JP7401784B2 - 機械発泡用硬化性組成物およびその発泡体の製造方法 - Google Patents
機械発泡用硬化性組成物およびその発泡体の製造方法 Download PDFInfo
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- JP7401784B2 JP7401784B2 JP2020558262A JP2020558262A JP7401784B2 JP 7401784 B2 JP7401784 B2 JP 7401784B2 JP 2020558262 A JP2020558262 A JP 2020558262A JP 2020558262 A JP2020558262 A JP 2020558262A JP 7401784 B2 JP7401784 B2 JP 7401784B2
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- gear pump
- pressure
- mechanical foaming
- discharge
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- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
- JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- OVFFWUHKSNMAOJ-UHFFFAOYSA-N tris(ethenyl)-[ethenyl(dimethyl)silyl]oxysilane Chemical compound C=C[Si](C)(C)O[Si](C=C)(C=C)C=C OVFFWUHKSNMAOJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
- B29C44/0492—Devices for feeding the different materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
- B05B1/30—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages
- B05B1/3033—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head
- B05B1/304—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head the controlling element being a lift valve
- B05B1/3046—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to control volume of flow, e.g. with adjustable passages the control being effected by relative coaxial longitudinal movement of the controlling element and the spray head the controlling element being a lift valve the valve element, e.g. a needle, co-operating with a valve seat located downstream of the valve element and its actuating means, generally in the proximity of the outlet orifice
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/004—Arrangements for controlling delivery; Arrangements for controlling the spray area comprising sensors for monitoring the delivery, e.g. by displaying the sensed value or generating an alarm
- B05B12/006—Pressure or flow rate sensors
- B05B12/008—Pressure or flow rate sensors integrated in or attached to a discharge apparatus, e.g. a spray gun
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/0018—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam
- B05B7/0025—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply
