JP7243941B2 - 積層体及び靴底 - Google Patents
積層体及び靴底 Download PDFInfo
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- JP7243941B2 JP7243941B2 JP2022562513A JP2022562513A JP7243941B2 JP 7243941 B2 JP7243941 B2 JP 7243941B2 JP 2022562513 A JP2022562513 A JP 2022562513A JP 2022562513 A JP2022562513 A JP 2022562513A JP 7243941 B2 JP7243941 B2 JP 7243941B2
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- 150000003839 salts Chemical class 0.000 claims description 25
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
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- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 3
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- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
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- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
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- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 3
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- VRFOKYHDLYBVAL-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCN1C=C[N+](C)=C1 VRFOKYHDLYBVAL-UHFFFAOYSA-M 0.000 description 2
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- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 2
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 2
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 2
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 2
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- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 description 1
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- 229960000380 propiolactone Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- TYRGSDXYMNTMML-UHFFFAOYSA-N propyl hydrogen sulfate Chemical compound CCCOS(O)(=O)=O TYRGSDXYMNTMML-UHFFFAOYSA-N 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- 229940100515 sorbitan Drugs 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- UZZYXUGECOQHPU-UHFFFAOYSA-N sulfuric acid monooctyl ester Natural products CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- 125000005040 tridecenyl group Chemical group C(=CCCCCCCCCCCC)* 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 125000005065 undecenyl group Chemical group C(=CCCCCCCCCC)* 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/12—Soles with several layers of different materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
- B32B2255/102—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer synthetic resin or rubber layer being a foamed layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
- B32B2437/02—Gloves, shoes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
前記第一のウレタン発泡層は、ウレタン樹脂の発泡体から構成される。前記ウレタン樹脂としては、ポリエーテル系ウレタン樹脂、ポリエステル系ウレタン樹脂、ポリカーボネート系ウレタン樹脂等が挙げられる。本発明において、例えば、ポリエステル系ウレタン樹脂とは、分子鎖中に、ポリエステルに由来する単位を有するウレタン樹脂を表すものとする。
