JP7415296B2 - Isopod insect control agent - Google Patents
Isopod insect control agent Download PDFInfo
- Publication number
- JP7415296B2 JP7415296B2 JP2022195275A JP2022195275A JP7415296B2 JP 7415296 B2 JP7415296 B2 JP 7415296B2 JP 2022195275 A JP2022195275 A JP 2022195275A JP 2022195275 A JP2022195275 A JP 2022195275A JP 7415296 B2 JP7415296 B2 JP 7415296B2
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- JP
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- Prior art keywords
- test
- ants
- ant
- pelargonic acid
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 claims description 5
- 230000001747 exhibiting effect Effects 0.000 claims 2
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- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
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- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- SGUSXTMVKMPQKI-UHFFFAOYSA-M sodium;2,2,3,3-tetrafluoropropanoate Chemical compound [Na+].[O-]C(=O)C(F)(F)C(F)F SGUSXTMVKMPQKI-UHFFFAOYSA-M 0.000 description 1
- YWICANUUQPYHOW-UHFFFAOYSA-M sodium;2-(phosphonomethylamino)acetate Chemical compound [Na+].OP(O)(=O)CNCC([O-])=O YWICANUUQPYHOW-UHFFFAOYSA-M 0.000 description 1
- JRQGDDUXDKCWRF-UHFFFAOYSA-M sodium;n-(2-methoxycarbonylphenyl)sulfonyl-4-methyl-5-oxo-3-propoxy-1,2,4-triazole-1-carboximidate Chemical compound [Na+].O=C1N(C)C(OCCC)=NN1C(=O)[N-]S(=O)(=O)C1=CC=CC=C1C(=O)OC JRQGDDUXDKCWRF-UHFFFAOYSA-M 0.000 description 1
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- 229940124530 sulfonamide Drugs 0.000 description 1
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- IUQAXCIUEPFPSF-UHFFFAOYSA-N tembotrione Chemical compound ClC1=C(COCC(F)(F)F)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O IUQAXCIUEPFPSF-UHFFFAOYSA-N 0.000 description 1
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- 239000004308 thiabendazole Substances 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- XSKZXGDFSCCXQX-UHFFFAOYSA-N thiencarbazone-methyl Chemical group COC(=O)C1=CSC(C)=C1S(=O)(=O)NC(=O)N1C(=O)N(C)C(OC)=N1 XSKZXGDFSCCXQX-UHFFFAOYSA-N 0.000 description 1
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- IYMLUHWAJFXAQP-UHFFFAOYSA-N topramezone Chemical compound CC1=C(C(=O)C2=C(N(C)N=C2)O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 IYMLUHWAJFXAQP-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- SMYKBXMWXCZOLU-UHFFFAOYSA-N tris-decyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCCC)C(C(=O)OCCCCCCCCCC)=C1 SMYKBXMWXCZOLU-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
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- 239000011782 vitamin Substances 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Description
本発明は、ペラルゴン酸およびその塩を有効成分とした新規な害虫防除剤に関する。
さらに、本発明は、害虫侵入阻害剤に関する。より詳しくは、本発明は、ペラルゴン酸またはその塩を有効成分とし、薬剤処理面内に害虫が侵入することを確実に阻害する害虫侵入阻害剤に関する。
The present invention relates to a novel pest control agent containing pelargonic acid and its salt as an active ingredient.
Furthermore, the present invention relates to pest infestation inhibitors. More specifically, the present invention relates to a pest invasion inhibitor that contains pelargonic acid or a salt thereof as an active ingredient and reliably inhibits pest invasion into a chemically treated surface.
ペラルゴン酸は、天然にも存在する、茶、トウモロコシ、柑橘、ホップ等の食品に含まれる直鎖飽和脂肪酸のひとつとして知られており、不快な臭いをもつ無色油状液体である。しかし非特許文献1に示されたように、ペラルゴン酸は動物に対する毒性が低いことが知られており、安全性が高いことから各種用途において原料や有効成分としての利用が検討されている。 Pelargonic acid is known as a naturally occurring linear saturated fatty acid found in foods such as tea, corn, citrus fruits, and hops, and is a colorless oily liquid with an unpleasant odor. However, as shown in Non-Patent Document 1, pelargonic acid is known to have low toxicity to animals and is highly safe, so its use as a raw material or active ingredient in various applications is being considered.
例えば、特許文献1には、ココア様香料組成物の原料としてペラルゴン酸を用いることが開示されている。また特許文献2には、除草剤の有効成分として用いることについて検討がなされている。さらに特許文献3では、ペラルゴン酸と植物精油とを併用することで種子の発芽抑制作用を高めることが検討されている。 For example, Patent Document 1 discloses the use of pelargonic acid as a raw material for a cocoa-like fragrance composition. Moreover, in Patent Document 2, a study is made regarding the use as an active ingredient of a herbicide. Furthermore, in Patent Document 3, it is considered that the combination of pelargonic acid and plant essential oil can enhance the germination inhibitory effect on seeds.
また、近年、屋外から家屋などの建造物内に侵入するアリ類により刺咬被害が増加し、アリ類も不快害虫の1つに挙げられている。その防除方法としては、殺虫活性成分を含有する液剤またはエアゾール剤を、アリ類に直接噴霧して駆除するタイプのものや、毒餌剤をアリ類に巣穴に持ち帰らせ、巣穴内のアリ類を駆除するタイプのものが主体である。
例えば、ピレスロイド系化合物を殺虫活性成分として含有させた液剤やエアゾール剤は、アリ類やアリ類の巣に直接噴霧することにより速効的な殺虫効果が得られることが知られている(例えば、特許文献4等)。また、フェニルピラゾール系化合物を殺虫活性成分として含有させた毒餌剤は、接触作用による速効的な殺虫性が示されず、アリ類が巣穴に毒餌剤を運搬して巣全体を崩壊させることが報告されている(特許文献5)。しかしながら、上記液剤やエアゾール剤は、接触作用により速効的な殺虫効果が得られるため、殺虫活性成分に接触しないアリ類は駆除することができない。また、上記毒餌剤は殺虫成分と共に含有される誘引成分によっては、運搬効果にバラツキが見られ十分な防除効果が得られないことがある。
一方、アリ類をはじめその他の害虫は、家屋内に侵入さえしなければ必ずしも駆除の必要がない場合も多いため、アリ類等の害虫の侵入を阻止したい家屋入り口や周辺等に、予め害虫忌避効果を発揮する薬剤を処理する方法が提案されているものの、その忌避効果は未だ十分ではなく、アリ類等の害虫の侵入を確実に阻害できる新たな薬剤の開発が望まれていた。
Furthermore, in recent years, bite damage caused by ants that invade buildings such as houses from outside has increased, and ants are also considered as one of the unpleasant pests. Control methods include spraying a liquid or aerosol containing an insecticidal active ingredient directly onto the ants, or using poisonous bait to force the ants to take them back to their burrows. The main types are those that are exterminated.
For example, it is known that a liquid or aerosol containing a pyrethroid compound as an insecticidal active ingredient can have a rapid insecticidal effect when sprayed directly onto ants or ant nests (for example, patented Reference 4 etc.). In addition, it has been reported that poisonous baits containing phenylpyrazole-based compounds as insecticidal active ingredients do not exhibit fast-acting insecticidal properties through contact action, and that ants carry the poisonous baits into their burrows and collapse the entire nest. (Patent Document 5). However, since the above-mentioned liquid agents and aerosol agents provide a rapid insecticidal effect through contact action, they cannot exterminate ants that do not come into contact with the insecticidal active ingredient. Further, depending on the attractant component contained together with the insecticidal component, the above-mentioned poisonous bait may have a dispersion in its transport effect and may not have a sufficient pesticidal effect.
On the other hand, in many cases, it is not necessary to exterminate ants and other pests as long as they do not invade the house. Although effective treatment methods have been proposed, their repellent effects are still insufficient, and there has been a desire to develop new agents that can reliably inhibit the invasion of pests such as ants.
ペラルゴン酸は、上述のとおり各種用途について検討がなされており、その一部については利用が進んでいる。近年、安全志向が高まる中、ユーザーの天然由来成分に対する期待は高まっており、ペラルゴン酸についても新たな用途の提供が望まれている。
そこで本発明は、安全性の高いペラルゴン酸に着目し、新たな用途として害虫防除剤を提供することを目的としている。
さらに、本発明は、屋外から家屋などの建造物内に侵入する害虫を確実に阻害する、害虫侵入阻害剤を提供することを目的としている。
As mentioned above, various uses of pelargonic acid have been studied, and some of them are being used. In recent years, as safety consciousness has increased, users' expectations for naturally derived ingredients have increased, and new uses for pelargonic acid are also desired.
Therefore, the present invention focuses on pelargonic acid, which is highly safe, and aims to provide a pest control agent as a new application.
A further object of the present invention is to provide a pest invasion inhibitor that reliably inhibits pests from entering buildings such as houses from outside.
本発明者は、上記課題を解決するために鋭意研究を重ねた結果、ペラルゴン酸およびその塩が、各種の害虫に対して優れた殺虫効果、忌避効果を奏することを、さらには、薬剤処理面内に害虫が侵入することを確実に阻害する優れた侵入阻害効果を有することを見出し、上記課題を解決するに至ったものである。 As a result of extensive research in order to solve the above problems, the present inventors have discovered that pelargonic acid and its salts have excellent insecticidal and repellent effects against various pests, and have also found that pelargonic acid and its salts have excellent insecticidal and repellent effects on various insect pests. The inventors have discovered that this product has an excellent invasion inhibiting effect that reliably inhibits the invasion of pests into the interior of the home, and has thus come to solve the above-mentioned problems.
本発明は、具体的には次の事項を要旨とする。
1.ペラルゴン酸又はその塩を有効成分として含有することを特徴とする害虫防除剤。
2.害虫防除が害虫忌避であることを特徴とする1.記載の害虫防除剤。
3.害虫忌避が侵入阻害であることを特徴とする2.記載の害虫防除剤。
4.ペラルゴン酸の塩が、ナトリウム塩、トリエタノールアミン塩、アンモニウム塩、カリウム塩のいずれか1種以上であることを特徴とする1.~3.いずれかに記載の害虫防除剤。
Specifically, the present invention has the following points.
1. A pest control agent characterized by containing pelargonic acid or its salt as an active ingredient.
2. 1. The pest control is pest repellent. Pest control agents listed.
3. 2. Pest repellent is characterized by inhibiting invasion. Pest control agents listed.
4. 1. The salt of pelargonic acid is any one or more of sodium salt, triethanolamine salt, ammonium salt, and potassium salt. ~3. The pest control agent described in any of the above.
(効果1)
本発明の害虫防除剤は、天然由来成分であるペラルゴン酸を有効成分とするため、環境や人畜に負荷も少なく安全性の高い新規な害虫防除剤を提供することができる。また、ペラルゴン酸の新たな用途を提供することができる。
(Effect 1)
Since the pest control agent of the present invention contains pelargonic acid, which is a naturally derived component, as an active ingredient, it is possible to provide a novel pest control agent that is highly safe and has less burden on the environment and humans and livestock. Moreover, new uses of pelargonic acid can be provided.
(効果2)
本発明の害虫侵入阻害剤は、そのまま若しくは水に希釈して、家屋等の建造物の入り口付近に直接散布することによって、薬剤処理面内にアリ類や等脚目類等の害虫が侵入することを確実に阻害することができるので、屋内等に居住する人やペット等の動物がアリ類等に刺咬される被害を防ぎ、害虫が屋内に侵入すること自体を抑制することができる。
また、本発明の害虫侵入阻害剤は、除草活性を有するペラルゴン酸またはその塩を有効成分としているため、散布した場所の除草効果も同時に得ることができる。すなわち、本発明の害虫侵入阻害剤は、家屋のまわりや駐車場に散布することにより、家屋内や車内への害虫の侵入を阻害すると共に、散布した場所の雑草の繁殖を抑制する効果が得られるという特徴を有するものである。
(Effect 2)
The pest invasion inhibitor of the present invention can be sprayed directly near the entrance of buildings such as houses, either as it is or diluted with water, to prevent pests such as ants and isopods from entering into the chemically treated surface. This can reliably prevent people living indoors, pets, and other animals from being bitten by ants, and prevent pests from invading indoors.
Furthermore, since the pest invasion inhibitor of the present invention contains pelargonic acid or its salt, which has herbicidal activity, as an active ingredient, it is possible to simultaneously obtain a herbicidal effect in the area where it is sprayed. That is, by spraying the pest invasion inhibitor of the present invention around a house or in a parking lot, it is effective to inhibit the invasion of pests into the house or car, and to suppress the proliferation of weeds in the sprayed area. It has the characteristic that it can be used.
以下、本発明の害虫防除剤について詳細に説明する。
本発明の害虫防除剤は、有効成分としてペラルゴン酸またはその塩を含有するものである。
本発明における害虫防除とは、害虫を死に至らしめる殺虫効果により防除することはもとより、害虫が忌避する効果により防除すること、さらには薬剤処理面内に害虫が侵入することを阻害することをも含むものである。
ここで、本発明における「忌避」、「侵入阻害」、「侵入回避」について、詳しく説明する。
本発明における忌避や忌避剤とは、薬剤処理面内に侵入した害虫が薬剤の臭い等を嫌がり、一度侵入した薬剤処理面内から出て遠ざかる行動や、その行動を促す薬剤を意味する。
一方、本発明における侵入阻害とは、薬剤処理面に対し害虫が触角や歩脚を接触すらさせることなく薬剤処理面の前からUターンする行動、若しくは、触角や歩脚を薬剤処理面に接触させたとしても薬剤処理面内に侵入することなくUターンする行動、すなわち、薬剤処理面内に害虫が全く侵入しない行動や、その行動を促す薬剤を意味する。さらに、本発明における侵入回避とは、薬剤処理面に対し害虫が触角や歩脚を接触すらさせることなく薬剤処理面の前からUターンする行動を意味する。
Hereinafter, the pest control agent of the present invention will be explained in detail.
