずれか1項記載の組成物。 - 1つ以上のポリオール成分と1つ以上のイソシアネート成分との反応による硬質ポリウレタンフォームの製造方法であって、前記反応を、炭化水素HCと、ポリエーテル修飾シロキサンと、任意にポリアルキルシロキサンとの存在下で、請求項1記載の組成物を使用して行うことを特徴とする、方法。
- 前記炭化水素HCと、ポリエーテル修飾シロキサンと、任意のポリアルキルシロキサンとの成分を、硬質PUフォームの製造のために反応混合物に別個にまたは一緒に供給する、請求項9記載の方法。
- 硬質ポリウレタン発泡物質を製造するための、請求項1記載の組成物を使用した、炭化水素HCと、ポリエーテル修飾シロキサンと、任意のポリアルキルシロキサンとの組合せ物の使用。
- 泡安定剤としての、請求項11記載の使用。
- 前記発泡物質の断熱特性を改善するための、請求項11記載の使用。
- 遮断板および/または断熱材としての、請求項9または10記載の方法によって得られる、硬質ポリウレタン発泡物質の使用。
- 冷却装置への、請求項14記載の使用。
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002003565A (ja) | 2000-06-20 | 2002-01-09 | Lion Corp | 硬質ポリウレタンフォーム用ポリオール組成物 |
JP2005171102A (ja) | 2003-12-11 | 2005-06-30 | Inoac Corp | 難燃性シール材 |
JP2007186551A (ja) | 2006-01-11 | 2007-07-26 | Toyo Tire & Rubber Co Ltd | 硬質ポリウレタンフォーム用ポリオール組成物及び硬質ポリウレタンフォームの製造方法 |
JP2008169368A (ja) | 2006-12-11 | 2008-07-24 | Bekku Kk | ポリオール組成物及び硬質ポリウレタンフォームの製造方法 |
JP2008168281A (ja) | 2006-09-07 | 2008-07-24 | Bekku Kk | 硬質ポリウレタンフォームの形成方法 |
JP2009046652A (ja) | 2006-12-05 | 2009-03-05 | Bekku Kk | ポリオール組成物 |
WO2010073651A1 (ja) | 2008-12-24 | 2010-07-01 | 旭有機材工業株式会社 | ポリウレタンフォーム用発泡性組成物及びポリウレタンフォーム |
JP2012001574A (ja) | 2010-06-14 | 2012-01-05 | Bekku Kk | ポリオール組成物 |
Family Cites Families (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1085037A (en) * | 1963-11-09 | 1967-09-27 | Mitsui Chemical Ind Co Ltd | Process for producing semi-rigid polyurethane foam |
US3953383A (en) | 1972-07-21 | 1976-04-27 | Nippon Oil Seal Industry Co., Ltd. | Catalytic process for copolymerizing epoxy compounds with carbon dioxide |
US3900424A (en) | 1972-07-21 | 1975-08-19 | Nippon Oil Seal Ind Co Ltd | Catalyst for copolymerizing epoxy compounds with carbon dioxide |
CH597270A5 (ja) | 1974-08-30 | 1978-03-31 | Goldschmidt Ag Th | |
DE3215317C1 (de) | 1982-04-23 | 1983-06-09 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Herstellung hochelastischer kalthaertender Polyurethanschaumstoffe |
DE3234462C1 (de) | 1982-09-17 | 1984-01-05 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Herstellung hochelastischer kalthaertender Polyurethanschaumstoffe |
US4500704A (en) | 1983-08-15 | 1985-02-19 | The Dow Chemical Company | Carbon dioxide oxirane copolymers prepared using double metal cyanide complexes |
DE3626297C1 (de) | 1986-08-02 | 1987-07-09 | Goldschmidt Ag Th | Verfahren zur Herstellung hochelastischer,kalthaertender Polyurethanschaumstoffe |
JPS63172737A (ja) | 1986-12-31 | 1988-07-16 | ユニオン・カーバイド・コーポレーシヨン | ポリシロキサン―ポリオキシアルキレン化合物 |
US4751251A (en) * | 1987-05-19 | 1988-06-14 | Dow Corning Corporation | Surfactant composition for rigid urethane and isocyanurate foams |
JPS6431347A (en) | 1987-07-27 | 1989-02-01 | Shin Kobe Electric Machinery | Sealed lead storage battery |
DE3933335C2 (de) | 1989-10-06 | 1998-08-06 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen mit geringer Wärmeleitfähigkeit und ihre Verwendung |