- B05B7/0031—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns
- B05B7/0043—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with devices for making foam with a compressed gas supply with disturbing means promoting mixing, e.g. balls, crowns including a plurality of individual elements, e.g. needles, baffles, rotatable blades
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/02—Spray pistols; Apparatus for discharge
- B05B7/04—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge
- B05B7/0416—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid
- B05B7/0483—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid with gas and liquid jets intersecting in the mixing chamber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/02—Spray pistols; Apparatus for discharge
- B05B7/12—Spray pistols; Apparatus for discharge designed to control volume of flow, e.g. with adjustable passages
- B05B7/1254—Spray pistols; Apparatus for discharge designed to control volume of flow, e.g. with adjustable passages the controlling means being fluid actuated
- B05B7/1263—Spray pistols; Apparatus for discharge designed to control volume of flow, e.g. with adjustable passages the controlling means being fluid actuated pneumatically actuated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/24—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
- B05B7/26—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device
- B05B7/262—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device a liquid and a gas being brought together before entering the discharge device
- B05B7/267—Apparatus in which liquids or other fluent materials from different sources are brought together before entering the discharge device a liquid and a gas being brought together before entering the discharge device the liquid and the gas being both under pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
- B29B7/007—Methods for continuous mixing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/726—Measuring properties of mixture, e.g. temperature or density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7404—Mixing devices specially adapted for foamable substances
- B29B7/7409—Mixing devices specially adapted for foamable substances with supply of gas
