JP7207300B2 - 多孔性ポリオレフィンフィルム - Google Patents

多孔性ポリオレフィンフィルム Download PDF

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JP7207300B2
JP7207300B2 JP2019520754A JP2019520754A JP7207300B2 JP 7207300 B2 JP7207300 B2 JP 7207300B2 JP 2019520754 A JP2019520754 A JP 2019520754A JP 2019520754 A JP2019520754 A JP 2019520754A JP 7207300 B2 JP7207300 B2 JP 7207300B2
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melting point
film
temperature
polyolefin
polyolefin film
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JPWO2019163935A1 (ja
JPWO2019163935A5 (https=
Inventor
直樹 豊田
遼 下川床
毅 石原
琢也 久万
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Toray Industries Inc
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Toray Industries Inc
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/26Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0018Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C08J9/286Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/52Separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/02Diaphragms; Separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/403Manufacturing processes of separators, membranes or diaphragms
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/414Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/417Polyolefins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/449Separators, membranes or diaphragms characterised by the material having a layered structure
    • H01M50/457Separators, membranes or diaphragms characterised by the material having a layered structure comprising three or more layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/491Porosity
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/489Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
    • H01M50/494Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • B29K2023/0608PE, i.e. polyethylene characterised by its density
    • B29K2023/065HDPE, i.e. high density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • C08J2205/044Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08J2323/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/60Other road transportation technologies with climate change mitigation effect
    • Y02T10/70Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Cell Separators (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
JP2019520754A 2018-02-23 2019-02-22 多孔性ポリオレフィンフィルム Active JP7207300B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2018030549 2018-02-23
JP2018030549 2018-02-23
JP2018030550 2018-02-23
JP2018030550 2018-02-23
PCT/JP2019/006736 WO2019163935A1 (ja) 2018-02-23 2019-02-22 多孔性ポリオレフィンフィルム

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JPWO2019163935A1 JPWO2019163935A1 (ja) 2020-12-17
JPWO2019163935A5 JPWO2019163935A5 (https=) 2022-02-25
JP7207300B2 true JP7207300B2 (ja) 2023-01-18

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Country Status (7)

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US (1) US20210115206A1 (https=)
EP (1) EP3757156A4 (https=)
JP (1) JP7207300B2 (https=)
KR (1) KR20200123407A (https=)
CN (1) CN111684002B (https=)
TW (1) TW201940528A (https=)
WO (1) WO2019163935A1 (https=)

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KR102295069B1 (ko) * 2018-08-17 2021-08-26 주식회사 엘지화학 전기화학소자용 분리막 및 이의 제조방법
WO2020242902A1 (en) * 2019-05-24 2020-12-03 Celgard, Llc Functional coating for separator
US20220389203A1 (en) * 2019-10-08 2022-12-08 Asahi Kasei Kabushiki Kaisha Polyolefin Microporous Membrane
CA3152938A1 (en) 2019-10-23 2021-04-29 Nova Chemicals Corporation Biaxially oriented mdpe film
WO2021222716A1 (en) * 2020-05-01 2021-11-04 Celanese International Corporation Copolymer having a reduced shutdown temperature and articles made with same
CN115668619A (zh) * 2020-05-28 2023-01-31 旭化成株式会社 蓄电设备用分隔件
CA3102574A1 (en) 2020-06-29 2021-12-29 Nova Chemicals Corporation Ethylene copolymer for biaxial orientation
US11814508B2 (en) 2020-08-24 2023-11-14 Celanese International Corporation Gel extruded articles made from high density polyethylene with narrow molecular weight distribution
JP7721997B2 (ja) * 2020-09-14 2025-08-13 東レ株式会社 ポリオレフィン微多孔膜及び電池セパレータ
KR20230160224A (ko) * 2021-03-23 2023-11-23 도레이 카부시키가이샤 폴리올레핀 미다공막, 전지용 세퍼레이터 및 이차전지
WO2024011364A1 (zh) * 2022-07-11 2024-01-18 宁德时代新能源科技股份有限公司 聚烯烃基膜及其制备方法、隔膜、二次电池及用电装置
KR102756695B1 (ko) * 2023-08-25 2025-01-21 한국화학연구원 고체 고분자 전해질의 함침에 사용되는 다공성 지지체, 이를 포함하는 이차전지 및 이의 제조방법
JP7718598B1 (ja) * 2023-09-27 2025-08-05 東レ株式会社 ポリオレフィン微多孔膜、電池用セパレータおよびリチウムイオン二次電池