US5104904A (en) * | 1990-04-23 | 1992-04-14 | Crowley Chemical Co. | Use of aromatic petroleum oils as surfactant for polyurethane foams |
JPH05247163A (ja) | 1991-09-20 | 1993-09-24 | Union Carbide Chem & Plast Technol Corp | ヒドロクロロフルオロカーボン類を用いて発泡させた硬質ポリウレタンフオームを製造するためのキヤツプされた界面活性剤の使用 |
US5169872A (en) | 1992-05-11 | 1992-12-08 | Dow Corning Corporation | Process for preparing rigid polyurethane and polyisocyanurate foams having enhanced benefits |
JPH06145280A (ja) * | 1992-10-23 | 1994-05-24 | Nisshinbo Ind Inc | 変性ポリイソシアヌレート発泡体の製造法 |
ATE169039T1 (de) * | 1993-02-10 | 1998-08-15 | Bayer Ag | Verfahren zur herstellung von schaumstoffen auf isocyanatbasis |
JP3061717B2 (ja) * | 1993-12-03 | 2000-07-10 | 日清紡績株式会社 | 変性ポリイソシアヌレート発泡体の製造法 |
DE4409043A1 (de) * | 1994-03-17 | 1995-09-21 | Bayer Ag | Verfahren zur Herstellung von gegebenenfalls zellförmigen Polyurethanen |
DE4409042A1 (de) * | 1994-03-17 | 1995-09-21 | Bayer Ag | Verfahren zur Herstellung von gegebenenfalls zellförmigen Polyurethanen und/oder Polyurethanharnstoffen |
JPH07304894A (ja) * | 1994-05-12 | 1995-11-21 | Nippon Unicar Co Ltd | 有機界面活性剤変性オルガノポリシロキサン化合物からなる硬質ポリウレタンフォーム用整泡剤 |
DE4444898C1 (de) | 1994-12-16 | 1996-10-10 | Goldschmidt Ag Th | Verfahren zur Herstellung von Polyurethankaltschäumen |
JPH09165427A (ja) | 1995-12-14 | 1997-06-24 | Mitsui Toatsu Chem Inc | 硬質ポリウレタンフォーム及びその製造方法 |
US5990187A (en) | 1997-03-26 | 1999-11-23 | Th. Goldschmidt Ag | Method of preparing polyurethane foam utilizing organofunctionally modified polysiloxanes |
US5844010A (en) | 1997-03-29 | 1998-12-01 | Th. Goldschmidt Ag | Method of preparing polyurethane foam utilizing block copolymers having linked siloxane blocks |
US5883142A (en) | 1997-05-08 | 1999-03-16 | Air Products And Chemicals, Inc. | Silicone surfactants for rigid polyurethane foam made with third generation blowing agents |
US5852065A (en) * | 1998-01-15 | 1998-12-22 | Air Products And Chemicals, Inc. | Low emission, cell opening surfactants for polyurethane flexible and rigid foams |
DE19905989A1 (de) | 1999-02-13 | 2000-08-17 | Bayer Ag | Feinzellige, wassergetriebene Polyurethanhartschaumstoffe |
US6133329A (en) | 1999-03-31 | 2000-10-17 | Oxid L.P. | Aromatic polyester polyols made from a natural oil |
US6239186B1 (en) | 1999-10-28 | 2001-05-29 | Air Products And Chemicals, Inc. | Silicone surfactants for the production of open cell polyurethane flexible foams |
AU764900B2 (en) | 2000-11-28 | 2003-09-04 | Evonik Goldschmidt Gmbh | Use of mixtures of organofunctionally modified polysiloxanes with branched alcohols in the production of flexible polyurethane foams |
US20020103091A1 (en) | 2001-01-29 | 2002-08-01 | Kodali Dharma R. | Reactive oil compositions and uses thereof |
DE10220799A1 (de) | 2002-05-10 | 2003-12-11 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von C13-Alkoholgemischen |
