KR20000072252A - Composition and preparation of natural plant essential oil for use as insecticidal and antimicrobial agents - Google Patents
Composition and preparation of natural plant essential oil for use as insecticidal and antimicrobial agents Download PDFInfo
- Publication number
- KR20000072252A KR20000072252A KR1020000048716A KR20000048716A KR20000072252A KR 20000072252 A KR20000072252 A KR 20000072252A KR 1020000048716 A KR1020000048716 A KR 1020000048716A KR 20000048716 A KR20000048716 A KR 20000048716A KR 20000072252 A KR20000072252 A KR 20000072252A
- Authority
- KR
- South Korea
- Prior art keywords
- composition
- essential oil
- weight
- bactericidal
- insecticidal
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/46—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=C=S groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Pest Control & Pesticides (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Botany (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
본 발명은 바퀴, 모기, 파리, 개미 등의 가정위생해충에 대한 구제효과 및 항균효과를 갖는 살균·살충제 조성물에 관한 것이다. 특히 본 발명은 겨자, 레몬, 생강 등 각종 식물체에서 추출한 식물성 정유를 살균·살충 성분으로 하는 살충제 조성물 및 그 제제에 관한 것이다.The present invention relates to a bactericidal / insecticide composition having a control effect and an antibacterial effect against domestic hygiene pests such as wheels, mosquitoes, flies, and ants. In particular, the present invention relates to insecticide compositions and preparations thereof, wherein the vegetable essential oils extracted from various plants such as mustard, lemon and ginger are used as sterilizing and insecticidal components.
종래 가정위생해충 구제용 살충제로는 피레트로이드계 살충제 (예를 들어, 알레트린(Allethrin), 프탈트린(Phthalthrin), 레스메트린(Retsmethrin), 카데트린 (Kadethrin), 펜발러레이트(Fenvalerate), 퍼메스린(Permethrin), 사이퍼메스린 (Cypermethrin), 델타메스린(Deltamethrin) 등)와 유기인계 살충제 (예를 들어, 디클로르보스(Dichlorvos), 클로르피리포스(Chlorpyrifos), 펜티온(Fenthion) 디메토에이트(Dimethoate), 페니트로티온(Fenitrothion), 피리미포스메틸 (Pyrimiphosmethyl) 등)가 사용되고 있으며, 이들 살충제의 효과를 상승시키기 위해 피페로닐 부톡사이드(piperonyl butoxide)와 같은 효과 상승제 및 페르몬 등이 첨가되기도 한다.Conventional insecticides for controlling home hygiene pests include pyrethroid insecticides (eg, allethrin, phthalthrin, resmethrin, cadthrin, penvalerate, Permethrin, Cypermethrin, Deltamethrin, etc.) and organophosphorus insecticides (e.g., Dichlorvos, Chlorpyrifos, Penthion) Dimethoate, Fenitrothion, Pyrimiphosmethyl, etc.) are used, and effect-boosting agents such as piperonyl butoxide to enhance the effectiveness of these pesticides, and Permone may be added.
그러나 이러한 종래의 유기합성 살충제는 종종 잔류독성, 인체에 미치는 영향, 여러 해충 종에서의 저항성 획득 등이 문제되고 있다.However, such conventional organic synthetic insecticides are often problematic in terms of residual toxicity, effects on the human body, and obtaining resistance from various pest species.
최근 이러한 문제를 해결하기 위한 방안으로, 환경 친화적이고 인체나 가축에 대한 독성이 약한 천연 식물성 물질을 해충 구제제로 이용하려는 연구가 이루어지고 있다.Recently, as a way to solve this problem, research has been made to use natural plant materials that are environmentally friendly and have low toxicity to humans or livestock as pest control agents.
예를 들면, 덴네티아 트리페탈라(Dennettia tripetala)의 식용과실에서 추출한 오일이 미국바퀴(Periplaneta americana)에 대해 독성이 있다는 보고가 있으며, 리모넨(limonene)은 독일바퀴의 난협에서 새끼가 발달하고 성장하는 것을 억제한다는 연구보고가 있다.For example, oils from edible fruits of Dennettia tripetala have been reported to be toxic to Periplaneta americana, and limonene has been developed and developed in the gyrus of German laps. There is a research report to discourage doing.
식물에서 추출한 방향성분 조성물에 관한 종래 특허들을 살펴보면,Looking at the conventional patents relating to the aromatic composition extracted from the plant,
미국 특허 4,455,304호에서 야라리안(Yaralian)은 고추(capsicum)를 이용한 동물 기피제 조성물을 발표하였다. 이 특허에서 개시하고 있는 것은 단지 고추와 마늘 추출물로 만든 조성물과 이 조성물의 이용방법에 관한 것이다.In US Pat. No. 4,455,304 Yarralian discloses animal repellent compositions using capsicum. What is disclosed in this patent only relates to compositions made from pepper and garlic extracts and to methods of using the compositions.
