JPH03285993A - Perfume composition - Google Patents
Perfume compositionInfo
- Publication number
- JPH03285993A JPH03285993A JP8644190A JP8644190A JPH03285993A JP H03285993 A JPH03285993 A JP H03285993A JP 8644190 A JP8644190 A JP 8644190A JP 8644190 A JP8644190 A JP 8644190A JP H03285993 A JPH03285993 A JP H03285993A
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- mosquito
- mosquitoes
- effect
- perfume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000002304 perfume Substances 0.000 title abstract description 10
- 241000255925 Diptera Species 0.000 claims abstract description 38
- 230000000694 effects Effects 0.000 claims abstract description 30
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims abstract description 10
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000007586 terpenes Nutrition 0.000 claims abstract description 9
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940043350 citral Drugs 0.000 claims abstract description 7
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims abstract description 7
- 235000000983 citronellal Nutrition 0.000 claims abstract description 5
- 229930003633 citronellal Natural products 0.000 claims abstract description 5
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 5
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229940100595 phenylacetaldehyde Drugs 0.000 claims abstract description 5
- 235000001510 limonene Nutrition 0.000 claims abstract description 4
- 229940087305 limonene Drugs 0.000 claims abstract description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 3
- 239000003205 fragrance Substances 0.000 claims description 60
- 239000000077 insect repellent Substances 0.000 claims description 14
- 230000001846 repelling effect Effects 0.000 claims description 11
- -1 terpene aldehyde Chemical class 0.000 claims description 9
- 230000000749 insecticidal effect Effects 0.000 abstract description 7
- 150000001299 aldehydes Chemical class 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 150000003505 terpenes Chemical class 0.000 abstract 2
- 239000012080 ambient air Substances 0.000 abstract 1
- 230000003444 anaesthetic effect Effects 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229930006978 terpinene Natural products 0.000 abstract 1
- 150000003507 terpinene derivatives Chemical class 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
- 238000009834 vaporization Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000341 volatile oil Substances 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 240000004784 Cymbopogon citratus Species 0.000 description 4
- 235000017897 Cymbopogon citratus Nutrition 0.000 description 4
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- 239000002386 air freshener Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- 241000256054 Culex <genus> Species 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 240000004460 Tanacetum coccineum Species 0.000 description 2
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 2
- 125000003172 aldehyde group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229940015367 pyrethrum Drugs 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001112 (2E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene Substances 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- NTXGFKWLJFHGGJ-ACCUITESSA-N 1,1-Diethoxy-3,7-dimethyl-2,6-octadiene Chemical compound CCOC(OCC)\C=C(/C)CCC=C(C)C NTXGFKWLJFHGGJ-ACCUITESSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- 241000134916 Amanita Species 0.000 description 1
- 241000256186 Anopheles <genus> Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 208000035473 Communicable disease Diseases 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000001941 cymbopogon citratus dc and cymbopogon flexuosus oil Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002316 fumigant Substances 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000000384 rearing effect Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野〕
本発明は蚊取り効果のある香料組成物、特に揮散する香
料成分によって、空中を飛んでいる蚊を落とすことが出
来る蚊取り効果のある香料組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention provides a fragrance composition that has a mosquito repelling effect, particularly a fragrance composition that has a mosquito repellent effect that can repel mosquitoes flying in the air by means of a volatilizing fragrance component. Regarding.
［従来の技術］
例えば、アカイエカ、ハマダラ力、テングカなどの家紋
は、特に夏期に一般家庭に発生する代表的な害虫として
知られ、雌の蚊は産卵期に吸血するため、吸血された局
部の皮膚に耐えがたいかゆみをもたらし、また各種の伝
染病の媒介の恐れもあることから、蚊の駆除は、ｌｌｆ
！ｆ的かつ快適な生活を維持する上で極めて重要な意義
を持つ。[Prior Art] For example, Culex mosquitoes, Anopheles mosquitoes, Amanita mosquitoes, and other family crests are known as typical pests that occur in households, especially in summer. Mosquitoes cause unbearable itching on the skin and may transmit various infectious diseases, so it is important to exterminate mosquitoes.
