JP7372729B2 - 複合粒子及び液晶表示装置 - Google Patents
複合粒子及び液晶表示装置 Download PDFInfo
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- JP7372729B2 JP7372729B2 JP2017541119A JP2017541119A JP7372729B2 JP 7372729 B2 JP7372729 B2 JP 7372729B2 JP 2017541119 A JP2017541119 A JP 2017541119A JP 2017541119 A JP2017541119 A JP 2017541119A JP 7372729 B2 JP7372729 B2 JP 7372729B2
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- JRSJRHKJPOJTMS-UHFFFAOYSA-N trimethoxy(2-phenylethenyl)silane Chemical compound CO[Si](OC)(OC)C=CC1=CC=CC=C1 JRSJRHKJPOJTMS-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- LGROXJWYRXANBB-UHFFFAOYSA-N trimethoxy(propan-2-yl)silane Chemical compound CO[Si](OC)(OC)C(C)C LGROXJWYRXANBB-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
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Description
本発明に係る複合粒子は、顔料と鎖状化合物と環状化合物とを含有する。本発明に係る複合粒子では、上記鎖状化合物が、上記環状化合物の環の内側を貫通している。本発明に係る複合粒子は、上記鎖状化合物が、上記環状化合物の環の内側を貫通している構造を有する。本発明に係る複合粒子では、例えば、樹脂部を有する。本発明に係る複合粒子は、例えば、樹脂部に顔料が含まれており、樹脂粒子である。
ρ:複合粒子の粒子径の標準偏差
Dn:複合粒子の粒子径の平均値
液晶表示装置用スペーサの用途に好適に使用可能にする観点からは、上記顔料は、黒色顔料又は白色顔料であることが好ましく、黒色顔料であることが好ましい。上記顔料は、黒色顔料であってもよく、白色顔料であってもよい。
本発明に係る複合粒子は、上記鎖状化合物と上記環状化合物とを含有する。本発明に係る複合粒子では、上記鎖状化合物は、上記環状化合物の環の内側を貫通している。本発明に係る複合粒子では、上記の構成が備えられているので、複合粒子の破壊強度の低下を抑制することができる。
複合粒子の破壊強度の低下をより一層抑制する観点から、上記鎖状化合物が上記環状化合物の環の内側を貫通して、鎖状化合物と環状化合物とが、包接化合物を形成していることが好ましい。上記鎖状化合物の全てが上記環状化合物の環の内側を貫通していなくてもよい。上記鎖状化合物は上記環状化合物における全ての環の内側を貫通していなくてもよい。
破壊強度の低下をより一層抑える観点からは、上記環状化合物の環状骨格は、3個以上(環状に連なっている原子の数)の原子が連なった環状骨格であることが好ましく、5個以上の原子が連なった環状骨格であることがより好ましく、10個以上の原子が連なった環状骨格であることが更に好ましい。環状に連なっている原子の数は、1000個以下であってもよく、500個以下であってもよい。環状に連なっている原子の数は、環を構成している原子のうち、環を構成している原子の数が最小となるように数えた値である。環状骨格を構成する原子は、炭素原子、酸素原子、窒素原子又は硫黄原子であることが好ましく、炭素原子又は酸素原子であることが好ましい。
複合粒子の破壊強度の低下をより一層抑制する観点から、上記環状化合物に架橋剤が結合していることが好ましい。上記架橋剤は上記環状化合物における側鎖であってもよい。この架橋剤の存在は、複合粒子の破壊強度の低下の抑制に大きく寄与する。
本発明に係る液晶表示装置は、液晶表示装置用部材と、上述した複合粒子とを備える。また、上記複合粒子は、液晶表示装置用スペーサとして好適に用いられる。すなわち、上記複合粒子は、液晶セルを構成する一対の基板と、該一対の基板間に封入された液晶と、上記一対の基板間に配置された液晶表示装置用スペーサとを備える液晶表示装置を得るために好適に用いられる。上記液晶表示装置用スペーサは、周辺シール剤に含まれていてもよい。
上記複合粒子の用途は特に限定されない。上記複合粒子は、液晶表示装置用スペーサとしてだけではなく、様々な用途に好適に用いられる。上記複合粒子は、調光ガラス用スペーサとして用いられることが好ましく、調光フィルム用スペーサとして用いられることが好ましい。
(1)複合粒子の作製
