TW474789B - Process for repelling and killing insects and compositions to effect the same comprising a monoterpene - Google Patents

Abstract

Closely related formulations of GRAS food additives serve as insect repellents, insecticides and larvicides. The ingredients of the repellent, insecticide and larvicide also exhibit useful disinfectant properties against vector-borne pathogenic micro-organisms.

Description

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 474789 Λ7 ----- ______ B7 V. Description of the Invention ^)-~---1 7 Invention Section. 4 The present invention relates to the field of insect repellents and pesticides . In more detail, the present invention relates to a method for deworming and killing insects, a composition for deworming effects, a composition for killing insects, and a preferred use of monoene, and other food additives generally recognized as safe (GRAS) Formulation with this composition. Describe the technology of knowing technology In order to protect farming and animals and to maintain public health, many years of research and efforts have been spent on insect control. Human-produced breast skin insects have eaten. Therefore, the control of insects to protect farming and livestock is of paramount importance, especially for farmers. Park insects are also particularly common in and around homes. Insects such as flies, mosquitoes, cockroaches and fleas can often be vectors for infectious diseases. Three main methods of chemically controlling harmful insects are known and used: gastrotoxin, toxin exposure, and fumigation. In the past, when there was less concern about the environment, less attention was paid to the toxicity caused by the use of organic and inorganic substances to control seeing insects. Today, virtually all insect repellents and pesticides are currently registered with the United States, and the EPA has warned against the use of insect repellents and pesticides near or in areas where food is supplied and where the fish are growing. Many of these insect control agents are toxic to humans when swallowed, inhaled, or physically contacted. Therefore, there is a need for a safer pesticide that is equivalent in efficiency to the more toxic reagents currently in use. One of the areas of interest in manufacturing environmentally safe insect repellents and insecticides is the general recognition that food seasonings are safe (GRA MAGIC). Monoterpenes known to be d-terpene diene have proven useful Yu's essential oil 'Chinese paper standard (.CNS) • grid (21GX297 ^ cent) ------- (Please read the precautions on the back before filling this page)

474789 Consumption cooperation among employees of the China Standards Administration of the Ministry of Economic Affairs. Du printed A7 __ 丨 丨 _ _ B / V. Invention Description (2) ~~ Food Seasoning Additives (21 CFR, Part 170-199, Food and Onigs, April 1, 1990 (incorporated by reference), and is similarly listed in the internationally recognized Fod Chemicals Codex (3d ed.). This rather fast-evaporating essential oil is derived from the peel of a citrus fruit. Varying terpenes (including terpenes) are also found in bark. In U.S. Patent No. 4,379,168 in 1983, Dotolo taught that when mixed with antioxidants to keep d-secretine from emitting foul odors in the air, the use of d-codiene is limited to pesticides, not repellents. Insecticide. However, the large use of water in the Do to 10 patent dilutes the efficiency of the diene. In general, the ability to expel animals can also be achieved by 诎 ... flavors. U.S. Patent No. 3,923,997 teaches the use of alpha-n-alkylbutyrolactone and / or delta-valerolactone as an anti-mating composition or exclusion agent for animals. SUMMARY OF THE INVENTION An object of the present invention is to provide a method capable of killing insects having a wax waterproof protective film to prevent drying. The method comprises using an effective dose of a solution of a mislene having a molecular formula of ciqHi6 to moisten insects and rapidly evaporable white mineral oil to destroy a wax waterproof protective film. The evaporating white mineral oil has an initial boiling point of about 176.7. (: (350 ° F) to 210T (410 °), the end point is about 207.2 ° C (405 ° F) to 268.9 ° C (516 °), and the flash point is about 61.1. (: (142.?) To 73.9. (: (165)). This method is used; the valley liquid may also contain one or more dishes, liquid stone and surfactant. A further object of the present invention is to provide a method that can be repelled by the odor emitted by the site. Method for insects to a place. The method includes moistening the place with a solution of a shoe formula having a molecular formula of CiaH16 to moisten the place and the paper size applies the China National Standard (CNS) A4 specification (210 × .2.9.7). ^^) ~ — '' ------ .n — ^ n ml —-ί ^ — 11- in-(Please read the notes on the back before filling this page}

, 1T Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

An '^ ---_ B7 V. Explanation of the invention (3) ~ White mineral oil that can evaporate slowly to camouflage the odor released from the site. The distillation initial boiling point of the white mineral oil that is treated slowly is approximately丨 82.2. [(36〇〇f) and above, the end point is about 315.6T (600, and above, the flash point is about 118. Generation (245 Wlj31n: (59〇 叩). The solution used in this method may also contain one or more And a fragrance. A still further object of the present invention is to provide a method for repelling mosquitoes for mammals (that is, animals and humans), and the method comprises using a secretive formula of effective agent i whose molecular formula is qoH〗 6 The solution was used to moisten the skin surface of exposed animals or humans and the slow-evaporating white mineral oil to camouflage the odor released from the site. The slow-evaporating white mineral oil had a starting boiling point of approximately 182.2 in distillation. (: (360 ° F) and above, the end point is about 315.6x (60 0F) and above, and the flash point is about η8.3 ° C (245 0F) to 310oC (590 0F). A further object is to provide a method capable of killing mosquito larvae ', and the method comprises spraying a mysterious solution of molecular formula CiqHis and a white mineral oil substrate to the water surface where the mosquitoes reproduce. The white mineral oil substrate contains a weight ratio of about 1: 99 to 99: 1 fast anti-eucalyptus white ore 7〇c The initial boiling point of the fast-evaporating white mineral oil is about 176.7c

