JP7119581B2 - 樹脂含浸化粧板用化粧紙、樹脂含浸化粧紙及び樹脂含浸化粧板 - Google Patents
樹脂含浸化粧板用化粧紙、樹脂含浸化粧紙及び樹脂含浸化粧板 Download PDFInfo
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- JP7119581B2 JP7119581B2 JP2018101795A JP2018101795A JP7119581B2 JP 7119581 B2 JP7119581 B2 JP 7119581B2 JP 2018101795 A JP2018101795 A JP 2018101795A JP 2018101795 A JP2018101795 A JP 2018101795A JP 7119581 B2 JP7119581 B2 JP 7119581B2
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- resin
- impregnated decorative
- impregnated
- paper
- decorative board
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- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0002—Wallpaper or wall covering on textile basis
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Description
特許文献1に記載の樹脂含浸化粧板の製造方法では、金属板にエンボス形状を設けて、樹脂含浸化粧板の表面に凹凸模様を付与して、手触り感を付与するようになっている。また、エンボス形状の粗密度合を調整して、グロスマット表現を付与することもできる。
しかしながら、特許文献1に記載の樹脂含浸化粧板の製造方法では、付与しようとする凹凸模様毎に、金属板を用意する必要があるため、コストが増大する可能性がある。
また、本発明の他の態様の樹脂含浸化粧紙は、(a)原紙、(b)原紙の表面側に設けた絵柄模様層、(c)及び絵柄模様層の表面上又は絵柄模様層中に配置されたマイクロカプセル発泡剤を備え、(d)マイクロカプセル発泡剤は、発泡後の粒径が15μm以上250μm以下であり、(e)発泡開始温度が100℃以上220℃以下である樹脂含浸化粧板用化粧紙と、樹脂含浸化粧板用化粧紙に含浸された熱硬化性樹脂とを備えることを要旨とする。
また、本発明の他の態様の樹脂含浸化粧板は、上記した樹脂含浸化粧紙と、樹脂含浸化粧紙と一体化された基材とを備えることを要旨とする。
図1に示すように、本発明の実施形態に係る樹脂含浸化粧板1は、樹脂含浸化粧紙2と基材3との積層体に加熱加圧成型を行い、樹脂含浸化粧紙2と基材3とを一体化させてなる化粧板である。すなわち、樹脂含浸化粧板1は、基材3と、基材3の表面3a側に設けられた樹脂含浸化粧紙2と、を備えている。本発明の実施形態に係る樹脂含浸化粧板1は、例えば、建築物の床面、壁面、天井等の内装、家具、各種キャビネット等の表面装飾材料、建具の表面化粧、車両内装等に用いられる樹脂含浸化粧板である。
基材3の種類は、特に制限されるものではなく、目的とする樹脂含浸化粧板1の用途に応じて、任意の基材を用いることができる。例えば、木材単板、合板、集成材、パーティクルボード、中密度繊維板、硬質繊維板等の木質基材や、板紙、織布、不織布、樹脂含浸紙、樹脂含浸布等の繊維質基材、石膏ボード、スレート板、珪酸カルシウム板、スラグ石膏板、木毛セメント板、スラグセメント板、軽量気泡コンクリート板、ガラス繊維強化コンクリート板等の無機質基材、鋼板、真鍮板、アルミニウム板、ジュラルミン板、ステンレス板等の金属基材、アクリル樹脂板、スチロール樹脂板、ABS(Acrylonitrile butadiene styrene)樹脂板、ポリカーボネート樹脂板、ナイロン樹脂板、ポリスチレン樹脂板、ポリプロピレン樹脂板、ポリエステル樹脂板、ガラス繊維強化プラスチック板等の合成樹脂基材等或いはこれらから選ばれる2種以上の複合体又は積層体等を採用できる。
