JP7284251B2 - 光硬化性立体造形用組成物、立体造形物及び立体造形物の製造方法 - Google Patents

光硬化性立体造形用組成物、立体造形物及び立体造形物の製造方法 Download PDF

Info

Publication number
JP7284251B2
JP7284251B2 JP2021509589A JP2021509589A JP7284251B2 JP 7284251 B2 JP7284251 B2 JP 7284251B2 JP 2021509589 A JP2021509589 A JP 2021509589A JP 2021509589 A JP2021509589 A JP 2021509589A JP 7284251 B2 JP7284251 B2 JP 7284251B2
Authority
JP
Japan
Prior art keywords
meth
acrylate
mass
acrylic acid
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2021509589A
Other languages
English (en)
Japanese (ja)
Other versions
JPWO2020196753A5 (https=
JPWO2020196753A1 (https=
Inventor
高士 堂本
慶次 後藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denka Co Ltd
Original Assignee
Denka Co Ltd
Denki Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denka Co Ltd, Denki Kagaku Kogyo KK filed Critical Denka Co Ltd
Publication of JPWO2020196753A1 publication Critical patent/JPWO2020196753A1/ja
Publication of JPWO2020196753A5 publication Critical patent/JPWO2020196753A5/ja
Application granted granted Critical
Publication of JP7284251B2 publication Critical patent/JP7284251B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1811C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/48Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10Esters
    • C08F222/1006Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10Esters
    • C08F222/1006Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/106Esters of polycondensation macromers
    • C08F222/1065Esters of polycondensation macromers of alcohol terminated (poly)urethanes, e.g. urethane(meth)acrylates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06Polymers provided for in subclass C08G
    • C08F290/067Polyurethanes; Polyureas
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062Copolymers with monomers not covered by C09D133/06
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0002Condition, form or state of moulded material or of the material to be shaped monomers or prepolymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Optics & Photonics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
JP2021509589A 2019-03-28 2020-03-26 光硬化性立体造形用組成物、立体造形物及び立体造形物の製造方法 Active JP7284251B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2019062349 2019-03-28
JP2019062349 2019-03-28
PCT/JP2020/013668 WO2020196753A1 (ja) 2019-03-28 2020-03-26 光硬化性立体造形用組成物、立体造形物及び立体造形物の製造方法

Publications (3)

Publication Number Publication Date
JPWO2020196753A1 JPWO2020196753A1 (https=) 2020-10-01
JPWO2020196753A5 JPWO2020196753A5 (https=) 2023-01-04
JP7284251B2 true JP7284251B2 (ja) 2023-05-30

Family

ID=72611503

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2021509589A Active JP7284251B2 (ja) 2019-03-28 2020-03-26 光硬化性立体造形用組成物、立体造形物及び立体造形物の製造方法

Country Status (5)

Country Link
US (1) US11787951B2 (https=)
EP (1) EP3882028B1 (https=)
JP (1) JP7284251B2 (https=)
CN (1) CN115989146A (https=)
WO (1) WO2020196753A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11008561B2 (en) 2014-06-30 2021-05-18 Bioverativ Therapeutics Inc. Optimized factor IX gene
KR20220097891A (ko) 2019-09-30 2022-07-08 바이오버라티브 테라퓨틱스 인크. 렌티바이러스 벡터 제형
US12291648B2 (en) * 2020-09-11 2025-05-06 Canon Kabushiki Kaisha Energy ray-curable resin compositions and its cured products
TW202337677A (zh) * 2022-03-29 2023-10-01 日商Dic股份有限公司 硬化性樹脂組成物、硬化物及立體造形物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014159556A (ja) 2013-01-22 2014-09-04 Jnc Corp 光学的立体造形用光硬化性組成物および造形物の製造方法
WO2017018525A1 (ja) 2015-07-29 2017-02-02 株式会社カネカ 光硬化型3次元立体造形物の製造方法
WO2017033427A1 (ja) 2015-08-26 2017-03-02 ナガセケムテックス株式会社 パターニング材料、パターニング方法、およびパターニング装置
WO2018235943A1 (ja) 2017-06-23 2018-12-27 国立大学法人九州大学 無機成形体製造用組成物、無機成形体の製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1030002A (ja) * 1996-07-16 1998-02-03 Olympus Optical Co Ltd 光硬化性流動樹脂組成物
EP2436510A1 (en) * 2010-10-04 2012-04-04 3D Systems, Inc. System and resin for rapid prototyping
JP5738367B2 (ja) * 2013-08-19 2015-06-24 シーメット株式会社 黄色度の低い光学的立体造形物
JP6188495B2 (ja) * 2013-08-30 2017-08-30 富士フイルム株式会社 積層体及びその応用
JP6679234B2 (ja) * 2015-07-29 2020-04-15 マクセルホールディングス株式会社 モデル材用樹脂組成物、サポート材用樹脂組成物、光造形品、および、光造形品の製造方法
JP6828273B2 (ja) 2016-05-25 2021-02-10 Dic株式会社 光造形用硬化性組成物、光硬化物、及び成形品の製造方法
US10259956B2 (en) * 2016-10-11 2019-04-16 Xerox Corporation Curable ink composition
EP3658598B1 (en) * 2017-07-28 2022-11-16 Nikon Corporation Photocurable composition and method of manufacturing three-dimensional object