(350 ° F) to 210 ° C (410 0F), the end point is about 207. 20C (405 0F) to 268.9 ° C (516 〇F), the flash point is about 61.1. 〇 (142 ° F) to 73.9 ° C (165 ° F); the slow-evaporating white mineral oil has a boiling point of approximately 182.2 ° (3 (360. 卩) and above) and an end point of approximately 315.6. : (6 () 0. 卩) and above, the flash point is about H8.3 ° C (245 ° F) to: 31〇. (: (590 叩). Going one step further in this task, the purpose is Provide—can kill and drive away the white paper size applicable to China National Standards (CNS) A4 specifications (210X297 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 474789 A7 (________ B7 V. Invention Description (4) ~ " --- The method of hamster flies, which includes a solution of a secret woman with a molecular formula of ^ 6 and The white mineral oil matrix moistens the leaf surface of the white hawthorn clusters, and the white mineral oil matrix contains a mixture of fast and slow-evaporating white mineral oil in a weight ratio of about 1:99 to 99: 1; the fast-evaporating The steaming hall of white mineral oil has an initial boiling point of approximately 176.7 ° C (350 ° F) to 210 ° C (410 ° F) and an end point of approximately 207.2. At 405 ° F to 268.9. (: (516 < ^), flash point is approximately 61.1. (: (142 ° F) to 73.9 ° C (165 ° F); the slowly evaporating white mineral oil has an initial boiling point of approximately 182.2% (360 Ii) and above, the end point is about 315,6. (: 0F). A still further object of the present invention is to provide a composition comprising a solution of a terpene with a molecular formula of 1 ^ * ^ 6 and a white mineral oil matrix The white mineral oil matrix is selected from the group consisting of 1 fast-evaporating white mineral oil, which has an initial boiling point of about 176.7 ° C (350 ° F) to 210. (: (410 ° F), The end point is about 2〇7.2 ° C (405 ° F) to 268.9 ° C (516 ° F), the flash point is about 61.10C (142 ° F) to 73.9 ° C (165 ° F), r2) slow burst White mineral oil, its distillation has a boiling point of approximately 182.2. (: (360 0F) and above, end point of approximately 315_60C (600 叩) and above, flash point of approximately 118.3C (245 ° F) to 310 ° C (590 叩), and (3) a mixture of fast and slow evaporating white mineral oil with a weight ratio of about 1: 99 to 99: 1. The composition may also contain one or more aldehydes, liquid silicon, and interfacial activity Agents and fragrances. Preferably, this group All the ingredients in the composition are GRAS when used in human food, so it is safe for humans to inhale, ingest and apply to the skin. --1 ------_________- 7. This Paper size applies Chinese National Standard (CNS) Α4ί! Grid (210X297 mm) _ ------ '' I -------------. (Please read the precautions on the back before filling in this Page) Order printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 474789 __________ B7 V. Description of the invention (5) ~~~ Detailed description of the preferred embodiment The composition of the present invention contains terpene with a molecular formula of terbium and white mineral oil. The composition may optionally further include at least one aldehyde, at least one liquid syrup, at least one surfactant, and an aromatic agent. Ethylene oxide contains organic compounds with general structural characteristics, that is, isopentane is repeated repeatedly. Carbon skeleton of the alkane unit (-CH2-CH2_CH (CH3) _CH2_) n. It is widely distributed in nature; the lower n value of the alkenes series, single boxene (n = 2) and sesquiterpene (n = 3), is the main component of most plant essential oils. Generally terpenes contain derived from trees Pine oil, turpentine extracted from citrus peel and d-terpene diene: pinene. The present invention has discovered pine oil, d-terpene diene and mixtures of these with other terpenes, such as TABSD (Uni OnCa (made by Corporation) can be used alternately or in combination to repel and / or kill insects. In any case, the pleasing citrus flavor of d-terpene diene has in fact been confirmed by the US Food and Drug Administration (21 CFR 172 · 515) as a GRAS food additive and Food Chemicals Codex, which gives d- The use of terpenes is a preferred embodiment of the present invention. The terpene diene is confirmed as follows: d-terpene diene, C1QH16 p-menthol-1, 8-diene, eucalyptus CAS No. 5989-27-5 Approximately 0. 0% of the total weight of the composition is a molecular formula: C! A6 terpenes. The other essential ingredient of the intended composition is a white mineral oil base. The properties of the composition of the invention are based on the preferred white mineral oil base material. Typically, the white mineral oil base is saturated hydrocarbon with branching ------ 'IIT ----- .. (Please read the notes on the back before filling this page) (210X297mm ) ---- ~ _____ B7 V. Description of the invention (6) ~~~ '----—— ~ —— Compound-based, linear and saturated ring structure. The aromatic content is very low, while paraffin is almost absent. Broadly, the present invention makes use of the following characteristics of white mineral oil: AII gravity '15. Substitution. F) 46 / 5〇_28 / 31 Special Gravity ’15.6 / 15 • Kou Yanjing). 79 " .881 Distillation (ASTM D 86) Start; Fu point 'Minimum end point, Maximum flash point (ASTM D 92) Carbon number 176.7 ° C (350oF) -210oC (410 ° F) 207.2 ° C ( 405 ° F) -315.6 + ° C (600 + ° F) 61.1 ° C (142 ° F) -310 ° C (590 ° F)