プラスチック-ポリウレタン原料芳香族イソシアネート試験方法第一部:イソシアネート基含有率の求め方に準拠して測定することができる。
前記第二のウレタン発泡層は、ウレタン樹脂の発泡体から構成される。前記ウレタン樹脂としては、ポリエーテル系ウレタン樹脂、ポリエステル系ウレタン樹脂、ポリカーボネート系ウレタン樹脂等が挙げられる。本発明において、例えば、ポリエステル系ウレタン樹脂とは、分子鎖中に、ポリエステルに由来する単位を有するウレタン樹脂を表すものとする。
法(成形機の吐出口に直結したクローズドモールドに混合発泡液を直接射出する)等により成形することができる。
反応容器に、イソシアネート成分として、4,4’-ジフェニルメタンジイソシアネート(以下「4,4’MDI」と略称。商標:ミリオネート MT、日本ポリウレタン工業株式会社製)543部と、カルボジイミド変性MDI(商標:コスモネート LL、三井化学ポリウレタン株式会社製)28.6部を仕込み、攪拌を開始した。
イソシアネート基反応性化合物(B1)としてポリオールb(2M1,3PD/1,4BGとAAから合成された水酸基価74.8のポリエステルポリオール。2M1,3PD/1,4BG=6/4モル比のもの)98.0部と、EG7.6部、発泡剤として水(C)0.17部、触媒(D)としてトリエチレンジアミン(TEDA)1.00部、N-エチル-N,N-ジメチル-N-ドデシルアンモニウムエチル硫酸塩7.2部、トリフルオロメタンスルホン酸リチウム1.2部を配合し、充分に撹拌、混合して、硬化剤(Y11)を調製した。
ポリオール、帯電防止剤の組成を表1に示すように変更したこと以外は調製例2と同様にして、硬化剤(Y12)~(Y15)を得た。
イソシアネート基反応性化合物(B2)としてポリオールc(EG/1,4BGとAAから合成された水酸基価56のポリエステルポリオール。EG/1,4BG=5/5モル比のもの。)96.00部と、EG8.10部、発泡剤として水(C)0.35部、触媒(D)としてトリエチレンジアミン(TEDA)0.80部、N-エチル-N,N-ジメチル-N-ドデシルアンモニウムエチル硫酸塩4.8部、トリフルオロメタンスルホン酸リチウム0.80部を配合し、充分に撹拌、混合して、硬化剤(Y21)を調製した。
ポリオール、帯電防止剤の組成を表2に示すように変更したこと以外は調製例7と同様にして、硬化剤(Y22)~(Y25)を調製した。
≪2液硬化型発泡ポリウレタン構成体の製造≫
構造体を作成する室内を室温30℃、相対湿度80%に調整した。次いで、混合容器に前記主剤(X)と前記硬化剤(Y11)を、(X)/(Y11)=100/111質量比で配合し攪拌、混合して、本発明の2液硬化型発泡ポリウレタン樹脂組成物(A-1)を調整して、40℃に予め加熱した金型(100mm×200mm×8mm)中に160gを注入し、直ちに金型の蓋をした後、40℃で2.5分間放置し、第1層目を作成した。金型から取り出し、その後、(100mm×200mm×20mm)の金型内に第1層目を入れた。
1層目、2層目の樹脂組成物の組成を、それぞれ表3に示すように変更したこと以外は、実施例1と同様にして、積層体を得た。
≪2液硬化型発泡ポリウレタン構成体の製造≫
構造体を作成する室内を室温30℃、相対湿度80%に調整した。混合容器に前記主剤(X)と前記硬化剤(Y13)を、(X)/(Y13)=100/150質量比で配合し攪拌、混合して、本発明の2液硬化型発泡ポリウレタン樹脂組成物(A-3)を調整して、40℃に予め加熱した金型(100mm×200mm×8mm)中に160gを注入し、直ちに金型の蓋をした後、40℃で2.5分間放置し、第1層目を作成した。金型から取り出し、その後、(100mm×200mm×20mm)の金型内に第1層目を入れた。
1層目、2層目の樹脂組成物の組成を、それぞれ表3に示すように変更したこと以外は、比較例1と同様にして、積層体を得た。
Claims (6)
- 第一のウレタン発泡層と、第二のウレタン発泡層とを有し、
前記第一のウレタン発泡層の密度が、0.8g/cm3以上1.2g/cm3以下であり、
前記第二のウレタン発泡層の密度が、0.3g/cm3以上0.7g/cm3以下であり、
前記第二のウレタン発泡層において、前記第一のウレタン発泡層との界面から200μmを超える範囲における発泡セルの平均セル径をa(μm)、前記第一のウレタン発泡層との界面から200μm以下の範囲における発泡セルの平均セル径をb(μm)としたとき、b/aが、1.2未満であることを特徴とする積層体。 - 前記第一のウレタン発泡層が、帯電防止剤(E)として、第4級アンモニウム塩(E1)と、有機金属塩(E2)とを含むものであり、前記第4級アンモニウム塩(E1)と前記有機金属塩(E2)との質量比(E1/E2)が、1/1以上10/1以下である請求項1記載の積層体。
- 前記第一のウレタン発泡層における静電防止剤(E)の含有率が、4.0質量%未満である請求項1又は2記載の積層体。
- 前記第二のウレタン発泡層が、帯電防止剤(E’)として、第4級アンモニウム塩(E1’)と、有機金属塩(E2’’)とを含むものであり、前記第4級アンモニウム塩(E1’)と前記有機金属塩(E2’)との質量比(E1’/E2’)が、1/1以上10/1以下である請求項1~3のいずれか1項記載の積層体。
- 前記第二のウレタン発泡層における帯電防止剤(E’)の含有率が、3.0質量%以下である請求項1~4のいずれか1項記載の積層体。
- 請求項1~5のいずれか1項記載の積層体を有することを特徴とする靴底。
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PCT/JP2022/004163 WO2022219891A1 (ja) | 2021-04-13 | 2022-02-03 | 積層体及び靴底 |
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WO2005012429A1 (ja) | 2003-07-31 | 2005-02-10 | Dainippon Ink And Chemicals, Inc. | ポリウレタン樹脂成形体及びその製造方法 |
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