WO2023095780A1 - Stinkbug repellent for plant application - Google Patents
Stinkbug repellent for plant application Download PDFInfo
- Publication number
- WO2023095780A1 WO2023095780A1 PCT/JP2022/043149 JP2022043149W WO2023095780A1 WO 2023095780 A1 WO2023095780 A1 WO 2023095780A1 JP 2022043149 W JP2022043149 W JP 2022043149W WO 2023095780 A1 WO2023095780 A1 WO 2023095780A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- repellent
- component
- present
- stink bug
- stink
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aldehyde or keto groups, or thio analogues thereof, directly attached to an aromatic ring system, e.g. acetophenone; Derivatives thereof, e.g. acetals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P17/00—Pest repellants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Definitions
- the present invention relates to a plant-applied stink bug repellent and a stink bug repelling method. More specifically, the present invention relates to a stink bug repellent agent for plant application and a stink bug repelling method that does not cause phytotoxicity to plants.
- Stinkbug insects include pests that suck fruit and shoots and damage agricultural and horticultural crops.
- Stink bugs are one of the hardest-to-control pests because young fruits that have been sucked are deformed or dropped, and in ripe fruits, that part rots and gives off an offensive odor. As one, it is subject to control.
- Stink bugs on the other hand, are also known to be unpleasant pests, known for their strong odors. This pheromone is the root of bad odors.
- the habitat of stink bugs has come closer to human dwellings, and the stink bugs have attracted attention as unpleasant pests due to their foul odor and physiological disgust caused by the stench. Since requests for control of stink bugs are increasing, various means for controlling stink bugs have been proposed.
- the purpose of the present invention is to provide a stink bug repellent for application to plants that does not cause phytotoxicity to plants such as agricultural and horticultural crops.
- the gist of the present invention is as follows. 1.
- a method for repelling stink bugs which comprises applying one or more components selected from the following component (A) as an active ingredient to a plant.
- the stink bug repellent agent for application to plants of the present invention is useful because it repels stink bugs when applied to plants such as agricultural and horticultural crops, and can reduce stink bug damage to agricultural and horticultural crops. Moreover, the stink bug repellent for application to plants of the present invention exhibits an excellent effect of causing no phytotoxicity to plants such as agricultural and horticultural crops.
- the stink bug in the present invention means an insect belonging to the suborder stink bug (heteroptera) of the order Hemiptera (order Hemiptera), and includes, for example, brown stink bug, Scott stink bug, Tsuya green stink bug, Kinek black stink bug (black stink bug), and quail stink bug.
- stink bugs white stink bug, spotted stink bug, blue stink bug, southern green stink bug, rice stink bug, rhinoceros stink bug, rice black stink bug stink bugs, bean bugs, stink bugs, and other stink bugs that belong to the family bean bugs
- stink bugs that belong to the family bean bugs such as bean stink bugs, stink bugs that belong to the family beetle bugs, such as red-headed stink bugs and spotted stink bugs
- Stink bugs such as stink bugs belonging to the family Mystic stink bug, such as , red-whiskered whisker, and stink bug, and stink bugs belonging to the family Mars stink bug, such as Marcus stink bug.
- the ingredient (A), which is an active ingredient in the stink bug repellent for application to plants of the present invention, will be described.
- Component (A)> The stink bug repellent for application to plants of the present invention contains one or more components selected from component (A) as active ingredients, and component (A) includes methionol, hexanoic acid, 4-hydroxybenzoic acid, Terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, ⁇ -amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2-(methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methyl It consists of pyrazine, ethyl vanillin and butyraldehyde.
- component (A) 4-hydroxybenzoic acid, geranyl tiglate, ethyl pentadecanoate, and 2-(methoxymethyl)pyrrolidine are compounds designated as food additives and are safe for humans.
- methylpyrazine has an excellent repellent effect against honeybees, in addition to its repellent effect against stink bugs and safety against plants such as agricultural and horticultural crops.
- hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, ⁇ -amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate and 2-ethyl-3-methylpyrazine One or more components selected from are preferable as the active component of the stink bug repellent for plant application of the present invention, from the viewpoint of being able to prevent honeybees, which are beneficial insects, from directly or indirectly coming into contact with agricultural chemicals.
- the active ingredients in the stink bug repellent for plant application of the present invention include not only the components belonging to the above (A), but also the compound group of the following components (B), (C), and (D) in the stink bug repellent of the present invention. It may be used as an active ingredient.
- the stink bug repellent for application to plants of the present invention may contain one or more components selected from component (B) as active ingredients.
- Component (B) is benzothiazole, ⁇ -ionone, 2-methyl-1-propanol, n-octanal, pyrrolidine, 2-acetylthiazole, butyl butyrate, 6-methylquinoline, ethyl decanoate, and methyl N-methylanthranilate.
- one or more components selected from benzothiazole, ⁇ -ionone, 2-methyl-1-propanol, n-octanal, 6-methylquinoline and methyl N-methylanthranilate are beneficial insects that honeybees From the viewpoint of being able to prevent direct or indirect contact with agricultural chemicals, it is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention.
- benzothiazole, 2-methyl-1-propanol, and n-octanal have not only a bee-repellent effect on the surface to which they are applied, but also a bee-repellent effect in the space above the surface to which they are applied (spatial repellent effect).
- one or more components selected from benzothiazole, 2-methyl-1-propanol and n-octanal from the viewpoint of reducing damage to honeybees due to application of insecticides is the stinkbug repellent for plant application of the present invention. It is more preferable as an active ingredient of the agent.
- one or more components selected from component (A) and one or more components selected from component (B) may be used in combination.
- the stink bug repellent for application to plants of the present invention may contain one or more components selected from component (C) as active ingredients.
- Component (C) consists of isobutyl phenylacetate, 5-methylquinoxaline, 2-naphthalene thiol, 3-methyl-1-butanol and 4-quinolinecarboxylic acid.
- isobutyl phenylacetate, 5-methylquinoxaline, and 2-naphthalenethiol are excellent in their repelling effect against honeybees, in addition to their repelling effect against stink bugs and safety against plants such as agricultural and horticultural crops. is confirmed separately.
- one or more components selected from isobutyl phenylacetate, 5-methylquinoxaline and 2-naphthalenethiol are useful insects from the viewpoint of preventing direct or indirect contact with agricultural chemicals. It is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention.
- one or more components selected from component (A) and one or more components selected from component (C) may be used in combination. Also, one or more components selected from component (B) and one or more components selected from component (C) may be used in combination.
- Component (D) The stink bug repellent for application to plants of the present invention may contain one or more components selected from component (D) as an active ingredient.
- Component (D) is anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, menthyl acetate, trans-2-methyl-2-butenal, anise alcohol, It is composed of 2,3-diethylpyrazine.
- Anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4'-methylacetophenone, benzyl acetate, and menthyl acetate among component (D) have a repelling effect on stink bugs and plants such as agricultural and horticultural crops. In addition to its safety against bees, it has been confirmed separately that it is also excellent in its repellent effect against honeybees.
- one or more components selected from anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, and menthyl acetate are beneficial insects that honeybees From the viewpoint of being able to prevent direct or indirect contact with agricultural chemicals, it is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention. Furthermore, among these, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, and benzyl acetate not only have a bee-repellent effect on the application surface, but also have a high bee-repellent effect (spatial repellent effect) in the upper space of the application surface.
- one or more components selected from component (A) and one or more components selected from component (D) may be used in combination. Further, one or more components selected from the component (B) and one or more components selected from the component (D) may be used in combination, or one component selected from the component (C) You may use together the above component and the 1 or more types of component selected from the said component (D). Since the components belonging to the above components (A), (B), (C) and (D) also have a honeybee repellent effect, if the stink bug repellent for plant application of the present invention contains a plant disease control component etc. Even when an agricultural chemical is used in combination, it is possible to prevent honeybees, which are beneficial insects, from coming close to the applied plant and prevent the honeybee from coming into direct or indirect contact with the agricultural chemical.
- the stink bug repellent for application to plants of the present invention in addition to the active ingredient, it is formulated with ingredients that are generally added to formulations as necessary, and the formulation is diluted with water. included. Among them, formulated solid preparations and liquid preparations are compact and excellent in storage stability, and are therefore advantageous and suitable for transportation and storage. Among them, the stink bug repellent for application to plants of the present invention is preferably used in a liquid form. Therefore, when diluted with water, a liquid formulation is preferable because it is easy to dilute with water and leaves little undissolved residue.
- the content of the active ingredient in the stink bug repellent for plant application of the present invention is preferably 0.001 w/v% or more, and preferably 0.01 w/v% or more, based on the total amount of the drug at the time of use. is more preferable, and more preferably 0.1 w/v% or more. If the content of this active ingredient is less than 0.001 w/v%, the repellent effect may not be sufficiently exhibited. Moreover, if the content exceeds 10 w/v%, there is a possibility that plants such as agricultural and horticultural crops will suffer from phytotoxicity, so the content is preferably 10 w/v% or less.
- a surfactant can be blended in formulating the stink bug repellent for application to plants of the present invention.
- any of nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants can be used without particular limitation.
- Activators or anionic surfactants are preferred.
- nonionic surfactants include sugar ester type, fatty acid ester type, vegetable oil type, alcohol type, alkylphenol type, polyoxyethylene-polyoxypropylene block polymer type, alkylamine type, and bisphenol type surfactants. , polycyclic aromatic types.
- anionic surfactants include carboxylic acid type, sulfonic acid type, sulfate type, and phosphate type surfactants.
- cationic surfactants include ammonium-type and benzalkonium-type surfactants.
- Amphoteric surfactants include those of the betaine type. These surfactants can be used either singly or in combination of two or more.
- a liquid carrier can be blended in formulating the stink bug repellent for application to plants of the present invention.
- the liquid carrier is not particularly limited as long as the effect of the present invention is exhibited, and various known liquids different from the active ingredient of the present invention can be used as the carrier.
- purified water, tap water, ion-exchanged water, distilled water, filtered water, sterilized water, ground water, well water, and the like are used.
- auxiliary components that are generally added to formulations can be blended.
- auxiliary ingredients that are generally added to formulations include stabilizers, preservatives, colorants, and agents for preventing accidental ingestion and accidental ingestion.
- stabilizers include antioxidants such as dibutylhydroxytoluene (BHT) and butylhydroxyanisole (BHA), ascorbic acid, and the like.
- preservatives include sorbic acid, sorbates, parahydroxybenzoic acid esters, thiabendazole, sodium chloride and the like.
- coloring agents include caramel pigments, gardenia pigments, anthocyanin pigments, safflower pigments, flavonoid pigments, red No. 2, red No. 3, yellow No. 4 and yellow No. 5.
- accidental ingestion/eating prevention agents include denatonium benzoate and the like.
- the plant-applied stink bug repellent of the present invention can be used in combination with agricultural chemicals applied to agricultural and horticultural crops such as gardening for the purpose of controlling pests and diseases other than stink bugs within a range that does not impair the effects of the present invention.
- Pesticides that can be used in combination with the stink bug repellent for plant application of the present invention are not particularly limited, and known compounds include, for example, neonicotinoid pesticides such as acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, allethrin, Pyrethroid pesticides such as resmethrin, d-phenothrin, tetramethrin, cypermethrin, deltamethrin, fenvalerate, permethrin, and etofenprox; phenylpyrazole pesticides such as ethiprole and fipronil; , acephate, isoxathion, phoxime and other insecticides and acaricides; pyrazole agrochemicals such as penthiopyrad and other fungicides; and organophosphorus agrochemical
- the plant to which the stink bug repellent for plant application of the present invention is applied is not particularly limited, and is generally cultivated as an agricultural or horticultural crop or grown in gardening, such as grains, beans, fruit trees and fruits, Examples include vegetables, root crops, processed crops, melons, pasture grasses, grasses, aromatic crops, and flowers.
- ⁇ Stink bug repellent effect confirmation test 1> In order to confirm that the stink bug repellent for plant application of the present invention exhibits a repelling effect against stink bugs, the following tests were conducted.
- component (A) methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, ⁇ -amylcinnamaldehyde, tigrin geranyl acid, ethyl pentadecanoate, isoeugenol, 2-(methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethyl vanillin, butyraldehyde, and benzothiazole, ⁇ -ionone, 2-methyl-1-propanol, n-octanal, pyrrolidine, 2-acetylthiazole, but
- Test insects As test insects, two southern green stink bugs were used in each test. (3) Test method A calcium carbonate/ethanol dispersion was applied to the entire inner wall of a KP cup (diameter 100 mm x height 90 mm) and air-dried. fixed with . 400 ⁇ L of each test sample or correction sample is uniformly treated on a half-moon shape obtained by cutting the diameter portion of another filter paper (diameter 90 mm), and a circular portion is placed on the filter paper fixed to the bottom surface of the KP cup. were placed so that they overlapped to form a test device. Two test insects (Southern stink bug) were released into the above test device, and their behavior was observed for 30 minutes (1800 seconds).