The pest control agent of the present invention contains pelargonic acid or a salt thereof as an active ingredient.
Pest control in the present invention includes not only pest control with an insecticidal effect that causes the death of pests, but also control with an effect that repels pests, and furthermore, prevention of pests from entering into a chemically treated surface. It includes.
Here, "repellent", "intrusion inhibition", and "intrusion avoidance" in the present invention will be explained in detail.
In the present invention, the term "repellent" or "repellent" refers to a chemical that causes insect pests that have invaded a chemically treated surface to dislike the smell of the chemical and move away from the chemically treated surface that they have invaded, or a chemical that encourages this behavior.
On the other hand, intrusion inhibition in the present invention refers to an action in which a pest makes a U-turn from in front of the chemical-treated surface without even touching the chemical-treated surface with its antennae or walking legs, or a behavior in which the insect pest makes a U-turn from in front of the chemical-treated surface without even touching the chemical-treated surface with its antennae or walking legs. This refers to a behavior in which pests make a U-turn without invading the chemically treated surface even if they are allowed to do so, in other words, a behavior in which pests do not invade the chemically treated surface at all, and a chemical that encourages this behavior. Furthermore, intrusion avoidance in the present invention refers to a behavior in which the insect pest makes a U-turn from in front of the chemically treated surface without even touching the chemically treated surface with its antennae or walking legs.
ペラルゴン酸は、炭素数9個からなる飽和脂肪酸であり、安全かつ速効的な除草活性を有する化合物として公知であり、我が国においても、1996年に除草剤として農薬登録された化合物である。ペラルゴン酸の塩としては、ナトリウム塩、カリウム塩、カルシウム塩、マグネシウム塩、アンモニウム塩、エタノールアミン塩、トリエタノールアミン塩等が挙げられ、本発明の害虫防除剤の有効成分として、ペラルゴン酸またはその塩として、ナトリウム塩、トリエタノールアミン塩、アンモニウム塩、カリウム塩が好ましい。これらの塩は単体として害虫防除剤中に加えても良いが、ペラルゴン酸と対応する中和剤とを別々に加えて害虫防除剤の調製時に塩を形成させてもよい。例えば、ペラルゴン酸と、中和剤としてトリエタノールアミンまたは水酸化ナトリウムを別々に加えて、トリエタノールアミン塩またはナトリウム塩として使用することができる。中和剤として、水酸化ナトリウム、トリエタノールアミン、アンモニア、水酸化カリウム等が好適である。 Pelargonic acid is a saturated fatty acid consisting of 9 carbon atoms, and is known as a compound having safe and fast-acting herbicidal activity, and is a compound that was registered as a pesticide as a herbicide in 1996 in Japan. Examples of salts of pelargonic acid include sodium salts, potassium salts, calcium salts, magnesium salts, ammonium salts, ethanolamine salts, triethanolamine salts, etc. Pelargonic acid or its As the salt, sodium salt, triethanolamine salt, ammonium salt, and potassium salt are preferred. These salts may be added alone to the pest control agent, or pelargonic acid and a corresponding neutralizing agent may be added separately to form a salt during the preparation of the pest control agent. For example, pelargonic acid and triethanolamine or sodium hydroxide as a neutralizing agent can be added separately to be used as a triethanolamine salt or a sodium salt. Suitable neutralizing agents include sodium hydroxide, triethanolamine, ammonia, potassium hydroxide, and the like.
本発明の害虫防除剤は、有効成分であるペラルゴン酸またはその塩を、害虫防除剤全体の0.01質量%以上、好ましくは0.05質量%以上、より好ましくは0.1質量%以上となるように用いるのがよい。また、ペラルゴン酸またはその塩をあまり多量に用いると臭いによる不快感が生じるおそれがあるので好ましくないため、10質量%以下含有することが好ましく、5質量%以下含有することがより好ましく、3質量%以下含有することがさらに好ましい。
本発明の害虫防除剤は、そのまま対象害虫に処理することができるが、所定の有効成分を含有した製剤を使用時に水で希釈して対象害虫に処理することもできる。この場合、水で希釈された製剤中での有効成分の含有量が0.01質量%以上、好ましくは0.05質量%以上となるように調製して使用することが好ましい。
The pest control agent of the present invention contains pelargonic acid or its salt as an active ingredient in an amount of 0.01% by mass or more, preferably 0.05% by mass or more, more preferably 0.1% by mass or more of the total pest control agent. It is best to use it as appropriate. In addition, if pelargonic acid or its salt is used in too large a quantity, it may cause discomfort due to odor, which is undesirable, so it is preferably contained in a content of 10% by mass or less, more preferably 5% by mass or less, and 3% by mass or less. % or less is more preferable.
The pest control agent of the present invention can be applied to target pests as it is, but a preparation containing a predetermined active ingredient can also be diluted with water before use and then applied to target pests. In this case, it is preferable to prepare and use the active ingredient so that the content of the active ingredient in the preparation diluted with water is 0.01% by mass or more, preferably 0.05% by mass or more.
本発明の害虫防除剤は、公知の方法により調製、製造することができる。例えば、ペラルゴン酸を水に添加し、有機溶剤や界面活性剤を用いて混合撹拌し、溶解、乳化、分散、懸濁化、可溶化して液剤やジェル剤とすることができる。またマイクロカプセル化して使用することもできる。ペラルゴン酸は油状液体であることから、有機溶剤や界面活性剤を用いて調製、製造することが適切である。その中でも、スプレー剤やエアゾール剤等の噴霧用製剤や、液剤をジョウロヘッド付き容器に充填した散布剤等が、本発明の害虫防除性能を最大限に活用することができる製剤型として好適である。スプレー剤やエアゾール剤とするには、所定の噴霧パターン、噴霧粒子を供給する噴霧装置を備えたエアゾール缶、薬剤ボトルを用いることができる。
本発明の害虫防除剤は、本発明の効果を奏する限り、液剤に限らず、粉剤、顆粒剤、微細粒等の固形剤として用いることもできる。
調製、製造例の1つとして、ペラルゴン酸またはその塩を、必要に応じて界面活性剤を用いて、有機溶剤に溶かして溶液(A液)を調製し、このA液を適量の水に混合、撹拌することにより使用時に希釈する必要がない害虫防除剤とする方法を挙げることができる。水としては、水道水、イオン交換水、蒸留水、ろ過処理した水、滅菌処理した水、地下水などの天然水等の1種または2種以上を混合して用いることができる。
The pest control agent of the present invention can be prepared and manufactured by a known method. For example, pelargonic acid can be added to water, mixed and stirred using an organic solvent or a surfactant, and dissolved, emulsified, dispersed, suspended, or solubilized to form a liquid or gel. It can also be used in microcapsule form. Since pelargonic acid is an oily liquid, it is appropriate to prepare and manufacture it using an organic solvent or a surfactant. Among these, atomizing preparations such as sprays and aerosols, and dispersing agents filled with liquid preparations in containers with a watering can head are suitable as formulation types that can make maximum use of the pest control performance of the present invention. . To prepare a spray or an aerosol, an aerosol can or a drug bottle equipped with a predetermined spray pattern and an atomizer for supplying atomized particles can be used.
The insect pest control agent of the present invention can be used not only as a liquid agent but also as a solid agent such as a powder, granules, and fine particles, as long as the effects of the present invention are achieved.
As one example of preparation and production, pelargonic acid or its salt is dissolved in an organic solvent using a surfactant if necessary to prepare a solution (liquid A), and this liquid A is mixed with an appropriate amount of water. For example, a method of stirring the pest control agent that does not require dilution during use can be mentioned. As water, one type or a mixture of two or more types of water such as tap water, ion-exchanged water, distilled water, filtered water, sterilized water, and natural water such as underground water can be used.
使用できる有機溶剤としては、例えば、アジピン酸ジイソブチル、アジピン酸ジオレイル、アジピン酸ジイソデシル、フタル酸ジエチルヘキシル、フタル酸ジデシル、トリメリット酸2-エチルヘキシル、トリメリット酸トリデシル等の多塩基酸アルコールエステル;2-エチルヘキサン酸セチル、ヤシ脂肪酸セチル、ラウリン酸メチル、ミリスチン酸メチル、オレイン酸メチル、オレイン酸オクチル等の脂肪酸アルコールエステル;ソルビタンモノラウレート、ソルビタンモノオレエート等の多価アルコール脂肪酸エステル;メタノール、エタノール、イソプロパノール、ブタノール、ヘキサノール、シクロヘキサノール、フェノキシエタノール、ベンジルアルコール等のアルコール;オクチルアルコール、ラウリルアルコール、3-メトキシ-3-メチル-1-ブタノール等の高級アルコール;エチレングリコール、プロピレングリコール、ジエチレングリコール、ヘキシレングリコール、ポリエチレングリコール、ポリプロピレングリコール等の多価アルコール;メチルジグリコール、メチルトリグリコール、エチレングリコールモノベンジルエーテル、エチレングリコールジメチルエーテル、ジエチレングリコールモノエチルエーテル、プロピレングリコールモノメチルエーテル、ジエチレングリコールモノベンジルエーテル等のグリコールエーテル;キシレン、トルエン、フェニルキシリルエタン、ケロシン、軽油、ヘキサン、シクロヘキサン、1,2-ジメチル-4-エチル-ベンゼン、メチルナフタレン、1-フェニル-1-キシリルエタン、1-キシリル-1-(3-α-メチルベンジルフェニル)エタン等の芳香族または脂肪族炭化水素;ノルマルパラフィン、イソパラフィン、流動パラフィン等のパラフィン系炭化水素;酢酸エチル、酢酸ブチル、ミリスチン酸イソプロピル、乳酸エチル等のエステル類;アセトン、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン等のケトン類;クロロベンゼン、ジクロロメタン、ジクロロエタン、トリクロロエタン等のハロゲン化炭化水素類;アセトニトリル、イソブチロニトリル等のニトリル類;ジメチルスルホキシド等のスルホキシド類;スルホラン、γ-ブチロラクトン、N-メチル-2-ピロリドン、N-エチル-2-ピロリドン、N-オクチル-2-ピロリドン、1,3-ジメチル-2-イミダゾリジノン等のヘテロ環系溶剤;N,N-ジメチルホルムアミド、N,N-ジメチルアセトアミド等の酸アミド類;炭酸プロピレン等の酸アルキリデン類;大豆油、ヤシ油、ナタネ油、キリ油、ヒマシ油、綿実油等の植物油;オレンジ油、ヒソップ油、レモン油等の植物精油の1種または2種以上が挙げられる。 Examples of organic solvents that can be used include polybasic acid alcohol esters such as diisobutyl adipate, dioleyl adipate, diisodecyl adipate, diethylhexyl phthalate, didecyl phthalate, 2-ethylhexyl trimellitate, and tridecyl trimellitate; - Fatty acid alcohol esters such as cetyl ethylhexanoate, cetyl coconut fatty acid, methyl laurate, methyl myristate, methyl oleate, and octyl oleate; Polyhydric alcohol fatty acid esters such as sorbitan monolaurate and sorbitan monooleate; methanol, Alcohols such as ethanol, isopropanol, butanol, hexanol, cyclohexanol, phenoxyethanol, benzyl alcohol; Higher alcohols such as octyl alcohol, lauryl alcohol, 3-methoxy-3-methyl-1-butanol; ethylene glycol, propylene glycol, diethylene glycol, Polyhydric alcohols such as xylene glycol, polyethylene glycol, polypropylene glycol; glycol ethers such as methyl diglycol, methyl triglycol, ethylene glycol monobenzyl ether, ethylene glycol dimethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, diethylene glycol monobenzyl ether, etc. ; Aromatic or aliphatic hydrocarbons such as α-methylbenzylphenyl)ethane; Paraffinic hydrocarbons such as normal paraffin, isoparaffin, and liquid paraffin; Esters such as ethyl acetate, butyl acetate, isopropyl myristate, and ethyl lactate; acetone, Ketones such as methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone; Halogenated hydrocarbons such as chlorobenzene, dichloromethane, dichloroethane, and trichloroethane; Nitriles such as acetonitrile and isobutyronitrile; Sulfoxides such as dimethyl sulfoxide; Sulfolane, γ-butyrolactone , N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-octyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone and other heterocyclic solvents; N,N-dimethylformamide, Acid amides such as N,N-dimethylacetamide; acid alkylidenes such as propylene carbonate; vegetable oils such as soybean oil, coconut oil, rapeseed oil, tung oil, castor oil, and cottonseed oil; orange oil, hyssop oil, lemon oil, etc. One or more types of plant essential oils may be mentioned.