Cio-C18 + and σ Any widely sold household pesticides must generally evaporate quickly without leaving traces on floors, carpets, furniture, etc. So far, this toxic solvent such as ^, ethyl trichloride, petroleum distillate, and fluorocarbons has been used as a propellant that leaves no traces of various pesticides at home and near the garden. Environmental considerations of the disappearance of the earth's ozone layer today have increased the limits on the use of these solvent compounds. The present invention does not use these base materials instead of using a fast-evaporating white mineral oil base, and preferably contains an average carbon number of 12 or more. (Volatile organic compounds with a carbon number equal to or greater than 12 are not controlled by air pollution in California.) For the purposes of this invention, the rapid evaporation of white mineral oil substrates is a special feature of 474789, which is printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Preparation of A7 B7 V. Description of the invention (7) The initial boiling point is about 176.7. (: (350 叩) to 210 ° C (410 ° F), the end point is about 207.2 ° C (405 ° F) to 268.9 ° C (516 ° F), and the flash point is about 61.pc (142 叩) To 73.9 ° C (165 ° F). Suitable oils that have been approved for food and other applications are registered under CAS Nos. 64742-

14-9 and 64742-47-8 and can be obtained from PENRECO (the department of PEIL Z0IL PRODUCTS COMPANY). I use a very fast-evaporating food-grade white mineral oil solvent as a substrate and apply this formula to a contact sprayer for insects to inhale. The solution of d-terpene and oil has efficient household and public insecticides. The function of the agent b D-code Erxian has the properties of a household cleaner and is used to soften waxes and emulsified oils. In insecticides, the rapidly evaporating white mineral oil matrix and the bathing properties of d-terpene diene together destroy the protective wax waterproof membrane covering the body of the insect, causing the insect to die quickly due to drying. At the same time, by using various oils to block the insect's fine respiratory organs (called breathing holes) and cause suffocation to speed up and knock down the insects. "The advantage of using mineral oil in the present invention is that the insects do not treat this oily slave Fatal suffocation by agents—if it develops resistance to other commonly used pesticides. Authorized tea review publication Managing Insects & Wtes with Spray Oils (hereby incorporated by reference) indicates that target pests have been observed to slightly oil With or without resistance. " By combining the molecular formula ClOHi6 and the slow evaporation of the white mineral oil matrix, the combination of insect repellent and skin moisture can be obtained.吴 on people and animals ’Wu fragrance prevents mosquitoes from landing, inserting people into tubes, and then biting. Similar to ΜΛ 张 Μ Applicable to Wa Family Standards (CNS) --------- · Equipment ——----_ ϊτ ------ 10. (Please read the precautions on the back before filling this page ) Consumption cooperation by employees of the Central Bureau of Standards, Ministry of Economic Affairs, Du printed Α7 --_________________ B7 i 'Invention test {^) ~' — ---- The fragrance of the ground 5 will also mask those that would normally attract other harmful flavors. . 'For the purposes of the present invention, the slow-evaporating white mineral oil matrix is characterized by a distillation starting boiling point of approximately 182.2 QC (36 QF) and above, and an end point of approximately 315.6. (: (600 ° F) and above, flash point is about 118 · 3T (245 to 31G ° C (59G ° F). Suitable oils that have been approved for food and other places are registered in CASNos. 8〇43 -47_5 and below, and can be obtained by penrec0 (the department of PENNZOIL PRODUCTS COMPANY). For the purpose of the present invention, "effective amount" will obviously be determined by the conditions of use. Therefore, 'through routine experiments, we know the technology It will be easy to determine the "effective amount". The effectiveness of pesticides and repellents can be improved by adding small amounts of at least one and preferably two GRAS food-grade slow-evaporating essential oil aldehydes immediately. Aldehydes mask the smell of attracting insects on animal bodies and foods after the relatively volatile aroma of cardiodipadiene evaporates. The irritating taste of aldehydes is also a known mucosal stimulant, which creates a sharp sense of smell, so Increase the repellent effect of the present invention. Preferably, more than one kind and preferably two kinds of 卯 ... food-grade aldehydes are used together. The two best kinds are: γ-ll carbalactone aldehyde C- 14 pure (so-called) peach aldehyde Dihydro-5-heptyl-2 (3Η) -Chrysanthemum with CAS No. 104-67-6 This paper size applies to China National Standard (CNS) A4 specification (210X297 /! · ^) '~~~ -----— (Please read the notes on the back before filling in this page) _ · 装 474789

V. Description of the invention (9) The Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs are detailed, containing γ-nonananonolactone c9h1so2 aldehyde C-18 difluoren-5-heptyl-2 (3H) -pyranone CAS No. 104-61-0 These two pathways are generally recognized as lactones just like other food seasonings that have been approved. They individually have the special flavor of peach and coconut. These aldehydes can individually account for about 0.005 to 5 of the total weight of the composition. In a related embodiment, the weight ratio of the mixture of fast and slow evaporating white mineral oil is 1:99 to 99: 1, resulting in effective and safe young mosquito killers * i d. The formula is also a mixture of mineral oil mixture, d-dilute, and any optional ingredients, sprayed on the water surface where mosquitoes reproduce. Field tests conducted by the Universversity of California-Riverside insect family confirmed that the larvicide was 100% potent within 12 days, suffocating larvae that thought of breathing on the water surface. The larvicides ^ aU-GRAS formulation is quite mild to other surface regulars who share this building and environment. The larvicidal formulation has also been developed by University 〇f

A field test conducted by California ’s Cooperative Extension in Holtville, CA has shown effectiveness in combating economically costly offender white flies against food crops in the southwestern United States. The white fly is a leaf-eater, which virtually wipes out all growing food crops. This formula is sprayed on the surface of all plant leaves and used as a combination of insecticides and repellents to kill the adults and the eggs and larvae they come into contact with. According to the invention, the thin oil film on the leaf surface field is used to cover off the plant smell that is attractive to the food. —————_________ 10 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X29731 ~ ~ ——)