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WO2002092677A1 (fr) 2001-05-17 2002-11-21 Asahi Kasei Kabushiki Kaisha Film polyolefinique microporeux
JP2005343957A (ja) 2004-06-01 2005-12-15 Tonen Chem Corp ポリエチレン微多孔膜の製造方法並びにその微多孔膜及び用途
WO2006025323A1 (ja) 2004-08-30 2006-03-09 Asahi Kasei Chemicals Corporation ポリオレフィン微多孔膜及び蓄電池用セパレータ
WO2008093572A1 (ja) 2007-01-30 2008-08-07 Asahi Kasei E-Materials Corporation ポリオレフィン製微多孔膜
JP2012501357A (ja) 2008-09-02 2012-01-19 東レ東燃機能膜合同会社 微多孔性高分子膜、かかる膜の作製方法、およびそれを用いたバッテリーセパレータフィルム
JP2013517152A (ja) 2010-01-13 2013-05-16 東レバッテリーセパレータフィルム株式会社 微多孔膜、及びその製造方法及び使用方法
WO2015146579A1 (ja) 2014-03-26 2015-10-01 東レバッテリーセパレータフィルム株式会社 ポリオレフィン製積層多孔質膜、それを用いた電池用セパレータおよびポリオレフィン製積層多孔質膜の製造方法
WO2017170289A1 (ja) 2016-03-31 2017-10-05 東レ株式会社 ポリオレフィン微多孔膜及びその製造方法、電池用セパレータ並びに電池
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JP4902455B2 (ja) * 2006-08-01 2012-03-21 東レ東燃機能膜合同会社 ポリオレフィン多層微多孔膜、その製造方法、電池用セパレータ及び電池
JP5235324B2 (ja) 2007-04-20 2013-07-10 旭化成イーマテリアルズ株式会社 ポリオレフィン製微多孔膜
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JP2015208893A (ja) 2014-04-24 2015-11-24 東レバッテリーセパレータフィルム株式会社 ポリオレフィン製積層微多孔膜
JP6094711B2 (ja) * 2015-06-19 2017-03-15 宇部興産株式会社 ポリオレフィン微多孔膜、蓄電デバイス用セパレータフィルム、および蓄電デバイス
JP2017088836A (ja) * 2015-11-11 2017-05-25 有限会社ケー・イー・イー 低熱収縮性ポリオレフィン微多孔膜及びその製造法。

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WO2000049073A1 (fr) 1999-02-19 2000-08-24 Tonen Chemical Corporation Film microporeux polyoléfinique et son procédé de préparation
WO2002092677A1 (fr) 2001-05-17 2002-11-21 Asahi Kasei Kabushiki Kaisha Film polyolefinique microporeux
JP2005343957A (ja) 2004-06-01 2005-12-15 Tonen Chem Corp ポリエチレン微多孔膜の製造方法並びにその微多孔膜及び用途
WO2006025323A1 (ja) 2004-08-30 2006-03-09 Asahi Kasei Chemicals Corporation ポリオレフィン微多孔膜及び蓄電池用セパレータ
WO2008093572A1 (ja) 2007-01-30 2008-08-07 Asahi Kasei E-Materials Corporation ポリオレフィン製微多孔膜
JP2012501357A (ja) 2008-09-02 2012-01-19 東レ東燃機能膜合同会社 微多孔性高分子膜、かかる膜の作製方法、およびそれを用いたバッテリーセパレータフィルム
JP2013517152A (ja) 2010-01-13 2013-05-16 東レバッテリーセパレータフィルム株式会社 微多孔膜、及びその製造方法及び使用方法
WO2015146579A1 (ja) 2014-03-26 2015-10-01 東レバッテリーセパレータフィルム株式会社 ポリオレフィン製積層多孔質膜、それを用いた電池用セパレータおよびポリオレフィン製積層多孔質膜の製造方法
WO2017170289A1 (ja) 2016-03-31 2017-10-05 東レ株式会社 ポリオレフィン微多孔膜及びその製造方法、電池用セパレータ並びに電池
JP2019143142A (ja) 2018-02-23 2019-08-29 東レ株式会社 多孔性ポリオレフィンフィルム

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