- the average time A (seconds) and the average time B (seconds) during which the test worms stayed on the filter paper not treated with the test sample or correction sample were measured. From the above “time A (seconds)” and “time B (seconds)", the "repellent rate Y" and the “corrected repellent rate Z" were calculated by the following formulas. The repelling rate of the correction sample was used as the "correction sample repelling rate” used when calculating the "corrected repelling rate Z".
- the component (A) which is the active ingredient in the stink bug repellent for plant application of the present invention, exerts an excellent repellent effect against stink bugs and is one of the plants that are likely to develop phytotoxicity. It was clarified that no phytotoxicity was caused to a certain rice plant.
- the component (B) which can be an active ingredient, also exerts a good repellent effect against stink bugs and does not cause any phytotoxicity to rice.
- Ingredient (C) which can be an active ingredient of the stink bug repellent for plant application, exhibits a good repellent effect against stink bugs, and although phytotoxicity to rice is recognized, it was found that there is no practical problem.
- the component (A), components (B), and (C), which are active ingredients, in the stink bug repellent for plant application of the present invention effectively repel stink bugs by applying them to plants such as agricultural and horticultural crops. It was confirmed by the above-mentioned test that the phytotoxicity to plants such as agricultural and horticultural crops is more effective than the practical level.
- the component (D), which can be an active ingredient was also subjected to a similar test. Although phytotoxicity was observed, it was confirmed separately that there was no practical problem.
- ⁇ Phytotoxicity confirmation test 2> (1) Preparation of test specimen 2.0 parts by weight of methiol, 3.3 parts by weight of Trebonair (10% by weight of etofenprox, the balance being water and surfactant), and water so that the total volume is 100 mL I used a mixture. (2) Test method Tests and evaluations were performed in the same manner as in the above "phytotoxicity confirmation test 1". (3) Results Methionol, which is one of the active ingredients of the stink bug repellent for plant application of the present invention, did not cause any phytotoxicity to plants even at a high concentration of 2.0 w/v%.
- anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4'-methylacetophenone, benzyl acetate, menthyl acetate, trans-2 which are component (D) in the present invention, -Methyl-2-butenal, anis alcohol, 2,3-diethylpyrazine 1.0 parts by weight, Trebon air (10% by weight of etofenprox, balance being water and surfactant) 3.3 parts by weight and the total amount
- a confirmatory test was carried out in the same manner as in the above "phytotoxicity confirmatory test 1" except that water was used so that the volume of the extract was 100 mL.
- the corrected stink bug repelling rate Z (%) was calculated in the same manner as in “Stink Bug Repellent Effect Confirmation Test 1", and phytotoxicity was evaluated based on the same evaluation criteria as in "Phytotoxicity Confirmation Test 1".
- the corrected repellency rate Z (%) of stink bugs and the evaluation results of phytotoxicity are summarized in Table 2 below.
- the stink bug repellent for plant application of the present invention repels stink bugs by applying it to plants such as agricultural and horticultural crops. It is useful for the cultivation of agricultural and horticultural crops because it exhibits both the excellent effect of not causing phytotoxicity to.
- the components belonging to component (A), component (B), component (C) and component (D) in the present invention also have a honeybee repellent effect, if stink bug repellent for plant application of the present invention does not cause plant disease Even when a pesticide such as a control component is used in combination, it is possible to prevent honeybees, which are beneficial insects, from coming close to the applied plant and prevent the bee from coming into direct or indirect contact with the pesticide.
Abstract
The present invention addresses the problem of providing a stinkbug repellent for plant application, with which there is no concern about chemical damage to plants such as agricultural and horticultural crops. To solve this problem, the present invention provides a stinkbug repellent for plant application in which one or more components selected from the following components (A) are used as active components. Components (A): Methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2-(methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethylvanillin, and butyraldehyde.
Description
本発明は、植物施用用カメムシ忌避剤及びカメムシ忌避方法に関する。詳しくは、植物に対する薬害の無い植物施用用カメムシ忌避剤及びカメムシ忌避方法に関する。
The present invention relates to a plant-applied stink bug repellent and a stink bug repelling method. More specifically, the present invention relates to a stink bug repellent agent for plant application and a stink bug repelling method that does not cause phytotoxicity to plants.
カメムシ目昆虫の中には、果実や新芽を吸汁し農園芸作物に被害を与える害虫が含まれている。吸汁された若い果実は、その部分が変形又は落果するほか、熟した果実ではその部分が腐敗し異臭がするなど、農園芸作物の品質を著しく低下させてしまうため、カメムシは難防除害虫の１つとして、防除対象とされている。
一方、カメムシは、強烈な臭いを出すことで知られる不快害虫でもあり、危険を感知すると、敵の撃退や仲間に危険を知らせるために、アルデヒド系の警報フェロモンを放出する。このフェロモンが悪臭の根源である。
近年、カメムシの生息域と人間の住居とが接近するようになり、悪臭や、その悪臭故の生理的嫌悪感などから不快害虫としても注目されるようになった。そして、その防除要請は増加傾向にあることから、カメムシを防除するための手段が各種提案されている。例えば、シラフルオフェンとピレスロイド系殺虫剤とを含有した液剤もしくはエアゾール剤を用いてカメムシの家屋内への侵入を阻止する方法（例えば、特許文献１等）等が提案されている。
しかしながら、これらの化学農薬は施用方法によっては、対象作物に対して薬害を与える場合もあり、ガーデニングなどではその利用をためらう使用者も多い。 Stinkbug insects include pests that suck fruit and shoots and damage agricultural and horticultural crops. Stink bugs are one of the hardest-to-control pests because young fruits that have been sucked are deformed or dropped, and in ripe fruits, that part rots and gives off an offensive odor. As one, it is subject to control.
Stink bugs, on the other hand, are also known to be unpleasant pests, known for their strong odors. This pheromone is the root of bad odors.
In recent years, the habitat of stink bugs has come closer to human dwellings, and the stink bugs have attracted attention as unpleasant pests due to their foul odor and physiological disgust caused by the stench. Since requests for control of stink bugs are increasing, various means for controlling stink bugs have been proposed. For example, a method has been proposed for preventing stink bugs from entering a house using a solution or aerosol containing silafluofen and a pyrethroid insecticide (for example, Patent Document 1, etc.).
However, depending on the method of application, these chemical pesticides may cause phytotoxicity to target crops, and many users hesitate to use them in gardening and the like.
一方、カメムシは、強烈な臭いを出すことで知られる不快害虫でもあり、危険を感知すると、敵の撃退や仲間に危険を知らせるために、アルデヒド系の警報フェロモンを放出する。このフェロモンが悪臭の根源である。
近年、カメムシの生息域と人間の住居とが接近するようになり、悪臭や、その悪臭故の生理的嫌悪感などから不快害虫としても注目されるようになった。そして、その防除要請は増加傾向にあることから、カメムシを防除するための手段が各種提案されている。例えば、シラフルオフェンとピレスロイド系殺虫剤とを含有した液剤もしくはエアゾール剤を用いてカメムシの家屋内への侵入を阻止する方法（例えば、特許文献１等）等が提案されている。
しかしながら、これらの化学農薬は施用方法によっては、対象作物に対して薬害を与える場合もあり、ガーデニングなどではその利用をためらう使用者も多い。 Stinkbug insects include pests that suck fruit and shoots and damage agricultural and horticultural crops. Stink bugs are one of the hardest-to-control pests because young fruits that have been sucked are deformed or dropped, and in ripe fruits, that part rots and gives off an offensive odor. As one, it is subject to control.
Stink bugs, on the other hand, are also known to be unpleasant pests, known for their strong odors. This pheromone is the root of bad odors.
In recent years, the habitat of stink bugs has come closer to human dwellings, and the stink bugs have attracted attention as unpleasant pests due to their foul odor and physiological disgust caused by the stench. Since requests for control of stink bugs are increasing, various means for controlling stink bugs have been proposed. For example, a method has been proposed for preventing stink bugs from entering a house using a solution or aerosol containing silafluofen and a pyrethroid insecticide (for example, Patent Document 1, etc.).
However, depending on the method of application, these chemical pesticides may cause phytotoxicity to target crops, and many users hesitate to use them in gardening and the like.
本発明は、農園芸作物など植物に対する薬害の心配がない、植物施用用カメムシ忌避剤の提供を目的としている。
The purpose of the present invention is to provide a stink bug repellent for application to plants that does not cause phytotoxicity to plants such as agricultural and horticultural crops.
本発明者は、上記課題を解決するために鋭意研究を重ねた結果、特定の成分が特異的にカメムシを忌避し、かつ、農園芸作物など植物に対する薬害がないことを見出し、上記課題を解決するに至ったものである。
As a result of intensive research to solve the above problems, the present inventors found that a specific component specifically repels stink bugs and does not cause phytotoxicity to plants such as agricultural and horticultural crops, thereby solving the above problems. It has come to be.
本発明は、具体的には次の事項を要旨とする。
１．下記成分（Ａ）から選択される１種以上の成分を有効成分とする、植物施用用カメムシ忌避剤。
成分（Ａ）：メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒド
２．下記成分（Ａ）から選択される１種以上の成分を有効成分として、植物に施用することを特徴とするカメムシ忌避方法。
成分（Ａ）：メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒド Specifically, the gist of the present invention is as follows.
1. A stinkbug repellent for application to plants, containing as an active ingredient one or more ingredients selected from the following ingredients (A).
Component (A): Methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2- (Methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethylvanillin and butyraldehyde2. A method for repelling stink bugs, which comprises applying one or more components selected from the following component (A) as an active ingredient to a plant.
Component (A): Methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2- (Methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethylvanillin and butyraldehyde
１．下記成分（Ａ）から選択される１種以上の成分を有効成分とする、植物施用用カメムシ忌避剤。
成分（Ａ）：メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒド
２．下記成分（Ａ）から選択される１種以上の成分を有効成分として、植物に施用することを特徴とするカメムシ忌避方法。
成分（Ａ）：メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒド Specifically, the gist of the present invention is as follows.
1. A stinkbug repellent for application to plants, containing as an active ingredient one or more ingredients selected from the following ingredients (A).
Component (A): Methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2- (Methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethylvanillin and butyraldehyde2. A method for repelling stink bugs, which comprises applying one or more components selected from the following component (A) as an active ingredient to a plant.
Component (A): Methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2- (Methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethylvanillin and butyraldehyde
本発明の植物施用用カメムシ忌避剤は、農園芸作物などの植物に施用することによりカメムシを忌避するため、農園芸作物に対するカメムシ被害を低減することが出来、有用である。
しかも、本発明の植物施用用カメムシ忌避剤は、農園芸作物などの植物に対する薬害がないという優れた効果を発揮するものである。 The stink bug repellent agent for application to plants of the present invention is useful because it repels stink bugs when applied to plants such as agricultural and horticultural crops, and can reduce stink bug damage to agricultural and horticultural crops.
Moreover, the stink bug repellent for application to plants of the present invention exhibits an excellent effect of causing no phytotoxicity to plants such as agricultural and horticultural crops.
しかも、本発明の植物施用用カメムシ忌避剤は、農園芸作物などの植物に対する薬害がないという優れた効果を発揮するものである。 The stink bug repellent agent for application to plants of the present invention is useful because it repels stink bugs when applied to plants such as agricultural and horticultural crops, and can reduce stink bug damage to agricultural and horticultural crops.
Moreover, the stink bug repellent for application to plants of the present invention exhibits an excellent effect of causing no phytotoxicity to plants such as agricultural and horticultural crops.
以下、本発明の植物施用用カメムシ忌避剤について詳細に説明する。
＜カメムシ＞
本発明におけるカメムシとしては、カメムシ目（半翅目）のカメムシ亜目（異翅亜目）に属する昆虫を意味し、例えば、クサギカメムシ、スコットカメムシ、ツヤアオカメムシ、カイネクロカメムシ（クロカメムシ）、ウズラカメムシ、トゲシラホシカメムシ、シラホシカメムシ、ブチヒゲカメムシ、アオクサカメムシ、ミナミアオカメムシ、イネカメムシ、オオトゲシラホシカメムシ、イネクロカメムシなどのカメムシ科に属するカメムシ、ヒメナガカメムシ、コバネヒョウタンナガカメムシなどのナガカメムシ科に属するカメムシ、ホソヘリカメムシ、クモヘリカメムシなどのホソヘリカメムシ科に属するカメムシ、ホソハリカメムシなどのヘリカメムシ科に属するカメムシ、アカヒメヘリカメムシ、ブチヒゲヘリカメムシなどのヒメヘリカメムシ科に属するカメムシ、アカヒゲホソミドリカスミカメ、アカスジカスミカメなどのカスミカメムシ科に属するカメムシ、マルカメムシなどのマルカメムシ科に属するカメムシなどのカメムシが挙げられる。 Hereinafter, the stink bug repellent for application to plants of the present invention will be described in detail.