- B29B7/7414—Mixing devices specially adapted for foamable substances with supply of gas with rotatable stirrer, e.g. using an intermeshing rotor-stator system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/748—Plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
- B29C44/3446—Feeding the blowing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/35—Component parts; Details or accessories
- B29C44/355—Characteristics of the foam, e.g. having particular surface properties or structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/60—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/16—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0058—Liquid or visquous
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/026—Crosslinking before of after foaming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Landscapes
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
Description
条件(A):25℃で0.1Hzにおけるη*が1000~50000Pa・sの範囲であり、
条件(B):25℃で10.0Hzにおけるη*が100~1000Pa・sの範囲である。
条件(C):25℃で(0.1Hzにおけるη*)/(10.0Hzにおけるη*)が70.0以下の範囲である。
前記機械式発泡装置は、
前記液体および前記気体を送出する流路と、
前記流路へ前記液体を供給する液体供給部と、
前記流路へ前記気体を供給する気体供給部と、
前記流路と前記気体供給部との間の連通状態を切り替え可能な開閉弁と、
前記流路の途中に配置された第1ギアポンプと、
前記第1ギアポンプよりも前記流路の下流側に配置され、前記第1ギアポンプよりも高速で回転駆動されることによって前記流路中に前記気体を混入させて前記発泡性材料を生成する吸引圧を発生させる第2ギアポンプと、
前記第1ギアポンプと前記第2ギアポンプとの間における前記流路内のポンプ間圧力を検出する第1圧力センサーと、
前記液体に前記気体が混入した前記発泡性材料を吐出する吐出口を有するノズルと、前記第2ギアポンプから送出された前記発泡性材料を前記ノズルまで送出する連通路を有する吐出弁本体部と、を備える吐出部と、
前記第1ギアポンプ、前記第2ギアポンプ、および前記気体供給部を駆動するとともに前記開閉弁を開いて前記吐出部から前記発泡性材料を吐出する吐出動作と、前記第1ギアポンプ、前記第2ギアポンプ、および前記気体供給部の作動を停止させるとともに前記開閉弁を閉じて前記発泡性材料の吐出を中断させる待機動作とを行うように装置各部を制御する制御部と、を有し、
前記制御部は、前記待機動作中において、前記ポンプ間圧力が予め設定した上限圧力になったとき、前記第2ギアポンプを回転駆動して前記第1ギアポンプと前記第2ギアポンプとの間における前記流路内の前記発泡性材料の少なくとも一部を前記第2ギアポンプの下流側に送出して前記流路内の圧力を前記上限圧力よりも低い圧力に低下させる、機械式発泡装置であり、
前記液体は、上記(1)~(7)のいずれか1つに記載の機械発泡用硬化性組成物であることを特徴とする発泡体の製造方法。
本発明に係る機械発泡用硬化性組成物は、レオメーターによる周波数依存性測定において、下記の条件(A)および(B)を充足する複素粘度η*を有する機械発泡用硬化性組成物であり、当該機械発泡用硬化性組成物の硬化形態が湿気硬化性ではないことを特徴とするものである(第1実施形態):
条件(A):25℃で0.1Hzにおけるη*が1000~50000Pa・sの範囲であり、
条件(B):25℃で10.0Hzにおけるη*が100~1000Pa・sの範囲である。
本実施形態の機械発泡用硬化性組成物は、レオメーターによる周波数依存性測定において、条件(A):25℃で0.1Hzにおけるη*が1000~50000Pa・sの範囲である。25℃で0.1Hzにおけるη*が上記範囲であれば、上記した発明の効果を有効に発現することができる点で優れている。かかる観点から、25℃で0.1Hzにおけるη*は1000~30000Pa・sの範囲であることが好ましく、1500~22000Pa・sの範囲であることがより好ましい。
