JP7454039B2 - 化学的に相溶化したフルオロポリマーブレンド - Google Patents
化学的に相溶化したフルオロポリマーブレンド Download PDFInfo
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- JP7454039B2 JP7454039B2 JP2022511123A JP2022511123A JP7454039B2 JP 7454039 B2 JP7454039 B2 JP 7454039B2 JP 2022511123 A JP2022511123 A JP 2022511123A JP 2022511123 A JP2022511123 A JP 2022511123A JP 7454039 B2 JP7454039 B2 JP 7454039B2
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- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
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- 239000000446 fuel Substances 0.000 description 1
- 125000003838 furazanyl group Chemical group 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000003505 heat denaturation Methods 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 125000004404 heteroalkyl group Chemical group 0.000 description 1
- NDNPFWOOAFWTAI-UHFFFAOYSA-N hexazinc;tetraborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] NDNPFWOOAFWTAI-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
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- 150000003949 imides Chemical class 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 125000004926 indolenyl group Chemical group 0.000 description 1
- 125000003387 indolinyl group Chemical group N1(CCC2=CC=CC=C12)* 0.000 description 1
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- 125000001041 indolyl group Chemical group 0.000 description 1
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- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
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- 230000003993 interaction Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000004936 isatinoyl group Chemical group N1(C(=O)C(=O)C2=CC=CC=C12)C(=O)* 0.000 description 1
- 125000001977 isobenzofuranyl group Chemical group C=1(OC=C2C=CC=CC12)* 0.000 description 1
- 125000003384 isochromanyl group Chemical group C1(OCCC2=CC=CC=C12)* 0.000 description 1
- 125000005438 isoindazolyl group Chemical group 0.000 description 1
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- 125000002183 isoquinolinyl group Chemical group C1(=NC=CC2=CC=CC=C12)* 0.000 description 1
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- 125000004932 phenoxathinyl group Chemical group 0.000 description 1
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- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
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- 125000003072 pyrazolidinyl group Chemical group 0.000 description 1
- 125000002755 pyrazolinyl group Chemical group 0.000 description 1
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- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
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- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
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- 230000009257 reactivity Effects 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
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- 235000010339 sodium tetraborate Nutrition 0.000 description 1
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- 239000007787 solid Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
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- 239000000758 substrate Substances 0.000 description 1
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Description
α=(1/L0)(ΔL/ΔT)
式中、L0は25℃におけるサンプルの初期高さを表す。ΔLは高さの変化(ミクロン;μm)を表す。ΔTは、温度の変化(摂氏;℃)を表す。いずれのサンプルも、温度変化(ΔT)が摂氏5度となった時点で測定した。特に言及しない限り、報告した値はいずれも射出成形サンプルのZ方向(厚さ)におけるものである。
