JP7309879B2 - 改善した耐食性、強度、延性及び靭性を有するチタン合金 - Google Patents
改善した耐食性、強度、延性及び靭性を有するチタン合金 Download PDFInfo
- Publication number
- JP7309879B2 JP7309879B2 JP2021532900A JP2021532900A JP7309879B2 JP 7309879 B2 JP7309879 B2 JP 7309879B2 JP 2021532900 A JP2021532900 A JP 2021532900A JP 2021532900 A JP2021532900 A JP 2021532900A JP 7309879 B2 JP7309879 B2 JP 7309879B2
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- corrosion
- alloy
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- titanium
- titanium alloy
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- 238000005260 corrosion Methods 0.000 title claims description 109
- 230000007797 corrosion Effects 0.000 title claims description 108
- 229910001069 Ti alloy Inorganic materials 0.000 title claims description 106
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 66
- 229910045601 alloy Inorganic materials 0.000 claims description 53
- 239000000956 alloy Substances 0.000 claims description 53
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 52
- 239000010936 titanium Substances 0.000 claims description 44
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 38
- 229910052719 titanium Inorganic materials 0.000 claims description 38
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 35
- 238000009835 boiling Methods 0.000 claims description 33
- 238000010998 test method Methods 0.000 claims description 31
- 229910052750 molybdenum Inorganic materials 0.000 claims description 27
- 238000002844 melting Methods 0.000 claims description 22
- 230000008018 melting Effects 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 229910052759 nickel Inorganic materials 0.000 claims description 21
- 239000012535 impurity Substances 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 229910052742 iron Inorganic materials 0.000 claims description 18
- 229910052726 zirconium Inorganic materials 0.000 claims description 17
- 230000009467 reduction Effects 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 238000005242 forging Methods 0.000 claims description 3
- 238000010309 melting process Methods 0.000 claims description 2
- 238000010313 vacuum arc remelting Methods 0.000 claims description 2
- 238000007792 addition Methods 0.000 description 20
- 239000000203 mixture Substances 0.000 description 17
- 238000004519 manufacturing process Methods 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- 238000005275 alloying Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 239000011651 chromium Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- 238000005336 cracking Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000010955 niobium Substances 0.000 description 6
- 229910001040 Beta-titanium Inorganic materials 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000010894 electron beam technology Methods 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 230000035882 stress Effects 0.000 description 5
- 229910010977 Ti—Pd Inorganic materials 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000001627 detrimental effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- -1 platinum group metals Chemical class 0.000 description 4
- 229910000883 Ti6Al4V Inorganic materials 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000013456 study Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001309 Ferromolybdenum Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910011214 Ti—Mo Inorganic materials 0.000 description 1
- 229910001093 Zr alloy Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- KHYBPSFKEHXSLX-UHFFFAOYSA-N iminotitanium Chemical compound [Ti]=N KHYBPSFKEHXSLX-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000006101 laboratory sample Substances 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000028161 membrane depolarization Effects 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 229910001285 shape-memory alloy Inorganic materials 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/183—High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Heat Treatment Of Steel (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862777213P | 2018-12-09 | 2018-12-09 | |
| US62/777,213 | 2018-12-09 | ||
| PCT/US2019/065213 WO2020123372A1 (en) | 2018-12-09 | 2019-12-09 | Titanium alloys having improved corrosion resistance, strength, ductility, and toughness |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| JP2022513757A JP2022513757A (ja) | 2022-02-09 |