Ili HH ^^ 装 —II —Order I I T I is' (Please read the notes on the back before filling this page) 474789

AT ____—____ _ i. 5. Description of the invention (10) ~~ Road to prevent other white Cangsheng from landing. Test results on a series of crops and growing flat grapes have shown that this food-grade invention works for those highly toxic pesticides without phototoxicity. 5 It should be noted that d-secretine and its associated dilute, pine oil, and every two of the two aldehydes (γ-ll carbamic acid lactate, γ_nonyl alkanoic acid vinegar) order | Known activity-like species exhibit bactericidal properties f against Gram-negative and positive pathogenic microorganisms. When considering the use of the household insecticide of the present invention, the mistress and these two pathways have even shown stronger activity against four different microorganisms in medical experimental tests. This is to be expected because the cell walls of certain microorganisms and certain viruses are generally composed of wax-like lipids, which can often be broken by baths and strong solutions of soap and water. The ability of these actives to break or even kill microorganisms produced by specific insects and eliminate the nasty odors caused by microorganisms produced by specific insects has been proven to have public health implications and economic value to consider, especially for entertaining food Battle of Sick Rot and Cang Sheng at the location. There are other additives that can be used in the present invention to increase the effectiveness or ease of use of the product. Printed by the Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs. Addition of not more than 2% or more of the weight of the composition to the following food-grade aromatic h 彳 can improve insect repellency. It also makes the present invention have a more pleasant odor for human users, and is classified in food grade under 21 CFR S172. 515: Anethole

Cl〇Hl2 ° CtH60 CAS iNo. 104-45-1 CAS No. 1 00-52-7 ^ Paper prostitute applies Chinese National Standard (CNS) Eighty-fourth Secret (2i〇χ29 ^ g -------- ~ ~ 474789 A7 B7 Description of the invention (η) Cinnanol benzoate c9h10o2 ^ θΗ10〇 CAS No. 93-89-0 CAS No. 104-51-1 Synthetic musk Haiti oil (mixture) c12h16n2o5 CAS NO. 8007-44-1 CAS No. 83-66-9 Vanillin C8H803 CAS. No. 121-33-5 (Please read the precautions on the back before filling out this page) The printing of the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs has changed from about 10-350. A small amount, generally! Weight% of liquid stone may be added to all the insecticidal / larvicidal embodiments of the present invention to reduce surface tension and help spray when wet. Better chemical protection of liquid silicon . +,

Described because it is approved for use in human food under 21 CFR S176. 200, dimethyl polysiloxane ° Hexa *: Liquid silicon CAS NO. 63148-62-9 * 25 ° C (77 ° F): 350 ctks (the only viscosity approved by the FDA for use in food) Liquid cancer dreams (Yijiji • Shixi Oxygen Burn) advised $ ctks; added to the insecticides at about 0.1 to 10% by weight Paper size applies to Chinese National Standard (CNS) A4 (210x297 mm) insect repellent, and / or consumer cooperation of the Central Standards Bureau of the Ministry of Economic Control, Du printed off-print / 4/89 A7 --------- --- B7 V. Description of the Invention (12) " ~ ~ — Insecticide. In some embodiments of the present invention, it is preferable to mix the formulation with water to promote the spray truck to a large area infected by the target pest. This oil-based ingredient is general, and different surfactants (soaps and detergents) promote the formation of emulsions with water. Some of them are toxic and harmful to the environment, especially those that are generally found to be the best oil-based larvicides and pesticides. When two emulsifiers are used, one is hydrophilic and the other is lipophilic. Together, in proportions and concentrations chosen, it combines water and oil and promotes the formation of emulsions of varying degrees of stability required for the end result. The two types of food-grade surfactants that are better used in the present invention are identified by their trade names, their general names, and their USF & DA production numbers:

