JP7054248B2 - 溶融性イントメッセント系難燃剤組成物 - Google Patents
溶融性イントメッセント系難燃剤組成物 Download PDFInfo
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- JP7054248B2 JP7054248B2 JP2019528073A JP2019528073A JP7054248B2 JP 7054248 B2 JP7054248 B2 JP 7054248B2 JP 2019528073 A JP2019528073 A JP 2019528073A JP 2019528073 A JP2019528073 A JP 2019528073A JP 7054248 B2 JP7054248 B2 JP 7054248B2
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- triazine
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- fiber
- diamino
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- 239000003063 flame retardant Substances 0.000 title description 86
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title description 85
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- 239000002131 composite material Substances 0.000 claims description 26
- NJYZCEFQAIUHSD-UHFFFAOYSA-N acetoguanamine Chemical compound CC1=NC(N)=NC(N)=N1 NJYZCEFQAIUHSD-UHFFFAOYSA-N 0.000 claims description 25
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- SWELIMKTDYHAOY-UHFFFAOYSA-N 2,4-diamino-6-hydroxypyrimidine Chemical compound NC1=CC(=O)N=C(N)N1 SWELIMKTDYHAOY-UHFFFAOYSA-N 0.000 claims description 10
- MJIWQHRXSLOUJN-UHFFFAOYSA-N 1,2,4-triazin-3-amine Chemical compound NC1=NC=CN=N1 MJIWQHRXSLOUJN-UHFFFAOYSA-N 0.000 claims description 6
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 6
- DPMZXMBOYHBELT-UHFFFAOYSA-N 1,3,5-trimethyl-1,3,5-triazinane Chemical compound CN1CN(C)CN(C)C1 DPMZXMBOYHBELT-UHFFFAOYSA-N 0.000 claims description 6
- LJVQHXICFCZRJN-UHFFFAOYSA-N 1h-1,2,4-triazole-5-carboxylic acid Chemical compound OC(=O)C1=NC=NN1 LJVQHXICFCZRJN-UHFFFAOYSA-N 0.000 claims description 6
- JTTIOYHBNXDJOD-UHFFFAOYSA-N 2,4,6-triaminopyrimidine Chemical compound NC1=CC(N)=NC(N)=N1 JTTIOYHBNXDJOD-UHFFFAOYSA-N 0.000 claims description 6
- NXFQWRWXEYTOTK-UHFFFAOYSA-N 2-methyl-4-amino-6-methoxy-s-triazine Chemical compound COC1=NC(C)=NC(N)=N1 NXFQWRWXEYTOTK-UHFFFAOYSA-N 0.000 claims description 6
- TZFOEYRGARRRGO-UHFFFAOYSA-N 2h-triazole-4,5-dicarboxylic acid Chemical compound OC(=O)C1=NNN=C1C(O)=O TZFOEYRGARRRGO-UHFFFAOYSA-N 0.000 claims description 6
- UIKGLXJNZXSPGV-UHFFFAOYSA-N 5,6-dimethyl-1,2,4-triazin-3-amine Chemical compound CC1=NN=C(N)N=C1C UIKGLXJNZXSPGV-UHFFFAOYSA-N 0.000 claims description 6
- WZUUZPAYWFIBDF-UHFFFAOYSA-N 5-amino-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound NC1=NNC(S)=N1 WZUUZPAYWFIBDF-UHFFFAOYSA-N 0.000 claims description 6
- YMIFDDZCSSDQHL-UHFFFAOYSA-N 6-[3-(trifluoromethyl)phenyl]-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=C(C=CC=2)C(F)(F)F)=N1 YMIFDDZCSSDQHL-UHFFFAOYSA-N 0.000 claims description 6
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- PKWIYNIDEDLDCJ-UHFFFAOYSA-N guanazole Chemical compound NC1=NNC(N)=N1 PKWIYNIDEDLDCJ-UHFFFAOYSA-N 0.000 claims description 6