! It has extremely important significance in maintaining a comfortable and comfortable life.
ところで、従来の家庭で用いる蚊取り効果のある家庭用
品としては、除虫菊由来のピレスロイド化合物を有効成
分とする蚊取り線香及びマット式の電気蚊取り等が知ら
れている。By the way, as conventional household products that have a mosquito repellent effect and are used at home, mosquito coils containing a pyrethrum-derived pyrethroid compound as an active ingredient and mat-type electric mosquito repellents are known.
これらは、線香の燃焼あるいはマットの加熱等加熱によ
り有効成分を空中に揮散させることにより、蚊取り効果
を発揮するものである。These products exhibit a mosquito repellent effect by volatilizing their active ingredients into the air through heating such as burning an incense stick or heating a mat.
また、蚊取り線香、マット式電気蚊取りには、その特異
臭をおきえるため芳香物質が混入されているものが多い
。In addition, many mosquito coils and mat-type electric mosquito repellents contain aromatic substances to eliminate their unique odors.
［発明が解決しようとする課題］
しかしながら、従来の蚊取り効果のある家庭用品は、な
んらかの手段で加熱することにより、その効果を発揮す
るものであり、家庭内で、より簡単かつ安全に、蚊取り
効果を発揮する手法が望まれていた。[Problem to be solved by the invention] However, conventional household products that have mosquito repelling effects exert their effect by heating them by some means, so it is easier and safer to use them at home to repel mosquitoes. A method to demonstrate this was desired.
すなわち、蚊は、昼夜を通じて家庭内を飛びかい、いつ
吸血するかが予測出来ないことが多い。In other words, mosquitoes fly around the home throughout the day and night, and it is often unpredictable when they will suck blood.
このような状況の下では、従来の蚊取り効果のある家庭
用品の場合、就寝中も燃焼、加熱あるいは発煙をともな
うため、安全の面からも健康の面からもその使用方法の
改善が強く求められていた。Under these circumstances, conventional household products that have mosquito repellent effects burn, heat, or emit smoke even while you sleep, so there is a strong need to improve the way they are used from both safety and health perspectives. was.
また、その香りは、芳香物質が加えられていても、除虫
菊由来の特異臭や加熱、発煙による焦臭をおさえること
は難しく、不快感の強いものであった。In addition, even if an aromatic substance was added, it was difficult to suppress the peculiar odor derived from pyrethrum and the burning odor caused by heating and smoking, resulting in a strong unpleasant sensation.
一方、インドを始めとする複数の国において、ある種の
植物が蚊や蝿などの昆虫に対して殺虫、忌避などの効果
を持つことが伝え知られていた。On the other hand, in several countries including India, it has been reported that certain plants have insecticidal and repellent effects against insects such as mosquitoes and flies.
特にレモングラスと呼ばれるイネ科の植物から得られる
精油は、蚊や蝿に対する殺虫性、忌避能力、揮発成分に
より蚊を落とす能力を持つことが報告きれているｏ （
Ｅｖａｌｕａｔｆｏｎ ｏｆ １ｎｓｅｃｔｉｃｉｄａ
ｌ。In particular, essential oil obtained from a grass family plant called lemongrass has been reported to have insecticidal and repellent properties against mosquitoes and flies, and the ability to repel mosquitoes due to its volatile components.
Evaluation of 1nsecticida
l.
ｆｕｍｉｇａｎｔ、ａｎｄ ｒｅｐｅｌｌａｎｔ ｐｒ
ｏｐｅｒｔｉｅｓ ｏｆ ｌｅｍｏｎ−ｇｒａｓｓ ｏ
ｉｌ、 Ｂ＋に、Ｔｉｖａｒｉ、ｅｔ ａｌ、Ｉｎｄｉ
ａｎ Ｊ、Ｅｘｐｔｌ。fumigant, and repellant pr
operties of lemon-grass o
il, B+, Tivari, et al, Indi
an J, Exptl.
