JP7260247B2 - 多段ポリマーを含む組成物、その調製方法及びその使用 - Google Patents
多段ポリマーを含む組成物、その調製方法及びその使用 Download PDFInfo
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- JP7260247B2 JP7260247B2 JP2017534209A JP2017534209A JP7260247B2 JP 7260247 B2 JP7260247 B2 JP 7260247B2 JP 2017534209 A JP2017534209 A JP 2017534209A JP 2017534209 A JP2017534209 A JP 2017534209A JP 7260247 B2 JP7260247 B2 JP 7260247B2
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J2451/04—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to rubbers
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FR1463306 | 2014-12-24 | ||
PCT/EP2015/081159 WO2016102666A1 (fr) | 2014-12-24 | 2015-12-23 | Composition comprenant un polymère à multiple couches, son procédé de préparation et son utilisation |
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JP2018500441A JP2018500441A (ja) | 2018-01-11 |
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FR3031106B1 (fr) * | 2014-12-24 | 2017-02-03 | Arkema France | Composition de polymeres a phases multiples, son procede de preparation, son utilisation et composition la comprenant |
WO2018033445A1 (fr) * | 2016-08-17 | 2018-02-22 | Ineos Styrolution Group Gmbh | Copolymères greffés transparents à base de phases molles d'acrylate |
FR3068979B1 (fr) * | 2017-07-12 | 2020-07-31 | Arkema France | Composition d'adhesif (meth)acrylique, son procede de preparation et son utilisation |
JP7217258B2 (ja) * | 2017-07-12 | 2023-02-02 | ヘクセル コンポジッツ、リミテッド | 樹脂組成物 |
FR3068980B1 (fr) * | 2017-07-12 | 2020-10-02 | Arkema France | Composition d'adhesif epoxy comprenant un polymere a etapes multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation |
FR3068977B1 (fr) * | 2017-07-12 | 2020-09-04 | Arkema France | Composition comprenant un polymere a phases multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation |
EP3652250A1 (fr) * | 2017-07-12 | 2020-05-20 | Hexcel Composites Limited | Composition de résine |
CN111936574B (zh) * | 2018-03-30 | 2023-12-29 | 株式会社钟化 | 相对于热固化性基质树脂的分散性得以改善了的粉粒体 |
IL279630B1 (en) | 2018-06-26 | 2024-10-01 | Arkema France | Curable preparations based on multiphase polymers |
GB2575056A (en) * | 2018-06-27 | 2020-01-01 | Hexcel Composites Ltd | Curable compositions comprising filled multistage polymers |
JP7391043B2 (ja) * | 2018-12-27 | 2023-12-04 | 株式会社カネカ | 樹脂組成物およびその利用 |
WO2020196922A1 (fr) * | 2019-03-28 | 2020-10-01 | 株式会社カネカ | Matière particulaire et son utilisation |
FR3097866B1 (fr) | 2019-06-26 | 2022-01-21 | Arkema France | Composition comprenant un composé renfermant deux groupes polymérisables, un polymère à étages multiples et un polymère thermoplastique, son procédé de préparation, son utilisation et article la comprenant |
US20220273547A1 (en) | 2019-07-31 | 2022-09-01 | Arkema France | Nail coatings based on photocurable compositions |
CN114341233A (zh) | 2019-09-27 | 2022-04-12 | 株式会社钟化 | 粉粒体及粉粒体的制造方法 |
FR3103817B1 (fr) | 2019-11-29 | 2021-12-17 | Arkema France | Composition comprenant un polymère à étapes multiples et un polymère (méth)acrylique, son procédé de préparation et son utilisation |
EP3838936A1 (fr) * | 2019-12-19 | 2021-06-23 | Arkema France | Compositions durcissables comprenant des polymères à plusieurs étages |
FR3131325A1 (fr) | 2021-12-23 | 2023-06-30 | Arkema France | Polymère à étapes multiples, son procédé de préparation, composition lecomprenant et son utilisation |
EP4393963A1 (fr) * | 2022-12-31 | 2024-07-03 | Arkema France | Procédés de préparation de compositions de particules polymères à plusieurs étages et formulations durcissables pour impression tridimensionnelle |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005078013A1 (fr) | 2004-02-16 | 2005-08-25 | Mitsubishi Rayon Co., Ltd. | Modificateur de résine, composition de résine l'utilisant et article ainsi formé |
JP2006089740A (ja) | 2004-09-15 | 2006-04-06 | Rohm & Haas Co | 光沢低下ポリマー組成物 |
JP2010072111A (ja) | 2008-09-16 | 2010-04-02 | Dainippon Printing Co Ltd | 偏光子保護用光学フィルム、偏光板、及び画像表示装置 |
JP2012062463A (ja) | 2010-08-20 | 2012-03-29 | Techno Polymer Co Ltd | 熱可塑性樹脂組成物及び成形品 |