<Stink Bug>
The stink bug in the present invention means an insect belonging to the suborder stink bug (heteroptera) of the order Hemiptera (order Hemiptera), and includes, for example, brown stink bug, Scott stink bug, Tsuya green stink bug, Kinek black stink bug (black stink bug), and quail stink bug. , stink bug, white stink bug, spotted stink bug, blue stink bug, southern green stink bug, rice stink bug, rhinoceros stink bug, rice black stink bug stink bugs, bean bugs, stink bugs, and other stink bugs that belong to the family bean bugs, stink bugs that belong to the family bean bugs, such as bean stink bugs, stink bugs that belong to the family beetle bugs, such as red-headed stink bugs and spotted stink bugs Stink bugs such as stink bugs belonging to the family Mystic stink bug, such as , red-whiskered whisker, and stink bug, and stink bugs belonging to the family Mars stink bug, such as Marcus stink bug.
＜カメムシ＞
本発明におけるカメムシとしては、カメムシ目（半翅目）のカメムシ亜目（異翅亜目）に属する昆虫を意味し、例えば、クサギカメムシ、スコットカメムシ、ツヤアオカメムシ、カイネクロカメムシ（クロカメムシ）、ウズラカメムシ、トゲシラホシカメムシ、シラホシカメムシ、ブチヒゲカメムシ、アオクサカメムシ、ミナミアオカメムシ、イネカメムシ、オオトゲシラホシカメムシ、イネクロカメムシなどのカメムシ科に属するカメムシ、ヒメナガカメムシ、コバネヒョウタンナガカメムシなどのナガカメムシ科に属するカメムシ、ホソヘリカメムシ、クモヘリカメムシなどのホソヘリカメムシ科に属するカメムシ、ホソハリカメムシなどのヘリカメムシ科に属するカメムシ、アカヒメヘリカメムシ、ブチヒゲヘリカメムシなどのヒメヘリカメムシ科に属するカメムシ、アカヒゲホソミドリカスミカメ、アカスジカスミカメなどのカスミカメムシ科に属するカメムシ、マルカメムシなどのマルカメムシ科に属するカメムシなどのカメムシが挙げられる。 Hereinafter, the stink bug repellent for application to plants of the present invention will be described in detail.
<Stink Bug>
The stink bug in the present invention means an insect belonging to the suborder stink bug (heteroptera) of the order Hemiptera (order Hemiptera), and includes, for example, brown stink bug, Scott stink bug, Tsuya green stink bug, Kinek black stink bug (black stink bug), and quail stink bug. , stink bug, white stink bug, spotted stink bug, blue stink bug, southern green stink bug, rice stink bug, rhinoceros stink bug, rice black stink bug stink bugs, bean bugs, stink bugs, and other stink bugs that belong to the family bean bugs, stink bugs that belong to the family bean bugs, such as bean stink bugs, stink bugs that belong to the family beetle bugs, such as red-headed stink bugs and spotted stink bugs Stink bugs such as stink bugs belonging to the family Mystic stink bug, such as , red-whiskered whisker, and stink bug, and stink bugs belonging to the family Mars stink bug, such as Marcus stink bug.
本発明の植物施用用カメムシ忌避剤における、有効成分である成分（Ａ）について説明する。
＜成分（Ａ）＞
本発明の植物施用用カメムシ忌避剤は、成分（Ａ）から選択される１種以上の成分を有効成分とするものであり、成分（Ａ）は、メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒドから構成されるものである。成分（Ａ）に含まれる成分のうち、４－ヒドロキシ安息香酸、チグリン酸ゲラニル、ペンタデカン酸エチル、２－（メトキシメチル）ピロリジン以外は、食品添加物として指定された化合物であり、人に対する安全性が高い成分である。
成分（Ａ）のうち、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、２－エチル－３－メチルピラジンは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル及び２－エチル－３－メチルピラジンから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。 The ingredient (A), which is an active ingredient in the stink bug repellent for application to plants of the present invention, will be described.
<Component (A)>
The stink bug repellent for application to plants of the present invention contains one or more components selected from component (A) as active ingredients, and component (A) includes methionol, hexanoic acid, 4-hydroxybenzoic acid, Terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2-(methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methyl It consists of pyrazine, ethyl vanillin and butyraldehyde. Among the components contained in component (A), 4-hydroxybenzoic acid, geranyl tiglate, ethyl pentadecanoate, and 2-(methoxymethyl)pyrrolidine are compounds designated as food additives and are safe for humans. is a component with high
Among components (A), hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, 2-ethyl-3 - It has been separately confirmed that methylpyrazine has an excellent repellent effect against honeybees, in addition to its repellent effect against stink bugs and safety against plants such as agricultural and horticultural crops. In the present invention, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate and 2-ethyl-3-methylpyrazine One or more components selected from are preferable as the active component of the stink bug repellent for plant application of the present invention, from the viewpoint of being able to prevent honeybees, which are beneficial insects, from directly or indirectly coming into contact with agricultural chemicals.
＜成分（Ａ）＞
本発明の植物施用用カメムシ忌避剤は、成分（Ａ）から選択される１種以上の成分を有効成分とするものであり、成分（Ａ）は、メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒドから構成されるものである。成分（Ａ）に含まれる成分のうち、４－ヒドロキシ安息香酸、チグリン酸ゲラニル、ペンタデカン酸エチル、２－（メトキシメチル）ピロリジン以外は、食品添加物として指定された化合物であり、人に対する安全性が高い成分である。
成分（Ａ）のうち、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、２－エチル－３－メチルピラジンは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル及び２－エチル－３－メチルピラジンから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。 The ingredient (A), which is an active ingredient in the stink bug repellent for application to plants of the present invention, will be described.
<Component (A)>
The stink bug repellent for application to plants of the present invention contains one or more components selected from component (A) as active ingredients, and component (A) includes methionol, hexanoic acid, 4-hydroxybenzoic acid, Terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2-(methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methyl It consists of pyrazine, ethyl vanillin and butyraldehyde. Among the components contained in component (A), 4-hydroxybenzoic acid, geranyl tiglate, ethyl pentadecanoate, and 2-(methoxymethyl)pyrrolidine are compounds designated as food additives and are safe for humans. is a component with high
Among components (A), hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, 2-ethyl-3 - It has been separately confirmed that methylpyrazine has an excellent repellent effect against honeybees, in addition to its repellent effect against stink bugs and safety against plants such as agricultural and horticultural crops. In the present invention, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate and 2-ethyl-3-methylpyrazine One or more components selected from are preferable as the active component of the stink bug repellent for plant application of the present invention, from the viewpoint of being able to prevent honeybees, which are beneficial insects, from directly or indirectly coming into contact with agricultural chemicals.
本発明の植物施用用カメムシ忌避剤における有効成分は、上記（Ａ）に属する成分のみならず、下記成分（Ｂ）、（Ｃ）、（Ｄ）の化合物群も、本発明のカメムシ忌避剤における有効成分としても良い。
＜成分（Ｂ）＞
本発明の植物施用用カメムシ忌避剤は、成分（Ｂ）から選択される１種以上の成分を有効成分とするものであっても良い。成分（Ｂ）は、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、ピロリジン、２－アセチルチアゾール、酪酸ブチル、６－メチルキノリン、デカン酸エチル、Ｎ－メチルアントラニル酸メチル、ｎ－オクタン酸ブチル、２－メチルピラジン、こはく酸（－）－メンチルから構成されるものである。
成分（Ｂ）のうち、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、６－メチルキノリン、Ｎ－メチルアントラニル酸メチルは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、６－メチルキノリン及びＮ－メチルアントラニル酸メチルから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。さらにこの中でも、ベンゾチアゾール、２－メチル－１－プロパノール、ｎ－オクタナールは、施用面に対するミツバチの忌避効果はもとより、施用面の上部空間におけるミツバチの忌避効果（空間忌避効果）が高いことが別途確認されており、殺虫剤施用によるミツバチの被害を低減する観点からベンゾチアゾール、２－メチル－１－プロパノール及びｎ－オクタナールから選択される１種以上の成分が、本発明の植物施用用カメムシ忌避剤の有効成分としてさらに好ましい。
本発明の植物施用用カメムシ忌避剤は、成分（Ａ）から選択される１種以上の成分と、上記成分（Ｂ）から選択される１種以上の成分とを併用しても良い。 The active ingredients in the stink bug repellent for plant application of the present invention include not only the components belonging to the above (A), but also the compound group of the following components (B), (C), and (D) in the stink bug repellent of the present invention. It may be used as an active ingredient.
<Component (B)>
The stink bug repellent for application to plants of the present invention may contain one or more components selected from component (B) as active ingredients. Component (B) is benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, pyrrolidine, 2-acetylthiazole, butyl butyrate, 6-methylquinoline, ethyl decanoate, and methyl N-methylanthranilate. , n-butyl octanoate, 2-methylpyrazine, and (-)-menthyl succinate.
Among the components (B), benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, 6-methylquinoline, and methyl N-methylanthranilate are effective in repelling stink bugs and in agricultural and horticultural crops. It has been separately confirmed that in addition to being safe for plants, it also has an excellent bee repellent effect. In the present invention, one or more components selected from benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, 6-methylquinoline and methyl N-methylanthranilate are beneficial insects that honeybees From the viewpoint of being able to prevent direct or indirect contact with agricultural chemicals, it is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention. Furthermore, among these, benzothiazole, 2-methyl-1-propanol, and n-octanal have not only a bee-repellent effect on the surface to which they are applied, but also a bee-repellent effect in the space above the surface to which they are applied (spatial repellent effect). It has been confirmed that one or more components selected from benzothiazole, 2-methyl-1-propanol and n-octanal from the viewpoint of reducing damage to honeybees due to application of insecticides is the stinkbug repellent for plant application of the present invention. It is more preferable as an active ingredient of the agent.
In the stink bug repellent for application to plants of the present invention, one or more components selected from component (A) and one or more components selected from component (B) may be used in combination.
＜成分（Ｂ）＞
本発明の植物施用用カメムシ忌避剤は、成分（Ｂ）から選択される１種以上の成分を有効成分とするものであっても良い。成分（Ｂ）は、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、ピロリジン、２－アセチルチアゾール、酪酸ブチル、６－メチルキノリン、デカン酸エチル、Ｎ－メチルアントラニル酸メチル、ｎ－オクタン酸ブチル、２－メチルピラジン、こはく酸（－）－メンチルから構成されるものである。
成分（Ｂ）のうち、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、６－メチルキノリン、Ｎ－メチルアントラニル酸メチルは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、６－メチルキノリン及びＮ－メチルアントラニル酸メチルから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。さらにこの中でも、ベンゾチアゾール、２－メチル－１－プロパノール、ｎ－オクタナールは、施用面に対するミツバチの忌避効果はもとより、施用面の上部空間におけるミツバチの忌避効果（空間忌避効果）が高いことが別途確認されており、殺虫剤施用によるミツバチの被害を低減する観点からベンゾチアゾール、２－メチル－１－プロパノール及びｎ－オクタナールから選択される１種以上の成分が、本発明の植物施用用カメムシ忌避剤の有効成分としてさらに好ましい。
本発明の植物施用用カメムシ忌避剤は、成分（Ａ）から選択される１種以上の成分と、上記成分（Ｂ）から選択される１種以上の成分とを併用しても良い。 The active ingredients in the stink bug repellent for plant application of the present invention include not only the components belonging to the above (A), but also the compound group of the following components (B), (C), and (D) in the stink bug repellent of the present invention. It may be used as an active ingredient.
<Component (B)>
The stink bug repellent for application to plants of the present invention may contain one or more components selected from component (B) as active ingredients. Component (B) is benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, pyrrolidine, 2-acetylthiazole, butyl butyrate, 6-methylquinoline, ethyl decanoate, and methyl N-methylanthranilate. , n-butyl octanoate, 2-methylpyrazine, and (-)-menthyl succinate.
Among the components (B), benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, 6-methylquinoline, and methyl N-methylanthranilate are effective in repelling stink bugs and in agricultural and horticultural crops. It has been separately confirmed that in addition to being safe for plants, it also has an excellent bee repellent effect. In the present invention, one or more components selected from benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, 6-methylquinoline and methyl N-methylanthranilate are beneficial insects that honeybees From the viewpoint of being able to prevent direct or indirect contact with agricultural chemicals, it is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention. Furthermore, among these, benzothiazole, 2-methyl-1-propanol, and n-octanal have not only a bee-repellent effect on the surface to which they are applied, but also a bee-repellent effect in the space above the surface to which they are applied (spatial repellent effect). It has been confirmed that one or more components selected from benzothiazole, 2-methyl-1-propanol and n-octanal from the viewpoint of reducing damage to honeybees due to application of insecticides is the stinkbug repellent for plant application of the present invention. It is more preferable as an active ingredient of the agent.
In the stink bug repellent for application to plants of the present invention, one or more components selected from component (A) and one or more components selected from component (B) may be used in combination.