Ｂｉｏｌ、４（２）、１２９−９（１９６６））。Biol, 4(2), 129-9 (1966)).
しかしながら、これらの植物あるいは植物精油は、やは
り特異臭をともなうものであり、不快感を伴うものであ
った。However, these plants or plant essential oils still have a distinctive odor, which is unpleasant.
本発明は前記従来技術に鑑みなされたものであり、その
目的は、芳香を持つとともに、熱を加えないで容易に揮
発し、しかも効果的に蚊取り効果を発現させることが出
来る蚊取り効果のある香料組成物を提供することにある
。The present invention has been made in view of the above-mentioned prior art, and its object is to provide a mosquito-repelling fragrance that has a fragrance, easily evaporates without applying heat, and can effectively exhibit a mosquito-repelling effect. An object of the present invention is to provide a composition.
［課題を解決するための手段〕
前記目的を達成するために本発明者らが鋭意検討した結
果、レモングラス精油あるいは他の植物精油に一般的に
存在する揮発成分の中である特定の構造を持つ揮発性の
高い化合物が、芳香を持ちかつ優れた蚊取り効果がある
ことを見出し、本発明を完成するに至った。[Means for Solving the Problems] In order to achieve the above object, the inventors of the present invention have made extensive studies, and have found that a certain structure among the volatile components generally present in lemongrass essential oil or other plant essential oils has been found. They discovered that this highly volatile compound has a fragrance and has an excellent mosquito repelling effect, leading to the completion of the present invention.
すなわち、本出願の請求項１記載の蚊取り効果のある香
料組成物は、蚊取り効果を持つ香料化合物を気中濃度で
０．６μｇ／ｃ■３以上となるように存在させることを
特徴とする。That is, the fragrance composition having a mosquito-repelling effect according to claim 1 of the present application is characterized in that the fragrance compound having a mosquito-repelling effect is present in an air concentration of 0.6 μg/c3 or more.
また、請求項２記載の香料組成物は、香料がシトラール
、シトロネラールを含むテルペン系アルデヒドであるこ
とを特徴とする
請求項３記載の香料組成物は、香料がリモネン、チルピ
ネンを含むテルペン系炭化水素であることを特徴とする
請求項４記載の香料組成物は、香料がアルデヒドＣ−８
であることを特徴とする
請求項５記載の香料組成物は、香料がフェニルアセトア
ルデヒドであることを特徴とする。The fragrance composition according to claim 2 is characterized in that the fragrance is a terpene aldehyde containing citral and citronellal.The fragrance composition according to claim 3 is characterized in that the fragrance is a terpene hydrocarbon containing limonene and tilpinene. The fragrance composition according to claim 4, wherein the fragrance is aldehyde C-8.
The fragrance composition according to claim 5 is characterized in that the fragrance is phenylacetaldehyde.
以下、本発明の構成を詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明において、蚊取り効果とは、空中を飛んでいる蚊
を殺虫効果あるいは麻痺効果により落下きせるものであ
る。In the present invention, the mosquito repellent effect is one that causes mosquitoes flying in the air to fall due to their insecticidal or paralyzing effect.
また、本発明にかかる蚊取り効果のある香料組成物は、
前記有効成分が有効量空中に揮散し、効力範囲内にいる
蚊に対して、殺虫効果、麻痺効果を発現するものを指し
、室内芳香剤、コロン、塗布医薬品、医薬部外品の他、
エアゾールスプレーデイスペンサー型のミスト製品等も
包括するものである。Moreover, the fragrance composition having a mosquito repelling effect according to the present invention is
Refers to products in which an effective amount of the above-mentioned active ingredient is vaporized into the air and exerts an insecticidal and paralyzing effect on mosquitoes within the effective range.