使用できる界面活性剤としては、非イオン界面活性剤、陰イオン界面活性剤、陽イオン界面活性剤および両性界面活性剤を用いることができる。具体的には、例えば、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンスチリルフェニルエーテル、ポリオキシエチレンアルキルエステル、ポリオキシエチレンソルビタンアルキレート、ポリオキシエチレンフェニルエーテルポリマー、ポリオキシエチレンアルキレンアリールフェニルエーテル、ポリオキシエチレンアルキレングリコール、およびポリオキシエチレンポリオキシプロピレンブロックポリマー、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンアルキルアミン、ポリオキシエチレン脂肪酸アミド、ポリオキシエチレン型シリコン系界面活性剤等の非イオン界面活性剤;ポリオキシエチレンアルキルエーテルフォスフェート、リグニンスルホン酸塩、アルキルアリールスルホン酸塩、ポリオキシエチレンアルキルアリールエーテルサルフェート、アルキルナフタレンスルホン酸塩、ジアルキルスルホコハク酸塩、ポリオキシエチレンスチリルフェニルエーテルサルフェート、アルキルベンゼンスルホン酸塩、アルキルスルホン酸塩、アルキル硫酸塩、アルキルマレイン酸共縮合物のナトリウム塩等の陰イオン界面活性剤;アルキルベタイン、アルキルアミドプロピルベタイン、2-アルキル-N-カルボキシメチル-N-ヒドロキシエチルイミダゾリニウムベタイン等の両性界面活性剤;アルキルアミン塩、第四級アンモニウム塩等の陽イオン界面活性剤の1種または2種以上が挙げられる。 As surfactants that can be used, nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants can be used. Specifically, for example, polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene styrylphenyl ether, polyoxyethylene alkyl ester, polyoxyethylene sorbitan alkylate, polyoxyethylene phenyl ether polymer, polyoxyethylene Alkylene arylphenyl ether, polyoxyethylene alkylene glycol, polyoxyethylene polyoxypropylene block polymer, polyoxyethylene hydrogenated castor oil, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene type silicone surfactant, etc. Nonionic surfactants; polyoxyethylene alkyl ether phosphate, lignin sulfonate, alkylaryl sulfonate, polyoxyethylene alkylaryl ether sulfate, alkylnaphthalene sulfonate, dialkyl sulfosuccinate, polyoxyethylene styrylphenyl Anionic surfactants such as ether sulfate, alkylbenzene sulfonate, alkyl sulfonate, alkyl sulfate, sodium salt of alkyl maleic acid cocondensate; alkyl betaine, alkylamidopropyl betaine, 2-alkyl-N-carboxymethyl Examples include one or more of amphoteric surfactants such as -N-hydroxyethylimidazolinium betaine; and cationic surfactants such as alkylamine salts and quaternary ammonium salts.
本発明の害虫防除剤を調製、製造するに際しては、水、有機溶剤および界面活性剤を適宜組み合わせて用いることができるが、本発明の効果を奏する限り、安定化剤、増粘剤、香料、色素、消泡剤、光安定化剤(紫外線吸収剤)、pH調整剤、凍結防止剤、防腐剤、噴射剤、酸化防止剤等その他の各種成分を用いることができる。
その他の各種成分としては、例えば、ブチルヒドロキシアニソール、ジブチルヒドロキシトルエン、没食子酸プロピル、トコフェロール、アスコルビン酸、ビタミン等の安定化剤;カルボキシビニルポリマー、ポリビニルアルコール、グアーガム、キサンタンガム、ポリビニルピロリドン、コロイド性含水珪酸アルミニウム、コロイド性含水珪酸マグネシウム等の増粘剤;イランイラン油、オレンジ油、カモミール油、カルダモン油、クミン油、グレープフルーツ油、クローブ油、月桃油、コパイバ油、コリアンダー油、紫蘇油、シダーウッド油、シトロネラ油、シナモン油、ジャスミン油、スギ油、スペアミント油、セージ油、ゼラニウム油、タイム油、ネロリ油、パイン油、薄荷油、ヒノキ油、ヒバ油、ペパーミント油、ベルガモット油、柚子油、ユーカリ油、ライム油、ラベンダー油、レモン油、レモングラス油、レモンバーム油、ローズマリー油、ロベージ油等の天然精油、アニスアルデヒド、アセトフェノン、アセチルオイゲノール、ベンジルアセテート、ベンジルアルコール、ベンジルサリシレート、ベンズアルデヒド、カルボン、セドロール、シンナミックアルコール、シンナミックアルデヒド、シスジャスモン、シトラール、シトロネラール、シトロネロール、クマリン、シンナミルアセテート、オイゲノール、α-ピネン、β-ピネン、リモネン、ミルセン、β-カリオフィレン、ゲラニオール、ゲラニルアセテート、ヘキシルシンナミックアルデヒド、インドール、リナロール、リナロールオキサイド、リナリルアセテート、メチルオイゲノール、メントール、ネロール、フェニルエチルアルコール、チモール等の香料;赤色2号、赤色3号、赤色102号、赤色106号、赤色227号、赤色504号、青色1号、青色2号、青色202号、黄色4号、黄色5号、黄色202号、緑色3号、緑色201号、緑色204号、橙色205号等の色素;シリコーン系化合物等の消泡剤;パラアミノ安息香酸、t-ブチルメトキシジベンゾイルメタン、サリチル酸フェニル等の光安定化剤(紫外線吸収剤);グルコン酸、グルコノデルタラクトン、L-酒石酸水素カリウム、炭酸ナトリウム、フマル酸、リンゴ酸、クエン酸、ピロリン酸二水素ナトリウム、L-酒石酸ナトリウム、リン酸三カリウム、リン酸、乳酸ナトリウム、アジピン酸およびナトリウムやカリウムの塩、アミン塩等のpH調整剤;エタノール、プロピレングリコール、エチレングリコール等の凍結防止剤;ソルビン酸カリウム、パラクロロメタキシレノール、パラオキシ安息香酸ブチル、パラオキシ安息香酸メチル、パラオキシ安息香酸エチル、パラオキシ安息香酸プロピル、安息香酸等の防腐剤;プロパン、プロピレン、n-ブタン、イソブタン等の液化石油ガス、ジメチルエーテル、CFC、HCFC、HFC等のクロロフルオロカーボン等の液化ガス、窒素、炭酸ガス、圧縮空気、亜酸化窒素等の圧縮ガス等の噴射剤;ブチルヒドロキシアニソール、ジブチルヒドロキシトルエン、トコフェロール、γ-オリザノール、エリソルビン酸、エリソルビン酸ナトリウム、没食子酸プロピル等の酸化防止剤の1種または2種以上が挙げられる。
When preparing and manufacturing the pest control agent of the present invention, water, organic solvents, and surfactants can be used in appropriate combinations, but as long as the effects of the present invention are achieved, stabilizers, thickeners, fragrances, Various other components such as a dye, an antifoaming agent, a light stabilizer (ultraviolet absorber), a pH adjuster, an antifreeze agent, a preservative, a propellant, and an antioxidant can be used.
Other various ingredients include, for example, stabilizers such as butylated hydroxyanisole, dibutylated hydroxytoluene, propyl gallate, tocopherol, ascorbic acid, and vitamins; carboxyvinyl polymer, polyvinyl alcohol, guar gum, xanthan gum, polyvinylpyrrolidone, and colloidal water content. Thickeners such as aluminum silicate and colloidal hydrated magnesium silicate; ylang-ylang oil, orange oil, chamomile oil, cardamom oil, cumin oil, grapefruit oil, clove oil, shellfish oil, copaiba oil, coriander oil, perilla oil, cedarwood oil, citronella oil, cinnamon oil, jasmine oil, cedar oil, spearmint oil, sage oil, geranium oil, thyme oil, neroli oil, pine oil, minced oil, cypress oil, cypress oil, peppermint oil, bergamot oil, yuzu oil, Natural essential oils such as eucalyptus oil, lime oil, lavender oil, lemon oil, lemongrass oil, lemon balm oil, rosemary oil, lovage oil, anisaldehyde, acetophenone, acetyl eugenol, benzyl acetate, benzyl alcohol, benzyl salicylate, benzaldehyde, carvone , cedrol, cinnamic alcohol, cinnamic aldehyde, cisjasmone, citral, citronellal, citronellol, coumarin, cinnamyl acetate, eugenol, α-pinene, β-pinene, limonene, myrcene, β-caryophyllene, geraniol, geranyl acetate, hexyl Flavors such as cinnamic aldehyde, indole, linalool, linalool oxide, linalyl acetate, methyl eugenol, menthol, nerol, phenylethyl alcohol, thymol; Red No. 2, Red No. 3, Red No. 102, Red No. 106, Red No. 227, Pigments such as Red No. 504, Blue No. 1, Blue No. 2, Blue No. 202, Yellow No. 4, Yellow No. 5, Yellow No. 202, Green No. 3, Green No. 201, Green No. 204, Orange No. 205; silicone compounds Antifoaming agents such as para-aminobenzoic acid, t-butylmethoxydibenzoylmethane, phenyl salicylate, etc.; light stabilizers (ultraviolet absorbers); gluconic acid, glucono delta lactone, potassium L-bitartrate, sodium carbonate, fumar Acid, malic acid, citric acid, sodium dihydrogen pyrophosphate, sodium L-tartrate, tripotassium phosphate, phosphoric acid, sodium lactate, adipic acid, and pH adjusters such as sodium and potassium salts and amine salts; ethanol, propylene Antifreeze agents such as glycol and ethylene glycol; Preservatives such as potassium sorbate, parachloromethylenol, butyl paraoxybenzoate, methyl paraoxybenzoate, ethyl paraoxybenzoate, propyl paraoxybenzoate, and benzoic acid; propane, propylene, Propellants such as liquefied petroleum gases such as n-butane and isobutane, liquefied gases such as dimethyl ether, chlorofluorocarbons such as CFC, HCFC, and HFC, compressed gases such as nitrogen, carbon dioxide, compressed air, and nitrous oxide; butylhydroxyanisole; , dibutylhydroxytoluene, tocopherol, γ-oryzanol, erythorbic acid, sodium erythorbate, propyl gallate, and the like.
本発明の害虫侵入阻害効果を得る害虫侵入阻害剤は、アリ類等の害虫の巣穴やその周囲に処理した際に土壌への吸収を抑えて、アリ類等の害虫が触角や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内にアリ類等の害虫が侵入することを確実に阻害する効果を十分に発揮させるために、粘度のある液剤としてもよい。粘度を調整するに際しては、例えば、グリセリン、ザンフロー、キサンタンガム、ペクチン、アラビアガム、グアーガム、寒天、セルロースおよびその誘導体、デンプンおよびその誘導体、カルボキシアルカリ化物、ポリアクリル酸塩、ポリマレイン酸塩、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー等の増粘剤の1種または2種以上を用いて調整すればよい。 The pest invasion inhibitor of the present invention, which has the effect of inhibiting pest invasion, suppresses absorption into the soil when applied to the burrows and surrounding areas of pests such as ants, and prevents pests such as ants from using their antennae and walking legs. In order to suppress contact with the chemically treated surface and to fully exhibit the effect of reliably inhibiting pests such as ants from entering the chemically treated surface, a viscous liquid may be used. When adjusting the viscosity, for example, glycerin, Zanflo, xanthan gum, pectin, gum arabic, guar gum, agar, cellulose and its derivatives, starch and its derivatives, carboxy alkalides, polyacrylates, polymaleates, polyvinyl alcohol, It may be adjusted using one or more thickeners such as polyvinylpyrrolidone and carboxyvinyl polymer.
固形剤とするには、例えば、クレー、タルク、炭酸カルシウム、ベントナイト、ジークライト、セリサイト、酸性白土、珪石、ケイソウ土、ゼオライト、カオリン、ホワイトカーボン、塩化カルシウム、塩化カリウム、硫酸アンモニウム、植物粉末(例えば、小麦粉、大豆粉、おが屑、ヤシ殻等)、グルコース、フルクトース、マルトース、シュークロース、ラクトース等の単糖類、二糖類、多糖類等の1種または2種以上を用い調製、製造することができる。 For example, clay, talc, calcium carbonate, bentonite, ziecrite, sericite, acid clay, silica stone, diatomaceous earth, zeolite, kaolin, white carbon, calcium chloride, potassium chloride, ammonium sulfate, vegetable powder ( For example, it can be prepared and manufactured using one or more of monosaccharides, disaccharides, and polysaccharides such as wheat flour, soybean flour, sawdust, coconut shells, etc.), glucose, fructose, maltose, sucrose, and lactose. can.