Tween 80, polysorbate go POE 2 0 Sorbitol early oleate 21 CFR S172.840 SPAN 80 Sorbitan monooleate 21 CFR S173.75 The inventor's opinion is that the following examples typically represent the invention The preferred embodiment. Example 1 A water-white clear insecticidal solution was prepared by mixing the following ingredients together at room temperature in weight percent of total weight and regardless of the order of addition: γ-nonyl charcoal sultone 0.024% γ ~ Π carbamate Ester 0.049% i Paper; d North Korea Standard (CNS) 21QX297j ^ _j '--- IIII ^^ 衣 IIII Order I ^ I »(Please read the notes on the back before filling this page} 4V4789 Λ7 B7 V. Description of the invention (13) d-terpene diene liquid silicon fast-evaporating white mineral oil 4. 015% 1.000% 94. 912% After printing by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, the solution has been simmered and It can be used as a contact insecticide for flying and crawling insects, such as blue rope, cockroaches, yard ants, mosquitoes, and others. It is best to be used in hand-held sprayers-rather concentrated mouth liquid, which can Wet the target insect completely. In the case of a winged insect, the spray should completely wet the insect, its crawl path, and either side of the crawl path ^ to-feet or more. The spray quickly kills the wet Dropped insects and will tend to maintain ants for a considerable amount of time thereafter Do not return to the spray path. Sometimes a second spray actually increases the potency after a few hours. Example 2 Prepare a water-white color by mixing the following ingredients at room temperature in weight percent and regardless of the order of addition Clear insect repellent solution: γ-nonyl carbolactone γ-ll carbolactone d-secadiene anisin (p-acrylic anisole) benzaldehyde benzoic acid cinnamyl alcohol Haiti oil synthesis muscarinaldehyde (3 -Methoxy-4-hydroxybenzaldehyde 0.024% 0.049% 4.015% 0.147% 0.245% 0.147% 0.098% 0.098% 0.024¾ 0.024¾ (Please read the precautions on the back before filling out this page}-TΓ t Paper size applies Chinese National Standard (CNS) M specification (21〇 < 297 mm) 474789 Λ7 B7 V. Description of the invention (14) 'I · Man-evaporating white mineral oil 95.100% After mixing-for a while, the solution It is stable and ready to be used on human skin and hair as well as animal skin and hair as an insect repellent to deal with such matters as mosquitoes, moths, flies and others. The application method can be in the liquid form of Rongqin, Spraying Li from a hand pressure sprayer, From a rolled-up diffuser and wipe with -full paper or cloth. The solution dries quite slowly and can moisturize the skin and fur for several hours. This period is its most effective insect repellent time. This ingredient also It can be regarded as—pleasant skin moisturizer. After the solution is evaporated, it can be used again to maintain the protective effect. Example 3. By combining the following at room temperature T by weight% of total weight and regardless of the order of addition, Ingredients to prepare water-white clear insect repellent solution: 0.024% 0.049% 4.015% 1.000% 0.850% Consumption cooperation with employees of the Central Standards Bureau of the Ministry of Economic Affairs Du printed water γ-nonanyl lactone γ-ll carbamic acid Ester d-secadiene liquid stone Tween-80 (surfactant) Span-80 (surfactant) Fast-evaporating white mineral oil Slowly evaporating white mineral oil After stirring for a while, the solution has stabilized 0.150% 70.434 % 23.478% and ready to use as woxgras grade oil-based larvicides or insecticides. For any application, it is sometimes convenient to transfer a water-emulsion emulsion to the water surface or the plant surface in one spray, and it is convenient to break the supply of water. Read the notes on the back and fill in this page again.) This paper size IT towel is based on the family standard rate (CNS) A4 specification (210X297 $ cents) 474789 A7 Employees' cooperation cooperation of the Central Prototype Bureau of the Ministry of Economic Affairs. And separate from the passing water. The amount of water transfer mass may change. For general use, up to about 10 gallons of water can be used to transfer about ... the solution of Example 3 to the target area. + The milky spray is used properly. The sprayer must be prepared to continuously mix the water and oil phases during use. When the above ingredients contain a selected amount of surfactant, a well-mixed oil-in-water emulsion spray will separate within a few seconds after hitting the target. The oil will adhere to show its designed function, and the transferred water will evaporate and flow away. aims. Of the two types of oil, the fast-drying oil will kill the adults and their larvae and eggs, while the slow-evaporating white mineral oil and changing fragrance will remain to form a coating on the plant surface and drive other insects from landing on the crop. Although used as a mosquito larva, a solvent (with or without passing water) as shown is used to stagnant water surfaces in ponds, swamps, and ditches, where mosquito larvae multiply. Example 3 is formulated to spread a tiny film quickly across the surface of the water, which isolates the larvae from breathing at the water-air junction. The amount of the prescription used depends on the implementation area and the field (mosquito population size and weather). Typically, approximately 15 gallons of oil from Example 3 may be used on the surface of each acre, plus the intended transfer of water. The sprayer must be prepared to mix the ingredients before use. Larvae are killed a few minutes after use and new growth is delayed by two weeks thereafter. Example three may be used several times a month during the breeding season. Example 3 is also effective for spraying rows of crops, fruit trees, and vines to kill and repel insects. The typical application rate is a solution between about 1G gallon per acre of Example 3, depending on the target pest, the density of the growing crop, and the temperature. Please read -4 and read the iS precautions before reordering. ▲ National Standard of this paper (CNS) A4 specifications (21〇χ297ϋ ~ r / leaf / A7 V. Invention day 1 — Degree and other factors depend on. In the growing season, the frequency of 'successful use' can vary from weekly to monthly In order to be delivered to the target in the form of a spray and mixed with water, the emulsion is quickly broken so that the plant surface is covered with oil 'and the water will run away to irrigate the vegetables. When the present invention has been included, the reference material is described as special It is obvious to those skilled in the art that the examples, implementations, products, and scope may be modified without departing from the present invention, which will be specifically pointed out in the scope of the following patent applications. The invention is suitably exemplarily disclosed in the text, and may be practical in the absence of any element that is not specifically disclosed in the text. Therefore, the present invention may be based on the basic elements disclosed herein The group is salty. ---------— 4 (Please read the notes on the back before filling this page)

-、 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

Ns 6 quasi-standard country 1 form 5 degree rule paper

Claims (1)