本発明の実施形態に係る樹脂含浸化粧紙2は、樹脂含浸化粧板用化粧紙4に熱硬化性樹脂5を含浸させた後、樹脂含浸化粧板用化粧紙4を乾燥させてなる化粧紙である。樹脂含浸化粧板用化粧紙4は、原紙6と、原紙6の表面6a側に設けられた絵柄模様層7と、絵柄模様層7の表面7a上に配置された発泡剤8と、を備えている。
なお、本実施形態では、発泡剤8を、絵柄模様層7の表面7a上に配置する例を示したが、他の構成を採用することもできる。例えば、絵柄模様層7中に配置してもよい。
原紙6としては、熱硬化性樹脂5の含浸が可能な吸水性のよい紙等の繊維質シート状体を用いることができる。例えば、薄葉紙、チタン紙、上質紙、晒又は未晒クラフト紙等を採用できる。特に、印刷適性と樹脂含浸適性との両面を考慮すると、チタン紙が最も好適である。また、基材3の表面3aの質感を活かす場合には、熱硬化性樹脂5の含浸により透明化する性質を有する、所謂透明紙を用いることが好ましい。原紙6の厚さは、特に制限されるものではないが、坪量20g/m2以上200g/m2以下の範囲が好ましい。
絵柄模様層7は、樹脂含浸化粧紙2に絵柄模様による意匠性を付与するための層である。絵柄模様層7は、染料又は顔料等の着色剤を適当なバインダー樹脂とともに希釈溶媒中に溶解又は分散してなる印刷インキ等を用いて形成される。印刷インキの種類は、特に制限されるものではなく、油性インキでもよいし、水性インキであってもよい。すなわち、印刷インキとしては、撥液性を有しない、通常の印刷インキを用いることができる。
特に、熱硬化性樹脂含浸適性を考慮すると、水性インキが最も好適である。水性インキは、油性インキと比較して、含浸樹脂の水溶液との馴染みがよい。それゆえ、水性インキを用いた場合、樹脂含浸化粧板1製造時の含浸工程において、樹脂含浸化粧板用化粧紙4に含浸樹脂を迅速且つ均一に含浸でき、さらに、含浸樹脂との一体化によって優れた絵柄模様層7に強度を発現できる。また、水性インキの種類は、特に制限されるものではないが、カゼイン、エマルジョン樹脂を主成分とするバインダー樹脂を含むものが好ましい。
エマルジョン樹脂としては、例えば、アクリル系、酢酸ビニル系、スチレン系、ウレタン系等を採用できる。また、バインダー樹脂には、カゼイン、エマルジョン樹脂の他に、インキの安定性を向上させるために、例えば、ポリビニルアルコール、ポリアクリルアミド等の水溶性樹脂や多糖類、セルロース誘導体等の水溶性高分子等を併用してもよい。
絵柄模様層7が形成する絵柄の種類は、特に制限されるものではなく、目的とする樹脂含浸化粧板1の用途に応じて、任意の絵柄を用いることができる。例えば、木目柄、石目柄、布目柄、抽象柄、幾何学図形、文字、記号、単色無地等、或いはこれらから選ばれる2種以上の組み合わせ等を採用できる。
発泡剤8は、樹脂含浸化粧紙2の表面の凹凸模様9によるグロスマット表現及び手触り感を付与するための層である。発泡剤8の種類は、特に制限されるものではなく、任意の発泡剤を用いることができる。例えば、アゾジカルボンアミド、アゾビスホルムアミド等のアゾ系、オキシベンゼンスルホニルヒドラジド、パラトルエンスルホニルヒドラジド等のヒドラジド系等の熱分解型の化学発泡剤、マイクロカプセル発泡剤等を採用できる。
特に、マイクロカプセル発泡剤が最も好適である。マイクロカプセル発泡剤は、カプセルと、カプセルに封入された揮発物質とを有している。そして、マイクロカプセル発泡剤は、揮発物質が揮発してカプセルを膨張させることで、発泡状態となる。カプセルの材料としては、例えば、塩化ビニリデンーアクリルニトリル共重合体等を用いることができる。また、揮発物質の材料としては、例えば、脂肪族炭化水素等を用いることができる。
また、発泡剤8の発泡開始温度は、100℃以上220℃以下が好ましい。100℃未満であると、発泡開始のタイミングが早いため、発泡後の発泡剤8が加熱加圧される時間が長くなり、発泡後の発泡剤8が潰され、グロスマット感や手触り感が弱くなる可能性がある。一方、220℃より高くなると、樹脂含浸化粧板1の製造時に金属板(鏡面板)を当接して行われる加熱加圧成型で、発泡剤8が十分に発泡されず、グロスマット感や手触り感が弱くなる可能性がある。より好適なのは、120℃以上200℃以下である。