さらに必要に応じて公知の殺菌剤、防カビ剤、殺虫殺ダニ剤、除草剤等の薬剤として、例えば、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ヘキサコナゾール、イマザリル、ミクロブタニル、シメコナゾール、テトラコナゾール、チアベンダゾール、ペンチオピラド、マンゼブ等の殺菌剤;塩化ベンゼトニウム、塩化ベンザルコニウム、塩酸クロルヘキシジン、グルコン酸クロルヘキシジン、ヒノキチオール、フェノキシエタノール、イソプロピルメチルフェノール等の防カビ剤;除虫菊エキス、天然ピレトリン、プラレトリン、イミプロトリン、フタルスリン、アレスリン、ビフェントリン、レスメトリン、フェノトリン、シフェノトリン、ペルメトリン、サイパーメスリン、エトフェンプロックス、シフルスリン、デルタメスリン、ビフェントリン、フェンバレレート、フェンプロパトリン、エムペントリン、シラフルオフェン、トランスフルトリン、メトフルトリン、プロフルトリン等のピレスロイド系化合物、カルバリル、プロポクスル、メソミル、チオジカルブ等のカーバメート系化合物、メトキサジアゾン等のオキサジアゾール系化合物、フィプロニル等のフェニルピラゾール系化合物、アミドフルメト等のスルホンアミド系化合物、ジノテフラン、イミダクロプリド等のネオニコチノイド系化合物、クロルフェナピル等のピロール系化合物等、フェニトロチオン、ダイアジノン、マラソン、ピリダフェンチオン、プロチオホス、ホキシム、クロルピリホス、ジクロルボス等の有機リン系化合物等の殺虫剤;アラクロール、アメトリン、アミノシクロピラクロール、アミノピラリド、アミプロホスメチル、アニロホス、アシュラム、アトラジン、アジムスルフロン、ベンカルバゾン、ベスロジン、ベンフレセート、ベンスルフロンメチル、ベンスリド、ベンタゾン、ベンチオカーブ、ベンゾビシクロン、ベンゾフェナップ、ビアラホス、ビシクロピロン、ビフェノックス、ビスピリバック、ブロマシル、ブロモブチド、ブタクロール、ブタミホス、ブテナクロール、カフェンストロール、カルフェントラゾンエチル、クロメトキシニル、クロリダゾン、クロルフタリム、クロロIPC、TCTP、シンメスリン、シノスルフロン、クロジナホップ、クロマゾン、クロメプロップ、クロピラリド、CNP、クミルロン、シアナジン、シクロスルファムロン、シハロホップブチル、ダイカンバ、ジクロベニル、ジフルフェニカン、ジメピペレート、ジメタメトリン、ジメテナミド、Pジメテナミド、ジチオピル、ジウロン、ダイムロン、エスプロカルブ、エトフメセート、エトベンザニド、エトキシスルフロン、フラザスルフロン、フェノキサプロップエチル、フェノキサスルフォン、フェントラザミド、フロラスラム、フルアジホップ、フルカルバゾンナトリウム塩、フルセトスルフロン、フルポキサム、グルホシネート、グリホサートアンモニウム塩、グリホサートイソプロピルアミン塩、グリホサートカリウム塩、グリホサートナトリウム塩、グリホサートトリメシウム塩、ハロスルフロンメチル、ヘキサジノン、イマザモックス、イマザピル、イマゼタピル、イマザキン、イマゾスルフロン、インダノファン、インダジフラム、ヨードスルフロンメチルナトリウム塩、アイオキシニル、イプフェンカルバゾン、イソプロチュロン、イソウロン、イソキサベン、イソキサフルトール、カルブチレート、レナシル、リニュロン、MCC、MCPA、MCPB、MCPP、メフェナセット、メソスルフロンメチル、メソトリオン、メタミホップ、メタミトロン、メタゾスルフロン、メチオゾリン、メチルダイムロン、メトラクロール、メトリブジン、メトスルフロンメチル、モリネート、モノスルフロン、モノスルフロンメチル、ナプロアニリド、ナプロパミド、ニコスルフロン、ノルフルラゾン、オルソベンカーブ、オルソスルファムロン、オキサジアルギル、オキサジアゾン、オキサジクロメホン、ペンディメタリン、ペノキススラム、ペントキサゾン、フェンメディファム、ピコリナフェン、ピノキサデン、プレチラクロール、プロジアミン、プロメトリン、プロパニル、プロピソクロール、プロポキシカルバゾンナトリウム塩、プロピリスルフロン、プロピザミド、ピラクロニル、ピラスルホトール、ピラゾリネート、ピラゾスルフロンエチル、ピラゾキシフェン、ピリブチカルブ、ピリフタリド、ピリミノバックメチル、ピリミスルファン、ピロキサスルホン、ピロキシスラム、キンクロラック、キノクラミン、キザロホップエチル、サフルフェナシル、セトキシジム、シデュロン、シマジン、シメトリン、スルフォスルフロン、テブティウロン、テフリルトリオン、テンボトリオン、テプラロキシジム、ターバシル、テトラピオン、テニルクロール、チアザフルロン、チエンカルバゾンメチル、チフェンスルフロンメチル、トプラメゾン、トリアファモン、トリフロキシスルフロン、トリフルラリン、2,4-PA、d-リモネン等の除草剤の1種または2種以上を用いることができる。 Furthermore, if necessary, known agents such as fungicides, fungicides, insecticides, acaricides, and herbicides may be used, such as bitertanol, bromoconazole, cyproconazole, difenoconazole, hexaconazole, imazalil, myclobutanil, simeconazole, Fungicides such as tetraconazole, thiabendazole, penthiopyrad, mancozeb; fungicides such as benzethonium chloride, benzalkonium chloride, chlorhexidine hydrochloride, chlorhexidine gluconate, hinokitiol, phenoxyethanol, isopropylmethylphenol; pyrethrum extract, natural pyrethrin, prarethrin, Pyrethroids such as imiprothrin, phthalthrin, allethrin, bifenthrin, resmethrin, phenothrin, cyphenothrin, permethrin, cypermethrin, etofenprox, cyfluthrin, deltamethrin, bifenthrin, fenvalerate, fenpropathrin, empenthrin, cilafluofen, transfluthrin, metofluthrin, profluthrin carbamate compounds such as carbaryl, propoxur, methomyl, thiodicarb, oxadiazole compounds such as methoxadiazone, phenylpyrazole compounds such as fipronil, sulfonamide compounds such as amidoflumet, neonicotinoid compounds such as dinotefuran and imidacloprid. compounds, pyrrole compounds such as chlorfenapyr, insecticides such as organophosphorus compounds such as fenitrothion, diazinon, marathon, pyridafenthion, prothiophos, phoxim, chlorpyrifos, dichlorvos; alachlor, ametrine, aminocyclopyraclor, aminopyralid, amipro Phosmethyl, Anilofos, Ashram, Atrazine, Azimsulfuron, Bencarbazone, Beslozin, Benfuresate, Bensulfuron Methyl, Bensuride, Bentazone, Benthiocarb, Benzobiciclone, Benzofenap, Bialafos, Bicyclopyrone, Bifenox, Bispyribac, Bromacil, Bromobutide, Butachlor , butamifos, butenachlor, cafenstrol, carfentrazone ethyl, clomethoxynil, chloridazone, chlorphthalim, chloroIPC, TCTP, simethrin, sinosulfuron, clodinafop, clomazone, clomeprop, clopyralid, CNP, cumyluron, cyanazine, cyclosulfamuron, cyhalofop Butyl, dicamba, dichlobenil, diflufenican, dimepiperate, dimethamethrine, dimethenamide, P dimethenamide, dithiopyr, diuron, dimeron, esprocarb, etofumesate, etobenzanide, ethoxysulfuron, frazasulfuron, fenoxaprop ethyl, fenoxasulfone, fentrazamide, florasulam, fluazifop, flucarbazone sodium salt, flucetosulfuron, flupoxam, glufosinate, glyphosate ammonium salt, glyphosate isopropylamine salt, glyphosate potassium salt, glyphosate sodium salt, glyphosate trimesium salt, halosulfuron methyl, hexazinone, imazamox, imazapyr, imazetapyr, Imazaquin, imazosulfuron, indanophane, indaziflam, iodosulfuron methyl sodium salt, ioxinil, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutole, carbutyrate, renacil, linuron, MCC, MCPA, MCPB, MCPP, mefenacet , mesosulfuron methyl, mesotrione, metamifop, metamitrone, metazosulfuron, methiozoline, methyldimeron, metolachlor, metribuzin, metsulfuron methyl, molinate, monosulfuron, monosulfuron methyl, naproanilide, napropamide, nicosulfuron, norflurazone, orthobencarb, orthosul famulon, oxadiargyl, oxadiazone, oxadiclomefon, pendimethalin, penoxsulam, pentoxazone, phenmedipham, picolinafen, pinoxaden, pretilachlor, prodiamine, promethrin, propanil, propisochlor, propoxycarbazone sodium salt, propyrisulfuron, propyzamide, Pyraclonil, pyrasulfotol, pyrazolinate, pyrazosulfuronethyl, pyrazoxifene, pyributicarb, pyrifthalide, pyriminobacmethyl, pyrimisulfan, pyroxasulfone, piroxisulam, quinclorac, quinocramine, quizalofopethyl, saflufenacil, setoxydim, siduron, Simazine, cymetrin, sulfosulfuron, tebutiuron, tefuryltrione, tembotrione, tepraloxydim, terbasil, tetrapion, tenylchlor, thiazafluron, thiencarbazone methyl, thifensulfuron methyl, topramezone, triafamone, trifloxysulfuron, trifluralin, 2 , 4-PA, d-limonene, etc., or two or more types of herbicides can be used.
本発明の対象となる害虫を、以下に例示する。
アリ類(クロヤマアリ、トビイロシワアリ、アミメアリ、クロオオアリ、トビイロケアリ、オオハリアリ、ヒメアリ、クロクサアリ、イエヒメアリ、ルリアリ、オオズアリ、キイロヒメアリ、クロヒメアリ、コトビイロケアリ、ハヤシトビイロケアリ、キイロシリアゲアリ、トビイロシリアゲアリ、ハリブトシリアゲアリ、オオシワアリ、シワアリ、メクラハリアリ、トゲアリ、ムネアカオオアリ、サムライアリ、アカヤマアリ、アメイロアリ、ウメマツアリ、シワクシケアリ、エゾクシケアリ、オオズアカアリ、アズマオオズアカアリ、アシナガアリ、クロナガアリ、ムネボソアリ、フシアリ、アルゼンチンアリ、ヒアリ、アカカミアリ等)、
等脚目類(ホソワラジムシ、ワラジムシ等のワラジムシ類、オカダンゴムシ等のダンゴムシ類、フナムシ等のフナムシ類等)、
腹足類(コウラナメクジ、チャコウラナメクジ、ノナメクジ等のコウラナメクジ科、ナメクジ、ヤマナメクジ等のナメクジ科、ニワコウラナメクジ等のニワコウラナメクジ科、オカモノアラガイ等のオカモノアラガイ科、アフリカマイマイ等のアフリカマイマイ科、ウスカワマイマイ等のオナジマイマイ科、ニッポンマイマイ等のナンバンマイマイ科等のマイマイ、カタツムリ類)、
クモ類(カバキコマチグモ、セアカゴケグモ等)、
半翅目類(アオクサカメムシ、ホソヘリカメムシ、オオトゲシラホシカメムシ、トゲシラホシカメムシ、チャバネアオカメムシ、クサギカメムシ、ミナミアオカメムシ、アカスジカスミカメ、アカヒゲホソミドリカスミカメ等のカメムシ類、モモアカアブラムシ、リンゴアブラムシ、ワタアブラムシ、ニセダイコンアブラムシ等のアブラムシ類等)、
鱗翅目類(チャドクガ等のドクガ類、アメリカシロヒトリ等のヒトリガ類、マイマイガ等のマイマイガ類、ハスモンヨトウ、アワヨトウ、トリコプルシア属、ヘリオティス属、ヘリコベルパ属等のヤガ類、ニカメイガ、コブノメイガ、ワタノメイガ、ノシメマダラメイガ等のメイガ類、イガ、コイガ等のヒロズコガ類等の成虫または幼虫)、
双翅目類(ユスリカ類、タネバエ、タマネギバエ等のハナバエ類、マメハモグリバエ等のハモグリバエ類、ミバエ類、ショウジョウバエ類、クロバネキノコバエ類、ニセケバエ類、ハマベバエ類、ハヤトビバエ類、オオキモンノミバエ等のノミバエ類、オオチョウバエ等のチョウバエ類、ブユ類、アブ類、サシバエ類等)、
膜翅目類(ミナミキイロアザミウマ、ミカンキイロアザミウマ、ハナアザミウマ、アザミウマ類等)、
多足類(ゲジ、トビズムカデ等の唇脚綱類や、ヤケヤスデ、アカヤスデ等の倍脚綱類)、
ダニ目(タカラダニ類等)、
鞘翅目類(ゴミムシ等のコウチュウ目等)、
革翅目類(ハサミムシ類等)、
網翅目類(ゴキブリ目等)、
直翅目類(ケラ類、バッタ類、コオロギ類等)を例示することができる。
本発明の害虫防除剤は、これらの中でも、腹足類、等脚目類、アリ類、半翅目類に対して有効に使用することができる。
Examples of pests targeted by the present invention are shown below.