474789 1. Application for Patent 1¾ 2, 3. Revision of Patent No. 86111070 Application for Amendment to Patent Scope Amendment Date: November 1990 A method for killing insects with a protective wax waterproof film covering the body to prevent dry insects, It comprises: using an effective dose of a terpene having the molecular formula C ^ H! 6 and a fast-evaporating white mineral oil solution to wet the insect to destroy the tadpole waterproof membrane, the fast-evaporating white mineral oil has a temperature of 176.7 ° C (350 ° F) to 210 ° C (410 ° F) distillation starting boiling point, an endpoint of 207.2 ° C (405 ° F) to 268.9 ° C (5160F), and a 61.1 ° C (142 ° F) to Flash point at 73.9 ° C (165 ° F). A method for repelling insects attracted by the odor released by a place. It includes using a solution of an effective dose of PI with molecular formula CiqHi6 and a slowly evaporating white mineral oil solution to wet the place to cover it. The odor released from the site, 'The slowly evaporating white mineral oil has a distillation starting boiling point of 182.2 ° C (360 ° F) and above, -315.6. End points of € (600. 卩) and above, and a flash point of 118.300 (245 ° F) to 310 ° C (590 ° F). A method for exterminating mosquitoes by animals or humans, comprising using an effective dose of a terpene having the molecular formula C1GH16 in a slowly evaporating white mineral oil solution to wet the exposed skin surface of an animal or human, the slowly evaporating white minerals The oil has a distillation starting boiling point of 182.2 ° C (360 ° F) and above, an end point of 315.6 ° C (600 ° F) and above, and 118.3. (: (245 ° F) to 310 ° C (590 ° F) The paper size is applicable to the Chinese national standard (Which) A4 specification (21〇 < 297mm) (Please read the precautions on the back before (Fill in this page) 474789 A8 B8 C8 ___ D8 6. Scope of patent application Ignition point. 4_ A method for killing mosquito larvae ', which comprises a solution of a terpene of the formula CwHw in a white mineral oil matrix on the surface of a mosquito breeding water. The white mineral oil matrix contains a weight ratio of 1: A mixture of fast evaporating white mineral oil and slow evaporating white mineral oil from 99 to 99: 1; the fast evaporating white mineral oil has a distillation starting boiling point of 176_70 ° C (350T) to 21 (TC (410 ° F),- End point from 207.2 ° C (405 ° F) to 268.9 ° C (516 ° F) and a flash point of 61.1 ° C (142 ° F) to 73.9 ° C (165 ° F); this slowly evaporating white mineral oil has -182_2 ° C (360 ° F) and above distillation starting boiling point,-315.6. (: (600.?) And above endpoint, and-118.3 ° C (245 ° F) to 310 ° C (590 ° F) ). 5. —A method for killing or repelling white flies, comprising wetting one or more or all of a solution of a knife-type C ^ H! 6 terpene in a white mineral oil base solution. At the leaves of plants infected by white flies, the white mineral oil matrix contains a fast-evaporating white mineral oil and a slowly-evaporating white mineral in a weight ratio of 1:99 to 99: i, respectively. A mixture of oils; the fast-evaporating white mineral oil has an initial boiling point of 176 7 ° C (3500Fg 21.00. € (410 F),-27.2.20C (405 ° F) to 268.9 C (516 ° F), and a flash point from w.pc (142 ° F) to 73.90C (165 ° F); the slowly evaporating white mineral oil has a steaming hall of 182.2 C (360 ° F) and above Initial boiling point, -315 6 ° C (600 F) and above, and a temperature of 118.3 ° C (245 ° F) to 310oC This paper size applies to Chinese national standards (CNS > Ai ^^ 1 () X297H-^ -(Please read the notes on the back before filling out this page), install _. Order-> · line 丨 The flash point β of (59 °° f) is the method of item 1 in the patent range, where the total 7 of the solution is reset as a reference, and the diluent is present in an amount of 0.1 to 50% by weight. • The method according to item 2 of the patent application, wherein the total weight of the case is 0.1 to 50% by weight based on the total weight of the solution. The method of item 3 of the Ming patent, wherein the box diluent is present in an amount of 0.1 to 50% by weight based on the total q amount of the solution. The method of item 4 in the monthly patent of $ 11, in which the amount of the boxene is 0.1 to 50% by weight based on the amount of ln converted from the solution / the method of item 5 in the patent specification, wherein the total amount of the solution is It is known that the chain diluent is present in an amount of 0.1 to 50% by weight. = Please call the method in the first item of the patent scope, where "ene is q-cotton 0 where the terpene is d-xiang 12. If the method of the second item in the patent scope is applied, diene. 13. Such as the application of the patent range of diene. 14. If the scope of patent application is-Dilute 0 15. If the scope of patent application is Diene. 16. The method according to the scope of application for patents No. 03, wherein the terpene is a method of 4 d-terpenes, wherein the terpene is a method of 5 d-terpenes, wherein the material is d-il 6 Method 'In which ene is ㈣ The paper size is suitable for National Standards (CNS) A4 specifications (210X 297) 17_ If the scope of patent application is 7th-thin. 18. If the scope of application for the patent No. 8-. Method of dilute 0, wherein the terpene is classified as a method, wherein the terpene is d-terpene d-terpene 9 method, wherein the terpene is cardiac terpene 19. For example, the first patent application scope is patent # 1. The method of item (1), wherein the diluent is the method of any one of items (1) to (2G) in the patent application range of d_21. T, wherein the solution further comprises at least one aldehyde. 22. The method of claim 21 in the scope of patent application, wherein the road system exists in an amount of 0.010 to 5% by weight based on the total weight of the solution. 23. The method of claim 21, wherein the tie is selected from the group consisting of 7 " decatolactone, nonanoic acid vinegar, and a mixture thereof. 24. The method of claim 22, wherein the aldehyde is selected from the group consisting of 7-undecanolactone, r-nonanonolactone, and a mixture thereof. 25 'The method according to any one of claims 1 to 20 of the patent application range, wherein the solution further comprises a lithone solution. 