JP2012532234A (ja) | 2009-07-07 | 2012-12-13 | エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツング | プラスチック成形組成物、成形品及び製造法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1117763A (en) * | 1964-06-19 | 1968-06-26 | Monsanto Co | Hydroxylated graft copolymer compositions |
KR900007766B1 (ko) | 1985-06-26 | 1990-10-19 | 더 다우 케미칼 캄파니 | 고무-개질 에폭시 화합물 |
JPH05262953A (ja) * | 1992-03-19 | 1993-10-12 | Mitsubishi Rayon Co Ltd | ゴム含有グラフト共重合体粒子の製造方法 |
DE19746006A1 (de) | 1997-10-20 | 1999-04-22 | Agomer Gmbh | Schäumbare Polyvinylhalogenidharzmassen, Verwendung von Polymerisaten darin als Verarbeitungshilfsmittel, daraus hergestellte Formteile |
ES2412804T3 (es) | 2003-06-09 | 2013-07-12 | Kaneka Corporation | Procedimiento para producir resina epoxi modificada |
KR100528771B1 (ko) * | 2003-08-02 | 2005-11-15 | 주식회사 엘지화학 | 아크릴-실리콘계 복합 충격보강제, 이의 제조방법 및 이를함유하는 염화비닐 수지 조성물 |
AU2004274270A1 (en) | 2003-09-18 | 2005-03-31 | Kaneka Corporation | Process for producing rubbery polymer particle and process for producing resin composition containing the same |
MX2007008855A (es) * | 2003-10-18 | 2008-03-13 | Roehm Gmbh | Masas de pieza moldeada de poli (met) acrilato resistentes a impactos con alta estabilidad termica. |
JP4839092B2 (ja) * | 2006-01-30 | 2011-12-14 | 矢崎総業株式会社 | 電線マーキング用インクジェットインク |
WO2008105189A1 (fr) | 2007-02-28 | 2008-09-04 | Kaneka Corporation | Composition de résine thermodurcissable, dans laquelle sont dispersées des particules de polymère caoutchouteux, et son procédé de production |
PL2189502T3 (pl) * | 2007-09-11 | 2013-09-30 | Kaneka Corp | Płynne kompozycje żywicy oraz produkt utwardzony, w którym wykorzystuje się płynną kompozycję żywicy |
EP2265665B1 (fr) | 2008-04-07 | 2021-10-20 | Arkema Inc. | Modificateurs d'impact mbs fonctionnels pour résines industrielles |
FR2934866B1 (fr) | 2008-08-05 | 2012-12-28 | Arkema France | Particules de type "coeur-ecorce" comprenant une ecorce a base de monomeres hydrophiles. |
FR2964970B1 (fr) * | 2010-09-22 | 2013-11-01 | Arkema France | Nouveaux modifiants chocs et compositions thermoplastiques renforcees choc |
DE102011003317A1 (de) * | 2011-01-28 | 2012-08-02 | Evonik Röhm Gmbh | Impact-modifiziertes Reaktionsharz |
JP2018180248A (ja) * | 2017-04-12 | 2018-11-15 | 日油株式会社 | 防眩性ハードコート用樹脂組成物、並びにこれを利用したインサート成型用防眩フィルム、樹脂成形品及び画像表示装置 |
-
2014
- 2014-12-24 FR FR1463306A patent/FR3031108B1/fr active Active
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- 2015-12-23 SG SG11201705040QA patent/SG11201705040QA/en unknown
- 2015-12-23 RU RU2017126213A patent/RU2703621C2/ru active
- 2015-12-23 CN CN201580076849.XA patent/CN107250260A/zh active Pending
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- 2015-12-23 EP EP15817865.7A patent/EP3237500B1/fr active Active
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- 2015-12-23 WO PCT/EP2015/081159 patent/WO2016102666A1/fr active Application Filing
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005078013A1 (fr) | 2004-02-16 | 2005-08-25 | Mitsubishi Rayon Co., Ltd. | Modificateur de résine, composition de résine l'utilisant et article ainsi formé |
JP2006089740A (ja) | 2004-09-15 | 2006-04-06 | Rohm & Haas Co | 光沢低下ポリマー組成物 |
JP2010072111A (ja) | 2008-09-16 | 2010-04-02 | Dainippon Printing Co Ltd | 偏光子保護用光学フィルム、偏光板、及び画像表示装置 |
JP2012532234A (ja) | 2009-07-07 | 2012-12-13 | エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツング | プラスチック成形組成物、成形品及び製造法 |
JP2012062463A (ja) | 2010-08-20 | 2012-03-29 | Techno Polymer Co Ltd | 熱可塑性樹脂組成物及び成形品 |
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BR112017013691B1 (pt) | 2022-05-31 |
MY185267A (en) | 2021-04-30 |
KR102505144B1 (ko) | 2023-02-28 |
EP3237500A1 (fr) | 2017-11-01 |
FR3031108B1 (fr) | 2018-08-17 |
CN107250260A (zh) | 2017-10-13 |
RU2017126213A3 (fr) | 2019-05-08 |
KR20170098913A (ko) | 2017-08-30 |
JP2018500441A (ja) | 2018-01-11 |
WO2016102666A1 (fr) | 2016-06-30 |
SG11201705040QA (en) | 2017-07-28 |
BR112017013691A2 (pt) | 2018-03-13 |
EP3237500B1 (fr) | 2022-01-26 |
FR3031108A1 (fr) | 2016-07-01 |
RU2017126213A (ru) | 2019-01-24 |
RU2703621C2 (ru) | 2019-10-21 |
CN118048006A (zh) | 2024-05-17 |
US20180002520A1 (en) | 2018-01-04 |
US10513603B2 (en) | 2019-12-24 |
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