本実施形態の機械発泡用硬化性組成物は、レオメーターによる周波数依存性測定において、上記(A)と共に、条件(B):25℃で10.0Hzにおけるη*が100~1000Pa・sの範囲である。25℃で10.0Hzにおけるη*が上記範囲であれば、上記した発明の効果を有効に発現することができる点で優れている。かかる観点から、25℃で10.0Hzにおけるη*は100~900Pa・sの範囲であることが好ましく、125~750Pa・sの範囲であることがより好ましい。
本実施形態の機械発泡用硬化性組成物は、さらに、条件(C):25℃で(0.1Hzにおけるη*)/(10.0Hzにおけるη*)が70.0以下の範囲であるのが好ましい。条件(A)、(B)を満足した上で、25℃で(0.1Hzにおけるη*)/(10.0Hzにおけるη*)が70.0以下の範囲であれば、上記した発明の効果を有効に発現することができる点で優れている。かかる観点から、条件(C)におけるη*(0.1Hz)/η*(10.0Hz)が、5.0~50の範囲であることが好ましく、5.0~43の範囲であることがより好ましい。
本発明の機械発泡用硬化性組成物(発泡前かつ硬化前の状態)のη*(複素粘度)は、レオメーターの周波数依存性測定により求められる。詳しくは、レオメーターとしてサーモフィッシャーサイエンティフィック株式会社製のレオメーター HAAKE MARSIIIを用いて、ローターはP35を使用し、温調設備により25℃雰囲気下における各周波数(f(Hz))による粘度を測定する。最適な測定を行うため、例えば、実施例で用いた機械発泡用硬化性組成物のサンプルに対しては、ローターギャップは0.5mmまたは1mmに、測定モードはひずみ制御(CD制御)(0.05~0.5%)または応力制御(CS制御)(1~30Pa)に設定して測定を行った(実施例の表2参照)が、必ずしも、これらの設定条件に制限されるものではない。なお、レオメーターとしては、上記HAAKE MARSIIIに制限されるものではなく、他の市販品を用いてもよい。同様にローターとしては、上記P35に制限されるものではなく、他の市販品を用いてもよい。
環状エーテル基を有する樹脂(化合物)に含まれる環状エーテル基としては、3員環または4員環が好ましく、3員環としてエポキシ基(グリシジル基)、脂環式エポキシ基(シクロアルケンオキサイド)などが、4員環としてオキセタン基などが挙げられるが、これらに限定されるものではない。環状エーテル基を有する樹脂(化合物)としては、具体的には、エポキシ樹脂や脂環式エポキシ樹脂やオキセタン樹脂などが挙げられるが、これらに限定されるものではなく、これらを2種類以上組み合わせてもよい。また、環状チオエーテル基(チイラン基)を用いることもできる。
ビニル基を有する化合物および環状エーテル基を有する化合物の他に、イソシアネート基を有する化合物を使用することができ、イソシアネート基を有する化合物に熱硬化性を付与するためアミン化合物を添加することが好ましい。
本発明の発泡体の製造方法は、液体に気体が混入した発泡性材料を生成し、当該発泡性材料を吐出して発泡させる機械式発泡装置を用いる発泡体の製造方法であって、
前記機械式発泡装置は、前記液体および前記気体を送出する流路と、前記流路へ前記液体を供給する液体供給部と、前記流路へ前記気体を供給する気体供給部と、前記流路と前記気体供給部との間の連通状態を切り替え可能な開閉弁と、前記流路の途中に配置された第1ギアポンプと、前記第1ギアポンプよりも前記流路の下流側に配置され、前記第1ギアポンプよりも高速で回転駆動されることによって前記流路中に前記気体を混入させて前記発泡性材料を生成する吸引圧を発生させる第2ギアポンプと、前記第1ギアポンプと前記第2ギアポンプとの間における前記流路内のポンプ間圧力を検出する第1圧力センサーと、前記液体に前記気体が混入した前記発泡性材料を吐出する吐出口を有するノズルと、前記第2ギアポンプから送出された前記発泡性材料を前記ノズルまで送出する連通路を有する吐出弁本体部と、を備える吐出部と、前記第1ギアポンプ、前記第2ギアポンプ、および前記気体供給部を駆動するとともに前記開閉弁を開いて前記吐出部から前記発泡性材料を吐出する吐出動作と、前記第1ギアポンプ、前記第2ギアポンプ、および前記気体供給部の作動を停止させるとともに前記開閉弁を閉じて前記発泡性材料の吐出を中断させる待機動作とを行うように装置各部を制御する制御部と、を有し、前記制御部は、前記待機動作中において、前記ポンプ間圧力が予め設定した上限圧力になったとき、前記第2ギアポンプを回転駆動して前記第1ギアポンプと前記第2ギアポンプとの間における前記流路内の前記発泡性材料の少なくとも一部を前記第2ギアポンプの下流側に送出して前記流路内の圧力を前記上限圧力よりも低い圧力に低下させる、ギアポンプ式の機械式発泡装置であり、
前記液体は、本発明の上記機械発泡用硬化性組成物であることを特徴とするものである。
本実施形態に係るギアポンプ式の機械式発泡装置10および当該装置に発泡性材料用の液体として供される、本発明の機械発泡用硬化性組成物(液状の樹脂とも称する)M1を用いる機械式発泡方法によって得られる発泡体Mは、液状の樹脂(液体に相当)M1に気体M2が混入した発泡性材料M0を大気中に吐出することによって気体M2が発泡して生成される(符号は図1参照)。
図1は、機械式発泡装置10の全体構成を概略的に示している。機械式発泡装置10は、樹脂M1に気体M2が混入した発泡性材料M0を生成し、当該発泡性材料M0を吐出して発泡させて発泡体Mを生成する。