なお、発泡剤8を、絵柄模様層7中に配置する場合には、発泡剤8は、絵柄模様層7が形成する絵柄の中で、その絵柄の他の部分よりも相対的に明度の低い暗色部分に混入して、絵柄模様層7中に配置する。暗色部分の体積と発泡剤8の体積との合計値に占める発泡剤8の体積の比率は、70%以上が好ましい。特に、90%以上が最も好適である。
また、発泡剤8の印刷インキの印刷方法は、絵柄模様層7と同様に、特に制限されるものではなく、例えば、グラビア印刷法、オフセット印刷法、スクリーン印刷法、フレキソ印刷法、凸版印刷法、インクジェット印刷法等、任意の印刷方法を用いることができる。
次に、本発明の実施形態に係る樹脂含浸化粧板1の製造方法について説明する。
まず、熱硬化性樹脂5を水に溶解又は分散させた水系含浸液に樹脂含浸化粧板用化粧紙4を浸漬し、樹脂含浸化粧板用化粧紙4に熱硬化性樹脂5を含浸させる。
熱硬化性樹脂5としては、公知の樹脂含浸化粧板の製造時に使用される熱硬化性樹脂を用いることができる。例えば、メラミン系樹脂、エポキシ系樹脂、ジアリルフタレート系樹脂、ベンゾグアナミン系樹脂、ウレタン系樹脂、アルキド系樹脂、不飽和ポリエステル系樹脂、フェノール系樹脂、尿素系樹脂等を採用できる。熱硬化性樹脂5の含浸は、樹脂含浸化粧板用化粧紙4の、絵柄模様層7や発泡剤8が形成されている表面側から行ってもよいし、反対面側から行ってもよい。また、片面ずつ2回に分けて含浸させたり、両面を同時に含浸させたりしてもよい。熱硬化性樹脂5の含浸率(含浸後の樹脂含浸化粧板用化粧紙4の重量に占める含浸樹脂の重量の比率)は、20%以上80%以下が好ましい。特に、40%以上70%以下が最も好適である。また、物性に優れた樹脂含浸化粧板1を得るためには、原紙6の全体に均一に熱硬化性樹脂5を含浸させることが重要である。
連続ラミネート方式を用いた場合、樹脂含浸化粧板1の表面形状は、連続ラミネート方式で使用される金属板や金属製無端ベルト、硬化型樹脂等で作製されたエンボスシートの表面形状がそのまま賦形されたものとなる。それゆえ、金属板や金属製無端ベルト、硬化型樹脂等で作製されたエンボスシートとして、表面を鏡面状等の平滑に研磨したものを用いることで、表面の光沢度や平滑性に優れた樹脂含浸化粧板1を得ることができる。
勿論、必要に応じて、所望の任意の艶消状やテクスチャー状の金属板や金属製無端ベルト、硬化型樹脂等で作製されたエンボスシートを用いることで、目的とする樹脂含浸化粧板1の用途に応じて任意の表面仕上げ状態の樹脂含浸化粧板1を得ることも可能である。
本発明の樹脂含浸化粧板1は、以上に詳述した実施の形態に限定されるものではなく、本発明の趣旨を逸脱しない範囲において、種々の変形を加えて実施することができる。
さらに、本発明の実施形態に係る樹脂含浸化粧板用化粧紙4は、絵柄模様層7が形成する絵柄と発泡剤8の配置位置とが同調しているため、絵柄模様層7が形成する絵柄と樹脂含浸化粧板1の表面の凹凸模様9とが意匠的に同調した樹脂含浸化粧板1を形成できる。
また、本発明の実施形態に係る樹脂含浸化粧板用化粧紙4は、発泡剤8が発泡前の平均粒径が絵柄模様層7の層厚の2/3倍以上50倍以下である。それゆえ、適切な凹凸模様9を形成でき、グロスマット感、手触り感、耐傷付性に優れた樹脂含浸化粧板1を提供できる。
また、本発明の実施形態に係る樹脂含浸化粧板1は、樹脂含浸化粧紙2と、樹脂含浸化粧紙2と一体化された基材3とを備えるようにした。そのため、コストを抑えつつ、グロスマット表現及び手触り感に優れた樹脂含浸化粧板1を提供することができる。
(実施例1)