미국 특허 4,440,783호에서 다우닝(Downing)은 이소티오시아네이트 (Isothiocyanate)와 레몬오일을 이용하여 쓰레기로부터 너구리, 개와 같은 동물들을 쫓는 조성물을 발표하였다.In US Pat. No. 4,440,783, Downing published a composition that uses isothiocyanate and lemon oil to chase animals such as raccoons and dogs from litter.
국제 특허 99/22751호에서 루이스(Louis)는 고추 추출물, 아릴 이소티오시아네이트(allyl isothiocyanate)와 레몬 오일의 조합물을 토양처리제, 살충제, 저장곡물 및 건물 훈증소독제로 메틸 브로마이드(methyl bromide)의 대체물질로서 사용하는 것에 관해 개시하고 있다.In International Patent 99/22751 Louis combines pepper extract, allyl isothiocyanate and lemon oil with a combination of methyl bromide as soil treatment, insecticide, storage grain and building fumigant. Disclosed is the use as a substitute.
또한, 아릴 이소티오시아네이트(allyl isothiocyanate)의 항균효과를 이용한 식품보존제, 필름 등에 관한 특허들이 출원되어 있다.In addition, patents have been filed on food preservatives, films and the like using the antimicrobial effect of aryl isothiocyanate.
그러나 아직까지 식물 추출물을 이용하여 바퀴, 파리, 모기, 개미 등의 가정위생해충 구제제로 효과적으로 이용한 사례는 없다.However, there have been no effective cases of using plant extracts to control home hygiene pests such as wheels, flies, mosquitoes and ants.
따라서, 본 발명은 각종 식물로부터 추출한 천연 식물성 정유를 이용하여 환경친화적이며 잔류독성이 없고 인체와 가축에 안전한 살균·살충제 조성물을 제공하는 것을 목적으로 한다.Accordingly, an object of the present invention is to provide a sterilizing and insecticidal composition that is environmentally friendly, does not have residual toxicity, and is safe for humans and livestock using natural vegetable essential oils extracted from various plants.
특히 본 발명은 천연 식물성 정유를 이용한 살균·살충제 조성물로서 바퀴, 파리, 모기, 개미 등 가정위생해충 구제효과 및 곰팡이 발생을 억제하는 항균효과가 우수하여 종래의 유기 살충제를 대체할 수 있는 살균·살충제 조성물을 제공하는 것을 목적으로 한다.In particular, the present invention is a bactericidal / insecticide composition using natural vegetable essential oils, which has excellent antibacterial effect for controlling household hygiene pests such as wheels, flies, mosquitoes, ants, and antibacterial effects and can replace conventional organic insecticides. It is an object to provide a composition.
또한, 본 발명은 상기 천연 식물성 정유 조성물이 우수한 살균·살충 작용을 나타낼 수 있도록 하는 동시에 그 적용을 용이하게 하는 효과적인 제형을 제공하는 것을 목적으로 한다.In addition, an object of the present invention is to provide an effective formulation that allows the natural vegetable essential oil composition to exhibit excellent bactericidal and insecticidal action and at the same time facilitates its application.
본 발명에서는 여러 식물에서 추출한 천연 식물성 정유로 가정위생해충 구제효과 및 항균효과를 가진 살균·살충 조성물을 만들고, 이 조성물을 에어로졸, 훈증제, 마이크로캡슐화한 분말제 등의 효과적인 제형으로 제조한다.In the present invention, a natural vegetable essential oil extracted from various plants is used to make a disinfectant and insecticidal composition having a home hygiene pest control effect and an antimicrobial effect, and prepare the composition in an effective formulation such as aerosol, fumigant and microencapsulated powder.
본 발명의 살균·살충제 조성물은 겨자정유 0.01∼30 중량%와; 레몬정유 0.01∼30 중량%와; 생강 추출물 및 백리향 추출물로부터 선택된 1 이상의 식물성 정유 0.01∼30 중량%와; 유기용제 잔부를 포함한다(이하, 본 발명의 "살충제 조성물"이라 한다).Sterilizing and insecticidal composition of the present invention is 0.01-30% by weight of mustard oil; 0.01-30% by weight of lemon essential oil; 0.01-30% by weight of one or more vegetable essential oils selected from ginger extract and thyme extract; It contains the organic solvent remainder (henceforth "the pesticide composition" of this invention).