- YAAWASYJIRZXSZ-UHFFFAOYSA-N pyrimidine-2,4-diamine Chemical compound NC1=CC=NC(N)=N1 YAAWASYJIRZXSZ-UHFFFAOYSA-N 0.000 claims description 6
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- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 10
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- 210000002268 wool Anatomy 0.000 description 6
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 5
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- 208000027418 Wounds and injury Diseases 0.000 description 4
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 4
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- QEGWXXRNPXRLHH-UHFFFAOYSA-N triazine;1,3,5-triazine-2,4,6-triamine Chemical compound C1=CN=NN=C1.NC1=NC(N)=NC(N)=N1 QEGWXXRNPXRLHH-UHFFFAOYSA-N 0.000 description 4
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- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
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- C08K5/0066—Flame-proofing or flame-retarding additives
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/3492—Triazines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
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Description
本出願は、2016年11月28日出願の米国仮特許出願第62/426,940号に基づく優先権を主張するものであり、その開示は参照により本明細書に組み込まれる。
Claims (4)
- 布の0.1~25重量%を構成し、第1のポリマー、および-50~400℃の範囲の融点を有する少なくとも1種の窒素化合物を含む、第1のセットの繊維、ならびに
第1のセットの繊維よりも高い融点を有する第2のポリマーを含む、第2のセットの繊維
を含む、布であり、
前記窒素化合物が、1,3,5-トリアジン、1,3,5-トリメチルヘキサヒドロ-1,3,5-トリアジン、3-アミノ-1,2,4-トリアジン、2-アミノ-4,6-ジクロロ-1,3,5-トリアジン、3-アミノ-5,6-ジメチル-1,2,4-トリアジン、2-アミノ-4-メトキシ-6-メチル-1,3,5-トリアジン、2,4-ジアミノ-6-メチル-1,3,5-トリアジン(アセトグアナミン)、2,4-ジアミノ-6-フェニル-1,3,5-トリアジン(ベンゾグアナミン)、2,4-ジアミノ-6-ヒドロキシピリミジン、3,5-ジアミノ-1,2,4-トリアゾール、2,4-ジアミノ-6-[3-(トリフルオロメチル)フェニル]-1,3,5-トリアジン、2,5-ジアミノ-1,3,4-チアジアゾール、1,2,3-トリアゾール-4,5-ジカルボン酸、アミトロール、3-アミノ-1,2,4-トリアゾール-5-チオール、2,4-ジアミノ-6-ヒドロキシピリミジン、1,2,4-トリアゾール-3-カルボン酸、2,4-ジアミノピリミジン、2,4,6-トリアミノピリミジン、トリアムテレン、および、これらの組合せからなる群から選択される、布。 - 前記窒素化合物が、アセトグアナミン、ベンゾグアナミン、または、これらの組合せである、請求項1に記載の布。
- 第1のセットの繊維および第2のセットの繊維を含む複合繊維であって、
第1のセットの繊維は、複合繊維の0.1重量%~25重量%であり、第1のセットの繊維はさらに、第1のセットの繊維の65重量%~99.5重量%であるポリマー、および第1のセットの繊維の0.5重量%~35重量%である窒素化合物を含み、
第2のセットの繊維は、複合繊維の75重量%~99.9重量%であり、第2のセットの繊維はさらに、ポリマーを含む、複合繊維であり、
前記窒素化合物が、1,3,5-トリアジン、1,3,5-トリメチルヘキサヒドロ-1,3,5-トリアジン、3-アミノ-1,2,4-トリアジン、2-アミノ-4,6-ジクロロ-1,3,5-トリアジン、3-アミノ-5,6-ジメチル-1,2,4-トリアジン、2-アミノ-4-メトキシ-6-メチル-1,3,5-トリアジン、2,4-ジアミノ-6-メチル-1,3,5-トリアジン(アセトグアナミン)、2,4-ジアミノ-6-フェニル-1,3,5-トリアジン(ベンゾグアナミン)、2,4-ジアミノ-6-ヒドロキシピリミジン、3,5-ジアミノ-1,2,4-トリアゾール、2,4-ジアミノ-6-[3-(トリフルオロメチル)フェニル]-1,3,5-トリアジン、2,5-ジアミノ-1,3,4-チアジアゾール、1,2,3-トリアゾール-4,5-ジカルボン酸、アミトロール、3-アミノ-1,2,4-トリアゾール-5-チオール、2,4-ジアミノ-6-ヒドロキシピリミジン、1,2,4-トリアゾール-3-カルボン酸、2,4-ジアミノピリミジン、2,4,6-トリアミノピリミジン、トリアムテレン、および、これらの組合せからなる群から選択される、複合繊維。 - 前記窒素化合物が、アセトグアナミン、ベンゾグアナミン、または、これらの組合せである、請求項3に記載の複合繊維。
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