26. The method of claim 25, wherein the silicone liquid is present in an amount of 0.1 to wt% based on the total weight of the solution. This paper size applies the Chinese national standard (CNS > A4 size (210X297mm) -91-A8 B8 C8 '^ ___ D8___' for patent application. For the method of applying for patent application No. 25, where the silicone liquid has a viscosity of 10 -350 centistoke of fluorene-based polylithic sintered oxygen.. For example, the method of the scope of application for patent No. 26, wherein the silicone liquid is a viscosity of 10-350 centistokes of fluorene-based polycondensate. Oxygen burning. 29. The method according to any one of claims 1 to 20, wherein the / grain solution further comprises at least one surfactant to facilitate the manufacture of water packs suitable for large-scale water-assisted spray applications. Oil-based emulsion. 30. Method of claim 29 in the patent application range, wherein the surfactant is present in an amount of 0.1 to 5 weight% based on the weight of the solution. 31. Such as the scope of patent application The method of item 29, wherein the surfactant is sorbitol monooleate, ethoxylated sorbitan monooleate, or a mixture thereof. 32. As described in claim 30 of the scope of patent application Method wherein the surfactant Sorbitan monooleate, polyethoxylated sorbitan monooleate, or a mixture thereof. The method according to any one of claims 20 to 20, wherein the solution further comprises Order—Aromatic agent. See the method of applying for patent _ item 33, wherein the amount of the aromatic agent is up to 2% by weight based on the total weight of the solution. 6. Scope of patent application 35. Scope of patent application The method of item 33, rejuvenation-one selected from the group consisting of fennel, benzaldehyde, stearic acid, and meat fragrant: line of musk, Haitian oil and vanilla. Into 36. If the scope of patent application The method according to item 34, wherein the aroma is selected from the group consisting of fungal brain, benzyl, benzoic acid, cinnamyl alcohol, synthetic musk, Haiti oil and vanillin. The method of any one of items 1 to 20, wherein the solution further comprises: an aldehyde, wherein the aldehyde is present in an amount of 0.010 to 5.0% by weight based on the total weight of the solution; "a silicone solution , Where based on the total weight of the solution, The silicone liquid is present in an amount of 0.1 to 10% by weight; and M is at least one surfactant, wherein the surfactant is present in an amount of 0.1 to 5% by weight based on the total weight of the solution. 3S. The method according to item 37 of the scope of the patent application, wherein the aldehyde is selected from the group consisting of r-undecanolactone, 7-nonanonolactone, and mixtures thereof; wherein The silicone liquid is a dimethylpolysiloxane having a viscosity of 10-350 centistoke; and the surfactant is sorbitan monooleate and polyethoxylated sorbitan monooleate. Sugar alcohol anhydride or a mixture thereof. 39. The method of claim 38, wherein the solution further comprises: a fragrance, wherein the fragrance is present in an amount of up to 2% by weight based on the total weight of the solution. -25- This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm) 6. Application for Patent Park 40. If the method of applying for the scope of patent No. 39, the aroma is selected from the fungus fragrance Brain, benzaldehyde, benzoic acid, cinnamyl alcohol, synthetic musk, Haitian oil, and vanillin. 41. The method as described in item M of item No. 1-20 in item M, wherein all the ingredients in the mixture are generally rated as safe for human consumption. As stated in the method of item 37 of the patent scope, in which all components of the solution are generally rated as safe for use in human consumption food ", 43.-a kind used to kill or repel an insect or a larva A composition comprising a terpene having a molecular formula Cu) Hi0 in a white mineral oil matrix, the white mineral oil matrix is selected from the group consisting of a fast-evaporating white mineral oil, which has a 176 7 < 3C (350 F) to 210. (: (410 ° F) distillation starting boiling point, -207 °. ^ (405 ° F) to 268-9 ° C (516 ° F) end point, and -61 1 ° c (142 ° F) to 73.9 ° C (165 ° F) flash point, a slowly evaporating white mineral oil with a distillation starting boiling point of 182.2 < JC (360 F) and above, a 315 6 < &c; c (600) ρ) and above, and a flash point of 118.3X (245 ° F) to 310 ° C (590 ° F), and a mixture thereof with a weight ratio of 1:99 to 99: 1, respectively. 44. A A composition for killing or repelling an insect or-larva, its paper size applies to China National Standard (CNS) A4 (210X 297 mm) -M 4/4 / 5V Α8 Β8 C8 D8 The range is composed of: (A) a terpene having the molecular formula C10H16; (B) a white mineral oil matrix; (C) optionally, at least-while; ⑼ selectively 'at least one silicone liquid; ⑻ selection In particular, at least one surfactant; and (F) optionally 'a fragrance. A The composition according to item 44 of the application, wherein the white mineral oil matrix is selected from the group consisting of A rapidly erupting white mineral oil, which has a distillation starting point of -176 7oc (3) to 2ioc (410 F), -2072. 匸 (405. 卩) ) To 268.9 ° C 61.PC (142 ° F) J. 73.9 ° C (165 ° F) flash point, a slowly evaporating white mineral oil with a temperature of 182.2 ° C (360 ° F) and above The initial boiling point of distillation, an end point of 315.6 ° 0 (600 叩) and above, and an 1183. (:: (245〇1?) To the flash point of 3WC (5), and (3) a weight ratio are A mixture of 1:99 to 99: 1. 46. The composition of claim 43 in the stated patent range, wherein the terpene is present in an amount of 0.1 to 50% by weight based on the total weight of the composition β 47. If the composition in the scope of patent application No. 44 is used, wherein the terpene is present in an amount of 0.1 to 50% by weight based on the total weight of the composition. 0 This paper applies Chinese National Standards (CNS) Α4 specification (210X297 mm) (Please read the precautions on the back before filling out this page) i .. · order · A8 B8 C8 patent application scope: the composition of the 45th scope of the benefit range, in which the composition Weighed the weight as the basis' the box of women's line exists 0.1 S 50% by weight 49: 1: the composition of the scope of the 43rd item, where the _ is d-50. If the composition of the scope of the 44th application for the patent, where The woman is & terpene. 