본 발명의 살충제 조성물에 포함되는 식물성 정유는 모두 식물체에서 추출한 방향성이 있는 물질로, 이들 방향성 물질은 종래부터 조미료, 화장품, 세제 등의 방향산업과 풍미산업에서 사용되어 온 것으로 환경과 인체에 대해 안전하며 잔류독성이 없다.The vegetable essential oils included in the pesticide composition of the present invention are all aromatic substances extracted from plants, and these aromatic substances have been used in aroma and flavor industries such as seasonings, cosmetics and detergents, and are safe for the environment and human body. No residual toxicity.
본 발명의 조성물의 첫번째 구성성분인 겨자정유는 아릴 이소티오시아네이트 (allyl isothiocyanate)로 이루어져 있다. 아릴 이소티오시아네이트(allyl isothiocyanate)는 자극적인 냄새를 가지고 있으며 휘발성이 강한 정유로 향균효과 및 방충효과가 있다.Mustard oil, which is the first component of the composition of the present invention, consists of aryl isothiocyanate. Aryl isothiocyanate has an irritating odor and is a highly volatile essential oil with antibacterial and insect repellent effects.
두번째 구성성분인 레몬정유는, 레몬오일, 디레몬엔(dlemonene), 시트로넬라 오일(citronella oil), 오렌지 오일, 만다린 오일(mandarin oil), 오렌지 터핀(orenge terpene), 시트러스 터핀(citrus terpene), 레몬 터핀(lemon terpene), 라임 터핀(lime terpene) 등의 물질로 이루어져 있다. 이 레몬정유는 살균효과 및 방향성 효과를 가지고 있어 살균제로 사용될 수 있다.The second ingredient, lemon essential oil, is lemon oil, dlemonene, citronella oil, orange oil, mandarin oil, orange terpene, citrus terpene , Lemon terpene (lemon terpene), lime terpene (lime terpene) and other materials. This lemon essential oil has a bactericidal and aromatic effect and can be used as a fungicide.
세번째 구성성분은 생강, 백리향을 비롯한 여러 식물의 추출물이 될 수 있다. 생강 및 백리향에서 추출한 추출물에는 유게놀(eugenol), 캄펜(camphene), Ο-사이멘(Ο-cymeme), 터피넨(terpinene), 티몰(tymol), 커커민 (curcumeme), 징지베린 (zingiberene), 캄포(camphor) 등의 물질이 포함되어 있다. 여러 식물체에서 추출되는 이러한 물질들은 방충 및 방향효과를 가지고 있다.The third ingredient can be an extract of several plants, including ginger and thyme. Extracts from ginger and thyme include eugenol, camphene, Ο-cymeme, terpinene, thymol, curcumeme and zingiberene , Camphor and the like. These substances, extracted from various plants, have insect repellent and aroma effects.
상기 천연 식물성 정유의 조성물을 만드는 데에는 공지된 통상의 유기용제가 사용된다. 본 발명의 일 실시예에서는 유기용제로 정제 등유를 사용하였다. 본 조성물에서 유기용제는 70∼99.9 중량% 정도로 포함된다.Known conventional organic solvents are used to make the composition of the natural vegetable essential oil. In one embodiment of the present invention, purified kerosene was used as the organic solvent. In the present composition, the organic solvent is included in an amount of 70 to 99.9 wt%.
본 발명에 따른 상기 살충제 조성물을 가정용 위생해충 구제 및 곰팡이 억제에 유효한 양으로 포함하는 다양한 제형의 살균·살충제가 통상의 제제화 방법을 이용하여 제조될 수 있다.Sterilization and insecticides of various formulations comprising the insecticide composition according to the present invention in an amount effective for controlling household hygiene pest control and mold suppression can be prepared using conventional formulation methods.
본 발명에서는 특히 상기 살충제 조성물을 에어로졸 제ㅈ, 훈증제 및 마이크로캡슐화된 분말제의 제형으로 제제화하는 방법이 제공된다.In particular, the present invention provides a method for formulating the pesticide composition into a formulation of aerosol, fumigant and microencapsulated powder.
본 발명의 조성물을 이용한 가정위생해충 구제용 에어로졸 제제와 훈증제는, 본 발명의 살충제 조성물을 에어로졸 캔에 담고 밀봉한 다음 공지된 통상의 분사제(예를 들어, 액화질소가스, 액화석유가스 등)를 충진하여 제조한다. 본 발명의 살충제 조성물과 분사제의 조성비는 사용되는 분사제에 따라 통상적인 사용량의 범위내에서 적절하게 조절한다. 예를 들어, 분사제로 액화질소가스를 사용할 경우 바람직한 부피비율은 20∼70:30∼80 정도가 된다.Aerosol formulations and fumigants for home hygiene pest control using the composition of the present invention, containing the pesticide composition of the present invention in an aerosol can, sealed, and then known conventional propellants (for example, liquefied nitrogen gas, liquefied petroleum gas, etc.) It is prepared by filling. The composition ratio of the pesticide composition and the propellant of the present invention is appropriately adjusted within the range of usual usage amount depending on the propellant used. For example, when using liquefied nitrogen gas as the propellant, the preferred volume ratio is about 20 to 70:30 to 80.