This also includes aerosol spray dispenser type mist products.
また、本発明におけるシトラール、シトロネラ−ルを含
むテルペンアルデヒド類、リモネン、チルピネンを含む
テルペン炭化水素類、アルデヒドＣ−８、フェニルアセ
トアルデヒドは、公知の香料化合物であり、標準商業品
種が本発明に用い得るが、有機合成などにより得られる
どのような品位の化合物でも用いることができる。In addition, terpene aldehydes including citral and citronellal, terpene hydrocarbons including limonene and tilpinene, aldehyde C-8, and phenylacetaldehyde in the present invention are known fragrance compounds, and standard commercial varieties are used in the present invention. However, any grade of compound obtained by organic synthesis etc. can be used.
ざらに天然の植物あるいはその精油から蒸留、抽出等の
方法で得られた香料化合物を本発明に用いることができ
る。Flavor compounds obtained from natural plants or their essential oils by methods such as distillation and extraction can be used in the present invention.
尚、揮発により効果を発揮するものであるため、気中濃
度に効果が依存するが、各蚊取り効果を持つ香料化合物
について、０．６μｇ／Ｃ１３以上で優れた効果が得ら
れる。Since the effect is exerted by volatilization, the effect depends on the concentration in the air, but excellent effects can be obtained at 0.6 μg/C13 or more for each fragrance compound having a mosquito repellent effect.
このように、本発明にかかる蚊取り効果のある香料組成
物は、特定の香料を一定濃度以上で気中に存在させ、蚊
に対して殺虫効果あるいは麻痺効果を及ぼすことにより
、容易に優れた蚊取り効果を発現することができる。As described above, the fragrance composition having a mosquito repelling effect according to the present invention can easily be used as an excellent mosquito repellent by having a specific fragrance present in the air at a certain concentration or more and exerting an insecticidal or paralyzing effect on mosquitoes. effect can be expressed.
［実施例］ 以下、本発明のより具体的な実施例を説明する。[Example] More specific examples of the present invention will be described below.
尚、本発明はこれにより限定されるものではない。また
、配合量は特に指定がない限り重量％で示す。Note that the present invention is not limited to this. Further, the blending amount is expressed in weight % unless otherwise specified.
り まず、蚊取り効果の評価法を説明する。the law of nature First, we will explain how to evaluate mosquito repellent effectiveness.
実験昆虫；同じ日に成虫となった吸血していない雌のア
カイエカを、一定環境で２日間飼育した後、−群を１２
匹として実験を行なった。Experimental insects: After rearing non-blood-sucking female Culex mosquitoes that became adults on the same day in a constant environment for 2 days, -groups of 12
Experiments were conducted as animals.
実験装置；口径６ｃｍ、高き１０ｃｍの透明ガラス製の
コツプを用い、蚊を内部に入れて蚊が逃げない程度の隙
間をあけて伏せ、内部の香気が循環しないように無風の
ドラフト中に静置し、蚊を自由活動させた。Experimental equipment: Using a transparent glass cup with a diameter of 6 cm and a height of 10 cm, put a mosquito inside and place it face down with a gap large enough to prevent the mosquito from escaping, and leave it in a windless draft so that the scent inside does not circulate. and allowed the mosquitoes to move freely.
香料；揮発性の低い溶媒であるＴ Ｅ Ｃ（Ｔｒｉｅｔ
ｈｙｌｃｉｔｒａｔｅ）を対照香料、効果の報告されて
いるレモングラス精油を基準香料として別表記載の８種
類を用いて検討した。Fragrance: TEC (Triet
hylcitrate) as a control fragrance and lemongrass essential oil, which has been reported to be effective, as a reference fragrance, using eight types listed in the attached table.