樹脂供給部100は、図1に示すように、第1配管12aを介してポンプ部200に連結されている。樹脂供給部100は、樹脂M1を貯蔵する樹脂タンク101を備えている。樹脂供給部100は、例えば、交換可能なカートリッジ等から構成される。樹脂供給部100の圧力としては、耐圧性を考慮すると0.1~1.0MPaであることが好ましい。
ポンプ部200は、図1に示すように、樹脂供給部100の下流側に配置された第1ギアポンプ211と、第1ギアポンプ211の下流側に配置された第2ギアポンプ212と、第1ギアポンプ211と第2ギアポンプ212との間に配置されて、第2配管12bに気体M2を供給する気体供給部220と、を備えている。第1ギアポンプ211および第2ギアポンプ212は、第2配管12bを介して互いに連結されている。
ヘッド部300は、図1に示すように、第2ギアポンプ212により送出された発泡性材料M0を撹拌するミキサー310と、ミキサー310により撹拌された発泡性材料M0を吐出する吐出部320と、を備えている。
制御部400は、図1に示すように、記憶部410と、演算部420と、入出力部430と、を備えており、各部は信号を送受信する電気配線などを介して相互に接続されている。
以下、図5を参照して、上述のような構成を有する機械式発泡装置10を使用して発泡体Mを生成する機械式発泡方法について説明する。
次に、図2および図6を参照して、逆流抑制の制御(ステップS18)について説明する。
次に、図3、図4(A)、(B)、図7~9を参照して、予備加圧(ステップS20)について説明する。
機械発泡に用いる発泡性材料を構成する液体(機械発泡用硬化性組成物)として下記表1および表2に記載の株式会社スリーボンド製の実施例1~7および比較例1~7の各商品を用い、これら機械発泡用硬化性組成物について、発泡前かつ硬化前の状態における複素粘度η*の周波数依存性確認を行った。さらに、発泡後において硬化前の状態で外観確認し、硬化条件による硬化後の発泡状態を確認し、各機械発泡用硬化性組成物の硬化形態および硬化条件とあわせてその結果を下記表1にまとめた。ここで、実施例4に記載のThreeBond3081Jの充填剤(シリカ粉)の添加量に対して、実施例5~7はそれぞれ1.2倍、1.4倍、1.8倍の添加量に変更したものを調製した。以下、ThreeBond(登録商標)をTBとも略す。
実施例2:TB1153C;整泡剤無添加
実施例3:TB1234B;整泡剤無添加
実施例4:TB3081J;整泡剤無添加
実施例5:TB3081J 充填剤1.2倍;整泡剤無添加
実施例6:TB3081J 充填剤1.4倍;整泡剤無添加
実施例7:TB3081J 充填剤1.8倍;整泡剤無添加
比較例1:TB3164;整泡剤無添加
比較例2:TB1280E;整泡剤無添加
比較例3:TB3013Q;整泡剤無添加
比較例4:TB1207B;整泡剤無添加
比較例5:TB1217H;整泡剤無添加
比較例6:TB1539;整泡剤無添加
比較例7:TB3013M;整泡剤無添加。
本実施例で機械発泡に用いる発泡性材料を構成する液体として用いる「TB1152C」は、上記した条件(A)、(B)を充足する複素粘度η*を有する1液型のオレフィン系熱硬化タイプの機械発泡用硬化性組成物であって、アリル基を有する樹脂を含み、オレフィン系シール剤等の用途に用いられる市販品である。
本実施例で機械発泡に用いる発泡性材料を構成する液体として用いる「TB1153C」は、上記した条件(A)、(B)を充足する複素粘度η*を有する1液型のオレフィン系熱硬化タイプの機械発泡用硬化性組成物であって、アリル基を有する樹脂を含み、オレフィン系燃料電池用シール剤等の用途に用いられる市販品である。
本実施例で機械発泡に用いる発泡性材料を構成する液体として用いる「TB1234B」は、上記した条件(A)、(B)を充足する複素粘度η*を有する1液型のシリコーン系熱硬化タイプの機械発泡用硬化性組成物であって、ビニルシロキサン基を有する樹脂を含み、シリコーン系液状接着剤、シール剤、ポッティング剤等の用途に用いられる市販品である。
本実施例で機械発泡に用いる発泡性材料を構成する液体として用いる「TB3081J」は、上記した条件(A)、(B)を充足する複素粘度η*を有する1液型のアクリレート系光硬化タイプの機械発泡用硬化性組成物であって、(メタ)アクリル基を有する樹脂を含み、アクリレート系シール剤、接着剤、液状ガスケット等の用途に用いられる市販品である。
実施例5、6、7で機械発泡に用いる発泡性材料を構成する液体は、いずれも上記した条件(A)、(B)を充足する複素粘度η*を有する1液型のアクリレート系であって、(メタ)アクリル基を有する樹脂を含む光硬化タイプの機械発泡用硬化性組成物である。
本比較例で発泡性材料を構成する液体として用いた「TB3164」は、上記した条件(A)、(B)を充足しない複素粘度η*を有する1液型のシリコーン系の湿気硬化タイプの硬化性組成物であって、(メタ)アクリロイル基と加水分解性シリル基とを含む樹脂と湿気硬化性触媒とを含有し、シリコーン系紫外線硬化性接着剤、シール剤、コーティング剤等の用途に用いられる市販品である。