Ants (black wood ant, brown carp ant, red-eared ant, black carpenter ant, brown carp ant, carpenter ant, Japanese carp ant, black grass ant, Japanese carp ant, Japanese carp ant, carpenter ant, yellow carp ant, black carp ant, black carp ant, falcon carp ant, yellow carpenter ant, black carp ant, brown carp ant, Japanese carpenter ant, wrinkle ant, black carp ant, spiny ant, red carpenter ant, samurai ant, red mountain ant, American carpenter ant, Japanese carpenter ant, Japanese carp ant, Japanese carp ant, red carpenter ant, red carpenter ant, red carpenter ant, black carpenter ant, black carpenter ant, fire ant, Argentine carpenter ant, fire ant, red carp ant, etc.),
Isopods (woodworms such as woodlice, woodlice, pillbugs such as pill bug, sea fungi such as sea fungus, etc.),
Gastropods (Slugidae, such as the African slug, Chakoura slug, and Snail slug; Ameriidae, such as the slug and Japanese slug; Sculinidae, such as the Niwakoura slug; Sculpinidae, such as the African snail; snails);
Spiders (Kabakikomachi spider, Redback spider, etc.),
Hemiptera (stinky bugs such as the green stink bug, the white-spotted stink bug, the great spiny stink bug, the brown stink bug, the German green stink bug, the brown stink bug, the southern stink bug, the red-striped stink bug, the red-striped stink bug, the red-spotted stink bug, the green peach aphid, Aphids such as apple aphid, cotton aphid, false radish aphid, etc.),
Lepidoptera (Helicoptera moths such as Chadoku moths, Helicoptera moths such as the American white flycatcher, Gypsy moths such as Gypsy moths, Noctuid moths such as Spodoptera spp., Fall armyworm, Trichoplusia sp., Heliothis sp., Helicoverpa sp. (adults or larvae of Japanese grass moths such as burrs, carp moths, etc.),
Diptera (hanger flies such as chironomids, seed flies, onion flies, leafminers such as the leafminer fly, fruit flies, fruit flies, fruit flies, black fungus flies, black flies, porphyry flies, chayote flies, and flea flies such as the giant flea fly) , butterfly flies such as the giant butterfly, blackflies, horseflies, stable flies, etc.),
Hymenoptera (southern yellow thrips, occidental thrips, red thrips, thrips, etc.),
Myriapods (chilliopods such as geji and tobisumkade, and diplopods such as yellow millipedes and red millipedes),
Acariformes (Takara mites, etc.),
Coleoptera (Coleoptera such as meal beetles, etc.),
Leatheroptera (earwigs, etc.),
Ophthalmia (such as Cockroaches),
Examples include Orthoptera (mosquitos, grasshoppers, crickets, etc.).
The pest control agent of the present invention can be effectively used against gastropods, isopods, ants, and hemiptera among these.
本発明の害虫侵入阻害剤は、アリ類等の害虫が触角や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内に害虫が侵入することを確実に阻害するために、薬剤処理面1平方メートル当たり、ペラルゴン酸またはその塩を、好ましくは0.01~30g、より好ましくは0.05~25gとなる量で散布する。施用頻度は、アリ類等の害虫の発生を確認したら、1~2週間に1回程度の頻度で施用するのがよい。施用手段は特に制限されない。
本発明の害虫侵入阻害剤は、害虫が侵入して欲しくない家屋などの建造物の入り口付近、例えば台所、勝手口、玄関、廊下、リビング、窓辺、ベランダ、ウッドデッキ、ポート、アスファルト等の家屋などの建造物周辺や駐車場等に噴霧または散布処理することにより、アリ類等の害虫が触角や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内にアリ類等の害虫が侵入することを確実に阻害する効果を発揮し、家屋などの建造物内や車内へのアリ類等の害虫の侵入を確実に阻害する点において極めて実用的である。
The pest invasion inhibitor of the present invention suppresses pests such as ants from coming into contact with chemically treated surfaces with their antennae and walking legs, and reliably prevents pests from entering chemically treated surfaces. Pelargonic acid or its salt is sprayed in an amount of preferably 0.01 to 30 g, more preferably 0.05 to 25 g per square meter of treated surface. As for the frequency of application, once the occurrence of pests such as ants is confirmed, it is recommended to apply once every 1 to 2 weeks. The means of application is not particularly limited.
The pest invasion inhibitor of the present invention can be used near entrances of buildings such as houses where pests do not want to enter, such as kitchens, back doors, entrances, hallways, living rooms, windowsills, balconies, wooden decks, ports, asphalt houses, etc. By spraying or spraying around buildings, parking lots, etc., pests such as ants are prevented from coming into contact with the chemically treated surfaces with their antennae and walking legs, and pests such as ants are prevented from coming into contact with the chemically treated surfaces. It exhibits the effect of reliably inhibiting intrusion, and is extremely practical in that it reliably inhibits the intrusion of pests such as ants into buildings such as houses and cars.
以下に実施例によって本発明をさらに詳しく説明するが、本発明はこれらに限定されるものではない。 EXAMPLES The present invention will be explained in more detail with reference to Examples below, but the present invention is not limited thereto.
<試験検体の調製1>
表1記載の組成からなる試験検体を調製し、実施例1~6および比較例1とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
実施例1~6は、ペラルゴン酸と25%アンモニア水とが中和してペラルゴン酸のアンモニウム塩を形成し、有効成分として作用する。
<Preparation of test specimen 1>
Test specimens having the compositions shown in Table 1 were prepared and used as Examples 1 to 6 and Comparative Example 1. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
In Examples 1 to 6, pelargonic acid and 25% aqueous ammonia are neutralized to form an ammonium salt of pelargonic acid, which acts as an active ingredient.
<殺虫試験1>
表2記載の各種害虫を対象として殺虫試験1を実施した。試験の概要は図1に示した。≪アリ類・等脚目類・ナメクジ殺虫試験≫
内径100mm、高さ45mmのプラスチック製カップ(商品名:KP-200(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に供試虫5頭を放ち、10cmの距離から各試験検体2mLを噴霧器で処理した。処理後、供試虫を清潔なプラスチック製カップに移し、12時間後に致死数を計数し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて行い、3回の平均値を致死率(%)として表2に記載した。
≪カメムシ殺虫試験≫
上記「アリ類・等脚目類・ナメクジ殺虫試験」と同様に、チャバネアオカメムシ、クサギカメムシ、ミナミアオカメムシ、ホソヘリカメムシは供試虫を3~5頭とし、24時間後の致死数を計数し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて1回行った。
≪ニッポンマイマイ殺虫試験≫
上記「アリ類・等脚目類・ナメクジ殺虫試験」と同様に、ニッポンマイマイは供試虫を1頭とし、12時間後の致死を確認し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて1回行った。
≪トビズムカデ殺虫試験≫
内径130mm、高さ100mmのプラスチック製カップ(商品名:KP-860MB(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に供試虫1頭を放ち、10cmの距離から各試験検体6mLを噴霧器で処理した。処理後、供試虫を清潔なプラスチック製カップに移し、24時間後に致死を確認し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて1回行った。
[式]:致死率(%)=致死した供試虫数/全供試虫数×100
<Insecticidal test 1>
Insecticidal test 1 was conducted targeting the various pests listed in Table 2. The outline of the test is shown in Figure 1. ≪Ants, isopods, slugs insecticidal test≫
Calcium carbonate was applied to the upper part of the inner wall of a plastic cup (trade name: KP-200 (manufactured by Konoike Plastics Co., Ltd.)) with an inner diameter of 100 mm and a height of 45 mm to prevent pests from escaping. Five test insects were released into the cup, and 2 mL of each test specimen was treated with a sprayer from a distance of 10 cm. After the treatment, the test insects were transferred to a clean plastic cup, the number of dead insects was counted after 12 hours, and the mortality rate (%) was calculated using the following formula. The test was conducted at 25° C. under bright conditions, and the average value of three tests is listed in Table 2 as the mortality rate (%).
≪Stink bug insecticidal test≫
Similar to the above-mentioned "Ants/Isopods/Slugs insecticidal test," the number of insects killed after 24 hours was calculated using 3 to 5 test insects for the German green stink bug, Japanese stink bug, southern stink bug, and white stink bug. They were counted and the mortality rate (%) was calculated using the following formula. The test was conducted once at 25° C. under bright conditions.
≪Japanese snail insecticidal test≫
Similar to the above "Ants/Isopods/Slugs Insect Killing Test", one Japanese snail was tested, mortality was confirmed after 12 hours, and the mortality rate (%) was calculated using the following formula. . The test was conducted once at 25° C. under bright conditions.
≪Tobizu Kade insecticidal test≫
Calcium carbonate was applied to the upper part of the inner wall of a plastic cup (trade name: KP-860MB (manufactured by Konoike Plastics Co., Ltd.)) with an inner diameter of 130 mm and a height of 100 mm to prevent pests from escaping. One test insect was released into the cup, and 6 mL of each test specimen was treated with a sprayer from a distance of 10 cm. After the treatment, the test insects were transferred to a clean plastic cup, mortality was confirmed 24 hours later, and the mortality rate (%) was calculated using the following formula. The test was conducted once at 25° C. under bright conditions.
[Formula]: Mortality rate (%) = Number of test insects killed / Total number of test insects x 100
表2に示したとおり、本発明のペラルゴン酸のアンモニウム塩を有効成分とした実施例1の害虫防除剤は、各種害虫に対して優れた殺虫効果を奏することが明らかとなった。 As shown in Table 2, it was revealed that the pest control agent of Example 1 containing the ammonium salt of pelargonic acid of the present invention as an active ingredient had excellent insecticidal effects against various pests.
実施例1と同様にして、表1に記載した実施例2~6について各種害虫に対する殺虫効果を確認した結果、以下のとおり優れた殺虫効果を奏することが確認された。
クロヤマアリ、クサギカメムシ、ミナミアオカメムシ、ホソヘリカメムシに対して実施例2を処理した結果、致死率は93.3%、100%、100%および100%であった。
ニッポンマイマイ、ホソヘリカメムシに対して、実施例3を処理した結果、いずれも致死率は100%であった。
ダンゴムシ、ワラジムシに対して実施例3~4を処理した結果、いずれも致死率は100%であった。
ダンゴムシ、ワラジムシおよびナメクジに対して実施例5を処理した結果、致死率は、80%、86.7%および100%であった。
ダンゴムシ、ナメクジに対して実施例6を処理した結果、致死率は、73.3%、93%であった。
In the same manner as Example 1, the insecticidal effects against various pests were confirmed for Examples 2 to 6 listed in Table 1, and as a result, it was confirmed that the insecticidal effects were excellent as shown below.
As a result of treating Example 2 with respect to black wood ant, black stink bug, southern green stink bug, and white stink bug, the mortality rate was 93.3%, 100%, 100%, and 100%.
As a result of treating the Japanese snail beetle and the Japanese stink bug in Example 3, the mortality rate was 100% in both cases.
As a result of treating pill bugs and woodlice in Examples 3 and 4, the mortality rate was 100% in both cases.
As a result of treating pill bugs, woodlice, and slugs with Example 5, the mortality rates were 80%, 86.7%, and 100%.
As a result of treating pill bugs and slugs in Example 6, the mortality rate was 73.3% and 93%.
<試験検体の調製2>
表3記載の組成からなる試験検体を調製し、実施例7~9とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 2>
Test specimens having the compositions shown in Table 3 were prepared and designated as Examples 7 to 9. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<忌避試験1>
表4記載の各種害虫を対象として忌避試験1を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿または固形餌を2ヵ所設置した。次に直径5.5cm、ナメクジ対象のみ直径7cmのろ紙に実施例7~9と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫を放ち、30分後の定着数を計数し、下記式にて忌避率(%)を算出した。試験は、25℃、明るい条件下にて行い、2回の平均値を忌避率(%)として表4に記載した。
試験では、クロヤマアリおよびアミメアリは各50頭、ダンゴムシおよびワラジムシは各40頭、ナメクジは20頭を用いた。
忌避率(%)={1-(試験検体定着数)/(試験検体定着数+対照定着数)}×100
以後、式中の「試験検体」とは、実施例または比較例の検体を意味する。
<Repellent test 1>
Repellent test 1 was conducted targeting the various pests listed in Table 4. The outline of the test is shown in Figure 2.
Calcium carbonate was applied to the upper part of the inner wall of a plastic container measuring 25 cm long, 30 cm wide, and 10 cm high to prevent pests from escaping. Inside the container, water-impregnated absorbent cotton or solid bait was placed at two locations as feeding grounds for the test insects. Next, filter paper with a diameter of 5.5 cm and 7 cm in diameter for slugs was impregnated with 2 mL each of Examples 7 to 9 and the control (100% acetone), and the filter paper was placed so as to surround the feeding area.
Next, test insects were released into the container, and the number of settled insects after 30 minutes was counted, and the repellency rate (%) was calculated using the following formula. The test was conducted at 25° C. under bright conditions, and the average value of the two tests is listed in Table 4 as the repellency rate (%).
In the test, 50 each of black wood ants and red-eared ants, 40 each of pillbugs and woodlice, and 20 slugs were used.
Repellency rate (%) = {1-(number of test specimens colonized)/(number of test specimens colonized + number of control colons)}×100
Hereinafter, the "test specimen" in the formula means a specimen of an example or a comparative example.
表4に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、各種害虫に対して優れた忌避効果を奏することが明らかとなった。 As shown in Table 4, it was revealed that the pest control agent containing pelargonic acid as an active ingredient of the present invention has an excellent repellent effect against various pests.
<試験検体の調製3>
表5記載の組成からなる試験検体を調製し、実施例10、比較例2とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 3>
Test specimens having the compositions shown in Table 5 were prepared and designated as Example 10 and Comparative Example 2. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<腹足類防除試験1>
チャコウラナメクジを対象として腹足類防除試験1を実施した。試験の概要は図1に示した。
内径100mm、高さ45mmのプラスチック製カップ(商品名:KP-200(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に供試虫1頭を放ち、10cmの距離から実施例10、比較例2の各試験検体3mLを噴霧器で処理した。処理後、供試虫を観察し完全停止するまでの時間(FT:秒)を測定した。また、チャコウラナメクジの粘液脱ぎ捨て行動の有無、逃亡行動の有無、15分後および24時間後の致死について確認し、その結果を表6に記載した。
表6中の「無」は粘液脱ぎ捨て行動や逃亡行動が無かったことを、「有」は粘液脱ぎ捨て行動や逃亡行動があったことを、「〇」は致死していたことを、「×」は生存していたことを意味する。
<Gastropod control test 1>
Gastropod control test 1 was conducted targeting Chakoura slugs. The outline of the test is shown in Figure 1.