DE10240186A1 (de) | 2002-08-28 | 2004-03-11 | Basf Ag | Verfahren zur Herstellung von emissionsarmen Polyurethan-Weichschaumstoffen |
US8133930B2 (en) | 2003-04-25 | 2012-03-13 | Dow Global Technologies Llc | Polyurethane foams made from hydroxymethyl-containing polyester polyols |
ATE388177T1 (de) | 2003-04-25 | 2008-03-15 | Dow Global Technologies Inc | Auf pflanzenöl basierende polyole und verfahren zu seiner herstellung |
US8293808B2 (en) | 2003-09-30 | 2012-10-23 | Cargill, Incorporated | Flexible polyurethane foams prepared using modified vegetable oil-based polyols |
DE50302270D1 (de) | 2003-10-04 | 2006-04-13 | Goldschmidt Gmbh | Verfahren zur Herstellung von organischen Siliciumverbindungen |
US7183330B2 (en) * | 2003-12-15 | 2007-02-27 | Air Products And Chemicals, Inc. | Silicone surfactants for rigid polyurethane foam made with hydrocarbon blowing agents |
DE102004011559A1 (de) | 2004-03-08 | 2005-09-29 | Rathor Ag | Phasenstabile Polyurethanprepolymere |
US7989647B2 (en) | 2005-03-03 | 2011-08-02 | South Dakota Soybean Processors, Llc | Polyols derived from a vegetable oil using an oxidation process |
US20060229375A1 (en) | 2005-04-06 | 2006-10-12 | Yu-Ling Hsiao | Polyurethane foams made with alkoxylated vegetable oil hydroxylate |
US20060235100A1 (en) | 2005-04-13 | 2006-10-19 | Kaushiva Bryan D | Polyurethane foams made with vegetable oil hydroxylate, polymer polyol and aliphatic polyhydroxy alcohol |
JP2008539314A (ja) | 2005-04-25 | 2008-11-13 | カーギル インコーポレイテッド | オリゴマーポリオールを含むポリウレタン発泡体 |
US20070066697A1 (en) | 2005-08-31 | 2007-03-22 | Gilder Stephen D | Strut-reinforced polyurethane foam |
US9856355B2 (en) | 2005-09-27 | 2018-01-02 | Evonik Degussa Gmbh | Silanol-functionalized compounds for the preparation of polyurethane foams |
DE102006030531A1 (de) | 2006-07-01 | 2008-01-03 | Goldschmidt Gmbh | Siliconstabilisatoren für flammgeschützte Polyurethan- bzw. Polyisocyanurat-Hartschaumstoffe |
WO2008058913A1 (de) | 2006-11-15 | 2008-05-22 | Basf Se | Verfahren zur herstellung von polyurethan-weichschaumstoffen |
US20100240860A1 (en) | 2007-11-01 | 2010-09-23 | Cargill, Incorporated | Natural oil-derived polyester polyols and polyurethanes made therefrom |
DE102008007081B4 (de) | 2008-01-31 | 2018-12-06 | Evonik Degussa Gmbh | Verfahren zur Herstellung von n-Buten-Oligomeren und 1-Buten aus technischen Mischungen I von C4-Kohlenwasserstoffen |
GB0807607D0 (en) | 2008-04-25 | 2008-06-04 | Imp Innovations Ltd | Catalyst |
KR20200028511A (ko) | 2008-09-08 | 2020-03-16 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리카보네이트 폴리올 조성물 |
CN101880452B (zh) | 2009-05-08 | 2012-07-04 | 深圳先进技术研究院 | 具有调温功能的高分子复合纳米材料 |
DE102009028061A1 (de) | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
US20110218259A1 (en) | 2010-03-02 | 2011-09-08 | Basf Se | Preparing polyurethanes |