本発明に係る開示した実施形態における所定の要素は、単一の構造、単一の工程、又は単一の物質等において実施できることが理解できるであろう。同様に、開示した実施形態における所定の要素は、複数の構造、工程、又は物質等で実施できる。
Claims (19)
- (a)フルオロポリマー、
(b)相溶化剤、及び
(c)ポリエーテルイミド(PEI)又はポリイミド(PI)
を含み、
前記フルオロポリマーは、フッ素化エチレンプロピレン(FEP)、パーフルオロアルコキシアルカン(PFA)、エチレンテトラフルオロエチレン(ETFE)、並びに、エチレン、テトラフルオロエチレン、及び、ヘキサフルオロプロピレンのターポリマー(EFEP)からなる群より選択されるフルオロポリマーであり、
前記相溶化剤は、反応性ポリマー相溶化剤及び/又はビス(オキサゾリン)化合物であり、
前記反応性ポリマー相溶化剤は、官能基化フルオロポリマー、多官能アミン、及び多官能無水物をブレンドして形成されたものであるポリマーアロイ組成物。 - 前記フルオロポリマーはPFAである、請求項1に記載のポリマーアロイ組成物。
- 前記相溶化剤は反応性ポリマー相溶化剤である、請求項1に記載のポリマーアロイ組成物。
- 前記相溶化剤はビス(オキサゾリン)化合物である、請求項1に記載のポリマーアロイ組成物。
- 前記相溶化剤は、反応性ポリマー相溶化剤及びビス(オキサゾリン)化合物を含む、請求項1に記載のポリマーアロイ組成物。
- 前記相溶化剤は1,4-ビス(4,5-ジヒドロ-2-オキサゾリル)ベンゼンである、請求項1に記載のポリマーアロイ組成物。
- 前記ポリイミドは溶融加工性熱可塑性ポリイミド(TPI)である、請求項1に記載のポリマーアロイ組成物。
- ナノ粒子を更に含む、請求項1に記載のポリマーアロイ組成物。
- 70~85重量%のPFA、5~20重量%の反応性ポリマー相溶化剤、及び5~20重量%のPEI又はPIを含む、請求項1に記載のポリマーアロイ組成物。
- 70~75重量%のPFA、10~15重量%の反応性ポリマー相溶化剤、10~15重量%のPIを含み、0.1~0.3重量%のビス(オキサゾリン)及び0.1~0.4重量%のナノ粒子を更に含み、
ポリマーアロイ組成物の全成分についての含有量の合計が100重量%である請求項1に記載のポリマーアロイ組成物。 - 前記相溶化剤は、せん断PFA、4,4’-(ヘキサフルオロイソプロピリデン)ジフタル酸無水物、4,4’-オキシジアニリン、及びPEI-アミンを含む、請求項1に記載のポリマーアロイ組成物。
- 前記相溶化剤は、75~85重量%のせん断PFA、2.5~3.5重量%の4,4’-(ヘキサフルオロイソプロピリデン)ジフタル酸無水物、1.2~1.7重量%の4,4’-オキシジアニリン、及び10~15重量%のPEI-アミンを含む、請求項1に記載のポリマーアロイ組成物。
- 前記ポリマーアロイ組成物は、最大引張強度が20~35MPaである、請求項1に記載のポリマーアロイ組成物。
- 前記ポリマーアロイ組成物は、100℃におけるZ方向の熱膨張率が115~145(μm/m-C)である、請求項1に記載のポリマーアロイ組成物。
- 前記ポリマーアロイ組成物は、150℃におけるZ方向の熱膨張率が150(μm/m-C)未満である、請求項1に記載のポリマーアロイ組成物。
- 前記ポリマーアロイ組成物は、100℃における貯蔵弾性率が200~350MPaである、請求項1に記載のポリマーアロイ組成物。
- 前記ポリマーアロイ組成物は、150℃における貯蔵弾性率が150~250MPaである、請求項1に記載のポリマーアロイ組成物。
- (a)フルオロポリマー、及び
(b)反応性ポリマー相溶化剤
を含むポリマーアロイ組成物であって、
前記反応性ポリマー相溶化剤は、1~5重量%のジアミン、10~15重量%のポリエーテルイミド-アミン、及び1~10重量%の二無水物を含み、
前記フルオロポリマーは、フッ素化エチレンプロピレン(FEP)、パーフルオロアルコキシアルカン(PFA)、エチレンテトラフルオロエチレン(ETFE)、並びに、エチレン、テトラフルオロエチレン、及び、ヘキサフルオロプロピレンのターポリマー(EFEP)からなる群より選択されるフルオロポリマーである、
ポリマーアロイ組成物。 - 官能基化フルオロポリマー、多官能アミン、及び多官能無水物をブレンドして、反応性ポリマー相溶化剤を形成する工程、及び
前記反応性ポリマー相溶化剤を、非官能基化フルオロポリマー、ポリマー、及びビス(オキサゾリン)化合物とブレンドして、熱可塑性アロイを形成する工程、
を有し、
前記非官能基化フルオロポリマーは、フッ素化エチレンプロピレン(FEP)、パーフルオロアルコキシアルカン(PFA)、エチレンテトラフルオロエチレン(ETFE)、並びに、エチレン、テトラフルオロエチレン、及び、ヘキサフルオロプロピレンのターポリマー(EFEP)からなる群より選択されるフルオロポリマーである、熱可塑性アロイの形成方法。
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014130215A (ja) | 2012-12-28 | 2014-07-10 | Ricoh Co Ltd | シームレスベルト及びその製造方法、並びに画像形成装置 |
CN105838160A (zh) | 2016-04-08 | 2016-08-10 | 北京凯瑞捷成新材料科技有限公司 | 涂料组合物及其制备的润滑耐磨聚四氟乙烯橡胶涂料 |
US20170226389A1 (en) | 2016-02-10 | 2017-08-10 | Tyco Electronics Corporation | Adhesive Arrangement |
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JPH10219110A (ja) * | 1997-02-07 | 1998-08-18 | Kanegafuchi Chem Ind Co Ltd | 樹脂組成物並びにそれからなる管状物及びその製法 |
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US7625974B2 (en) * | 2005-09-30 | 2009-12-01 | Alphagary Corporation | Highly filled unsaturated fluoropolymer compositions for cables |
JP6871176B2 (ja) * | 2015-05-29 | 2021-05-12 | スリーエム イノベイティブ プロパティズ カンパニー | オキサゾールを含むペルフルオロエラストマー組成物 |
CN108368294A (zh) * | 2015-12-07 | 2018-08-03 | 纳幕尔杜邦公司 | 氟化弹性体的固化剂 |
CN109153834A (zh) * | 2016-05-20 | 2019-01-04 | 沙特基础工业全球技术有限公司 | 包括含氟弹性体和聚酰亚胺的复合材料、制备复合材料的方法及包含它的制品 |
CN109867954B (zh) * | 2017-12-05 | 2021-07-27 | 财团法人工业技术研究院 | 树脂组合物 |
KR102081090B1 (ko) * | 2017-12-29 | 2020-02-25 | 에스케이씨코오롱피아이 주식회사 | 불소계 수지를 포함하는 블랙 폴리이미드 필름 및 이의 제조방법 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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