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014159556A (ja) 2013-01-22 2014-09-04 Jnc Corp 光学的立体造形用光硬化性組成物および造形物の製造方法
WO2017018525A1 (ja) 2015-07-29 2017-02-02 株式会社カネカ 光硬化型3次元立体造形物の製造方法
WO2017033427A1 (ja) 2015-08-26 2017-03-02 ナガセケムテックス株式会社 パターニング材料、パターニング方法、およびパターニング装置
WO2018235943A1 (ja) 2017-06-23 2018-12-27 国立大学法人九州大学 無機成形体製造用組成物、無機成形体の製造方法

Also Published As

Publication number Publication date
WO2020196753A1 (ja) 2020-10-01
EP3882028B1 (en) 2023-08-23
US20220073753A1 (en) 2022-03-10
US11787951B2 (en) 2023-10-17
CN115989146A (zh) 2023-04-18
EP3882028A4 (en) 2022-03-02
EP3882028A1 (en) 2021-09-22
JPWO2020196753A1 (https=) 2020-10-01

Similar Documents

Publication Publication Date Title
JP7284251B2 (ja) 光硬化性立体造形用組成物、立体造形物及び立体造形物の製造方法
JP6688941B2 (ja) 光造形用硬化性組成物、消失模型及び立体造形物の製造方法
JP6275413B2 (ja) 光造形用(メタ)アクリル系樹脂組成物及び支持体の製造方法
JP6081401B2 (ja) サポート部形成用の光硬化性樹脂組成物
JP4282873B2 (ja) 光造形用硬化性組成物および成形品
WO2018105463A1 (ja) 光学的立体造形用光硬化性樹脂組成物
JP2008189782A (ja) 面露光による光学的立体造形用樹脂組成物
JP2016020474A (ja) インクジェット光造形法における光造形品形成用モデル材及び光造形品の製造方法
JP7547894B2 (ja) 光造形用ポリマー組成物
CN105820552A (zh) 三维造型用支持材料、三维造型用组合物组、三维造型装置及制备三维成型体的方法
JP2022099528A (ja) 活性エネルギー線硬化性樹脂組成物
JP2731363B2 (ja) 光学的立体造形用樹脂組成物
JP3705511B2 (ja) 光学的立体造形用の光硬化性樹脂組成物
JP6812116B2 (ja) モデル材用樹脂組成物、および、光造形品の製造方法
JP7289676B2 (ja) 立体造形用の硬化性樹脂組成物
JP7199611B2 (ja) 光硬化性樹脂組成物および三次元光造形物
JP2020100790A (ja) 造形材、造形物、及び三次元造形装置
JP4315507B2 (ja) 耐熱性に優れる光硬化性樹脂組成物
JP7500951B2 (ja) 造形物製造用のインク、三次元造形物の製造方法、及び三次元造形装置
JP2004238597A (ja) 耐熱性に優れる光硬化性樹脂組成物
JP7429783B2 (ja) 光硬化性組成物、立体造形物、及び歯科用製品
TW202248232A (zh) 光固化性樹脂組成物、光固化物以及立體造型物的製造方法
JP2000143740A (ja) 光硬化性樹脂組成物
JP3705508B2 (ja) 耐熱性に優れる光硬化性樹脂組成物
JP7302133B2 (ja) 光学材料用光硬化性組成物、光学材料及びレンズ

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20221221

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20221221

A871 Explanation of circumstances concerning accelerated examination

Free format text: JAPANESE INTERMEDIATE CODE: A871

Effective date: 20221221

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20230131

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20230323

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20230509

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20230518

R150 Certificate of patent or registration of utility model

Ref document number: 7284251

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150