＜成分（Ｃ）＞
本発明の植物施用用カメムシ忌避剤は、成分（Ｃ）から選択される１種以上の成分を有効成分とするものであっても良い。成分（Ｃ）は、フェニル酢酸イソブチル、５－メチルキノキサリン、２－ナフタレンチオール、３－メチル－１－ブタノール、４－キノリンカルボン酸から構成されるものである。
成分（Ｃ）のうちフェニル酢酸イソブチル、５－メチルキノキサリン、２－ナフタレンチオールは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、フェニル酢酸イソブチル、５－メチルキノキサリン及び２－ナフタレンチオールから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。
本発明の植物施用用カメムシ忌避剤は、成分（Ａ）から選択される１種以上の成分と、上記成分（Ｃ）から選択される１種以上の成分を併用しても良い。また、成分（Ｂ）から選択される１種以上の成分と、上記成分（Ｃ）から選択される１種以上の成分とを併用しても良い。 <Component (C)>
The stink bug repellent for application to plants of the present invention may contain one or more components selected from component (C) as active ingredients. Component (C) consists of isobutyl phenylacetate, 5-methylquinoxaline, 2-naphthalene thiol, 3-methyl-1-butanol and 4-quinolinecarboxylic acid.
Of the components (C), isobutyl phenylacetate, 5-methylquinoxaline, and 2-naphthalenethiol are excellent in their repelling effect against honeybees, in addition to their repelling effect against stink bugs and safety against plants such as agricultural and horticultural crops. is confirmed separately. In the present invention, one or more components selected from isobutyl phenylacetate, 5-methylquinoxaline and 2-naphthalenethiol are useful insects from the viewpoint of preventing direct or indirect contact with agricultural chemicals. It is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention.
In the stink bug repellent for application to plants of the present invention, one or more components selected from component (A) and one or more components selected from component (C) may be used in combination. Also, one or more components selected from component (B) and one or more components selected from component (C) may be used in combination.
本発明の植物施用用カメムシ忌避剤は、成分（Ｃ）から選択される１種以上の成分を有効成分とするものであっても良い。成分（Ｃ）は、フェニル酢酸イソブチル、５－メチルキノキサリン、２－ナフタレンチオール、３－メチル－１－ブタノール、４－キノリンカルボン酸から構成されるものである。
成分（Ｃ）のうちフェニル酢酸イソブチル、５－メチルキノキサリン、２－ナフタレンチオールは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、フェニル酢酸イソブチル、５－メチルキノキサリン及び２－ナフタレンチオールから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。
本発明の植物施用用カメムシ忌避剤は、成分（Ａ）から選択される１種以上の成分と、上記成分（Ｃ）から選択される１種以上の成分を併用しても良い。また、成分（Ｂ）から選択される１種以上の成分と、上記成分（Ｃ）から選択される１種以上の成分とを併用しても良い。 <Component (C)>
The stink bug repellent for application to plants of the present invention may contain one or more components selected from component (C) as active ingredients. Component (C) consists of isobutyl phenylacetate, 5-methylquinoxaline, 2-naphthalene thiol, 3-methyl-1-butanol and 4-quinolinecarboxylic acid.
Of the components (C), isobutyl phenylacetate, 5-methylquinoxaline, and 2-naphthalenethiol are excellent in their repelling effect against honeybees, in addition to their repelling effect against stink bugs and safety against plants such as agricultural and horticultural crops. is confirmed separately. In the present invention, one or more components selected from isobutyl phenylacetate, 5-methylquinoxaline and 2-naphthalenethiol are useful insects from the viewpoint of preventing direct or indirect contact with agricultural chemicals. It is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention.
In the stink bug repellent for application to plants of the present invention, one or more components selected from component (A) and one or more components selected from component (C) may be used in combination. Also, one or more components selected from component (B) and one or more components selected from component (C) may be used in combination.
＜成分（Ｄ）＞
本発明の植物施用用カメムシ忌避剤は、成分（Ｄ）から選択される１種以上の成分を有効成分とするものであっても良い。成分（Ｄ）は、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチル、ｔｒａｎｓ－２－メチル－２－ブテナール、アニスアルコール、２，３－ジエチルピラジンから構成されるものである。
成分（Ｄ）のうちアニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチルは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル及び酢酸メンチルから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。さらにこの中でも、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジルは、施用面に対するミツバチの忌避効果はもとより、施用面の上部空間におけるミツバチの忌避効果（空間忌避効果）が高いことが別途確認されており、殺虫剤施用によるミツバチの被害を低減する観点から２，３，５－トリメチルピラジン、４’－メチルアセトフェノン及び酢酸ベンジルから選択される１種以上の成分が、本発明の植物施用用カメムシ忌避剤の有効成分としてさらに好ましい。 <Component (D)>
The stink bug repellent for application to plants of the present invention may contain one or more components selected from component (D) as an active ingredient. Component (D) is anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, menthyl acetate, trans-2-methyl-2-butenal, anise alcohol, It is composed of 2,3-diethylpyrazine.
Anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4'-methylacetophenone, benzyl acetate, and menthyl acetate among component (D) have a repelling effect on stink bugs and plants such as agricultural and horticultural crops. In addition to its safety against bees, it has been confirmed separately that it is also excellent in its repellent effect against honeybees. In the present invention, one or more components selected from anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, and menthyl acetate are beneficial insects that honeybees From the viewpoint of being able to prevent direct or indirect contact with agricultural chemicals, it is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention. Furthermore, among these, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, and benzyl acetate not only have a bee-repellent effect on the application surface, but also have a high bee-repellent effect (spatial repellent effect) in the upper space of the application surface. It has been separately confirmed that one or more components selected from 2,3,5-trimethylpyrazine, 4′-methylacetophenone, and benzyl acetate are used in the present invention from the viewpoint of reducing damage to honeybees due to insecticide application. is more preferable as an active ingredient of stink bug repellent for plant application.
本発明の植物施用用カメムシ忌避剤は、成分（Ｄ）から選択される１種以上の成分を有効成分とするものであっても良い。成分（Ｄ）は、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチル、ｔｒａｎｓ－２－メチル－２－ブテナール、アニスアルコール、２，３－ジエチルピラジンから構成されるものである。
成分（Ｄ）のうちアニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチルは、カメムシへの忌避効果と農園芸作物などの植物に対する安全性に加えて、ミツバチに対する忌避効果にも優れていることが、別途確認されている。本発明において、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル及び酢酸メンチルから選択される１種以上の成分は、益虫であるミツバチが直接的または間接的に農薬と接触することを防止できる観点から、本発明の植物施用用カメムシ忌避剤の有効成分として好ましい。さらにこの中でも、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジルは、施用面に対するミツバチの忌避効果はもとより、施用面の上部空間におけるミツバチの忌避効果（空間忌避効果）が高いことが別途確認されており、殺虫剤施用によるミツバチの被害を低減する観点から２，３，５－トリメチルピラジン、４’－メチルアセトフェノン及び酢酸ベンジルから選択される１種以上の成分が、本発明の植物施用用カメムシ忌避剤の有効成分としてさらに好ましい。 <Component (D)>
The stink bug repellent for application to plants of the present invention may contain one or more components selected from component (D) as an active ingredient. Component (D) is anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, menthyl acetate, trans-2-methyl-2-butenal, anise alcohol, It is composed of 2,3-diethylpyrazine.
Anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4'-methylacetophenone, benzyl acetate, and menthyl acetate among component (D) have a repelling effect on stink bugs and plants such as agricultural and horticultural crops. In addition to its safety against bees, it has been confirmed separately that it is also excellent in its repellent effect against honeybees. In the present invention, one or more components selected from anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, and menthyl acetate are beneficial insects that honeybees From the viewpoint of being able to prevent direct or indirect contact with agricultural chemicals, it is preferable as an active ingredient of the stink bug repellent for application to plants of the present invention. Furthermore, among these, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, and benzyl acetate not only have a bee-repellent effect on the application surface, but also have a high bee-repellent effect (spatial repellent effect) in the upper space of the application surface. It has been separately confirmed that one or more components selected from 2,3,5-trimethylpyrazine, 4′-methylacetophenone, and benzyl acetate are used in the present invention from the viewpoint of reducing damage to honeybees due to insecticide application. is more preferable as an active ingredient of stink bug repellent for plant application.
本発明の植物施用用カメムシ忌避剤は、成分（Ａ）から選択される１種以上の成分と、上記成分（Ｄ）から選択される１種以上の成分とを併用しても良い。また、成分（Ｂ）から選択される１種以上の成分と、上記成分（Ｄ）から選択される１種以上の成分とを併用しても良いし、成分（Ｃ）から選択される１種以上の成分と、上記成分（Ｄ）から選択される１種以上の成分とを併用しても良い。
上記成分（Ａ）、成分（Ｂ）、成分（Ｃ）及び成分（Ｄ）に属する成分は、ミツバチ忌避効果も併せ持つため、仮に、本発明の植物施用用カメムシ忌避剤に植物病害防除成分等の農薬を併用する場合においても、益虫であるミツバチが施用した植物に近接することを抑制し、ミツバチが直接的または間接的に農薬と接触することを防止し得るものである。 In the stink bug repellent for application to plants of the present invention, one or more components selected from component (A) and one or more components selected from component (D) may be used in combination. Further, one or more components selected from the component (B) and one or more components selected from the component (D) may be used in combination, or one component selected from the component (C) You may use together the above component and the 1 or more types of component selected from the said component (D).
Since the components belonging to the above components (A), (B), (C) and (D) also have a honeybee repellent effect, if the stink bug repellent for plant application of the present invention contains a plant disease control component etc. Even when an agricultural chemical is used in combination, it is possible to prevent honeybees, which are beneficial insects, from coming close to the applied plant and prevent the honeybee from coming into direct or indirect contact with the agricultural chemical.
上記成分（Ａ）、成分（Ｂ）、成分（Ｃ）及び成分（Ｄ）に属する成分は、ミツバチ忌避効果も併せ持つため、仮に、本発明の植物施用用カメムシ忌避剤に植物病害防除成分等の農薬を併用する場合においても、益虫であるミツバチが施用した植物に近接することを抑制し、ミツバチが直接的または間接的に農薬と接触することを防止し得るものである。 In the stink bug repellent for application to plants of the present invention, one or more components selected from component (A) and one or more components selected from component (D) may be used in combination. Further, one or more components selected from the component (B) and one or more components selected from the component (D) may be used in combination, or one component selected from the component (C) You may use together the above component and the 1 or more types of component selected from the said component (D).
Since the components belonging to the above components (A), (B), (C) and (D) also have a honeybee repellent effect, if the stink bug repellent for plant application of the present invention contains a plant disease control component etc. Even when an agricultural chemical is used in combination, it is possible to prevent honeybees, which are beneficial insects, from coming close to the applied plant and prevent the honeybee from coming into direct or indirect contact with the agricultural chemical.
＜製剤＞
本発明の植物施用用カメムシ忌避剤の形態としては、有効成分以外に、必要に応じて一般的に製剤に添加される成分と共に製剤化したものと、製剤化したものを水で希釈したものが含まれる。中でも、製剤化した固形製剤や液状製剤が、コンパクトであり、かつ保存安定性に優れるため、移送時や保管時において有利であり、好適である。中でも、本発明の植物施用用カメムシ忌避剤は、液状のものとして使用することが好ましいため、水で希釈する場合には希釈しやすく、溶け残りが少ない点において液状製剤が好適である。
本発明の植物施用用カメムシ忌避剤における有効成分の含有量としては、使用時における薬量全体に対して０．００１ｗ／ｖ％以上含有することが好ましく、０．０１ｗ／ｖ％以上含有することがより好ましく、０．１ｗ／ｖ％以上含有することがさらに好ましい。この有効成分の含有量が０．００１ｗ／ｖ％より少ない場合は、忌避効果を十分に発揮できない場合がある。また、この含有量が１０ｗ／ｖ％を超えると、農園芸作物などの植物に薬害が発生する可能性も出てくるため、含有量は１０ｗ／ｖ％以下であることが好ましい。 <Formulation>
As the form of the stink bug repellent for application to plants of the present invention, in addition to the active ingredient, it is formulated with ingredients that are generally added to formulations as necessary, and the formulation is diluted with water. included. Among them, formulated solid preparations and liquid preparations are compact and excellent in storage stability, and are therefore advantageous and suitable for transportation and storage. Among them, the stink bug repellent for application to plants of the present invention is preferably used in a liquid form. Therefore, when diluted with water, a liquid formulation is preferable because it is easy to dilute with water and leaves little undissolved residue.
The content of the active ingredient in the stink bug repellent for plant application of the present invention is preferably 0.001 w/v% or more, and preferably 0.01 w/v% or more, based on the total amount of the drug at the time of use. is more preferable, and more preferably 0.1 w/v% or more. If the content of this active ingredient is less than 0.001 w/v%, the repellent effect may not be sufficiently exhibited. Moreover, if the content exceeds 10 w/v%, there is a possibility that plants such as agricultural and horticultural crops will suffer from phytotoxicity, so the content is preferably 10 w/v% or less.