| JPWO2020123372A5 JPWO2020123372A5 (https=) | 2022-08-26 |
| JP2022513757A5 JP2022513757A5 (https=) | 2022-08-26 |
| JP7309879B2 true JP7309879B2 (ja) | 2023-07-18 |
Family
ID=69160260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021532900A Active JP7309879B2 (ja) | 2018-12-09 | 2019-12-09 | 改善した耐食性、強度、延性及び靭性を有するチタン合金 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11352687B2 (https=) |
| EP (1) | EP3891313B1 (https=) |
| JP (1) | JP7309879B2 (https=) |
| CN (1) | CN113412339B (https=) |
| CA (1) | CA3122511C (https=) |
| WO (1) | WO2020123372A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881859B (zh) * | 2020-06-19 | 2022-11-11 | 新疆大学 | 一种中小规格钛及钛合金薄壁管材的制备方法 |
| CN115896540B (zh) * | 2022-11-16 | 2024-01-30 | 哈尔滨工业大学 | 一种Ti-Mo-Ni-Al-Zr耐腐蚀钛合金及其制备方法 |
| CN116815014B (zh) * | 2023-05-30 | 2025-10-31 | 西安交通大学 | 一种高氧耐受性的超高强塑Ti-Cr-Zr-Al-O钛合金及制备方法 |
| CN117802351B (zh) * | 2024-02-29 | 2024-06-04 | 成都先进金属材料产业技术研究院股份有限公司 | 高强耐蚀钛合金管材及其制备方法 |
| CN118345410A (zh) * | 2024-05-09 | 2024-07-16 | 鞍钢集团北京研究院有限公司 | 一种高点蚀电位和低电阻率钛合金双极板及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19533743A1 (de) | 1995-09-12 | 1997-03-13 | Vladislav Prof Tetjuchine | Titanlegierung |
| US20040058190A1 (en) | 2002-09-25 | 2004-03-25 | Grauman James S. | Fabricated titanium article having improved corrosion resistance |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4750542A (en) | 1987-03-06 | 1988-06-14 | A. Johnson Metals Corporation | Electron beam cold hearth refining |
| US4823358A (en) | 1988-07-28 | 1989-04-18 | 501 Axel Johnson Metals, Inc. | High capacity electron beam cold hearth furnace |
| US4857269A (en) * | 1988-09-09 | 1989-08-15 | Pfizer Hospital Products Group Inc. | High strength, low modulus, ductile, biopcompatible titanium alloy |
| US4936375A (en) | 1988-10-13 | 1990-06-26 | Axel Johnson Metals, Inc. | Continuous casting of ingots |
| US5358686A (en) | 1993-02-17 | 1994-10-25 | Parris Warren M | Titanium alloy containing Al, V, Mo, Fe, and oxygen for plate applications |
| JP2000144287A (ja) * | 1998-11-06 | 2000-05-26 | Daido Steel Co Ltd | 耐摩耗性に優れた生体用チタン合金 |
| US6607846B1 (en) * | 2002-09-25 | 2003-08-19 | Titanium Metals Corporation | Titanium article having improved corrosion resistance |
| RU2256713C1 (ru) * | 2004-06-18 | 2005-07-20 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") | Сплав на основе титана и изделие, выполненное из него |
| RU2391426C1 (ru) * | 2009-01-11 | 2010-06-10 | Федеральное Государственное Унитарное Предприятие "Центральный Научно-Исследовательский Институт Конструкционных Материалов "Прометей" (Фгуп "Цнии Км "Прометей") | Титановый сплав для силовых крепежных элементов |
| CN102421549B (zh) | 2009-03-27 | 2014-07-16 | 钛金属公司 | 用于半连续铸造中空锭块的方法和装置及由此所得的产品 |
| RU2425164C1 (ru) * | 2010-01-20 | 2011-07-27 | Открытое Акционерное Общество "Корпорация Всмпо-Ависма" | Вторичный титановый сплав и способ его изготовления |
| DE102014014683A1 (de) * | 2014-10-02 | 2016-04-07 | VDM Metals GmbH | Titanlegierung |
| CN108467971A (zh) * | 2018-06-08 | 2018-08-31 | 南京赛达机械制造有限公司 | 一种耐腐蚀钛合金航空发动机叶片 |
-
2019
- 2019-12-09 EP EP19836232.9A patent/EP3891313B1/en active Active
- 2019-12-09 US US16/707,671 patent/US11352687B2/en active Active
- 2019-12-09 CN CN201980091503.5A patent/CN113412339B/zh active Active
- 2019-12-09 CA CA3122511A patent/CA3122511C/en active Active
- 2019-12-09 JP JP2021532900A patent/JP7309879B2/ja active Active
- 2019-12-09 WO PCT/US2019/065213 patent/WO2020123372A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19533743A1 (de) | 1995-09-12 | 1997-03-13 | Vladislav Prof Tetjuchine | Titanlegierung |
| US20040058190A1 (en) | 2002-09-25 | 2004-03-25 | Grauman James S. | Fabricated titanium article having improved corrosion resistance |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2022513757A (ja) | 2022-02-09 |
| EP3891313A1 (en) | 2021-10-13 |
| CN113412339B (zh) | 2023-04-28 |
| US20200181749A1 (en) | 2020-06-11 |
| CN113412339A (zh) | 2021-09-17 |
| CA3122511C (en) | 2023-09-05 |
| CA3122511A1 (en) | 2020-06-18 |
| WO2020123372A1 (en) | 2020-06-18 |
| US11352687B2 (en) | 2022-06-07 |
| EP3891313B1 (en) | 2022-08-17 |
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