본 발명의 살충제 조성물을 마이크로캡슐화한 분말제는, 10∼90%의 전분수용액 100 중량부에 향균 및 살충효과를 갖는 천연 식물성 정유 0.1∼100 중량부를 첨가하여 고속 교반하여 에멀전 상태로 유화시킨 후 이 유화액에 가교제 역할을 하는 글루타르디알데하이드를 넣어 마이크로캡슐 슬러리를 만들고 연속적으로 스프레이 건조공정을 도입하여 분말 형태의 마이크로캡슐 분제를 제조한다.The powder agent microencapsulating the pesticide composition of the present invention is added to 100 parts by weight of 10 to 90% of the starch aqueous solution, and 0.1 to 100 parts by weight of natural vegetable essential oils having antibacterial and insecticidal effects are emulsified in an emulsion state by high speed stirring. Glutardialdehyde serving as a crosslinking agent is added to the emulsion to form a microcapsule slurry, and a spray drying process is continuously introduced to prepare a microcapsule powder in powder form.
이하, 실시예를 통해 본 발명을 보다 구체적으로 설명한다. 그러나 다음의 실시예에 의해 본 발명의 기술적 범위가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples. However, the technical scope of the present invention is not limited by the following examples.
실시예 1Example 1
에어로졸 제제의 제조Preparation of Aerosol Formulations
천연 식물성 정유의 유기용제로는 엑슨사(Exxen, 미국)의 정제 등유인 아이소파 엘(ISOPAR™L)을 사용하였다.As an organic solvent of natural vegetable essential oils, ISOPAR ™ L, a refined kerosene from Exxen (USA), was used.
처방 1 : 에어로졸(살충원액과 분사제를 합하여 100㎖ 중)Prescription 1: aerosol (pesticide solution and propellant in 100ml)
겨자정유 0.5㎖Mustard oil 0.5ml
생강정유 0.5㎖Ginger essential oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 48.5㎖Ifael 48.5ml
액화석유가스 50.0㎖Liquefied petroleum gas 50.0 ml
처방 2 : 에어로졸(살충원액과 분사제를 합하여 100㎖ 중)Prescription 2: aerosol (in 100ml of pesticide solution and propellant)
겨자정유 0.5㎖Mustard oil 0.5ml
유게놀정유 0.5㎖Eugenol Essential Oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 48.5㎖Ifael 48.5ml
액화석유가스 50.0㎖Liquefied petroleum gas 50.0 ml
처방 3 : 에어로졸(살충원액과 분사제를 합하여 100㎖ 중)Prescription 3: aerosol (pesticide solution and propellant in 100 ml)
겨자정유 0.5㎖Mustard oil 0.5ml
아네솔정유 0.5㎖Anesol Essential Oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 48.5㎖Ifael 48.5ml
액화석유가스 50.0㎖Liquefied petroleum gas 50.0 ml
처방 4 : 에어로졸(살충원액과 분사제를 합하여 100㎖ 중)Prescription 4: aerosol (pesticide solution and propellant in 100 ml)
겨자정유 0.5㎖Mustard oil 0.5ml
백리향정유 0.5㎖0.5ml thyme oil
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 48.5㎖Ifael 48.5ml
액화석유가스 50.0㎖Liquefied petroleum gas 50.0 ml
처방 5 : 에어로졸(살충원액과 분사제를 합하여 100㎖ 중)Prescription 5: aerosol (in 100ml of pesticide solution and propellant)
겨자정유 0.5㎖Mustard oil 0.5ml
생강정유 0.5㎖Ginger essential oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 28.5㎖Ifael 28.5ml
액화석유가스 70.0㎖Liquefied petroleum gas 70.0 ml
실시예 2Example 2
훈증제의 제조Preparation of fumigation
천연 식물성 정유의 유기용제로는 엑슨사(Exxen, 미국)의 정제 등유인 아이소파 엘(ISOPAR™L)을 사용하였다.As an organic solvent of natural vegetable essential oils, ISOPAR ™ L, a refined kerosene from Exxen (USA), was used.