表面被覆されたカーボンブラック5重量部、ジビニルベンゼン475重量部、及びテトラメチロールメタントリアクリレート475重量部が混合された分散液に、セルム(登録商標)スーパーポリマーSM1313P(鎖状化合物分子量:約1.1万、全体分子量:18万(代表値))50重量部を添加した。次に過酸化ベンゾイル20重量部を添加し、それぞれの添加段階で均一に混合し、混合液を得た。この混合液を3重量%のポリビニルアルコール水溶液8500重量部中に入れ、十分に撹拌した後、ホモジナイザーで乳化径が約3~10μmになるように乳化した。
STN型液晶表示装置の作製:
イソプロピルアルコール70重量部と水30重量部とを含む分散媒に、得られた複合粒子を、得られるスペーサ分散液100重量%中で固形分濃度が2重量%となるように添加し、撹拌し、液晶表示装置用スペーサ分散液を得た。
セルム(登録商標)スーパーポリマーSM1313Pの配合量を50重量部から100重量部に変更したこと以外は、実施例1と同様にして複合粒子及び液晶表示装置を得た。
セルム(登録商標)スーパーポリマーSM1313Pの配合量を50重量部から150重量部に変更したこと以外は、実施例1と同様にして複合粒子及び液晶表示装置を得た。
ジビニルベンゼン475重量部とテトラメチロールメタントリアクリレート475重量部とを、ジビニルベンゼン950重量部に変更したこと以外は、実施例1と同様にして複合粒子及び液晶表示装置を得た。
セルム(登録商標)スーパーポリマーSM1313Pをセルム(登録商標)スーパーポリマーSA1313P(鎖状化合物分子量:約1.1万、全体分子量:19万(代表値))に変更したこと以外は、実施例1と同様にして複合粒子及び液晶表示装置を得た。
セルム(登録商標)スーパーポリマーSM1313Pをセルム(登録商標)スーパーポリマーSM2403P(鎖状化合物分子量:約2万、全体分子量:60万(代表値))に変更したこと以外は、実施例1と同様にして複合粒子及び液晶表示装置を得た。
セルム(登録商標)スーパーポリマーSM1313Pを添加しなかったこと以外は、実施例1と同様にして複合粒子及び液晶表示装置を得た。
表面被覆されたカーボンブラックを添加しなかったこと以外は、実施例1と同様にして複合粒子及び液晶表示装置を得た。
(1)粒子径
得られた複合粒子について、粒度分布測定装置(ベックマンコールター社製「Multisizer4」)を用いて、約100000個の粒径を測定し、平均粒子径及び標準偏差を測定した。
得られた複合粒子について、上述した方法により、変動係数(CV値)を測定した。
得られた複合粒子について、圧縮破壊歪を測定した。上記圧縮破壊歪は、以下のようにして測定した。圧縮破壊歪を下記の基準で判定した。
試料台上に複合粒子を散布した。散布された複合粒子1個について、微小圧縮試験機(島津製作所社製「微小圧縮試験機MCT-W200」)を用いて、複合粒子の中心方向に、複合粒子が破壊するまで負荷(反転荷重値)を与えた。その後、複合粒子が破壊したときの変位を測定した。平均粒子径に対する破壊したときの変位の割合を圧縮破壊歪とした。なお、負荷速度は0.33mN/秒とした。
○:圧縮破壊歪が50%以上
△:圧縮破壊歪が45%以上、50%未満
×:圧縮破壊歪が45%未満
得られた液晶表示装置に所定の電圧を印加して、液晶表示装置用スペーサに起因する光抜け等の表示不良の有無を電子顕微鏡で観察し、表示品質を下記の基準で判定した。
○:液晶表示装置用スペーサに起因する基板の間隔(ギャップ)ムラや光抜け等の表示不良は全く認められず、優れた表示品質であった
△:液晶表示装置用スペーサに起因する基板の間隔(ギャップ)ムラや光抜け等の表示不良が若干認められた
×:液晶表示装置用スペーサに起因する基板の間隔(ギャップ)ムラや光抜け等の表示不良が著しく認められた
81…液晶表示装置
82…透明ガラス基板
83…透明電極
84…配向膜
85…液晶
86…シール剤
Claims (9)
- 樹脂粒子本体を含有し、
前記樹脂粒子本体内に、顔料と、鎖状化合物と、環状化合物とを含有し、
前記環状化合物に架橋剤が結合しており、
前記鎖状化合物が、前記環状化合物の環の内側を貫通しており、
前記鎖状化合物が前記環状化合物の環の内側を貫通している構造が、ロタキサンである、複合粒子。 - 前記環状化合物及び前記鎖状化合物の合計100重量%中、前記環状化合物における前記架橋剤を除く部分及び前記鎖状化合物の合計の含有量が1重量%以上、70重量%以下である、請求項1に記載の複合粒子。
- 前記環状化合物における前記架橋剤が、アクリル重合体又はスチレン重合体を含む、請求項1又は2に記載の複合粒子。
- 粒子径が2μm以上、15μm以下である、請求項1~3のいずれか1項に記載の複合粒子。
- 前記顔料が、黒色顔料又は白色顔料である、請求項1~4のいずれか1項に記載の複合粒子。
- 前記顔料が、カーボンブラック、チタンブラック、アニリンブラック又は酸化鉄を含む、請求項1~5のいずれか1項に記載の複合粒子。
- 前記鎖状化合物の重量平均分子量が3000以上、100000以下である、請求項1~6のいずれか1項に記載の複合粒子。
- 前記環状化合物における環状骨格が、10個以上の原子が連なった環状骨格である、請求項1~7のいずれか1項に記載の複合粒子。
- 液晶表示装置用部材と、
請求項1~8のいずれか1項に記載の複合粒子とを備える、液晶表示装置。
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