本発明の植物施用用カメムシ忌避剤の形態としては、有効成分以外に、必要に応じて一般的に製剤に添加される成分と共に製剤化したものと、製剤化したものを水で希釈したものが含まれる。中でも、製剤化した固形製剤や液状製剤が、コンパクトであり、かつ保存安定性に優れるため、移送時や保管時において有利であり、好適である。中でも、本発明の植物施用用カメムシ忌避剤は、液状のものとして使用することが好ましいため、水で希釈する場合には希釈しやすく、溶け残りが少ない点において液状製剤が好適である。
本発明の植物施用用カメムシ忌避剤における有効成分の含有量としては、使用時における薬量全体に対して０．００１ｗ／ｖ％以上含有することが好ましく、０．０１ｗ／ｖ％以上含有することがより好ましく、０．１ｗ／ｖ％以上含有することがさらに好ましい。この有効成分の含有量が０．００１ｗ／ｖ％より少ない場合は、忌避効果を十分に発揮できない場合がある。また、この含有量が１０ｗ／ｖ％を超えると、農園芸作物などの植物に薬害が発生する可能性も出てくるため、含有量は１０ｗ／ｖ％以下であることが好ましい。 <Formulation>
As the form of the stink bug repellent for application to plants of the present invention, in addition to the active ingredient, it is formulated with ingredients that are generally added to formulations as necessary, and the formulation is diluted with water. included. Among them, formulated solid preparations and liquid preparations are compact and excellent in storage stability, and are therefore advantageous and suitable for transportation and storage. Among them, the stink bug repellent for application to plants of the present invention is preferably used in a liquid form. Therefore, when diluted with water, a liquid formulation is preferable because it is easy to dilute with water and leaves little undissolved residue.
The content of the active ingredient in the stink bug repellent for plant application of the present invention is preferably 0.001 w/v% or more, and preferably 0.01 w/v% or more, based on the total amount of the drug at the time of use. is more preferable, and more preferably 0.1 w/v% or more. If the content of this active ingredient is less than 0.001 w/v%, the repellent effect may not be sufficiently exhibited. Moreover, if the content exceeds 10 w/v%, there is a possibility that plants such as agricultural and horticultural crops will suffer from phytotoxicity, so the content is preferably 10 w/v% or less.
＜界面活性剤＞
本発明の植物施用用カメムシ忌避剤の製剤化に際し、界面活性剤を配合することができる。界面活性剤としては、非イオン性界面活性剤、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤の何れでも特に制限なく使用することができるが、中でも、非イオン性界面活性剤または陰イオン性界面活性剤が好適である。
具体的には、例えば、非イオン性界面活性剤としては、糖エステル型、脂肪酸エステル型、植物油型、アルコール型、アルキルフェノール型、ポリオキシエチレン－ポリオキシプロピレンブロックポリマー型、アルキルアミン型、ビスフェノール型、多環芳香族型のものが挙げられる。陰イオン性界面活性剤としては、カルボン酸型、スルホン酸型、硫酸エステル型、リン酸エステル型のものが挙げられる。陽イオン性界面活性剤としては、アンモニウム型、ベンザルコニウム型のものが挙げられる。両性界面活性剤としては、ベタイン型のものが挙げられる。
これらの界面活性剤は、単独もしくは２種以上を混合したもの何れも用いることができる。 <Surfactant>
A surfactant can be blended in formulating the stink bug repellent for application to plants of the present invention. As the surfactant, any of nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants can be used without particular limitation. Activators or anionic surfactants are preferred.
Specifically, for example, nonionic surfactants include sugar ester type, fatty acid ester type, vegetable oil type, alcohol type, alkylphenol type, polyoxyethylene-polyoxypropylene block polymer type, alkylamine type, and bisphenol type surfactants. , polycyclic aromatic types. Examples of anionic surfactants include carboxylic acid type, sulfonic acid type, sulfate type, and phosphate type surfactants. Examples of cationic surfactants include ammonium-type and benzalkonium-type surfactants. Amphoteric surfactants include those of the betaine type.
These surfactants can be used either singly or in combination of two or more.
本発明の植物施用用カメムシ忌避剤の製剤化に際し、界面活性剤を配合することができる。界面活性剤としては、非イオン性界面活性剤、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤の何れでも特に制限なく使用することができるが、中でも、非イオン性界面活性剤または陰イオン性界面活性剤が好適である。
具体的には、例えば、非イオン性界面活性剤としては、糖エステル型、脂肪酸エステル型、植物油型、アルコール型、アルキルフェノール型、ポリオキシエチレン－ポリオキシプロピレンブロックポリマー型、アルキルアミン型、ビスフェノール型、多環芳香族型のものが挙げられる。陰イオン性界面活性剤としては、カルボン酸型、スルホン酸型、硫酸エステル型、リン酸エステル型のものが挙げられる。陽イオン性界面活性剤としては、アンモニウム型、ベンザルコニウム型のものが挙げられる。両性界面活性剤としては、ベタイン型のものが挙げられる。
これらの界面活性剤は、単独もしくは２種以上を混合したもの何れも用いることができる。 <Surfactant>
A surfactant can be blended in formulating the stink bug repellent for application to plants of the present invention. As the surfactant, any of nonionic surfactants, anionic surfactants, cationic surfactants and amphoteric surfactants can be used without particular limitation. Activators or anionic surfactants are preferred.
Specifically, for example, nonionic surfactants include sugar ester type, fatty acid ester type, vegetable oil type, alcohol type, alkylphenol type, polyoxyethylene-polyoxypropylene block polymer type, alkylamine type, and bisphenol type surfactants. , polycyclic aromatic types. Examples of anionic surfactants include carboxylic acid type, sulfonic acid type, sulfate type, and phosphate type surfactants. Examples of cationic surfactants include ammonium-type and benzalkonium-type surfactants. Amphoteric surfactants include those of the betaine type.
These surfactants can be used either singly or in combination of two or more.
＜液体担体＞
本発明の植物施用用カメムシ忌避剤の製剤化に際し、液体担体を配合することができる。液体担体としては、本発明の効果を奏する限り、特に限定されるものではなく、本発明の有効成分とは異なる公知の各種液体を担体として用いることができる。
希釈に際しては例えば、精製水、水道水、イオン交換水、蒸留水、ろ過処理した水、滅菌処理した水、地下水、井戸水等が用いられる。
本発明の植物施用用カメムシ忌避剤を製剤化する場合は、上記界面活性剤や液体担体のほか、必要に応じて、一般的に製剤に添加される助剤成分を配合することができる。一般的に製剤に添加される助剤成分の例としては、安定化剤、防腐剤、着色料、誤飲・誤食防止剤等が挙げられる。安定化剤の例としては、ジブチルヒドロキシトルエン（ＢＨＴ）やブチルヒドロキシアニソール（ＢＨＡ）等の酸化防止剤、アスコルビン酸等が挙げられる。防腐剤の例としては、ソルビン酸、ソルビン酸塩、パラヒドロキシ安息香酸エステル類、チアベンダゾール、塩化ナトリウム等が挙げられる。着色料としては、カラメル色素、クチナシ色素、アントシアニン色素、紅花色素、フラボノイド色素、赤色２号、赤色３号、黄色４号、黄色５号等が挙げられる。誤飲・誤食防止剤としては、安息香酸デナトニウム等が挙げられる。 <Liquid carrier>
A liquid carrier can be blended in formulating the stink bug repellent for application to plants of the present invention. The liquid carrier is not particularly limited as long as the effect of the present invention is exhibited, and various known liquids different from the active ingredient of the present invention can be used as the carrier.
For dilution, for example, purified water, tap water, ion-exchanged water, distilled water, filtered water, sterilized water, ground water, well water, and the like are used.
When formulating the stink bug repellent for application to plants of the present invention, in addition to the above surfactants and liquid carriers, if necessary, auxiliary components that are generally added to formulations can be blended. Examples of auxiliary ingredients that are generally added to formulations include stabilizers, preservatives, colorants, and agents for preventing accidental ingestion and accidental ingestion. Examples of stabilizers include antioxidants such as dibutylhydroxytoluene (BHT) and butylhydroxyanisole (BHA), ascorbic acid, and the like. Examples of preservatives include sorbic acid, sorbates, parahydroxybenzoic acid esters, thiabendazole, sodium chloride and the like. Examples of coloring agents include caramel pigments, gardenia pigments, anthocyanin pigments, safflower pigments, flavonoid pigments, red No. 2, red No. 3, yellow No. 4 and yellow No. 5. Examples of accidental ingestion/eating prevention agents include denatonium benzoate and the like.
本発明の植物施用用カメムシ忌避剤の製剤化に際し、液体担体を配合することができる。液体担体としては、本発明の効果を奏する限り、特に限定されるものではなく、本発明の有効成分とは異なる公知の各種液体を担体として用いることができる。
希釈に際しては例えば、精製水、水道水、イオン交換水、蒸留水、ろ過処理した水、滅菌処理した水、地下水、井戸水等が用いられる。
本発明の植物施用用カメムシ忌避剤を製剤化する場合は、上記界面活性剤や液体担体のほか、必要に応じて、一般的に製剤に添加される助剤成分を配合することができる。一般的に製剤に添加される助剤成分の例としては、安定化剤、防腐剤、着色料、誤飲・誤食防止剤等が挙げられる。安定化剤の例としては、ジブチルヒドロキシトルエン（ＢＨＴ）やブチルヒドロキシアニソール（ＢＨＡ）等の酸化防止剤、アスコルビン酸等が挙げられる。防腐剤の例としては、ソルビン酸、ソルビン酸塩、パラヒドロキシ安息香酸エステル類、チアベンダゾール、塩化ナトリウム等が挙げられる。着色料としては、カラメル色素、クチナシ色素、アントシアニン色素、紅花色素、フラボノイド色素、赤色２号、赤色３号、黄色４号、黄色５号等が挙げられる。誤飲・誤食防止剤としては、安息香酸デナトニウム等が挙げられる。 <Liquid carrier>
A liquid carrier can be blended in formulating the stink bug repellent for application to plants of the present invention. The liquid carrier is not particularly limited as long as the effect of the present invention is exhibited, and various known liquids different from the active ingredient of the present invention can be used as the carrier.
For dilution, for example, purified water, tap water, ion-exchanged water, distilled water, filtered water, sterilized water, ground water, well water, and the like are used.
When formulating the stink bug repellent for application to plants of the present invention, in addition to the above surfactants and liquid carriers, if necessary, auxiliary components that are generally added to formulations can be blended. Examples of auxiliary ingredients that are generally added to formulations include stabilizers, preservatives, colorants, and agents for preventing accidental ingestion and accidental ingestion. Examples of stabilizers include antioxidants such as dibutylhydroxytoluene (BHT) and butylhydroxyanisole (BHA), ascorbic acid, and the like. Examples of preservatives include sorbic acid, sorbates, parahydroxybenzoic acid esters, thiabendazole, sodium chloride and the like. Examples of coloring agents include caramel pigments, gardenia pigments, anthocyanin pigments, safflower pigments, flavonoid pigments, red No. 2, red No. 3, yellow No. 4 and yellow No. 5. Examples of accidental ingestion/eating prevention agents include denatonium benzoate and the like.
＜農薬＞
本発明の植物施用用カメムシ忌避剤は、本発明の効果を妨げない範囲で、カメムシ以外の害虫や病害防除を目的として、ガーデニング等の農園芸作物に施用される農薬と併用することが出来る。
本発明の植物施用用カメムシ忌避剤と併用し得る農薬としては、特に制限されず、公知化合物、例えば、アセタミプリド、イミダクロプリド、クロチアニジン、ジノテフラン、チアクロプリド、チアメトキサム、ニテンピラムなどのネオニコチノイド系農薬、アレスリン、レスメトリン、ｄ－フェノトリン、テトラメトリン、シペルメトリン、デルタメトリン、フェンバレレート、ペルメトリン、エトフェンプロックスなどのピレスロイド系農薬、エチプロール、フィプロニルなどのフェニルピラゾール系農薬、ジクロルボス、トリクロルホン、シアノホス、フェニトロチオン、クロルピリホス、ダイアジノン、マラチオン、アセフェート、イソキサチオン、ホキシムなどの有機リン系農薬等の殺虫・殺ダニ剤、ペンチオピラドなどのピラゾール系農薬等の殺菌剤、ブタミホスなどの有機リン系農薬等の除草剤が挙げられる。 <Pesticides>
The plant-applied stink bug repellent of the present invention can be used in combination with agricultural chemicals applied to agricultural and horticultural crops such as gardening for the purpose of controlling pests and diseases other than stink bugs within a range that does not impair the effects of the present invention.
Pesticides that can be used in combination with the stink bug repellent for plant application of the present invention are not particularly limited, and known compounds include, for example, neonicotinoid pesticides such as acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, allethrin, Pyrethroid pesticides such as resmethrin, d-phenothrin, tetramethrin, cypermethrin, deltamethrin, fenvalerate, permethrin, and etofenprox; phenylpyrazole pesticides such as ethiprole and fipronil; , acephate, isoxathion, phoxime and other insecticides and acaricides; pyrazole agrochemicals such as penthiopyrad and other fungicides; and organophosphorus agrochemicals such as butamiphos.