처방 1 : 훈증제(살충원액과 분사제를 합하여 100㎖ 중)Prescription 1: fumigant (in 100ml of pesticide solution and propellant)
겨자정유 0.5㎖Mustard oil 0.5ml
생강정유 0.5㎖Ginger essential oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 28.5㎖Ifael 28.5ml
액화석유가스 70.0㎖Liquefied petroleum gas 70.0 ml
처방 2 : 훈증제(살충원액과 분사제를 합하여 100㎖ 중)Prescription 2: fumigant (in 100ml of pesticide solution and propellant)
겨자정유 0.5㎖Mustard oil 0.5ml
유게놀정유 0.5㎖Eugenol Essential Oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 28.5㎖Ifael 28.5ml
액화석유가스 70.0㎖Liquefied petroleum gas 70.0 ml
처방 3 : 훈증제(살충원액과 분사제를 합하여 100㎖ 중)Prescription 3: fumigant (in 100ml of pesticide solution and propellant)
겨자정유 0.5㎖Mustard oil 0.5ml
아네솔정유 0.5㎖Anesol Essential Oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 28.5㎖Ifael 28.5ml
액화석유가스 70.0㎖Liquefied petroleum gas 70.0 ml
처방 4 : 훈증제(살충원액과 분사제를 합하여 100㎖ 중)Prescription 4: fumigant (in 100ml of pesticide solution and propellant)
겨자정유 0.5㎖Mustard oil 0.5ml
백리향정유 0.5㎖0.5ml thyme oil
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 28.5㎖Ifael 28.5ml
액화석유가스 70.0㎖Liquefied petroleum gas 70.0 ml
처방 5 : 훈증제(살충원액과 분사제를 합하여 100㎖ 중)Prescription 5: fumigant (in 100ml of pesticide solution and propellant)
겨자정유 0.5㎖Mustard oil 0.5ml
생강정유 0.5㎖Ginger essential oil 0.5ml
레몬정유 0.5㎖Lemon essential oil 0.5 ml
아이소파 엘 48.5㎖Ifael 48.5ml
액화석유가스 50.0㎖Liquefied petroleum gas 50.0 ml
실시예 3Example 3
마이크로캡슐 분제의 제조Preparation of Microcapsule Powder
1) 단계 1 : n-octenyl로 치환된 식품 전분(치환율 0.005) 43g을 물 55g에 넣어서 녹였다. 이 용액의 비중을 증가시키기 위하여 4g의 NaCl을 첨가하여, 단일상으로 잘 녹은 전분 수용액을 준비하였다.1) Step 1: 43 g of food starch (substitution rate 0.005) substituted with n-octenyl was dissolved in 55 g of water. In order to increase the specific gravity of this solution, 4 g of NaCl was added to prepare a starch aqueous solution dissolved in a single phase.
2) 단계 2 : 상기 실시예 1의 처방 1의 살충제 조성물(겨자정유 0.5㎖, 생강정유 0.5㎖, 레몬정유 0.5㎖ 및 아이소파 엘 48.5㎖로 구성된 것으로, 분사제를 제외한 것을 말한다. 이하 동일하다) 15g을, 상기 단계 1에서 준비한 45% 전분 수용액에 첨가하여 호모게나이저로 5,000rpm, 3분 동안 고속 교반시켰다. 균일하고 작은 크기의 입자를 얻기 위하여 에멀전 상태의 유화를 실시하였다.2) Step 2: The pesticide composition of Formula 1 of Example 1 (0.5 ml of mustard essential oil, 0.5 ml of ginger essential oil, 0.5 ml of lemon essential oil, and 48.5 ml of isoelel, except for propellant). 15g) was added to the 45% aqueous solution of starch prepared in Step 1 and stirred at 5,000 rpm for 3 minutes using a homogenizer. The emulsion was emulsified in order to obtain particles of uniform and small size.
3) 단계 3 : 상기 단계 2의 유화 혼합액(45wt% 전분 수용액 100g에 본 발명의 살충제 조성물 10g을 유화시킨 용액)에 가교제 역할을 하는 글루타르디알데하이드 4g을 넣고 20분 동안 7,000rpm에서 가교시켜 마이크로캡슐 슬러리를 얻었다.3) Step 3: Into the emulsion mixture of step 2 (solution of emulsifying the pesticide composition 10g of the present invention in 100g of 45wt% starch aqueous solution) 4g of glutaraldehyde serving as a crosslinking agent and crosslinked at 7,000rpm for 20 minutes to micro A capsule slurry was obtained.
4) 단계 4 : 상기 단계 3에서 얻은 마이크로캡슐 슬러리를 스프레이 건조 공정에 도입하여 펌프에 의해 20㎖/분 이하로 이송하면서 동시에 공기 압축기로 7∼9bar로 공기를 불어 넣어 분말 형태의 마이크로캡슐을 얻었다.4) Step 4: The microcapsule slurry obtained in the step 3 was introduced into the spray drying process, and the air was blown at 7 to 9 bar by an air compressor while conveying the pump to 20 ml / min or less by a pump to obtain a microcapsule in powder form. .