Calcium carbonate was applied to the upper part of the inner wall of a plastic cup (trade name: KP-200 (manufactured by Konoike Plastics Co., Ltd.)) with an inner diameter of 100 mm and a height of 45 mm to prevent pests from escaping. One test insect was released into the cup, and 3 mL of each test specimen of Example 10 and Comparative Example 2 was treated with a sprayer from a distance of 10 cm. After the treatment, the test insects were observed and the time (FT: seconds) until they completely stopped was measured. In addition, the presence or absence of mucus shedding behavior of the Chakoura slug, the presence or absence of escape behavior, and mortality after 15 minutes and 24 hours were confirmed, and the results are listed in Table 6.
In Table 6, "No" indicates that there was no mucus shedding behavior or escape behavior, "Yes" indicates that there was mucus shedding behavior or escape behavior, "〇" indicates that death occurred, and "×" means that he was alive.
一般的に、ナメクジ等の腹足類は、ピレスロイド系殺虫剤を体表に処理しても、体表の粘液を脱ぎ捨てることにより殺虫効果が得られにくいことが知られている。
表6の実施例10の結果より明らかなように、ペラルゴン酸は処理してから行動を完全停止するまでの時間(FT)が191秒(約3分程度)であり、粘液の脱ぎ捨て行動や逃亡行動が見られず、15分以内に致死することが確認された。
一方、比較例2のピレスロイド系殺虫剤の1つであるピレトリンを処理した場合は、公知技術のとおり、体表の粘液脱ぎ捨て行動や逃亡行動が見られ、24時間後も致死しなかった。
表6に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、公知のピレスロイド系殺虫剤では得られない、確実に致死活性が得られる、ナメクジ等の腹足類に対する優れた防除効果を発揮することが明らかとなった。
In general, it is known that even if gastropods such as slugs are treated with pyrethroid insecticides on their body surfaces, it is difficult to obtain insecticidal effects because they shed mucus on their body surfaces.
As is clear from the results of Example 10 in Table 6, the time (FT) from when pelargonic acid was treated to when the behavior completely stopped was 191 seconds (about 3 minutes), and the mucus shedding behavior and escape No movement was observed, and it was confirmed that the animal would die within 15 minutes.
On the other hand, when the animals were treated with pyrethrin, which is one of the pyrethroid insecticides in Comparative Example 2, as is known in the art, they shed mucus on the body surface and escaped, and no mortality occurred even after 24 hours.
As shown in Table 6, the insect pest control agent containing pelargonic acid as an active ingredient of the present invention has an excellent control effect against gastropods such as slugs, with reliable lethal activity that cannot be obtained with known pyrethroid insecticides. It has become clear that it is effective.
<試験検体の調製4>
表7記載の組成からなる試験検体を調製し、実施例11、比較例3、4とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 4>
Test specimens having the compositions shown in Table 7 were prepared and designated as Example 11 and Comparative Examples 3 and 4. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<腹足類防除試験2>
チャコウラナメクジを対象として腹足類防除試験2を実施した。試験の概要は図1に示した。
上記「腹足類防除試験1」と同様に試験を行った。処理後、供試虫を観察し完全停止するまでの時間(FT:秒)を測定した。また、チャコウラナメクジの粘液脱ぎ捨て行動の有無、逃亡行動の有無、15分後および24時間後の致死について確認し、その結果を表8に記載した。
表8中の「無」は粘液脱ぎ捨て行動や逃亡行動が無かったことを、「有」は粘液脱ぎ捨て行動や逃亡行動があったことを、「有*」は粘液脱ぎ捨て行動はあるが完全に脱ぎ捨てられずにいたことを、「〇」は致死していたことを、「×」は生存していたことを意味する。
<Gastropod control test 2>
Gastropod control test 2 was conducted targeting Chakoura slugs. The outline of the test is shown in Figure 1.
The test was conducted in the same manner as the above "Gastropod control test 1". After the treatment, the test insects were observed and the time (FT: seconds) until they completely stopped was measured. In addition, the presence or absence of mucus shedding behavior, the presence or absence of escape behavior, and mortality after 15 minutes and 24 hours of the Chakoura slug were confirmed, and the results are listed in Table 8.
In Table 8, "No" indicates that there was no mucus shedding behavior or escape behavior, "Yes" indicates that there was mucus shedding behavior or escape behavior, and "Yes*" indicates that there was mucus shedding behavior but the mucus was completely removed. "〇" means that the patient was not killed, "X" means that the patient was alive.
上述したとおり、ピレスロイド系殺虫剤をナメクジ等の腹足類の体表に処理しても、体表の粘液を脱ぎ捨てることにより殺虫効果が得られにくいが、天然系成分の中には、例えば、L-カルボンのように体表の粘液脱ぎ捨て行動を阻害し致死させるものが存在する一方で、リモネンのように体表の粘液脱ぎ捨て行動を阻害できない成分があることも知られている。
表8の実施例11の結果より明らかなように、ペラルゴン酸は処理してから行動を完全停止するまでの時間(FT)が240秒(約4分程度)であり、粘液の脱ぎ捨て行動や逃亡行動が見られず、15分以内に致死した。
一方、体表の粘液脱ぎ捨て行動を阻害し致死させることが公知のL-カルボンを処理した場合には、ペラルゴン酸処理と同様に逃亡行動は見られず、15分以内に致死したが、体表の粘液脱ぎ捨て行動が見られ、行動を完全停止するまでの時間(FT)が425秒(7分以上)であった。また、リモネンを処理した場合には、体表の粘液脱ぎ捨て行動や逃亡行動が見られ、24時間後も致死に至らなかった。
表8に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、L-カルボン等の公知の腹足類駆除剤よりも優れた防除効果が得られることが明らかとなった。
As mentioned above, even if a pyrethroid insecticide is applied to the body surface of a gastropod such as a slug, it is difficult to obtain an insecticidal effect because the mucus on the body surface is shed, but some natural ingredients, such as L- While there are substances such as carvone that inhibit the action of shedding mucus on the body surface and cause death, it is also known that there are ingredients such as limonene that cannot inhibit the action of shedding mucus on the body surface.
As is clear from the results of Example 11 in Table 8, the time (FT) from when pelargonic acid is treated to when the behavior completely stops is 240 seconds (about 4 minutes), and the time required for pelargonic acid to completely stop its behavior is 240 seconds (approximately 4 minutes). No movement was observed and the animal died within 15 minutes.
On the other hand, when treated with L-carvone, which is known to inhibit mucus shedding behavior on the body surface and cause death, similar to pelargonic acid treatment, no escape behavior was observed and death occurred within 15 minutes, but the body surface Mucus shedding behavior was observed, and the time (FT) until the behavior completely stopped was 425 seconds (more than 7 minutes). In addition, when treated with limonene, behavior such as shedding mucus on the body surface and escape behavior were observed, and death did not occur even after 24 hours.
As shown in Table 8, it has been revealed that the pest control agent containing pelargonic acid as an active ingredient of the present invention has a better control effect than known gastropod insecticides such as L-carvone.
<試験検体の調製5>
表9記載の組成からなる試験検体を調製し、実施例12、比較例5とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 5>
Test specimens having the compositions listed in Table 9 were prepared and designated as Example 12 and Comparative Example 5. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<アリ類忌避試験1>
表10記載のアリ類を対象としてアリ類忌避試験1を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を2ヵ所設置した。次に直径5.5cmのろ紙に実施例12または比較例5と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫(50頭)を放ち、30分後の餌場への定着数を計数し、下記式にて忌避率(%)を算出した。
また、試験検体を含浸させたろ紙に対する侵入回避効果(試験検体を含浸させたろ紙に対しアリ類が触角や歩脚を接触すらさせることなくろ紙の前からUターンする行動を促す効果)の有無についても、確認した。試験は、25℃、明るい条件下にて行い、忌避率(%)として表10に記載した。
忌避率(%)={1-(試験検体定着数)/(試験検体定着数+対照定着数)}×100
表10中の「有」は侵入回避効果が認められたことを、「無」は侵入回避効果が認められなかったことを意味する。
<Ant repellent test 1>
Ant repellent test 1 was conducted using the ants listed in Table 10. The outline of the test is shown in Figure 2.
Calcium carbonate was applied to the upper part of the inner wall of a plastic container measuring 25 cm long, 30 cm wide, and 10 cm high to prevent pests from escaping. Inside the container, water-impregnated absorbent cotton was placed at two locations as feeding grounds for the test insects. Next, filter paper with a diameter of 5.5 cm was impregnated with 2 mL each of Example 12 or Comparative Example 5 and the control (100% acetone), and the filter paper was placed so as to surround the feeding area.
Next, test insects (50 insects) were released into the container, and the number of insects settled on the feeding area after 30 minutes was counted, and the repellency rate (%) was calculated using the following formula.
In addition, whether or not there is an intrusion avoidance effect on the filter paper impregnated with the test specimen (an effect that encourages ants to make a U-turn in front of the filter paper without even touching the antennae or walking legs with the filter paper impregnated with the test specimen). I also confirmed that. The test was conducted at 25° C. under bright conditions, and the repellency rate (%) is shown in Table 10.
Repellency rate (%) = {1-(number of test specimens colonized)/(number of test specimens colonized + number of control colons)}×100
In Table 10, "Yes" means that an intrusion avoidance effect was observed, and "No" means that an intrusion avoidance effect was not observed.
表10の実施例12の結果より明らかなように、ペラルゴン酸はクロヤマアリ、アミメアリのアリ類の種類に関わらず忌避率が100%であり、優れた忌避効果を奏することが確認された。これに対し、ピレスロイド系殺虫剤のフェンプロパトリンは忌避率が50%未満であり、しかもクロヤマアリとアミメアリのようにアリ類の種類により忌避効果に差があった。
さらに、ペラルゴン酸を含浸させたろ紙に対する侵入回避効果をも有することが確認された一方、フェンプロパトリンを含浸させたろ紙に対する、侵入回避効果は認められなかった。
表10に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤よりも優れたアリ類忌避効果および薬剤処理面内に対する侵入回避効果を発揮することが明らかとなった。
As is clear from the results of Example 12 in Table 10, pelargonic acid had a repellency rate of 100% regardless of the type of ants, such as black wood ants and red-eared ants, and it was confirmed that it had an excellent repellent effect. On the other hand, the repellency of the pyrethroid insecticide fenpropathrin was less than 50%, and the repellent effect differed depending on the type of ant, such as the black wood ant and the red-eared ant.
Furthermore, while it was confirmed that it had an intrusion avoidance effect on filter paper impregnated with pelargonic acid, no intrusion avoidance effect was observed on filter paper impregnated with fenpropathrin.
As shown in Table 10, it is clear that the pest control agent containing pelargonic acid as an active ingredient of the present invention exhibits a superior ant repelling effect and intrusion prevention effect to chemically treated surfaces than pyrethroid insecticides. became.
上記「アリ類忌避試験1」において確認された、アリ類侵入回避効果について、詳しく調査するため以下の「アリ類侵入阻害確認試験」と「アリ類侵入阻害詳細確認試験」を行った。
<試験検体の調製6>
下記表11記載の組成からなる試験検体を調製し、実施例13、比較例6~11とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
In order to investigate in detail the ant invasion avoidance effect confirmed in the above "ant repellent test 1", the following "ant invasion inhibition confirmation test" and "ant invasion inhibition detailed confirmation test" were conducted.
<Preparation of test specimen 6>
Test specimens having the compositions shown in Table 11 below were prepared and designated as Example 13 and Comparative Examples 6 to 11. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<アリ類侵入阻害確認試験>
試験の概要は図3に示す。
縦15cm、横20cm、高さ10cmのプラスチック製容器の内壁面上部にアリ類が逃亡しないよう炭酸カルシウムを施した。前記容器内には、アリ類の餌場として、水を含浸した脱脂綿を1ヵ所設置した。次に直径5.5cmのろ紙に試験検体をそれぞれ2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内にアリ類(クロヤマアリ、10頭)を放ち、ろ紙上に侵入したアリ類の数を(a)侵入回数として、10分間カウントした。試験は、25℃、明るい条件下にて行った。
この(a)侵入回数は、触角や歩脚を当該ろ紙に接触させ、さらに前進してろ紙内に侵入した回数を意味する。
上記試験検体の組成とそれぞれの(a)侵入回数を表11に示した。
<Ant invasion inhibition confirmation test>
The outline of the test is shown in Figure 3.
Calcium carbonate was applied to the upper part of the inner wall of a plastic container measuring 15 cm long, 20 cm wide, and 10 cm high to prevent ants from escaping. Inside the container, absorbent cotton impregnated with water was placed at one location as a feeding ground for ants. Next, filter papers each having a diameter of 5.5 cm were impregnated with 2 mL of each test specimen, and the filter papers were placed so as to surround the feeding area.
Next, ants (black wood ants, 10 individuals) were released into the container, and the number of ants that invaded the filter paper was counted for 10 minutes as (a) the number of invasions. The test was conducted at 25° C. under bright conditions.