本発明の植物施用用カメムシ忌避剤は、本発明の効果を妨げない範囲で、カメムシ以外の害虫や病害防除を目的として、ガーデニング等の農園芸作物に施用される農薬と併用することが出来る。
本発明の植物施用用カメムシ忌避剤と併用し得る農薬としては、特に制限されず、公知化合物、例えば、アセタミプリド、イミダクロプリド、クロチアニジン、ジノテフラン、チアクロプリド、チアメトキサム、ニテンピラムなどのネオニコチノイド系農薬、アレスリン、レスメトリン、ｄ－フェノトリン、テトラメトリン、シペルメトリン、デルタメトリン、フェンバレレート、ペルメトリン、エトフェンプロックスなどのピレスロイド系農薬、エチプロール、フィプロニルなどのフェニルピラゾール系農薬、ジクロルボス、トリクロルホン、シアノホス、フェニトロチオン、クロルピリホス、ダイアジノン、マラチオン、アセフェート、イソキサチオン、ホキシムなどの有機リン系農薬等の殺虫・殺ダニ剤、ペンチオピラドなどのピラゾール系農薬等の殺菌剤、ブタミホスなどの有機リン系農薬等の除草剤が挙げられる。 <Pesticides>
The plant-applied stink bug repellent of the present invention can be used in combination with agricultural chemicals applied to agricultural and horticultural crops such as gardening for the purpose of controlling pests and diseases other than stink bugs within a range that does not impair the effects of the present invention.
Pesticides that can be used in combination with the stink bug repellent for plant application of the present invention are not particularly limited, and known compounds include, for example, neonicotinoid pesticides such as acetamiprid, imidacloprid, clothianidin, dinotefuran, thiacloprid, thiamethoxam and nitenpyram, allethrin, Pyrethroid pesticides such as resmethrin, d-phenothrin, tetramethrin, cypermethrin, deltamethrin, fenvalerate, permethrin, and etofenprox; phenylpyrazole pesticides such as ethiprole and fipronil; , acephate, isoxathion, phoxime and other insecticides and acaricides; pyrazole agrochemicals such as penthiopyrad and other fungicides; and organophosphorus agrochemicals such as butamiphos.
＜植物＞
本発明の植物施用用カメムシ忌避剤の適用対象の植物は、特に限定されず、農園芸作物として栽培される、または、ガーデニングで育成される植物全般、例えば、穀類、豆類、果樹・果実類、野菜類、根菜類、加工用作物類、瓜類、牧草類、芝類、香料等用作物類、及び花卉類等が挙げられる。中でも、イネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッコリー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木（苗木）、西洋芝（ベントグラス、ライグラス、ブルーグラス）もしくは日本芝であることが好ましい。 <Plant>
The plant to which the stink bug repellent for plant application of the present invention is applied is not particularly limited, and is generally cultivated as an agricultural or horticultural crop or grown in gardening, such as grains, beans, fruit trees and fruits, Examples include vegetables, root crops, processed crops, melons, pasture grasses, grasses, aromatic crops, and flowers. Among them, rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green bean, pea, fava bean, adzuki bean, strawberry, cabbage, radish, mibuna, mizuna, turnip, Nabana, Chinese cabbage, broccoli, Cauliflower, lettuce, non-head lettuce, tomato, cherry tomato, eggplant, bell pepper, hot pepper, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, mitsuba, ginger, shallot, tobacco, carnation, iris, chrysanthemum, fig , citrus, timber (sapling), Western grass (bentgrass, ryegrass, bluegrass) or Japanese grass.
本発明の植物施用用カメムシ忌避剤の適用対象の植物は、特に限定されず、農園芸作物として栽培される、または、ガーデニングで育成される植物全般、例えば、穀類、豆類、果樹・果実類、野菜類、根菜類、加工用作物類、瓜類、牧草類、芝類、香料等用作物類、及び花卉類等が挙げられる。中でも、イネ、コムギ、オオムギ、トウモロコシ、ナタネ、ワタ、ヒマワリ、サトウキビ、ジャガイモ、ブドウ、ダイズ、インゲン、エンドウ、ソラマメ、アズキ、イチゴ、キャベツ、ダイコン、ミブナ、ミズナ、カブ、ナバナ、ハクサイ、ブロッコリー、カリフラワー、レタス、非結球レタス、トマト、ミニトマト、ナス、ピーマン、トウガラシ、タマネギ、キュウリ、メロン、スイカ、カボチャ、ホウレンソウ、テンサイ、オクラ、ミツバ、ショウガ、ラッキョウ、タバコ、カーネーション、アイリス、キク、イチジク、カンキツ、材木（苗木）、西洋芝（ベントグラス、ライグラス、ブルーグラス）もしくは日本芝であることが好ましい。 <Plant>
The plant to which the stink bug repellent for plant application of the present invention is applied is not particularly limited, and is generally cultivated as an agricultural or horticultural crop or grown in gardening, such as grains, beans, fruit trees and fruits, Examples include vegetables, root crops, processed crops, melons, pasture grasses, grasses, aromatic crops, and flowers. Among them, rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugar cane, potato, grape, soybean, green bean, pea, fava bean, adzuki bean, strawberry, cabbage, radish, mibuna, mizuna, turnip, Nabana, Chinese cabbage, broccoli, Cauliflower, lettuce, non-head lettuce, tomato, cherry tomato, eggplant, bell pepper, hot pepper, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, mitsuba, ginger, shallot, tobacco, carnation, iris, chrysanthemum, fig , citrus, timber (sapling), Western grass (bentgrass, ryegrass, bluegrass) or Japanese grass.
以下、処方例および試験例等により、本発明をさらに詳しく説明するが、本発明は、これらの例に限定されるものではない。
なお、実施例において、特に明記しない限り、数値はｗ／ｖ％を意味する。 Hereinafter, the present invention will be described in more detail with formulation examples, test examples, etc., but the present invention is not limited to these examples.
In the examples, numerical values mean w/v% unless otherwise specified.
なお、実施例において、特に明記しない限り、数値はｗ／ｖ％を意味する。 Hereinafter, the present invention will be described in more detail with formulation examples, test examples, etc., but the present invention is not limited to these examples.
In the examples, numerical values mean w/v% unless otherwise specified.
＜カメムシ忌避効果確認試験１＞
本発明の植物施用用カメムシ忌避剤が、カメムシに対して忌避効果を示すことを確認するために、以下の試験を行った。
（１）試験検体の調製
試験検体として、成分（Ａ）として、メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン、ブチルアルデヒドを、成分（Ｂ）として、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、ピロリジン、２－アセチルチアゾール、酪酸ブチル、６－メチルキノリン、デカン酸エチル、Ｎ－メチルアントラニル酸メチル、ｎ－オクタン酸ブチル、２－メチルピラジン、こはく酸（－）－メンチルを、成分（Ｃ）として、フェニル酢酸イソブチル、５－メチルキノキサリン、２－ナフタレンチオール、３－メチル－１－ブタノール、４－キノリンカルボン酸を、成分（Ａ）～（Ｃ）以外の成分としてペリルアルデヒドを使用し、ヘキサン酸は０．１ｗ／ｖ％水溶液を、それ以外は０．１ｗ／ｖ％エタノール溶液を使用した。
補正用検体として、エタノールのみと水のみを使用した。なお、このエタノールのみや水のみを使用した補正用検体では、カメムシに対する忌避効果は認められなかった。 <Stink bug repellent effect confirmation test 1>
In order to confirm that the stink bug repellent for plant application of the present invention exhibits a repelling effect against stink bugs, the following tests were conducted.
(1) Preparation of Test Specimen As component (A), methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, tigrin geranyl acid, ethyl pentadecanoate, isoeugenol, 2-(methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethyl vanillin, butyraldehyde, and benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, pyrrolidine, 2-acetylthiazole, butyl butyrate, 6-methylquinoline, ethyl decanoate, methyl N-methylanthranilate, butyl n-octanoate, 2-methylpyrazine, amber Acid (−)-menthyl as component (C), isobutyl phenylacetate, 5-methylquinoxaline, 2-naphthalene thiol, 3-methyl-1-butanol, 4-quinolinecarboxylic acid as components (A) to (C ), 0.1 w/v % aqueous solution of hexanoic acid was used, and 0.1 w/v % ethanol solution was used for the others.
Only ethanol and only water were used as calibration samples. It should be noted that no repelling effect against stink bugs was observed in the correction samples using only ethanol or only water.
本発明の植物施用用カメムシ忌避剤が、カメムシに対して忌避効果を示すことを確認するために、以下の試験を行った。
（１）試験検体の調製
試験検体として、成分（Ａ）として、メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン、ブチルアルデヒドを、成分（Ｂ）として、ベンゾチアゾール、α－イオノン、２－メチル－１－プロパノール、ｎ－オクタナール、ピロリジン、２－アセチルチアゾール、酪酸ブチル、６－メチルキノリン、デカン酸エチル、Ｎ－メチルアントラニル酸メチル、ｎ－オクタン酸ブチル、２－メチルピラジン、こはく酸（－）－メンチルを、成分（Ｃ）として、フェニル酢酸イソブチル、５－メチルキノキサリン、２－ナフタレンチオール、３－メチル－１－ブタノール、４－キノリンカルボン酸を、成分（Ａ）～（Ｃ）以外の成分としてペリルアルデヒドを使用し、ヘキサン酸は０．１ｗ／ｖ％水溶液を、それ以外は０．１ｗ／ｖ％エタノール溶液を使用した。
補正用検体として、エタノールのみと水のみを使用した。なお、このエタノールのみや水のみを使用した補正用検体では、カメムシに対する忌避効果は認められなかった。 <Stink bug repellent effect confirmation test 1>
In order to confirm that the stink bug repellent for plant application of the present invention exhibits a repelling effect against stink bugs, the following tests were conducted.
(1) Preparation of Test Specimen As component (A), methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, tigrin geranyl acid, ethyl pentadecanoate, isoeugenol, 2-(methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethyl vanillin, butyraldehyde, and benzothiazole, α-ionone, 2-methyl-1-propanol, n-octanal, pyrrolidine, 2-acetylthiazole, butyl butyrate, 6-methylquinoline, ethyl decanoate, methyl N-methylanthranilate, butyl n-octanoate, 2-methylpyrazine, amber Acid (−)-menthyl as component (C), isobutyl phenylacetate, 5-methylquinoxaline, 2-naphthalene thiol, 3-methyl-1-butanol, 4-quinolinecarboxylic acid as components (A) to (C ), 0.1 w/v % aqueous solution of hexanoic acid was used, and 0.1 w/v % ethanol solution was used for the others.
Only ethanol and only water were used as calibration samples. It should be noted that no repelling effect against stink bugs was observed in the correction samples using only ethanol or only water.
（２）供試虫
供試虫として、ミナミアオカメムシ２頭を各試験に使用した。
（３）試験方法
ＫＰカップ（直径１００ｍｍ×高さ９０ｍｍ）の内壁全体に、炭酸カルシウム／エタノール分散液を塗布し風乾させたのち、このＫＰカップ内の底面に、ろ紙（直径９０ｍｍ）を両面テープで固定した。別のろ紙（直径９０ｍｍ）の直径部分を切断した半月形のものに、各試験検体又は補正用検体４００μＬを均一に処理して、前記ＫＰカップ内の底面に固定したろ紙の上に、円形部分が重なるように載置し、試験装置とした。
上記試験装置に供試虫（ミナミアオカメムシ）２頭を放ち、３０分間（１８００秒）その行動を観察し、試験検体又は補正用検体を処理したろ紙上に供試虫が留まった２頭の平均時間Ａ（秒）と、試験検体又は補正用検体を処理していないろ紙上に供試虫が留まった２頭の平均時間Ｂ（秒）を計測した。
上記「時間Ａ（秒）」と「時間Ｂ（秒）」から、下記算出式により「忌避率Ｙ」および「補正忌避率Ｚ」を算出した。「補正忌避率Ｚ」を算出する場合に使用する「補正用検体の忌避率」は補正用検体の忌避率を用いた。
忌避率Ｙ（％）＝｛（時間Ｂ（秒））－（時間Ａ（秒））｝÷１８００×１００
補正忌避率Ｚ（％）＝｛試験検体の忌避率－補正用検体の忌避率｝÷｛１００－補正用検体の忌避率｝×１００
カメムシの補正忌避率Ｚ（％）を、下記表１にまとめて示す。 (2) Test insects As test insects, two southern green stink bugs were used in each test.
(3) Test method A calcium carbonate/ethanol dispersion was applied to the entire inner wall of a KP cup (diameter 100 mm x height 90 mm) and air-dried. fixed with . 400 μL of each test sample or correction sample is uniformly treated on a half-moon shape obtained by cutting the diameter portion of another filter paper (diameter 90 mm), and a circular portion is placed on the filter paper fixed to the bottom surface of the KP cup. were placed so that they overlapped to form a test device.