실시예 4Example 4
본 발명의 살충제 조성물의 집파리 성충에 대한 효능시험Efficacy test on adult housefly insecticide composition of the present invention
집파리 성충을 이산화탄소로 몇 분간 마취시킨 후 접촉독성으로 국소처리법과 분무법을 사용하였고, 훈증독성으로 여과지법(filter paper)을 사용하였다. 국소처리법은 마취된 집파리 복부에, 실시예 1의 처방 1∼4의 살충제 조성물을 0.5㎕ 처리하고, 그물망에 넣고 24시간 후에 사충수를 조사하였다. 분무법은 마취된 집파리에 회전분무탑(rotary spray tower) 장치를 이용하여 상기와 동일한 본 발명의 살충제 조성물 5㎖를 처리하고, 그물망에 넣고 24시간 후에 사충수를 조사하였다. 여과지법(filter paper)은 플라스틱 용기에 여과지를 깔고 상기와 동일한 본 발명의 살충제 조성물 0.2㎖를 처리한 후 집파리를 넣고 덮개를 닫고 24시간 후에 사충수를 조사하였다.The housefly adult was anesthetized with carbon dioxide for several minutes, followed by topical treatment and spraying for contact toxicity, and filter paper for fumigation toxicity. In the topical treatment method, 0.5 µl of the insecticide composition of the formulations 1 to 4 of Example 1 was treated on the anesthetized housefly abdomen, and the insects were examined after 24 hours in a net. In the spray method, 5 ml of the insecticide composition of the present invention was treated in the anesthesia housefly using a rotary spray tower apparatus, and put into a net, and the insecticide was examined after 24 hours. In the filter paper (filter paper) was placed on a filter paper in a plastic container and treated 0.2ml of the insecticide composition of the present invention as described above, the housefly was put in and the lid was closed and irradiated with insects after 24 hours.
천연식물성 정유조성물의 집파리 성충에 대한 살충효과를 실험한 결과는 상기 표 1과 같다. 실시예 1의 처방 1∼4에 모두 집파리 성충에 대해 살충효과가 있는 것으로 나타났다.Experimental results of the insecticidal effect on the adult housefly essential oil composition of the housefly are shown in Table 1 above. All of the formulations 1 to 4 of Example 1 were found to have an insecticidal effect against housefly adults.
실시예 5Example 5
본 발명의 살충제 조성물의 집파리 유충에 대한 효능시험Efficacy test on housefly larvae of the insecticide composition of the present invention
병아리 사료 30g을 원형플라스틱용기에 담고 실시예 1의 처방 1의 살충제 조성물을 표 2의 농도별로 넣어 혼합한 후, 파리 유충 50 마리를 넣고 24시간 후에 사충수를 조사하였다. 대조군으로는 시판 유기 살충제를 사용하였다.30g of chick feed was put in a round plastic container, and the insecticide composition of Formulation 1 of Example 1 was mixed for each concentration of Table 2, and 50 fly larvae were added and examined for insects after 24 hours. A commercial organic insecticide was used as a control.
본 발명의 천연 식물성 살충제 조성물의 집파리 유충에 대한 살충효과를 실험한 결과는 상기 표 2와 같다. 실시예 1의 처방 1은 대조군과 비슷한 매우 우수한 살충효과를 나타내었으며 100L당 40g 처리시에는 100%의 살충효과를 보였다.Experimental results of the insecticidal effect on the housefly larvae of the natural vegetable insecticide composition of the present invention are shown in Table 2. Formulation 1 of Example 1 showed a very good insecticidal effect similar to that of the control group and showed a pesticidal effect of 100% when treated with 40 g per 100 L.
실시예 6Example 6
본 발명의 살충제 조성물의 독일바퀴에 대한 효능시험Efficacy test on the German wheel of the insecticide composition of the present invention
독일바퀴 수컷 성충을 이산화탄소로 몇 분간 마취시킨 후 접촉독성으로 국소처리법과 분무법을 사용하였고, 훈증독성으로 여과지법(filter paper)을 사용하여 실험하였다. 국소처리법은 마취된 독일바퀴 수컷 성충 복부에 실시예 1의 살충제 조성물 1㎕를 처리한 후 그물망에 넣고 24시간 후에 사충수를 조사하였다. 분무법은 마취된 집파리에 회전분무탑(rotary spray tower) 장치를 이용하여 상기와 동일한 살충제 조성물 5㎖를 처리하고 그물망에 넣고 24시간 후에 사충수를 조사하였다. 여과지법은 플라스틱 용기에 여과지를 깔고 상기와 동일한 살충제 조성물 0.2㎖을 처리한 후 독일바퀴 수컷 성충을 넣고 덮개를 닫고 24시간 후에 사충수를 조사하였다.The male adult male wheel was anesthetized with carbon dioxide for a few minutes, followed by topical treatment and spraying for contact toxicity, and filter paper for fumigation toxicity. In the topical treatment, 1 µl of the insecticide composition of Example 1 was treated to anesthetized male adult male abdomen and placed in a net, and the insects were examined after 24 hours. In the spray method, anesthetized housefly was treated with the same pesticide composition 5ml using a rotary spray tower apparatus, put into a mesh, and irradiated with insects after 24 hours. In the filter paper method, the filter paper was placed in a plastic container and treated with the same insecticide composition 0.2ml, and the male wheel was added to the adult male.