香り刺激；コツプ内に内径２ｃｍ、高き１ｃｍのポリエ
チレン製の円筒型の小皿に、ＴＥＣで５％に希釈した各
香料を約２０ｍｇ入れ、９０分間刺激した。Fragrance stimulation: Approximately 20 mg of each fragrance diluted to 5% with TEC was placed in a small cylindrical dish made of polyethylene with an inner diameter of 2 cm and a height of 1 cm, and stimulated for 90 minutes.
第 １ 表
以上の実験では、香料の蚊取り効果により蚊が麻痺効果
あるいは殺虫効果により死に至って落下し、効果が高い
ほど落下に要する時間が短かくなる。In the experiments shown in Table 1 and above, the mosquito-repellent effect of the fragrance paralyzes or kills mosquitoes, causing them to die and fall, and the higher the effect, the shorter the time required for the fragrance to fall.
従って、各香料によって、落下した蚊をカウントし、経
時による落下％の推移を調べることにより、その香料の
蚊取り効果を評価することができる。Therefore, by counting the number of fallen mosquitoes for each fragrance and examining the change in the percentage of falling mosquitoes over time, it is possible to evaluate the mosquito repelling effect of that fragrance.
そこで、ＴＥＣをコントロール、レモングラス油を基準
となる効果香料として、別表中に記載した８種の香料に
ついて実験を行ない、それぞれの蚊の落下数をカウント
し、経時による落下％の推移を調べた。Therefore, using TEC as a control and lemongrass oil as a reference effective fragrance, we conducted an experiment using the eight types of fragrances listed in the attached table, counted the number of falling mosquitoes for each type, and examined changes in the percentage of falling mosquitoes over time. .
結果を次の第１表に示す。The results are shown in Table 1 below.
ゲラニオールは、シトラールと同様の炭素骨格を持ち、
官能基がアルデヒド基から水酸基に置き変わった化合物
であり、フェニルアセトアルデヒドとフェニルエチルア
ルコールも同じ関係にある。Geraniol has a carbon skeleton similar to citral,
It is a compound in which the functional group has been replaced with a hydroxyl group instead of an aldehyde group, and phenylacetaldehyde and phenylethyl alcohol have the same relationship.
また、シトラールジエチルアセタールは、アルデヒド基
がアセタール化されて、その特性を失っている。Furthermore, the aldehyde group of citral diethylacetal has been acetalized and has lost its properties.
このように、香料全般に蚊取り効果があるのでなく、特
定の香料にのみ、優れた蚊取り効果があることが理解き
れる。In this way, it is easy to understand that not all fragrances have a mosquito-repelling effect, but only certain fragrances have an excellent mosquito-repelling effect.
また、効果の顕著な香料は、テルペン炭化水素あるいは
アルデヒドを官能基に持つ化合物であることが分る。It is also found that the most effective fragrances are compounds with terpene hydrocarbons or aldehydes as functional groups.
これらの効果の顕著な香料は、全て芳香を持つものの、
あまり高い濃度で用いると嗜好が低下すると考えられる
が、前記実験例では、気中濃度は０．６μｇ／ｃ■３で
あり、この程度の嗜好のよい濃度において十分な蚊取や
効果が発揮される。Although these fragrances with remarkable effects all have aromas,
It is thought that preference will be reduced if it is used at too high a concentration, but in the above experimental example, the airborne concentration was 0.6 μg/c3, and sufficient mosquito repelling and effectiveness was demonstrated at this palatable concentration. Ru.
尚、このような気中濃度を得るためには、シトラールは
１０重量％以上、その他の効果香料では５重量％以上配
合した調香料を得、それを有効成分として各種組成物に
配合することが好適である。In order to obtain such a concentration in the air, it is necessary to obtain a perfume containing 10% by weight or more of citral and 5% or more by weight of other effective fragrances, and then incorporate them into various compositions as active ingredients. suitable.
また、本発明にかかる蚊取り効果のある香料組成物は、
次のような各種用途に使用可能である。Moreover, the fragrance composition having a mosquito repelling effect according to the present invention is
It can be used for various purposes such as:
（１）室内での蚊取り剤として使用する例。(1) Example of use as an indoor mosquito repellent.