まず、図1に示すように、原紙6として、吸水性のよい坪量80g/m2の化粧紙用チタン紙を用意した。続いて、原紙6の一方の面(表面6a)に、カゼインを主成分とした水性インキで木目模様を印刷して絵柄模様層7を形成した。印刷方法としては、ダイレクトグラビア印刷方式を用いた。続いて、インラインで、絵柄模様層7の表面2aに、発泡剤8を含有したカゼインを主成分とした水性インキで、絵柄模様層7の木目模様と意匠的に同調した導管模様を印刷して、導管模様状に発泡剤8を配置して、樹脂含浸化粧板用化粧紙4を形成した。印刷方法としては、ダイレクトグラビア印刷方式を用いた。発泡剤8としては、発泡後の粒径が120μm、発泡開始温度が180℃となるものを用いた。
比較例1では、発泡剤8として、発泡後の粒径が10μmとなるものを用いた。それ以外は、実施例1と同じ材料・手順で、樹脂含浸化粧板1を作製した。
(比較例2)
比較例2では、発泡剤8として、発泡後の粒径が260μmとなるものを用いた。それ以外は、実施例1と同じ材料・手順で、樹脂含浸化粧板1を作製した。
(比較例3)
比較例3では、発泡剤8として、発泡開始温度が90℃のものを用いた。それ以外は、実施例1と同じ材料・手順で、樹脂含浸化粧板1を作製した。
(比較例4)
比較例4では、発泡剤8として、発泡開始温度が230℃のものを用いた。それ以外は、実施例1と同じ材料・手順で、樹脂含浸化粧板1を作製した。
実施例1、比較例1~4の樹脂含浸化粧板1に対し、以下に示す性能評価を行なった。
(グロスマット表現試験)
グロスマット表現試験では、樹脂含浸化粧板1に発現されたグロスマット表現の程度について評価した。グロスマット表現が優れている場合を「◎」とし、グロスマット表現が十分である場合を「○」とし、グロスマット表現が殆どない場合を「△」とし、グロスマット表現が全くない場合を「×」とした。
手触り感試験では、樹脂含浸化粧板1に発現された手触り感の程度について評価した。手触り感が優れている場合を「◎」とし、手触り感が十分である場合を「○」とし、手触り感が殆どない場合を「△」とし、手触り感が全くない場合を「×」とした。
(耐傷付性試験)
耐傷付性試験では、樹脂含浸化粧板1にコイン引掻き試験を実施し、凹凸模様9の傷の付き方を評価した。傷が全くない場合を「◎」とし、傷が殆どない場合を「○」とし、浅いが目立つ傷がある場合を「△」とし、目立つ深い傷がある場合を「×」とした。
これらの評価結果を表1に示す。
具体的には、比較例1の樹脂含浸化粧板1は、発泡後の粒径が小さい発泡剤8を用いたため、グロスマット感や手触り感が弱くなり、グロスマット表現試験、手触り感試験が「×」となった。また、比較例2の樹脂含浸化粧板1は、発泡後の粒径が大きい発泡剤8を用いたため、発泡後の発泡剤8が脱落等して耐傷付性が弱くなり、耐傷付性試験が「×」となった。さらに、比較例3の樹脂含浸化粧板1は、発泡開始温度が低い発泡剤8を用いたため、発泡後の発泡剤8が加熱加圧される時間が長くなり、発泡後の発泡剤8が潰され、グロスマット表現試験が「△」となり、手触り感試験が「×」となった。また、比較例4の樹脂含浸化粧板1は、発泡開始温度が高い発泡剤8を用いたため、加熱加圧成型で発泡剤8が十分に発泡されず、グロスマット表現試験、手触り感試験が「△」となった。
したがって、実施例1の樹脂含浸化粧板1は、比較例1~4の樹脂含浸化粧板1よりも、グロスマット表現、手触り感、及び耐傷付性が良好であることが確認された。
Claims (4)
- 原紙、前記原紙の表面側に設けた絵柄模様層、及び前記絵柄模様層の表面上又は前記絵柄模様層中に配置された発泡後のマイクロカプセル発泡剤を備え、前記マイクロカプセル発泡剤は、120℃以上200℃以下の温度で発泡が開始され、発泡後の粒径が15μm以上250μm以下である樹脂含浸化粧板用化粧紙、並びに前記樹脂含浸化粧板用化粧紙に含浸された熱硬化性樹脂を備える樹脂含浸化粧紙と、
前記樹脂含浸化粧紙と一体化された基材と、を備えることを特徴とする樹脂含浸化粧板。 - 原紙、前記原紙の表面側に設けた絵柄模様層、及び前記絵柄模様層の表面上又は前記絵柄模様層中に配置された、発泡開始温度120℃以上200℃以下の未発泡のマイクロカプセル発泡剤を備える樹脂含浸化粧板用化粧紙、並びに前記樹脂含浸化粧板用化粧紙に含浸された熱硬化性樹脂を有する樹脂含浸化粧紙と、基材との積層体に加熱加圧成形を行い、前記樹脂含浸化粧紙と前記基材とを一体化させるとともに、前記加熱加圧成形時の熱によって、発泡後の粒径が15μm以上250μm以下となるように前記マイクロカプセル発泡剤を発泡させることを特徴とする樹脂含浸化粧板の製造方法。