51. The composition of claim 45, wherein the terpene is a cardiac diene. 52. The composition of claim 46, wherein the terpene is d · terpene diene. 53. The composition of claim 47, wherein the terpene is a d-terpene diene. 54. The composition according to item 48 of the patent application, wherein the terpene is d_IS dilute. 55. The composition according to any of item 43, 46, 49, and 52 of the patent application, wherein the solution is further Contains at least one aldehyde. 56. If the composition of any one of the scope of patent application Nos. 44, 45, 47, 48, 50, 51, 53 and 54 is applied, based on the total weight of the composition, the aldehyde is present. 〇 to 5.00 weight. /. The amount. 57. If the composition of the scope of patent application No. 55, in which the aldehyde is present in an amount of 0.010 to 5.0% by weight based on the total weight of the composition "2S. This paper size applies Chinese national standards (CNS ) Α4 size (210X297 mm) (Please read the precautions on the back before filling in this page) The scope of patent application 58. The composition of the 56th scope of the patent application, such as aldehydes (please read the precautions on the back before filling this page) Free Deca-lactone, T-nonanolactone And their mixtures. 59. The composition according to claim 57 in which the aldehyde is selected from the group consisting of r-undecanolactone, nonanonolactone, and a mixture thereof. 60. The composition according to any one of claims 43, 46, 49 and 52 of the scope of patent application, wherein the solution further comprises a silicone solution. 61. The composition according to any one of claims 44, 45, 47, 48, 50, 51, 53 and 54 of the scope of patent application, wherein the silicone liquid system is present based on the total weight of the composition. Amount from 1 to 10% by weight. 62. The composition according to item 60 of the patent application, wherein the silicone liquid is present in an amount of 0.1 to 10% by weight based on the total weight of the composition. 63. The composition according to item 61 of the patent application, wherein the silicone liquid is a dimethylpolyoxane having a viscosity of 10-350 centistoke. 64. The composition according to item 62 of the patent application, wherein the lithoxone solution is a dimethyl polyoxoxiran having a viscosity of 10-350 centistoke. 65. The composition of any one of claims 43, 46, 49, and 52 of the scope of patent application, wherein the solution further comprises at least one surfactant to facilitate the manufacture of water packs suitable for large-scale water-assisted spray applications_ ________- 2Q -___ This paper size applies to China National Standard (CNS) A4 (210X297 mm) Oil-based emulsion. 66. If the composition of any one of the scope of patent application Nos. 44, 45, 47, 48, 50, 51, 53 and 54 is applied, based on the total weight of the composition, the surfactant is present in the range of 0.1 to The amount of 5 weight 0 / 〇. 7. The composition of claim 65, wherein the surfactant is present in an amount of 0.1 to 5% by weight based on the total reset of the composition. 8 'The composition of claim 66, wherein the surfactant is sorbitan monooleate, polyethoxylated sorbitan monooleate, or a mixture thereof. 69. The composition of claim 67, wherein the surfactant is sorbitan monooleate, sorbitan monooleate or a mixture thereof. 70. The composition 'according to any one of claims 43, 46, 49 and 52 of the patent application scope, wherein the solution further comprises a fragrance. 71. If the composition of any one of the scope of patent applications 44, 45, 47, 48, 50, 51, 53 and 54 is applied, wherein the total reset of the composition is used as a basis, the fragrance is present as much as 2% by weight. 72. The composition according to item 70 of the scope of patent application, wherein the fragrance is present in an amount of up to 2% by weight based on the total weight of the composition. 73. If the composition of the scope of patent application No. 71, in which the fragrance is used, the paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 474789 A8 Βδ C8 D8 It is selected from the group consisting of anisin, benzaldehyde, benzoic acid, cinnamyl alcohol, synthetic musk, Haiti oil and vanillin. 74. The composition of claim 72, wherein the fragrance is selected from the group consisting of anisin, benzaldehyde, benzoic acid, cinnamyl alcohol, synthetic musk, Haitian oil, and vanillin. 75. The composition according to any one of claims 43, 45, 46, 48, 49, 51, and 54 in which the white mineral oil matrix is the slowly evaporating white mineral oil. 76. The composition of any one of items 43, 46, 49 and 52 of the scope of application for a patent, wherein the composition further comprises: an aldehyde, wherein the aldehyde is present in the range of 0.010 to 5 based on the total weight of the solution An amount of Q% by weight; a silicone liquid in which the silicone liquid is present in an amount of 0.1 to 10% by weight based on the total weight of the solution; and at least one surfactant in which the solution is Based on the total weight, the surfactant is present in an amount of 0 to 5% by weight. 77. The composition of the scope of patent application No. 76, wherein the route is selected from the group consisting of 7 * -undecanolactone, r-nonanonolactone and mixtures thereof Wherein the silicone liquid is a difluorenyl polysiloxane having a viscosity of 10-35 centistokes; and the surfactant is sorbitan monooleate, polyethoxylation Sorbitan monooleate or a mixture thereof. 78. The composition according to item 77 of the application, wherein the solution is One step includes: a fragrance, wherein the fragrance is present in an amount of up to 2% by weight based on the total weight of the solution. For example, the composition of claim 78, wherein the fragrance is selected from the group consisting of anisin, benzaldehyde, benzoic acid, cinnamyl alcohol, synthetic musk, Haiti oil and vanillin. 80. The composition according to any one of claims 43 to 54 of the scope of patent application, wherein all the ingredients in the composition are generally rated as safe for human consumption food. 81. A composition as described in item 76 of the Shining Patent, in which all the ingredients in the composition are generally rated as safe for human consumption. • ------- This paper size applies to China National Standard (CNS) A4 (210X297 mm)