Two test insects (Southern stink bug) were released into the above test device, and their behavior was observed for 30 minutes (1800 seconds). The average time A (seconds) and the average time B (seconds) during which the test worms stayed on the filter paper not treated with the test sample or correction sample were measured.
From the above "time A (seconds)" and "time B (seconds)", the "repellent rate Y" and the "corrected repellent rate Z" were calculated by the following formulas. The repelling rate of the correction sample was used as the "correction sample repelling rate" used when calculating the "corrected repelling rate Z".
Evasion rate Y (%) = {(time B (seconds)) - (time A (seconds))} / 1800 x 100
Corrected repellency rate Z (%) = {repellency rate of test specimen - repellency rate of correction specimen} / {100 - repellency rate of correction specimen} x 100
The corrected repelling rate Z (%) of stink bugs is summarized in Table 1 below.
供試虫として、ミナミアオカメムシ２頭を各試験に使用した。
（３）試験方法
ＫＰカップ（直径１００ｍｍ×高さ９０ｍｍ）の内壁全体に、炭酸カルシウム／エタノール分散液を塗布し風乾させたのち、このＫＰカップ内の底面に、ろ紙（直径９０ｍｍ）を両面テープで固定した。別のろ紙（直径９０ｍｍ）の直径部分を切断した半月形のものに、各試験検体又は補正用検体４００μＬを均一に処理して、前記ＫＰカップ内の底面に固定したろ紙の上に、円形部分が重なるように載置し、試験装置とした。
上記試験装置に供試虫（ミナミアオカメムシ）２頭を放ち、３０分間（１８００秒）その行動を観察し、試験検体又は補正用検体を処理したろ紙上に供試虫が留まった２頭の平均時間Ａ（秒）と、試験検体又は補正用検体を処理していないろ紙上に供試虫が留まった２頭の平均時間Ｂ（秒）を計測した。
上記「時間Ａ（秒）」と「時間Ｂ（秒）」から、下記算出式により「忌避率Ｙ」および「補正忌避率Ｚ」を算出した。「補正忌避率Ｚ」を算出する場合に使用する「補正用検体の忌避率」は補正用検体の忌避率を用いた。
忌避率Ｙ（％）＝｛（時間Ｂ（秒））－（時間Ａ（秒））｝÷１８００×１００
補正忌避率Ｚ（％）＝｛試験検体の忌避率－補正用検体の忌避率｝÷｛１００－補正用検体の忌避率｝×１００
カメムシの補正忌避率Ｚ（％）を、下記表１にまとめて示す。 (2) Test insects As test insects, two southern green stink bugs were used in each test.
(3) Test method A calcium carbonate/ethanol dispersion was applied to the entire inner wall of a KP cup (diameter 100 mm x height 90 mm) and air-dried. fixed with . 400 μL of each test sample or correction sample is uniformly treated on a half-moon shape obtained by cutting the diameter portion of another filter paper (diameter 90 mm), and a circular portion is placed on the filter paper fixed to the bottom surface of the KP cup. were placed so that they overlapped to form a test device.
Two test insects (Southern stink bug) were released into the above test device, and their behavior was observed for 30 minutes (1800 seconds). The average time A (seconds) and the average time B (seconds) during which the test worms stayed on the filter paper not treated with the test sample or correction sample were measured.
From the above "time A (seconds)" and "time B (seconds)", the "repellent rate Y" and the "corrected repellent rate Z" were calculated by the following formulas. The repelling rate of the correction sample was used as the "correction sample repelling rate" used when calculating the "corrected repelling rate Z".
Evasion rate Y (%) = {(time B (seconds)) - (time A (seconds))} / 1800 x 100
Corrected repellency rate Z (%) = {repellency rate of test specimen - repellency rate of correction specimen} / {100 - repellency rate of correction specimen} x 100
The corrected repelling rate Z (%) of stink bugs is summarized in Table 1 below.
＜薬害確認試験１＞
（１）試験検体の調製
試験検体として、上記「カメムシ忌避効果確認試験」の成分（Ａ）～（Ｃ）と、それ以外の成分であるペリルアルデヒドを用いた。
成分（Ａ）～（Ｃ）、ペリルアルデヒドそれぞれ１成分０．１重量部、トレボンエアー（エトフェンプロックス１０重量％、残量は水及び界面活性剤）３．３重量部及び、全体量が１００ｍＬとなる様に水を配合したものを使用した。
（２）試験方法
バケツ（直径１９０ｍｍ、高さ１２４ｍｍ）で栽培したイネ（コシヒカリ）を、供試植物とした。幼穂形成期の供試植物に、スプレー容器（Ｔ－９５トリガー、キャニヨン株式会社製）を用いて、供試植物全体が濡れる様に試験検体６０ｍＬを散布した。
散布から１週間後の供試植物の薬害の程度を観察し、下記評価基準に基づいて薬害を評価した。
［評価基準］
－：薬害なし、±：薬害が認められるが実用上問題ない程度、＋：薬害が認められ実用上問題がある
本試験においては、イネの葉が変色したものを「薬害」と定義する。
薬害の評価結果を、下記表１にまとめて示す。 <Phytotoxicity Confirmation Test 1>
(1) Preparation of Test Specimens As test specimens, the components (A) to (C) of the above-mentioned "stinkbug repellent effect confirmation test" and the other component, perillaldehyde, were used.
Components (A) to (C), 0.1 parts by weight of perillaldehyde each, 3.3 parts by weight of Trebonair (10% by weight of etofenprox, remaining water and surfactant), and a total volume of 100 mL A mixture of water was used so that
(2) Test method Rice (Koshihikari) cultivated in a bucket (diameter: 190 mm, height: 124 mm) was used as a test plant. Using a spray container (T-95 Trigger, manufactured by Canyon Co., Ltd.), 60 mL of the test sample was sprayed on the test plant in the panicle formation stage so that the entire test plant was wet.
One week after spraying, the degree of phytotoxicity of the test plants was observed, and phytotoxicity was evaluated based on the following evaluation criteria.
[Evaluation criteria]
-: no phytotoxicity, ±: phytotoxicity observed but to the extent that there is no practical problem, +: phytotoxicity observed but practically problematic In this test, discoloration of rice leaves is defined as "phytotoxicity".
The evaluation results of phytotoxicity are summarized in Table 1 below.
（１）試験検体の調製
試験検体として、上記「カメムシ忌避効果確認試験」の成分（Ａ）～（Ｃ）と、それ以外の成分であるペリルアルデヒドを用いた。
成分（Ａ）～（Ｃ）、ペリルアルデヒドそれぞれ１成分０．１重量部、トレボンエアー（エトフェンプロックス１０重量％、残量は水及び界面活性剤）３．３重量部及び、全体量が１００ｍＬとなる様に水を配合したものを使用した。
（２）試験方法
バケツ（直径１９０ｍｍ、高さ１２４ｍｍ）で栽培したイネ（コシヒカリ）を、供試植物とした。幼穂形成期の供試植物に、スプレー容器（Ｔ－９５トリガー、キャニヨン株式会社製）を用いて、供試植物全体が濡れる様に試験検体６０ｍＬを散布した。
散布から１週間後の供試植物の薬害の程度を観察し、下記評価基準に基づいて薬害を評価した。
［評価基準］
－：薬害なし、±：薬害が認められるが実用上問題ない程度、＋：薬害が認められ実用上問題がある
本試験においては、イネの葉が変色したものを「薬害」と定義する。
薬害の評価結果を、下記表１にまとめて示す。 <Phytotoxicity Confirmation Test 1>
(1) Preparation of Test Specimens As test specimens, the components (A) to (C) of the above-mentioned "stinkbug repellent effect confirmation test" and the other component, perillaldehyde, were used.
Components (A) to (C), 0.1 parts by weight of perillaldehyde each, 3.3 parts by weight of Trebonair (10% by weight of etofenprox, remaining water and surfactant), and a total volume of 100 mL A mixture of water was used so that
(2) Test method Rice (Koshihikari) cultivated in a bucket (diameter: 190 mm, height: 124 mm) was used as a test plant. Using a spray container (T-95 Trigger, manufactured by Canyon Co., Ltd.), 60 mL of the test sample was sprayed on the test plant in the panicle formation stage so that the entire test plant was wet.
One week after spraying, the degree of phytotoxicity of the test plants was observed, and phytotoxicity was evaluated based on the following evaluation criteria.
[Evaluation criteria]
-: no phytotoxicity, ±: phytotoxicity observed but to the extent that there is no practical problem, +: phytotoxicity observed but practically problematic In this test, discoloration of rice leaves is defined as "phytotoxicity".
The evaluation results of phytotoxicity are summarized in Table 1 below.
表１に示す結果より、本発明の植物施用用カメムシ忌避剤における、有効成分である成分（Ａ）は、カメムシに対する優れた忌避効果を発揮し、かつ、薬害が発現しやすい植物の１つであるイネに対して、薬害を全く発生させないことが明らかとなった。
同様に、本発明の植物施用用カメムシ忌避剤において、有効成分となり得る成分（Ｂ）も、カメムシに対する良好な忌避効果を発揮し、かつ、イネに対する薬害を全く発生させないことが、また、本発明の植物施用用カメムシ忌避剤の有効成分となり得る成分（Ｃ）は、カメムシに対する良好な忌避効果を発揮し、イネに対する薬害が認められるものの実用上問題ない程度であることが明らかとなった。
すなわち、本発明の植物施用用カメムシ忌避剤における、有効成分である成分（Ａ）や、成分（Ｂ）、（Ｃ）は、農園芸作物などの植物に施用することにより有効にカメムシを忌避し、農園芸作物などの植物に対する薬害は実用レベル以上の優れた効果を発揮することが上記試験により確認された。
また、本発明の植物施用用カメムシ忌避剤において、有効成分となり得る成分（Ｄ）も、同様の試験を行ったところ、カメムシに対する良好な忌避効果を発揮し、イネに対する薬害を全く発生させない、もしくは薬害が認められるものの実用上問題ない程度であることが別途確認された。 From the results shown in Table 1, the component (A), which is the active ingredient in the stink bug repellent for plant application of the present invention, exerts an excellent repellent effect against stink bugs and is one of the plants that are likely to develop phytotoxicity. It was clarified that no phytotoxicity was caused to a certain rice plant.
Similarly, in the stink bug repellent agent for application to plants of the present invention, the component (B), which can be an active ingredient, also exerts a good repellent effect against stink bugs and does not cause any phytotoxicity to rice. Ingredient (C), which can be an active ingredient of the stink bug repellent for plant application, exhibits a good repellent effect against stink bugs, and although phytotoxicity to rice is recognized, it was found that there is no practical problem.
That is, the component (A), components (B), and (C), which are active ingredients, in the stink bug repellent for plant application of the present invention effectively repel stink bugs by applying them to plants such as agricultural and horticultural crops. It was confirmed by the above-mentioned test that the phytotoxicity to plants such as agricultural and horticultural crops is more effective than the practical level.
In the stink bug repellent agent for application to plants of the present invention, the component (D), which can be an active ingredient, was also subjected to a similar test. Although phytotoxicity was observed, it was confirmed separately that there was no practical problem.
同様に、本発明の植物施用用カメムシ忌避剤において、有効成分となり得る成分（Ｂ）も、カメムシに対する良好な忌避効果を発揮し、かつ、イネに対する薬害を全く発生させないことが、また、本発明の植物施用用カメムシ忌避剤の有効成分となり得る成分（Ｃ）は、カメムシに対する良好な忌避効果を発揮し、イネに対する薬害が認められるものの実用上問題ない程度であることが明らかとなった。
すなわち、本発明の植物施用用カメムシ忌避剤における、有効成分である成分（Ａ）や、成分（Ｂ）、（Ｃ）は、農園芸作物などの植物に施用することにより有効にカメムシを忌避し、農園芸作物などの植物に対する薬害は実用レベル以上の優れた効果を発揮することが上記試験により確認された。
また、本発明の植物施用用カメムシ忌避剤において、有効成分となり得る成分（Ｄ）も、同様の試験を行ったところ、カメムシに対する良好な忌避効果を発揮し、イネに対する薬害を全く発生させない、もしくは薬害が認められるものの実用上問題ない程度であることが別途確認された。 From the results shown in Table 1, the component (A), which is the active ingredient in the stink bug repellent for plant application of the present invention, exerts an excellent repellent effect against stink bugs and is one of the plants that are likely to develop phytotoxicity. It was clarified that no phytotoxicity was caused to a certain rice plant.
Similarly, in the stink bug repellent agent for application to plants of the present invention, the component (B), which can be an active ingredient, also exerts a good repellent effect against stink bugs and does not cause any phytotoxicity to rice. Ingredient (C), which can be an active ingredient of the stink bug repellent for plant application, exhibits a good repellent effect against stink bugs, and although phytotoxicity to rice is recognized, it was found that there is no practical problem.
That is, the component (A), components (B), and (C), which are active ingredients, in the stink bug repellent for plant application of the present invention effectively repel stink bugs by applying them to plants such as agricultural and horticultural crops. It was confirmed by the above-mentioned test that the phytotoxicity to plants such as agricultural and horticultural crops is more effective than the practical level.