The number of intrusions (a) means the number of times the antennae or walking legs come into contact with the filter paper, move forward, and enter the filter paper.
Table 11 shows the composition of the above test specimens and the number of penetrations (a) for each.
表11の実施例13の結果より明らかなように、ペラルゴン酸を含浸させたろ紙上にアリ類は侵入することが全くなく、優れた侵入阻害効果を発揮することが確認された。これに対し、ペラルゴン酸と同じ飽和脂肪酸である酪酸(比較例6)を含浸させたろ紙上にアリ類が10分間に49回、カプリル酸(比較例7)を含浸させたろ紙上に25回、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸(比較例8~11)は、それぞれを含浸させたろ紙上に13~15回侵入しており、ペラルゴン酸とは異なり侵入阻害効果を示さないことも明らかとなった。
ペラルゴン酸は、酪酸、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸と炭素数のみが相違する飽和脂肪酸であるが、薬剤処理面内にアリ類が一度も侵入しない、すなわち、薬剤処理面内への侵入阻害効果を発揮する点において、他の脂肪酸と大きく相違することが確認された。
ペラルゴン酸が有する優れた薬剤処理面内への侵入阻害効果は、本発明者が多くの実験を行い初めて確認した格別顕著な効果である。
As is clear from the results of Example 13 in Table 11, ants did not invade the filter paper impregnated with pelargonic acid at all, and it was confirmed that an excellent invasion inhibiting effect was exhibited. In contrast, ants appeared 49 times in 10 minutes on filter paper impregnated with butyric acid (Comparative Example 6), which is the same saturated fatty acid as pelargonic acid, and 25 times on filter paper impregnated with caprylic acid (Comparative Example 7). , capric acid, lauric acid, myristic acid, and palmitic acid (Comparative Examples 8 to 11) invaded the filter paper impregnated with each of them 13 to 15 times, and unlike pelargonic acid, they did not exhibit an invasion inhibiting effect. It also became clear.
Pelargonic acid is a saturated fatty acid that differs only in the number of carbon atoms from butyric acid, caprylic acid, capric acid, lauric acid, myristic acid, and palmitic acid, but ants never invade the chemically treated surface. It was confirmed that this fatty acid differs greatly from other fatty acids in that it exhibits an in-plane invasion inhibiting effect.
The excellent effect of pelargonic acid on inhibiting the entry of chemicals into the treated surface is a particularly remarkable effect that was first confirmed by the present inventor through numerous experiments.
<試験検体の調製7>
下記表12記載の組成からなる試験検体を調製し、実施例14、比較例12~15とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 7>
Test specimens having the compositions shown in Table 12 below were prepared and designated as Example 14 and Comparative Examples 12 to 15. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<アリ類侵入阻害詳細確認試験>
試験の概要は図3に示す。
縦15cm、横20cm、高さ10cmのプラスチック製容器の内壁面上部にアリ類が逃亡しないよう炭酸カルシウムを施した。前記容器内には、アリ類の餌場として、水を含浸した脱脂綿を1ヵ所設置した。次に直径5.5cmのろ紙に試験検体をそれぞれ2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内にアリ類(クロヤマアリ、10頭)を放ち、ろ紙に接近したアリ類の行動を観察した。ろ紙に触角や歩脚を接触させることなくUターンしたアリ類の数を(b)侵入回避回数、ろ紙に触角や歩脚を接触させたが、ろ紙に侵入することなくUターンしたアリ類の数を(c)接触後回避回数として、10分間カウントした。また、(b)侵入回避回数と(c)接触後回避回数の和を(d)侵入阻害回数とした。さらに、(d)侵入阻害回数における(b)侵入回避回数の割合を「侵入回避率(%)」とした。
試験は、25℃、明るい条件下にて行った。
上記試験検体の組成とそれぞれの(b)侵入回避回数、(c)接触後回避回数、(d)侵入阻害回数、侵入回避率(%)を表12に示した。
<Detailed confirmation test for inhibiting ant invasion>
The outline of the test is shown in Figure 3.
Calcium carbonate was applied to the upper part of the inner wall of a plastic container measuring 15 cm long, 20 cm wide, and 10 cm high to prevent ants from escaping. Inside the container, absorbent cotton impregnated with water was placed at one location as a feeding ground for ants. Next, filter papers each having a diameter of 5.5 cm were impregnated with 2 mL of each test specimen, and the filter papers were placed so as to surround the feeding area.
Next, ants (10 black mountain ants) were released into the container, and the behavior of the ants that approached the filter paper was observed. The number of ants that made a U-turn without touching the filter paper with their antennae or walking legs (b) Number of invasion avoidance, the number of ants that made a U-turn without touching the filter paper with their antennae or legs, The number was counted as (c) the number of avoidance after contact for 10 minutes. Furthermore, the sum of (b) the number of times of intrusion avoidance and (c) the number of times of avoidance after contact was defined as (d) the number of times of intrusion inhibition. Furthermore, the ratio of (b) number of intrusion avoidance to (d) number of intrusion inhibition was defined as "intrusion avoidance rate (%)".
The test was conducted at 25° C. under bright conditions.
Table 12 shows the composition of the test specimens and their respective (b) number of intrusion avoidance, (c) number of avoidance after contact, (d) number of intrusion inhibition, and intrusion avoidance rate (%).
表12の実施例14の結果より明らかなように、ペラルゴン酸を含浸させたろ紙の前からUターンする(d)侵入阻害回数は、炭素数のみが相違する飽和脂肪酸である酪酸、カプリル酸、カプリン酸、ラウリン酸(比較例12~15)に比べて約1.5~4倍程度高く、ペラルゴン酸は極めて優れた薬剤処理面内への侵入阻害効果を有することが明らかとなった。中でも、ペラルゴン酸は、薬剤処理面にアリ類が触角や歩脚を接触すらさせずに薬剤処理面の前からUターンする(b)侵入回避回数が、触角や歩脚を接触さてからUターンする(c)接触後回避回数に比べて概略5倍程度高いことも確認された。このことは、(d)侵入阻害回数における(b)侵入回避回数の割合を意味する「侵入回避率(%)」が、ペラルゴン酸(実施例14)は、酪酸、カプリル酸、カプリン酸、ラウリン酸(比較例12~15)に比べて極めて高いことからも、明白である。
すなわち、ペラルゴン酸は、アリ類が触角や歩脚を薬剤処理面に接触させることを抑制し、薬剤処理面内にアリ類が侵入することを確実に阻害する優れた効果を発揮することが明らかとなった。
As is clear from the results of Example 14 in Table 12, the number of (d) entry inhibition of U-turn from the front of the filter paper impregnated with pelargonic acid is greater than that of butyric acid, caprylic acid, which are saturated fatty acids that differ only in the number of carbon atoms. This was approximately 1.5 to 4 times higher than that of capric acid and lauric acid (Comparative Examples 12 to 15), making it clear that pelargonic acid has an extremely excellent effect of inhibiting the penetration of chemicals into the treated surface. Among them, pelargonic acid is effective for ants to make a U-turn from in front of the chemical-treated surface without even touching the chemical-treated surface with their antennae or walking legs. (c) It was also confirmed that the number of avoidance after contact was approximately five times higher. This means that the "invasion avoidance rate (%)", which means the ratio of (b) the number of invasion avoidance to the number of (d) invasion inhibition, is This is clear from the fact that it is extremely high compared to acids (Comparative Examples 12 to 15).
In other words, it is clear that pelargonic acid has the excellent effect of inhibiting ants from coming into contact with the chemically treated surface with their antennae and walking legs, and reliably preventing ants from invading into the chemically treated surface. It became.
<試験検体の調製8>
表13記載の組成からなる試験検体を調製し、実施例15、比較例16とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 8>
Test specimens having the compositions shown in Table 13 were prepared and designated as Example 15 and Comparative Example 16. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<アリ類忌避試験2>
表14記載のアリ類を対象としてアリ類忌避試験2を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう逃亡処理を施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を2ヵ所設置した。次に直径5.5cmのろ紙に実施例15または比較例16と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。容器内に供試虫を放ち、30分後の定着数を計数し、下記式にて忌避率(%)を算出した。これを「初期」の忌避率とする。
次いで、直径5.5cmのろ紙に実施例15または比較例16と対照(アセトン100%)を各2mLずつ含浸させ、1週間ドラフト内で風乾させた。上記と同様の試験を1週間風乾させたろ紙を用いて再度行い、12時間後の定着数を係数し、下記式にて忌避率(%)を算出した。これを「1週間後」の忌避率とした。試験は、25℃、明るい条件下にて行い、2回の平均値を忌避率(%)を表14に記載した。
忌避率(%)={1-(試験検体定着数)/(試験検体定着数+対照定着数)}×100
<Ant repellent test 2>
Ant repellent test 2 was conducted using the ants listed in Table 14. The outline of the test is shown in Figure 2.
Escape treatment was applied to the upper part of the inner wall of a plastic container measuring 25 cm in length, 30 cm in width, and 10 cm in height to prevent pests from escaping. Inside the container, water-impregnated absorbent cotton was placed at two locations as feeding grounds for the test insects. Next, filter paper with a diameter of 5.5 cm was impregnated with 2 mL each of Example 15 or Comparative Example 16 and the control (100% acetone), and the filter paper was placed so as to surround the feeding area. Test insects were released into the container, and the number of settled insects was counted after 30 minutes, and the repellency rate (%) was calculated using the following formula. This is taken as the "initial" repellency rate.
Next, a filter paper with a diameter of 5.5 cm was impregnated with 2 mL each of Example 15 or Comparative Example 16 and the control (100% acetone), and air-dried in a fume hood for one week. The same test as above was conducted again using filter paper that had been air-dried for one week, and the number of fixations after 12 hours was calculated as a coefficient to calculate the repellency rate (%) using the following formula. This was defined as the repellency rate "after one week". The test was conducted at 25° C. under bright conditions, and the average value of the two tests is shown in Table 14 as the repellency rate (%).
Repellency rate (%) = {1-(number of test specimens colonized)/(number of test specimens colonized + number of control colons)}×100
表14の実施例15の結果より明らかなように、ペラルゴン酸はクロヤマアリ、アミメアリに対して、初期、1週間後ともに忌避率が100%であることが確認された。これに対し、アリ類に対する天然成分由来の忌避成分として知られているサリチル酸ベンジル(比較例16)は、初期の忌避率はクロヤマアリ、アミメアリともに100%であるものの、1週間後の忌避率は、クロヤマアリに対しては46.2%、アミメアリに対しては84.8%と、忌避率が低下することが明らかとなった。この忌避率の低下は、サリチル酸ベンジルが揮散性の高い薬剤であることから、1週間風乾させたろ紙には、忌避活性に十分なサリチル酸ベンジルが残存していないことに起因するものと考えられる。
これらの結果より、本発明のペラルゴン酸を有効成分とした害虫防除剤は、長期間安定したアリ類忌避効果を発揮することが明らかとなった。
As is clear from the results of Example 15 in Table 14, it was confirmed that pelargonic acid had a repellency rate of 100% against black wood ants and red-eared ants both initially and after one week. On the other hand, benzyl salicylate (Comparative Example 16), which is known as a naturally derived repellent ingredient for ants, has an initial repellency rate of 100% for both black wood ants and red-eared ants, but after one week, the repellency rate is It became clear that the repellency rate was 46.2% against black wood ants and 84.8% against red-eared ants. This decrease in repellency is thought to be due to the fact that, since benzyl salicylate is a highly volatile drug, not enough benzyl salicylate remains in the filter paper air-dried for one week to have repellent activity.
These results revealed that the pest control agent containing pelargonic acid as an active ingredient of the present invention exhibits a stable ant repellent effect over a long period of time.
<試験検体の調製9>
表15記載の組成からなる試験検体を調製し、実施例16、比較例17とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 9>
Test specimens having the compositions shown in Table 15 were prepared and designated as Example 16 and Comparative Example 17. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<等脚目類防除試験1>
表16記載の等脚目類を対象として等脚目類防除試験1を実施した。試験の概要は図2に示した。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を2ヵ所設置した。次に直径5.5cmのろ紙に実施例16または比較例17と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫(20頭)を放ち、30分後の餌場への定着数を計数し、下記式にて忌避率(%)を算出した。また、試験検体を含浸させたろ紙に対する侵入回避効果(試験検体を含浸させたろ紙に対し等脚目類が触角や歩脚を接触すらさせることなくろ紙の前からUターンする行動を促す効果)の有無についても確認した。試験は、25℃、明るい条件下にて行い、忌避率(%)として表16に記載した。
忌避率(%)={1-(試験検体定着数)/(試験検体定着数+対照定着数)}×100
表16中の「有」は侵入回避効果が認められたことを、「無」は侵入回避効果が認められなかったことを意味する。
<Isopod control test 1>
Isopod control test 1 was conducted targeting the isopods listed in Table 16. The outline of the test is shown in Figure 2.
Calcium carbonate was applied to the upper part of the inner wall of a plastic container measuring 25 cm long, 30 cm wide, and 10 cm high to prevent pests from escaping. Inside the container, water-impregnated absorbent cotton was placed at two locations as feeding grounds for the test insects. Next, filter paper with a diameter of 5.5 cm was impregnated with 2 mL each of Example 16 or Comparative Example 17 and the control (100% acetone), and the filter paper was placed so as to surround the feeding area.