本比較例で発泡性材料を構成する液体として用いた「TB1280E」は、上記した条件(A)、(B)を充足しない複素粘度η*を有する1液型のシリコーン系の湿気硬化タイプの硬化性組成物であって、加水分解性シリル基を含む樹脂と湿気硬化性触媒とを含有し、シリコーン系液状ガスケット等の用途に用いられる市販品である。
本比較例で発泡性材料を構成する液体として用いた「TB3013Q」は、上記した条件(A)、(B)を充足しない複素粘度η*を有する1液型のアクリレート系の光硬化タイプの硬化性組成物であって、(メタ)アクリル基を有する樹脂を含み、アクリレート系電装用シール剤等の用途に用いられる市販品である。
本比較例で発泡性材料を構成する液体として用いた「TB1207B」は、上記した条件(A)、(B)を充足する複素粘度η*を有する1液型のシリコーン系の湿気硬化タイプの硬化性組成物であって、加水分解性シリル基を含む樹脂と湿気硬化性触媒とを含有し、シリコーン系液状ガスケット等の用途に用いられる市販品である。
本比較例で機械発泡に用いる発泡性材料を構成する液体として用いた「TB1217H」は、上記した条件(A)、(B)を充足しない複素粘度η*を有する1液型のシリコーン系の湿気硬化タイプの硬化性組成物であって、加水分解性シリル基を含む樹脂と湿気硬化性触媒とを含有し、シリコーン系液状ガスケット等の用途に用いられる市販品である。
本比較例で発泡性材料を構成する液体として用いた「TB1539」は、上記した条件(B)を充足し、条件(A)を充足しない複素粘度η*を有する1液型の植物由来系の熱硬化タイプの硬化性組成物であって、イソシアネート基を含む樹脂を含有し、ヒマシ油(リシノレイン酸を主成分)を変性したポリマーを使用した1液性低温加熱速硬化型弾性接着剤等の用途に用いられる市販品である。
本比較例で発泡性材料を構成する液体として用いた「TB3013M」は、上記した条件(A)、(B)を充足しない複素粘度η*を有する1液型のアクリレート系の光硬化タイプの硬化性組成物であって、(メタ)アクリル基を有する樹脂を含み、アクリレート系接着剤、シール剤、コーティング剤等の用途に用いられる市販品である。
実施例1~7及び比較例1~7で使用した液体について、サーモフィッシャーサイエンティフィック株式会社製のレオメーター HAAKE MARSIIIを用いて、ローターはP35を使用し、温調設備により調整した25℃雰囲気下における各周波数(f(Hz))による粘度η*を測定した。実施例1~7及び比較例1~7で使用した液体において最適な測定を行うため、ローターギャップは0.5mmまたは1mmに、測定モードはCD制御(0.05~0.5%)またはCS制御(1~30Pa)に設定して測定を行った。詳細な条件は下記表2にまとめる。また、表1、2では、周波数(単位)を「f(Hz)」とし、粘度(単位)を「η*(Pa・s)」とし、η*(0.1Hz)/η*(10.0Hz)の比を「チクソ比」とする。各周波数ごとの粘度η*とこれらに基づくチクソ比の測定(計算)結果を表1の「発泡前」の「硬化前」の「f(Hz)」、「η*(Pa・s)」及び「チクソ比」の欄に示す。
単位面積当たりのひずみのため、無次元数(図10の角度θ)に対して100を乗じた数値を用いるため単位は「%」で表している;
応力制御:CS(Controlled Shear)制御;
単位面積当たりのずり応力のため単位は「Pa」で表す。
株式会社スリーボンド製の機械式発泡装置MFD-10(メカニカルフォーミングディスペンサー)(図1~図4)に示す構成を有する機械式発泡装置)を使用して実施例1~7及び比較例1~7の液体を、上記した本発明の発泡体の製造方法に沿って機械発泡させて吐出した。ここで、初期吐出圧力は2.8MPaにし、発泡倍率は1.9倍にし、送り込む気体にはドライの窒素ガスを使用し、ノズル内径は直径0.5mmのノズルを使用した。発泡倍率は、装置内の二つギアポンプにおいて第一ギアに対する第二ギアの回転速度を調整して設定した。詳しくはギアポンプの送液速度変更は専用のコントローラーで設定値を変更し、第一ギアに対する第二ギアの駆動用モーターの回転速度を調整して設定した。各液体を吐出する末端のニードル式バルブの絞り(吐出圧力)とギアポンプの回転速度の調整(吐出速度)により最適な吐出状態にした。液体の粘度に併せて吐出圧力及び速度を変えて最適化した。つまり、求めている吐出量よりも少ない場合は圧力を上げ、求めている吐出量より多い場合は圧力を下げる調整を行った。具体的には、吐出圧力2.8MPa~3.0MPaの範囲で調整し、吐出速度は0.15g/sec一定とした。吐出し始めて、発泡しない液体に対しては倍率を上げて再確認した。1.9倍で発泡しない場合、倍率を最高3.0倍まで上げて再確認した。機械発泡させた各液体をアルミニウム板上に幅4mm×高さ2mm×長さ50mmにビード塗布し、各液体の最適な硬化条件で硬化させた。ここでは、表1の硬化条件であり、各液体の公知の技術資料に記載されている標準硬化条件を用いた。硬化物の温度が25℃になった後、カッターで硬化物をビードの断面が見える形で切断し、硬化物の断面を以下の評価基準に従い目視で確認した。得られた評価結果を表1の「発泡後」で「硬化後」の「発泡状態」の欄に示す。また、表1の発泡倍率1.9倍や3.0倍というのは、あくまで目標とする装置の設定である(実際は、その倍率になっていないケースもある)。