［１］室内芳香剤（ゲルペース、その他）［２］枕、寝
具に香料を用い就寝中の蚊の吸血を防止する。[1] Indoor air fresheners (gelpace, etc.) [2] Use fragrances on pillows and bedding to prevent mosquitoes from sucking blood while sleeping.
（２）野外などでの携帯使用をする例
［１］ ニアリール、ヂイスベシサーによるスプレー型
態の製品［２］直接皮膚に塗布することによるクリーム
［３コ携帯使用が可能な線香水、匂い袋（３）香りを主
体とする機能商品としての使用例香水、オーデコロン、
化粧品等。(2) Examples of portable use outdoors [1] Spray-type products such as Near Reel and Diisvesicer [2] Creams that can be applied directly to the skin [3] Portable perfumes and scent bags (3) ) Usage examples of functional products with scent as the main ingredient: perfume, cologne,
Cosmetics etc.
次に各種配合例を示し、より詳細に発明を説明する。尚
、各実施例とも優れた蚊取り効果を示した。Next, various formulation examples will be shown and the invention will be explained in more detail. In addition, each of the examples showed excellent mosquito repelling effects.
大豊豆工 室内芳香剤
標準商業品種の蚊取り効果のある香料を重量濃度で５％
、１０％、２０％加えたフレグランス洋調合香料をトリ
ステアリン酸デカグリセリン５ｇエタノール３０％水溶
液８０ｇを混合加熱して形成きれる流動性のゲルペース
に２０％になるように溶解し、放冷して固化きせること
により、固型の室内芳香剤を調製する。Daiho Dou Kou Indoor air freshener Standard commercial grade fragrance with mosquito repellent effect at 5% weight concentration
, 10%, 20% fragrance Western blended fragrance is mixed and heated with 5 g of decaglycerin tristearate and 80 g of 30% ethanol aqueous solution to form a fluid gel paste. Dissolve it to a concentration of 20%, and leave to cool to solidify. A solid room air freshener is prepared by drying.
尚、調香のため他の各種香料を添加しても効果に特に影
響はない。Note that the addition of various other fragrances for perfume adjustment does not particularly affect the effect.
実施例２ 携帯用エアスプレー
シトロネラールを１５％含む香料
エチルアルコール９５％
スパン８５
ツイン８１
プロペラント
６
６
大凰五旦 線香水
を５：４の比で配合した組成物 ９０．０トリミ
リスチン酸グリセリン １０．０（製法）
各成分を混合撹拌して線香水を得た。Example 2 Portable Air Spray Composition containing 15% citronellal fragrance 95% ethyl alcohol Span 85 Twin 81 Propellant 6 6 Dao Wudan line perfume in a ratio of 5:4 90.0 trimyristic acid Glycerin 10.0 (manufacturing method) Each component was mixed and stirred to obtain a perfume string.
大ｌ五土 クリーム
シトラールを６０％以上含む香料
ミツロウ
セレシン
ワセリン
ラノリン
コスビオール
オリーブ油
ソルビタンモノオレエート
精製水
酸化防止剤
０
０
５
０
５
少量
】Ｌ亮」１浸−匂い袋
チルピネンを１５％含む調香料と流動パラフィンアルデ
ヒド Ｃ−８を１５％含む香料を１ｇ含浸させた綿塊を
麻製のサツシェにつめて匂い袋とする。Dail Goto Cream Fragrance containing 60% or more of citral Beeswax Ceresin Vaseline Lanolin Cosbiol Olive oil Sorbitan monooleate Purified hydroxide antioxidant 0 0 5 0 5 Small amount] L Ryo 1 Soak - Fragrance containing 15% of scent bag Chilpinene A cotton ball impregnated with 1 g of fragrance containing 15% of liquid paraffin aldehyde C-8 was packed into a hemp sachet to make a scent bag.