본 발명의 천연 식물성 살충제 조성물의 독일바퀴 수컷 성충에 대한 살충효과를 실험한 결과는 상기 표 3과 같다. 실시예 1의 처방 1∼4 모두 독일바퀴 수컷성충에 대해 살충효과가 있는 것으로 나타났다.Experimental results of the insecticidal effect on the adult male wheel of the natural vegetable insecticide composition of the present invention are shown in Table 3. All of Formulations 1 to 4 of Example 1 were found to have an insecticidal effect against the German wheeled male adult.
본 발명의 살균·살충제 조성물과 이를 효과적으로 제형화한 제제는 식물성 성분으로 이루어져 환경과 인체에 안전한 것은 물론, 바퀴, 파리, 모기, 개미 등 가정위생해충을 구제하는 효과 및 곰팡이 발생을 억제하는 효과가 우수하여 종래의 유기 살충제를 대체하는 살균·살충제로 사용될 수 있다.The bactericidal / insecticide composition of the present invention and the formulation effectively formulated therein are made of plant components and are safe for the environment and the human body, as well as the effects of controlling home hygiene pests such as wheels, flies, mosquitoes, ants, and inhibiting mold development. It is excellent and can be used as a sterilizing and insecticide to replace the conventional organic insecticide.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020000048716A KR20000072252A (en) | 2000-08-22 | 2000-08-22 | Composition and preparation of natural plant essential oil for use as insecticidal and antimicrobial agents |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020000048716A KR20000072252A (en) | 2000-08-22 | 2000-08-22 | Composition and preparation of natural plant essential oil for use as insecticidal and antimicrobial agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20000072252A true KR20000072252A (en) | 2000-12-05 |
Family
ID=19684523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020000048716A KR20000072252A (en) | 2000-08-22 | 2000-08-22 | Composition and preparation of natural plant essential oil for use as insecticidal and antimicrobial agents |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR20000072252A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002076217A1 (en) * | 2001-03-22 | 2002-10-03 | Naturobiotech Co., Ltd. | Plant extracts composition contained pesticidal activities |
| KR100433790B1 (en) * | 2001-04-25 | 2004-06-04 | 주식회사 비아이지 | Sustained release preparation of preservative containing essential oil for agricultural products |
| KR100446582B1 (en) * | 2000-12-28 | 2004-09-04 | 가부시키가이샤 닛뽄 에이세이 센터 | Apparatus for controlling humidity and prevention of termite intrusion |
| KR100817296B1 (en) * | 2007-05-23 | 2008-03-27 | 주식회사 바이오미스트테크놀로지 | Stable automatic disinfection system |
| KR100852398B1 (en) * | 2007-05-08 | 2008-08-14 | 케이씨피주식회사 | Composition for controlling noxious animals in horticultural crops and using method thereof |
| KR101298097B1 (en) * | 2010-12-21 | 2013-08-20 | (주)창조바이오텍 | Scuticociliates Insecticide Composition Comprising Camphene as an Active Ingredient |
| CN106137842A (en) * | 2016-08-03 | 2016-11-23 | 南安辰光日用化工品有限公司 | A kind of anophelifuge floral water containing plant component |
| KR20170079300A (en) | 2015-12-30 | 2017-07-10 | (주) 피러스 | Botanical insecticide composition containing essential oil from wood extract and pine resin, and the preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6051233A (en) * | 1997-10-31 | 2000-04-18 | Champon; Louis S. | All natural soil treatment and insecticide composition containing plant extract heat components |
| KR100270561B1 (en) * | 1998-09-11 | 2000-11-01 | 안용찬 | The composition of insecticide |
| KR20010059093A (en) * | 1999-12-30 | 2001-07-06 | 우종일 | Composition of essential oil having a protecting power against insects and plant pathogenic fungi and an antioxidant activity and product containing thereof for preserving the quality of agricultural products |
| KR100341016B1 (en) * | 2000-08-21 | 2002-06-20 | 정종상 | Biodegradable microencapsulation process of natural plant essential oil and its preparation |
-
2000
- 2000-08-22 KR KR1020000048716A patent/KR20000072252A/en not_active Application Discontinuation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6051233A (en) * | 1997-10-31 | 2000-04-18 | Champon; Louis S. | All natural soil treatment and insecticide composition containing plant extract heat components |