○:泡が均等に分散している
×:泡が不均一に分散しているまたは泡が分離している。
実施例1~7及び比較例1~7で使用した液体の初期の外観(色)を確認した。その後、当該液体を上記[発泡状態確認]と同様に発泡させて高さ300ccのポリカップに多めに吐出した。1分後にポリカップの口の端部をガラス板によりすり切りした後、すり切りしたポリカップの液体の外観を評価基準に従い目視で確認した。得られた評価結果を表1の「発泡後」で「硬化前」の「外観」の欄に示す。
○:初期の外観よりも白くなる
×:初期の外観と同じ。
13 吸気口、 21 第1圧力センサー、
22 第2圧力センサー、 100 樹脂供給部(液体供給部)、
200 ポンプ部、 211 第1ギアポンプ、
212 第2ギアポンプ、 220 気体供給部、
230 開閉弁、 240 切り替え弁、
300 ヘッド部、 310 ミキサー、
311 入口部、 312 出口部、
313 混合室、 320 吐出部、
321 ノズル、 322 吐出弁本体部、
331 第1ノズル弁、 332 第2ノズル弁、
400 制御部、 M 発泡体、
M0 発泡性材料、 M1 液体(機械発泡用硬化性組成物)、
M2 気体、 P1 ポンプ間圧力、
P2 吐出圧力、 Pmax 上限圧力、
Pmin 下限圧力、 Pt 目標圧力、
Pc 補正圧力、 Ps 設定圧力。
Claims (8)
- レオメーターによる周波数依存性測定において、下記の条件(A)および(B)を充足する複素粘度η*を有する機械発泡用硬化性組成物であり、
当該機械発泡用硬化性組成物の硬化形態が湿気硬化性ではないことを特徴とする、ギアポンプ式機械発泡用の1液型硬化性組成物:
条件(A):25℃で0.1Hzにおけるη*が1000~50000Pa・sの範囲であり、
条件(B):25℃で10.0Hzにおけるη*が100~1000Pa・sの範囲であり、
条件(C):25℃でη * (0.1Hz)/η * (10.0Hz)が、5.0~50である。 - 前記条件(A)および(B)におけるη*が、それぞれ1000~30000Pa・sおよび100~900Pa・sであることを特徴とする請求項1に記載のギアポンプ式機械発泡用の1液型硬化性組成物。
- 1液型熱硬化性組成物又は1液型光硬化性組成物である、請求項1または2に記載のギアポンプ式機械発泡用の1液型硬化性組成物。
- 1液型のオレフィン系熱硬化タイプ、1液型のシリコーン系熱硬化タイプ、又は1液型のアクリレート系光硬化タイプである、請求項1~3のいずれか1項に記載のギアポンプ式機械発泡用の1液型硬化性組成物。
- 整泡剤を含まないことを特徴とする請求項1~4のいずれか1項に記載のギアポンプ式機械発泡用の1液型硬化性組成物。
- 硬化性組成物の硬化形態が、室温硬化性、熱硬化性および光硬化性よりなる群から選択される少なくとも一つであることを特徴とする請求項1に記載のギアポンプ式機械発泡用の1液型硬化性組成物。
- ビニル基および環状エーテル基よりなる群から選択される少なくとも一つの反応性官能基を有する樹脂を含むことを特徴とする請求項1~6のいずれか1項に記載のギアポンプ式機械発泡用の1液型硬化性組成物。
- 液体に気体が混入した発泡性材料を生成し、当該発泡性材料を吐出して発泡させる、ギアポンプ式機械式発泡装置を用いる発泡体の製造方法であって、
前記機械式発泡装置は、
前記液体および前記気体を送出する流路と、
前記流路へ前記液体を供給する液体供給部と、
前記流路へ前記気体を供給する気体供給部と、
前記流路と前記気体供給部との間の連通状態を切り替え可能な開閉弁と、
前記流路の途中に配置された第1ギアポンプと、
前記第1ギアポンプよりも前記流路の下流側に配置され、前記第1ギアポンプよりも高速で回転駆動されることによって前記流路中に前記気体を混入させて前記発泡性材料を生成する吸引圧を発生させる第2ギアポンプと、
前記第1ギアポンプと前記第2ギアポンプとの間における前記流路内のポンプ間圧力を検出する第1圧力センサーと、
前記液体に前記気体が混入した前記発泡性材料を吐出する吐出口を有するノズルと、前記第2ギアポンプから送出された前記発泡性材料を前記ノズルまで送出する連通路を有する吐出弁本体部と、を備える吐出部と、
前記第1ギアポンプ、前記第2ギアポンプ、および前記気体供給部を駆動するとともに前記開閉弁を開いて前記吐出部から前記発泡性材料を吐出する吐出動作と、前記第1ギアポンプ、前記第2ギアポンプ、および前記気体供給部の作動を停止させるとともに前記開閉弁を閉じて前記発泡性材料の吐出を中断させる待機動作とを行うように装置各部を制御する制御部と、を有し、
前記制御部は、前記待機動作中において、前記ポンプ間圧力が予め設定した上限圧力になったとき、前記第2ギアポンプを回転駆動して前記第1ギアポンプと前記第2ギアポンプとの間における前記流路内の前記発泡性材料の少なくとも一部を前記第2ギアポンプの下流側に送出して前記流路内の圧力を前記上限圧力よりも低い圧力に低下させる、機械式発泡装置であり、
前記液体は、請求項1~7のいずれか1項に記載のギアポンプ式機械発泡用の1液型硬化性組成物であることを特徴とする発泡体の製造方法。
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