- 前記樹脂含浸化粧板用化粧紙は、前記絵柄模様層が形成する絵柄と前記マイクロカプセル発泡剤の配置位置とが同調していることを特徴とする請求項2に記載の樹脂含浸化粧板の製造方法。
- 前記マイクロカプセル発泡剤は、発泡前の平均粒径が前記絵柄模様層の層厚の2/3倍以上50倍以下であることを特徴とする請求項2又は3に記載の樹脂含浸化粧板の製造方法。
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JPS5816846A (ja) * | 1981-07-24 | 1983-01-31 | 大日本印刷株式会社 | 木目模様化粧板の製造法 |
AU549226B2 (en) * | 1981-09-29 | 1986-01-23 | Dai Nippon Insatsu Kabushiki Kaisha | Embossing plastic sheet |
JPS58110250A (ja) * | 1981-12-24 | 1983-06-30 | 大日本印刷株式会社 | 同調エンボス化粧板の製造法 |
JPS59222348A (ja) * | 1983-06-01 | 1984-12-14 | 凸版印刷株式会社 | 凹凸模様化粧シ−トの製造方法 |
JPS62130849A (ja) | 1985-11-30 | 1987-06-13 | 大日本印刷株式会社 | 熱硬化性樹脂化粧板の製造法 |
JPH06226944A (ja) * | 1993-02-01 | 1994-08-16 | Dainippon Printing Co Ltd | 凹エンボスを有する化粧板の製造方法 |
JPH07310417A (ja) * | 1994-05-17 | 1995-11-28 | Toppan Printing Co Ltd | 化粧紙とその化粧紙を用いた化粧板の製造方法 |
JPH0839748A (ja) * | 1994-07-29 | 1996-02-13 | Toppan Printing Co Ltd | 同調エンボス化粧紙とその製造方法 |
JP4065337B2 (ja) * | 1995-03-30 | 2008-03-26 | スリーエム カンパニー | 塗膜複合体及び装飾シート |
JP3012193B2 (ja) | 1996-03-28 | 2000-02-21 | 大建工業株式会社 | 化粧板及びその製造方法 |
JPH1016374A (ja) * | 1996-06-28 | 1998-01-20 | Dainippon Printing Co Ltd | 木目化粧シ−ト |
US6139945A (en) * | 1997-11-25 | 2000-10-31 | Premark Rwp Holdings, Inc. | Polymeric foam substrate and its use as in combination with decorative surfaces |
RU2432202C2 (ru) * | 2006-06-08 | 2011-10-27 | Акцо Нобель Н.В. | Микросферы |
JP5568932B2 (ja) * | 2008-09-30 | 2014-08-13 | 大日本印刷株式会社 | 床材用化粧シート及び床用化粧材 |
JP2012206439A (ja) * | 2011-03-30 | 2012-10-25 | Dic Corp | 熱転写用フィルム、及び加飾成形品 |
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JP5914285B2 (ja) * | 2012-09-28 | 2016-05-11 | 北越紀州製紙株式会社 | 防滑性シート |
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