| KR100270561B1 (en) * | 1998-09-11 | 2000-11-01 | 안용찬 | The composition of insecticide |
| KR20010059093A (en) * | 1999-12-30 | 2001-07-06 | 우종일 | Composition of essential oil having a protecting power against insects and plant pathogenic fungi and an antioxidant activity and product containing thereof for preserving the quality of agricultural products |
| KR100341016B1 (en) * | 2000-08-21 | 2002-06-20 | 정종상 | Biodegradable microencapsulation process of natural plant essential oil and its preparation |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100446582B1 (en) * | 2000-12-28 | 2004-09-04 | 가부시키가이샤 닛뽄 에이세이 센터 | Apparatus for controlling humidity and prevention of termite intrusion |
| WO2002076217A1 (en) * | 2001-03-22 | 2002-10-03 | Naturobiotech Co., Ltd. | Plant extracts composition contained pesticidal activities |
| KR100433790B1 (en) * | 2001-04-25 | 2004-06-04 | 주식회사 비아이지 | Sustained release preparation of preservative containing essential oil for agricultural products |
| KR100852398B1 (en) * | 2007-05-08 | 2008-08-14 | 케이씨피주식회사 | Composition for controlling noxious animals in horticultural crops and using method thereof |
| KR100817296B1 (en) * | 2007-05-23 | 2008-03-27 | 주식회사 바이오미스트테크놀로지 | Stable automatic disinfection system |
| KR101298097B1 (en) * | 2010-12-21 | 2013-08-20 | (주)창조바이오텍 | Scuticociliates Insecticide Composition Comprising Camphene as an Active Ingredient |
| KR20170079300A (en) | 2015-12-30 | 2017-07-10 | (주) 피러스 | Botanical insecticide composition containing essential oil from wood extract and pine resin, and the preparation method thereof |
| CN106137842A (en) * | 2016-08-03 | 2016-11-23 | 南安辰光日用化工品有限公司 | A kind of anophelifuge floral water containing plant component |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP7415296B2 (en) | Isopod insect control agent | |
| DK1744632T3 (en) | Insecticidal compositions and methods of use thereof | |
| US5653991A (en) | Process for repelling and killing insects and compositions to effect the same comprising a monoterpene | |
| KR100912554B1 (en) | Synergistic and Residual Pesticidal Compositions Containing Plant Essential Oils | |
| US8133921B2 (en) | Edible plant extract based insecticidal composition | |
| US20070237837A1 (en) | Biocompatible tea tree oil compositions | |
| US20030175369A1 (en) | Natural moths repellent compositions | |
| JPS62500935A (en) | Long-acting pyrethrum/pyrethroid-based insecticide with added silicone stabilizer | |
| US6051233A (en) | All natural soil treatment and insecticide composition containing plant extract heat components | |
| JP3556981B2 (en) | Ant repellent | |
| KR100341016B1 (en) | Biodegradable microencapsulation process of natural plant essential oil and its preparation | |
| KR20000072252A (en) | Composition and preparation of natural plant essential oil for use as insecticidal and antimicrobial agents | |
| AU732614B2 (en) | Ant spray containing D-limonene and methods of making and using same | |
| JP7249566B2 (en) | herbicide | |
| US6784211B1 (en) | Ant spray containing d-limonene and methods of making and using the same | |
| US20150072030A1 (en) | Biocompatible tea tree oil compositions | |
| KR100644283B1 (en) | The mixture composition of terpenes, having insecticidal activity | |
| EP1418928A1 (en) | All natural soil treatment & insecticide composition containing plant extract heat components | |
| JP7017725B2 (en) | Pest control composition | |
| KR100297423B1 (en) | Environmentally Friendly Low Toxic Oil-in-water Latex Pesticides | |
| KR20040092146A (en) | Sustained release materials for the control of insect pests and its preparing methods | |
| PANTA et al. | CHAPTER FIFTEEN SOME BIOYPESTICIDE FORMULATIONS DEVELOPED AT IPFT | |
| TW474789B (en) | Process for repelling and killing insects and compositions to effect the same comprising a monoterpene | |
| JP2003026507A (en) | Exterminator agent against harmful gastropods and method for exterminating the harmful gastropods | |
| WO2005107458A1 (en) | Insect pest control agent, insecticidal powdery formulation and isopod behavior disruptive agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E601 | Decision to refuse application |