In the stink bug repellent agent for application to plants of the present invention, the component (D), which can be an active ingredient, was also subjected to a similar test. Although phytotoxicity was observed, it was confirmed separately that there was no practical problem.
＜薬害確認試験２＞
（１）試験検体の調製
メチオノール２．０重量部、トレボンエアー（エトフェンプロックス１０重量％、残量は水及び界面活性剤）３．３重量部及び、全体量が１００ｍＬとなる様に水を配合したものを使用した。
（２）試験方法
上記「薬害確認試験１」と同様に、試験と評価を行った。
（３）結果
本発明の植物施用用カメムシ忌避剤の有効成分の１つであるメチオノールは、２．０ｗ／ｖ％という高濃度においても、植物体に対する薬害が全く確認されなかった。 <Phytotoxicity confirmation test 2>
(1) Preparation of test specimen 2.0 parts by weight of methiol, 3.3 parts by weight of Trebonair (10% by weight of etofenprox, the balance being water and surfactant), and water so that the total volume is 100 mL I used a mixture.
(2) Test method Tests and evaluations were performed in the same manner as in the above "phytotoxicity confirmation test 1".
(3) Results Methionol, which is one of the active ingredients of the stink bug repellent for plant application of the present invention, did not cause any phytotoxicity to plants even at a high concentration of 2.0 w/v%.
（１）試験検体の調製
メチオノール２．０重量部、トレボンエアー（エトフェンプロックス１０重量％、残量は水及び界面活性剤）３．３重量部及び、全体量が１００ｍＬとなる様に水を配合したものを使用した。
（２）試験方法
上記「薬害確認試験１」と同様に、試験と評価を行った。
（３）結果
本発明の植物施用用カメムシ忌避剤の有効成分の１つであるメチオノールは、２．０ｗ／ｖ％という高濃度においても、植物体に対する薬害が全く確認されなかった。 <Phytotoxicity confirmation test 2>
(1) Preparation of test specimen 2.0 parts by weight of methiol, 3.3 parts by weight of Trebonair (10% by weight of etofenprox, the balance being water and surfactant), and water so that the total volume is 100 mL I used a mixture.
(2) Test method Tests and evaluations were performed in the same manner as in the above "phytotoxicity confirmation test 1".
(3) Results Methionol, which is one of the active ingredients of the stink bug repellent for plant application of the present invention, did not cause any phytotoxicity to plants even at a high concentration of 2.0 w/v%.
＜カメムシ忌避効果確認試験２＞
試験検体として、本発明における成分（Ｄ）である、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチル、ｔｒａｎｓ－２－メチル－２－ブテナール、アニスアルコール、２，３－ジエチルピラジンの１．０ｗ／ｖ％エタノール溶液を使用した以外は、上記「カメムシ忌避効果確認試験１」と同様に確認試験を実施した。
また、試験検体として、本発明における成分（Ｄ）である、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチル、ｔｒａｎｓ－２－メチル－２－ブテナール、アニスアルコール、２，３－ジエチルピラジン１．０重量部、トレボンエアー（エトフェンプロックス１０重量％、残量は水及び界面活性剤）３．３重量部及び、全体量が１００ｍＬとなる様に水を配合したものを使用した以外は、上記「薬害確認試験１」と同様に確認試験を実施した。
上記「カメムシ忌避効果確認試験１」と同様に、カメムシの補正忌避率Ｚ（％）を算出し、「薬害確認試験１」と同じ評価基準に基づいて薬害を評価した。
カメムシの補正忌避率Ｚ（％）と薬害の評価結果を、下記表２にまとめた。 <Stink bug repellent effect confirmation test 2>
As test specimens, anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, menthyl acetate, trans-2-methyl, which are component (D) in the present invention, -2-Butenal, anise alcohol, confirmation test was carried out in the same manner as the above "stink bug repellent effect confirmation test 1" except that a 1.0 w / v% ethanol solution of 2,3-diethylpyrazine was used.
Also, as test specimens, anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4'-methylacetophenone, benzyl acetate, menthyl acetate, trans-2, which are component (D) in the present invention, -Methyl-2-butenal, anis alcohol, 2,3-diethylpyrazine 1.0 parts by weight, Trebon air (10% by weight of etofenprox, balance being water and surfactant) 3.3 parts by weight and the total amount A confirmatory test was carried out in the same manner as in the above "phytotoxicity confirmatory test 1" except that water was used so that the volume of the extract was 100 mL.
The corrected stink bug repelling rate Z (%) was calculated in the same manner as in "Stink Bug Repellent Effect Confirmation Test 1", and phytotoxicity was evaluated based on the same evaluation criteria as in "Phytotoxicity Confirmation Test 1".
The corrected repellency rate Z (%) of stink bugs and the evaluation results of phytotoxicity are summarized in Table 2 below.
試験検体として、本発明における成分（Ｄ）である、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチル、ｔｒａｎｓ－２－メチル－２－ブテナール、アニスアルコール、２，３－ジエチルピラジンの１．０ｗ／ｖ％エタノール溶液を使用した以外は、上記「カメムシ忌避効果確認試験１」と同様に確認試験を実施した。
また、試験検体として、本発明における成分（Ｄ）である、アニスアルデヒド、４－ヒドロキシ安息香酸プロピル、２，３，５－トリメチルピラジン、４’－メチルアセトフェノン、酢酸ベンジル、酢酸メンチル、ｔｒａｎｓ－２－メチル－２－ブテナール、アニスアルコール、２，３－ジエチルピラジン１．０重量部、トレボンエアー（エトフェンプロックス１０重量％、残量は水及び界面活性剤）３．３重量部及び、全体量が１００ｍＬとなる様に水を配合したものを使用した以外は、上記「薬害確認試験１」と同様に確認試験を実施した。
上記「カメムシ忌避効果確認試験１」と同様に、カメムシの補正忌避率Ｚ（％）を算出し、「薬害確認試験１」と同じ評価基準に基づいて薬害を評価した。
カメムシの補正忌避率Ｚ（％）と薬害の評価結果を、下記表２にまとめた。 <Stink bug repellent effect confirmation test 2>
As test specimens, anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4′-methylacetophenone, benzyl acetate, menthyl acetate, trans-2-methyl, which are component (D) in the present invention, -2-Butenal, anise alcohol, confirmation test was carried out in the same manner as the above "stink bug repellent effect confirmation test 1" except that a 1.0 w / v% ethanol solution of 2,3-diethylpyrazine was used.
Also, as test specimens, anisaldehyde, 4-hydroxypropyl benzoate, 2,3,5-trimethylpyrazine, 4'-methylacetophenone, benzyl acetate, menthyl acetate, trans-2, which are component (D) in the present invention, -Methyl-2-butenal, anis alcohol, 2,3-diethylpyrazine 1.0 parts by weight, Trebon air (10% by weight of etofenprox, balance being water and surfactant) 3.3 parts by weight and the total amount A confirmatory test was carried out in the same manner as in the above "phytotoxicity confirmatory test 1" except that water was used so that the volume of the extract was 100 mL.
The corrected stink bug repelling rate Z (%) was calculated in the same manner as in "Stink Bug Repellent Effect Confirmation Test 1", and phytotoxicity was evaluated based on the same evaluation criteria as in "Phytotoxicity Confirmation Test 1".
The corrected repellency rate Z (%) of stink bugs and the evaluation results of phytotoxicity are summarized in Table 2 below.
表２に示す結果より、本発明における成分（Ｄ）においても、濃度１．０ｗ／ｖ％でカメムシに対する優れた忌避効果を発揮し、かつ、薬害が発現しやすい植物の１つであるイネに対して、薬害を全く発生させないことが明らかとなった。
From the results shown in Table 2, even in the component (D) in the present invention, at a concentration of 1.0 w / v%, it exhibits an excellent repellent effect against stink bugs, and rice, which is one of the plants that easily expresses phytotoxicity. On the other hand, it was clarified that no phytotoxicity was caused at all.
本発明の植物施用用カメムシ忌避剤は、農園芸作物などの植物に施用することによりカメムシを忌避するため、農園芸作物に対するカメムシ被害を低減することが出来るだけでなく、農園芸作物などの植物に対する薬害を発生させないという優れた効果を両立させて発揮するので、農園芸作物の栽培には有用である。
また、本発明における成分（Ａ）、成分（Ｂ）、成分（Ｃ）及び成分（Ｄ）に属する成分は、ミツバチ忌避効果も併せ持つため、仮に、本発明の植物施用用カメムシ忌避剤に植物病害防除成分等の農薬を併用する場合においても、益虫であるミツバチが施用した植物に近接することを抑制し、ミツバチが直接的または間接的に農薬と接触することを防止し得るものである。
The stink bug repellent for plant application of the present invention repels stink bugs by applying it to plants such as agricultural and horticultural crops. It is useful for the cultivation of agricultural and horticultural crops because it exhibits both the excellent effect of not causing phytotoxicity to.
In addition, since the components belonging to component (A), component (B), component (C) and component (D) in the present invention also have a honeybee repellent effect, if stink bug repellent for plant application of the present invention does not cause plant disease Even when a pesticide such as a control component is used in combination, it is possible to prevent honeybees, which are beneficial insects, from coming close to the applied plant and prevent the bee from coming into direct or indirect contact with the pesticide.
また、本発明における成分（Ａ）、成分（Ｂ）、成分（Ｃ）及び成分（Ｄ）に属する成分は、ミツバチ忌避効果も併せ持つため、仮に、本発明の植物施用用カメムシ忌避剤に植物病害防除成分等の農薬を併用する場合においても、益虫であるミツバチが施用した植物に近接することを抑制し、ミツバチが直接的または間接的に農薬と接触することを防止し得るものである。
The stink bug repellent for plant application of the present invention repels stink bugs by applying it to plants such as agricultural and horticultural crops. It is useful for the cultivation of agricultural and horticultural crops because it exhibits both the excellent effect of not causing phytotoxicity to.
In addition, since the components belonging to component (A), component (B), component (C) and component (D) in the present invention also have a honeybee repellent effect, if stink bug repellent for plant application of the present invention does not cause plant disease Even when a pesticide such as a control component is used in combination, it is possible to prevent honeybees, which are beneficial insects, from coming close to the applied plant and prevent the bee from coming into direct or indirect contact with the pesticide.
Claims (2)
- 下記成分（Ａ）から選択される１種以上の成分を有効成分とする、植物施用用カメムシ忌避剤：
成分（Ａ）：メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒド。 A stinkbug repellent for plant application, containing as an active ingredient one or more ingredients selected from the following ingredients (A):
Component (A): Methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2- (Methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethylvanillin and butyraldehyde. - 下記成分（Ａ）から選択される１種以上の成分を有効成分として、植物に施用することを特徴とするカメムシ忌避方法：
成分（Ａ）：メチオノール、ヘキサン酸、４－ヒドロキシ安息香酸、酢酸テルピニル、１，５－ジメチルナフタレン、２－アセチルナフタレン、α－アミルシンナムアルデヒド、チグリン酸ゲラニル、ペンタデカン酸エチル、イソオイゲノール、２－（メトキシメチル）ピロリジン、プロピオンアルデヒド、２－エチル－３－メチルピラジン、エチルバニリン及びブチルアルデヒド。
A method for repelling stink bugs, which comprises applying to a plant at least one component selected from the following component (A) as an active ingredient:
Component (A): Methionol, hexanoic acid, 4-hydroxybenzoic acid, terpinyl acetate, 1,5-dimethylnaphthalene, 2-acetylnaphthalene, α-amylcinnamaldehyde, geranyl tiglate, ethyl pentadecanoate, isoeugenol, 2- (Methoxymethyl)pyrrolidine, propionaldehyde, 2-ethyl-3-methylpyrazine, ethylvanillin and butyraldehyde.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010209062A (en) * | 2009-02-10 | 2010-09-24 | Kochi Univ | Controlling agent for hemiptera pest, thysanoptera eye pest or acarina pest |
| US20150140136A1 (en) * | 1998-07-28 | 2015-05-21 | Ecosmart Technologies, Inc. | Pesticidal compositions and methods for using same |
| JP2018095636A (en) * | 2016-12-09 | 2018-06-21 | アース製薬株式会社 | Pest control agent |
| WO2021235422A1 (en) * | 2020-05-19 | 2021-11-25 | アース製薬株式会社 | Honeybee repellent |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150140136A1 (en) * | 1998-07-28 | 2015-05-21 | Ecosmart Technologies, Inc. | Pesticidal compositions and methods for using same |
| JP2010209062A (en) * | 2009-02-10 | 2010-09-24 | Kochi Univ | Controlling agent for hemiptera pest, thysanoptera eye pest or acarina pest |
| JP2018095636A (en) * | 2016-12-09 | 2018-06-21 | アース製薬株式会社 | Pest control agent |
| WO2021235422A1 (en) * | 2020-05-19 | 2021-11-25 | アース製薬株式会社 | Honeybee repellent |
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