WO2011163133A1 (en) | 2010-06-20 | 2011-12-29 | Novomer, Inc. | Aliphatic polycarbonates |
DE102010063241A1 (de) | 2010-12-16 | 2012-06-21 | Evonik Goldschmidt Gmbh | Siliconstabilisatoren für Polyurethan- oder Polyisocyanurat-Hartschaumstoffe |
DE102010063237A1 (de) | 2010-12-16 | 2012-06-21 | Evonik Goldschmidt Gmbh | Siliconstabilisatoren für Polyurethan- oder Polyisocyanurat-Hartschaumstoffe |
KR101983007B1 (ko) | 2011-08-08 | 2019-09-10 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리머 합성용 촉매 및 방법 |
CN103044687B (zh) | 2012-12-21 | 2015-03-11 | 江苏美思德化学股份有限公司 | 一种含氟有机硅聚醚共聚物及其制备方法 |
CN103055759A (zh) | 2012-12-21 | 2013-04-24 | 南京美思德新材料有限公司 | 一种兼有稳泡和开孔性能的聚氨酯泡沫有机硅表面活性剂 |
DE102013212481A1 (de) | 2013-06-27 | 2014-12-31 | Evonik Industries Ag | Oligomerisierung von C4-Strömen mit geringstem Gehalt an 1-Buten |
CN103657518B (zh) | 2013-12-16 | 2015-11-04 | 南京美思德新材料有限公司 | 一种非离子有机硅表面活性剂及其制备方法 |
CN103665385B (zh) | 2013-12-16 | 2016-03-02 | 江苏美思德化学股份有限公司 | 一种含烯酸酯有机硅聚醚共聚物及其制备方法 |
CN105873994B (zh) * | 2013-12-30 | 2019-08-16 | 赢创德固赛有限公司 | 适用于制备硬质聚氨酯或聚异氰脲酸酯泡沫的组合物 |
DE102014209536A1 (de) | 2014-05-20 | 2015-11-26 | Evonik Degussa Gmbh | Herstellung qualitativ hochwertiger Oxo-Alkohole aus unsteten Rohstoffquellen |
PT3310835T (pt) | 2015-06-18 | 2022-09-20 | Basf Se | Processo para a produção de espumas rígidas de poliuretano |
CA3028512A1 (en) * | 2016-06-23 | 2017-12-28 | Evonik Degussa Gmbh | Composition suitable for production of rigid polyurethane or polyisocyanurate foams |
CN107312321B (zh) * | 2017-07-31 | 2019-01-25 | 陕西理工大学 | 一种发泡的tpu复合相变储能材料及其制备方法 |
-
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Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002003565A (ja) | 2000-06-20 | 2002-01-09 | Lion Corp | 硬質ポリウレタンフォーム用ポリオール組成物 |
JP2005171102A (ja) | 2003-12-11 | 2005-06-30 | Inoac Corp | 難燃性シール材 |
JP2007186551A (ja) | 2006-01-11 | 2007-07-26 | Toyo Tire & Rubber Co Ltd | 硬質ポリウレタンフォーム用ポリオール組成物及び硬質ポリウレタンフォームの製造方法 |
JP2008168281A (ja) | 2006-09-07 | 2008-07-24 | Bekku Kk | 硬質ポリウレタンフォームの形成方法 |
JP2009046652A (ja) | 2006-12-05 | 2009-03-05 | Bekku Kk | ポリオール組成物 |
JP2008169368A (ja) | 2006-12-11 | 2008-07-24 | Bekku Kk | ポリオール組成物及び硬質ポリウレタンフォームの製造方法 |
WO2010073651A1 (ja) | 2008-12-24 | 2010-07-01 | 旭有機材工業株式会社 | ポリウレタンフォーム用発泡性組成物及びポリウレタンフォーム |
JP2012001574A (ja) | 2010-06-14 | 2012-01-05 | Bekku Kk | ポリオール組成物 |
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CA3125572A1 (en) | 2020-07-16 |
US20220041829A1 (en) | 2022-02-10 |
EP3677610A1 (de) | 2020-07-08 |
ES2898877T3 (es) | 2022-03-09 |
WO2020144004A1 (de) | 2020-07-16 |
KR20210112351A (ko) | 2021-09-14 |
CN113272353A (zh) | 2021-08-17 |
BR112021013187A2 (pt) | 2021-09-28 |
JP2022516371A (ja) | 2022-02-25 |
PL3677610T3 (pl) | 2022-01-31 |
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CN113272353B (zh) | 2023-05-02 |
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