［発明の効果］
以上説明したように、本発明にかかる蚊取り効果のある
香料組成物によれば、常温での効果香料成分の揮発によ
り容易かつ安全に蚊に対する殺虫効果あるいは麻痺効果
を発現することが出来る。[Effects of the Invention] As explained above, according to the fragrance composition having a mosquito repelling effect according to the present invention, the insecticidal or paralyzing effect against mosquitoes can be easily and safely expressed by volatilization of the effective fragrance ingredients at room temperature. I can do it.
Claims (5)
ｃｍ＾３以上となるように存在させることを特徴とする
蚊取り効果のある香料組成物。(1) Airborne concentration of fragrance with mosquito repellent effect is 0.6μg/
A fragrance composition having a mosquito repelling effect, characterized in that the fragrance composition is present in an amount of cm^3 or more.
ラール、シトロネラールを含むテルペン系アルデヒドで
あることを特徴とする蚊取り効果のある香料組成物。(2) The fragrance composition according to claim 1, wherein the fragrance is a terpene aldehyde containing citral and citronellal.
ネン、チルピネンを含むテルペン系炭化水素であること
を特徴とする蚊取り効果のある香料組成物。(3) The fragrance composition according to claim 1, wherein the fragrance is a terpene hydrocarbon containing limonene and tilpinene.
デヒドＣ−８であることを特徴とする蚊取り効果のある
香料組成物。(4) The fragrance composition according to claim 1, wherein the fragrance is aldehyde C-8.
ニルアセトアルデヒドであることを特徴とする蚊取り効
果のある香料組成物。(5) The fragrance composition according to claim 1, wherein the fragrance is phenylacetaldehyde.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8644190A JPH03285993A (en) | 1990-03-31 | 1990-03-31 | Perfume composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8644190A JPH03285993A (en) | 1990-03-31 | 1990-03-31 | Perfume composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03285993A true JPH03285993A (en) | 1991-12-17 |
Family
ID=13887006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8644190A Pending JPH03285993A (en) | 1990-03-31 | 1990-03-31 | Perfume composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03285993A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1214879A3 (en) * | 2000-12-12 | 2002-11-13 | Takasago International Corporation | Antifungal fragrance composition |
| JP2003138290A (en) * | 2001-11-01 | 2003-05-14 | Takasago Internatl Corp | Perfume composition having mosquito repellent effect |
| JP2007502860A (en) * | 2003-04-24 | 2007-02-15 | ヴァンダービルト ユニバースィティ | Compositions and methods for controlling insects |
| US8865230B2 (en) | 2006-06-27 | 2014-10-21 | Tyratech, Inc. | Compositions and methods for treating parasitic infections |
| CN104414930A (en) * | 2013-09-09 | 2015-03-18 | 青岛锦涟鑫商贸有限公司 | Traditional Chinese medicine spray for expelling insects |
-
1990
- 1990-03-31 JP JP8644190A patent/JPH03285993A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1214879A3 (en) * | 2000-12-12 | 2002-11-13 | Takasago International Corporation | Antifungal fragrance composition |
| US6960350B2 (en) | 2000-12-12 | 2005-11-01 | Takasago International Corporation | Antifungal fragrance composition |
| JP2003138290A (en) * | 2001-11-01 | 2003-05-14 | Takasago Internatl Corp | Perfume composition having mosquito repellent effect |
| JP2007502860A (en) * | 2003-04-24 | 2007-02-15 | ヴァンダービルト ユニバースィティ | Compositions and methods for controlling insects |
| US8865230B2 (en) | 2006-06-27 | 2014-10-21 | Tyratech, Inc. | Compositions and methods for treating parasitic infections |
| CN104414930A (en) * | 2013-09-09 | 2015-03-18 | 青岛锦涟鑫商贸有限公司 | Traditional Chinese medicine spray for expelling insects |
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