Next, test insects (20 insects) were released into the container, and the number of insects settled on the feeding area after 30 minutes was counted, and the repellency rate (%) was calculated using the following formula. In addition, it has an effect of avoiding intrusion on filter paper impregnated with the test specimen (effect that encourages isopods to make a U-turn in front of the filter paper without even touching their antennae or walking legs with the filter paper impregnated with the test specimen). We also confirmed the presence or absence of The test was conducted at 25° C. under bright conditions, and is listed in Table 16 as the repellency rate (%).
Repellency rate (%) = {1-(number of test specimens colonized)/(number of test specimens colonized + number of control colons)}×100
In Table 16, "Yes" means that an intrusion avoidance effect was observed, and "No" means that an intrusion avoidance effect was not observed.
表16の実施例16の結果より明らかなように、ペラルゴン酸はダンゴムシ、ワラジムシに対して、市販のダンゴムシ忌避剤の有効成分としても使用され、ピレスロイド系殺虫剤として公知のピレトリン(比較例17)に比べ、高い忌避活性を示すことが明らかとなった。さらに、ペラルゴン酸を含浸させたろ紙に対する侵入回避効果をも有することが確認された。
表16に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤よりも優れた等脚目類防除効果を発揮することが明らかとなった。
As is clear from the results of Example 16 in Table 16, pelargonic acid is also used as an active ingredient in commercially available pill bug repellents against pill bugs and woodlice, and pyrethrin (comparative example 17), which is known as a pyrethroid insecticide, It was revealed that it exhibited high repellent activity compared to . Furthermore, it was confirmed that it also has the effect of preventing intrusion into filter paper impregnated with pelargonic acid.
As shown in Table 16, it has been revealed that the pest control agent containing pelargonic acid as an active ingredient of the present invention exhibits a superior effect on controlling isopods than pyrethroid insecticides.
<試験検体の調製10>
表17記載の組成からなる試験検体を調製し、実施例17、比較例18、19とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 10>
Test samples having the compositions shown in Table 17 were prepared and designated as Example 17 and Comparative Examples 18 and 19. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<等脚目類防除試験2>
表18記載の等脚目類を対象として等脚目類防除試験2を実施した。試験の概要は図3に示した。
縦15cm、横20cm、高さ10cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を1ヵ所設置した。次に直径5.5cmのろ紙に実施例17、比較例18または比較例19と対照(アセトン100%)を各2mLずつ含浸させ、餌場を囲うようにろ紙を設置した。
次に、容器内に供試虫(10頭)を放ち、ろ紙への侵入回数と侵入阻害回数(試験検体を含浸させたろ紙に対し等脚目類が触角や歩脚を接触すらさせることなくろ紙の前からUターンする回数と、触角や歩脚を当該ろ紙に接触させたとしても当該ろ紙に侵入することなくUターンする回数の和)を、15分間計数し、下記式にて侵入阻害率(%)を算出した。試験は、25℃、明るい条件下にて行い、侵入阻害率(%)を表18に記載した。
侵入阻害率(%)={(侵入阻害回数)/(侵入回数+侵入阻害回数)}×100
<Isopod control test 2>
Isopod control test 2 was conducted targeting the isopods listed in Table 18. The outline of the test is shown in Figure 3.
Calcium carbonate was applied to the upper part of the inner wall of a plastic container measuring 15 cm long, 20 cm wide, and 10 cm high to prevent pests from escaping. Inside the container, absorbent cotton impregnated with water was placed at one location as a feeding ground for the test insects. Next, filter paper with a diameter of 5.5 cm was impregnated with 2 mL each of Example 17, Comparative Example 18, or Comparative Example 19, and the control (100% acetone), and the filter paper was placed so as to surround the feeding area.
Next, test insects (10 insects) were released into the container, and the number of times they invaded the filter paper and the number of times they inhibited their entry (the isopods did not even touch the antennae or walking legs to the filter paper impregnated with the test sample). The sum of the number of U-turns from in front of the filter paper and the number of U-turns without entering the filter paper even if the antennae or walking legs touch the filter paper is counted for 15 minutes, and the invasion inhibition is calculated using the following formula. The rate (%) was calculated. The test was conducted at 25° C. under bright conditions, and the invasion inhibition rate (%) is listed in Table 18.
Invasion inhibition rate (%) = {(Number of invasion inhibition)/(Number of invasion + Number of invasion inhibition)}×100
表18の実施例17の結果より明らかなように、ペラルゴン酸はダンゴムシ、ワラジムシに対して、ピレスロイド系殺虫剤の中でも揮散性が高いことが公知のエンペントリン(比較例18)やプロフルトリン(比較例19)に比べ、侵入阻害回数が多い一方で侵入回数が極めて低いことが明らかとなった。
また、エンペントリン(比較例18)やプロフルトリン(比較例19)の試験系においては、試験終了後に致死個体が確認されたが、ペラルゴン酸の試験系では、致死個体は確認されなかった。ペラルゴン酸を直接等脚目類に処理しないこの試験系においては、忌避効果および侵入阻害効果のみが発揮されることも確認された。
表18に示したとおり、本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤よりも優れた等脚目類防除効果を発揮することが明らかとなった。
As is clear from the results of Example 17 in Table 18, pelargonic acid is effective against pill bugs and woodlice, such as empenthrin (Comparative Example 18) and profluthrin (Comparative Example 19), which are known to have high volatility among pyrethroid insecticides. ), it became clear that while the number of invasion inhibition was high, the number of invasions was extremely low.
Furthermore, in the test systems for empenthrin (Comparative Example 18) and profluthrin (Comparative Example 19), lethal individuals were confirmed after the test, but in the test system for pelargonic acid, no lethal individuals were confirmed. It was also confirmed that in this test system, in which pelargonic acid is not directly applied to isopods, only repellent and invasion inhibiting effects are exerted.
As shown in Table 18, it has been revealed that the pest control agent containing pelargonic acid as an active ingredient of the present invention exhibits a superior effect on controlling isopods than pyrethroid insecticides.
<試験検体の調製11>
下記表19記載の組成からなる試験検体を調製し、実施例18、比較例20とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 11>
Test specimens having the compositions shown in Table 19 below were prepared and designated as Example 18 and Comparative Example 20. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<ムカデ忌避確認試験>
試験の概要は図3に示した。
縦25cm、横30cm、高さ30cmのプラスチック製容器の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。直径10cmのろ紙に実施例18と比較例20(アセトン100%)を各4mLずつ含浸させ、前記容器内に設置し、ろ紙上に市販の毒餌(アース製薬(株)ムカデコロリ(毒餌剤)容器タイプ)を載置した。
次に、容器内に1日絶食させたトビズムカデ1頭を放ち、24時間後の致死を確認した
。試験は、25℃、明るい条件下にて行い、忌避評価結果を表20に記載した。
この確認試験ではろ紙上に侵入してはじめて餌(毒餌)を摂食できるため、忌避評価結果は、トビズムカデが致死した場合には忌避効果はなく「×」と、トビズムカデが致死していない場合は忌避効果があるとして「〇」と表記した。
<Centipede repellent confirmation test>
The outline of the test is shown in Figure 3.
Calcium carbonate was applied to the upper part of the inner wall of a plastic container measuring 25 cm long, 30 cm wide, and 30 cm high to prevent pests from escaping. Filter paper with a diameter of 10 cm was impregnated with 4 mL each of Example 18 and Comparative Example 20 (100% acetone), placed in the container, and a commercially available poison bait (Earth Pharmaceutical Co., Ltd. Centipede Colori (poison bait) container type) was placed on the filter paper. ) was placed.
Next, one black-spotted caddisfly that had been fasted for one day was released into the container, and mortality was confirmed 24 hours later. The test was conducted at 25° C. under bright conditions, and the repellency evaluation results are listed in Table 20.
In this confirmation test, the bait (poisonous bait) can only be ingested after entering the filter paper, so the repellency evaluation results are "x" if the black-throated crested crested crested crest is killed because there is no repellent effect, and if the crested crested crested crested crested crest is not killed, then the repellent effect is "x". It is marked as "〇" because it has a repellent effect.
表19に示したとおり、ペラルゴン酸は、ムカデに対しても優れた忌避効果を奏することが明らかとなった。 As shown in Table 19, it was revealed that pelargonic acid also has an excellent repellent effect against centipedes.
<試験検体の調製12>
下記表20記載の組成からなる試験検体を調製し、実施例19とした。試験検体の調製に際しては、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌した。
<Preparation of test specimen 12>
A test sample having the composition shown in Table 20 below was prepared and designated as Example 19. When preparing the test sample, each component was mixed and stirred using a magnetic stirrer so that the composition was uniform.
<カメムシ忌避確認試験>
試験の概要は図4に示した。
内径130mm、高さ100mmのプラスチック製カップ(商品名:KP-860MB(鴻池プラスチック社製))の内壁面上部に害虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に、供試虫の餌場として水を含浸した脱脂綿を2ヵ所設置し、片方の餌場に実施例19の試験検体を2mL含浸させた。
次に、前記カップ内に表21記載の供試虫(5頭)を放ち、24時間後の餌場への定着数を計数し、下記式にて忌避率(%)を算出した。
忌避率(%)={1-(試験検体定着数)/(試験検体定着数+対照定着数)}×100
試験は25℃、明るい条件下にて行い、忌避率(%)を表21に記載した。
<Stink bug repellent confirmation test>
The outline of the test is shown in Figure 4.
Calcium carbonate was applied to the upper part of the inner wall of a plastic cup (trade name: KP-860MB (manufactured by Konoike Plastics Co., Ltd.)) with an inner diameter of 130 mm and a height of 100 mm to prevent pests from escaping. Absorbent cotton impregnated with water was placed in two places in the cup as feeding areas for the test insects, and one feeding area was impregnated with 2 mL of the test specimen of Example 19.
Next, test insects (5 insects) listed in Table 21 were released into the cup, and the number of insects settled on the feeding area after 24 hours was counted, and the repellency rate (%) was calculated using the following formula.
Repellency rate (%) = {1-(number of test specimens colonized)/(number of test specimens colonized + number of control colons)}×100
The test was conducted at 25° C. under bright conditions, and the repellency rate (%) is shown in Table 21.
表21に示したとおり、ペラルゴン酸は、カメムシに対しても種類を問わず良好な忌避活性を奏することが明らかとなった。 As shown in Table 21, it was revealed that pelargonic acid has good repellent activity against stink bugs regardless of their species.
本発明のペラルゴン酸を有効成分とした害虫防除剤は、ピレスロイド系殺虫剤等の公知の薬剤に比べ、優れた害虫防除効果、特に害虫忌避効果や、侵入阻害効果若しくは侵入回避効果を奏するものである。詳しくは、本発明の害虫防除剤は、腹足類、等脚目類、アリ類、半翅目類、多足類に対して優れた致死活性を有するものであり、さらには、腹足類、等脚目類、アリ類、多足類に対して優れた忌避効果や侵入阻害効果を発揮するものである。
本発明の侵入阻害効果は、ペラルゴン酸またはその塩を有効成分とする薬剤処理面に対し、害虫が触角や歩脚を接触することなく薬剤処理面の前からUターン行動をとる、若しくは接触させたとしても薬剤処理面の前からUターン行動をとることに起因する、優れた効果である。
本発明の害虫防除剤は、除草活性を有するペラルゴン酸またはその塩を有効成分としているため、散布した場所の除草効果も同時に得ることができる。これにより、本発明の害虫防除剤を家屋等の建造物の入り口付近や駐車場などに処理することにより、薬剤に接触した害虫は致死し、薬剤処理面内に対しては害虫が侵入することを確実に阻害するので、家屋内や車内等に害虫を侵入させることがなく、さらに処理した場所の雑草の繁殖を抑制する効果が得られるという特徴を有するものである。
本発明の害虫防除剤が奏するこれらの効果は、本発明者により新たに見出された知見であり、格別顕著な効果である。
The pest control agent containing pelargonic acid as an active ingredient of the present invention exhibits superior pest control effects, particularly pest repellent effects, invasion inhibiting effects, or invasion avoidance effects, compared to known agents such as pyrethroid insecticides. be. Specifically, the insect pest control agent of the present invention has excellent lethal activity against gastropods, isopods, ants, hemiptera, and myriapods; It exhibits excellent repellent and invasion inhibiting effects against species, ants, and myriapods.
The invasion inhibiting effect of the present invention is such that pests make a U-turn from in front of the chemically treated surface without touching the chemically treated surface with their antennae or walking legs, or are allowed to come in contact with the chemically treated surface containing pelargonic acid or its salt as an active ingredient. Even so, this is an excellent effect resulting from taking a U-turn action from before the drug treatment surface.
Since the pest control agent of the present invention contains pelargonic acid or its salt, which has herbicidal activity, as an active ingredient, it is possible to simultaneously obtain a herbicidal effect in the area where it is sprayed. As a result, by applying the pest control agent of the present invention near the entrance of buildings such as houses, parking lots, etc., pests that come into contact with the agent are killed, and pests do not invade into the area treated with the agent. Since it reliably inhibits the spread of pests, it prevents pests from entering the inside of houses, cars, etc., and it also has the advantage of suppressing the proliferation of weeds in the treated area.
These effects exhibited by the pest control agent of the present invention are newly discovered findings by the present inventor, and are particularly remarkable effects.
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JP2012524072A (en) | 2009-04-17 | 2012-10-11 | ストラータコー,インコーポレイティド | Insecticidal compositions for insects and arthropods |
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